Department: chemistry Year: Second Level Students Term: Second, 2009/2010 .Time Allowed: 20 min Total point: 10 ...................:.

Name: . Section:Seat no First test I) Select the correct answer and list it in the appropriate box given below: 1) The correct order according to increase in pH: a) HNO3 < CH3COONa < NaNO3 b) HCl < NaCl < NH4Cl c) CH3COOH < NaCl < NH4Cl d) H2SO4 < NH4NO3 < CH3COONa 2) The colour of M.O indicator in each of 0.1 N HCl, 0.3 N Na2CO3 and 5% NaCl is , . and respectively. a) yellow, orange, red b) colorless, pink, colorless c) red, yellow, orange d) yellow, red, orange 3) These properties are of primary standard substances except a) low equivalent weight b) high purity c) inexpensive d) nontoxic 4) 0.64 g of impure Na2CO3 sample was dissolved and titrated to phenolphthalein end point with 21.5 ml of 0.25 N HCl. The percentage of Na2CO3 in the sample is (At.wt: Na = 23, C= 12, O = 16, H = 1) a) 1.78 % b) 98.2 % c) 44.5 % d) 89.0 % Question Answer 1 2 3 4

II) Complete the following and list it in the appropriate box given below: 5) One equivalent of NaHCO3 is detected by titration against HCl using . .as indicator. 6) The number of milliliters of H2O must be added to 200.0 ml of 0.100 N acid to make it exactly 0.0800 N is 7) The pH of NaCl solution is.. 8) 10 ml of a mixture of H3PO4 and NaH2PO4 were titrated with 0.1 N NaOH and required 7 ml. to reach a M.O. end point. Another 10 ml mixture required 19 ml. NaOH to reach a ph.ph end point. The normalities of H3PO4 and NaH2PO4 are..& respectively.

Question Answer

5 indicator

6 ml (H2O)

7 pH =

8 N (H3PO4) =. N (NaH2PO4) =

Department: chemistry Year: Second Level Students Term: Second, 2009/2010 .Time Allowed: 20 min Total point: 10 ...................:.Name: . Section:Seat no First test I) Complete the following and list it in the appropriate box given below: 1) The number of milliliters of H2O must be added to 200.0 ml of 0.100 N acid to make it exactly 0.0800 N is 2) One equivalent of NaHCO3 is detected by titration against HCl using . .as indicator. 3) The pH of NaCl solution is.. 4) 10 ml of a mixture of H3PO4 and NaH2PO4 were titrated with 0.1 N NaOH and required 7 ml. to reach a M.O. end point. Another 10 ml mixture required 19 ml. NaOH to reach a ph.ph end point. The normalities of H3PO4 and NaH2PO4 are..& respectively. Question 1 2 3 4 Answer ml pH = N (H3PO4) =. (H2O) indicator N (NaH2PO4) = II) Select the correct answer and list it in the appropriate box given below: 5) The correct order according to increase in pH: a) HNO3 < CH3COONa < NaNO3 b) HCl < NaCl < NH4Cl c) H2SO4 < NH4NO3 < CH3COONa d) CH3COOH < NaCl < NH4Cl 6) The colour of M.O indicator in each of 0.1 N HCl, 0.3 N Na2CO3 and 5% NaCl is , . and respectively. a) yellow, orange, red b) yellow, red, orange c) colorless, pink, colorless d) red, yellow, orange 7) These properties are of primary standard substances except a) inexpensive b) high purity c) low equivalent weight

d) nontoxic

8) 0.64 g of impure Na2CO3 sample was dissolved and titrated to phenolphthalein end point with 21.5 ml of 0.25 N HCl. The percentage of Na2CO3 in the sample is.(At.wt: Na = 23, C= 12, O = 16, H = 1) a) 1.78 % b) 89.0 % c) 44.5 % d) 98.2 % Question Answer 5 6 7 8