Physics: 1-C; 2-A,D; 3-B,C; 4-B,C;

5-A,C,D; 6-A,C,D; 7-BCD; 8-B,C;

9-B,D; 10-A,D; 11-A,B,D; 12-B,C;
13-C; 14-A; 15-A; 16-C; 17- B; 18-C;
19-B; 20-B; 21-C; 22-C.
Chemistry: 23-C; 24-BC; 25-B;
26-D; 27-B; 28-AB; 29-BCD; 30-C;
31-D; 32-C; 33-AC; 34-A; 35-A;
36-B; 37-C; 38-D; 39-B; 40-C; 41-D;
42-B; 43-A; 44-B.
Mathematics: 45-A; 46-C; 47-B;
48-AC; 49-BC; 50-A; 51-D; 52-AB;
53-BC; 54-C; 55- AD; 56-D; 57-B;
58-A; 59-C; 60-C; 61-C; 62-B; 63-A;
64-C; 65-D; 66-B.

. :

.: . .... t. ...
... .. ...
CH
2
= CH
2
+ Br
2
CH (Br)-CH
2
(Br)
... .. ... HBr. ..
.: ... .. . .:. :.
... . . (. .. .. ..
..)
3. .. . . . .. . . . i) . :
... ... .:.. ..
ii) .. .. .... 'C'
.. ... ... ... ..
. . ... ... ...
.. 2 '' ... .: 1 ''
... ... sp
3
....... sp
2

. sp
2
....... 'sp' ....
....... .........
. . . . . . .. . . . ..
... ... ......
4. .. ... . .- ... ...
... .. ..... . ..
... .. .... .: .. ..
.. ... ..... .. .. ...
.. ... .. .. ..
... ... .:
.. 1) . ..
O O O

O-C-C
6
H
5
C-C
6
H
5
C-C
6
H
5

OH

O O + O

OH
O- ... P- ...
.... ....
O
..

2) NH
4
CNO(NH
2
-C) - NH
2
(... . ...
. .)
b) . ... . (. .:. :.
. .:..)
. ...... ... ...
..::.. .. . .:
i) .. .... ..
H
. .
Cl-Cl Cl+Cl
ii) .. ...- ..
. .
CH
3
-CH
3
+Cl CH
3
- CH
2
+ HCl
. .
CH
3
-CH
2
+Cl -ClCH
3
-CH
2
Cl + Cl
iii) .. e... ..
. .
Cl + Cl Cl
2
. .
C
2
H
5
+ C
2
H
5
C
4
H
10
.
CH
2
-CH
3
+ Cl CH
3
-CH
2
-Cl
C) .-.... .-.. . ..
.... .. . . .: . .
.... .. .. ... .... .
.. .. .... .. ....
. .. :... . 'C' . .
. .:
.. . .:.. .... t. ...
..
:. .-.:. ...
(2 ..... . 1 ... .. .:)
d) . .. .... .. . ..
. . .. . .. . .
....
... . ... 'HBr'
. . .:.. ..
.. . .. .:..
. .. . .. .:
. . . . : . :. .. .
. .:... ....: . .: . .
..: .: . ..
(2 .:. :. . 1 ... .. .:)
e) .. .... .. . . . .
.... .. .. .
.. .. .::.. .... ...
... ......
(Super impossable object and
mirror images)
.. ... .. . ..: .::..
.... ...... ....
(Non-Super imposable object
and mirror images)
.. .. .. . .. ....
...... ... . .. . .
.. . .. . .. ....
.. (Cheir) . . ... ..
(hand) . ...
... .. . .. .... .. ..
. . ... ...... .
. .. .t ... . ..
.. . . . .. ....
III ...... ....
a) .... ..-: .: .. . .
. .... . :.. :. . .. ..
.. . . ... (99.9%)
.. ...
:.. :. . 'H
2
' ... .. ..
... .:
... .. (.. ....)
2H
2
O+2e
-
2OH
-
+ H
2
... .. (......)
2OH
-
H
2
O+1/2 O
2
+ 2e
-
... ... ... ... .. ...
.. . .
. . .. ..
.. ..:. 'H
2
'
.. .. . . . .
. .:
Zn+2HCl
ZnCl
2
+ H
2
Zn, Sn, Al .. . . . NaOH
.... ... . .. H
2
.. ..
. ... . .:
Zn + 2NaOH Na
2
ZnO
2
+ H
2
. ... :.. :. . . .:.
.... ... .. ...
NaClNa
+
+ Cl
-
2H
2
O 2OH
-
+ 2H
+
... 2Cl
-
Cl
2
+2e
-
2e
-
... 2H
2
O 2OH
-
+ H
2
. .:. .. .t .. :.
... ... ... .:. ....
H
2
.. ..
.
C + H
2
O
1000C
CO+H
2
.. t. .
.... . (.) ...
.... .. .. .. 'H
2
' ... ..
.. .:
b) .... ...
.... . .t. .... H
2
.
.: .. . :. ....
....
. ...
Pt . Pd .. ... .: ..
. .. . .. . .. .:
5000C .. 'H
2
' ... .....
. :. .. .:
'H
2
' t ... . :...
.. .. .. : .... .. ..
2H
2
+O
2
2H
2
O; H = -285 KJ/mole
H
2
. .. . . . . ..
.. .:
WO
3
+3H
2
W+ 3H
2
O
2 AgCl + H
2
Ag+2HCl
.. d-.. .... ... .
. .. .. . 'H
2
'. .....
.. PdH
0.7
, TiH
1.8
. . .. . :.. :. .
- . . -
HBrH
+
+ Br
-
+
CH
3
-CH = CH
2
+ H
+
CH
3
- CH - CH
3
2 .....
CH
3
-
+
CH- CH
3
+ Br
-
CH
3
-CH-CH
3
2 - ....

Br
.:: :
R-O-O-R 2 RO
.
R
.
O+H-Br R-OH+B
.
r
CH
3
-C
.
H-CH
2
-Br (2 . .:. :.)
B
.
r+CH
3
-CH-CH
2

CH
3
-CH(Br)-CH
2
(1 . .:. :.)
CH
3
-C
.
H-CH
2
-Br+H-BrCH
3
-CH
2
-CH
2
Br+
B
.
r
alc. KOH
CH
3
- CH
2
Br CH
2
= CH
2
+ HBr
Con. H
2
SO
4
CH
3
CH
2
OH CH
2
= CH
2
+ H
2
O
170 C

AlCl
3
C) C and E are at the same potential
D) The potential difference
between D and A is 2BRV
with D at a higher potential
6. Electrons with de-Broglie wave-
length fall on the target in an
x-ray tube. Then
h
2
A) The K.E. of the electron is
2m
2
B) The cut-off wavelength of
emitted x-ray is
C) The momentum of the electron
is h/
D) The cut-off wavelength of the
2mc
2
emitted x-ray is
h
7. 3 cal of heat is given to one mole
of a monatomic gas contained in
a closed vessel at 300 K. The
A) The temp. of the gas increases
by 2 K.
B) The temp. of the gas increases
by 1K.
C) The r.m.s. speed of the mole-
cules increases
D) The fractional change in the
r.m.s. speed of the molecule of
the gas is 1/600
8. If two resistors of resistances
R
1
= (4 0.5) and R
2
= (16
0.5) then the equivalent resist-
ance in series is R
s
and equivalent
resistance is parallel is R
p
A) The max. percentage of error
in finding R
s
is 4 %
B) The max. percentage of error
in finding R
p
is 7.2 %
C) The max. percentage of error
is finding R
s
is 5%
D) The max. percentage of error
in finding R
p
is 8.4 %
9. Figure shows a part of circuit.
Then
A) power dissipated in 3 resist-
ance is 9W
B) power dissipated in 3 resist-
ance is 27 W
C) potential difference
V
A
-V
D
= 44 V
D) potential difference
V
A
-V
D
= 20 V
10. A proton of specific charge
(change per unit mass) moves
with a velocity v
0
i

in a
3
magnetic field of ( j

+k

) Tesla.

2
Then
A) path of the particle is circle
B) path of the particle is helix
C) speed of the particle at time

v
0
v
0
is
(
i

+ j

)
3 3 3
D) distance moved by particle in

v
0
time t = is
3 3
11. The ionization energy of a
Hydrogen like atom is 54.4 eV.
Then
A) Its first excitation potential
40.8 volt
B) Its atomic number is 2
C) It can absorb a photon of ener-
gy 50 eV
D) It can absorb a photon of
energy 56 eV
12. A ray of light is incident at an
angle of 60 on one face of
prism of refracting angle 30. If
the angle of deviation produced
by the prism is 30C then
A) Angle of emergence is 60
B) Angle of emergence is 0
C) refractive index of the prism
is

3
D) refractive index of the prism
is

2
Assertion and Reason:
13. I: cross-sectional area of the
water pouring out of a tap
decreases as the height from the
ground decreases.
II: work done by gravity
reduces the pressure.
14. I: The rate of change of speed
for a particle of its highest point
of parabolic path in projectile
motion is zero.
II: The rate of change of veloci-
ty for a particle of its highest
point in the parabolic path of
projectile motion is 'g'.
15. I: Hollow prism forms no spec-
tra as a solid equilateral prism of
glass.
II: Neglecting the thickness of
the hollow prism glass surface
the media is same. So dispersion
is not to take place.
I: Total power consumed in the
circuit is maximum when current
in the circuit is maximum.
II: Current in the circuit will be
maximum when power con-
sumed by load is maximum.
Comprehension I :
In figure there is a frame of two
square loops having resistors and
inductors as shown. This frame is
placed in uniform but time varying
magnetic field as shown in figure.
The magnetic field is given by
B = (20 + 10t) wb/m
2
in both
regions [L = 10 H and R = 10]
17. The direction of induced current
in bigger loop will be
A) Clockwise
B) Anticlockwise
C) First clockwise for some time
then anti clock wise and so
on
D) First anti clock wise for some
time then clock wise and so
on
18. The induced emf in the frame
only due to the variation of mag-
netic field will be
A) 0.3 volt B) 0.1 volt
C) 0.5 volt D) 0.4 volt
19. The current in the frame as a
function of time will be

16.

IIT - JEE

Paper-II

- v 3 -v 2009 16

MATHEMATICS
INSTRUCTIONS
(Q.Nos 45-53): These Questions
have only one correct option. You
will be awarded 3 marks for correct
answer and -1 mark (minus one
mark) for wrong answer.
(Q.Nos 54-57) : These Questions
are Assertion & Reasoning type,
with only one correct option. You
will be awarded 3 marks for correct
answer and -1 mark for wrong
answer.
(Q.Nos 58-63) : These Questions
are Comprehension type, with only
one correct option. You will be
awarded 4 marks for correct answer
and -1 mark for wrong answer.
(Q.Nos 64-66) : These Questions in
column-1 are to be matched with the
answers in the column-2. They may
have one or more correct options.
You will be awarded 6 marks for
correct answer. There will be one
mark for each correct match. There is
no negative marking.
45. For a complex number z, if,
z-2-i = zsin (arg z),
then locus of z is
A) a pair of straight lines
B) circle
C) parabola
D) ellipse
46. The value of
(
25
C
0
)(
25
C
22
)
+
(
25
C
1
)(
25
C
21
)
+ .................. +
(
25
C
22
)(
25
C
0
)
is equal to:
A)
(
50
C
22
)
B)
(
50
C
23
)
C)
(
50
C
27
)
D) none
[tan
-1
x - log(1+x
2
)]
47. e dx is
equal to:
A) e
tan
-
1
x
+ tan
-1
x + c
B) (tan
-1
x) e
tan
-1
x
C) e
-tan
-
1
x
+ c
D) e
tan
-
1
x
+ c
48. A curve passing through the
point (1, 4) is such that the
segment joining a point P(x, y)
on the curve and the point of
intersection of the normal at P
with the x-axis is bisected by the
y-axis. The curve represents:
A) a pair of straight lines
B) An ellipse
C) A parabola
D) Hyperbola
49. If the variable curves y
2
=
4(x
2
+a) and y = x
3
+ b ( a and b
are variable parameters) touch
each other, then their point of
contact lies on a:
A) straight line
B) circle
C) parabola
D) hyperbola
(n N, [.] denotes the greatest
integer function):
A) is equal to 2n
B) is equalto 2n-1
C) is equal to 2n-2
D) does not exist
51. f(x) = 1 + sin x, x < 0
= x
2
-x+1, x 0.
Then the wrong statement is
A) f is continuous at x = 0
B) f is not differentiable x = 0
C) f is a one-one function
D) f has a local maximum at x = 0
52. Let the coordinates of a point P
with respect to the system of
non-coplanar vectors a, b and c
be (3, 2, 1). The coordinates of P
with respect to the system of vec-
tors a+b+c, a-b+c and a+b-c
will be:
3 1 3 1
A)
(
, , 1
)
B)
(
, 1,
)
2 2 2 2
1 3
C)
(
, , 1
)
D) none
2 2
53. Two persons Aand B toss a coin,
each simultaneously for 5 times.
The probability that they get
head 3 times simultaneously is:
1 45
A) B)
3 512
5
C) D) None of these
12
Assertion & Reasoning
Bubble (A) if both the statements
are TRUE and StII is the correct
explanation of St I.
Bubble (B) if both the statements
are TRUE but StII is NOT the
correct explanation of St-I.
Bubble (C) if STATEMENT I is
TRUE and STATEMENT II is
FALSE.
Bubble (D) if STATEMENT I is
FALSE and STATEMENT II is
TRUE.
x
2
54. St-I: If the ellipses + y
2
= 1
4
x
2
and + y
2
= 1, for suitable
a
2
value of a cut on four concylic
points, the equation of circle
passing through these four points
is x
2
+y
2
= 1.
St-II: If S = 0 and S
1
= 0 are two
conics then S + S
1
= 0 repre-
sents a conic through their points
of intersection.
55. St-I: The value of
3/4
/2 +cos
-1
x

dx
2sin
-1
x+3cos
-1
x+cos
-1
(1-x)
1/4
is equal to 1/4
b b
St-II:

f(t)dt =

f(a+b-t)dt
a a
56. St-I: Between any two roots of
the equation e
x
cosx-1= 0, there
lies a root of e
x
sinx-1 = 0.
St-II: If f(x) is a differentiable
function then between any two
roots of the equation f(x) = 0
there lies a root of f
1
(x) = 0.
57. St-I: Adie is rolled 3 times. The
probability of getting a number
larger than or equal to the previ-
ous numbers in each trail is 7

.
27
St-II: The number of combina-
tions of n different things taken
r at a time allowing repetitions
is
(n+r-1)
C
r
.
Comprehension - 1
One focus and the corresponding dire-
x
2
y
2
-ctrix of the ellipse + = 1
a
2
b
2
coincide with the vertex and directrix
of a parabola. The second focus of the
ellipse is the focus of the parabola.
50.
53. The normal y = mx -2am - am
3
to the parabola y
2
= 4ax sub-
tends a right angle at the vertex
if
A) m = 1 B) m =

2
C) m = -

2 D) m =
1
/

2
54. If f(x) = x + tanx and f is an
inverse of g then g
'
(x) equals to
1
A)
1+(g(x)-x)
2
1
B)
2-(g(x)-x)
2
1
C) D) None
2+(g(x)-x)
2
55. Let e be the eccentricity of a
hyperbola and (e) be the eccen-
tricity of its conjugate
hyperbola then
3

1
....(e) de
is equal to n times
A) 4 if n is even B) 4 if n is odd
C) 2 if n is even D) 2

2 if n is odd
56. Let (x) be a function satisfying
and '(x) = (x) and(0)=1 and
g be a function satisfying (x) +
g(x) = x
2
. The value of
1

0
(x)g(x)dx
=
1 1
A) (e-7) B) (e-2)
4 4
1 e
2
3
C) (e-3) D) e -
5 2 2
Assertion - Reason
Bubble (A) if both the statements
are TRUE and St-II is the correct
explanation of St-I.
Bubble (B) if both the statements
are TRUE but St-II is NOT the cor-
rect explanation of St-I.
Bubble (C ) if St-I is TRUE and St-
II is FALSE.
Bubble (D ) if St-I is FALSE and
St-II is TRUE.
57. St-I: The equation sin(cos x) =
cos(sin x) does not possess real
roots.
St-II: If sin x > 0 then 2n < x <
(2n+1), n I.
58. St-I: In a throw of die the prob-
ability of getting one in even
number of throws is 5/11.
St-II: If p be the probability of
success and q be the probability
of failure of an event in one trial
then p + q = 1.
59. St-I: If composite function

1
(
2
(
3
(....(
n
(x)).....) is an increas-
ing function and if r of the functions
are decreasing functions while rest
are increasing, then the maximum
value of r(n-r) is
n
2
_
4
- 1 when
n = 4k+2, where k is integer.
St-II: The composite function of
two decreasing functions is a
decreasing function.
60. St-I: is a function such that
'(x)=(x-1)(x-2)
2
(x-3), then
has only 2 points of local
extrema.
St-II: has an extremum at any
point for which '(x) = 0
Comprehension -1:
Let (x) = x
3
+ ax
2
+ bx + c be the
given cubic polynomial, and (x) = 0
be the corresponding cubic equation,
where a, b, c R. Now, (x) =
3x
2
+ 2ax+b. Let D = 4a
2
- 12b be
the discriminant of the equation
(x) = 0. Then
61. If D = 4(a
2
-3b) > 0 and
(x
1
).(x
2
) > 0 where x
1
, x
2
are
the roots of
'
(x), then:
A) (x) has all real and distinct roots
B) (x) would have three real roots
but one of the root would be
repeated
C) (x) would have just one real root
D) None of these
62. If D = 4(a
2
-3b) > 0 and
(x
1
).(x
2
) = 0, where x
1
, x
2
are
the roots of
'
(x), then:
A) (x) has all real and distinct roots
B) (x) has three real roots but one
of the root would be repeated
C) (x) would have just one real root
D) None of these
63. If D = 4(a
2
-3b) > 0 and (x
1
) .
(x
2
) < 0, where x
1
, x
2
are the
roots of (x), then
A) (x) has all real and distinct roots
B) (x) has three real roots but
one of the root would be
repeated
C) (x) would have just one real root
D) (x) has three real roots but all
same
Comprehension - 2:
It can be observed that the number
of positive integers from 1 to N
which are divisible by a fixed posi-
tive integer k, ( 1 < k < N) is [N/k],
where [x] denotes greatest integer x.
Several probability problems involv-
ing divisibility may require this nota-
tion. Thus if one number is selected
from the set {1, 2, 3,...., N} then the
probability P
5
that the number is
divisible by 5 must be given by P
5
=
N
[]
5

N
64. If two numbers x and y are drawn
with replacement from the set
S = {1, 2, 3, .........,n} then the
probability P
2
that x
2
-y
2
is
divisible by 2 is given by
n
2
1
[]
(
2
)
A) P
2
=- B) P
2
=
2
n
n
n
2
[

]
[

]
2 2
C) P
2
=12
+ 2
(

)
n n
D) None of these
65. If two numbers x and y are drawn
with replacement from the set S
= {1, 2, 3, ......,n} then the proba-
bility P
3
that x
2
-y
2
is divisible
by 3 is given by
n n
2

3 3
A)
[

]
B)
(
[

]
)
n n
n
n
2
3

3
3 [ ]
[ ]
C) 1-

-3 (

)
n n
n
n
2

3 3 [ ] [
]
D) 1-2

+2 (

)
n n
66. Which of the following is true
A) P
2
is always greater than P
3
if
n2
B) P
2
is always less than P
3
if n3
C) P
2
+P
3
= 1
D) P
2
= P
3
for some N > 6
{

IIT-JEE

Paper-II

58. The eccentricity of the ellipse is
1 1
A) B)
2

2
1 1
C) D)
3

3
59. The equation of their common
directrix is
A) x =

3
a B) x = 2 a
1
C) x = D) x = -2a

3
a
60. The latus rectum of the parabola is
8
A) 4 | a | B) | a |

2
8 4
C) | a | D) | a |

3
Comprehension 2
The eigen values of a matrix A are
the values of x for which det (xI
A) = 0 where I is an identity matrix
of same order as that of A.
2 -3 4
Let A =
[
0 1 8
]
, then
0 0 -3
61. Which of the following is not an
eigen value of A
A) 2 B) -3
C) 1 D) 0
62. The matrix A is
A) Skew Symmetric
B) Symmetric
C) Lower Triangular
D) Upper Triangular
63. The eigen values of any triangu-
lar matrix are the elements
A) below the leading diagonal
B) above the leading diagonal
C) on the leading diagonal
D) none of these
- v 3 -v 2009 17
Matrix Match Type
64.
Column-1 Column-2
A) If the area bounded by P) The number of lines
x = 3t
2
+ 1, y = 2t
3
- 1 in space which are
and x = 4 is A then 5A is equally inclined to
the axes
B) Let V = 2i+j-k and W= i+3k. Q) 24
If U is a unit vector, then the
maximum value of the square
of the scalar triple product
[UVW] is
C) The product of the inradius R) square of the natural
and circumradius of the number n for which
triangle whose sides are sin 2nx
given by roots of the
f(x) =
has
equation
1+ cos
2
nx
/6 as its fundamental
x
3
-2x
2
+x-16 = 0 is period.
D) On a train route, there are
8 stopages. Number of ways of S) 59
choosing 3 stoppages such that
at least 2 are consecutive is
65.
Column-1 Column-2
A) The range of k for which the P) (1, 3
1/4
)
equation k sin + cos 2
= 2k 7 possesses a solution is
B) The interval in which x must be
1
so that the greatest term in the Q)
[

, 1
]
expansion of (1-x)
21
has the

2
numerically greatest coefficient is
C) If the sides of a triangle are in
5 6
G.P. and the largest angle is R)
(

,

)
twice the smallest then the common
6 5
ratio (r > 1) lies in
D) The range of x for which of
the equation S) [2, 6]
2 cos
-1
x = sin
-1
2x

1 - x
2
holds is
66.
Column-1
dy
A) The number of solutions of the differential equation x(x+1) + y = x(x+1)
2
e
-
x
2
dx
which approach a finite limit as x tends to zero is
x+2 2y+3 3z+4
B) Double the distance of the point (-2, 3, -4) from the line = =
3 4 5
measured parallel to the plane 4x + 12y 3z + 1 = 0 is
C) If the lines given by the equations x.cos + y + 1 = 0;
x+y.cos+1 = 0 and x+y+cos = 0 ( 2 k, kZ) are concurrent, then
the value of
1

2
(cosec
2
/2 + cosec
2
/2+cosec
2
/2) is
x
2
y
2
x
2
y
2
D) From any point on hyperbola - = 1, tangents are drawn to - = 2.
4 9 4 9
The area cut off by the chord of contact on the asymplotes is equal to
Column-2
P) 17
Q) 2
R) 24
S) 1

37. St-I: In acidic medium Zn
2+
is
not precipitated by S
2-
ions
St-II: ZnS remain soluble in
aqueous solution.
38. St-I: Hydroboration - oxida-
tion converts terminal
alkyne to ketone.
St-II: Addition of H
2
O during
hydroboration-oxidation
follows anti-
Markonikov's addition.
Passage I:
Alkyl halides undergo substitution
reactions in the presence of aqueous
alkali. Increase in the alkyl sub-
stituents on alkyl halide increases the
reactivity. More hindered alkyl-
halides when treated with concen-
trated alkali, elimination products
are over powered to substitution
products. Use of hindered base
preferably produce elimination prod-
ucts. During substitution as well as
elimination reactions there maybe
possibility of rearrangement provid-
ed the reaction intermediate becom-
ing a carbocation.
alc KOH
39. CH
3
-CH-CH
2
Br

CH
3
p (major). The major product formed is
A) CH
2
= C -CH
3

CH
3
B) CH
3
-CH = CH-CH
3
C) CH
3
-CH
2
-CH = CH
2
D) None
ONa

40. + CH
3
CH
2
-Br

Q (major)
The major product formed is
A) B) CH
2
= CH
2
C)

O

CH
2

CH
3
D) None
Br

OH
-
aq/ether
41. CH
3

CH

CH
2
CH
3

OH

CH
3

CH

CH
2
CH
3
the
d(+)
stereo chemistry of the product can be
A) d+ B) l(-) C) dl() D) none
Passage II:
A metal complex having composi-
tion Cr(NH
3
)
4
Cl
2
Br has been isolat-
ed in two forms(x) and (y). 'x' reacts
with AgNO
3
gives a yellow precipi-
tate soluble in concentrated ammonia
while 'y' with AgNO
3
gives a white
precipitate which is quite soluble in
dilute aquears ammonia.
42. Structure of 'x' can be
A) [Cr(NH
3
)
4
Cl
2
]NO
3
B) [Cr(NH
3
)
4
Cl
2
]Br
C) [Cr(NH
3
)
4
BrCl]Cl
D) [Cr(NH
3
)
4
ClBr]NO
3
43. Hybridisation of Cr in the com-
plex A or B is
A) d
2
sp
3
B) sp
3
d
2
C) dsp
2
D) sp
3
d
44. The magnetic moment (spin-
only value) of the complex is
A) 2.82 BM
B) 3.87 BM
C) 1.73 BM
D) 4.89 BM
MATHEMATICS
(Q.Nos 45-56): These Questions
have one or more than one correct
option. You will be awarded 3 marks
for correct answer and -1 mark
(minus one mark) for wrong answer.
(Q.Nos 57-60): These Questions are
Assertion & Reasoning, with only
one correct option. You will be
awarded 3 marks for correct answer
and -1 mark for wrong answer.
(Q.Nos 61-66): These Questions are
Comprehension, with only one cor-
rect option. You will be awarded 3
marks for correct answer and
-1 mark for wrong answer.
(1+x)
2
(1+x)
3
(1+x)
4
45. If (x) =

(1+x)
4
(1+x)
6
(1+x)
8

(1+x)
6
(1+x)
9
(1+x)
12
then the coefficient of x in f(x) is
A) 0 B) 12
C) 48 D) 24
46. Atrain moves on a circular track
passing through eight stations on
its route before returning to the
originating station. The number
of ways in which a train can stop
at 3 of these intermediate stations
such that no two stations are
adjacent is
A) 14 B) 12 C) 20 D) 24
47. The probability that sin
-1
(sin x)
+ cos
-1
(cos y) is an integer for
x, y {1, 2, 3, 4} is
1 3
A)

B)

16 16
15
C)

D) None of these
16
48. Let (x) = ax
2
+bx+c; a, b, cR
and a 0. If (x)>0 xR and
g(x) = (x)+'(x)+''(x) then
A) g(x) > 0 for all x R
B) g(x) < 0 for all x R
C) g(x) = 0 has non-real roots
D) g(x) = 0 has real roots
49. The complex numbers Z
1
, Z
2
Z
1
- Z
3
and Z
3
satisfying =1+i
Z
2
- Z
3
are the vertices of a triangle
which is
A) equilateral B) isosceles
C) right-angled D) scalene
50. If n

1
, n

2
are two unit vectors and
is the angle between them, then
cos (/2) =
1

1
A)

n
1
+n
2

B)

1
-n

2
2 2
1 1
n

1
n

2
C)

1
.n

D)
2
2
n

1
n

2
51. The symmetric form of the equa-
tion of the line of intersection of
the planes x + y - z = 1 and
2x - 3y + z = 2 is
x y z
A) = =
2 3 5
x y z-1
B) = =
2 3 5
x y-1 z
C) = =
2 3 5
x-1 y z
D) = =
2 3 5
52. Asquare is inscribed in the circle
x
2
+ y
2
- 10x - 6y+30 = 0. One
side of the square is parallel to
the line y = x + 3, then one ver-
tex of the square is
A) (3, 3) B) (7, 3)
C) (6, 3) D) (6, -

3 )

. :

.. . :... ... ..
.. . .... .. ...t
....: .. ...... .....
...
I. . . . .. . . .. . . .:.
... .:. .. .. ..
..:.. ..: ... :. ....
.: . . .:. ...
....
.:. ... .... ..: ...
.... .:
i) ... . .. .
ii) ..... ...
iii) ... ...
iv) .. .... ...
v) :.... ...
. .. ..... .. ....
.... . :.. . ..
.. .. .:. .. ....
... ... .... ..
... .. .. . . ...
:. . ..: .. ..: ..:
.:. ... ..:..
As, Pb, Cd .. : ... ..
.. .. .. . .....
.. .:.. .. ...
. . . , .. . BHC ..
.. . .. . 2-4 ...
.. ... .. . . .. .
.. . .. ..
.:. .. ..: :.. .:.
. ..
1) .. . ...: .. .. ..
2) ... .. . .. ..
.. . .. .. ..
3) . . : . . . . . .
...
. ..... ... ... .... .
... ...:. .. .. .. .
. ...
... .. ... . ...:.
... ... ...
.. . ... . .. . ..
t. . . . . .. .: . . .
... ... ... .... ...
... ... ..... ... ...
:.. .: ... .. ...
... .... ...
.. . ... ... .. . .
.... . .:. BOD, .. .
: .t. ... .. .
..... .: :.... t..
.. . TNT .. .. ..
. .. ..... ..... ..
:. .. . ..t
... .. .. ..
.. ... . :.. :. . .:
. . . . . .. .. . . .
.. . ... .... ...
.... . .. . ....
. . :.. ... ... ..
. .:.
. . . ..... .: ....
.. . t . . . .. . . .. .
. . . . . . . .. .
.... .....
.. . .. . ..
.... .... .....
.... .. ..... .: :..
.. .. .. .... ..
. .... .....
..... .. .. .... :
... .... . ... ..
.... ... .... . ...
...
..... ... BOD :.. .
.... . ... ...
. . . . . .. .. ..
.. .. .. ... ..
... . .... .. ....
NaOH, H
2
SO
4
. .. . . :
.. ..: .. .. t.. ..
.. . .. ... .....
II .....
.... .. ...
1 .:. .- ... :. .. .....
. .... ... ... ...
.. . .... ... .:
...... .:
.. .. . ...
....
. .: . . . : . . . . . .
.. ... 1) . .:. :.
2) .... t. 3) . .. t.
. ...... . .:. :.
(. .. . ) . : . . . . .
CH
4
+ Cl
2
CH
3
Cl+ HCl
... ... .... t. .:.
.. ... .. ...
.. ... . .. . NO
2
+
. .... ....:
. . . ... . .
.t. .:... ... .. ...
C
2
H
5
Cl + NaOHC
2
H
5
OH + NaCl
2. ... . ... .... .
. ... ......
.. .... .....
.. .. .. ... .... .:
:. ... - ... 2 ""
... ... ...
.. sp ....... sp
2
.
sp
2
....... sp
3
.. ...
. .:
... ... . .:. :. .
.. t. .... t. ... .....
.t .. .. ... . .
.t. ... ... .. ...
O OH

CH
3
-C - H+ HCNCH
3
-CH
CN
.-.eaee- -. .e. .o+t. e- -e- .e.
-e - e-e .-- te _.. .e- -e- a..- e- .o.-
. . e- -e- .ea.,.a .e. e .o-- .o
.-.-e .-_-.e e..-e --.-- -.. ..-
- - - - - - Lq- - - ?
.:.....
- . . -
.
..... .. .. ....
I. ....
.. .. 1 .:. ...
2 ..... ...
II. ..
.. .. 1 .. .. ...
2 . ..
... . .:
. :.. ....
3 ....
. .. ....
. .. . .:..
4 .. . ..
III. ... 1 ... .. .
. 2 ... ...
.. 3 . .:.
.. ...
IV. .. 1 .. ....
...
V. .. 1 .. ..
. .. . . ..
2 ... ..
...
VI. . . . .
.:. .. 1 CaO, CaCO
3
.
.. . ...

1 1
A) (1-e
-t
) B) (1-e
-t
)
20 40
1 1
C) e
-t
D) e
-t
20 10
Comprehension -II:
A specially designed tuning fork
(A) is used to measure the speed in
air at 27C using a resonance tube of
diameter 7.5 cm resonance is
observed for two lengths (un cor-
rected) of the air column L
1
=
179.25 cm and L
2
= 113.25 cm.
The tuning fork (A), when sound-
ed together with a 2.5 m long
sonometer wire ( = 25 g/m) vibrat-
ing with 36 loops at a load of 12.25
kg, gives a beat frequency of 4 Hz.
When the tuning fork (A) is sound-
ed together with the same sonome-
ter, now vibrating instead with 35
loops, it produces beats at 10 Hz.
20. The frequency of tuning fork is
A) 400 Hz B) 500 Hz
C) 430 Hz D) 330 Hz
21. The frequency of sonometer in
two cases are
A) 404 Hz and 390 Hz
B) 434 Hz and 420 Hz
C) 504 Hz and 490 Hz
D) 334 Hz and 320 Hz
22. The speed of sound in air (at
27C) is
A) 340 m/s B) 310 m/s
C) 330 m/s D) 300 m/s
(Q.Nos 23-34): These Questions
have one or more than one correct
option. You will be awarded 3 marks
for correct answer and -1 mark
(minus one mark) for wrong answer.
(Q.Nos 35-38): These Questions are
Assertion & Reasoning, with only
one correct option. You will be
awarded 3 marks for correct answer
and -1 mark for wrong answer.
(Q.Nos 39-44): These Questions are
Comprehension, with only one cor-
rect option . You will be awarded 3
marks for correct answer and
-1 mark for wrong answer.
23. A car tyre has a volume of 10 L
when inflated. The tyre is inflat-
ed to a pressure of 3 atm, at 17
o
C with air. While driving the
temperature of the tyre is
increased to 47
o
C. The pressure
of the tyre at this temperature
would be
A) 3.0 atm B) 3.21 atm
C) 3.31 atm D) None of these
24. In which of the following com-
pound vanadium can have +2
oxidation state?
A) NH
4
VO
2
B) K
4
[V(CN)
6
]
C) VSO
4
D) VOSO
4
25. 0.116 g of C
4
H
4
O
4
(A) is neu-
tralised by 0.074 g Ca(OH)
2
. The
number of protonic hydrogen in
A would be
A) 1 B) 2 C) 3 D) 4
26. The orbital angular momentum
of an electron in 2s-orbital is
h h
A) B)
4 2
h
C) V
2
. D) Zero
2
27. Half life period of a radioactive
substance is 140 days. After how
much time 15g will decay from
16 g sample of it?
A) 140 day B) 560 day
C) 280 day D) 420 day
28. Which of the following are iso
electronic?
+
A) -CH
3
B) -NH
2
+
C) -NH
3
D) -NH
4
+
29. Which of the following can have
same bond order as that in CO?
A) NO
-
B) NO
+
C) CN
-
D) N
2
30. Ph-CH-CH
2
-CH
2
-Br

Br
Zn-Cu
x.'x' is

A) Ph-CH = CH-CH
2
Br
B) Ph-CH(Br).CH = CH
2
C) Ph
D) Ph-CC-CH
3
31. In which of the following reac-
tions, two products will be
formed other than Ph
3
PO
(Phosphonium Oxide)?
A) CH
3
-C-CH
3
+Ph
3
P = CH
2

O
CH
3
B) CH
3
CHO+Ph
3
P = C
CH
3
C) HCHO+Ph
3
P = CH-CH
3

D) PhCHO+Ph
3
P = CHPh
33. Which of the following pairs are
epimers
A) D-Glucose, D-Galactose
B) D-Glucose, D-Fructose
C) D-Glucose, D-Mannose
D) -D-Glucopyranose,
-D-Glucopyranose
A1(OC
2
H
5
)
3
34. CH
3
CHO CH
3
COOC
2
H
5
.
The reaction is called:
A) Tischenko reaction
B) Cannizzaro reaction
C) Claisen condensation
D) Aldol condensation
Assertion & Reason Type
Bubble (A) if both the statements
are TRUE and St-II is the correct
explanation of St-I.
Bubble (B) if both the statements
are TRUE but St-II is NOT the cor-
rect explanation of St-I.
Bubble (C ) if St-I is TRUE and
St-II is FALSE.
Bubble (D ) if St-I is FALSE and
St-II is TRUE.
35. St-I: Ethyl acetate is more reac-
tive than ethanamide towards
nucleophillic substitution.
St-II: -OC
2
H
5
- is better leav-
ing group in ethyl acetate than -
NH
2
group in ethanamide.
36. St-I: Formation of Cl
-
is
exothermic but formation
of O
2-
is endothermic.
St-II: O is more electronegative
than Cl.
32.
CHEMISTRY

. :

. .. .. 'H
2
' ..... .: ....
:. ... '-1' ..... :.
....:
C) .. .:.. ... ...
. .. . ... .. .. ...
. ... .. ... ... :
... ... .... .: .:. .
... . ..... ... ..
.. . ... ... .:. ...
....: .... ... . ..
. .. ... ... :: . ..
.. .. ... . .. .:
... (Ice) .: . ...
. ... ... ... .:
.... .. .. ..: .....
. .:. .. ... .... 2774
K .. .. 87 ... :..
.... .:
. . . .. ..... ..
:.. ..... ....:
H
2
O + H
2
O

H
3
O
+
+ OH
-
. ... .. . ... ...
. .:

H
2
O + C CO + H
2
. .. . .. . .. ...
Na
2
O + H
2
O 2 NaOH
CaO + H
2
O Ca (OH)
2
.. .. . .. ... ...
SO
3
+ H
2
O H
2
SO
4
Cl
2
O
7
+ H
2
O 2H ClO
4
. .... .. . ..:.
. ......
SiCl
4
+ 2H
2
O SiO
2
+ 4HCl
AlCl
3
+ 3H
2
O Al(OH)
3
+ 3HCl
PCl
5
+ 3H
2
O H
3
PO
3
+ 3HCl
... ... ... .. ..
CO
2
, . .. ..:. .... ..
... ...
6CO
2
+ 6H
2
O C
6
H
12
O
6
+ 6O
2
4. .... ... .. .... (Q
f
)
(Formal Charge)
.. ... . ....... .
..:..... ... .. ....
.. ... . .. . .. ....
....
.. .... .: .. . .:.
. .. . .. .. ..
.... ..... .. ...
... .. . . . . . . ..
..: ... ... .. ..
.. .... ....
.. .... = V - (L+ 1/2S)
... V= .... ..... ..
e
-
. ..
L = .... . e
-
. ..
S = ... e
-
. ..
. ...... .. .. ..
1) PH
3
'P' . ..: Q
f
Q
f
= {5-2-1/2 (6)} = 0
2) N
2
O ... 'N' ..... Q
f
:
N
..
= N
= O
..
:
Q
f
= {5-0-1/2 (8) } = +1
V. ... .-.. .... ...-
...-.
. .. . ... ... 4
.. . .. ....
i) .... ... ....
: . : . :. :.: ... ..
...:.: ..
. .. .... .. .. .
.. .... ... . .. ..
. . . ..: . .. .
... . .. . . t
. .. .... .. . ....
......
ii) .. e.. ....
: .:.:.:.: . ...:.:
...
. .. .... .. ..
.... .. ... . .. :.
. ..... ....:
... .:. ... ... Cu,
O, C. .. : .. ....
. . .....
iii) .... .... : .:.
:.:.: .. ...:.: .. t.
. .. .... ... ....
... ..: ... . ... ...
... .. ..... ...
. .. ... . .. ....
. ... ... ... .... ..:
... . .... : .....
N
2
O, NO, N
2
O
3
, N
2
O
4
, N
2
O
5
. 14 ... ...
... ... ... .. 8 16
24 24 40 ....:
... ... ::. ... :
1 2 3 4 5 (. .... :)
iv) ...- .. ..--. ....
. . .:.:.:.: ..
. .. .... .. . . ..
. . . .. . .. . . .
.. . . .:. .. ..
. . .. . . : . . . ..
: ....:
2H
2
.
+ O
2
.
- 2 H
2
O
.
... .. ...
...... .. .... ... .. .
. . ... ... ... ....
.: ... 4 ...
i) .. ...- ... ...
.... . .. .... ..
. .. ..... . . .....
2 Al + N
2
2 Al N
. .. .. ... ..... :
0 .: -2. ... .:
C + O
2
CO
2
ii) .. - . . . :. . . . .
... . ... ... ... ....
.. .. ... . .. .. .:
2 H
2
O 2 H
2
+ O
2
2 KClO
3
2KCl + 3O
2
. :. ... ... ... ..
CaCO
3
CaO + CO
2
iii) ... ... .. ..
... .. .... ..:
..... : .. . .:
Zn + CuSO
4
ZnSO
4
+ Cu
Fe + 3H
2
O Fe
2
O
3
+ 3H
2
Au, Ag .. .. H
2
... .:.
'SRP' . ..... .. .: . ...
.: H
2
.... .. .
. .... F
2
. ..:. .
. ..... ... ....:
iv) e.... .. ... ..
.. .... ...... .. .... ..:.
. ... .. ....
... .. . .... ..
3 ... ..... . .. ...t
.. . .... .. .....
:. ... ... .. . ..
.:. ..... . . .... ...
. .:
OH
-
P
4
PH
3
+ H
3
PO
2
. ..
..... : . 'P' .... -3
. PH
3
1 .. . . . : .
H
3
PO
2
...:
... ... .:... .. ..
... .. ....
.. ::. ..... . . ..
.... ... ..: .. .....
: . .. .... ... .:
Ag
+2
(
..
)
Ag
(
.
)
2Ag
+
(
..
)
VI. .. .. .:. .. ..-:
...-.
i) CaO: ..... .
'CaO' .:..... .. . ..
:. .. .:.. .. CO
2

.. .: ...
'CaO' 'Quick lime' . ..
....
: ... . .. . CaCl
2
.. .. .. .. .. ..
ii) CaCO
3
: .. ..: ..
.. .: .. .. ..
... .:
... .. . . . CaCO
3
. . .. .. ..
: . .. ... . ..
.... .. .. ....
- . . -
..... ..... . .
... .: . . ...
1070 K
CaCO
3
CaO + CO
2
MODEL PAPER FOR AIEEE
PAPER

PHYSICS
INSTRUCTIONS
(Q.Nos 1-12): These Questions
have one or more than one correct
option. You will be awarded 3 marks
for correct answer and -1 mark
(minus one mark) for wrong answer.
(Q.Nos 13-16): These Questions are
Assertion & Reasoning, with only
one correct option. You will be
awarded 3 marks for correct answer
and -1 mark for wrong answer.
(Q.Nos 17-22): These Questions are
Comprehension, with only one cor-
rect option. You will be awarded 3
marks for correct answer and -1
mark for wrong answer.
1. Two particles start simultaneous-
ly from the same point and move
along two straight lines inclined
at 60 with respect to each other,
one with uniform velocity 4 m/s
and the other with constant accel-
eration 0.5 m/s
2
. The distance
between the particles when the
relative velocity is minimum is
A) 4 m B)
4

3 m
C)
4

13 m
D)
4

2 m
2. It is desired
to construct
a toy by
attaching a
solid cone
on top of
solid hemi-
sphere as
shown in the figure. The radius of
the hemisphere and the base of
cone is R. If the toy is to be in a
stable equilibrium in the shown
position then:
(Given that both cone and hemi-
sphere are made of same material)
A) H <

3 R
B) H >

3
R
C)

3
R < H < 2R
D) Centre of mass of the com-
bined system must not be
above O
'
3. A bottle is kept on the ground in
the figure.
The bottle
can be mod-
elled as hav-
ing two
cyl i ndr i cal
zones. The
lower zone
of the bottle
has a cross-sectional radius of
R

2
and is filled with honey of
density 2. The upper zone of the
bottle is filled with the water of
density and has a cross-section-
al radius R. The height of lower
zone is H while that of upper zone
is 2H. If now the honey and the
water parts are mixed together to
form a homogeneous solution
(Assume that total volume does
not change)
A) The pressure inside the bottle
at the base will remain unal-
tered.
B) The normal reaction on the
bottom from the ground will
remain unaltered.
C) The pressure inside the bottle
at the base will increase by an
amount 9/2 gH.
D) The pressure inside the bottle
at the base will increase by an
amount (1/4) g H.
4. A particle
is sus-
p e n d e d
by two
ideal
strings as
shown in the figure. Now mass M
is given a small displacement
perpendicular to the plane of tri-
angle formed.
Choose the correct statements.
A) The period of oscillation of the
3

3 l
system is 2

g
B) The period of oscillation of the
3
l
system is 2

g
C) The period of oscillation of the
system is independent of M
D) If the distance between the
suspension points was kept
constant and the strings were
quadrupled then the period of
the system will double.
5. A vertical con-
ducting ring of
radius R falls
vertically in a
h o r i z o n t a l
magnetic field
of magnitude
'B' as shown. When the speed of
ring is V
A) No current flows in the ring
B) Aand B are at the same potential