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CHB-101
Title: Inorganic Chemistry
Maximum Marks: 34 Total Duration: (50 hours)
Books Recommended:
1. Basic Inorganic Chemistry; F.A. Cotton; G. Wilikinson & P.L.Gauss; Wiley
2. Inorganic Chemistry; A.G.Sharpe; ELBS.
3. Concise Inorganic Chemistry; J.D.Lee.ELBS.
4. Inorganic Chemistry; G.L.Miessler & T.A.Tarr; Prentice Hall.
5. Inorganic Chemistry; D.D.Shriver; P.W. Atkins & C.H.Langford; Oxford.
6. Concepts and Models of Inorganic Chemistry ; B. Douglas : D.Mc.Daniel &
J.Alexander ; Wiley
7. Vogel’s Qualitative Inorganic Analysis; Svehla; 6th edn. ; Orient Longman
1994.
B.Sc. 1st Year
Paper –II Organic Chemistry (50 Hours)
Course No. CHB-102
Curved arrow notation, drawing electron movements with arrow; half and full headed
arrows. Homolytic and heterolytic fission of covalent bonds.
Reactive Intermediates: Carbocations, Carbanions and Free radicals (Structure and
stability) Carbenes, Benzynes and nitrenes (Generation and Structure).
Types of Reagents: Electrophilels and mucleophiles Methods of determination of
reaction mechanism.
Unit II
A: Sterochemistry of Organic Compounds.
Concept of stereo isomerism, Types of stereo isomerism.
Optical Isomerism: elements of symmetry, molecular chirality, Chiral and achiral
molecules with two sterogenic centers, enantiomers and diastercomers. Meso
compounds. Resolution foenantiomers. Inversion, retention and racemisation.
Relative and absolute configuration, Sequence rules. D.L and R.S Systems of
nomenelature.
Geometrical Isomerism: Determination of configuration of geometrical isomers, E
and Z system of nomenclature, Geometric isomerism in oximes and alicyclic
compounds.
Conformational Analysis: Conformational analysis of n-butane, ethylene glycol and
1.2-dibromoethane using Newman, Sawhorse and Fischer projection formulae.
B. Cycloalkanes.
Conformations of cyclohexane and its monosubstituted derivate, Axial and equatorial
bonds.
Nomenclatute, methods of formation and chemical reactions and stability of
cycloparaffins (3 to 6 membered rings) Baeyer’s strain theory and its limitations.
Ring strain in smaller rings with respect to cyclopropane ring, banana bonds.
Liquid State
Intermolecular forces, structure of liquids (a qualitative description), Structural
differences between solids, liquid crystal displays and Thermography.
Solid State: Defintion of space lattice, unit cell and its demenisons, crystal systems,
Laws of crystallography:- (i) Law of constancy of interf acial angles (ii) Law
of rational indices (iii) Law of summetry
Symmetry elements in crystals. Latticie planes and Miller indices. X-ray diffraction
by crystals. Derivation of Bragg’s and Miller equation. Determination of crystal
structure by Laue’s method and powder method. Example of NaCI, KCI & CsCi.
Unit IV Chemical Kinetics and Catalysis (13 hours)
Determination of order or reaction: derivation of integrated rate equations for second
and third order reactions. Determination of order of reaction by differential,
integration, half life period and isolation methods.
Techniques for kinetic investigation: Conductometry, Potentiometry, Polarimetry and
Spectrophotometry.
Effect of temperature on rate of reaction, Arrheniuys equation, concept of activation
energy.
Theories of chemical kinetics: Simple Collision theory – Basic approximations,
evaluation of rate constant for atomic reactions, extension to molecular reactions and
limitations. Brief idea of Transition state theory (equilibrium hypothesis).
Books Suggested
The elements of Physical Chemistry ; P.W. Atkins ; ELBS
Mathematics for Chemists, D. Dogget & B.T. Sutchliffe ; Longman, 1995
Chemical Mathematics, D.M. Hirst; Longman
Principles of Physical Chemistry by B. R. Puri, L.R. Sharma and M.S. Pathanaia;
S. Chand & Co.
A Text Book of Physical Chemistry; K.K. Sharma; Vikas Publishing House.
A Text Book of Physical Chemistry ; A.S.Negi & S.C Anad : Wiley Eastern Ltd.