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• ∆S = -(∂∆G/∂T)p = nF(∂Erxn/∂T)p
E = Eo’ + (2.303RT/nF)log[Ox]/[Red]
Eo’ = Eo + (2.303RT/nF)log γox/γred
Reference Electrodes
E = Eo + (2.303RT/nF) log[Ox]/[Red]
Reference Electrodes
Cu/Zn/Zn+2, Cl-/AgCl/Ag/Cu’
Cu’
¾ Ecell is sum of several interfacial
potentials and none can be measured
Ag
independently.
Electrolyte φCu’ - φCu
φ
Zn ¾ Maintain constant interfacial potentials
Cu
at all interfaces then change in E must
be due to changes at electrode-solution
interface (Zn/electrolyte).
Distance
Electrochemical Potentials
Junction Potentials
¾ Zn+2 energy state depends on local chemical and electrical
environment.
Cu/Zn/Zn+2/Cu+2/Cu’
zi uiCi v (cm/s)
ti = u = E (V/cm) {cm2/V-s}
Σ zj ujCj
Junction Potentials