Exercce1( 7) Repose pr vu ou fax ux affirmations. est fixde 830°C, R831 yet independ eT et dP; temperate de exe Iori oer indépendats dela composition el A ; sone factions mola. —— Dube gatas paride enthalpie bre. En Gedue les coeficiems ’atvité des espeves A et B sont tivités de A et de B et de la relation (i), sen déduie la relation lint les coefficients a1 (ne dépend que de le température comme les Bonne chance170) : XA tid seal opie tens AS, Ve decal de et SCV, 1 a a, ‘ni espero de ($8) en con de (2), : 2 Deri a vrinion de einem dm mcs eg fcion de ton Wlume ei pase Vs Ve dtcmpss conte par Demis POAIK Genii) Shediea SA: ” Gy tll) = tS maa, Stee asec Seep a saat ee Erion ade tI: A 610s eck? ose mes et . See onion nae see Afaceri en Ney oer Sic it rete i wares a ose Bes ted acne pia ee a eee i pena cian ced we tite go.) --nepi—mpptamurner, 2 Pete dr Sorte re an Peet a ces cet nae ee 7 Ae ce peta et lea mpi ini, a i ie re Gem eaten eh tons er ene pt tar me nt a ge tn Pawel - te aa etd ine ang colette lic exo wn coe cai mmaferaton iri Coen ine dete afemion Donates :Crgps) mF Coe) =": JoreiO'Pa 4 Sua ‘cx “es we Tee© ce meet wn volume de $i. & Sree Sie ue en ps aur pra, exit peer 27%; sous 1013 Le ac yi ce que son volume soit Sal. SL GEES oer verebleneat oe mnie ene jo js 3) Sete epee pression aes is as Se inl Scag eve exti Ia variation de énergie interne et le mi 85) © © fish rhaab ase se Sie tle ne Ae ea inh hao ote np ya ca < bem bet hia td oie heat bie i ct 2 . SaaS AM eee arene ee ee” 7 See ee enn mG, wea no o ian i ins de tite mv do At de cd ton, deminer ce Sate gp ae te Codi cy Ge ae Cement teal lpr omnes denim ape ag or inane hwcware, Semin wo exreson snpliite de bay, ty, ealarcde " Peep sae dena erg 7 doa pesca Dernsne Eo = 70). Serhan ere a ee eating de acaage. : Tete =le Sta -/ Gsy MS, — | = — température 3 Decne sn de pi elie hy Petparée & partir d'un mélange de deux espices. Pour une es solutions parfsites. A 30°C, la ‘3 comporteat comme Les mélanges beazsne-toluéneLge deninea pe | wort ne ‘Us fonction thormodynamique E dépead de V 1 parle tcement Tle eee on ern [i sei Bir Ae cota be rn duel ($5), { eee eee cae ) am PACE et RENO dans le journal cheney physical volume 48 page 1231 de 1968 doonaeat ke ‘oulats dos meres de capaci calrifiqn do frre decry (COF,) consign dase ables Dawofes relatives mm inst de + Feel OLAS Ao 7 FerhBh SEK; AB yeaa Fane agraso popu, erp cana stole use Ty dy iguid 8 Ty; rH st Tyce ba vapeur a Te Sie eer scene corde cme ppc on dt Fe ete SCL mol ber ei pac, Ce ee a een \Exercise 1( 112) (On realise une ‘catone 2) escrowME paver ne ae dehere fas ders cee XK Come OU deaane Oariiin Ze nies cetate OMa sideow de yal 17 celal me? season we ae 2 es Gretta niget nnore 3T ete ‘im, sachant «que. ce gaz_—(beit a voor Stee 2 (-<38)} 2. Douner le coeficca de fugacité de ce pxz Ala pression de SOD op ee f > P Dundes: Pout une male de gaz a Sade: BSR -ART fd’ = So, AP » uot soypeien tgaureencnoan D Q tres © D rane Tae On xr de Van det Waa Ge diorpize) sont eafeamés dans ua récineat de fume V. Pour une mole de ce gaag'Péigbition de Van der Waals est (r )=RT @psss @ &) (fone) {Dans le as d'un melange tai, apple la formule de volume molar partie apparent ‘i. Ce demir permet ava wee pare mol ven précisnt la pate de ta court F | { | | i i i !er sour | ‘TRAVAUX DIRIGES DE THERMODYNAMIQUE 2012-20 ui DE, 13) ICENCE DE, CHIMIE/SCTENCES PHYSIOUES Ce i ite ean hae Fo er oe ei sven par SPC wm peo canine, tempt de cougon ot = spain deol Lea pare ge 8273 13K a but er CP Seed LO) Top RAIA) pesercice2 \fCOAD SNE i, puonlinomotcazine et Je parndichlorobenzine foment une solton 5 icine reson tole coaune le mouse le ublem deans. ian Oteea] Ase] iE - #10120 Tao [570 : Dein eons de Vapi des dex corps AY iat preter la sion apour de chaque constant ‘dans le mélange pour we fraction molzire de =" ~ a 2a } Lid Beast é i thi a oe nanan ana “opertre cxstate (35°), a cour de presion totale en fonction de Pune des a a‘enti ee ext mation Ge Ane + i : te pres oad g 3a! oN : . . ag: ! . as eae: .AVAUX DLRTGES pe THEAMODyNAMT GU E]{. Glue Exeecrcey [ Can end ab J Asan Ghat itis gen nol ar ee fo Ht =Aootn fr Asin fis are 7? Ep (2 9 i} Vis? — Mee ' } Ealealews Jo nwriction. a Qonrait intrmu, ft avadl dp ie rls on fe bbl potat fajor fm roibaus! AU = G+W Com mi ado alabaliges ole F=4 ap prac racic cinta poems Lt. galon mpe Ps ya aire pecceamiern Las dg ablb2) A botatet: | Au=-Sp dv} pd =)pod Te Jecr=ofe- ) Conve homie in sbbAlpe pevosill on post pp be fae de Lape. _ AME pve she oe Le ae =H epi = egfe = TFs ar ie > wee ve He Tek “7-(2) aT 45 8 = o| (EY 5 _T_tic, PEET® diel) RB m6) Yeo: Cp ys 2° Ca te= woeee ee Teva gp w Wa at 2k FL w Au! A= 3004s [eel a]= -S4A 70 MAu= MU = W=-5¢4 Folal = -2U64,30 Wy Leaders ba anrshi by Porarege bre, prweratl uf Le luh mo on wae o sd poshet fin sbabalip oO tgmfort OES =) Ye [or wv [freon otl=OF P = $64 704G AE = ~2U6G309 ° Camme Tack w Y= a aw B= op (g4W=0 WY W=-W wa-factr=-[[nv=| ('ggav= -eff ert | puemerae QM eme=cle » Pai = LE cmea — Met DP ycn atin | ant we 2 oe >| We eb | at We sce h We -43 14550; Qe w= 4384, ssl | Conderion': B= 0, G2 : om apagie unbsrire, Be 2 Colaba bs worse BIT muaondl | rowed gt Be -cholean mf aa “Aus @+W yelp = 06 Comme fhanadermalion adiabetint R= ee a AU= W=-fy (\y-Ve) = GCR-T) | PY RTE = y= SE gmei fh poWyse(B% Pick oy, | eg e) E Be *(6- tg) Gp +kT = Gh + RAT Cv (eT) = - Per F-| % S petperatstoN be debut rnp ion taethaner * Drom, jn Sperone bavlher Ine Ta Aba GoW AN = 6 Cor Mo CrdT sb rcty RtW=0 Wa-y W= -P (- ae & Droyodl of La vantne M=0, W=- y= suo etEXERCICER, 9) Clad be a capaci online de Moin Ona’ [Se=mern | Me ~ ort Le membre de mmol. detorn noma a mah = Tee erm ym ie = Plan Ve Be a AGOK FKL 34 AL! o> Ta ERE | [ehctommens fa prrrien, fe ardlame of ba dam proir , dann thocun hr Hab Av 3 elf fix 4 bor i= RT ehle fesdrog gual [i aR Spa = Ale 3 Any el Etats eee => Vp= OB————— 3 346x334X3% —y [ws yaeent F — RAs fbn per ane f= bd mal yee Ns <0, 503.00 [Es Gybx 834xAbow ar Tyee] AW: (28 =o =f = the bar some =% Jamar ao 7 Weatee 5 s_ pb veck ~ pV=Re a\~ he YH MT ~ 36, 64531 [f= abe waa eck(Um DHA Qe kas es yiat id demn or WW Sa | Wt Wyaet Wea c| | We War ns p= net i yoneT Sw= ~plv + W, =) le | etedo Wa =~ RAT iy = -merpiov | Waa etn Ve) Lx oMAT (inh, — Sts) | | wo reat dnt | ‘ | cee ANS Waa > 34, 6x wong oA ace! Aah We “fe pav= | 4 Weas= “fe (We) = 7 4) W.= 5 fox M55-0 5 [was 32205 a bey AU= Wl) | Wy aS Jina. ar tea Cea fen = MG IT LT) ae wt Ou bi ekedsllet Zi tad cer geet y poo Not W, : “ply = -p | dv wn Rah (Joobers)) ne Wan = (nai ~4, 0066) $e We (409-302-454 +42a)r0 9 > We ~22 85] ——— «ddomnos Cth san cowry Ja tre ba thom prmclioo 2 —3 é mbit ra pet ale da -doaladie peste cedeel Q= Qe TG sreny,)its alpette 2) x Biba KPBS A(thew oe Ms > Waa => p, Vs) = fs WW) <4 Rend vnent de Covet > per Spex ues Avo spel hansen: onnpl jmbovne AU at oclle cle hen he wwrretiom do 2! ork He AS Mx = 260,37 gh Tot oor Truanafrvnation jrthoune on remap iimetion ine thane | (Tae tects cle) dus oa aware?’ wy SQ =- SW een ee dy Ws gineg lim aes Woo, = WRI dn j $=" r i 15 =~ WRAY | gy fs = 54 boda ne os g )A3 = -593, ay AgeAs sa8(1,-th) : ( 43, iz L| 4b - 134,608 34 (ahoo 350) & MN A = Sx3f/ 6002" | wy A =F 6505 Wy 2G.aT ds= $e A 3Gp= He ? 3 * a= [sz |" tadra neq) A as ie T $= My, Ink aa 43 fim = 7 Ze Sn fy OAS = Fete baths iy At 45 = Rebus sin se ee tan lt ethibe tipes 4u~ NG “he _ TA8 (T-%) s Mo : | in TY Stay] Al ~4be0)PO) ion 2 Mobodiay | a Qz oF 7 49,= 0314] foavijn nie Yaa reba Raronant ionbans bag nore nate Wom (ToT) AD = ee (30-474 25) s De - 3,04. é5| \ds= (‘su | 8g= dang“ % 4 T. : AS=)mop, it ot YF Cm e { a dn 32 350 AS= yank BM f5 10% 04" Fair ¢ ee r et Lad ape beeps | ie ti Ga fe he ee 4 AD mop emergea Au= ©5 : : N cla pwaalion of Mansregse aeharons ott nag” clon Lamang shores ports snchoogrt In, Aa Mena don woo Gy bias, iS iss (Ss UB A) AL 1H) ay bd AS = S396 44-4 19S bg 07 FIED | aS$= OTK Sa pwreaternd whe Cone pe 2 pruble lone A endlragic paste cn 2h La cours det Cel Ass Act snd £2) EXER CECE 2 #8 % -5é) detormimens fe awristion Meidrops meio elt Mieeu Apen _ we oe Hb (4-se) Bo Mob.) la ae 4s, AiO, Ii ANE, K) ae Lp. ee q is ue AS ='A5,+ 8,0 45, dctommow? JS,* cpg ST = 7 \ CHa = Cp dn “ CS a cf ¥ al® n DG, =) 8 = E(5q er Tete bed = T ip = ah AS.2 Ah ~ At _ iv 192 \ 2 = Vepuae = Cpey Wn ; ele 4 -AS= Cp@lnB + Crying — Se 1 1 ESAS) 983.40 An! bs=(95s1-386) hn (Zea) gaa 1 pon drys mi ay mina eae peeorn atone iw Baz | ~ Allg bl 2,2 Als = Me tts At, AN,= [tags = GO?) Noe -2444 oki id Gyo | dr = Cyn) (Te-Te) = ~Cpen (Fs DHsas= Sey (RT) AN ce "fant (273.416 2689-5 9938 +3246 (265, 15-973, oy Fawtigt ‘| As 15, =Gi5),,+ Ae)uys Ai = 05," Be EREHCEY 0 Chexbeno La “h, Fagoct de nalere ASo’e A, sare. res ee °F callion ce Borthalyt. joer lea, FRO H)eV a G=G sc nerbof ‘tT 2G) = (26 + npr glad) 7 6'- br) [Z=- a BF pn bb apne: 36 | ~~ NE meray + pea(ogy Pac |= mar(+3. 4 (4-6 ' x c= (B'S), Vz mer(s +4) a 4 Adp, » Gedhke i Vdp = MAT Sf + MAT x eee) ‘ rca pau P) ais= peers p Hale } 14 ! Oise OFF wee J vd =meT|, gions I p ot nese p “gg ae wih j= “He de ee de,aldp % (im a yas op mined 2¢ poe lt-P) f ae t) : af xt = goehp 20 f. x «par ba) PoP te fp p tpece Clay APF)fap (Peateyy. A Tock: ban = 4645 atm Ly) fe Corfe’ ae pops ven yt 9 VE eter. ART (mbye =) Vp = 29°4 dy- RTI Tidy een] VeV4V" { fe so ie Af “shel preer(agxpl= 27 ve (ow) = 2y8 Fea) Vs BE 4 1a pe pacts 7B et i (mmbn ae dy +z ata dy V3 TT fon Lanter yeVdp = maT ding mar dly= Vee H t= & ? =~ mat) Ne iv 2a “parish a jp ve We if Re G ~ mar) Mand = ise dv mer val ; ve fetiemb . by V 2 Vin} zan\ ot - | ean aT LE my Wee) f : b) _ A 4 Bae ae Py rant a Gy : 48 Ax Bl- Tbe gv+ Ar VN =o by? &F ~mb)” car en Ce Cor ida ot te 4 A- mbe=e ov [A= abss we d > se Sane prey 4 Be Fu 4 # =H 1 i aieaia _ Wee ata L ee a2. 32 woe EP PS af <5 tS i eote|8 |» au a d c € 1 “~ fb Fre F = © ~~ ie F = Pe cs 3 + “1 Wen js) Exercice ¢ D dome be od Alun on ot A wee le da orlune q ae ie V= mV ea oa. mV | EW lt veal =| = da " pikieant a, > a pov See Eo 1 Doht po, pz 4th : t A= “ft z w cb am enbrew> ba pdulion fo ba nts tums Ai ot ak! a ” Hed) Mie ue i Gaia 1 pz dmogge di he gd 1Mg aa te) 2 ddd dee, Da Jno a = pase oe A =a wv a) aml ilaes ee sh—Vee tale snot bi ag a tar fur defailion, — QV a! fe + on, > A f de als til an us = etn mallee = hath, | 4 Me fy, (i, ae =RTIn¥, %95¢ ve eee EXERCECEF thovanion ond Swropen: fends Bop er Panos ison feces AX be UAB eco pe ; 1 yghsembe de je Law (vdeoed AU i nena ds nde 4 fivcce aig apslvins fatok - pc cee Bote _fepinecm Bo 5 vs oi Visa rhe de Me a ne oe uoim WV, mee Mon Jre ma ‘molars! byw, an OK Sox ip ter ho prion peelere Himes 2k {pubs Le RS 0, - MMe S58 +9 — 25 be ~My ty Ah a= sos Gre G, ee Se bowl ot Ub pee - “conn arts ot plate » Ty = AFG Oot oe mA} ire y A 8OR ) ; a donc we pos pablo 2b e vie b fifo Sugnteas%Vz As Bim scm table's con a/b vdeo DLaeuminens Ve fon Adintien viet - milion: Ve BV. aw BS tascmicm oe a SRI ame am ) ec Be Su, 832 otc 264334 Va = $1, 382. 42x6,134 im Ve 54 F3z< 02753 /m| «Ve eo Abdan Ld, 5 N= Navy +n Vy, | Mal, = VV, & Vy Vem = Hh = avec Va Ap amecm® ef K= BMC Vx Axbm+c oi m(h e€mc) My Vy = At bin-bm + Cm mc gss—oA3S4ai A8054 -4,Exercrccs ede sa _cbirigges et fer defination Tae Re id =f +kTUn p: SAi + RAMP Tr) ye BM ww dae [c= Mi = KTdnpe Rng, A N~ + RTAac ) SAE FTN Ce) ‘3 j « Cob iak . d ws de (CA poy a + Rid Be pr peru et | |e prents aT ote BM" T= 308 k Ve Als Aire. = AB" mode He Pox debs a8 = ~414. 408 Bren rood ADKg sta ° 1 (e) ADKGeo wey jal Cos) = loys Siler fool G : AN! G = AOKe4F2u5)+ seen) —" - G2 754503 | - } t- 7 7 : Mut + Wg * HO ahovmmine £ moni ce amie se chaps nelle “SH hens Jin ivan de mr. 1M = Mt oct Mie, Worse Be Meow emit: My ‘as Me ® Wag ag Crag Vem: Ape = By sce sed Mest e175 Gf yp = me mu = Ave Sve ~BA4FS y= gga tes Ne yap Qo. call + o- | M (nag) ~ MUM) = Me) 8g = 5 a im ° ; ~f ~~ ° 3 a ect) = Coe gxVem =o SS Ad = sso mil Guo = axssosssateay (C2? Serkan Ala dow midien Wile Le wrelume mikaire sie retract 4a (HeOe) Vi < VO. — Min = md or fe Heo fe I) ra) = % Fino * 0 = Miho ti,0 = nO § thd ox N20 Ming Mw ead Doe Angie Jame fc 7 _ by [nck “gil \ rn Aa, ug [00 I> tet o+2 T 4, fh r 8 34h boo Anos) sBare F EXavwg \ 1) tro keaton de wre pore (Ri) fogs a obion’ apr’ Get fa = AVeblient quand Ga a Contrwcnomo en poncho t poradibrermobomysme“C2) 4 Pim perotichbrckengens pie 42% oatne Ys Or debris 7 et en on ‘ inant tans Qectiw dowd 5 be mele 3 en ditounine 1 Peers fete io F ' fo bre: : Poona 052885 I fe =n Gxoe E85 = BSF mmiy. =~ LEROY BT monly (Loabern he dampen dy ov. carne Aaro fe wnalange fase Comme pdudion gorfute (dhe gi foot opp 2 poor bot fr = Pubs = (Se fradkion me A ’ an = Iho aw madetone Oe Soba poe . yg (neon A éulr) We Zmpmitls Mas Di day +E jamaTas a's SP adn gy eh — TARE Si= Sdn Si - RTA OT oee & = -Aoi ee ._ gTony SinS = Rn Vi - RTA & | ~RIny, -aTadi — 0 | IT a An = adn _ In aT ] @ © dump , aH at weve Te “Ce ee Bhi. Ins kT* T Ke-hi nh eR_ssommig ) Ccny Soa f= |e -i %- al Y= 5 50— A345 Goo 4 A a =-(asr2t 3x An(4375) rly A ‘WY; +PT OMY; - 0 ' QT \ TOS _ wy: py eS bavi : y; a oT Tr mn he Sha pAv x ia eS jExencie 6 dl Acdbemonben apr a lack pics fa 6 pont ult . \ fay (4) va par he fen ae Atul gin eh ot th (4 fe + RTE de pebben de Gibho ~Vdp + 8dT4 ¥ aed a Tetp pants doe gin DE +L, ediion Le G smd a zudu ar dum? Yi dffounliow a (Lo ’ bs pth 07 18 2. he Wr er ande doi a ~ ali Kr ee Gt so a oda TET(ET 2hdchCidui= = Zot er pati Aoi eeraiebg)=° Tee = Lu(ersy robe SLi)=? ZO Ym =T are vearcsbint. it =0 Bo ~) zd t cork duso asdase Qn dt =2 ER 3 ‘ Ty 2he dt 2Taab) F(A _ lb tia babe. opis (te) Ma pebsrg ES 205 yefElmeoreati) @- Go) 4 ~9Af4-Ty)) # Lb +2b,6)= © : 7 04-24, (1-0) + Ugly # Aga A-bs) + Oph t2h.G, = HB ~ 2a + UG # Elly + LAT 5 Wa Tete Tahar 2h ak ~99\ TEIN ath T, — 4+-79AL =—— we bin om pal wcladiicen : Tq ene _G, doh — 6 OGa ats Gr (2 4#2060a) ~ To by x abrba) = © AN SBUTH —baTg rhb =o AAA G) 4 28e(4- Te by Gy -2be Gee | a aay + 24,4 ~205¢%5) 4G 2, Bea Ss | Ga Gy 4 ay | 720s, wD % 2h ac OTR FET og Ey 2B? © | 5 = | Cartan byzg + (2h Be afer =o = be 2h ba=% th - 24,= 0 A ~ Jaggi thee ~ au, = 2h Aq - ih, = nh +b, =Jeni, = be -2&G5 EP Gz 4 ) Bat ~ Oz be-2etk @ + kn = RU ho ~kG-riaeEe a ~ 7 ~ SPA" a iny, ~RTDIME, poeta gy? Je gos gee eantp & = Siig -R Bie) — In ¥W “ying = % LMT;ey Aa pact on cn eT, b [Arm Weert; + J sors ern ¥i : icp a doy 2 4 Lemp PD =F KTM: (bain) = ATE Wilms ty) = 8 alls, « PB) My lnty + S-7) =RMg(Thn Pete Rf Ung + elt, a, 7 Lf) +00 (ringer ¢ a) sabe Ly dee mbar ge Ge CO ei S 6" ag" ar 7 ah (ps) & sees wwelabion 19 ena “7 / I = |,a ~ Rrafrdnz, 4 ch ~ TY) > Ri ngs fat Radin ty + en ) 7 i a | FT = RYN~ac @-T)+R ne (A | owt 7 TPE se Tho ot ere & a a . (tt ar 7 5) 6 A BHO ante 8 “os ath t/ OT fet c(h eden BBso gue | 1 AT nF) = Soni [ert exe( G'] eek AtB = = : Ga [erhaty=Pels-Cay] ra [Dee poe a H G =G-G GY sailptpt) cor Mx MentorsSse) = SAE i+ RTA) Si fer dag) =Lin.(arhngi) & WSS (4-T) = UmfRe(a-G)* G"=m, [ee(4- Ca) % me [e(4-Ta)*]