TCVN TIEU CHUAN QUOCGIA TCVN 9069:2012 Xudt ban ln 1 VAT LIEU LOC DANG HAT DUNG TRONG XU LY NU'OC SACH — PHU’ONG PHAP THU Granular filtering material for water purification - Test methods HA NOI - 2012TCVN 9069:2012 Loi néi dau TCVN 9069:2012 durgc chyén didi tr TCXDVN 310:2004 theo quy dinh tai khodn 1 Bidu 69 cla Luat Tiéu chuan va Quy chuan ky thuat va diém a khodn 1 Bidu 7 Nghi dinh sé 127/2007/ND-CP ngay 4118/2007 eta Chinh phi quy dinh chi tiét thi hanh mét sé digu cia Luat Tiéu chudn va Quy chudn ky thuat. TTCVN 9069:2012 do Vién Vat ligu xay dung - BO Xay dyng bién soan, BO Xay ding 48 nghi, Téng cuc Tigu chudn Bo Iwéng Chat lugng thdm dinh, B@ Khoa hoc va Céng nghé céng bé.ee TIEU CHUAN QUOCGIA TCVN 9069:2012 ase ee Vat ligu loc dang hat dung trong xi? ly nuéc sach — Phuong phap thr Granular filtering material for water purification - Test methods 1 Pham vi 4p dung Tiéu chudn nay qui dinh phyong phap xac dinh cdc tinh chat ca vat ligu loc (sdi 48, c&t thach anh, than antraxit, than hoat tinh dang hat) ding trong hé théng xir ly nuéc sach. 2 Tailigu vign din Cac tai ligu vign din sau la c&n thiét cho viée ap dung tiéu chuan. 86i véi cdc tai ligu vién d&n ghi nm céng bé thi 4p dung ban duge néu. Béi véi cdc tai ligu vign dln khéng ghi nam céng bé thi 4p dung phign ban méi nhat, bao gdm cd cdc stra ai, bd xung (néu cé). TCVN 9068:2012 Vat liéu loc dang hat ding trong xurly nude sach — Yéu cdu ky thuat. 3 Lay mau ther 31 Léy mau déi véi sdi de, cét thach anh va than antraxit 3.1.1 Léy mau déi voi vat ligu chira trong bao Ly mau trong bao géi kin, ghi rO tén, dia chi cita hang cung cép, loai vat liu loc, kich &. Sau dé, tron du cdc mu durge lay & céc bao khéc nhau truéc khi tién hanh thir nghiém. Khéi long mau t6i thiu dugc quy dinh trong Bang 1, sé bao can léy mu duoc quy dinh trong Bang 2. Bang 4 — Khéi lgng mau sdi dé, cat thach anh va than antraxit can ly 48 phan tich Kich c& lén nhat cia hat Khél lwgng mau téi thidu trong mau, mm ly a8 phan tich, kg 63,0 45,0 375 32,0 25,4 23,0 19,0 14,0 12,5 9,0 595 45 aTCVN 9069:2012 Bang 2 - Lay mau sdi d, cat thach anh, than antraxit theo Ié hang dong bao 86 bao chira vat ligu ‘ a cia nits Kang $6 Ilweng bao t6i thidu can ly mau 28 2 9-15 3 16-25 5 26-50 8 51-80 13 91-150 20 151-280 32 281-500 50 501-1200 80 1201-3200 125 3201-10000 200 10001-35000 315 35001-150000 500 3.1.2 Léy mau d6i véi vat ligu chira trong céngteno Khi céc thung cOngteno chira séi d%, cét thach anh, than antraxit duge dua dén cong trréng phai tién hanh lay mu ngay. Khi ldy mu phai ldy & vi tri mat c&t ngang cita vat ligu dang durge xép. Khéi long mau durgc ly theo quy dinh trong Bang 1. $6 lugng thing céngteno chtra vat liéu loc c&n dug lay mu theo quy dinh trong Bang 2. 3.4.3 Lay mau déi v6i hang cho roi Mau cé thé durgc ldy tai nai sn xudt hoc noi chia hang. Khong dug ly mu 6 céng trudng tri khi 6 sy thod thuan b&ng van ban cila cdc bén lién quan, khi 46 viée dy mu phai durgc tién hanh tai 10 diém khdc nhau: mot mau & gan ngudi lay mAu, méi géc ila bai dé vat liéu loc Ay mot mau, mot mau & gilra va cdc mau cén lai dug lay ngdu nhién. 3.2 Lady mdu déi voi than hoat tinh dang hat - Dung cy Idy mau la mét éng vat nhon cé duréng kinh 20 mm. Khi ldy mau, éng ly mu phai xuyén hét chidu dai cla bao nhung can han ché t6i da sy lam vé vun than hoat tinh. ~ Mau phai dug ldy tai noi chtra hang néu la hang ché rdi va trong 5 % sé bao néu chira trong bao géi kin. - B4i voi mAu 6 khdi lugng lén, khodng (2 + 3) kg, can chia mau thanh bén phan bang nhau véi méi phan [4 mot mau rdi giri ba mau di dé thir nghiém. Mau due chiva trong Io thy tinh kin 6 ky higu va ghi rd tén nguéi ly mau. 6TCVN 9069:2012 4 Qui dinh chung 4.4 Méi quan hé gira kich cf cia sdi d&, cat thach anh, than antraxit va lgng dung dich HCI dam aac (36%) duoc pha vao nude theo ty 16 1:1, voi khdi lugng mu t6i thidu ding 48 xac dinh 46 hod tan trong axit €ugc quy dinh trong Bang 1. Bang 4 - Khéi lwgng mau t6i thiu ding a xac dinh dé héa tan trong axit HCI ty 1¢ 4:1 Kich c& cua hat trong mau] Khdilwong mau téithiéu, | Thé tich tdi thidu cilia dung mm 9 dich HCI ty 19 4:4, mL 63,0 4000 7000 a5 250 800 254 250 800 790 250 800 125 250 800 59,5 100 320 4.2. C& hat s6i d6, cét thach anh, than antraxit, than hoat tinh dang hat durgc xdc dinh bang cach sang qua cdc bd sang tiéu chudn. Co hat [a kich thuée mat sang nhé nhat ma né lot qua. 4.3. Kh6i lugng m&u t6i thiéu tng véi c& hat ln nhat dung 48 xéc dinh c&p phéi séi 8, cat thach anh va than antraxit duc quy dinh trong Bang 2. Bang 2 - Khéi legng mau téi thidu ding dé x4c dinh cdp phéi sdi dé, cat thach anh va than antraxit C& hat Ion nhat trong mau, mm] Khoi lwgng mau t6i thigu, kg 63,0 23,0 37,5 16,0 25,4 11,0 19,0 68 12,5 45 95 23 475 05 2,36 0 4.4. 8 tranh tinh trang ni suy qué mic khi xc dinh duéng kinh higu dung dey va deo thi phai chon sang sao cho ty s6 duréng kinh mat sang olla cdc sang 6 kich c& mat sang ké can nhau la 4/2. 4.8 K&t qua xAc dinh thanh phan c4p phéi c& hat cila sdi d& va vat ligu loc dug thé hién bang dB thi logarit voi truc hoanh thé hién duéng kinh mat sang va truc tung thé hién phan tram vat liéu loc lot qua sang.TCVN 9069:2012 5 Phwong phap thir 5.1 Xac dinh d@ hoa tan cia sdi dé, cat thach anh, than antraxit trong axit HCI ty 16 4:1 5.1.4 Cach tién hanh ~ Riva mu bing nuréc cdt va sdy khd & nhiét 46 (110 5) °C 6&n khéi leg khéng thay di, DE mau ngugi trong binh hut 4m rdi can mau, lay chinh xéc dén 0,1 g. - Cho m&u vao céc thly tinh ri dd dung dich HCI ty 16 1:1 sao cho ngap hoan toan mau (lugng dung dung dich HCI khéng it hon quy dinh trong Bang 1). B& m&u én dinh & nhiét & phéng, thinh thodng khudy nhe trong 30 min sau khi ngteng sui bot. - Léy mau ra khdi cdc, riva mau bang noc cAt va sdy khO & nhiét 6 (110 + 5) °C dén khéi long khéng thay d8i. 84 m&u nguéi trong binh hut 4m rdi can méu, ly chinh x4c dén 0,1 g. - Tién hanh thir hai lan véi méi kich c& sdi dé, ct thanh anh va than antraxit. 5.1.2 Bidu thi két qua D6 héa tan trong axit (M) tinh bang %, l4y chinh xc dén 0,1 %, la gia tri trung binh cong cia hai lan thir due tinh theo céng thire (1) sau: m= 2x100 ay 0 trong dé: dp [a khéiluong mu trudec khi ng&m, 9; dy & khéi long mau mat di sau khi ng&m, g 5.2 Xéc dinh 49 ve vyn ciia cét thach anb, than antraxit va than hoat tinh dang hat 6.2.1 Cach tién hanh ~ Léy 35 mL mau vat ligu loc rdi can. Cho mau vao mét éng dong hinh try bang kim loai clia thiét bj xac dinh 46 ve vun. Ong dong hinh try 6 dong kinh trong 40 mm, chiéu cao 100 mm. Ong dong hinh try Guge od dinh ddng tam trén mét banh xe c6 dung kinh 340 mm. Cho vao éng dong hinh try 18 vién bi thép cé dwéng kinh 12 mm. Quay banh xe quanh truc xuyén tam voi tc d6 25 r/min. - 86 ve vun cila vat ligu loc duc xéc dinh bang cach tién hanh lién tiép ba ln thir trén cling mot mau. Trong lin thir nghiém dau tién, x&c dinh thanh phan cp phéi clia vat ligu lgc. Sau Khi thu Iai toan bo vat ligu Igc tir cdc sang, tién hanh thi thém hai lan nia. Lan thir tiép theo thir nhdt, cho vat ligu vao 6ng dong hinh try c6 bi thép & trong va quay trong vong 15 min (twong duong 760 lan va dap hay 375 vong quay), sau a6 xc dinh thanh phan cp phi c& hat. Lan thir tiép theo thir hai tién hanh tuong ty nhung cho quay vat ligu loc trong vdng 30 min (tung dirong 1500 lan va dap hay 750 vong quay). ac dinh thanh phan cp phéi of hat vat ligu loc va vé biéu dd cdp phéi vat ligu loc cho ca ba lan thir.TCVN 9069:2012 5.2.2 Biéu thj két qua BO vo vn cia vat liéu loc durge tinh theo biéu 43 cp phéi Hinh 1. 1- Bidu ad ep phi vat iu loc truée va dip 2- Bidu 43 cp phéi vat litu loc sau va dap 8 96 Vét lidu loc lot qua sing Ht Buding kinh mat sing. Hinh 4 - Biéu a8 cdp phél vat ligu loc ding 48 xac dinh 46 ve vun Sau khi va 8p, goi X ld % luvgng vat ligu loc véi thanh phan c& hat ¢6 duéng kinh nhd hon dueng kinh higu dung dey ban dau. Phan vat ligu loc 6 kich o& In horn der ld (100 - X) % va dai dign cho 90 % vat ligu Igc c6 kha nding str dyng sau khi nghién dap. Do 46 c6 thé si dung: ” x(100- x) @ Luong mat ditinh theo % la: Bx (x =10) @) Luong mat di nay (%) la thuée do 46 ve vyn cia vat ligu loc. 6.3 X4c dinh khdi lvgng riéng cia sdi, cat thach anh va than antraxit 5.3.1 Dung cy - Binh thuy tinh tam gic, chiu nhiét ding 48 do khéi lugng riéng (binh do khéi lwgng riéng);TCVN 9069:2012 - Can ky thuat, cd 46 chinh x4c dén 0,01 g; + Binh hat am; - Ta sdy; - Bép cach cat hodc bép cach thuy. 5.3.2 C4ch tién hanh - Riva sach méu thi nghiém bang nuéc thudng va sau dé trang Iai bang nue ct. Can khodng 200 g miu (46i v6i s6i), 50 g mu (adi véi cat thach anh hodc than antraxit). S4y mau & nhiét a6 tir 105 °C dén 110°C. Lay ra, d& ngudi mau trong binh hut Am. = Riza sach binh do khéi long riéng bang nude cét, Sdy binh trong th sAy & nhiét 46 110 °C. Lay ra, 48 ngudi trong binh hit 4m. Cn va ghi khéi long cla binh (im,). - 86 mau vao binh do khdi lwgng riéng. Can va ghi khdi lugng cilia binh do khdi long riéng 43 chira mu thi nghiém (mz). - 88 nuéc cét vao binh do khéi Igng riéng sao cho chiém khoang 2/3 thé tich binh. L&c du binh chira mdu va dun s6i trén bép cach cat hodc bép cdch thu khodng 15 min dén 20 min 48 dudi hét bot khi ra khéi binh. B& ngudi dén nhiét do phong. BS thém nude ct dén vach dinh mirc cila binh, Can va ghi khdi long cia binh chia mAu thi nghiém va nuéc cét (ms). ~ Bd mau ra khdi binh. Riza sach binh, 43 nue ct vao dén vach dinh mirc ciia binh rbi cn (m,). 6.3.3 Bidu thi két qua Kh6i lurgng ring (p) cita di tinh bang kg/dm®; Cia cat, than antraxit tinh bang g/em* va durgc tinh theo cong thirc (2) sau: “wees trong a6: Pn 'a kh6i legng riéng cia nue cAt dy bang 1 gicm® hoac 1 kg/dm®, ‘my la khéi lugng binh do khdi Ivgng riéng, g; ‘mz 1a khéi lugng binh da chia mu thi nghiém; ‘msl khéi lvgng binh da chira mau thi nghiém va nude cAt; m4 la khéi lugng binh chira nuéc cat. 5.4 Xac djnh 46 4m cua than hoat tinh dang hat 5.4.1 Céch tién hanh Cn chinh xde 2 g than hoat tinh. Séy mau trong ti s4y 2h & 140 °C hog 3h & 110°C. BS ngugi mau trong binh hat 4m sau dé can that nhanh dé tranh sai s6 do anh hudng cia 46 Am khong khi. 10TCVN 9069:2012 5.4.2 Bidu thj két qua D6 4m cua than hoat tinh, tinh bang %, dec xac dinh theo c6ng thir sau: Khéi lveng mat di BO Am (%) = ————————- « 100 6) Khéi lugng ban dau 5.5 Xac inh dung trong cua than hoat tinh dang hat Dung trong ca than hoat tinh dang hat la gia tri trong long than tinh bang g ca 1 cm? than hoat tinh trong khéng khi. Dung trong than can duge higu chinh trén co sé a6 Am cia than hoat tinh. 5.5.1 Gach tién hanh = Dung cy xc dinh: Hinh 2 giéi thigu dung cy xdc dinh dung trong ctia than hoat tinh, Phéu chira va phéu rét duc lam bang thu tinh hodc kim loai. Can phai cé a9 chinh xac 161 thiéu 0,1 g. Kich thuéc tinh bang milimét 0 9 Phu cha kep 2 {oo .. , S SS _ Mang rung 8 ing kim loai Z Phu dink tuong Phi rét Rep vio gid da aia Sng dong 100m! os [Cet bang 29) Thank trin D127 107 a) Bin dp [a3 Ming rung bing kim tog! Hinh 2— Dung cy xéc dinh dung trong than hoat tinh = Cho tir tly mu than hoat tinh vao ph&u chira. Ding mang rung d8 cho than tir ph&u chira qua phéu rét vao 6ng dong €4 chia 46 voi luu Iwgng Ién hon 0,75 em’/s nhung phai nhé hon 1,0 ems cho dén vach 100 cm*. Bigu chinh Ivu Iueng than vao éng dong bang céch thay déi 66 déc cla mang rung, hodic bang cach nang [én hoc ha xuéng phéu chiva. Bua toan b6 Iuong than trong éng dong vao dia cn va cn véi a9 chinh xdc 0,1 g. 5.5.2 Bidu thj két qua Dung trong cla than hoat tinh dang hat ciia san pham khé tinh bang g/cm’, dug tinh theo céng thirc sau: Khéi lwgng than hoat tinh * (100 - % a6 am) Dung trong = —————4eng0ssi(“‘(‘(i«‘~*W (6)TCVN 9069:2012 5.6 Xac dinh thanh phan cap phéi c& hat cia than hoat tinh dang hat 5.6.1 Dung cy (a) Dung cy chia mau, (b) B@ rung sang, chay dién, c6 ding hd hen gid, kiéu Ro-Tap. (c) B6 sang, tiéu chudn. (d) Khay tiép nhan, phia dudi. (©) Nap day, sang trén cling. (f) Cn, c6 a9 chinh xdc t6i thigu 0,1 g. (g) Ban chai, bang soi ddng mam 6.6.2 Cach tién hanh - Lap rp cac sang vao bé rung sang theo thir ty c& mat sang tang dan ti dui lén trén. Mat sang nhé- nhdt va lén nhat ciia cdc sang phai phi hop véi kich thuéc ciia than hoat tinh theo quy dinh. - Tron déu mau. Néu thém vao hoa bét mau di tir 5 g tra én phai dao tron lai mau cho déng nhat - Cho mau 4a can vao sang trén cling. Bay np sang lai va cho may rung sang hoat dong. Thai gian Tung sang lién tye cho phép Id 3 min + 3 s. Nhdc sang ra khéi may rung rdi dé lugng than edn lai trong sang trén cing vao dla cn da trir bi va cn véi 4 chinh xéc la 0,1 g. Lan uot lap lai thao téc nay cho lvgng than trén mi sang cén lai va khay tiép nhan phia dudéi. Chai nhe 48 g& ra nhGng hat con mac lai trén méi sang. - Céng khéi Iugng than trén mdi sang va khay tiép nhan lai, néu téng khdi lveng c6 sai sé én hon 2,0 g so voi kh6i long mAu thi nghiém thi phai tin hanh thir lai. 5.6.3 Bidu thi két qua Phan tram than cén lai tran méi sang dug tinh theo céng thirc sau: Kh6i lwong than cdn lai trén sing x 100 % than cdn lai trén mBi sng = —$$ $$$ @ Téng khéi lugng than ~ Tir phan tram lung than hoat tinh cén lai trén méi sang, ta tinh toan dug phan tram tich lug Iot qua méi sang. Phan tram tich luf I9t qua mdi sng bing téng oc phan tram phan cén Iai trén méi sang (nhiing sang c& nhé hon) céng phan tram than & khay tiép nhan. = Vé biéu 48 cAp phéi vat ligu loc trén gidy logarit. Truc tung bidu thi % vat liéu loc lot qua méi sang, truc hoanh biu thi dung kinh mat sang, - Duong kinh higu dung ciia than tinh bang duéng kinh mat sang dé 10 % than Iot qua. Hé sé khéng dng nhdt UC tinh bang ty s6 deo/do.TCVN 9069:2012 §.7 Xac dinh 49 mai mon ciia than hoat tinh dang hat 6 mai mén cia than hoat tinh dang hat cé thé xac dinh bang phwong phap thi nghiém khudy mai mon ho&c bang phong phap thi nghiém mai mon Ro-Tap. 5.7.4 Phuong phép thi nghigm khudy mai mon La phurong phap xac dinh gid tri phan trim cén lai cia c& hat trung binh sau khi than bj mai mén do téc éng cia truc khudy hinh cht? T trong mot may khudy duge ché tao dic biét. 6.7.1.4 Dung cy = May sang, chay dién, o6 ddng hd hen gid, kibu Ro-Tap. - BO sang tiéu chudn. - Khay, tiép nhan phia duéi - Nap day, sing trén cung. = Cn, c6 49 chinh xac 0,1 g. - Ban chai, bang sqi dng mam. - May khudy: Chi tiét cAu tao may khudy theo Hinh 3. Thiét bi bao gdm mét true khudy hinh cht T, tam bang thép tron dyéng kinh 12,5 mm, khi hoat dong c6 s6 vong quay la (855 + 15) vong/min. Truc khudy va binh chiva dugc lam bang vat ligu thich hgp (thép, thép khéng ri ho&c dng). Truc khudy chir T phai duge thay thé khi chidu dai thanh ngang cia truc ng&n hon so v6i kich thuréc thiét ké 14 0,5 mm. 6.7.1.2 Cach tién hanh (a) Bat sang co dvéng kinh mat sang 2,35 mm én trén sang c6 durdng kinh mat sang 0,215 mm rdi dat len may rung sang. Ray khodng (250 + 300) mL than bing may rung sang lién tyc trong thoi gian (180 + 2) s. Loai bé phan cén lai & sang trén va phan lot qua sang duéi. (b) Cho Iwgng mau than hoat tinh (250 + 300) mL ké trén vao sang dau tién trong bé sang tiéu chudn. ‘Sang rung lin tuc trong thdi gian 15 min + 10 s. (c) Nhdc bé sang ra khdi may rung sang rdi cho Ivgng than cén lai trén sang vao dia can da triy bi rdi cn véi d6 chinh xac 0,1 g. Lan lvgt lap lai thao tac nay véi cdc sang cén Iai va khay tiép nhan phia dui, Chai nhe d8 go ra nhing hat cén mac lai trén mdi sang. Ghi lai kh6i lvgng mdi lan can phan than con lai trén méi sang va ting khéi leng than hoat tinh ciia tat cd cdc sang, (d) Gép tt ca Ivgng than clia tat ca cdc sang lai va dao tron nhe nhang trong binh chwva dung tich 1 L. Trut than vao may khudy mai mén. Cho may khuay hoat déng trong thdi gian (60 + 1) min. (e) 86 than trong may khudy mai mon ra va sang lai bang bd sang tiéu chuan twong ty nhw trong muc. (b). Dung may rung sang nhu da ding trong ln phan tich ban dau. Ghi lai khéi lweng phan than cén lai trén mdi sang va téng khéi lgng than clia tat cd cdc sang.TCVN 9069:2012 5.7.1.3 Bidu thi két qua Kich thuréc trung binh cila hat than ban dau va sau khi thi nghigm khudy mai mén (Dp), tinh bang mm, urge tinh theo céng thiFe (3) sau: LW xd) D = Se Ns ym) (8) - Binh xe truyén dong 7 D=100mm i Vong bi Bu long diéu chink Tdi ding Khoding 100mm one ng dng D=100mm | Han hop kim Hinh 3 - May khudy mai mon Khodng 150mm trong a6: W Ia khéi lugng phan than con lai trén sang thir i (g); Dy la gia tri trung binh cia kich thuéc mat sang clia hai sang lién nhau. Phan tram c& hat trung binh cén git lai duge sau thi nghigm khudy mai mén (Dy), tinh bang %, duoc tinh theo céng thtrc sau: (Dy ban dau — Dy sau thi nghiém khudy mai mén) DB a ) Dp ban dau 5.7.2 Phuong phap thi nghigm mai mén Ro - Tap La phuong phap xac dinh gia tr) phan tram con lai ciia c& hat trung binh sau khi than bj mai mén do tac 46ng cia nhtng vién bi thép trong may Ro-Tap. 8.7.2.4. Dung cy - Dung cy chia mau. - May rung sang Ro-Tap, chay dién, kém theo ddng hd hen gid. 14TCVN 9069:2012 - BO sang, tiéu chudn. - Khay, tiép nhan phia duoi. - Nap day, sang trén culng. - Cn, 06 46 chinh xéc 0,1 g. - Ban chai, bang soi ding mm. - Té hyp khay, dyng mau ding cho thi nghiém d6 mai mdn Ro-Tap: TS hop khay duge thé hién chi tiét trong Hinh 4. TS hop nay bao gdm mét chiéc nap Ro-Tap, cé nuit day, khay néng thanh thap; mot khay thi nghiém mai mén duge ché tao aac biét, va mét khay tiép nhan phia duéi. Chi tiét khay thi nghiém mai mon éuige thé hién trong Hinh 4, Can 10 vién bi thép c6 dong kinh 12,5 mm va 10 vién bi thép 06 dung kinh 19,05 mm. Cac vién bi thép phai dam bdo 46 nh&n. Nhéng vién bi nay dugc cho vao khay thi nghiém 46 mai man cling vei mau than 6.7.2.2 Cach tién hanh - Lap rap cdc sang vao bé rung sang theo thir ty c&’ mat sang tang dan tir dui lén trén. Mat sang nhd nhét va lén nhét cia cdc sang phai phi hgp véi kich thuc ctia than hoat tinh theo qui dinh. - Trén déu mau. Néu thém vao hode bét mau tlr 5 g tré lén phai trén lai mau cho déng nhat. - Cho mau da can vao sang trén cling. Rung sang véi thdi gian 10 min 3s. ~ Chuan bj s&n khay thi nghiém 4 mai mén cé chiva 10 vign bi cd dung kinh 12,5 mm va 10 vién bi éuéng kinh 19,05 mm. Nh4c sang ra khéi may rung sang Ro-Tap ri 48 long than can lai trong sang trén cling vao dia can da tri bi va cn véi d6 chinh xac la 0,1 g. Lan lugt lap lai thao t&c nay cho lweng than trén m&i sang cén lai va khay tiép nh&n phia duéi, Chai nhe 8 g& ra nhtng hat cdn mc lai trén mdi sang. Ghi Iai khéi lurgng than cén Iai trén mbi sang va téng khéi long than. ~ Cho tat cd than vao khay thi nghiém d6 mai mén. Té hep khay thi nghiém mai mén duge lap vao may rung Ro-Tap. T& hgp khay thi nghiém phai can bang va vira khit voi may Ro-Tap. Rung td hyp khay trong thdi gian 20 min + 10 s. Néu déng hd hen gi’ ty dong khéng dam bao dé chinh xc thi phai kiém soat qua trinh rung bang déng hé bam gidy. - Nhdc khay thi nghiém 46 mai mén ra khéi may Ro-Tap va cho vao b6 sang ban dau. Phia trén cung c6 thé ding mét sang tam cé duréng Kinh mét sang Ién hon so véi sang dau tién dé tach nhteng vién bi thép ra khdi than. Cac vién bi thép nay cing cé thé dug nhat ra khéi than bang tay. - Tién hanh lap lai qua trinh phan tich c4p phdi hat nh ban dau.TCVN 9069:2012 ‘Bon vi tinh bang milimét Thanh bang déng ‘Son va khung theo tiéu chudn Méi han 50 112.5} Hinh 4 - Chi tiét khay thi nghigm mai mon 5.7.2.3 Bidu thj két qua - Kich thuéc trung binh cia hat than ban dau va sau khi thi nghiém 46 mai mén Ro-Tap (Dp), tinh bang mm, duge tinh theo céng thire (4) sau: LW xd.) PSU) (10) trong 46: W [a khéi lugng phan than cén lai trén sang thi, g. la gia tri trung binh cila kich thuéc mat sng cia hai sang lién nhau. Lugng than trong khay tiép nhan khéng dug tinh dén trong céng thirc (4). - Phan trim c& hat trung binh cdn git lai durgc sau thi nghiém mai mén Ro-Tap (Dp), tinh bang %, dug tinh theo céng thirc sau: Dp sau thi nghiém 46 mai mon Ro-Tap Dg = —————_____—- x 100 (i) Dp ban dau 5.8 Xac dinh chi sé hdp phy iét cua than hoat tinh dang hat 6.8.1 Hoa chat va dung cy 16TCVN 9069:2012 - Axit HCI 5 %: Hoa tan 70 ml axit HCI 44m 4c trong 550 mi nuéc cat. - Dung dich natri thiosulfit NazS,0; 0,1N: Hoa tan 25 g Na,S,0;.5H,0 trong 1 L nuréc ct. Cho thém vai gigt Chloroform 48 han ché sy phn huy dung dich natri thiosulfit Na,S2O3 do vi khudn. Kiém tra néng d6 cia dung dich natrithiosulfit Na,S,03 bang dung dich KH(IOs)2 0,05M. Dung dich KH(IOs)2 0,1N duge chun bj nhu sau: S4y KH(!O;)2 trong 16 s4y tai 105 °C. 8 ngudi trong binh hit 4m. Can 3,249 g KH(IO,)2 va hoa tan trong 1 L nuée cat. ~ Dung dich iét: Hoa tan 12,7 g |. va 19,1 g KI trong mét long nuéc cét nhd khoang 25 mi. Tiép tuc pha thém nuéc cAt cho dii 1 L. Bao quan trong chai thu tinh mau 6 nut ham. Kiém tra ndng d6 cla dung dich iét bing dung dich natri thiosulfit NazS2Os 0, 1N. - Dung djch hé tinh bét: Tan 2,5 g hd tinh bét trong cdi dd véi mét Iugng nhé nude cét lanh. Sau a6 khudy hoa tan chung trong 1 L nuéc cAt va dé lang. Sir dung phan dung dich trong & phia trén. Bao quan dung dich hd tinh bét b&ing cach cho thém 1,25 g axit xalicylic vao 1 L dung dich. e) Gidy loc Whatman. f) Pipet, loai 10; 25; 50; 100 mL. 5.8.2 Cach tién hanh ~ Nghién that nhé than hoat tinh sao cho hon 95 % lugng than cé thé lot qua mat sang c6 dudng kinh 45 pm. Sau dé, sdy khé mét lugng than da nghidn nhé trong 2 h & 140°C hode trong 3 h & 110 °C. - Tuy thude vao loai than hoat tinh st dung, cn 1g dén 1,6 g than nghidn nhé a& s4y khd va cho vao binh thu tinh Erlenmeyer (Binh tam gidc) nit nhdm ¢6 hep cé dung tich 250 mL. Tiép 46, cho 10 mL. axit HCI 5 % vao va lc cho dén hi toan bé than ngdm nuéc. Dun s6i mAu trén bép dign trong thai gian 30s. = B& ngudi mu & nhigt 49 phdng. Cho thém vao 100 mL dung dich iét tiéu chudin 0,1 N rdi day kin va le manh trong 30 s. Tién hanh loc mu ngay bang gidy loc Whatman. ~ Loai bd 20 dén 30 mL nude mau lgc ban dau, phan can lai cho vao ¢éc thuy tinh va dung dita khudy thuy tinh khudy du mau. Dung pipet hut 50 mL nuéc loc mau cho vao binh tam giéc cé dung tich 250 mL. Chuan 46 50 mL nude loc mu véi dung dich natri thiosulfite NajS,03 0,1N cho dén khi mat mau vang. Thém 1 mL dung dich hé tinh bét va chudn 4 tiép cho dén khi hét mau xanh. Ghi thé tich dung dich natri thiosulfite NazS2O3 0,1N tiéu tn. CHU THICH: Dung krong hép phy cia than hoal tinh abi véi bAt ky mOt chat bj hdp phy nao s& phy thude vao ndng dO cia ‘chat bj hdp phy trong mdi trudng tiép xdc véi than hoat tinh. Khéi lugng m&u sir dung a8 thir nghiém phy thudc vao do host tinh ella than. Vi vay, nbng 46 du cia mu loc cn phai biét 68 c6 kha ning p dung mét hg sé éidu chinh pha hop v6i dinh ghia, Néu nhu néng a) du C tinh theo durong long cia phén mu ioc khong nm trong khodng 0,008 N + 0,0334 N nhu Ga hi trong Bang 3 thi cln phaitién hanh fai voi mot khdi lvgng mu Kha.TCVN 9069:2012 5.8.3 Bidu thi két qua Chi sé hp phy iét ola than hoat tinh dang hat durgc xac dinh theo cong thirc sau: Chi s6 hép phy Iét Xxp (12) trong dé: x A- (2,2 Bx mL dung dich thiosulit tiéu tén) ie Ana (13) m Trong lugng mu, g Nz x mL dung dich thiosulfittigu tn cs (14) 50 Im la s6 mg it dug hdp phy bdi 1 g than hoat tinh. N; la ndng 66 dong lweng cila dung dich it. Nz a ndng 66 dong lveng ciia dung dich natti thiosutft. A= Nix 12693. B=Npx 126,93. CC landng a6 dong long cia phan nec loc mau cn lai. D lahé s6 higu chinh duge ly theo Bang 3. Ghi cha: Cach sth dung bang 3 Cot dau va hang dau cia bang 3 lan luot tong tng 1a cc gid tri phan nghin va phan chyc nghin cia gid tri C. Lay vi dy khi tim @urgc gid trj cla C 1a 0,0094 ta lam nhu sau: Tir c6t 1 tim gid tri 0,009 giéng sang phwong ngang, tir hang 1 tim gid tri 0,0004 giéng xuéng duéi dug diém giao cat gifra hang va cét. Biém giao cat nay chinh la gid tri D can tim.TCVN 9069:2012 Bang 3- Hé sé higu chinh D c 0,0000 |0,0001 |0,0002 |0,0003 |0,0004 |0,0005 |0,0006 |0,0007 |0,0008 | 0,0009 0,0080 |1,1625 | 1,1613 | 1,1600 | 1,1575 |1,1550 | 1,1538 |1,1513 |1,1500 | 1,1475 | 1,1463 0,0090 |1,1438 | 14,1425 |1,1400 |1,1375 |1,1363 /1,1350 |1,1325 |1,1300 |1,1288 /1,1275 0,0100 |1,1250 |1,1238 |1,1225 |1,1213 |1,1200 |1,1175 |1,1163 | 1,1150 |1,1138 |1,1113 0,0140 |1,1100 |1,1088 |1,1075 |1,1063 |1,1038 |1,1025 |1,1000 | 1,0988 |1,0975 |1,0963 0,0120 |1,0950 |1,0938 |1,0925 | 1,0900 | 1,0888 | 1,0875 |1,0863 | 1,0850 | 1,0838 | 1,0825 0,0130 |1,0800 | 10788 |1,0775 |1,0763 | 1,0750 |1,0738 |1,0725 |1,0713 |1,0700 | 1,0688 0,0140 | 1,0675 | 1,0663 |1,0650 |1,0625 | 1,0613 |1,0600 | 1,0588 | 1,0575 | 1,0563 | 1,0550 0,0150 |1,0538 |1,0525 |1,0513 |1,0500 |1,0488 |1,0475 | 1,0463 |1,0450 |1,0438 | 1,0425 0,0160 |1,0413 | 1,0400 | 1,0388 | 1,0375 |1,0375 |1,0363 |1,0350 | 1,0333 | 1,0325 |1,0313 0,0170 |1,0300 | 1,0288 |1,0275 |1,0263 |1,0250 | 1,0245 |1,0238 | 1,0225 | 1,0208 | 1,0200 0,0180 |1,0200 | 1,0188 | 1,0175 |1,0163 |1,0150 | 1,0144 | 1,0138 |1,0125 |1,0125 | 1,0113 0,0190 |1,0100 | 10088 | 1,0075 |1,0075 |1,0063 | 1,0050 | 1,0050 | 1,0038 | 1,0025 | 1,0025 0,0200 |1,0013 | 1,0000 | 1,0000 |0,9988 |0,9975 |0,9975 |0,9963 |0,9950 |0,9950 /0,9938 0,0210 |0,9938 |0,9925 |0,9925 |0,9913 |0,9900 |0,9900 | 0,9888 |0,9875 |0,9875 |0,9863 0,0220 |0,9863 |0,9850 |0,9850 |0,9838 |0,9825 |0,9825 |0,9813 |0,9813 |0,9800 | 0,9788 —t 0,0230 |0,9788 |0,9775 |0,9775 |0,9763 |0,9763 |0,9750 |0,9750 |0,9738 |0,9738 |0,9725 0,0240 |0,9725 |0,9708 |0,9700 |0,9700 |0,9688 | 0,9688 |0,9675 |0,9675 |0,9663 /0,9663 0,0250 |0,9650 /0,9650 |0,9638 |0,9638 | 0.9625 /0,9625 |0,9613 |0,9613 |0,9606 |0,9600 0,0260 |0,9600 |0,9588 |0,9588 /0,9575 |0,9575 |0,9563 |0,9563 |0,9550 |0,9550 |0,9538 0,0270 |0,9538 |0,9525 | 0,9525 |0,9519 |0,9513 |0,9513 |0,9506 |0,9500 |0,9500 | 0,9488 0,0280 |0,9488 |0,9475 |0,9475 |0,9463 |0,9463 /0,9463 |0,9450 |0,9450 |0,9438 | 0,9438 0,0290 |0,9425 |0,9425 |0,9425 |0,9413 |0,9413 |0,9400 |0,9400 |0,9394 /0,9388 | 0,9388 0,0300 |0,9375 |0,9375 |0,9375 |0,9363 |0,9363 |0,9363 |0,9363 |0,9350 |0,9350 |0,9346 0,0310 |0,9333 |0,9333 |0,9325 |0,9325 |0,9325 |0,9319 |0,9313 |0,9213 |0,9300 | 0,9300 0,0320 |0,9300 |0,9294 |0,9288 |0,9288 |0,9280 |0,9275 |0,9275 |0,9275 |0,9270 | 0,9270 0,0330 |0,9263 |0,9263 |0,9257 |0,9250 |0,9250