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Functional Micro/Macro Additive Manufacturing

Jae-Won Choi, Ph.D., Assistant Professor


Director, Innovative Design and Manufacturing Laboratory, Mechanical Engineering, The University of Akron

Feel free to contact if you have any questions E-mail: palagent@gmail.com

Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

Contents
Introduction Projects Review Applications - 3D Functional Microstructures Future Work

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Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

Introduction Additive Manufacturing Additi M f t i

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Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

Additive Manufacturing (AM)


What is AM ?
Process of joining materials to make objects from 3D model data, as opposed to subtractive manufacturing (lathes, mills, etc.) Definition AM is a standard terminology defined by ASTM gy y Rapid Prototyping (RP), Solid Freeform Fabrication (SFF), Layered M L d Manufacturing (LM) Addi i F b i i f i (LM), Additive Fabrication, etc. Synonyms

Pre-production (Rapid Prototyping) to Rapid Manufacturing and Tooling. Coverage

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Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

Representative AM Process
Stereolithography Apparatus (SLA)
Working principle
Curing photocrosslinkable liquid material using a laser

Examples

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Representative AM Process
Fused Deposition Modeling (FDM)
Working Principle
Depositing a molten material using a filament and heated nozzles

Examples

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Representative AM Process
Selective Laser Sintering (SLS)
Working Principle
Sintering a powder material using a CO2 laser

Examples

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Functional Micro/Macro Additive Manufacturing

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Representative AM Process
Electron Beam Melting (EBM)
Working Principle
selectively melting Ti6Al-4V powder using an electron beam

Examples

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Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

Additive Manufacturing
Various processes
Additive manufacturing processes

Powder materials

Liquid materials

Solid materials

Sintering g process

Printing or joining process

Extrusion p process (molten material) Fused Deposition Modeling (FDM) Solid Ground Curing (SGC) Photomasking p processes

Liquid polymerizati on process

Bonding of sheets with adhesive Laminated Object Manufacturing (LOM)

Bonding of sheets with light

Selective Laser Sintering (SLS)

3D Printing (3DP)

Laser processes

Deposition process

Foil polymerizati on

Dynamicmask Projection

Stereolithogr aphy (SL)

Multi-Jet Modeling (MJM)

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Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

Projects Review - Macro Additive


Manufacturing

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Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

Micro channel Micro-channel Fabrication in SLA Using micro-wires in SLA

Build open micro-channel

Place micro-wire in channel

Complete build (embed wire)

Remove wire

31.6 m wire
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57.2 57 2 m wire i

83.5 83 5 m wire
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Choi, J.W. *, Quintana, R., Wicker, R., Rapid Prototyping Journal, 17 (5), 2011.

Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

Advanced AM I
Multiple Material Stereolithography (MMSL)

Build using material 1 Raise the platform

Rotate material vat 1 under build platform

Finished multiple material part

Manual Cleaning and drying the platform with a part

Continue the process to build multiple material functional devices Build using material 2

Rotate material vat 2 under build platform

Kim, H.C., Choi, J.W., Wicker, R.B., Rapid Prototyping Journal, 16: 232-240, 2010. Kim, H.C., Choi, J.W., MacDonald, E., Wicker, R.B. International Journal of Advanced Manufacturing Technology, 46: 1161-1170, 2010. Innovative Design and Manufacturing Lab 12

Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

Advanced AM I
Multiple Material Stereolithography (MMSL)

Choi, J.W., Kim, H.C., Wicker, R., Multi-material stereolithography, Journal of Materials Processing Technology, 211: 318-328, 2011.. Innovative Design and Manufacturing Lab 13

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J.W. Choi J.W. Choi

Advanced AM I
Multiple Material Stereolithography (MMSL)
1 2

Building the bottom using the material 1 (diluted ProtoTherm 12120 (Red))

Building the half hollow structure using the g g material 2 (diluted WaterShed 11120 (Clear))

Building the other half hollow structure using the material 3 (diluted 14120 White)

Building the staircase, spirals, and top using the material 1

Applications (NGCs, medical models) 14

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Advanced AM II
Flexible Fused Deposition Modeling (FFDM)

Choi, J.W., Medina, F., Kim, C., Espalin, D., Rodriguez, D., Stucker, B., Wicker, R. Development of a Mobile Fused Deposition Modeling System with Enhanced Manufacturing Flexibility, Journal of Materials Processing Technology, 211: 424-432, 2011 Innovative Design and Manufacturing Lab 15

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J.W. Choi J.W. Choi

Advanced AM II
Flexible Fused Deposition Modeling (FFDM)

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Functional Micro/Macro Additive Manufacturing

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Projects Review

Micro Additive Manufacturing

:Microstereolithography

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Micro AM - Microstereolithography
What is Microstereolithography (SL)
Process of layer-by-layer joining materials to make microobjects Evolved from conventional stereolithography (SL) Typically the x-y resolution of a few microns and z resolution of a few tens of microns Types
Scanning SL
Si il t conventional SL Similar to ti l Using a focused laser (beam spot size 10 m)

Projection SL
Using a physical or dynamic (or digital) mask (pattern size 5 m)
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SL - History
IC Technology

1960 1970

MEMS

1980
LIGA, Berker et al. SLA, Hull Ikuta and Kirowatari Tagaki et al. Two-photon, Maruo et al. Mask-based MSL,Nagomoto et al. LCD MSL B h l LCD-MSL, Bertsch et al.

1986 1988 1993 1990

1996

199 1997 2000


MSL : Microstereolithography LCD : Liquid crystal display DMD : Digital micromirror device

DMD-MSL, Bertsch et al. g, Commercial Microsintering, Micromac Acculas, Commercial MSL, D-Mac
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2001

2003 2004

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Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

DMD-based projection SL

Choi, J W Ha, Y M Lee S H Choi K H Choi J.W., Ha Y.M., Lee, S.H., Choi, K.H., Journal of Mechanical Science and Technology 20: 2094 2104 2006 Technology, 2094-2104, 2006. Choi, J.W., Wicker, R.B., Cho, S.H., Ha, C.S., Lee, S.H., Rapid Prototyping Journal, 15: 59-70, 2009. Innovative Design and Manufacturing Lab 20

Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

DMD-based projection SL
Configuration
Light emission subsystem
Mercury lamp with the output of 200 W Filtered at the wavelength of 365 nm

EXFO OmniCure S2000TM model


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Lamp output
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Functional Micro/Macro Additive Manufacturing

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DMD-based projection SL
Configuration
Dynamic pattern generation subsystem
Texas Instrument 1024 by 768 micro-mirror array Mirror size of 13.68 m 12 tilting angle to selectively reflect a light bundle
-12 degrees tilt (off t t ) ( ff state) Flat state

DMD

Off state (dummy light) (-12 degrees tilt)

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Flat state (not energized)

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+12 degrees tilt (on state)

On state for image-forming (+12 degrees tilt) Incident light

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DMD Discovery 1100TMController Board

DMD operation
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Functional Micro/Macro Additive Manufacturing

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DMD-based projection SL
Configuration
Image focusing subsystem
Objective lenses with different numerical apertures (N.A.)
NA: 0.13 NA: 0.3 NA: 0.45

Build subsystem
High-resolution z stage (100 nm) ) Custom made platform

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Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

DMD-based projection SL
Deep-dip process
Settling time is required Low viscosity resin is required
Projection lens Fabricated layer Focused light Unstable resin surface Platform Vat Refreshed resin surface

(a)

Resin

(b)

(c)

(d)

(a) Step 1 : Irradiation for given time (b) Step 2 : Fast moving downward to cover fabricated layer (c) Step 3 : Slow moving upward to desired position (d) Step 4 : Waiting until resin surface becomes flat
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Functional Micro/Macro Additive Manufacturing

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DMD-based projection SL
Material issues
Photocrosslinkable and low viscosity liquid materials Commercial resins
SI40 provided b 3D S t id d by Systems (R k Hill SC) (Rock Hills, WaterShed 11120, ProtoTherm 12120, and Somos 14120 White provided by DSM Somos (New Castle, DE)

Most of commercial resins are too viscous


acrylate- or diacrylate-based monomers as diluents A viscosity of less than ~200 cP is recommended 200 propoxylated (2) neopentyl glycol diacrylate 1,6-hexanediol diacrylate (HDDA) i b isobornyl acrylate (IBXA or IBOA) l l t
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Functional Micro/Macro Additive Manufacturing

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DMD-based projection SL
Material issues
Monomers, oligomers, and polymers available
Crosslinkable sites such as a carbon double bond Photoinitiator (PI) is required
Depends on the wavelength of a chosen light

Overcure and cure depth control


Curing characterization for photocrosslinkable materials is defined by critical energy (Ec) and light penetration depth (Dp) For cure depth control, a light absorber is required
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Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

Fabrication examples

Dime

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Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

Fabrication examples
~30 m 30 ~30 m ~50 m

~10 m 10 ~130 m

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Advanced SL I
Large-area fabrication
Collimating lens set DMD Optical fiber Reflecting mirror Focusing unit Lamp

Additional high precision x-y stage i i t under the system LightGate

Tube lens Z Stage

X-Y Stage

Resin Vat Objective lens

Ha, Y.M., Choi, J.W., Lee, S.H., Journal of Mechanical Science and Technology, 22: 514~521, 2008. Innovative Design and Manufacturing Lab 29

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Advanced SL I
Large-area fabrication

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Advanced SL I
Large-area fabrication

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Functional Micro/Macro Additive Manufacturing

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Advanced SL I
Large-area fabrication

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Advanced SL I
Large-area fabrication

3D model

fabricated teeth

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Advanced SL II
Multi-material fabrication
Using additional syringe pump and custom-made small vat Manual washing process

Choi, J.W. *, MacDonald, E., Wicker, R.B., International Journal of Advanced Manufacturing Technology, 49: 543-551, 2010. Innovative Design and Manufacturing Lab 34

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Advanced SL II
Multi-material fabrication
Single material fabrication in the developed system

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Advanced SL II
Multi-material fabrication

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Functional Micro/Macro Additive Manufacturing

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SL Applications - 3D Functional
Microstructures

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SL Applications I

Fluidics Biomedical Fluidics,


sleeve

3D micro-vanes within a sleeve in cataract surgery


Phacoemulsification
Removing the crystalline ultrasound irrigation
maintaining a constant pressure dissipating heat maintaining an endothelial cell survival Impinging flow from the irrigation solution on the corneal endothelial cells in the inner eye damages these cells during the procedure
Irrigation tip

phacoemulsifier

artificial lens

It is required t reduce the fl i i d to d th flow velocity during the procedure


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Source: http://www.eyesurgeryeducation.com

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Functional Micro/Macro Additive Manufacturing

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SL Applications I

Fluidics Biomedical Fluidics,

3D micro-vanes within a sleeve in cataract surgery

Choi, J.W. *, Yamashita, M., Sakakibara, J., Kaji, Y., Oshika, T., Wicker, R. Biomedical Microdevices, 12: 875-886, 2010. Innovative Design and Manufacturing Lab 39

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SL Applications II

Electrical Mechanical Electrical,

3D micro-patterns for conductive wires

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Functional Micro/Macro Additive Manufacturing

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SL Applications III
Tissue engineering scaffolds

Tissue Engineering

Artificial structure or template to support implanted or seeded cells to be a three-dimensional tissue


scaffolds requirements: degradation rate, porosity, pore size, shape, distribution, and mechanical properties di t ib ti d h i l ti materials requirements
Biodegradability: degradable into nontoxic products, leaving the desired living tissue Biocompatibility: not to provoke any unwanted tissue response to the implants and to possess the right surface chemistry to promote cell attachment & function M Manufacturability f t bilit

optimal scaffold pore size and geometry vary according to cell types

3D design and fabrication are necessarily needed

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Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

SL Applications III

Tissue Engineering

Tissue engineering scaffolds


Biodegradable/biocompatible/photocrosslinkable Poly(propylene fumarate) (PPF) is a good material
O i i ll d Originally developed f b l d for bone regeneration ti Synthesized using propylene glycol and diethyl fumarate PPF can be diluted with diethyl fumarate

O EtO O
Diethyl fumarate (DEF) Propylene glycol (PG)

OEt

HO

OH

HO

O O
PPF

O
n

OH

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Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

SL Applications III

Tissue Engineering

Tissue engineering scaffolds using PPF/DEF

Choi, J.W., Choi, K.H., Chung, I., Ha, C.S., Lee, S.H, Wicker, R.B., Journal of Materials Processing Technology, 29: 5494-5503, 2009 Innovative Design and Manufacturing Lab 43

Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

SL Applications IV
Microneedles for transdermal drug delivery
Stratum corneum is the main barrier to delivery drugs To avoid the barrier, painless microneedles can puncture the skin with micron size holes micron-size Microneedles can potentially include drugs
stratum corneum capillary network papillary layer blood circulation permeation uptake DRUG Epidermis Dermis Subdermal tissue DRUG permeation Epidermis Dermis
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stratum corneum microneedle

stratum corneum punctured holes

uptake

Epidermis Puncture process

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Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

SL Applications IV
Microneedles for transdermal drug delivery
~460 60 m ~160 m

Choi, J.W., Irwin, M., Wicker, R.B., Proc. of SPIE, Photonics West, Jan. 23-28 2010, San Francisco, CA, 7596: 75960H-1~11. Innovative Design and Manufacturing Lab 45

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SL Applications V
Microlens arrays for optics
collimating light in an optoelectronic sensor, an optical communication device, and confocal microscopes

Park, I.B., Lee, S.D., Kwon, T.W., Choi, J.W., Lee, S.H. Journal of the Korean Society for Precision Engineering, 25: 123-130, 2008. Innovative Design and Manufacturing Lab 46

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SL Applications VI
Nerve guidance conduits (NGCs)
To support peripheral nerve regeneration Using poly(ethylene glycol) (PEG) with the molecular weight of 3400 (non toxic) (non-toxic)

Choi, J.W., Irwin, M., Wicker, R.B., Proc. of SPIE, Photonics West, Jan. 23-28 2010, San Francisco, CA, 7596: 75960H-1~11. Innovative Design and Manufacturing Lab 47

Functional Micro/Macro Additive Manufacturing

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Current Work

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Current Work I
TITLE: Multi-scale, multi-material additive manufacturing and its application
Collimating lens Optical fiber DMD board Prism Tube lens Focusing unit Lamp

Continuous projection for multimulti scale fabrication Automatic material changeover Automatic washing g mechanism

Cleaning system X-Y stage Z stage Small vat Reflecting mirror Objective lens

Pump system p y

Vat for used material

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Current Work II
TITLE: Low-Temperature, Low-Cost Direct Writing of Photocrosslinkable Solutions Filled with Copper Nanoparticles for 3D Conductive Patterns on Flexible Substrates

Using geometry-controlled nanoparticles

Copper nanoparticles in photocrosslinkable solution

Microstereolithography process with material changeover

Final 3D conductive patterns on a flexible substrate

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Current Work III


TITLE: Multi-Material, Large-Area Microstereolithography of Biodegradable/Biocompatible 3D Microneedle Arrays for Long-Term, Sustained, and Controlled Drug Release

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Functional Micro/Macro Additive Manufacturing

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Current Work IV
TITLE: Direct Writing with Micro/Macro Stereolithography for 3D Electronics

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Collaborators
Dr. Ryan Wicker, UTEP AM, DW Dr. Eric MacDonald, UTEP 3D electronics Dr. Namsoo Kim, UTEP Nanoparticle synthesis, Packing technology Dr. Karina Arcaute, UTEP Nerve Guidance Conduits Dr. Kenneth Church, UTEP, nScript Micro-dispensing Micro dispensing Dr. Michael Irwin, UTEP Chemistry, Biomaterials Dr. Brenda Mann, Univ. of Utah Poly (ethylene glycol) synthesis Dr. Dr Brent Stucker Univ of Louisville Ultrasonic Consolidation (UC),Flexible FDM Stucker, Univ. (UC) Flexible Dr. Jun Sakakibara, Tsukuba Univ., Japan - Fluidics Dr. Seokhee Lee, Pusan Natl Univ., Korea - SL, Automation Dr. Dr Changsik Ha Pusan Natl Univ Korea Polymer Ha, Nat l Univ., Dr. Kyunghyun Choi, Cheju Natl Univ., Korea DW, Printed OLDE Dr. Hochan Kim, Andong Natl Univ., Korea Automation, Software development Dr. Dr Inhwan Lee Chungbuk Natl Univ Korea - SL Bioreactor Lee, Nat l Univ., SL,
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Functional Micro/Macro Additive Manufacturing

J.W. Choi J.W. Choi

Acknowledgements
Several photos and materials has been obtained from W.M. Keck Center at UTEP ( (PI, Dr. Ryan Wicker). y ) Several photos has been copied from the Wikipedia website for better understanding. Several photos and materials has been obtained from the web-based lecture materials.

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