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Gas Encyclopaedia
This application enables data on many gas molecules to be accessed rapidly. You can search on a raw chemical formula, chemical name or UN transportation code. The values displayed on this page are extracted from the literature and the proprietary current AIR LIQUIDE Group data.

User guide

Gas selection Chemical Formula Name


Ammonia

UN Transportation Code

NH3 Ammonia CAS Number : 7664-41-7 UN1005 ;R717;


Main applications Gas Properties Vapor Pressure Graph Liquid Gas Conversion Safety Data Sheets Major Hazards Material compatibility

Ammonia: SUPPLY MODE Cylinders, Liquefied gas tank, Main applications Industries Applications

Chemicals Ammonia is the starting material for nitric acid manufacture. Laboratories & analysis Ammonia is used in calibration gas mixtures for environmental emission monitoring, petrochemical industry, industrial hygiene monitors and trace impurity analyzers.

Electronics Ammonia is used in semiconductor manufacturing and advanced materials for the deposition of silicon nitride (Si3N4) by Chemical Vapor Deposition (CVD).

Environment Ammonia is a refrigerating fluid used instead chlorofluorocarbons (freons) in some refrigerators.

Top of the page Gas Properties Molecular Weight

Molecular weight : 17.03 g/mol Melting point : -78 C Latent heat of fusion (1,013 bar, at triple point) : 331.37 kJ/kg Liquid density (1.013 bar at boiling point) : 682 kg/m3 Liquid/gas equivalent (1.013 bar and 15 C (59 F)) : 947 vol/vol Boiling point (1.013 bar) : -33.5 C Latent heat of vaporization (1.013 bar at boiling point) : 1371.2 kJ/kg Vapor pressure (at 21 C or 70 F) : 8.88 bar Critical temperature : 132.4 C Critical pressure : 112.8 bar Gas density (1.013 bar at boiling point) : 0.86 kg/m3 Gas density (1.013 bar and 15 C (59 F)) : 0.73 kg/m3 Compressibility Factor (Z) (1.013 bar and 15 C (59 F)) : 0.9929 Specific gravity (air = 1) (1.013 bar and 21 C (70 F)) : 0.597 Specific volume (1.013 bar and 21 C (70 F)) : 1.411 m3/kg Heat capacity at constant pressure (Cp) (1.013 bar and 15 C (59 F)) : 0.037 kJ/(mol.K) Heat capacity at constant volume (Cv) (1.013 bar and 15 C (59 F)) : 0.028 kJ/(mol.K) Ratio of specific heats (Gamma:Cp/Cv) (1.013 bar and 15 C (59 F)) : 1.309623 Viscosity (1.013 bar and 0 C (32 F)) : 0.000098 Poise Thermal conductivity (1.013 bar and 0 C (32 F)) : 22.19 mW/(m.K) Solubility in water (1.013 bar and 0 C (32 F)) : 862 vol/vol Autoignition temperature : 630 C

Solid phase

Liquid phase

Critical point

Gaseous phase

Miscellaneous

Go back to choosing the units Top of the page Vapor Pressure Graph

The vapor pressure curve may be obtained by clicking on the image. On the graph, pressure is in bar or 0.1 MPa, temperature in K or C. The critical point is indicated by a black spot on the liquid-vapor equilibrium curve.

Top of the page Liquid Gas Conversion Liquid to gas conversion This module enables a volume (measured at 1 atmosphere and boiling point) or a mass of liquid gas to be converted into a volume or a mass of gas measured at 1 atmosphere and 15 C. Data : liquid Phase Input the volume (m3) or mass (kg)
Calculate

Gas to liquid conversion This module enables a volume (measured at 1 atmosphere and 15 C) or a mass of gas in gaseous phase to be converted into a mass or a volume of liquid (measured at 1 atmosphere and boiling point). Data : Gas Phase Input the volume (m3) or mass (kg)
Calculate

Go back to choosing the units

Top of the page Safety Data Sheets Safety Data Sheets (SDS) include information on product ingredients, physical and chemical properties, potential effects on toxicology and ecology, identification of hazards, handling and storage instructions, as well as personnel protection recommendations and information related to transportation requirements, first-aid and emergency processes. Top of the page Major Hazards Major hazard : Inhalation and Bodily Contact Toxicity (Am. Conf. Of Gov. Ind. Hygienists ACGIH 2000 Edition) : 25 ppm Flammability limits in air (STP conditions) : 15-30 vol% Odour : Pungent, Irritating UN Number : UN1005 EINECS Number : 231-635-3

DOT Label (USA) : NFG DOT Hazard class (USA) : Non flammable Gas

Top of the page Material compatibility Air Liquide has assembled data on the compatibility of gases with materials to assist you in evaluating which products to use for a gas system. Although the information has been compiled from what Air Liquide believes are reliable sources (International Standards: Compatibility of cylinder and valve materials with gas content; Part 1: ISO 11114-1 (Jul 1998), Part 2: ISO 11114-2 (Mar 2001)), it must be used with extreme caution. No raw data such as this can cover all conditions of concentration, temperature, humidity, impurities and aeration. It is therefore recommended that this table is used to choose possible materials and then more extensive investigation and testing is carried out under the specific conditions of use. The collected data mainly concern high pressure applications at ambiant temperature and the safety aspect of material compatibity rather than the quality aspect. Material Compatibility Metals Aluminium Satisfactory Brass Non recommended Copper Non recommended Ferritic Steels (e.g. Carbon steels) Satisfactory Stainless Steel Satisfactory Plastics

Polytetrafluoroethylene (PTFE) Satisfactory Polychlorotrifluoroethylene (PCTFE) Satisfactory Vinylidene polyfluoride (PVDF) (KYNAR) Non recommended, notable acceleration of the process of ageing and significant loss of mass by extraction or chemical reaction.

Polyamide (PA) (NYLON) Satisfactory Polypropylene (PP) Satisfactory

Elastomers

Buthyl (isobutene - isoprene) rubber (IIR) Satisfactory Nitrile rubber (NBR) Acceptable but significant loss of mass by extraction or chemical reaction. Chloroprene (CR) no data Chlorofluorocarbons (FKM) (VITON) Non recommended, significant loss of mass by extraction or chemical reaction. Silicon (Q) Non recommended, significant loss of mass by extraction or chemical reaction. Ethylene - Propylene (EPDM) Satisfactory

Lubricants Hydrocarbon based lubricant Non recommended, significant loss of mass by extraction or chemical reaction. Fluorocarbon based lubricant Satisfactory Top of the page Selection of the units You can choose the units in which the values are displayed. By default, SI units are selected. Quantity Units
29

Mass kg Volume m3 Pressure bar psi kPa ft3 l lb g

Temperature

C Density kg/m3 Enthalpy kJ/kg

lb/ft3

mol/l

(lb-mol)/ft3

Btu/lb

kJ/mol

kcal/kg

kcal/mol

Btu/lb-mol

Heat Capacity kJ/(mol.K) cal/(mol.K) Btu/(lb.F) J/(mol.K) kJ/(kg.K) Btu/(lb-mol.F) kcal/(kg.K)

Viscosity Poise lb/(ft.s) Pa.s Pa.s

Thermal Conductivity mW/(m.K) Btu.ft/(h.ft2.F) cal.cm/(h.cm2.C) W/(m.K)

(cal.cm)/(s.cm2.C) Concentration vol %


31

vol ppm

vol/vol

Solubility vol/vol lb/ft3 (lb-mol)/ft3 mol/l g/l

Specific volume m3/kg ft3/lb l/mol


81

ft3/lb-mol
82

77

78

Click to change the values

Top of the page


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Products Gas Encyclopdia Contact us now For any technical information on this topic, a quotation

By E-mail: Click here

Gas Encyclopdia: The book

To order by Air liquide, Ed Elsevier This encyclopaedia gives you a quick access to the physical and thermodynamics properties of 138 gases.

Specialty gases

Specialty gases To feed or to calibrate your analyzers with pure gases and mixtures, select the right products in our specialty gases and equipment catalogs and send us a request for a quotation.

Suggestions

Safety Data Sheets

Legal notice Site Map RSS Copyright AIR LIQUIDE 2009

Aller au menu Aller au contenu


Top of Form

s
Bottom of Form

Search

Language

Contact us now

COMPANY OUR OFFER PRESS SHAREHOLDERS

INVESTORS CAREERS

Top of Form

11

19

Gas Encyclopaedia
This application enables data on many gas molecules to be accessed rapidly. You can search on a raw chemical formula, chemical name or UN transportation code. The values displayed on this page are extracted from the literature and the proprietary current AIR LIQUIDE Group data.
User guide Gas selection Chemica l Formula
Ammonia

UN Name Transportati on Code

NH3 Ammonia CAS Number : 7664-41-7 UN1005 ;R717;

Main applications Gas Properties Vapor Pressure Graph Liquid Gas Conversion Safety Data Sheets Major Hazards Material compatibility

Ammonia: SUPPLY MODE Cylinders, Liquefied gas tank, Main applications Industries Applications

Chemicals Ammonia is the starting material for nitric acid manufacture.

Laboratories & analysis Ammonia is used in calibration gas mixtures for environmental emission monitoring, petrochemical industry, industrial hygiene monitors and trace impurity analyzers.

Electronics Ammonia is used in semiconductor manufacturing and advanced materials for the deposition of silicon nitride (Si3N4) by Chemical Vapor Deposition (CVD).

Environment Ammonia is a refrigerating fluid used instead chlorofluorocarbons (freons) in some refrigerators.

Top of the page Gas Properties Molecular Weight Molecular weight : 17.03 g/mol

Solid phase Melting point : -78 C Latent heat of fusion (1,013 bar, at triple point) : 331.37 kJ/kg

Liquid phase Liquid density (1.013 bar at boiling point) : 682 kg/m3 Liquid/gas equivalent (1.013 bar and 15 C (59 F)) : 947 vol/vol Boiling point (1.013 bar) : -33.5 C Latent heat of vaporization (1.013 bar at boiling point) : 1371.2 kJ/kg Vapor pressure (at 21 C or 70 F) : 8.88 bar

Critical point Critical temperature : 132.4 C Critical pressure : 112.8 bar

Gaseous phase Gas density (1.013 bar at boiling point) : 0.86 kg/m3 Gas density (1.013 bar and 15 C (59 F)) : 0.73 kg/m3 Compressibility Factor (Z) (1.013 bar and 15 C (59 F)) : 0.9929 Specific gravity (air = 1) (1.013 bar and 21 C (70 F)) : 0.597 Specific volume (1.013 bar and 21 C (70 F)) : 1.411 m3/kg Heat capacity at constant pressure (Cp) (1.013 bar and 15 C (59 F)) : 0.523 kcal/(kg.K) Heat capacity at constant volume (Cv) (1.013 bar and 15 C (59 F)) : 0.399 kcal/(kg.K) Ratio of specific heats (Gamma:Cp/Cv) (1.013 bar and 15 C (59 F)) : 1.309623 Viscosity (1.013 bar and 0 C (32 F)) : 0.000098 Poise Thermal conductivity (1.013 bar and 0 C (32 F)) : 22.19 mW/(m.K)

Miscellaneous Solubility in water (1.013 bar and 0 C (32 F)) : 862 vol/vol Autoignition temperature : 630 C

Go back to choosing the units Top of the page Vapor Pressure Graph

The vapor pressure curve may be obtained by clicking on the image. On the graph, pressure is in bar or 0.1 MPa, temperature in K or C. The critical point is indicated by a black spot on the liquid-vapor equilibrium curve.

Top of the page Liquid Gas Conversion Liquid to gas conversion This module enables a volume (measured at 1 atmosphere and boiling point) or a mass of liquid gas to be converted into a volume or a mass of gas measured at 1 atmosphere and 15 C. Data : liquid Phase Input the volume (m3) or mass
Calculate

(kg)

Gas to liquid conversion This module enables a volume (measured at 1 atmosphere and 15 C) or a mass of gas in gaseous phase to be converted into a mass or a volume of liquid (measured at 1 atmosphere and boiling point). Data : Gas Phase Input the volume (m3) or mass
Calculate

(kg)

Go back to choosing the units

Top of the page

Safety Data Sheets Safety Data Sheets (SDS) include information on product ingredients, physical and chemical properties, potential effects on toxicology and ecology, identification of hazards, handling and storage instructions, as well as personnel protection recommendations and information related to transportation requirements, first-aid and emergency processes.

Top of the page Major Hazards Major hazard : Inhalation and Bodily Contact Toxicity (Am. Conf. Of Gov. Ind. Hygienists ACGIH 2000 Edition) : 25 ppm Flammability limits in air (STP conditions) : 15-30 vol% Odour : Pungent, Irritating UN Number : UN1005 EINECS Number : 231-635-3 DOT Label (USA) : NFG DOT Hazard class (USA) : Non flammable Gas

Top of the page Material compatibility Air Liquide has assembled data on the compatibility of gases with materials to assist you in evaluating which products to use for a gas system. Although the information has been compiled from what Air Liquide believes are reliable sources (International Standards: Compatibility of cylinder and valve materials with gas content; Part 1: ISO 11114-1 (Jul 1998), Part 2: ISO 111142 (Mar 2001)), it must be used with extreme caution. No raw data such as this can cover all conditions of concentration, temperature, humidity, impurities and aeration. It is therefore recommended that this table is used to choose possible materials and then more extensive investigation and testing is carried out under the specific conditions of use. The collected data mainly concern high pressure applications at ambiant temperature and the safety aspect of material compatibity rather than the quality aspect. Material

Compatibility Metals Aluminium Satisfactory Brass Non recommended Copper Non recommended Ferritic Steels (e.g. Carbon steels) Satisfactory Stainless Steel Satisfactory Plastics Polytetrafluoroethylene (PTFE) Satisfactory Polychlorotrifluoroethylene (PCTFE) Satisfactory Vinylidene polyfluoride (PVDF) (KYNAR) Non recommended, notable acceleration of the process of ageing and significant loss of mass by extraction or chemical reaction. Polyamide (PA) (NYLON) Satisfactory Polypropylene (PP) Satisfactory Elastomers Buthyl (isobutene - isoprene) rubber (IIR) Satisfactory Nitrile rubber (NBR) Acceptable but significant loss of mass by extraction or chemical reaction. Chloroprene (CR) no data

Chlorofluorocarbons (FKM) (VITON) Non recommended, significant loss of mass by extraction or chemical reaction.

Silicon (Q) Non recommended, significant loss of mass by extraction or chemical reaction.

Ethylene - Propylene (EPDM) Satisfactory

Lubricants Hydrocarbon based lubricant Non recommended, significant loss of mass by extraction or chemical reaction. Fluorocarbon based lubricant Satisfactory Top of the page Selection of the units You can choose the units in which the values are displayed. By default, SI units are selected.

Quantity Units

29

Mass kg lb g

Volume m3 ft3 l

Pressure bar psi kPa

Temperature C F K R

Density kg/m3 lb/ft3 mol/l (lb-mol)/ft3

Enthalpy kJ/kg Btu/lb kJ/mol kcal/kg kcal/mol Btu/lb-mol

Heat Capacity kJ/(mol.K) cal/(mol.K) Btu/(lb.F) J/(mol.K) kJ/(kg.K) Btu/(lb-mol.F) kcal/(kg.K)

Viscosity Poise lb/(ft.s) Pa.s Pa.s

Thermal Conductivity mW/(m.K) Btu.ft/(h.ft2.F) cal.cm/(h.cm2.C) W/(m.K)

(cal.cm)/(s.cm2.C) Concentration vol %


31

vol ppm

vol/vol

Solubility vol/vol lb/ft3 (lb-mol)/ft3 mol/l g/l

Specific volume m3/kg ft3/lb


81

l/mol

ft3/lb-mol
82

77

78

Click to change the values

Top of the page


Bottom of Form

Products

Gas Encyclopdia

Contact us now
For any technical information on this topic, a quotation By E-mail: Click here

Gas Encyclopdia: The book

To order by Air liquide, Ed Elsevier This encyclopaedia gives you a quick access to the physical and thermodynamics properties of 138 gases.

Specialty gases

Specialty gases To feed or to calibrate your analyzers with pure gases and mixtures, select the right products in our specialty gases and equipment catalogs and send us a request for a quotation.

Suggestions
Safety Data Sheets

Legal notice Site Map RSS Copyright AIR LIQUIDE 2009

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