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2.
The speed of light in the medium is Ans: Sol: Minimum on the axis of the beam Intensity is maximum along the axis refractive index maximum along the axis speed minimum along the axis.
Statement 1: Two particles moving in the same direction do not -----Ans: Statement -1 is true, Statement 2 is true; Statement-2 is the correct explanation of Statement-1
3.
As the beam enters the medium -----Ans: Sol: Converge Intensity is maximum at the centre and decreases with increasing radius light energy getting concentrated near centre beam is converging.. 8.
Sol: Linear momentum is conserved and initial momentum is not zero final momentum is not zero particles have speed after collision Particles have some K.E after collision. The figure shows the position time (x of --Ans: Sol: 0.8 Ns Impulse = change in momentum = mv2 mv1 = 0.4 ( 1) 0.4 1 = 0.8 Ns t) graph
4.
Ans:
2 m M
9.
Sol:
Mass lost = ( m) 2 Energy released = ( m)c By conservation of momentum and energy 1M 2 v each has energy 2 2
Two long parallel wires are at a distance 2d apart. They carry ------Ans:
B X d d X
1M 2 v 2 2
5.
1 2
m c2
2 m M
The binding energy per nucleon for the ---------Ans: Sol: E2 > E1 In radioactive decay, the parent nucleus decays to a more stable daughter nuclei. E2 > E1
Sol:
6.
Statement 1 When ultraviolet light is incident on a photocell, its stopping potential ----Ans: Statement 1 is true, Statement-2 is false.
Hence graph (2) is correct. 10. A ball is made of a material of density ---
where ---
Ans:
oil
Ans:
5, 1, 2
water
Sol: Sol: Since water is greater than oil, oil shoule be above water. > oil it should sink in oil and float in water. Hence Answer 3.
15. If a source of power 4 kW produces 10 / second, the ---Ans: X - rays Energy of a photon =
4000 1020 1 1.6 10
19
photons
Sol:
4000 1020
q 2
2 0r 2
eV
Sol:
5 nm (X- rays)
16. A radioactive nucleus (initial mass number A and atomic number Z) emits -----Ans:
A Z 4 Z 8
ZX A Z 8
Taking symmetrical elements of charge as shown the sin components cancel out. The cos components add upto / 2 K dq 2 cos 0 r2
/2
Sol:
YA
12
12
(Z
8)
= 2
0
K.
q cos rd r r2
17. Let there be a spherically symmetric charge distribution with charge ----Ans:
0r
= 2. =
1 4
0
/2
r2 0
2
co d
q 2
2 0r
j
Sol:
5 3
r R
12. A diatomic ideal gas is used in a Carnot engine as the working substance ---dx
Ans: Sol:
0.75 In the adiabatic part of the cycle 1 1 T1V1 = T2 V2 1 = T2 (32 V1) T1 1 7/5 1 2/5 = (32) = (32) = (32) T2 =4 T1 = 4 T2 T1 T2 3 = = 0.75 T1 4
x r
5 4
x R
4 x dx
13. The respective number of significant figures for the numbers ------
=4
5 4
x 2 x dx R
=4
5 x3 4 3
5 r3 4 3
x4 4R
=4
r4 4R 5 r3 4 3 r4 4R
Sol:
Q = R0 e
Q12 2C
t/RC
4
0
Q02 1 . 2C 2
0r
5 3
r R
Q1 =
Q0 2 1 2
Q0 2
Q0 .e t1 /
18. In a series LCR circuit R = 200 and the voltage and the frequency of the main supply -----Ans: Sol: 242 W Since the lag by removing the capacitance is equal to the lead by removing the inductor XC = XL. The circuit is in resonance condition. Power dissipated is = 242 W 19. In the circuit shown below, the key K is closed at t = 0. -------Ans:
V R1 R 2 V at t = 0 and at t = R2 R1R 2
e t1 /
e t1 /
ln 2
t1
1 log2 e 2 Q0 4 Q0 e
t1
t2 /
---(1)
1 4 e
t2 /
V2 R
220 2 200
2 log2 e
(i ) (ii) t1 t2
t2
1 4
---(2)
Sol:
At the instant of switching on there is no current through L. Therefore current at V t = 0 is R2 At t = , VL = 0 R1R2 Reff = R1 R2
V R1 R2 R1R2
Sol:
E 3R 2
=
2
2E 3R
B v 3 R
Aliter R + 1R = Blv ---- (i) R + 2R = Blv ---- (ii) (i) (ii) 1R 2R = 0 = 1+ 2=22 (ii) 3 2 R = Blv B v 2 = 3 R
1 1
2 2 2
2 2 2
x 2 K 2t 2 1 1 K 2t 2
+ constant
2
B v 2 B v ; = 3R 3 R
23. The equation of a wave on a string of linear mass density 0.04 Ans: Sol: 6.25 N y = 0.02 sin
(ac)X = (ac)Y =
2 t 0.04
2 x 0.50
ac
Compare with y = A sin ( t kx) 2 2 and k = 0.04 0.50 0.5 1 v= = 12.5 m s k 0.04 But v =
Ans:
T
2
T=v 0.04
mv0gt2 cos k 2
L
x
T = (12.5) = 6.25 N
Sol:
r p
k direction
24. Two fixed frictionless inclined planes making an angle ------Ans: Sol: 4.9 m s
2
y
r
tv0 sin
1 2 gt j 2
gt j 2
j gt)
gt j
Acceleration of A along the plane, . a = g sin = g sin60 Component of acceleration of A in the vertical direction, 2 av = a sin = g sin 60 2 (av)A = g sin 60 2 Similarly (av)B = g sin 30 (av)AB = (av)A (av)B 2 2 = g [sin 60 sin 30 ] 3 1 = 9.8 4 4 = 4.9 m s
2
r p
= v 0t cos t v 0 sin i
mv0 cos m v 0 sin i
gt j 2
gt j
gt k tmv0 cos
v0 sin
gt k 2
mv0gt2 cos k
mv0gt2 k 2
25. For a particle in uniform circular motion, the acceleration -----V2 cos i R V2 sin j R
Ans: Sol:
mv0gt2 cos k 2
Y V P(R, ) R X
27. Two identical charged spheres are suspended by strings of Ans: Sol: 2
15 15
V2 ac = R
q2 4
2 0d
l sin 15 =
q2 mg 4
2 0d
l cos 15 = mg tan 15 =
= ---- (i)
0
b 6 .x 2a
mg d2 4
x=
0.8 g1 1.6
g 2
2a b
=0
1/ 6
at equilibrium
U(x) =
Uat equilibrium =
a 2a b
12 / 6
b 2a b
6/6
q2 mg' d2 4
------(ii) =
ab2 4a2
D=0
q2 mgd2 4
0
b2 2a
b2 4a
b2 4a b2 4a
K=2 30. Two conductors have the same resistance at 0 C but their temperature Ans:
At t = 2 s, v = 12 m s ac =
In series R0 = R1 + R2 Rt = R1 + R2 = R1 + R1 1t + R2 + R2 2t = (R1 + R2) + t[R1 1 + R2 2] ------ (i) But Rt = R0 + R0 t = (R1 + R2) + (R1 + R2) t ----- (ii) From (i) & (ii) R1 1 R2 2 = R1 R2 =
1 2
ac
at
7.2
12
R1
R2
14 m s
29. The potential energy function for the force between two atoms ----b2 4a
a
12
In parallel R R0 = 2 R1 Rt = R 1 =
R1 2
1t 1t
1t R 1 1t
2t 2t
1
2t 2t
Ans:
b2 4a
b
But Rt =
R 1 2
Sol:
U(x) = F=
x x6 dU x = [ 12 ax dx
13 7
+ 6bx ] = =
t=
21
1t 2t
1t
2t 1t 1 2t 2t
1 2t 2 2 1
1 2t 2t 2
2 2
1t
2 1 1
t
1 2t 2
6 b x 7 1= . 12 a x 13
; At t = 0,
35. If 10 dm of water is introduced into a 1.0 dm flask at 300 K, .................. CHEMISTRY Ans : 1.27 10
3
PART B
mol
31. In aqueous solution the ionization constants ......... Ans : The concentration of H and HCO 3 are approximately equal. Sol : H2CO3
HCO 3
+ H + HCO 3 +
Sol : PV = nRT n=
3170 (Pa) 8.314 (J K
1
3
10 3 (m3 ) 300(K )
mol 1)
= 1.27 10
mol
36. From amongst the following alcohols the one that would react fastest with.............. Ans : 2Methylpropan2ol
CH3
+ 2 H + CO3 Since the k2 value is very low compared to + that of k1, the H obtainable from HCO 3 is
CH3 C
OH
2-Methylpropan-2-ol (3alcohol)
g
+
with
13
37. If sodium sulphate is considered to be completely dissociated into cations and anions in aqueous solution, the change ................ Ans : 0.0558 K Sol : Tf = i kf m = 3 1.86 0.01 = 0.0558 K are given
2+
> Al
3+
38. Three reactions involving H2PO4 Sol : For isoelectronic species the radii decreases with increase in atomic number. 34. In the chemical reactions, ................ Ans : benzene diazonium chloride and fluorobenzene below:.................. Ans : (ii) only Sol :
39. The main product of the following reaction is ..... Ans : H5C6
C H C CH(CH3)2 H
NH2
N2Cl
NaNO2 HCl, 278K
Sol :
(A)
F
HBF4 heat
Sol :
Sol : E
z2 n2
9 EHe 4 9 19.6 = 4
CH
CH3
H H2 O
ELi2
10 18 J atom 1
17
= 4.41 10
J atom
(2 carbocation)
1, 2 migration of hy dride ion
43. On mixing, heptane and octane form an ideal solution. At 373 K, the vapour pressures ........... Ans : 72.0 kPa
CH3
H
Sol : nA =
40. The energy required to break one mole of Cl Cl 1 bonds in Cl2 is 242 kJ mol ........... Ans : 494 nm
242 6.02 103 1023
44. Which one of the following has an optical isomer? ......... J molecule
1
Sol : E =
3+
E=
c
3+
is chiral.
6.626
10 34 (Js) 103 10
6
108 (ms 1)
45. Consider the following bromides:............ Ans : B > C > A Sol : Order of SN1 reactivity is related to the relative stability of carbocation formed by ionisation (B) gives allylic secondary carbocation, (C) gives secondary carbocation and (A) gives primary carbocation on ionisation. 46. One mole of a symmetrical alkene on ozonolysis gives two moles of an aldehyde ................
242 6.02
23
(J molecule 1)
= 0.494 10 = 494 nm
41. 29.5 mg of an organic compound containing nitrogen was digested according to Kjeldahls method ................ Ans : 23.7 Sol : % of N = =
14
14
( V1 V2 ) N1 100 w 1000
CH
CH CH 3
ozonoly sis
2 butene
42. Ionisation energy of He+ is 19.6 10 The energy ............... Ans : 4.41 10
17
J atom .
2CH 3
CHO
Ethanal
Molecular mass : 44 u
J atom
47. Consider the reaction: + Cl2(aq) + H2S(aq) S(s) + 2H (aq) + 2Cl (aq) ................... Ans : A only Sol : Slow step is the rate determining step. According to A; rate = K[Cl2][H2S] K[Cl 2 ][H2 S] According to B; rate = [H ] 48. The Gibbs energy for the decomposition of Al 2O3 at 500 C is as follows:.................. Ans : 2.5 V Sol : G = nFE 3 966 10 3 (J) 2 E = 2.5 V 49. The correct order of increasing basicity of the given conjugate bases ..................
52. For a particular reversible reaction at temperature T, H and S were found to be ........... Ans : T > Te Sol : At equilibrium, H = Te S G= HT S = S (Te T) G will be negative when T > Te. 53. Percentages of free space in cubic close packed structure and in body centered .............. Ans : 26% and 32% Sol : For ccp and bcc percentages of free space are 26% and 32% respectively.
96500
54. The polymer containing strong intermolecular forces e.g. hydrogen bonding ............... Ans : nylon6, 6 Sol : Nylon6,6 is a fibre having strong intermolecular forces due to hydrogen bonding. 55. At 25 C, the solubility product of Mg(OH)2 is 11 2+ 1.0 10 . At which pH, will Mg ions start precipitating ................ Ans : 10
Ans : RCO O
HC
N H2
Sol : Acidic strength of the corresponding conjugate acid is CH3 COOH > CH CH > NH3 > CH4 Hence the basicity of the conjugate base must be the reverse. 50. The edge length of a face centered cubic cell of an anionic substance is 508 pm............ Ans : 144 pm Sol : 2(r(+) + r()) = a 508 r(+) + r() = = 254 2 r() = 254 110 = 144 pm 51. Out of the following, the alkene that exhibits optical isomerism is ............. Ans : 3methyl1pentene
Sol :
10 11 10
3
= 10
/M
sign for the four successive elements ............... Ans : Mn > Cr > Fe > Co Sol : Mn > Cr > Fe > Co Standard reduction potential values of 2+ Mn /Mn = 1.18 V 2+ Cr /Cr = 0.91 V 2+ Fe /Fe = 0.44 V 2+ Co /Co = 0.28 V
H CH3
Sol :
CH2
C CH3
CH
CH2
57. Biuret test is not given by ................ Ans : carbohydrates Sol : Biuret test is carbohydrates. not answered by
m Sm n n
58. The time for half life period of a certain reaction A Products is 1 hour. When the initial concentration of the reactant A,.................. Ans : 0.25 h Sol : For a zero order reaction, t 1 2.0 mol L 0.5 mol L
1 1 1
reflexive . mq m Sp
n q
pn
pn = mq
p Sm q n
S is symmetric. Again,
m Sp , pS r n q q s
mq = pn and ps = qr ms = nr
mSr n s
a
2
S is transitive S is an equivalence relation but is not an equivalence relation. 62. The number of complex numbers z such that |z 1| = |z + 1| = .. Ans: Sol: 1 z is a point equidistant from 3 given points. z is the centre of the circle passing through 1, 1, i.
59. A solution containing 2.675 g of CoCl3.6NH3 1 (molar mass = 267.5 g mol ) is passed through a cation exchanger. .................. Ans : [Co(NH3)6]Cl3 Sol : No. of moles of AgCl =
4.78 143.5
0.03 63. If and B are the roots of the equation 2 x x + 1 = 0, Ans: Sol: 1
, 2009 2 2009
i.e., 0.01 moles of the compound gives 0.03 moles of AgCl No. of moles of Cl per unit = 3 Formula of the complex is [Co(NH3)6]Cl3 60. The standard enthalpy of formation of NH3 is 1 46.0 kJ mol . If the enthalpy of formation of H2 1 from its atoms is 436 kJ mol and that of N2 is 1 712 kJ mol . .......... Ans : +352 kJ mol
1
=( = = 2009 =( = = =
2
)
2
2007
2 2009
4018 4017
= (
+ ) = 1.
Sol : N2 + 3H2 2NH3 2 46 = +712 + 3 +436 (6 N H) 1 N H = +352 kJ mol PART C -MATHEMATICS 61. Consider the following relations : R = {(x, y)|x, y are real numbers and .. Ans: S is an equivalence relation but R is not an equivalence relation. x Ry = x = wy x Rx R is reflexive xRy x = wy and y Rx y = wx 1 where w = , this is possible only w
64. Consider the system of linear equations : x1 + 2x2 + x3 = 3 2x1 + 3x2 + x3 = 3 Ans: No solution.
Sol:
1 2 1 A= 2 3 1 3 5 2 3 2 1 Ax1 = 3 3 1 1 5 2
Sol:
Ax1
0.
C2
C2
3 36 108.
R be a differentiable function
n 300 n 1 2 2 = n[150 n + 1] 2 3150 = 151n n 2 n 151n + 3150 = 0 252 50 or n= 2 2 n = 25 Total time = 25 + 9 = 34 = 34 mts.
3150 =
g(x) = [f(2f(x) + 2)] g (x) = 2f(2f(x) + 2) 2f (x) g (0) = 2f(2f(0) + 2) 2f(0) = 4 1 f(2 2) = 4 f(0) = 4.
70. The equation of the tangent to the curve 4 y = x + 2 , x Ans: Sol: y=3 y=x+
4 x2
67. Let f : R
Given Lim
x
71. The area bounded by the curves y = cos x and y = sin x Ans: Sol:
4 2 2
68. Let p(x) be a function defined on R such that p(x) = p(1 x), . Ans: Sol: 21 f(x) = p(x) + p(1 x) f(x) = p(x) p(1 x) = 0(given) f(x) = 0 f(x) = k constant when x = 0, p(0) + p(1) k = 42 p(x) + p(1 x) = 42
1 1
Required area =
4 5 4
cos x sin x dx
0 4
sin x cos x dx
p x dx
0 1 0
p1 x
42
+
5 2
cos x sin x dx
5 4
2
0
p x dx
42
=
2 1 2 2
2 1
= 4 2 2.
p x dx
0
21.
72. Solution of the differential equation cos x dy = y (sinx y) dx, Ans: secx = (tanx +c)y Consider dy = y(sinx y)dx dy y sin x y 2 consider dx dy y tan x y 2 sec x dx
69. A person is to count 4500 currency notes. .. Ans: Sol: 34 minutes Sol: In the first 9 minutes the person counts 9 150 = 1350 notes Total left notes = 4500 1350 = 3150 He counts in A.P with d = ( 2) and a = 150
c=
z=
1 y
dz dx
1 dy 2 dx y
= =
20
23 17
16 1
secx
sec 2 x
tan x C
in
three-dimensional
space
sec x y
tan x C
Ans: Sol:
i j 2k
(a b) + c = 0 a (a b) + a c = 0 (a . b)a (a . a)b + a c = 0 3j 3k 2b 2i j k 0 2b 2i 2j 4k
=1
78. Let S be a non-empty subsets of R. .. Ans: Sol: Every rational number x S satisfies x 0
i j 2k
2k , . i j
Ans: Sol:
( 3, 2)
a.c
There is a rational number x S such that x > 0 means that There exist some positive rational number in S. Then its negation becomes All rational numbers in S are negative. That is Every rational number x S satisfies x 0.
4 and . .. 5
Ans: 75. If two tangents drawn from a point P to the 2 parabola y = 4x are at right angles, . Ans: Sol: x= 1 Locus of p is directrix of y = 4x x= 1
x 5 y b 1 passes ..
2
Sol:
) tan tan
5 12 = 3 5 1 4 12 56 . = 33
80. The circle x + y = 4x + 8y + 5
2 2
3 4
x 5
y b
= 20 Equation is 4x x y 1 c 3
10 m 5
But cos =
= |10 m| < 25 25 < 10 + m < 25 35 < m < 15. 81. For two data sets, each of size 5 Ans:
11 2
2
2 3
3 non-singular matrices
1 1 0
Sol: Consider
2 1 2 2
Sol:
n1
n2
n1 x
n1d12 n2d22 , n2
0 0 1 . 1 0 0
x x1 x 2 2 2 4 3 2
d12 d22 2
R be defined by
d1 = (2 d2 = (4
2
2
3) = 1 3) = 1 4 5 1 1 2
2
11 . 2
1=k+2 k = 1. 86. Four numbers are chosen at random Ans: Statement 1 is true, Statement 2 is false.
Sol: If four chosen numbers form an AP, the common differences can be 1, 2, 3, 4, 5 or 6. (e.g. 1, 7, 13, 19 is an AP with common difference 6) Statement 2 is not true.
10
83. For a regular polygon, let r and R be the.. 87. Let S1 Ans: Sol: There is a regular polygon with
r R 2 3
j j 1 10 C j , S 2
10
j 10 C j ..
j 1
j 1
Ans: Let n sided regular polygon is inscribed in a circle. From the figure it is clear that
Sol:
S1 =
j 1
10
jj 1
Cj
S2 =
j 1
j
10
10
Cj
R r
2 n
S3 =
j 1
j2
10
Cj
10
S1
S3 =
j 1 10
j2
j j2
10
Cj
=
j 1
j 10 C j
1 1 3 , and 2 2 2
= S2 S1+ S2 = S3.
j) !
10
9 10
10 8 j 1
8! j 2 ! 10
Since
j!
90. Let A be a 2
Cj
2
jj 1
j 1
Cj
90
Ans: Sol:
= 90
2.
. 88. Statement 1 : The point A (3, 1, 6) is the mirror image. Ans: Statement 1 is true, Statement 2 is true; Statement 2 is a correct explanation for statement 1 A (3, 1, 6) B = (1, 3, 4) Midpoint of AB is (2, 2, 5) 2 2+5=5 Statement 2 is true D. Rs of AB are [2, 2, 2] or [1, 1, 1] which represent the D.Rs of normal to the plane x y + z = 5 Statement 1 is true We used statement 2 to prove statement 1. R be a continuous function
a b c d
Statement 2 is NOT
|A| = 1 true. a b a b
c d
c d
1 0 0 1
Sol:
a bc a d b a d c bc d2 a2 bc d2 bc 1 (1) 1
a db a dc
0 (2) 0
Statement 1 is true, Statement 2 is true; Statement 2 is a correct explanation for statement 1 f(x) = f(x) =
e f(x) = 0 2 x e = x e
2x
Sol:
1 e
x
2e x 1
x
f x
ex
0
2e
x
2e
x 2
1 log2 2 Checking the sign of f(x) as x crosses 1 log 2, we note that f(x) is maximum at 2 1 x = log 2 . 2 1 Maximum value of f(x) = 1 2 2 2 1 = 2 2 Statement 2 is true
e =2
x=
1 2 1.414 = 0.3535 4 4 2 2 Since f(x) is continuous in R, f(x) has to assume all values between 0 and 0.3535