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Nate Suga
160
HO
R O O
OH
R O O
O O
OH
dP = 1
OH
dP = 2
Alkyl Polyglucosides
APG surfactants: Fischer synthesis Corn starch glucose and coconut oil-derived alcohol Originally from Staley, enkel now Cognis and other suppliers APGs Nonionic, nitrogen-free, EO free and ,4-dioxane free APGs A natural choice for personal care products because of the level of detergency, low color, and no nitrosamine issues owever, there are deficiencies Solubility Foaming in formulation is moderate Irritation can be high
Alkyl Polyglucosides
Blending approach tried by Cognis
Mitigate some of the deficiencies Still contains SLES, SLS
+
OH R O
1
Cl OH
OH HO OH O R
1
HO R
3
APG Quat
OH HO OH O R1 O O H3C HO CH3 N
+
R2 Cl
-
Quaternized Alkylpolyglucosides
APG Sulfonate
OH O HO OH O R1 O O O HO S O Na
+
Alkylpolyglucosides Sulfonate
APG Phosphate
O O O O
1
O O P
O O
Alkylpolyglucosides Phosphate
Nate Suga
Sodium Laurylglucosides
Property Color, Gardner Activity, % Odor p ( 0% aq) Appearance, 0% aq. oss Miles Foam ( %, 5C, DI water), mm Immed. min. 5 min. Draves Wetting ( % active)
160
SugaNate 160 < 40 mild, fatty alcohol 7.0 Clear
ydroxypropylsulfonate
55 5 50 7.
SugaNate 160
Personal Care Applications
Sulfate-free shampoos Low & high p shampoos Bath gels Body washes Facial cleansers Baby cleansing products Personal care wipes Make-up removers Pet Shampoos
Nate Suga
Sodium Laurylglucosides
160
ydroxypropylsulfonate
Practical Formulation Benefits: igh Foaming Comparable to AOS in foam height Much milder than traditional sulfates, ether sulfates, sulfonates or AOS Builds a wet, dense, stable foam Superior detergency, especially compared to SLS & SLES Stable over a broad p range
Nate Suga
Sodium Laurylglucosides
160
ydroxypropylsulfonate
Environmental and Toxicology Benefits Biodegradable by OECD30 standards Natural raw material source No potential for eye or skin irritation Much safer for the environment compared to traditional surfactants
Nate Suga
Sodium Laurylglucosides
Property Color, Gardner Activity, % Odor p ( 0% aq) Appearance, 0% aq. Ross Miles Foam (1%, 25C, DI water), mm Immed. 1 min. 5 min. Draves Wetting ( % active)
160
SugaNate 160 < 40 mild, fatty alcohol 7.0 Clear
ydroxypropylsulfonate
SugaNate 160
Foaming in ard Water Immediate
a g Ha Wate
a ein onate
odi m a ret
ate
ga ate 6
a a
O g a
SugaNate 160
Foaming in ard Water 5 minutes
a g a ate
a e in u onate
% & % ')% ( & 0 # #
odium auret
odium aur
uga ate
a a
g a
"!
% % & $
% ' &
u ate
5 min
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ard
5 min
55
Nate Suga
Sodium Laurylglucosides
160
ydroxypropylsulfonate
The hair contains oils that come from the scalp. The build up of which constitutes the major portion of what is commonly called soils.
Nate Suga
Sodium Laurylglucosides
160
ydroxypropylsulfonate
A key article related to this analysis is entitled Hair Lipids and their contribution to perception of hair oiliness. The Koch article defines two types of oils, the first referred to as external oiliness and the second as internal oiliness.
Nate Suga
160
Detergency Testing
In order to evaluate the detergency of given surfactants, a test methodology was developed. It was assumed that since squalene is a component of both internal and external oiliness, it would be a good starting material to evaluate. The method developed called Squalene Titer (SQ), measures the minimal quantity of detergent to emulsify a standard quantity of squalene. The SQ test is carried out in a test tube with increasing amounts of surfactant, until upon shaking the oil globules are no longer present at the surface.
SUGANATE 160
Detergency Testing
Nate Suga
RESULTS
Material Nonyl phenol 9 mole ethoxylate Sodium Laurylglucosides Hydroxypropyl Sulfonate SLS Disodium laureth -3-sulfosuccinate Sodium Salt SLES-2 Cocamidopropyl betaine
160
Squalene Value 37.5 18.7 15.8 11.5 10.0 7.5
Nate Suga
160
DETERGENCY TESTING C NCLUSI NS Since SLS and SLES- are commonly used detergents in hair care, their performance is not unexpected. NP- is known to be a good laundry detergent. What is unexpected is the magnitude of the Squalene Titer for the sulfates and the performance of SUGANATE 160!
Nate Suga
160
With irritancy this low and detergency this high, SugaNate 160 is truly breakthrough technology!
NATE SUGA
SugaNate 160
Toxicological Properties EYE IRRITATI N ET-CAM: en's Egg Test Chorioallantoic Membrane - Practically no ocular irritation potential in vivo, score of Zero MatTek Epi-Ocular: In vitro epidermal keratinocytes - esults indicate SugaNate 0 has a 'nonirritating' classification, equivalent Draize score of Zero
SugaNate 160
Toxicological Properties ACUTE SKIN IRRITATI N our Occlusive skin patch test on human 4 volunteers - 53 Test Subjects - 53/53 showed no visible skin reaction - No potential for dermal irritation SKIN SENSITIZATI N epeat Insult Patch testing ( IPT) - SugaNate 0 does not indicate a potential for dermal irritation or allergic contact sensitization
SugaNate 160
Toxicological Properties BI DEGRADABILITY eady Biodegrability Test (30 E) OECD 30 days - 0- % biodegradable in - Exceeds 70% biodegradability requirement BACTERIA REVERSE MUTATI N ASSAY Ames test, OECD 47 - No detectable genotoxic activity at the noncytotoxic concentrations of SugaNate 0, neither in the absence nor in the presence of the S enzyme activation
SugaNate 160
Toxicological Properties
AQUATIC T XICITY - DAP NIA ESA SOP 0 , based on USEPA ( 00 ) 4 our Acute (Survival) Toxicity Test using Freshwater Cladocern - EC50 .3 mg/L AQUATIC T XICITY - GREEN ALGAE USEPA OPPTS 40.5400 and USEPA Method 003.0 7 our Growth Inhibition Test using Freshwater Unicellular Green Algae - IC50 5 . mg/L AQUATIC T XICITY - RAINBOW FIS LARVAE ESA SOP 7, based on USEPA ( 00 ) our Fish Imbalance Test using the Larvae of Eastern ainbowfish - EC50 (Imbalance) 7.3 mg/L
SugaNate 160
Comparison of Aquatic Toxicity
SugaNate 160 Sodium Lauryl Sodium Laureth Sulfate Sulfate Daphnia 4 hour Freshwater algae 7 hour EC50 .3 mg/L IC50 5 . mg/l LC50 4. mg/L No comparable data LC50 4. mg/L ( 4 hr) 5 mg/L EC50 > 5 mg/L
Nate Suga
160
S IPPED TO YOU
PRESERVATIVE FREE!
SugaNate 160
Antimicrobial Properties SPECIFICATION Aerobic Bacteria < 00 cfu/g Yeast & Mold < 00 cfu/g C. Albicans absent Staph. aureus absent Gram Neg. Bacteria - absent Lot # 18865B08 < 0 < 0 Absent Absent Absent
SugaNate 160
Antimicrobial Properties ZONE OF IN IBITION STUDY - ACTIVITY SUMMA
SCO ING: 3 Y Excellent; Very Good; Good; 4 OK (moderate); Poor; No Activity
An
Score
The material can be considered to have reasonably good antimicrobial activity at the % active level. It would appear that using this material in formulations could contribute to enhancing overall resistance to microbial contamination.
SugaNate 160
7.27
Viscosity, 25 C
% LMB
In testing comparing this formulation to the National Brand using the ETCAM testing procedure, this formulation scored a 6 and the National Brand scored an 11. This test was performed by Consumer Product Testing Co. of Fairfield, NJ.
P ASE A A A A B B B B B C
COMPOUND Water Mineralizer (Water & Montmorillonite) Glycerin Euxyl K7 (Water & SodiumBenzoate & Potassium Sorbate) SugaNate 160 Sweet Almond Oil Safflower Oil Soybean Oil Tocopherol Zenigloss UPH
PROCEDURE: At R/T, charge Phase A ingredients into main vessel, mixing to uniformity after each addition. Premix Phase B in a side vessel under impeller until uniform. Slowly add Phase B to Phase A. Mix to uniformity, avoiding aeration. Fill.
Bubble Bath
VOV004-
P ASE A A A A B B B C
COMPOUND Water Mineralizer (Water & Montmorillonite) Glycerin Cosmetic Xanthan apid- (Xanthan Gum) SugaNate 160 Sweet Almond Oil Fragrance Eyuxyl K7 (Water & SodiumBenzoate & Potassium Sorbate)
PROCEDURE: At R/T, charge Phase A ingredients into main vessel and mix to uniformity. Premix Phase B ingredients in a side vessel to uniformity. Add Phase B to Phase A mixing carefully to avoid aeration. When uniform, add Phase C. Mix until batch is completely homogenous. Fill.
P ASE A A A A B B B C
COMPOUND Water Unifier (Water & Montmorillonite) Glycerin Xanthan apid- (Xanthan Gum) SugaNate 160 ColaTeric LMB (Lauramidopropyl Betaine) Fragrance Eyuxyl K7 (Water & SodiumBenzoate & Potassium Sorbate)
PROCEDURE: Charge Phase A water and unifier into main vessel and begin impeller mixing. Slurry Glycerin and Xanthan and add to batch. Mix to uniformity. Add remaining ingredients severally, mixing to uniformity after each addition.
Shampoo
VOV004-5 -
P ASE A A B C C D E
COMPOUND Water Mineralizer (Water & Montmorillonite) Glucovis 50 (Mannan & Xanthan Gum) SugaNate 160 Cocoamidopropyl Betaine Fragrance Euxyl K7 (Water & SodiumBenzoate & Potassium Sorbate)
PROCEDURE: Charge Phase A ingredients into main vessel. Stir while heating to 80C. At 80C, sprinkle in Phase B. Mix uniformly until dispersed. Then homogenize the batch for 10 minutes or until the batch is completely uniform in appearance. Switch to impeller mixing and remove the batch from heat. Add Phase C ingredients, mixing to uniformity after each addition. At 40C, add Phases D and E ingredients, mixing batch to uniformity after each addition. Continue mixing the batch until it is completely cooled to R/T. Fill.
Body Wash
VOV004- 0-
P ASE A A B B C C D D E
COMPOUND Water Xanthan Gum SugaNate 160 Cocoamidopropyl Betaine Emulgade PL /50 (Cetearyl Glucoside & Cetearyl Alcohol) aspberry Butter (Octyldodecanol, Beeswax, aspberry Oil) Fragrance Tocopherol Euxyl K7 (Water & SodiumBenzoate & Potassium Sorbate)
PROCEDURE: Charge Phase A water into main vessel. Slowly sprinkle in Xanthan while heating to 75C under impeller mixing. Mix to uniformity. Maintaining temperature and adequate mixing speed, add Phase B, mixing to uniformity after each addition. Bring temperature to 85C. Add Phase C ingredients, mixing to uniformity after each addition. Begin cooling while mixing, adjusting speed as needed to avoid aeration. At 40C, add Phases D and E ingredients, mixing to uniformity after each addition. Mix to R/T and fill.
Nate Suga
160
Regulatory Status NICNAS Approved in Australia TSCA Listed NDSL listed Schedule 4 0,000 kg of active or 5,000 kg of total product in Canada DSL full approval (under review) REACH registered in Europe Japan approved (ENCS)
Nate Suga
160
Regulatory Status Listed on CleanGredients, Design for the Environment (Database for Household Ingredients) Listed as a USDA Bio-Based Product and BioPererred Ingredient ( 7% Bio-Based Carbon Score) Whole Foods Market Premium Ingredient
Nate Suga
160
Nate Suga
160
and Soap
Aqua (Water), Aloe Barbadensis Leaf Juice, Cocamidopropyl Betaine, Glycerin, Sodium Laurylglucosides ydroxypropylsulfonate, Sodium Cocoyl Isethionate, Stearic Acid, Sodium Lauroyl Sarcosinate, Rosmarinus Officinalis (Rosemary) Leaf Extract, Calendula Officinalis Flower Extract, Chamomilla Recutita (Matricaria) Flower Extract, Dioscorea Villosa (Wild Yam) Root Extract, Styrax Benzoin Resin Extract, Cedrus Atlantica Bark Oil, Citrus Medica Limonum (Lemon) Peel Oil, Copaifera Officinalis (Balsam Copaiba) Resin, Coriandrum Sativum (Coriander) Seed Oil, Geranium Maculatum Oil, Lavandula Angustifolia (Lavender) Oil, Pogostemon Cablin (Patchouli) Oil, Rosmarinus Officinalis (Rosemary) Leaf Oil, Arginine, Bisabolol, Sodium Citrate, Sodium PCA, Panthenol, Tocopheryl Acetate, Guar Hydroxypropyltrimonium Chloride, Alcohol, Benzyl Alcohol, Potassium Sorbate, Sodium Benzoate, Limonene, Linalool.
Nate Suga
160
Nate Suga
160
Nate Suga
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160
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160
Nate160 Suga
alba BOTANICA Rainforest Foaming Cream Cleanser
Nate Suga
160
Nate Suga
160
Nate Suga
Save Your
160
air Shampoos
Nate Suga
160
Nate Suga
160
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160
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160
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160
oney
Nate Suga
MyChelle Dermaceuticals
160
Nate Suga
Aromafloria
160
Nate Suga
160
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NATE SUGA
SugaNate 160
Industrial Applications
Carpet Cleaners Hard Surface Cleaners Dish Wash Products Hand Soaps
Nate Suga
High foaming Good emulsification Excellent lime soap dispersion Maximum flexibility in the preparation of light and heavy-duty cleaners
Nate Suga
SugaNate 160 is also mild to the skin, making it useful in hand soaps, dish wash products and anywhere worker exposure is a concern.
Nate Suga
Useful over a broad pH range Suitable for low pH, acid formulations Suitable for high pH, high alkaline formulations The stability of SugaNate 160 at any pH makes it desirable for I&I and household applications.
Nate Suga
Nate Suga
Standard 00.3
pH 3 .3
QR
6 X 39 W 2 4 2V V Q P
eg t
t sqr
As a Hydrotroping Detergent
SugaNate 160
e e t - SugaNate
E C D @
3 9 6 7 2 2 28
52 4 4
1 2
(a
u t ee e t
ea
ut
f1
1 -6
10
ga ate
FRG
pi
i i R S T U FG 39 A 6 3 3 g f g h
QI
QH F G H I Y ` a b d fe c
P Q
t e
SugaNate 160
Foaming in Hard Water Immediate
a g Ha Wate
a ein onate
odi m a ret
ate
ga ate 6
a a
O g a
wv
wv
wv
wv
wv
wv
wvv
wvy
wv x
wv u
SugaNate 160
Foaming in Hard Water 5 minutes
a g a ate
a e in u onate
d e d fhd g e i
odium auret
odium aur
uga ate
a a
g a
d d e
d f e
u ate
5 min Hard
u ate
5 min
55
SugaNate 160
Formulations
and Soap Formulation
PROCEDURE: Mix all ingredients, check pH and adjust to 5.5 -6.5 with NaOH as needed.
Nate Suga
160
Formulations
AEROSOL CARPET AND UP OLSTERY CLEANER
DI Water Glycol ether PM SugaNate 160 Fragrance Tinopal CBS-X A-46 Propellant
FAX SUGA
WHY
FAX? SUGA
Natural derivation and non-petroleum based EO / PO Free Biodegradable Low toxicity Renewable resource Low order of skin and eye irritation High electrolyte tolerance Eco-Friendly
FAX SUGA
Gemini Surfactants
OH HO O O HO O R1 OH O P O O OH O O OH O R1 n ONa
+
OH OH
S tr ct re
FAX SUGA
Gemini Surfactants
Product Line
SugaFax D04 SugaFax D08 SugaFax D10 SugaFax D12 SugaFax D86
5 products High and Low foam versions All 40% active products in water Aesthetically appealing for industrial applications
SUGA FAX
Gemini Surfactants
Property Color, Gardner Activity, % Viscosity (as is) 25C Odor D04 4 40 11 mild, sweet D08 + 40 13 sweet D10 <1 40 20 mild, fatty alcohol 7.5 Clear D12 1 40 00 mild, fatty alcohol 7.5 Cloudy D86 1 40 20 mild, fatty alcohol 7.0 Clear
7.0 Clear
7.5 Clear
FAX SUGA
Gemini Surfactants
Ross-Miles Foam Height (1% active) Immed. 1 minute 5 minutes
D04 10 0 0
D08 20 0 0
Immed.
13. sec
2.6 sec
FAX SUGA
Gemini Surfactants
Solubility (10% active) D04 D08 D10 D12 D86
50% NaOH
Soluble
Soluble
Soluble
Soluble
25% NaOH
Soluble
Soluble
Soluble
Soluble
25% H2SO4
Soluble
Soluble
Soluble
Cloudy
Soluble
Surface Tension
60.0
D86
50.0 40.0 30.0 20.0 0.0%
0.1%
1.0%
10.0%
100.0%
% SugaFax
16
14
12
D12 SXS
Weight % of Hydrotrope
10
D08 D86
D10
6
INC-K
0 20 25 30 35 40 45 50 55 60 65 70
Cloud Point, C
SUGAFAX
Gemini Surfactants Regulatory Status
CAS Numbers Complete TSCA Fully approved NDSL, Canada,
Toxicity
Eye Practically non-irritating - chorioallantoic membrane test score is 4.25 which is lower than Johnsons baby shampoo which scores an 11.00 Skin No irritation skin patch test, 57 out of 57 for 72 hours
BIODEGRADABLE
SUGAFAX
Gemini Surfactants
Application Properties
SUGAFAX
Gemini Surfactants SugaFaxes are Safe & Green
Naturally derived Extremely safe Green Surfactants Useful in applications over a broad pH range Soluble & Stable in 50% Caustic Soluble & Stable in 25% mineral acids Useful in a variety of applications