Subject : Chemistry Time : 90 min JPDPP Test No.

: 08 Marks:125 TARGET IITJEE - 2011

Name : ____________________________________________________ Batch : ___________ Roll no.___________

SOLID STATE (C8)

SECTION - I
Straight Objective Type
This section contains 10 multiple choice questions. Each question has choices (A), (B), (C) and (D),
out of which ONLY ONE is correct.

1. Solids which do not show the same physical properties in different directions are called
(A) Pseudo solids (B) Isotropic solids
(C) Polymorphic solids (D*) Anisotropic solids

2. The unit cell of diamond is made up of

(A) 6 carbon atoms, 4 atoms constitue ccp and two atoms occupy half of octahedral voids
(B )8 carbon atoms, 4 atoms constitue ccp and 4 atoms occupy all the octahedral voids
(C*) 8 carbon atoms ,4 atoms constitue fcc lattice and 4 atoms occupy half of the tetrahedral voids
alternately
(D) 12 carbon atoms 4, atoms from fcc lattice and 8 atoms occupy all the tetrahedral holes.

3. Face-centred cubic packing of uniform spherical units is respresented by

(A) ABAB.... (B) ABBAAB.....
(C*) ABCABC... (D) ABCACBABA..

4. In a cubic closest packed structure of mixed oxides, the lattice is made up of oxide ions, 20% of tetrahe-
dral voids are occupied by divalent X 2  ions and 50% of the octahedral voids are occupied by trivalent Y 3 
ions. The formula of the oxide is :
(A) X 2 YO4 (B*) X 4 Y5 O10
(C) X5 Y4 O10 (D) XY2O 4

5. Dopping of AgCl crystals with CdCl2 results in

(A) Schottky defect (B) Frenkel defect
(C*) Substitutional cation vacancy (D) Formation of F-centers

6. In a metal oxide, the oxide ions are arranged in hexagonal closed packing and the metal ions (M) occupy
two third of octahedral voids. The formula of the oxide is
(A) MO2 (B) M2 O
(C*) M2O3 (D) MO

0
7. The radius ratio Cs to Cl is 0.90. If the radius of Cl ion is 1.80 A , the false statement regarding the
CsCl structure is
0
(A) The distance between the centers of Cl ions is greater than 3.60 A .
0
(B*) The distance between the centers of two Cl ions is 3.60 A
0
(C) The distance between Cs ions and Cl is 3.42 A .
0
(D) The distance between two Cs ion is greater than 3.42 A .
8. The egde length of face centerd unit cubic cell of an ionic solid MX is 508 pm. If the radius M ion is 110.
pm, the radius of X  ion is
(A) 618 pm (B) 398 om
(C) 288 pm (D*) 144 pm

9. Olive oil when allowed to cool slowely gets solidified and forms a solid over a range of temperature. Best
forms description of the solid based on above observation is
(A) inoic solid (B) covalent network solid
(C) metallic solid (D*) molecular solid

10. Select the correct statements

(A) The non-stoichiometric from of NaCl is yellow and that of KCl is blue lilac.
(B) Solids containing F-centers (Farbe) are paramagentic.
(C) Conduction by electrons is known as n-type supper conduction
(D*) All the above are correct

SECTION - II
Multiple Correct Answers Type
This section contains 5 multiple correct answer(s) type questions. Each question has 4 choices
(A), (B), (C) and (D), out of which ONE OR MORE is/are correct.

11. The hcp and ccp structure for a given element will have
(A) the same density (B) the same fraction of unoccupied space
(C) the same coordinates number (D*) All of the above

12. Which of the following is/are correct statement(s) about ccp ?

(A*) There are tetrahedral sites (B*) There are octahedral sites
(C) There are cubic sites (D) All of the above

13. For the structure of zinc blende, the correct statement is/are
(A) S2  ions form hcp
(B*) S2  ions form ccp
(C) S2  ions occupy octahedral sites and Zn2  ions tetrahedral sites
(D*) Both Zn2  and S2  ions occupy tetrahedral sitres.

14. Select the covalent crystal (s)

(A*) Diamond (B*) Graphite
(C) Zinc sulphide (D) Silver iodide

15. Lattice energy of a soild increases if

(A) ions are large (B*) ions are small
(C) ions are of equal size (D) None of these

SECTION - III
Reasoning Type
This section contains 2 reasoning type questions. Each question has 4 choices (A), (B), (C) and (D),
out of which ONLY ONE is correct.

16. Statement 1 : In any ionic solid [MX] with Schottky defects, the number of positive and negative ions are
same.
Statement 2 : Equal number of cation and anion vacancies are present.
(A*) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
17. Statement 1: Due to Freknel defect, there is no effect on the density of the cystalline solid.

Statement 2: In Freknel defect, no cation or anion leaves the crystal.

(A*) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True

SECTION - IV
Comprehension Type
This section contains 2 paragraphs. Based open each paragraph, there are 3 multiple choice questions. Each
question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

Paragraph for Question Nos. 18 to 20

Imperfection in Ionic solids: In an ideal crystal there must be regular repeating arrangemnt of the constitut
ing particles and its entropy must be zero at absolute zero temperature. However, it is impossible to obtain
an ideal crystal and it suffers from certain defects called imperfections. In pure crystal, these defects arise
either due to disorder or dislocation of the constituting particles from their normal positions or to the move
ment of the particles even at absolute zero temperature. Such defects increase with rise in temperature. In
addition to this, certain defects arise due to the presence of some impurities. Such defects not only modify
the existing properties of the crystalline solids but also impart certain new charactristics to them.
In pure crystal, e.g. silicon or germanium at 0K, the electrons are present fully occupied lowest
energy states and are not expected to conduct any electricity. However at temperature above 0K, some
electrons leave their bonds and become free to move in the crystal lattice, giving rise to electrical conductiv
ity. The electron deficient bonds, called holes (+ ively charged ) and thermally mobile electrons move in
opposite directions under the electric field.
Stoichimetric point defects include (1) Schottky defects, which arise due to missing of both cations
and anions from their lattice sites without disturbing the stochiometry and (2) Frenkel defects, which arise
due to misplacement of certain ions in the crystal lattice. The fromer defects gives rise to decrease in density
of the crystal and the latter lead to no change of density.
Another type of defects are non-stoichiometric defects where the cations and anoins are not present
in the stoichiometric ratio. In metal excess defect, metal ions or positive ions are in excess as compared to
anions of non-metals stoichiometrically. In the other hand in metal deficient defect, the cations are in lesser
proportion than stoichiometric value. Since the crystal is neutral electrically,the balance of charge is
maintained by free electrons or extra positive charges. The metal excess defects give rise to conduction of
electricity due to the presence of free electrons. Aslo crystals having metal excess defects are paramagentic
and coloured due to the presence of electrons in the anions vacancies.
Impurity defects arise when some foregion atoms are presnt at the lattice sites in place of the host
atoms or at the vacant interstitial sites.
When 15 groupes elements like P or As are doped into Si or Ge, the added inpurity atoms occupy
the lattice sites forming four covalent bonds with 4 Si/Ge atoms leaving an extra electron free to move. Such
a crystal is said to be n-type semi conductor because the conduction of electricity is due to the movement of
extra unbonded electrons.
If droping of a colvant crystals of 14 group elements are caused by addition of small amounts of
elements of group 13, e.g. Al of Ga with three valence electrons, one covlant bond formed will be electron
deficient and acts as a positive hole. The presence of such holes in the crystal leads to electrical conductivity
and the crystal is said to be p-type semiconductor.

18. When LiCl is heated into the vapour of lithium, the crystal acquires pink color. This is due to
(A) Schottky defects (B) Frenkel defects
(C*) Metal excess defects leading to F-centers (D) Electronic defects

19. Strongly heated ZnO crystal can conduct electricity. This is due to
(A) Movement of extra Zn2  ions presnt in the interstitial sites.
(B*) Movement of electrons in the anion vacancies
(C) Movement of both Zn2  ions and electrons
(D) NOne of these
20. AgCl is crystallizes from molten AgCl containing a little CdCl2 . The solid obtained will have.
(A*) cationic vacancies equal to number of Cd2 ions incorporated
(B) cationic vacancies equal to double the number of Cd2 ions
(C) anionic vacancies
(D) neither cationic nor anionic vacancies

Paragraph for Question Nos. 21 to 23

n A
Density () of a crystal  gm cm3
NA  a3
where n = number of atoms per unit cell
A = Mass of structural unit ( atomic weight/Formular wt.)
NA = Avogadro’s number  6.023  1023
a = edge length of the cell

21. At room temperature sodium (Na) crystallises in a body centred cubic lattice with edge length equal to
0
4.24 A. The density of sodium will be
(A) 2.0gm cm3 (B*) 1.0 gm cm 3 (C) 23.0 gm cm 3 (D) 4.0 gm cm 3

22. An element crystallizes in a structure having fcc unit cell of an edge length 200 pm. What will be the density
of this element if 200 gm of it contains 24  1023 atoms ?
(A) 24  1023 gm cm 3 (B*) 41.6 gm cm 3 (C) 2.46 gm cm 3 (D) None of these

23. Copper crystal fcc structure. Atomic radius of copper is 128 pm. The egde length of copper crystal is
(A) 36.2 pm (B) 362 nm (C) 3.62  10 10 cm (D*) 362  10 10 cm

SECTION - V
Matrix - Match Type
p q r s
This section contains 2 questions. Each question contains statements given in two
A p q r s
columns, which have to be matched. The statements in Column-I are labelled p q r s
B
A, B, C and D, while the statements in Column-II are labelled p, q, r and s. Any C p q r s
given statement in Column-I can have correct matching with ONE OR MORE D p q r s
statement(s) in Column-II. The appropriate bubbles corresponding to the answers
to these questions have to be darkened as illustrated in the following example.If the correct matches are A-p,
s ; B-q and r; C-p and q; and D-s then the correct darkening of bubbles will look like the following :

24. Match electrical properties listed in column II with the materials listed in column l.

Column I Column II

(A) Pure crystal of silicon at 0 K (P) Semi-conductor-p-holes carry current

(B) Pure crystal of silicon at 400 K (Q) Semiconductor-electrons carry current
(C) Silicon doped with arsenic impurity (R) Insulator
(D) Silicon crystal dopped with gallium (S) Semiconductor-equal number of p-holes and electrons
carry current
Ans: A-R , B-S , C-Q, D-P.
25. Match the following

Column I Column II

(A) Quartz (P) Three corners of SiO 4 4  tetrahedron are shared

(B) Amorphous SiO2 (Q) Two corners of SiO44  are shared
(C) Sheet Silicates (R) All four corners of SiO 4 4  are shared
(D) Cyclic silicates (S) Corners of SiO 4 4  are randomly linked

Ans: A-R, B-S, C-P, D-Q .

SECTION - VI
Integer Answer Type

This section contains 6 questions. The answer to each of the questions is a

Double digit integer, ranging from 0 to 99. The appropriate bubble below the
respective question number in the ORS have to be darkened.

0
26 The unit cell cube length for LiCl (NaCl structure) is 5.14 A . Assuming anion-anion constant, calculate the
ionic radius for chloride ion.
[Ans: 2 ]

27. A compound CuCl has face-centerd cubic structure. Its density is 3.4gcm3 .What is the length of unit cell ?

[ Ans: 6 ]

28. A f.c.c. element (atomic mass = 60 ) has a cell edge of 400 pm. What is its density ?
[ Ans: 6 ]

0
29 At room temperature, sodium crystallizes in a body centred cubic lattice with a  4.24 A. Calculate
theoretical density of sodium ( At.wt. of Na= 23 ).
[ Ans: 1 ]
30 The density of solid argon is 1.65 g/mL at 2330 C . If the argon atom is assumed to be sphere of radius
1.54 x 10-8cm, what percentage of solid argon is apparenly empty space ? ( At.wt. of Ar = 40 ).
[ Ans: 62]
31. In a compound AB, the ionic radii A  and B  are 88 pm and 200 pm respectively. What is the
co-ordinates number of A  ?
[Ans: 6]

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 Subject : Chemistry JP DPP Test No. : 08 TARGET IITJEE - 2011

Name : ____________________________________________ Batch:____________ Roll No.__________

SOLID STATE (C8)

Marking Scheme

1. For each question in Section–I , you will be awarded 3 marks if you darken the bubble corresponding to the correct answer
and zero marks if no bubble is darkened. In case of bubbling of incorrect answer, minus one (–1) mark will be awarded.

2. For each question in Section–II , you will be awarded 5 marks if you darken the bubble corresponding to the correct answer
and zero marks if no bubble is darkened. In case of bubbling of incorrect answer, minus two (–2) mark will be awarded.

3 For each question in Section–III, you will be awarded 3 marks if you darken the bubble corresponding to the correct answer,
and zero mark if no bubble is darkened. In case of bubbling of incorrect answer, minus one (–1) mark will be awarded.

4. For each question in Section–IV, you will be awarded 4 marks if you darken the bubble corresponding to the correct answer,
and zero mark if no bubble is darkened. In case of bubbling of incorrect answer, minus one (–1) mark will be awarded.

5. For each question in Section–V, you will be awarded 2 marks for each row in which you have darkened the bubble(s)
corresponding to the correct answer. Thus, each question in this section carries a maximum of 8marks. There is no negative
marking for incorrect answer(s) for this this section.

6. For each question in Section–VI, you will be awarded 4 marks if you darken the bubble corresponding to the correct answer,
and zero mark if no bubble is darkened. In case of bubbling of incorrect answer, minus one (–1) mark will be awarded.

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3 (B)
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5 (D)
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(B)
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(C)
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(D)
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29
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Mistakes to be rectified : ________________________________________________________________

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