CHEMISTRY-Paper 2 SECTION A [Structured Items]

SET A

Diagram 1 shows the structural formula of two of hydrocarbons.

H C H
Ethene

H C H H

H C H

H C H H

compound Y Diagram 1

(a)

State the name of the homologous series in which ethene is placed. .. [1 mark]

(b)

Write the general formula of the homologous series that you are stated in (a). .. [1 mark]

(c)

Write the molecular formula of compound Y .. [1 mark]

(d) What is observation when bromine water is added to compound Y and exposed to ultra violet
ray? .. [1 mark]

(e)

State the type of reaction when bromine water is reacted with compound Y. .. [1 mark]

(f)

(i)

State the name of the products formed when ethene burnt completely in excess oxygen. ... [1 mark] Write the chemical equation for the reaction in (f) (i). ... [2 marks]

(ii)

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2

SET A

Diagram 2 shows the set-up of apparatus to study the rate of reaction between hydrochloric acid with sodium tiosulphate solution. Observer eye

250 cm3 conical flask Sodium thiosulphate solution + hydrochloric acid X sign Diagram 2 In this reaction, a 250 cm3 conical flask contained 45 cm3 of 0.2 mol dm-3 sodium thiosulphate solution, Na2S2O3 is placed on a white paper marked with the X sign. 5.0 cm3 of 2.0 mol dm-3 hydrochloric acid was added to the sodium thiosulphate solution and the mixture swirled. At the same time the stopwatch was started. The time is taken as soon as the X sign is no longer visible. (a) In this reaction, a precipitate is formed. What is the colour of the precipitate? .. [1 mark] White paper

(b)

Calculate the number of moles of HCl and the number of moles of Na2S2O3 used in the experiment.

[2 marks]

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(c)

SET A

The chemical equation for the reaction occurred in this reaction is : Na2S2O3 + 2HCl 2NaCl + S + SO2 + H2O Based on the calculation in (b) and the chemical equation above, calculate the mass of the precipitate formed. [Given that the relative atomic mass of S = 32]

[2 marks]

(d)

(i) State two factors that affect the rate of reaction in this experiment. ... ... [2 marks] (ii) By using any one of the factor that you are stated in (d) (i), explain how the factor that you are stated in (d) (i) affect the rate of reaction. ... ... ... ... ... [4 marks]

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3 (a) Bronze is an alloy of copper. (i)

SET A

State the name of the element that is added to copper to form bronze. ... [1 mark]

(ii)

Explain why bronze is harder than pure copper. ... ... ... [2 marks]

(iii)

Draw the arrangement of particles in pure copper and bronze.

Pure copper (b) Synthetic polymers are widely used in our daily lives. (i)

Bronze

[2 marks]

Complete the table below with the correct name of monomers. Polymer Name of monomer

Polyvinylchloride

Natural rubber

[2 marks]

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(ii)

SET A

State one use of polyvinylchloride in our daily lives. ... [1 mark]

(c)

There are 4 types of glass that are fused glass, soda-lime glass, borosilicate glass and leadcrystal glass. What type of glass is used to make a boiling tube? Give a reason. .............. .............. [2 marks]

Hydrochloric acid, HCl is a strong acid. Table 4.1 shows two solutions of hydrochloric acid, HCl with different concentration. Solution A B Concentration / mol dm-3 1.0 0.001 Table 4.1 pH 1.0 3.0

(a)

what is meant by acid ? .. .. [1 mark]

(b)

pH value of the solution A and B are different. Explain why. .. .. .. .. [3 marks]

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SET A

(c)

Diagram 4.2 shows the set-up of apparatus for titration of 25 cm3 of 1.0 mol dm-3 sodium hydroxide solution with solution A, using phenolphthalein as indicator.

Solution A

25 cm3 of 1.0 mol dm-3 sodium hydroxide solution + phenolphthalein indicator Diagram 4.2 (i) State the colour change of the solution in the conical flask at the end point. ... [1 mark] (ii) State the type of the reaction occurred. ... [1 mark] (iii) Write the chemical equation for the reaction. ... [1 mark]

(iv) Calculate the volume of solution A needed to neutralise the sodium hydroxide solution.

[3 marks]

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SET A

Diagam 5 shows the set-up of apparatus to investigate the reaction between iron(II) sulphate solution and acified potassium dichromate(VI) solution through the transfer of electrons at a distance.

Carbon electrode

Carbon electrode

Iron(II) sulphate solution Diluted sulphuric acid Diagram 5 (a) What is the colour of iron(II) sulphate solution?

Acidified potassium dichromate(VI) solution

.. [1 mark]

(b) (i)

Write the half equation for the reaction occur at X. ... [1 mark]

(ii)

State the change in oxidation number of iron. ... [1 mark]

(c)

The incomplete half equation occur at Y is : Cr2O72- + . Complete the equation. + 6e Cr3+ + H2O [1 mark] [1 mark]

(d) On the diagram above, show the direction of electrons flow.

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SET A

(e)

You are provided with the following : (i) Bromine water Potassium iodide solution Carbon electrodes Beaker Porous pot Connecting wire By using the given materials and apparatus, draw the set-up of apparatus to investigate the redox reaction through transfer of electron at a distance.

[2 marks] (ii) (iii) On your diagram in (e) (i), indicate the positive and negative terminal. [1 mark] State the change in oxidation number for bromine in this reaction. ... [1 mark]

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6 The following equation is not balanced :

10

SET A

Na2SO4(aq) + BaCl2(aq)
(a)

BaSO4(s) + NaCl(aq)

Identify the reactants and products of the reaction. Reactants : .. Products : ... [ 2 marks] Write the balanced equation. ... [ 1 mark] Calculate :

(b)

(c) (i)

the number of mole of sodium sulphate that react completely with a solution containing 4.16 g of barium chloride [ Relative atomic mass : Cl = 35.5; Ba = 137 ]

[ 2 marks]

(ii)

the mass of barium sulphate formed when 1 mol of sodium sulphate is reacted completely with barium chloride. [ Relative atomic mass : O = 16; S = 32; Ba = 137 ]

[ 2 marks]

(d)

In an experiment, when chlorine gas is passed over heated iron wool, a chloride compound with 34.5 % iron by mass is formed. Determine the empirical formula of the chloride compound. [ Relative atomic mass : Cl = 35.5; Fe = 56 ]

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11

SET A
[ 3 marks]

SECTION B [Limited Respond Items]

7 Diagram 7.1 shows the set-up of apparatus to investigate the electrolysis of magnesium chloride 1.0 mol dm-3 solution.

Carbon electrodes

Magnesium chloride 1.0 mol dm-3

A A Diagram 7.1 (a) (i) Based on Diagram 7.1, state the name of the products at the cathode and the anode. Explain your answer in term of factor that affects discharge of ion. [8 marks] Predict the product at anode and cathode if magnesium chloride 1.0 mol dm-3 solution is replace by magnesium chloride 0.0001 mol dm-3 solution. [2 marks]

(ii)

(b)

Diagram 7.2 shows the set up of apparatus when cell X is combined with cell Y.

V
Magnesium plate

Copper plate

Copper plate

Copper(II) sulphate solution

Cell X

Diagram 7.2

Cell Y

Compare cell X and cell Y base on ; the name of the cells, energy conversion, the observations and half equations for the reactions at the electrodes in both cells. . [10 marks]

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8 (a)

12

SET A

Diagram 8.1 shows the structure of anion parts of a soap and a detergent. These anions consist of part A and part B as shown in the diagram.

Anion of a soap

Anion of a detergent

Part A Diagram 8.1 (i)

Part B

Name part A and part B of the anions. State the solubility of part A and part B in the cleansing action. [4 marks] Compare the effectiveness of the cleansing action of the two anions shows in the diagram 8.1 in hard water. Explain your answer. Write an ionic equation to show the reaction of anion of soap in hard water. [6 marks]

(ii)

(b)

Diagram 8.2 shows the label of soft drink.

Ingredient : Water, citric acid, aspartame, octyl butanoate and tartazine. Expiry date : 03 Jan 2011 Diagram 8.2 Based on the ingredient used, classify the type of food additives that contained in this soft drink. [4 marks] (c) A patient is suffering from tuberculosis for a period of time. Suggest a type of medicine that should be taken and the prescription should be followed by the patient. [4 marks]

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CHEMISTRY-Paper 2 SECTION C [Open Respond Items]

9

13

SET A

Table 9 shows the proton number of atoms of elements X, Y and Z. Element W X Y Z Table 9 Proton Number 1 3 6 8

(a)

State the arrangement of elements X, Y and Z in the order of increasing atomic radius. Explain your answer. [4 marks]

(b)

The reaction between elements X and Y form a chemical compound. Explain the formation of this compound. [6 marks] (c) (i) The reaction between elements Z and W form another chemical compound. Draw the electron arrangement of the compound formed. [2 marks] Compare two physical properties below for the compounds formed in (b) and (c). Melting point Electric conductivity. Explain the differences in each pysical property. [8 marks]

(ii)

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10 (a)

14

SET A

Diagrams 10.1 and 10.2 show two energy level diagrams. Energy
CaCO3 + 2NaCl

Energy
Mg + FeSO4 H= - 200 kJ

H= + 12.6 kJ

MgSO4 + Fe

CaCl2 + Na2CO3

Diagram 10.1

Diagram 10.2

(i)
(ii)

Compare both the energy level diagrams above. Your explanation should include the following : ionic equations type of chemical reactions energy content of reactants and products [6 marks] Based on Diagram 10.1, calculate the change in temperature of the solution if excess magnesium powder is added to 50 cm3 of 0.2 mol dm-3 iron(II) sulphate solution. [Specific heat capacity of solution : 4.2 J g -1 oC-1] [3 marks]

(b)

Explain why the heat of reaction between 1.0 mole of silver nitrate solution and 1.0 mole of sodium chloride solution is the same as the heat of reaction between 1.0 mole of silver nitrate solution and 0.5 mole of magnesium chloride solution. [4 marks] A student carried out an experiment to determine the heat of neutralisation for the reaction between 50 cm3 of 2.0 mol dm-3 hydrochloric acid and 50 cm3 of 2.0 mol dm-3 sodium hydroxide solution. The following data was obtained : Initial temperature of hydrochloric acid Initial temperature of sodium hydroxide solution Highest temperature of the mixture of the solutions (i) Calculate the heat of neutralisation for this reaction. [Specific heat capacity of solution = 4.2 J g -1 oC -1] [3 marks] (ii) If the experiment is repeated using sulphuric acid to replace hydrochloric acid and all other conditions are the same, predict the heat change. Explain your answer. [4 marks] = = = 30.2 oC 30.2 oC 42.2 oC

(c)

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15 END OF QUESTION PAPER-SET A

SET A

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