Académique Documents
Professionnel Documents
Culture Documents
Akihisa Inoue
Institute for Materials Research, Tohoku University, Sendai 980-77, Japan
Tsuyoshi Masumoto
Research Institute of Electrical and Magnetic Materials, Sendai 982, Japan
Abstract- This paper reviews our recent results on some resulting from the Invar effect in the amorphous state. On the
applications of new nanocrystalline soft magnetic Fe-M-B (M= contrary, the crystallized nanocrystalline alloys have
Zr, Hf, Nb) alloy ribbons “NANOPERM?.” NANOPERM? has excellent soft magnetic properties as well as high B, values
a structure consisting of nanoscale bcc grains and a small above 1.5 T mainly because of the higher Fe contents than
amount of an intergranular amorphous layer. N A N O P E W
those in the Fe-metalloid based nanocrystalline alloys, which
exhibits high saturation magnetic flux density above 1.5 T as
well as excellent soft magnetic properties. Furthermore, its results from the high glass forming ability of M elements.
remanence ratio can be controlled according to the demands of The nanocrystalline temary Fe-M-B alloys consist of a-Fe
various applications. Toroidal cores with gap, common mode grains about 10-20 nm in size surrounded by a small amount
choke coils, ISDN (integrated service digital network) of an intergranular layer [7], [SI. The intergranular
interface pulse transformers and flux gate magnetic amorphous phase has a rather high Curie temperature (T,)
detectors made of “NANOPERM@” have been developed. The resulting from large amounts of M and B elements in the
excellent characteristics of the components were confirmed in phase, which causes strong magnetic exchange coupling
trial. N A N O P E W is therefore expected to be used widely in
between the a-Fe grains. Furthermore, the nanoscale a-Fe
the magnetic application field.
grains contain small amounts of M and B elements, which
results in small magnetostriction. Consequently, good soft
I. INTRODUCTION
magnetic properties should be obtained [7].
We have further tried to synthesize a fine nanocrystalline
In the last decade, some nanocrystalline soft magnetic
structure in the Fe-M-B alloys to obtain excellent magnetic
alloys consisting of bcc nanoscale crystalline phase have been
properties. Recently, we have succeeded in the development
obtained by crystallizing melt-spun amorphous ribbons. The
of a new type of nanocrystalline soft magnetic Fe-M-B based
alloys are classified into two groups. One is composed of Fe-
metalloid amorphous based alloys such as Fe-Si-B-Nb-Cu [11 alloy “NANOPElUVf@”with high B,, above 1.5 T, as well as
[2] and Fe-P-C-Ge-Cu [3] containing elements immiscible
excellent soft magnetic properties [7], [SI. Figure 1 shows the
with Fe such as Cu or Au. The simultaneous addition of Nb dependence of effective permeability ( k )at 1 kHz,coercivity
and Cu or Ge and Cu is essential for achieving the (HJ and T, of the intergranular amorphous phase on the
nanocrystalline structure which results in excellent soft grain size (0) and the magnetostriction (4)for Fe-M-B(-Cu)
magnetic properties. However, the alloys exhibit lower alloys. The soft magnetic properties strongly depend on D
saturation magnetic flux density (B,) (up to 1.3 T) than the and 4, and can be significantly improved with the decrease
Fe-metalloid amorphous alloys mainly because of the in D and 141 and the increase in T, of the intergranular
decrease in Fe content by addition of alloying elements. The amorphous phase by optimizing the chemical composition
origin of the good soft magnetic properties of the and adding small amount of elements. It is to be noted that
nanocrystalline alloys has been explained on the basis of the Fe-Zr-Nb-B-Cu alloy system has the small grain size of 7 nm,
random anisotropy model [2] which describes the nearly zero-magnetostriction, high T,(amor.) about 500 K,
magnetocrystalline anisotropy as averaged out due to strong high k above lo5 at 1 kHz,and low H, below 2 Nm. Table I
ferromagnetic exchange coupling between the ferromagnetic summarizes the properties of the nanocrystalline Fe-M-B
grains. based alloys “NANOPERM@.”Figure 2 shows the relation
The second group is composed of Fe-M-B (M = Zr, Hf, Nb) between B, and k at 1 kHz for NANOPERM@, for
based alloys we reported [4]-[7]. It has been already known nanocrystalline Fe-Si-B-Nb-Cu alloys [9] and for
that the alloy systems have inferior magnetic properties conventional soft magnetic materials. Since NANOPEW
appears at the upper right in the figure among the materials,
it can be said that N A N O P E W is the best for the
Manuscript received March 25, 1997. achievement of both high and high B,. For example, the
A Makino, +81-258-24-4111, fax +81-258-24-4145, makinoak@alps.co.jp;
T. Hatanai, hatanait@alps.co.jp; Y. Naitoh, naitohyu@alps.co.jp; T. Bitoh,
nanocrystalline Fe85 Z r 33Nb33B68cu1 alloy exhibits high iu,
bitohter@aIsp.co.jp. of 16x104 and high B, of 1.57 T and nearly zero
0018-9464/97$10.00 0 1997 IEEE
Authorized licensed use limited to: TOHOKU UNIVERSITY. Downloaded on March 09,2010 at 01:30:35 EST from IEEE Xplore. Restrictions apply.
3794
TABLE I
SAMPLE THICKNESS (i), GRAIN SIZE (D),
SATURATION MAGNETIC FLUX DENSITY (Es),
l75Rh4EABLXTY &), COERcIvrrY (HJ, MAGNETOSTRICTION (A),
ELECTFSCAL RESISTIBILITY @) AND CORE LOSS (w
FOR NANOCRYSTALLINE Fe-M-B BASEDALLOYS, NANOCRYSTALLINE Fe-Si-B-Nb-CuALLOYS AND
CONVENTIONALSOFT MAGNETIC ALLOYS.
3
magnetos~ction[SI.
Figure 3 s m ~ z e expected
s app~ication fields for 1
together with magnetic ch
are required for each applications. N 1
high B,, ,&, low core loss (W)and sufficiently small A,
n
simultaneously. Furthennore, remanence ratio (B,/B,) can be E
controlled according to the dem e
In this paper, we present some
0
which should indicate that N
core material in many kinds of w
.-
v)
.-c
11. EXPERIMENTAL
PROCEDURE E
en
Alloy ingots were prepared by induction melting in an
Ar atmosphere. A single-roller melt-spinning method in
an Ar atmosphere was used to produce rapidly solidified
NANOPERM@ribbons 15 m m in width and 15-20 pm in 4
thickness. The as-quenched ribbons were slit and wound
into toroidal cores or chemically etched into rings to be 4
used as samples. The samples were annealed in vacuum to
prevent oxidation. The annealing treatment was carried
out by keeping the samples at 793-923 K for 60-1800 s.
The samples were usually annealed without magnetic
field. -1 1 2
tu ration
Fig. 1. Dependence of f i at 1 kHz,Hc and T, of the intergranular amorphous
phase on D and & for Fe-M-B(-Cu) alloys crystallized under optimum
conditions.
Authorized licensed use limited to: TOHOKU UNIVERSITY. Downloaded on March 09,2010 at 01:30:35 EST from IEEE Xplore. Restrictions apply.
3795
Power transformers
Distribution transformers
. Power transformers for
switched power supplies
Data communication
interface components
- Pulse transformers
EM1 prevention
components
- Common mode choke coils
Magnetic heads
Sensors
. Current transformers
. Magnetic direction sensors
Magnetic shielding
Reacto i s
. Magnetic saturable choke coils
1. Magnetic switching cores I
Fig. 3. Magnetic characterizations and application fields for NANOPERM"
Authorized licensed use limited to: TOHOKU UNIVERSITY. Downloaded on March 09,2010 at 01:30:35 EST from IEEE Xplore. Restrictions apply.
3196
Authorized licensed use limited to: TOHOKU UNIVERSITY. Downloaded on March 09,2010 at 01:30:35 EST from IEEE Xplore. Restrictions apply.
3191
Figure 11 shows the characteristics of the flux gate 1o3 1o4 1o5 1o6
magnetic detectors made of NANOPERM" and Permalloy, Frequency, f (Hz)
which are used for magnetic direction sensors. Chemically
etched rings were used for the core. An ac magnetic field (f Fig. 8. Frequency dependence of impedance for pulse transformers made of
= 3.8 kHi) was applied to the core to change the core NANOPERM" and MnZn-ferrite. The broken line shows the required
impedance by ITU-T 1.430 standards.
Authorized licensed use limited to: TOHOKU UNIVERSITY. Downloaded on March 09,2010 at 01:30:35 EST from IEEE Xplore. Restrictions apply.
3798
L -I
f = 3.8 kHz
40 L
U
-f 30
c
(II
+ 20
I!
1 f=10kHz
We have succeeded in the development of a new type of 9 (a) Permalloy (b) NANOPERP
-
c
nanocrystalline soft magnetic material ‘ c ~ ~ ~ ~a ~ ~ ~ * y y
with high B, above 1.5 T, as well as excellent soft magnetic !
F
i
a
properties. The excellent characteristics of a toroidal core L
0
with a gap, a common mode choke coil, a pulse- a,
Ln
transformer and a flux gate magnetic detector made of 2
5?
NANQPEM* were proved experimentally. c
[I] Y. Yoshizawa, S. Oguma, and K. Yamauchi, “New Fe-based soft [6] A. Makino, A. Inoue, and T. Masumoto, “Soft magnetic properties of
magnetic alloys composed of ultrafine grain structure,” J. Appl. Pys., vol. nanocrystalline Fe-M-B (M = Zr, m, Nb) alloys with high
64, pp. 6044-6046, November 1988. magnetizationq” Nanostruct.. Mater., vol. 6, pp. 985-988, May 1995.
[2] G. Herzer, “6rain structure and magnetism of nanorrystallie [7] A Makino, A Inoue, and T. Masumoto, “Nanocrystalline soft magnetic
ferromagnets,” IEEE Trans. Mug., vol. 25, pp. 3327-3329, September Fe-M-B (M = Zr, Hf, Nb) alloys produces by crystallization of
1989. amorphous phase,”Mater. Truns. JIM, vol. 36, pp. 924-938, July 1995
[3] Y. Fujii, H. Fujita, A. Seki, and T. Tomida, “Magnetic properties of fine [8] A. M h o , T. Hatanai, A Inoue, and T. Masumoto, “Nanocrystalline
crystalline Fe-P-C-Cu-X alloys,” J. Appl. Phys., vol. 70, pp. 6241-6243, soft magnetic Fe-M-B (M = Zr, W, Nb) alloys and their applications,”
November 1991. Mater. SCJ.Eng.,in press.
[4] K. Suzuki, N. Kataoka, A. Inoue, A. Makino, and T. Masumoto, “High [9] Y. Yoshizawa, S. Oguma, A Hiraki and K. Yamauchi, “Development of
saturation magnetization and soft magnetic properties of bcc Fe-Zr-B soft magnetic materials “FINEMET” composed of ultrahe grain
alloys with ultrafime grain structure,” Mater. Trans. JIM, vol. 31, pp. structure,” H~tuchiMetals Technical Review, vol. 5, pp. 13-20, 1989.
743-746, August 1990. [lo] Y. Naitoh, T. Bitoh, T. Hatanai, A Makino, A Inoue, and T. Masumoto,
[5] A. Makino, K. Suzuki, A Inoue, and T. Masumoto, “Low Core Loss of a “Development of common mode choke coil made of new nanocrystalline
bcc Fe86Zr7B6CuLAlloy with Nanoscale Grain Size,” Mater. Trans. JA4, soft magnetic alloy NANOPERM”,” SCJ.Rept. Res. Inst. Tohoku Univ.A,
vol. 32, pp. 551-556, June 1991. vol. 43, pp. 161-165, March 1997.
Authorized licensed use limited to: TOHOKU UNIVERSITY. Downloaded on March 09,2010 at 01:30:35 EST from IEEE Xplore. Restrictions apply.