MATERIAL SAFETY DATA

EDITION: 7 1. PRODUCT NAME: epoxy plus pipeline repair grout TG (tropical grade) Chemical Nature A three-component grout based on a Bisphenol A/F epoxy resin, a hardener based on isophoronediamine and a filler containing inert silicaceous fillers. Manufacturer weber sbd Saint-Gobain Weber Limited Dickens House Enterprise Way Flitwick Bedford. MK45 5BY. EMERGENCY TELEPHONE NUMBER. 08703 330070 2. COMPOSITION Resin component contains Bisphenol A/F Resin with Av. MW < 700 and benzyl alcohol (<10%) CAS No. 100-51-6. Contains epoxy constituents. See information supplied by the manufacturer. EEC Symbol: Xi, N R Phrases: 36/38,43,51/53 DATE: DECEMBER 2002

Hardener component contains isophoronediamine (30-60%) CAS No. 2855-13-2 EEC Symbol: C R Phrases: 21/22, 34,43,52/53

Filler contains inert silicaceous fillers 3. HAZARDS IDENTIFICATION Resin Component Irritating to eyes and skin May cause sensitisation by skin contact Toxic to aquatic organisms, may cause long-term effect on the aquatic environment Hardener Component Causes burns Harmful in contact with skin and if swallowed May cause sensitisation by skin contact Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment

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Filler Component: Essentially non hazardous 4. FIRST AID MEASURES SKIN CONTACT: Wipe off excess with absorbent disposable paper towels. Wash with plenty of soap and water. Do not use organic solvents. Rinse immediately with water for at least 15 minutes. Get medical attention immediately. Move affected person to fresh air. In case of irritation to respiratory system or mucous membrane or if symptoms persist seek medical attention. Seek medical attention instantly. Immediately rinse mouth repeatedly with water. If swallowing has occurred the affected person should drink copious amount of water.

EYE CONTACT:

INHALATION:

INGESTION:

5. FIRE-FIGHTING MEASURES Suitable Extinguishers: Water mist, Carbon dioxide, Foam and Dry powder. Do not use high-pressure water jet extinguishers. Toxic fumes may be given off of carbon monoxide. Fire fighters should wear selfcontained breathing apparatus Exposure hazards Do not release chemically contaminated water into drains, soil or surface water. Sufficient measures must be taken to retain water used for extinguishing. Dispose of contaminated water and soil according to local regulations. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Avoid contact with skin, eyes and clothing. Avoid breathing vapours. Avoid ignition sources. Environmental Precautions Prevent contamination of soil drains and surface water. Methods for Cleaning Take up with absorbent, dry inert material and place in a suitable and closable container for disposal according to local regulations. Ensure adequate ventilation. 7. HANDLING AND STORAGE Handling Resin: Irritant, sensitising. Hardener: Corrosive, sensitising, harmful in contact with skin and if swallowed. Avoid vapour formation and ignition sources. Ensure good ventilation. Do not eat or drink in workplace.

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Storage Store away from food and drink. Store in original undamaged containers securely closed. Store at room temperature away from direct sunlight. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Technical Protective Measures No special measures required. Exposure Limits Resin and Hardener None Filler: Occupational Exposure Limits 8 hour TWA According to EH40/00 Total inhalable dust Respirable dust Respiratory Protection Not normally necessary. Work in well ventilated area. Wear suitable vapour mask if working in confined spaces. Hand Protection Wear suitable gloves Eye Protection Wear suitable goggles or face protection. Skin Protection Wear overalls and closed footwear. 9. PHYSICAL AND CHEMICAL PROPERTIES Both resin and hardener components are liquids. The flash points of both the resin and hardener components are above 100oC. The filler is a mixture of graded silica sand and fine fillers. 10. STABILITY AND REACTIVITY Thermal Decomposition Temperature: Above 200oC. Materials to avoid: Strong acids and alkalis and strong oxidizing agents. Hazardous Decomposition Products: If the materials are involved in a fire hazardous oxides of carbon or nitrogen or other hazardous vapours may be released. 11. TOXICOLOGICAL INFORMATION Bisphenol F epichlorohydrin resin MW<700 LD50: Oral 23800mg/kg (rat) Dermal >2000mg/kg (rabbit) Benzyl alcohol LD50: Oral 1610mg/kg (rat) 10.0 mg/mm3 4.0 mg/mm3

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LC50/4h

Dermal 2000mg/kg (rabbit) Inhalative >1000mg/l (rat)

Isophoronediamine (2855-13-2) LD50: Oral 1303mg/kg (rat) Dermal 1840mg/kg (rabbit) Skin Sensitisation in Guinea pigs: Both resin and hardener may cause sensitisation by skin contact. Resin component: Irritant. Hardener Component: Corrosive.

Skin and Eye irritation tested on rabbits: 12. ECOLOGICAL INFORMATION

Prevent contamination of soil, drains or surface water. No other specific information available. 13. DISPOSAL CONSIDERATIONS Incineration or landfill in accordance with local regulations. Contaminated packaging material should be disposed of identically to the product itself. For easy disposal any unmixed resin and hardener can be mixed and allowed to cure. Once fully cured E P Pipeline Repair Grout Tropical Grade can be disposed of as normal household waste. Uncontaminated packaging material should be treated as household waste or as recycling material. 14. TRANSPORT INFORMATION Resin Component: UN No.3082 Environmentally hazardous liquid n.o.s (epoxy resin) Class 9 Hardener Component: RID/ADR: Class 8 IMDG-Code: Class 8 IATA: Class 8 Packing Group: III UN No.: 2289 Isophoronediamine Flash Point: 117oC. Filler Component: Classification for transport not required 15. REGULATORY INFORMATION Resin Component Symbol: Contains: Xi (Irritant) & N (Dangerous for the environment) Bisphenol A epoxy resin with average MW <700. Contains epoxy constituents. See information supplied by the manufacturer.

R Phrases: R36/38 R43 R51/53

Irritating to eyes and skin May cause sensitisation by skin contact Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment

S Phrases:

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S24 S28 S37/39

Avoid contact with skin After contact with skin, wash immediately with plenty of soap and water. Wear suitable gloves and eye/face protection.

Hardener Component Symbol: Contains: C (Corrosive) Contains isophoronediamine (30-60%)

R Phrases: R21/22 R34 R43 R52/53 the S Phrases: S26 S28 S36/37/39 S45 immediately S61 data

Harmful in contact with skin and if swallowed. Causes burns May cause sensitisation by skin contact. Harmful to aquatic organisms, may cause long-term adverse effects in aquatic environment

In case of contact with eyes, rinse immediately with plenty of water and seek medical attention. After contact with skin, rinse immediately with plenty of water Wear suitable protective clothing, gloves and eye/face protection In case of accident or if you feel unwell, seek medical advice (show the label where possible) Avoid release to the environment. Refer to special instructions/safety sheet

Filler Component: Essentially non hazardous 16. OTHER INFORMATION The information supplied by the manufacturer on epoxy constituents is contained within this data sheet. This safety sheet has been prepared in accordance with the provisions of the EC SDS Directive 91/155.

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