UGH U N I V E R S I T Y

STUDIED

Science and technology Series, No. !

TABLES OF THE P R O P E R T I E S OF
AQUA-AMMONIA SOLUTIONS
Part 1 of The Thermodynamics of Absorption Refrigeration

BUIIOESS H. JENNINGS, _ . _ . , M.S.

Associate Professor of Mechanical Engineering
and
FRANCIS 1\ SHANNON, B.S. in M.S., M.S.
Formerly 0. Kemble Baldwin Hcscanli Fellow

'

h \*1

fe:
.....

\ws>,*t_v*

Reprinted from Refrigerating Engineering

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BETHLEHEM, PENNSYLVANIA
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231677

The Thermodynamics
Of Absorption Refrigeration
Part 1. Tablet of the Propertie*

of Aqua-Ammonia

Solutiont

By Burgess H. Jennings1 and

Francis P. Shannon2
HESE tables of aqua-ammonia make available comTplete
and accessible tabulations, in the English language and in customary engineering units, of the properties of aqua-ammonia solutions. The richest sources of
basic data in this field are found in German literature,
although some experimental work has also been done in
the United States, England and France. The problem
faced by the authors was one of first critically evaluating
the various sources of data, then of correlating and preparing the best of these data for interpolation (and extrapolation), and finally of preparing the tables.
No
basic experimental work was done by the authors. The
previously published work of A. A. Berestneft* (1) and
A. B. Stickney (2) in this country, who prepared charts
and tabulations, should be mentioned, as they were the
first to make use of the recent German data in this field.
The form selected for the tables gives as arguments;
pressure in pounds per square inch absolute as ordinate
and weight concentration of the ammonia in the liquid as
abscissa. For each value of pressure and of weight concentration, there are tabulated:
t temperature in *F., at which a solution of the concentration given is saturated, i.e., boils under the
pressure in question.
lit enthalpy (total-heat) Btu. per lb., of the saturated
liquid aqua.
It. enthalpy (total-heat) Btu. per lb., of saturated vapor in equilibrium with above mentioned liquid.
x. weight
percentage
ammonia concentration
of
saturated vapor in equilibrium with the above mentioned liquid. Thus, if the liquid were heated, vapor
of this concentration (x.) would start to rise from
it and each lb. of vapor generated would have an
enthalpy of magnitude h..
The enthalpy (total-heat) function, of such wide utility
with simple fluids, can also be applied for fluid mixtures
as in this case of ammonia and water. Thermodynamically,
enthalpy is what is known as a point function, i.e., the
magnitude of the value for a given condition is independent of the path by which the fluid is brought to that
condition. In the case of liquid, ammonia-water mixtures,
the heat of solution has been considered in computing
the enthalpy values. In the case of the vapor mixtures
the heat of mixing is considered zero. This is very closely
true with vapors free from liquid. The datum for enthalpy computations was taken as 32" F. Thus enthalpy
readings for anhydrous ammonia from the Bureau of
* Presented at the JJrd Annual Meeting- of The American Society of
Refrigerating Engineer*. New York. N. V.. Jan. 2e>. 193S. Copyright
privileges held by RirticrisTiNG KNCINBIIINC.
1
Associate Prof, of Mechanical Engineering. Lehigh University.
* Refrigerating Engineer. I'ottsville Shops, Philadelphia sad Reading
Coal and Iron Company, formerly C. Kenible Baldwin Research Fellow at Lehigh University.
Copyright. 193$, The American Society of Refrigerating Engineers.

Standards Ammonia Tables (16), which use a datum of

40" F., must have 77.9 subtracted from them to permit,
their use with these aqua tables. However, as the aqua
tables are rather complete in themselves the use of the
Bureau of Standard Tables in absorption refrigeration
should seldom be necessary. In deciding the question of a
datum point temperature, both steam-water with its
32" F. datum and ammonia with the customary 40 F.
datum were considered for setting the temperature, as was
also the possibility of using a 40* F. datum for the
ammonia phase and a separate 32" F. datum for the
water-steam phase. The single 32 F. datum appeared
preferable and was adopted. Thus the enthalpy of pure
water at 32 F. and of anhydrous ammonia at 32 F.
are each taken as essentially zero for these tables.
Enthalpy values for sub-cooled liquid can also be read
from these tables. Sub-cooled liquid is liquid at a temperature lower than that at which it is saturated under its
super-imposed pressure. Thus liquid at 181.4* F. with a
concentration of 32 per cent has an h, of 63.8 Btu. per lb. at
its saturation pressure of 100 lb. per sq. in. or in subcooled state at any higher pressure such as 150 lb. per
sq. in. Sub-cooled liquid frequently occurs in practice.
This constancy of values for sub-cooled liquids disregards
the slight magnitude of the so-called feed-pump work.
A separate table (Table 2) for specific volume values of
saturated or sub-cooled aqua is also presented. A chart
showing the freezing point temperatures of ammoniawater solutions appears as Fig. 1. For convenience in
changing from molal to weight concentration, or vice
versa, Fig. 2 has been prepared. The molecular weight of
N'H. being 17 and of H.0 18, the data of Fig. 2 give for
example at .36 molal, .36 .0131 .3469 wt. and at
.32 wt., .32 -f .0126 = .3326 molal.
The P, T, X relations of the ammonia-water system,
under conditions prevalent in the absorption cycle, have
been studied to some extent by several investigators (3)
(4). However, the recent work of WUcherer (5) offers
the most extensive and precise set of data on these relations. The investigations of Zinner (6), corroborated by
those of Baud and Gay (7), provide quite complete data
for computing the enthalpy of the liquid phase. Hitherto this function had been derived entirely from the very
limited data of H. Mollier ( 8 ) . Because of the comprehensive range and the thermodynamic consistency of the
data by WUcherer and Zinner ( 9 ) , these sources were
used exclusively in these tabulations for the P, T, X
relations of the liquid and vapor phases and for the enthalpies of the liquid phase. The enthalpy of the vapor
phase was calculated on the accepted assumptions that
the vapor phase follows Dalton's law of partial pressures, and that there is no heat of gaseou? solution (10).
The properties of the pure components were taken from
the Bureau of Standards Ammonia Tables (16) and
Keenan's Steam Tables (15).

Reprinted from the May, 1938, itsue of Refrigerating Engineering

temperature for a given liquid concentration, the equilibrium vapor

concentration was calculated. The

100
final constant pressure lines in English units were then readily obtained
by standard multiple difference interpolation formulae.
+ 50
The liquid phase enthalpies were

derived from the data of Zinner (6)

by exactly the same method used for
0
the P, T, X relations, namely, suc\
cessive interpolation with multiple
\
difference formulae.
\
-50
The enthalpy of the vapor phase
\
SOLU T I O N
was calculated in the following manI CE*. OLUT ION
ner. The partial pressure of each
-I0O
component
is considered proportional
\
"" ~ J_>
v _ _ - -, - - ^ S O L I D N H s to the molal concentration of that
4 SOL.
< H HsO
isoc
~'
/* 8. SOL.
component in the vapor. The enthalpy, using the weight concentraNHyH,C
2NH H 0 +SOLID NHj
1 +
tions, of these components, is then
- -1
found from the appropriate anhydrous ammonia or steam tables as
i0
A0
J3
50
70
60
80
9
J0(
z0
(
)
superheated vapor existing at the
WEIGHT * NH..
calculated partial pressures and
FIG. 1. AQUA AMMONIA FREEZING POINT CURVE.
equilibrium temperatures. The enthalpy of the aqua ammonia vapor
is then considered the sum of that of the two comThe values for the specific volume of the liquid phase
ponents. These calculations were made for all key isobars
were derived from several sources (7) (11) (12) (13)
and subdivided into final pressure intervals by interby a method to be described later. The freezing point
polation.
data for aqua ammonia were taken from the Critical
Tables (14).
To calculate values of specific volume of the liquid
The P, T, X relations of the liquid phase were taken phase under conditions found in the absorption cycle, it
uncritically from the data by WUcherer and are presented
was necessary to extrapolate considerably from known
essentially in the form used by him, namely with P and X
data. Use was made of a basic thermodynamic relation
as the arguments. This was done to minimize the labor developed by V. Fischer (9), which states that the molal
and possible error of interpolation. Constant pressure
mixture-contraction (the molal volume of the components
lines were selected at close intervals
from WUcherer data and interpolated
to smaller sub-intervals of concentration by standard multiple difference
interpolation formulae. These formu014
lae were carried to the point that
further computation had no effect on
the second decimal place. The "second
\
\
/
012
differences" of the interpolation meth*
ods were usually adequate for this
/
\
degree of precision. The resulting isot
bars, expressed in metric atmospheres,
y OIO
/
\
z
were then sub-divided into pressure
_
/
\
a:
intervals in lb. per sq. in. absolute by
u.
u.
similar interpolation methods. From
/
\
a.008
the resulting data, many arbitrarily
z
o
\
1
selected values were checked against
i
the original data by bivalent interpo_
\
Z.006
lation. The vapor concentrations in
Id
U
z
equilibrium with the liquid phase for
o
the above key isobars had to be calu
.004
culated by another method, because
the rapid curvature of their path is
/
\
too severe for usual interpolation
/
-A
002
methods. The method used was to
deterriiine the deviation between the
vapor concentration, as calculated by
WEIGHT CONCEN r R A T I O N
Raoult's Law, and the vapor concen1
X
1

1
5
J
>
.000
*sV
1
3
c
tration of WUcherer (5). This devia
T
*
*.
MOLAL
CONCENTRATION
tion was then plotted to high precision
re. 2. CONCENTRATION CONVERSION CURVE. MOLAL (.r) WEIGHT (_)
against temperatures and a smooth
curve drawn through the values.
From this curve, by reversing the
calculation and using the liquid phase
\ 18-W
\ w + \7l
200

r i

-J

,_(j_) [__.) .

TABLE IPROPERTIES OF AQUA-AMMONIA SOLUTIONS

AMMONIA CONCENTRATION, WEIGHT PER CENT

10
t
101.8
lit
69.7
h 1105.0
x,
0.00

89.3
49.7
979.5
J0.20

78.0
32.8
876.2
52.20

68.0
15.6
793.0
66.70

58.6
0.9
727.7
76.30

t
bf
h.

112.7
74.6
989.8
29.70

100.8
56.1
886.3
51.20

90.4
38.8

02.*

127.6
89.8
997.5
-'9.15

28

30

32

ft*

36

38

40

64.8S

72.6
6.6
687.2
81.50

53.7
28.6
631.5
90.50

35.8
61.9
592.5
95.50

29.1
74.1
589.1
96.23

115 6
71.4
894.8
50.30

105.1
53.5
811.8
63.76

95.9
36.4
746.2
72.00

87.5
21.8
696.0
79.90

68.8
13.2
638.3
89.80

50.6
46.7
598.5
95.00

43.7
59.0
594.5
96.00

139.2
101.2
1003.8
28.50

127.1
82.7
902.2
48.93

116.6
65.2
819.8
62.35

107.2
48.7
754.8
71.23

98.7
33.0
704.2
78.72

79.9
1.9
644.7
89.05

61.4
35.6
604.1
94.48

54.4
47.9
599.6
95.75

148.7
110.6
1009.3
27.83

136.7
92.3
908.9
47.56

126.1
74.9
827.2
60.91

116.7
58.4
762.3
70.46

108.1
42.7
712.0
77.54

89.0
7.5
650.8
88. J 3

70.4
26.3
609.4
93.97

63.4
38.8
604.3
95.50

t
170.1
|M 137.9
h. 1131.7
X.
0.00
176.8
t
IM 144.7
1136.4
m
Xs
0.00
1*2.9
t
ht
150.8
h. 1138.9

156.6
118.6
1014.2
26.94

144.7
100.3
915.0
46.47

134.2
82.9
834.1
60.21

124.6
66.4
769.5
69.57

116.0
50.7
719.3
76.77

96.7
15.3
656.6
87.83

77.9
18.6
614.3
93.60

70.8
31.1
608.6
95.25

64.1
43.3
603.5
96.50

57.7
55.4
596.9
97.50

51.3
67.3
586.7
98.15

45.0
79.2
571.2
98.63

38.9
89.7
566.5
99.07

27.1
32.9
99.6 -108.8
338.5
562.4
99.63
99.39

21.3
-117.2
554.5
99.76

15.7
-124.9
550.1
99.84

163.3
124.4
1018.5
26.18

151.4
107.1
920.5
45.50

140.8
89.7
840.3
59.57

131.3
73.1
776.1
68.88

122.5
57.3
72*. 0
76.48

102.9
21.7
661.9
87.36

84.1
12.3
618.8
93.33

77.0
24.8
612.6
95.00

70.2
37.1
607.1
96.25

63.7
49.1
600.2
97.18

57.4
61.0
590.1
97.92

51.1
72.8
574.8
98.42

45.0
~569.9
98.97

38.9
32.9
93.4 -102.7
565.6
561.4
99.31
99.5*

27.0
-111.4
557.1
99.72

0.00

169.3
131.4
1022.6
25.52

146.6
95.6
846.1
58.63

137.0
79.0
782.3
68.10

128.2
63.2
732.2
75.37

108.5
27.6
666.8
86.80

89.6
6.4
622.9
93.05

82.5
19.0
616.2
94.80

75.7
31.3
610.3
96.00

69.1
43.4
603.3
96.96

62.6
55.4
593.1
97.75

56.4
67.3
578.1
98.33

50.1
78.0
573.1
98.87

44.0
88.0
568.5
99.23

38.0
97.4
5*4.2
99.49

188.3
156.2
1141.0
0.00

174.6
136.7
1026.2
24.93

157.3
113.0
925.6
44.70
162.5
118.3
930.3
43.98

151.8
100.8
851.5
57.78

142.1
84.2
788.0
67.42

133.2
68.4
738.0
74.72

113.4
32.9
671.3
86.42

94.6
1.3
626.7
92.77

87.5
13.9
619.6
94.55

80.6
26.2
613.3
95.82

73.9
38.4
606.0
96.80

67.4
50.4
595.9
97.62

61.0
62.5
581.2
98.25

54.8
73.2
576.1
98.77

48.6
3.2
571.4
99.15

10

193.2
161.1
1143.0
0.00

179.5
141.6
1029.6
24.48

167.3
123.2
934.7
43.37

156.5
105.7
856.5
57.17

146.8
89.0
793.3
66.88

137.9
73.2
743.3
74.18

118.0
37.5
675.5
85.98

99.1
3.3
630.2
92.49

91.9
9.4
622.3
94.31

85.0
21.9
615.5
95.61

78.3
34.0
608.5
96*1

71.7
46.0
598.4
97.50

65.3
58.1
583.9
98.15

59.(1
68.8
578.7
98.66

126.1
94.0
1115.6

o.oo

141.5
109.1
1122.0
0.00
153.0
120.8
1126.8

7
8

o.oo

42

44.9
40.3
35.7
40.2
5.8
21.4
11.2
16.3
31.0
109.5
120.6
131.4
-141.8
-151.2
- 1 6 0 . 0 168.1 175.5 1 8 2 . 2 1 8 8 . 6
535.6
539.0
341.6
581.2
576.5
567.6
544.2
551.0
549.4
546.8
100.00
99.99
99.98
98.00
99.20
99.40
99.95
99.50
99.70
99.80
26.8
21.8
16.8
22.8
16.8
10.8
4.1
0.8
11.6
6.3
86.0
97.6
109.0
-120.2
130.2
139.5 148.2 156.1 1 6 3 . 2 169.8
538.7
541.5
343.7
585.9
580.6
3461
571.0
552.3
551.5
348.7
99.97
99.93
99.96
97.70
99.90
98.83
99.15
99.35
99.57
99.71
14.2
9.1
3.9
30.*
37.1
24.6
18.6
7.1
1.3
12.8
82.8
71.0
94.5
-106.1
-116.4
- 1 2 6 . 0 134.9 143.1 1 5 0 . 4 157.3
541.7
543.7
545.7
584.6
590.6
574.3
553.6
557.6
547.9
550.3
99.94
99.93
99.88
98.46
99.44
97.40
98.90
99.18
99.84
99.63
4.6
0.7
47.8
61
41.5
35.2
29.1
23.1
11.6
17.3
60.0
71.9
83.7
95.5
-105.9
- 1 1 5 . 6 124.6 132.8 1 4 0 . 2 147.2
543.6
545.9
548:9
595.2
589.1
551.8
578.9
562.6
558.4
554.8
99.89
99.92
99.84
97.10
99.77
98.10
98.65
99.01
99.32
99.55
3.6
8.9
56.7
50.3
14.3
43.9
31.6
19.9
37.6
25.7
51.0
63.0
74.9
97.2
86.8
- 1 0 7 . 0 116.1 124.3 131.8 138.8
545.4
548.0
551.8
599.6
593.2
583.1
562.7
567.2
$55.3
358.9
99.90
99.86
99.80
96.80
97.72
98.40
V8.85
99.20
99.70
99.47

81.1
22.3
737.2
73.90

44

46

48

50

55

60

65

70

59.0
64.0
74.5
83.4
95.1
54.2
90.5
49.5
204.4 2 0 8 . 6
216.2 2 1 9 . 8
199.7
-220.6
-217.6
194.4
525.4
522.0
528.8
516.5
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I MILE IPROPERTIES OF AQl \-\MMONIA SOLUTIONS (Continued page 2 )

AMMONIA ( H M i M l t V l l U N .
10

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215.6
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148.6
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127.3
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100.4
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270.2
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188

TABLE IPROPERTIES OF A QUA-AM MOM A SOLUTIONS (Continued page 3)

AMMONIA CONCENTRATION, WEIGHT PER CENT
0

52

t
283.5
ht 252.5
hs 1174.3
0.00
x

270.9
234.0
1(86.6
17.97

259.3
216.2
1010.5
32.41

248.5
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238.4
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228.6
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841.7
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54

285.9
1
hf 255.0
hs 1175.0
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0.00

273.3
236.5
1088.1
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261.7
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947.3
44.84

240.8
184.7
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56

t
288.2
hi 257.4
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0.00

275.6
238.9
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264.0
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290.5
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277.9
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266.2
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231.0
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164.7
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150.0
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34

36

38

40

42

44

46

48

SO

55

60

33.8
13.3
341.9
100.00

27.2
21.5
542.5
100.00
28.9
19.6
543.0
100.00

189.3
83.1
679.9
91.19

15

24.3
15.1
541.3
100.00

276
24.2
542.8
100.00

196.9
95.8
693.9
89.22

10

24.5
160
541.$
100.00

28.1
26.8
543.1
100.00

204.7
108.9
709.5
86.87

188

24.9
20.7
541.8
100.00

28.7
29.3
543.5
100.00

212.8
122.3
727.2
83.94

125

99

25.8
26.1
542.4
100.00

29.2
31.1
543.8
99.99

234.2
157.9
789.0
74.35

120

98

29.8
34.3
344.2
99.99

257.9
195.8
873.7
59.34

130.0

97

**'#f
30.4
364
$44.4
9.*

267.2
211.9
919.6
51.16

96

35.4
23.4
542.1
100.00

26.1
31.2
543.0
100.00

277.5
228.6
972.7
41.23

ht

95

37.4
33.8
545.5
99.99

288.2
245.8
1033.7
29.88

94

2t.9
36.2
543.7
99.99

299.7
263.3
It 03.4
16.39

85

93
263
28.7
542.7
100.00

t
312.0
ht 218.9
hs 1182.4
XS
0.00

SO

93

~6S

70

75

*i.?

48.0

a.o

to.*
552.6
99.9*

92

SPPS-INF

79.8
9 99

98

99

188

123

I
s
i
5
%

TABLE IPROPERTIES OF AQUA-AMMONIA SOLUTIONS (Continued page 4)

AMMONIA

42

44

46

48

50

60

65

70

85

87

192.0
73.5
657.1
94.5*

163.6
33.4
625.5
97.43

156.9
25.2
619.4
97.88

150.4
17.7
613.6
98.25

144.0
11.1
607.9
98.56

157.8
5.3
602.2
98.82

124.1
6.5
591.4
99.31

112.8
13.5
582.4
99.62

103.9
13.9
375.7
99.7$

96.4
14.0
570.2
99.85

90.2
8.5
565.7
99.90

84.8
1.7
561.8
99.92

80.3
7.2
558.5
99.95

766
11.1
557.3
99.9*

202.2
87.7
669.0
93.30

194.7
76 5
639.2
94.44}

187.4
65.8
650.2
95.32

180.2
55.4
641.9
96.12

173.1
45.5
633.8
96.78

166.3
36.5
627.1
97.34

159.6
28.2
620.9
97.80

153.0
20.7
614.9
98.18

146.6
14.0
609.2
98.50

140.3
8.2
603.4
98.77

126.5
3.7
592.4
99.26

115.1
10.7
583.3
99.58

106.3
13.0
376.7
99.71

98.8
11.2
571.1
99.82

92.5
6.0
566.5
99.88

87.1
0.9
562.5
99.91

82.6
9.9
559.1
99.94

80.9
13.8
557.9
99.95

212.4
102.2
682.4
91.78

204.8
90.7
671.2
93.14

197.3
79.5
461.2
94.2*

190.0
68.8
632.1
95.19

182.8
58.5
643.6
96.02

175.8
48.6
635.4
9666

168.9
39.6
628.6
97.25

162.2
31.2
622.3
97.73

155.6
23.7
616.2
98.10

149.2
16.8
610.4
98.44

142.7
10.9
604.5
98.72

128.9
1.2
593.4
99.22

117.4
8.0
584.2
99.54

108.7
10.4
$77.6
99.67

101.2
8.6
572.0
99.79

94.8
5.4
567.2
99.86

89.4
3.5
563.1
99.89

84.8
12.4
559.6
99.93

222.9
117.2
697.6
89.99

215.1
105.2
684.6
91.61

199.9
82.5
663.1
94.14

192.3
71.7
653.9
95.08

185.3
61.4
645.3
95.91

178.3
51.5
637.0
96.54

171.4
42.5
630.1
97.14

164.4
34.2
623.7
97.65

158.0
26.5
617.5
98.04

151.5
19.6
611.6
98.38

145.1
13.5
605.6
98.67

131.1
1.4
594.3
99.16

119.7
5.4
585.0
99.50

111.0
7.7
578.3
99.64

91.6
5.9
563.7
99.88

225.5
120.2
699.4
89.80

217.6
108.2
686.5
91.44

202.3
85.5
664.9
93.94

195.0
74.7
6556
94.97

187.8
64.4
646.9
95.80

180.7
54.4
638.5
96.46

173.8
45.4
631.5
97.07

167.0
37.0
625.0
97.57

160.3
29.2
618.7
97.98

153.8
22.3
612.7
98.33

147.4
16.1
606.6
98.62

133.4
3.9
595.1
99.14

122.0
2.9
585.7
99.46

113.2
5.3
579.0
99.61

103.4
S.
572.7
99.77
105.6
3.5
373.3
99.75

97.0
0.9
567.8
99.84

233.6
132.6
714.1
17.74

207.4
93.6
673.3
92.98
209.9
96.6
675.1
92.83

99.2
1.6
56S.4
99.82

247.0
150.8
735.0
84.94

238.7
138.1
718.1
87.33

230.6
125.7
703.2
89.41

222.5
113.7
690.1
91.12

214.8
102.1
678.5
92.54

207.2
91.0
668.0
93.7*

199.7
80.2
658.5
94.75

192.5
69.8
649.7
95.5*

185.4
59.8
641.2
96.26

178.4
50.7
634.0
96.88

171.6
42.3
627.4
97.42

164.9
34.5
621.0
97.85

158.3
27.4
614.8
98.21

151.8
21.2
608.6
98.51

137.8
8.9
596.9
99.06

126.2
2.0
587.5
99.40

117.4
0.4
580.6
99.57

109.8
1.3
574.6
99.71

260.2
169.1
758.7
81.74

251.7
1560
759.1
84.55

243.3
143.3
721.9
86.98

235.1
131.0
706.8
89.10

227.2
119.0
693.5
90.81

219.4
107.5
681.6
92.25

211.8
96.3
671.0
93.4$

204.3
85.5
6*1.3
94.47

197.0
75.1
652.5
95.37

189.8
65.0
644.0
96.06

182.8
55.9
636.7
96.70

175.9
47.4
629.9
97.26

169.1
39.5
623.4
97.72

162.5
32.4
617.0
98.09

156.1
26.0
610.6
98.41

142.0
13.6
598.6
98.98

130.4
6.7
589.1
99.34

119.8
4.3
582.0
99.53

273.2
187.5
785.2
77.83

264.6
174.0
762.8
81.27

2561
160.8
743.0
84.17

247.7
148.1
725.5
86.65

239.5
135.8
710.2
88.76

231.6
124.0
696.9
90.49

225.7
112.5
684.8
91.97

2160
101.3
674.0
93.1*

206.3
90.5
664.2
94.25

201.1
80.0
655.1
95.16

193.8
69.9
646.6
95.87

186.8
60.8
639.2
96.54

179.9
52.2
632.3
97.11

173.2
44.4
625.6
97.38

166.6
37.3
619.1
97.97

160.2
31.0
612.6
98.30

146.1
18.5
600.3
98.90

300.0
228.0
858.0
65.83

277.5
192.2
789.5
77.34

268.9
178.6
766.8
80.87

260.4
165.4
746.8
83.80

252.1
152.8
729.1
86.27

243.8
140.5
713.7
88.41

235.7
128.8
700.3
90.17

220.2
106.2
677.0
92.94-

212.6
95.4
667.0
94.03

205.2
84.9
657.7
94.95

197.9
74.8
649.0
95.68

177.2
49.2
627.6
97.44

170.5
41.9
620.9
97.84

164.0
35.5
614.3
98.19

149.9
22.9
601.8
98.82

304.4
232.6
862.4
65.25

281.7
196.8
793.7
76.86

273.0
183.1
770.9
80.45

264.5
170.0
750.6
83.43

256.1
157.5
732.7
85.93

247.9
145.1
717.2
88.11

239.8
133.5
703.7
89.88

224.2
110.9
680.0
92.71

216.7
100.2
669.8
93.82

209.2
89.8
660.4
94.73

202.0
79.7
651.5
95.52

190.8
65.6
641.4
96.39
194.8
70.5
643.7
96.24

183.9
57.1
634.3
96.95

328.8
271.4
952.0
49.25

227.8
117.3
6*8.0
91.70
231.9
122.0
691.2
91.42

134.4
11.3
590.5
99.28
138.4
15.9
591.8
99.24

187.8
61.9
636.5
96.81

181.0
53.8
629.5
97.32

174.3
46.5
622.8
97.72

167.7
39.8
616.0
98.09

153.5
27.0
603.2
98.76

342.9
292.0
997.1
41.03

332.8
275.9
955.9
48.73

308.6
237.0
866.6
64.71

285.8
201.1
797.7
76.39

277.0
187.5
774.7
80.05

268.4
174.4
754.2
83.06

259.6
161.7
736.1
85.59

251.8
149.5
720.3
87.80

243.7
138.0
706.5
89.42

235.8
126.7
693.8
91.18

2280
115.4
682.4
92.4*

220.4
104.6
672.0
93.62

212.9
94.2
662.5
94.37

205.6
84.1
653.6
95.35

198.4
74.8
645.7
96.11

191.4
66.2
638.4
96.68

184.5
58.1
631.3
97.20

177.8
50.6
624.5
97.60

171.2
43.9
617.7
97.99

357.1
313.0
1044.8
31.58

346.9
290.5
1000.6
40.60

336.8
280.4
959.7
48.25

312.7
241.2
870.8
64.18

289.7
205.4
801.7
75.94

280.8
191.7
778.5
79.65

272.2
178.5
757.7
82.88

263.1
165.9
739.4
85.27

255.6
153.8
723.3
87.50

247.4
142.2
709.3
19.37

239.5
131.2
696.4
90.4

231.7
119.7
6*4.7
92.2*

224.1
108.8
674.2
93.44

216.5
98.5
664.5
94.41

209.2
88.3
655.6
95.21

202.0
79.1
647.6
95.98

194.9
70.3
640.2
96.56

188.0
62.2
633.1
97.09

181.3
54.7
626.2
97.51

371.7
333.9
1094.8
21.66

361.0
317.2
1047.6
31.17

350.7
300.8
1003.8
40.17

340.7
284.7
963.3
47.79

316.6
2455
874.7
63.67

293*
209.6
805.4
75.52

284.7
195.9
782.0
79.25

2760
182.7
761.1
82.32

267.6
170.0
742.5
84.95

259.2
157.9
726.2
87.20

250.9
140.3
712.0
19.13

243.2
135.6
699.0
96.71

235.1
123.8
687.0
92.09

227.7
113.0
676.5
3.27

220.0
102.7
666.6
94.25

212.9
92.6
657.7
95.06

205.5
83.3
649.6
95.85

198.4
74.5
642.1
96.44

191.5
66.4
634.9
96.98

386.4
355.0
1146.8
11.06

375.6
338.1
1097.0
21.30

364.9
321.4
1050.5
30.78

354.6
305.0
1007.1
39.75

344.5
288.9
966.9
47.35

320.3
249.8
878.6
63.17

297.2
213.6
809.1
75.11

288.5
199.8
785.5
78.88

279.6
186.4
764.4
81.97

271.1
174.1
745.6
84.63

262.6
161.3
729.0
86.91

254.4
150.8
714.7
88.88

246.8
139.9
701.5
90.4*

238.2
127.1
669.2
91.96

231.1
117.2
678.5
93.09

223.4
106.8
668.7
94.10

216.0
96.8
659.8
94.90

208.9
87.6
651.6
95.72

201.8
78.9
643.9
96.34

t
401.0
kt
376.0
hs 12O0.5
XT
0.00

390.1
359.0
1148.1
10.84

379.3
342.2
1098.8
20.96

368.6
325.6
1052.8
30.41

358.3
309.1
1010.0
39.54

348.2
293.0
970.1
46.94

324.2
253.5
882.3
62.68

300.8
217.5
812.9
74.70

291.8
203.7
789.1
78.51

283.1
190.4
767.8
81.63

274.6
178.2
748.8
84.32

266.1
165.6
732.0
86.65

257.7
155.2
717.5
18.64

256.2
144.0
704.0
90.21

241.7
131.8
691.7
*1.7*

234.5
121.2
410.1
92.91

226.6
110.8
670.9
93.95

219.2
100.7
661.8
94.75

212.0
91.4
655.5
95.61

260

1
404.4
kt 379.8
hs 1201.0
XT
0.00

393.6
362.9
1149.4
10.62

382.9
346.1
1100.9
20.62

372.2
329.5
1055.4
30.05

361.9
313.1
1012.9
38.96

351.8
294.9
973.3
46.56

327.7
257.3
885.6
62.23

304.2
221.3
816.0
74.30

295.2
207.5
792.2
78.15

286.5
194.4
770.8
81.32

278.0
181.8
751.7
84.04

269*
169.8
734.9
86.40

261.0
159.1
720.2
88.40

243.4
156.1
694.1
91.56

237.7
125.S
683.0
92.74

229.9
114.9
673.0
93.80

222.4
104.5
663.8
94.60

270

t
ht
hs

407.8
313.4
1201.4
0.00

397.0
366.6
1150.5
10.40

386.4
350.0
1102.6
20.29

375.8
332.9
1057.6
29.71

365.4
317.0
1015.5
38.59

355.3
300.8
9762
46.21

331.0
260.9
889.0
61.80

307.5
224.9
819.4
73.90

298.4
211.1
795.5
77.81

289.7
197.9
774.0
81.03

281.2
185.4
754.7
83.80

272.9
173.5
737.6
86.16

2*4.2
162.7
722.7
18.16

253.5
I47.S
706.4
90.05
256.6
151.4
708.8
89.84

248.6
140.0
696.5
vl.J!

346.8
129.0
415.0
92.57

233.1
US.7
674.8
93.66

280

411.1
317.0
1201.8
0.00

4004
370.3
1131.5
10.18

389.8
353.6
H04.3
19.97

379.2
337.1
1059.8
29.39

3*8.8
320.7
tots.i
38.23

*567
304.5
979.1
45.8*

334.4
264.6
892.4
61.40

310.7
228.4
822.8
73.50

301.6
214.6
798.8
77.50

292.8
201.3
777.1
80.77

284.3
188.8
757.7
83.57

273.8
176.6
740.4
85.90

267.4
166.1
725.2
87.92

259.5
154.8
711.2
89.43

251.4
143.1
698.4
91.14,

343.4
132.1
417.1
92.40

298

414.2
3*0.5
1202.1
0.90

403.6
373.8
1152.5
9.96

393.0
357.2
1105.8
19.65

382.5
340.7
1061.8
29.09

372.1
324.3
1020.5
37.87

362.0
368.1
981.8
45.51

337.6
268.2
895.7
61.00

513.8
231.8
826.1
73.10

304.7
217.9
802.0
77.25

295.9
204.6
780.2
80.54

287.4
192.2
760.7
83.37

278.3
180.0
743.2
85.67

270.3
169.4
727.8
87.68

262.4 .
158.0
713.5
89.42

254.3
144.4
700.6
90.9*

24f..5
136.4
MP*!
92JM

324.9
283.7
1063.2
26.35

303.8
250.2
959.1
45.71

293.7
234.1
915.1
54.01

269.0
195.6
826.0
69.74

247.6
159.8
759.8
80.50

339.0
304.0
1125.5
13.89

528.0
286.6
1065.3
26.04

317.3
269.7
1011.0
33.92

306.8
253.2
962.1
45.32

296.6
237.1
918.3
53.58

272.4
198.8
829.3
69.34

353.0
324.7
1192.4
0.00

341.8
306.9
1126.9
13.69

330.8
289.5
1067.4
25.74

320.1
272.6
1013.6
35.5*

309.7
256.1
965 1
44.92

299.5
240.0
921.5
55.18

355.1
327.6
1193.0
0.00

344.6
309.8
1128.4
13.62

333.5
292.4
1069.5
25.4$

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loss tbo actual molal volume of the solution) il a function of two constant* and the molal concentration of the
components. From ail known data on liquid volumes,
these constants were calculated. The resulting values
were plotted as a function of temperature and fitted with
a second degree equation. The resulting equation in conjunction with Fischer's relation made it then possible
to calculate from the specific volumes of the components,
the specific volume of the aqua at any temperature and
concentration.
The values (Tables 1 and 2) are listed for the saturated
state. However, the properties of sub-cooled liquid may
be found with reasonable accuracy by neglecting the effect of pressure on the state of sub-cooled liquid.
Accepting Wucherer's and Zinner's estimate of the
accuracy of their own work, the accuracy of the data,
in English units, appears as follows:

Find:

x correct to 0.005 approximately.

kf correct to 0.7 Btu. per lb.
h. correct to 1 Btu. per lb., except at pressure extremes of the tables.
The values of this table were interpolated so as to reproduce the original values well within the accuracy
stated. The precision of the tables has been carried to a
greater degree than the original data justify, especially
in the case of x. and h.. This was done to provide systematic accuracy of the tables for use in interpolation
and for the many calculations that involve quantity differences. It is thought that linear interpolation between
values in the tables will yield reasonable precision.
The values for specific volume of the liquid as calculated
from the general equation were found to check the majority of reported values well within 0.0001 cu. ft. per
lb. within the range of measurements. For temperatures
beyond 140 F. and concentrations above 50 per cent the
values given are extrapolations unsupported by measurement. However, the close correspondence of the general
equation to measurements by several investigators in
known ranges justifies the extrapolation.
If the enthalpy of superheated aqua vapor is desired,
it may be calculated in the same general manner as outlined for saturated aqua vapor by assuming the vapor is
merely a mixture of superheated components. However,
superheated aqua vapor, i.e., superheated in regard to
mixture equilibrium conditions, is not commonly met in
the absorption cycle except in the evaporator. Here the
condition of the vapor is so nearly anhydrous, that the
enthalpy of the vapor may be taken directly from the ammonia tables and then reduced to a 32 F. datum.
Some examples are given in selecting values from the
tables. For the most part exact tabular values are taken
to avoid the confusion of interpolation. It is suggested
in using these tables that if one has much work in a
given range, the construction of a graphical working plot
of the requisite data will greatly reduce the labor of
arithmetical interpolation.
Given:

Find:

Given:

150 lb. per sq. in. absolute and

Saturation temperature 225.5* F.
I.in
0.28
Liquid
concentration
Enthalpy of liquid
120.2 Btu. per lb.
Enthalpy of vapor
699.4 Btu. per lb.
Vapor concentration
0.8980 Weight fraction of ammonia

Find:

Saturation temperature
Liquid concentration
Enthalpy of liquid
Enthalpy of vapor

105.6* F.
0.70
3.5 Btu. per lb.
573.3 Btu. per lb.

Given:

Liquid concentration
Enthalpy of liquid
Pressure

0.50
60.6
180 lb. per sq. in.
absolute.

Find:

Tem per atu re.

Saturation pressure

These conditions are presented in the case

of strong liquor leaving the heat exchanger.
It is a matter of direct tabular values if
liquid is sub-cooled or saturated. However,
under some conditions its enthalpy, by heat
balance calculation, may exceed the saturation
value, i.e., the liquid may be partially vaporized.
Under such conditions a "cut and
try" solution is required.
Let h = total enthalpy of the mixture,
h. ss enthalpy of the vapor phase,
ht = enthalpy of the liquid phase,
x. = concentration of the vapor phase,
xt = concentration of the liquid phase,
x ; concentration of the mixture,
m = portion of the mixture vaporized.
Ammonia balance: mx. -f- (1 m ) # _ : *
Heat balance
mh\ -f- (J m) hf h
x xt

Whence is desired

h hf

=
x, Xt

aa m
h. ht

To solve the problem given above, select a point, at the

same pressure as given but with lower liquid concentration, which will satisfy the above equation.
Under the conditions given in this example, the equation is satisfied by the following values.
Given:

h s s 60.6 Btu. per lb.

* = 0.50
p s s 180 lb. per sq. in.
A final trial of
xt = 0.48
t =166.6*F.
p s s 180 lb. per sq. in.
A, = 37.3 Btu. per lb.
h, = 619.1 Btu. per lb.
x, 0.9797
m 0.04
gives a successful solution.

Saturation pressure

The above liquid is cooled to 110.5* F. under

150 lb. per sq. in. pressure and liquid concentration remains 0.28.

Vapor concentration

150 lb. per sq. in.

absolute
0.9975

Given:

4.

Enthalpy of liquid, 5.5 Btu. per lb.

This state is equivalent to 28 per cent liquid
boiling at 110.5* F. This is sub-cooled liquid
and the fact that a saturation pressure of
25 lb. per sq. in. ia given has no significance.

The conditions given are thus satisfied at 180 lb. per

sq. in. and 166.6 F. with 4.0 per cent of the mixture in
the vapor phase.
5.

Given:
Find:

Temperature
Liquid concentration
The specific volume of
the liquid.

220
0.30

TABLE 2.

SPECIFIC VOLUME OF AQUA AMMONIACu. Ft. Per Lb.

in Saturated or Sub-Cooled State
W tight

Temp.

of ammonia

concentration

' F.

0.00

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

20
40
60
80
100
120
140
160
180
200
220
240
260

.0160
.0160
.0160
.0161
.0161
.0162
.0163
.0164
.0165
.0166
.0168
.0169
.0171

.0166
.0167
.0167
.0168
.0169
.0170
.0171
.0172
.0174
.0176
.0178
.0182
.0189

.0172
.0172
.0173
.0174
.0175
.0176
.0178
.0180
.0182
.0185
.0189
.0194
.0207

.0177
.0178
.0179
.0180
.0182
.0184
.0186
.0188
.0191
.0195
.0200
.0209
.0227

.0182
.0183
.0185
.0186
.0189
.0191
.019*
.0197
.0201
.0206
.0213
.0224
.0249

.0188
.0190
.0192
.0195
.0197
.0200
.0204
.0208
.0213
.0220
.0229
.0244
.0275

.0196
.0199
.0201
.0204
.0208
.0212
.0216
.0222
.0228
.0237
.0248
.0267
.0305

.0206
.0209
.0213
.0216
.0221
.0226
.0231
.0238
.0246
.0257
.0272
.0293
.0339

.0218
.0222
.0226
.0231
.0236
.0242
.0250
.0258
.0268
.0281
.0298
.0324
.0377

.0232
.0236
.0242
.0248
.0254
.0262
.0270
.0280
.0292
.0307
.0328
.0356
.0418

.0247
.0253
.0260
.0267
.0275
.0284
.02*4
.0304
.0320
.0338
.0361
.03*5
.046S

Density of mixture per

cu. ft. 0.326 -f
0.036=
Specific volume is thus
1/0.362

From Table 2 read 0.0200 cu. ft. per lb.

6. Given:

The conditions in Example 1

Find: The specific volume of the vapor.
Pressure
150 lb. per sq. in.
Temperature
225.5 F.
Vapor concentration
0.8980
(weight)
Molal vapor concentration 0.8980+0.0051
(cf. Fig. 2) 0.9031
Ammonia partial pressure 0.9031 X 150 135.5 lb. per sq. in.
Water partial pressure
0.0969 X 150
14.5 lb. per sq. in.
Specific volume ammonia at 135.5 lb.
per sq. in. at 225.5
F. from B. of S.
Ammonia Tables
3.06 cu. ft per lb.
or 0.326 lb. per cu. ft.
Specific volume steam
14.5 lb. per sq. in.
at 225.5 F. from
Steam Tables
27.81 cu. ft. per lb.
or 0.036 lb. per cu. ft.

The American Society of Refrigerating Engineers

37 West 39th Street
New York, N. Y.

0.362 lb. per cu. ft

2.76 cu. ft. per lb.

The authors wish to acknowledge the work of N. J.

Palladino, R. J. Prowell and S. B. Nissley, who largely
carried out the detailed work of the computations and
checking of the tabular values. The authors realize that
in an undertaking of this size, mistakes, both typographical and arithmetic, exist, but hope that careful and
repeated checking has kept these to a minimum.

Bibliography
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
(15)
(16)

A. A. Berestneff, Refrigerating Data Book, 2nd Ed. p. 18.

A. B. Stickney, RENIIGEBATINO ENGINEERING, Oct., 193S, mppl.
T. A. Wilson, University of Illinois Bulletin No. 146.
J. L. Clifford and K. Hunter, Journal of Physical
Chemistry,
Vol. 37. 1933.
J. Wucherer, Ztit. f.d.g. Kiltt Industrie, Vol. 39, June, July,
1932.
K. Zinner. Zeis f.d.g. Kilte Industrie, Vol. 41, Feb., 1934.
E. Baud ft L. Gay, Annales de Chemic et Phys., Vol. 17, p. 39*,
1929.
H. Mollier, Mitt. Forschunj sarbeiten. Vol. 63/64. 1909.
V. Fisher Forschung a.d. Gtbeit d. tng.. Vol. 6, March, 1935.
Lewis ft Randall, "Thermodynamics", 1st ed., p. 225.
International Critical Tables, Vol. I l l , p. 59.
A. Mittasch et al., Ztit. anora. alio. Chem., Vol. 159, p. 1, 1926.
King, Hall ft Ware, Jour, of Am. Chem. Soc, Vol. 52, p. 5132,
1930.
International Critical Tables, Vol. IV, p. 261.
Steam Tables. J. H. Keenan. Am. Soc. Mech. Efifrrs.. 1930.
Tables of the Thermodynamic Properties of Ammonia, U. S
Bureau of Standards Circular No. 142, 1923.

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