C. Y.

Yeung (AL Chemistry)

F6 AL Chemistry (Tutorial 2)
Name: _________________ (I) 1. Multiple Choices The enthalpy changes for two reactions are given by the equations below: 2Fe(s) + C(s) + Class: ________ ( ) Date: __________

3 O 2(g) Fe2O3(s) 2

H = -822 kJ mol-1 H = -110 kJ mol-1

1 O 2(g) CO (g) 2

What is the enthalpy change for the following reaction? 3C(s) + Fe2O3(s) 2Fe(s) + 3CO(g) A. +712 kJ mol-1 B. +492 kJ mol-1 C. 492 kJ mol-1 D. 712 kJ mol-1 2. An enthalpy profile is shown below: enthalpy

y
reactants

x
products reaction coordinate What is the activation energy of the reverse reaction? A. x 3. B. y C. (x+y) D. (x-y)

Which one of the following equations correctly defines the enthalpy change of formation of carbon monoxide? A. C. C(g) +

1 O 2(g) CO(g) 2
D.

B. C(s) +

C(s) + O(g) CO(g)

C(s) + CO2(g) 2CO(g)

1 O 2(g) CO(g) 2

4.

The enthalpy changes of formation of gaseous ethene and gaseous ethane are 52 kJ mol-1 and 85 kJ mol-1 respectively at 298 K. What is the enthalpy change of the reaction at 298 K for the following process? C2H4(g) + H2(g) C2H6(g) A. -137 kJ mol-1 B. -33 kJ mol-1 C. 33 kJ mol-1 D. 137 kJ mol-1

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C. Y. Yeung (AL Chemistry) 5. An exothermic chemical reaction proceeds by two stages. reactants stage 1 intermediate stage 2
-1

product

The activation energy of stage 1 is 50 kJ mol . The overall enthalpy change of reaction is 100 kJ mol-1. Which diagram could represent the enthalpy profile for the reaction?

A.

enthalpy (kJ mol-1 ) 100 75 50 25 0 -25 reactants -50 -75 -100

B.

enthalpy (kJ mol-1 ) 100 75 50 25 0 reactants -25 -50 -75 -100

products

products reaction coordinate

reaction coordinate

C.

enthalpy (kJ mol-1 ) 100 75 50 25 0 -25 reactants -50 -75 -100

D.

enthalpy (kJ mol-1 ) 100 75 50 25 0 -25 -50 -75 -100

reactants products

products

reaction coordinate

reaction coordinate

6.

c [C4H8(g)] = x kJ mol-1, H

of H

the reaction 2C2H4(g) C4H8(g) = y kJ mol-1. What

is the value of c [C2H4(g)]? H A. ( C.

x y + y ) kJ mol-1 B. ( x + ) kJ mol-1 2 2 x +y x y kJ mol-1 D. kJ mol-1 2 2

7.

Which of the following processes is endothermic? A. C. the condensation of steam. the freezing of water. B. D. the electrolysis of water. H+(aq) + OH-(aq) H2O(l)

8.

The standard enthalpy changes of formation of carbon dioxide and water are -394 kJ mol-1 and -286 kJ mol-1 respectively. If the standard enthalpy change of combustion of propyne (C3H4) is -1938 kJ mol-1, what is its standard enthalpy change of formation? A. +1258 kJ mol-1 B. +184 kJ mol-1 C. -184 kJ mol-1 D. -680 kJ mol-1

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C. Y. Yeung (AL Chemistry) 9. Which one of the following has the same value as the standard enthalpy change of formation of carbon monoxide? A. C.

1 H [CO 2(g) ] f 2 H [CO 2(g) ] f 1 H [graphite] c 2

B. D.

1 H [graphite] c 2

H [graphite] c

- H [CO (g) ] c

10. In an experiment to measure the enthalpy change of neutralization of hydrochloric acid, 20 cm3 of solution containing 0.04 mol of HCl is placed in an expanded polystyrene cup of negligible heat capacity. A 20 cm3 sample of aqueous sodium hydroxide containing 0.04 mol of NaOH, at the same initial temperature, is added and the temperature rises by 15 K. If the heat capacity of the final solution is 4.2 J K -1 cm-3, what is the enthalpy change of neutralization of hydrochloric acid? A. C. (II) 1. -31.5 kJ mol-1 -63 kJ mol-1 B. -0.20 kJ mol-1 D. -15.8 kJ mol-1

Structural Questions From calorimetric measurements, the standard enthalpy changes of combustion at 298 K for graphite, hydrogen and ethanol are 393.1, -285.8 and 1367 kJ mol-1 respectively. Determine the standard enthalpy change of formation for ethanol at 298 K through the construction of a Born-Haber Cycle.

2.

Given the following thermochemical data. Reaction C(graphite) + 2H2(g) CH4(g) C(graphite) + O2(g) CO2(g) H2(g) + (a)

1 O2(g) H2O(l) 2

H / kJ mol -1 298 -75.0 -393.5 -285.9

Calculate the enthalpy change H for the reaction 298 CH4(g) + 2O2(g) 2H2O(l) + CO2(g)

(b) The enthalpy change H is 801.7 kJ mol-1 for the following reaction: 298 CH4(g) + 2O2(g) 2H2O(g) + CO2(g) Calculate the enthalpy change of vaporization of water at 298 K. (c) The enthalpy change of combustion of diamond at 298 K is 395.4 kJ mol-1. Which allotrope of carbon, diamond or graphite, is energetically more stable? Explain why carbon does not convert from the less stable allotrope to the more stable one at room temperature. ~ End ~ 3/3