Problem 10.

27 Komponen
Methane (1)
T= 373.15 K Ethane (2)
R= 83.1446 cm3.bar/K.mol Propane (3)

Tc (K) Zcij
190.60 241.23 265.49 0.286 0.283
241.23 305.30 336.01 0.283 0.279
265.49 336.01 369.80 0.281 0.278

Vcij (cm3/mol) 𝜔𝑖𝑗

98.6 120.5 143.4 0.012 0.056
120.5 145.5 171.3 0.056 0.100
143.4 171.3 200 0.082 0.126

Trij (K) Pcij (bar)

1.958 1.547 1.406 45.990 47.008
1.547 1.222 1.111 47.008 48.720
1.406 1.111 1.009 43.261 45.255

B0 Bij (cm3/mol)
-0.061 -0.127 -0.162 -20.502 -51.515
-0.127 -0.223 -0.274 -51.515 -112.854
-0.162 -0.274 -0.333 -78.453 -166.840

B1 𝛿
0.129 0.111 0.098 0 30.33
0.111 0.065 0.028 30.33 0
0.098 0.028 -0.027 107.52 23.09

∅ ̂_1 1.019 𝛿 12 30.327

∅ ̂_2 0.881 𝛿 23 23.094
∅ ̂_3 0.775 𝛿 13 107.516

𝑓 ̂_1 7.491 bar

𝑓 ̂_2 13.255 bar
𝑓 ̂_3 9.766 bar
 Yi Condition
0.21
0.43 P= 35 bar
0.36 T= 100 °∁

Zcij
0.281
0.278
0.276

0.082
0.126
0.152

Pcij (bar)
43.261
45.255
42.480

(cm3/mol)
-78.453
-166.840
-243.919

107.52
23.09
0
Komponen Yi Condition
CO2 0.60
CO 0.20 P= 50 bar
NO 0.15 T= 50 °∁
NO2 0.05

T= 323.15 K
R= 83.1446 cm3.bar/K.mol
Tc (K)
304.20
201.07 132.90
234.13 154.75 180.20
306.89 202.84 236.20 309.6

Vcij (cm3/mol)
94.000
93.700 93.400
74.558 74.300 58.00
95.690 95.386 76.006 97.40

Trij (K)
1.062
1.607 2.432
1.380 2.088 1.793
1.053 1.593 1.368 1.044

B0
-0.300
-0.115 -0.019
-0.169 -0.047 -0.083
-0.306 -0.117 -0.173 -0.311

B1
0.006
0.116 0.135
0.095 0.131 0.124
𝑓 ̂_1
0.001 0.115 0.093 -0.005
 δ 12 = 41.660
δ 13 = 30.451
δ 14 = 4.551
δ 23 = 3.307
δ 24 = 43.749
δ 34 = 32.680

∅ ̂_1 0.833 𝑓 ̂_1 24.994

∅ ̂_2 1.029 𝑓 ̂_2 10.285
∅ ̂_3 1.018 𝑓 ̂_3 7.634
∅ ̂_4 0.826 𝑓 ̂_4 2.064
 Zcij
0.274
0.287 0.299
0.263 0.275 0.251
0.28025 0.287 0.263 0.274

𝜔𝑖𝑗
0.224
0.136 0.048
0.404 0.3155 0.583
0.183 0.0945 0.362 0.141

Pcij (bar)
73.830
51.117 34.990
68.537 47.623 64.800
74.730 50.657 67.825 72.450

Bij (cm3/mol)
-102.38
-32.31 -3.90
-37.16 -1.49 -2.393
-104.29 -35.45 -40.231 -110.75

𝛿
0
41.660 0
30.451 3.307 0
4.551 43.749 32.680 0
bar
bar
bar
bar