OO. O 4 © ae GRILEDECHIMIE ‘O. « REZOLVATE Qs ...¢a la Oxford! Hl te Antreneazi-ti SinapseleComplement grupat 1) Nu pot fi utilzati ca agenti de alchilare pentru amine: 1. sulfatul acid de etil bromura de benzil iodura de ali bromura de butiril {a aceasta intrebare, R-NHa ataca nucleofil substratul. Se pune problema reactivitatl substratului in reactia de substitutie nucleofila: 1. IM CHs-CH-SOsH, grupa ~SOaH* este o grupa fugace foarte buna, -SOuH find in acelasi timp un Nucleofil foarte slab, deci reactia de alchilare va decurge fara probleme. ¥ 2. si 3. Pozitile alice si benzilece au o reactivitate crescuta, iar legaturile C-Br si C-I sunt usor desfacute in reactia de substitutie nucleofila. 4. Siaceasta reactie este posibila find 0 combinatie de aditie + eliminare, insa teoretic acesata reactie este una de acilare, nu de alchilare. X 2) Derivatul crotonic A, obtinut din doua molecule de propanal: 1. se poate condensa crotonic cu a treia molecula de propanal, jucand rolu! de componenta carbonilica 2. prezinta izomerie geometrica 3. _saturarea compusului A cu hidrogen conduce la un compus cu atom de carbon asimetric 4. este reducator A He Hs ° oO wy, CL 20120 Ne aA meee 1. Compusul A poate condensa cu inca 0 molecula de propanal ca si componenta carbonilica, deoarece pentru a fi cealalta componenta, cea metilenica, ar avea nevoie de un atom de hidrogen la C2. 7 Lv Saturarea cu hidrogen va genera un carbon asimetric la C2. 7 4, Compusul a poate fi oxidat la stadiul de acid carboxilc, in acest caz fiind agent reducator. 7 2. Da, prezinta izomerie geometrica la legatura dubal C 3) Sunt corecte afirmatiile: 1. 2-cloro-2-butena este un compus halogenat cu reactivitate scazuta 2. Bromura de ciclohexil este un compus halogenat cu reactivitate normala 3. 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Exista doar doua variante in care un carbon poate fi nular: partea de acid carbonic este H-CONHR; sau parte de amina este R-COONRCHs. > vo. 16