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(A)
(B)
(C )
(D)
Q.2 Hyperconjugation is best described as (A) delocalization of electrons into a nearby empty orbital (B) delocalization of electrons into a nearby empty orbital (C) the effect of alkyl groups donating a small amount of electron density inductively into a carbocation (D) the migration of a carbon or hydrogen from one carbocation to another Q.3 The observed dipole moment of Nitromethane is higher than the dipole moment calculated from its structural descriptions. It is because of ? (A) Hyperconjugation (C ) Inductive effect (B) Resonance (D) None of the above
(I)
(II)
(III)
(IV)
(B) II < IV < III < I (D) I < II < III < IV
(a)
(b)
(d)
>
>
>
Q.7 Hyperconjugation can not be used to explain following(A) Stability of carbocations (C ) E.S. in arenes (B) Stability of free radicals (D) Stability of carbanions
Q.8 Arrange following free radicals in increasing order of no-bond resonance structures
(I)
(II)
(III)
(B) III > II > I (D) All have same no. of structures
Q.9 The kind of delocalization involving sigma bond orbitals is called(A) Inductive effect (C ) Electromeric effect Q.10 Which is more stable ? (I) CH3 C CH3
CH3
SOLUTIONS (HYPERCONJUGATION)
Ans.1 Stability of alkene no. of Hyperconjugative structures no. of H
In
Ans.3 Due to following Hyperconjugative structure, distance between the charges is increased which results in higher dipole moment (=qd)
etc.
Ans.4 Alkyl groups are o, p-directing due to Hyperconjugation Hyperconjugative effect of alkyl group increases in the following order which also determine the increasing order of electrophilic substitution at o, p-positions.
CH 3 | C | CH 3 CH 3 | H C | CH 3 H | H C | CH 3
CH 3
<
<
< CH3
Ans.5 Stability of alkene No. of Hydrogens. Ans.6 Stability of carboncation no. of Hyperconjugative structure no. of Hydrogen Ans.7 Hyperconjugation is the delocalisation of electrons into nearby empty orbital. But in case of carbanion there is no. empty orbital to receive electrons. Ans.8 More the Hyperconjugative structures, Greater is the stability of free radicals. Ans.9 By definition. Ans.10 CD is bond stronger than CH bonds resulting in difficult delocalization of electrons of CD bond into empty 'p' orbital.