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[40 marks]
Answer all questions
1. (a) The following figure shows the principal energy levels of the hydrogen atom.
(i) The figure shows that as the quantum numbers of the energy level
increases, the separate lines of the energy levels becomes closer until
they converge, at n = ∞
State the magnitude of the nuclear force towards the electron in the
hydrogen atom at this point.
…………………………………………………………………………………....
[ 1 mark ]
(ii) Calculate the minimum energy required to ionise a hydrogen atom in its
ground state.
[1 mark ]
[ 2 marks ]
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(b) Hydrogen combines with chlorine to form hydrogen chloride. The mass
spectrum of hydrogen bromide is shown below.
Intensity
100 P2
50
P1
P4
P3
0
30 35 40 45 m/e
……………………………………………………………………………………
[ 3 marks ]
(c) The figure below shows the plot of pV/RT against pressure for hydrogen
pV/RT
1.0
Pressure/atm
(i) Give a reason why hydrogen gas deviates from the ideal behaviour at high
pressure.
…………………………………………………………………………………….
…………………………………………………………………………………….
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(ii) Unlike hydrogen gas, hydrogen chloride gas shows a very marked negative
deviation from ideal behaviour at medium pressure. Give two reasons.
1.
…………………………………………………………………………………….
…………………………………………………………………………………….
2.
…………………………………………………………………………………….
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[ 3 marks ]
2. Chlorine dioxide gas, ClO2, which is a reddish yellow gas. It is used for the
disinfection and the principal agent used in the decontamination of buildings in the
United states after the 2001 anthrax attack.
(a) Chlorine dioxide gas can be prepared in the laboratory by the following
reactions:
2AgClO3 (s) + Cl2 (g) 2AgCl (s) + 2ClO2 (g) + O2 (g); ∆H = zero
(ii) From the value obtained in a (i) above; comment on the relative stability
of chlorine dioxide.
…………………………………………………………………………………...
…………………………………………………………………………………...
[ 3 marks ]
(b) Chlorine dioxide is a strong oxidizing agent in acidic solution. This is why it is
used as a bleaching agent.
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(ii) Aqueous hydrogen sulphide, H2S
[4 marks ]
[2 marks]
(c) Chlorine dioxide undergoes disproportionation in alkaline solution to give a
mixture of chlorate (III) and chlorate (V) ions.
Write an ionic equation for the reaction.
…………………………………………………………………………………...
[ 1 mark ]
3. The first ionization energies of some Group 2 and group 3 elements are given as
follows.
Group 2 Ionisation energy Group 13 Ionisation energy
-1
elements (kJmol ) elements (kJmol-1)
Be 900 B 798
Mg 726 Al 575
Ca 592 Ga 575
Sr 546 In 556
Ba 502 Tl 589
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[ 1 mark ]
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(b) The first ionization energy of the Group 2 elements decreases down the group.
State the 2 factors that contribute to the decrease in 1st ionization energy from
Be to Ba.
1. ………………………………………………………………………………..
2. ………………………………………………………………………………..
[2 marks]
(c) Explain why the 1st ionization energy of magnesium is higher than that of
aluminium.
…………………………………………………………………………………...
…………………………………………………………………………………...
…………………………………………………………………………………...
[ 2 marks ]
(d) The 1st ionization energy of boron and barium do not show a marked difference,
however, barium compounds are ionic whereas boron compounds are
predominately covalent. Give an explanation for this observation.
…………………………………………………………………………………...
……………………………………………………………………………….......
…………………………………………………………………………………...
[ 2 marks ]
(e) Burning of magnesium in air produces magnesium oxide and a little
magnesium nitride
(i) Draw a Lewis structure for magnesium nitride.
(ii) When magnesium nitride is warmed with water, a gas that turns moist red
litmus paper blue is liberated.
Write a balanced equation for the reaction between magnesium nitride
and water.
…………………………………………………………………………………..
[ 3 marks]
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4. An organic compound X of molar mass of 136.9g mol-1 has the following
composition by mass:
[ 2 marks ]
(b) When X is boiled under reflux with aqueous sodium hydroxide, 2-methyl-1-
propanol is formed.
…………………………………………………………………………………...
[ 2 marks ]
(i) Y has four isomers. Give the structural formula for the isomer that
exhibits geometrical isomerism.
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(iii) State one isomer of alkene Y that produces carbon dioxide when heated
with concentrated acidified KMnO4? Give an equation for the reaction.
Isomer:
Equation:
[ 4 marks]
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[ 2 marks]
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SECTION B
(60 marks)
[ 8 marks ]
(b) The following reaction is used industrially to produce a combustible gas from coal.
Use the data given to calculate the partial pressures of hydrogen and carbon
monoxide, and hence calculate a value for Kp
[ 3 marks ]
(c) Hydrangeas are flowering plants which commonly have pink flowers. They
produce blue flowers in soils which contain high concentrations of Mg 2+ (aq). The
pH of well limed soil is 9.0, whereas the pH of peat-based soil is 6.5. The
numerical value of the solubility product, Ksp of magnesium hydroxide is 1.8 x 10-
12
Deduce and explain which of these types of soil favours good cultivation of blue
hydrangeas.
[ 4 marks]
7. (a) A solid halide reacts with concentrated sulphuric acid to form HX gas which is
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then oxidized to X2 gas. The solid plays an important role in black-white
photography. Identify the solid halide. Explain your answer.
[5 marks]
(ii) Draw the structures of the two isomers and name them.
[5 marks]
(c) Explain the observations when an aqueous solution of silver nitrate is added to
(i) triamminetrichlorocobalt(III)
8. (a) (i) Suggest reasons why magnesium gives the nitride, Mg3N2, in addition to its
oxide when burned in air.
(ii) A 1.00g sample of the powder obtained from burning magnesium in air was
boiled with water. The ammonia that was evolved neutralizes 12.00 cm3 of
0.5 mol dm-3 hydrochloric acid. Construct balanced equations for the reaction
of magnesium nitride with water.
Calculate the percentage of magnesium nitride in the 1.00g sample.
[ 6 marks]
(b)
NaCl AlCl3 CCl4 SiCl4
Describe the reaction, if any, of each of the four chlorides with water, stating the
appropriate pH of any solution formed, and writing balanced equation for any
reaction that takes place. Offer an explanation for any differences that occur in
their reactivity.
[6 marks ]
(c) Articles made from copper and its alloys can be cleaned of their oxides tarnish by
the use of metal polishes containing aqueous ammonia and an abrasive.
Assuming the tarnish copper contains copper(II) ions, suggest with an equation, how
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the aqueous ammonia might react with the tarnish, and suggest the colour of the
resultant solution.
[ 3 marks ]
9. The amino acids tyrosine, lysine and glycine are constituents of many proteins.
(a) State the reagents and conditions you could use to break proteins down into amino
acids.
[ 2 marks ]
(b) Draw a ring around each chiral centre in the above molecules.
[ 2 marks]
(c) In aqueous solution amino acids exist as zwitterions. Draw the zwitterionic
structure of glycine.
[ 1 mark ]
(d) For each of the following reactions, draw the structure of the organic compound
formed.
(i) glycine + excess NaOH(aq).
(ii) tyrosine + excess NaOH(aq)
(iii) lysine + excess HCl (aq)
(iv) tyrosine + excess Br (aq)
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[ 5 marks ]
(e) Draw the structural formula of a tripeptide formed from all three of these amino
acids, showing clearly the peptide bonds.
[ 2 marks ]
(f) The formula of part of the chain of a synthetic polyamide is shown below.
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(i) Identify the repeat unit of the polymer by drawing square brackets around it on
the above formula.
(ii) Draw the structures of the two monomers from which the polymer could be
made.
[ 2 marks ]
(b State the reagent needed to carry out the following reaction.
) X
[ 1mark ]
OH in NaOH (aq)
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Z
COCl
CH3NH2
H2O
[ 3 marks ]
(i) State which one of these compound reacts with alkaline aqueous iodine, and draw
the structural formulae of the products formed during this reactions.
[ 3 marks ]
(ii) The reduction of D with NaBH4 produces just one alcohol, but a similar reduction
of E produces two isomers in equal amounts. Explain these observations, drawing
structures where appropriate.
[ 3 marks ]
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END OF QUESTION PAPER
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