Quantum Theory of Radiation

Introduction:
Our discussion of Einsteins theory of relativity took us into a world far beyond that of ordinary experience the world of objects moving at speeds close to the speed of light. Now you are about to explore a second world that is outside ordinary experience- the subatomic world. You will encounter a new set of surprise that, though may sometime seem bizarre, have led physicists step by step to a deeper view of reality.

Thermal radiation:
An object and its environment can exchange energy as heat via electromagnetic waves. Energy transferred in this way is often called thermal radiation to distinguish it from electromagnetic signals and from nuclear radiation. When an object is in thermal equilibrium with its surroundings, it emits and absorbs energy at the same rate. The rate at which an object radiates energy is proportional to the surface area of the object and to the fourth power of its absolute temperature. This result found empirically by Josef Stefan in 1879 and derived theoretically by Ludwig Boltzmann about five years later, is called the Stefan-Boltzmann law:

Prad = AT 4 ,
where

[1]

Prad = power radiated in watts

A= objects surface area = a universal constant called Stefans constant, =5.6703x10-8 W/m2k4 = emissivity of the objects surface which has a value between 0 and 1, depending on the composition of the surface. A surface with the maximum emissivity of 1.0 is said to be a blackbody radiator, but such a surface is an ideal one and does not occur in nature. When radiation falls on an opaque object, part of the radiation is reflected and part is absorbed. Lightcoloured objects reflect most visible radiation whereas dark objects absorb most of it. The rate at which an object absorbs radiation is given by

Pabs = env , T4
where Tenv is the temperature of the surroundings (in Kelvins).

[ 2]

If an object emits more radiation that it absorbs, it cools while the surroundings absorb radiation from the object and warm. It the object absorbs more than it emits, the object warms and the surroundings cool. The net power radiated by and object at temperature T in an environment at temperature Tenv is
4 Pnet = Pabs Prad = [Tenv T 4 ],

[3]

Pnet is positive if net energy is being absorbed via radiation, and negative if it is being lost via radiation. When an object is in thermal equilibrium with its surroundings, radiation at the same rate.

T = Tenv and the object emits and absorbs

Blackbody radiation:
As discussed earlier, an object that absorbs all the radiation incident upon it has an emissivity equal to 1 and is called a blackbody. The concept of a blackbody is important because the characteristics of the radiation emitted by such an ideal object can be calculated theoretically. Materials such as black velvet come close to being ideal blackbodies. The best practical approximation of an ideal black body is a small hole leading to a cavity, such as a keyhole in a closed door (Fig.1). Radiation incident on the hole has little chance of being reflected back out of the hole before it is absorbed by the walls of the cavity. The radiation emitted through the hole is thus characteristic of the temperature of the object.

Most of the radiation emitted by an object at temperature below about 6000C is concentrated at wavelengths much longer than those of visible light (visible light is electromagnetic radiation with wavelengths between about 400 and 700 nm). As an object is heated, the rate of energy emission increases and the energy radiated extends to shorter and shorter wavelengths. Fig. 2 shows the power radiated by a blackbody as a function of wavelength for several different temperatures. The wave length at which the power is a maximum varies inversely with the temperature, a result known as Weins displacement law:

max =

2.898 mm . K , T

Figure 1 : A hole in a cavity approximates an ideal black body. [ 4]

The law is used to determine the temperatures of stars from analyses of their radiation. It can also be used to map the variation in temperature over different regions of the surfaces of an object. Such a map is called a thermograph. Thermographs can be used to detect cancer because cancerous materials are at a slightly higher temperature than the surrounding tissue. Eq. [4] can also be written as

max T = 2.898 x10 3 m. K

It may be noted that the term displacement in Weins displacement law refers to the way the peak is moved or displaced as the temperature is varied. The spectral distribution curves shown in Fig.2 played an important role in the history of physics. It was the discrepancy between theoretical calculations of what the black body spectral distribution should be using classical thermodynamics and the experimental measurements that led to Max Plancks first ideas about the quantization of energy in 1897. Figure 2: Radiated power versus wavelength for radiation emitted by a black body.

Example 1:

(a) The surface temperature of the sun is about 6000 K. If the sun is assumed to be a blackbody radiator, at what wavelength max would its spectrum peak? (b) Calculate max for a blackbody al room temperature T= 300 K.
Solution: (a) We can find max from Weins displacement law as:

max =

2.898 x10 3 m. K = 483 x10 9 m = 483 nm 6000 K

(b)

m = ax

2.898 x10 3 m. K = 9.66 x10 6 m = 9660 nm 300 K

So, we see that the peak wavelength from the sun is in the visible spectrum. The blackbody radiation spectrum describes the suns radiation fairly well. For T= 300 K, the blackbody spectrum peaks in the infrared wave length, much longer than the wavelengths visible to the eye. Surfaces that are not black to our eyes may act as blackbodies for infrared radiation and absorption. Skin of human beings of all races is black to infrared radiations hence the emissivity of skin is 1.00 for its own radiation process.

Example 2:

Calculate the net loss in radiated energy for a naked person in a room at 200 C assuming the person to be a blackbody with a surface area of 1.4 m2 and a surface temperature of 330 C(=306 K). (The surface temperature of human body is slightly less than the internal temperature of 370 C because of the thermal resistance of the skin.

Solution:
4 Pnet = A [T 4 Tenv ]

= 1x [5.6703 x10 8 W m 2 .K 4 ] x1.4m 2 [306 4 293 4 ]K 4 = 111 W

This large energy loss is approximately equal to the basal metabolic rate of about 120 W. We protect ourselves from this great loss of energy by wearing clothes.

The ultraviolet catastrophe:

Why does the blackbody spectrum have the shape shown in Fig. 2. This problem was examined at the end of the nineteenth century by Lord Rayleigh and James Jeans. Since the radiation that emerges from the hole (in Fig.1) is just a sample of the radiation inside the box, understanding the nature of the radiation inside the box allows one to understand the radiation that leaves through the hole. For this reason, Rayleigh and Jeans started by considering the radiation inside a cavity of absolute temperature T whose walls are perfect reflectors to be a series of standing electromagnetic waves (Fig. 3). The condition for standing waves in such a cavity is that the path length from wall to wall, whatever the direction, must be a whole number of half wavelength so that a node occurs at each reflecting surface. Fig. 3: Electromagnetic radiation in a cavity whose walls are perfect reflectors consists of standing waves that have nodes at the walls.

The number of standing waves with wavelengths between and +d turned out to be

N ( )d =
where V is the volume of the box.

8V

d,

[5]

Each individual wave contributes an energy KT to the radiation in the box. This result follows from classical thermodynamics. The radiation in the box is in thermal equilibrium with the walls at temperature T. Radiation is reflected from the walls because it is absorbed and quickly remitted by the atoms of the walls, which in the process oscillate at the frequency of the radiation. At temperature T, the mean thermal kinetic energy of an oscillating atom is KT/2. For a simple harmonic oscillator, the mean kinetic energy is equal to the mean potential energy, so the mean total energy is KT. Let us first calculate the energy density of radiation inside the cavity: energy density = (number of standing waves per unit volume) x (energy per standing wave) or, u( )=

KT ,

[6]

The radiancy is related to the energy density (energy per unit volume) u( ) at the wavelength according to

R ( ) =

c u( ), 4

[ 7]

This result follows from the classical electromagnetism by calculating the amount of radiation passing through an element of surface area within the cavity. Finally from Eq. [7], we get Radiancy= R ( ) =

8
4

c KT [ ], 4

[8]

This result is known as the Rayleigh-Jeans formula; based firmly on the classical theories of electromagnetism and thermodynamics, it represents our best attempt to apply classical physics to understanding the problem of blackbody radiation. In Fig. 4, the radiancy calculated from the Rayleigh-Jeans formula is compared with the observed radiancy from blackbody spectra. The radiancy calculated from Eq. [8] approaches the data at long wavelengths, but at short wavelengths the classical theory (which predicts R as 0 ) fails miserably. The failure of the RayleighJeans formula at short wavelength is known as the ultraviolet catastrophe and represents a serious problem for classical physics, because the theories of thermodynamics and electromagnetism on which Rayleigh-Jeans formula is based, have been carefully tested in many other circumstances and found to give extremely good agreement with experiment. It was apparent in the case of blackbody radiation that the classical theories would not work and that a new kind of physical theory was needed.

Fig. 4: The failure of the classical RaleighJeans formula to fit the observed radiancy. At long wavelengths the theory approaches the data, but at short wavelengths the classical formula fails miserably.

Plancks hypothesis and radiation law:

The new physics that gave the correct interpretation of thermal radiation was proposed by the German physicist Max Planck in 1900. Planck reasoned that the reflections at the walls of the cavity resulted from radiation being absorbed and then quickly reemitted by the atoms of the wall; during this period the atoms would oscillate at a frequency equal to the frequency the radiation. Planck suggested that an oscillating atom can absorb or reemit energy only in discrete bundles (called quanta). If the energy of the quanta were proportional to the frequency of the radiation, then as the frequencies became large, the energy would similarly become large. Since no individual wave could contain more than KT of energy, no standing wave could exist whose energy quantum was large than KT. This effectively limited the high frequency (low wavelength) radiant intensity and solved the ultraviolet catastrophe. In Plancks theory, each oscillator can emit or absorb energy only in quantities that are integer multiples of a certain basic quantity of energy ,
E = n, n =1,2,3,.......

where n is the number of quanta. Furthermore, the energy of each of the quanta is determined by the frequency

= h
where h is the constant of proportionality now known as Plancks constant. So, the main points that establish Plancks radiation law can be summarized as:

(1) An oscillator absorbs energy from the radiation field and delivers it back to the field in

quanta of 0, , 2 , 3 ,.etc. where is the quanta of energy propositional to frequency of the oscillator.

(2) An oscillator cannot have arbitrary energy but must occupy one of a discrete energy sets given by = nh , where n is an integer.
(3) The number of oscillators emitting particular energy is given by statistical distribution law of Boltzmann, which is

N r = N 0e

kT , [9]

If N is the total number of Planck oscillators and E is the total energy, then the energy per oscillator is given by

< E >=

E , N

[10 ]

Let N0, N1, N2, Nr,..etc. be the number of oscillators having energies 0, , 2 , ..r ,..etc respectively. Then

N = N0 + N1 + N 2 +.......... .. + Nr +.......... ...... and E = 0.N0 +.N1 + 2.N 2 +.......... .......... .. + rNr +.......... ....
Using Maxwells distribution formula [9], we can write

N = N0 + N1 + N 2 + .......... .......... . + Nr + .......... ...... = N + N e x + N e 2 x + .......... .......... . + N e rx + ..........

0 0 0 0

= N0 [1 + y + y + .......... .......... ......... + y + .......... ...... = N0 [1 y ]1 =

where
x = kT and y = ex

N0 , kT 1e

[11]

Similarly, we can write

E = 0 + .N1 + 2 .N2 + .............. + r Nr + ........... 2 r kT + ...................... + r N e kT + ............ = N0e kT + 2 N0e 0 2z + 3z 2 + ........................... + rz( r 1) + ................] N0e kT N0e kT = N0e kT [1 z ] 2 = = , [12] [1 z]2 2 [1 e kT ] = N 0e
kT [1 + Using [11] & [12] in [10], we can find the following expression for the average energy of an oscillator

<E>=

E = N

e kT 1
8 2d c3

= e

h kT 1

, [13]

The number of oscillator per unit volume in the frequency range and +d can be shown to be given by dN = , [14 ]

When the average energy of the oscillator is multiplied by the number of oscillators per unit volume in the frequency range and +d , then we obtain the energy density E d belonging to the range d . Thus the energy density is given by

E d =

2 8 d

. e

h kT 1
d =

, [15]
cd , can also be represented in terms of 2

The equation [15] for the energy density, using = wavelength as

&

 d | = E d= E

8h c 3 1 cd . . . c 3 3 hc kT 2 e 1 8hc 1 = . d , [16] hc 5 e kT 1

Eq.[15] or [16] is known as Plancks radiation law. From [16], we can write

Radiancy = R ( ) =

c c 8 hc 1 2hc 2 1 x energy density = . . = . hc hc 4 4 5 5 e kT 1 e kT 1

Case 1:
We shall now derive Rayleigh-Jeans law from Eq.[16]: For large wavelength, T is large. Therefore,
hc

e kT = 1 +

hc 1 hc 2 + [ ] + .......... kT 2! kT hc kT ..... ..... [18 ]

1 +
With the help of [18], we can write Eq.[16] as

E d | =

8 hc 1 . hc d 5 e kT 1 8 hc 1 = 5 . d 1 + hc 1 kT 8 kT = 4 d ..... ..... [19]

which is Rayleigh-Jeans law.

Case 2:
We shall now derive the Weins law from Plancks law. For small wavelengths, T is small. Therefore, In this case, we can neglect 1 in [ approximation, we can write

hc kT >> 1 . e
and write [ ] e kT 1

] e kT 1

hc

hc

as

. e kT

hc

With this

E d | =
as

8hc 1 . d ,. 5 hc e kT 1

E d | =

8 hc 8 hc 1 . d = 5 .e hc kT d , [26] 5 hc e kT
6

which is Weins law. Example 3. Find the intensity of light emitted from the surface of the sun in the wavelength range 600.00 to 605.00 nm. Solution : The exact result is found by integrating radiancy within the limit 600 to 605 nm. However, result can also be found approximately by finding the area under the radiancy R( ) curve between these limits. The area within these limits can be found by calculating the height of the curve at the median wavelength = 602.5 nm and multiplying this by the width of the interval = 5 nm. First we evaluate hc/ kT at = 602.5 nm X=

(6.626 10 34 J .s ) ( 2.998 10 8 m / s ) hc = = 4.116 kT (602 .5 10 9 m)(1.38 10 23 J / K )( 5800 K )

R( ) =

2 (6.626 10 34 J .s) (2.998 10 8 m / s) 2 2hc 2 1 . = hc 5 (602.5 10 9 m) 5 e 4.116 1 kT 1 e

= 7.81 1013 W/m3

The intensity in the 5 nm range from 600 nm to 605 nm is than approximately R( ) = = (7.81 1013 W/m2) (5 10-9 m) = 0.39 MW/m2