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Abstract
Research and development of nanofilled polymers has greatly increased in recent years. Research into the use of carbon nanotubes in the early 90’s prompted
investigation into other nanoparticles. These nanofillers come in the form of platelets of a thickness as small as a couple of nanometers. They will usually stack on
top of each other to form tactoids and these tactoids can contain up to hundreds of layers of platelets. Because of the high polarity of these nanoclays they do not
mix readily with polymers, as such a compatibiliser is needed to provide a link between polymer and nanoclay[1]. Maleic Anyhdride is one commonly use grafting
agent for this task[2]. Grafting is a process in which monomers are covalently bonded onto the polymer chain. Considerable work has been done in recent years on
the different techniques of grafting. These techniques include chemical, radiation and reactive extrusion. Of these processes this study is concerned with radical
induced grafting by reactive extrusion. Fusabond is the commercially available Maleic Anhydride grafted polyethylene and this project aims to replace this.
Methodology
Conclusions
From the results obtained it may be seen that
grafting of Maleic Anhydride onto the
polyethylene backbone is possible. It is
dependant on a number of factors and it has
been shown in this work that benzoyl peroxide is
Fig 8: Flexular Modulus data for blends containing 3wt% an unsuitable initiator. The use of DiCumyl
Fig 6: FTIR spectra for Run 15 and Fusabond of Runs 1-21, Fusabond and virgin HDPE Peroxide produced good grafting yields.
Furthermore the improvement in properties of
nanocomposites is not solely dependant on the
% Maleic Anhydride present in the compatibiliser,
rheology can affect how miscible the polymer,
compatibilser and additive are.
References
1 Fracture toughness of high density polyrthylene-g-MA/montmorillonite
nanocomposites (S.C. Tjong, S.P. Bao, Composites Science and
Technology; 67;2007;314-323)
2 The synthesis of Polyolefin graft co polymers by reactive extrusion (G.
Fig 7: % Maleic anhydride grafted for runs 1-21 made Moad Polymer Science 1999; 24; 81-142 )
Fig 9: Flexular Strength data for blends containing 3wt% 3 www. Dupont..com
with dicumyl peroxide as the initiator and Fusabond of Runs 1-21, Fusabond and virgin HDPE 4 Nanocomposite science and technology (Pulickel M. Ajayan)
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