CODE Magna
NARAYANA
I I T A C A D E M Y
GRAND TEST 1
XII STD Spark PAPER 2
Time: 3 hours Maximum marks: 240
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
INSTRUCTIONS
A. General:
1. This booklet is your Question Paper containing 57 questions. The
booklet has 14 pages.
2. The question paper CODE is printed on the right hand top corner
of this booklet.
3. Blank papers, clipboards, log tables, slide rules, calculators,
cellular phones, pagers, and electronic gadgets in any form are not
allowed to be carried inside the examination hall.
4. The answer sheet, a machinereadable Objective Response Sheet
(ORS), is provided separately.
5. DO NOT TAMPER WITH / MUTILATE THE ORS OR THE
BOOKLET.
B. Filling the ORS
6. On the lower part of the ORS, write in ink, your name in box L1,
your Registration No. in box L2 and Name of the Centre in box L3.
Do not write these anywhere else.
7. Write your Registration No. in ink, in the box L4 provided in the
lower part of the ORS and darken the appropriate bubble UNDER
each digit of your Registration No. with a good quality HB pencil.
8. The ORS has a CODE printed on its lower and upper parts.
9. Make sure the CODE on the ORS is the same as that on this
booklet and put your signature in ink in box L5 on the ORS
affirming that you have verified this.
10. IF THE CODES DO NOT MATCH, ASK FOR A CHANGE OF
THE BOOKLET.
C. Question paper format:
11. The question paper consists of 3 parts (Part I: Chemistry, Part
II: Mathematics, Part III: Physics). Each part has 4 sections.
12. Section I contains 4 multiple choice questions. Each question has 4
choices (A), (B), (C) and (D), out of which only one is correct.
13. Section II contains 5 multiple correct answer type questions. Each
questions has 4 choices (A), (B), (C) and (D), out of which one or
more answers are correct.
14. Section III contains 2 questions. Each question has four statements
(A, B, C and D) given in column I and five statements (p, q, r, s
and t) in column II. Any given statement in column I can have
correct matching with one or more statements(s) given in column
II. For example, if for a given question, statement B matches with
the statements given in q and r, then for that particular question,
against statement B, darken the bubbles corresponding to q and r in
the ORS.
15. Section IV contains 8 questions. The answer to each of the
questions is a singledigit integer, ranging from 0 to 9. The answer
will have to be approximately bubbled in the ORS as per the
instructions given at the beginning of the section.
D. Marking Scheme:
16. For each question in Section I, you will be awarded 3 marks if
you have darkened only the bubble corresponding to the correct
answer and zero mark if no bubble is darkened. In case of bubbling
of incorrect answer, minus one (1) mark will be awarded.
17. For each question in Section II, you will be awarded 4 marks if
you have darkened all the bubble(s) corresponding to the correct
choice(s) for the answer, and zero mark if no bubble is darkened.
In all other cases, minus one (1) mark will be awarded.
18. For each question in Section III, you will be awarded 2 marks
for each row in which you have darkened the bubble(s)
corresponding to the correct answer. Thus, each question in this
section carries a maximum of 8 marks. There is no negative
marking for incorrect answer(s) for this section.
19. For each questions in Section IV, you will be awarded 4 marks if
you darken the bubble corresponding to the correct answer, and
zero mark if no bubble is darkened. In all other cases, minus one (
1) mark will be awarded.
Name of the Student Roll Number
I have read all the instructions and shall abide by them
..
Signature of the Candidate
I have verified all the information filled in by the
Candidate
..
Signature of the Invigilator
NARAYANA IIT JEE ACADEMY
HYDHG
Test Date : 30 11  2009
CODE : Magna HYDHG/SR IIT
SPARK/PAPER2
PART:1  C H E M I S T R Y
SECTION I
Straight Objective Type
This section contains 4multiple choice questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.
1) In the reaction sequence [ ]
X
is ketone;
a
)
a)
b) c) d)
2)
3 2
CH O CH CH NO 1
2 2
2
2 2
CH =CH NO 2
CH =CH Cl 3
CH =CH 4
Which of the following is the correct order of C C bond length among these compounds?
a) 1 2 3 4 > > > b) 4 3 2 1 > > > c) 1 3 2 4 > > > d) 2 3 1 4 > > >
3) In a reaction a Aproducts, the rate is doubled when the concentration of A is increased 4 times.
If 50% of the reaction occurs in 1414 sec , how long would it takes for the completion of 75%
reaction.
a) 4242sec b) 2825 sec c) 2414 sec d) 2121 sec
4)
The
o
E
in the given diagram is
a) 0.52 V b) 0.61 V c) 0.74 V d) 0.83 V
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CODE : Magna HYDHG/SR IIT
SPARK/PAPER2
SECTION II
Multiple Correct Answer Type
This section contains 5 Multiple correct answer(s) type questions. Each question has 4 choices (A), (B),
(C) and (D), out of which ONE OR MORE
5) Which of the following statements are true?
a)
3 2 2
CH CH CH I
will react more readily than ( )
3
2
CH CHI
for
N
S 2
reactions
b)
3 2 2
CH CH CH Cl
will react more readily than
3 2 2 N
CH CH CH Br for S 2
reactions
c)
3 2 2 2
CH CH CH CH OH
will react more readily than ( )
3 2 N
3
CH C CH OH for S i
reactions in the presence of pyridine
d)
3 6 5
CH O C H Br
will react more readily than
2 6 5 2 N
NO C H CH Br for S 2
reactions
6)
3(s) (s) 2(g)
MCO MO CO +
1
]
?
a)[ ]
2
4
NiCl is tetrahedral
b) ( )
3 2
2
Ni PPh Cl is tetrahedral 1
]
c) ( )
3 2
2
Ni PPh Cl is square planar 1
]
d) [ ]
2
4
NiCl is square planar
8) Select the correct option against mentioned property
a)
a)
(Rate of reaction with
3
CH I
)
b)
(Basic nature)
c)
Rate of reaction with
2 4
H SO
d)
I F
>
(Nucleofugacity)
9) White phosphorous ( )
4
P
has
a) six PP single bonds b) covalency of phosphorus, 5
c) four lone pairs of electrons d) PPP angle of 60
O
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CODE : Magna HYDHG/SR IIT
SPARK/PAPER2
SECTION III
Matrix Match Type
This section contains 3 questions. Each question contains statements given in two
columns which have to be matched. Statements (A, B, C, D) in Column I have to be
matched with statements (p, q, r, s, t) in Column II. Any statement in Column I can
have correct matching with ONE OR MORE statement(s) in column II. The answers to
these questions have to be appropriately bubbled as illustrated in the following example.
If the correct matches are A p, A t, B p, B q, Bs, Bt, C p, C r Ct, and D q
then the correctly bubbled matrix should be as shown:
10. Match the following
Column I Column II
(A)
Alc.KOH
3 2 3 3 3
CH CH CH CH CH CH CH CH

Cl
(p)
shows
Hydrogen
effect
(B) (q) doesnt show
Hydrogen
effect
(C) CH
2
Cl
CH
3
Et OH
EtO
(r) shows solvent
isotopic effect
(D)
Alc.KOH
3 2 3
CH CH CH C Ph CH CH CH C Ph
  
Cl O O
(s) does show elemental
effect
(t) carbanion formation
11. Match the reactions mentioned in ColumnI with the nature of the reaction/characteristic(s) of the
products mentioned in ColumnII
Column I Column II
(A)
strongly heated
3 2
H PO
(p) One of the products acts as reducing
agent
(B) 2
i)H O
3
ii)
PCl
anhydrous salt
high
temp
L M N + +
. If oxidation state of the central atom in
L,M,N are X,Y,Z respectively (X<Y<Z). The value of Y Z X + is ___
17) When a system is taken from state A to B along path ACB, as shown in the
figure, 8J of heat flows into system and system does 3J of work. How much heat
flows into the system along the path ADB, if the work done by the system is
4J?
18) When copper sulphate dissolves in the ammonium hydroxide one deep blue complex is formed.
What is the coordination no of copper in this complex?
19) The mono nitration will mainly take place at which position?
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CODE : Magna HYDHG/SR IIT
SPARK/PAPER2
PartII : M A T H E M A T I C S
SECTION I
Straight Objective Type
This section contains 4multiple choice questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.
20) If
( )
2
sin cosec
A B 2
2 2
1 1
2 2
A A B
t dt 1
A dt, B dt then e B 1 ?
1 t t 1 t
1 A B 1
+
+ +
+
a) sin b) cos ec c) 0 d) 1
21) The curves
2 2
1 2
C : y x 3 ; C : y kx , k 1 < intersect each other at two different points. The
tangent drawn to
2
C
, at one of the points of intersection ( ) ( )
1
A a, y a 0 >
meets
1
C
again at
( ) ( )
2 1 2
B 1, y . y y .
Then value of
a ___?
a) 4 b) 3 c) 2 d) 1
22) Let A(1, 2), B(3, 4) be two points and C(x, y) be a point such that area of ABC is 3 sq.units
and ( ) ( ) ( ) ( ) x 1 x 3 y 2 y 4 0 +
. Then maximum number of positions of C, in the xy plane
is
a) 2 b) 4 c)8 d) none of these
23) If ( ) ( )
2 2
sin cos cos sin msin cos then
a)
1
 m
2
b)
1
 m
2
c)
 m 1
d)
 m 1
SECTION II
Multiple Correct Answer Type
This section contains 5 Multiple correct answer(s) type questions. Each question has 4 choices (A), (B),
(C) and (D), out of which One Or More Than One Correct
24) Thirteen persons are sitting in a row. Number of ways in which four persons can be selected so
that no two of them are consecutive is equal to ____
a) number of ways in which all the letters of the word M A R R I A G E are permutated if no
two vowels are never together.
b) number of numbers lying between 100 and 1000 using only the digits 1,2,3,4,5,6,7 without
repetition.
c) number of ways in which 4 alike chocolates can be distributed among 10 children so that each
child getting at most one chocolate.
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CODE : Magna HYDHG/SR IIT
SPARK/PAPER2
d) number of triangles can be formed by joining 12 points in a plane, of which 5 are collinear.
25) Given
2 2 2
 ax bx c   Ax Bx C, x R, a,b,c A,B,C R and d=b 4ac 0 and + + + + >
2
D=B 4AC 0 > . Then which of the following statements are true
a)
 a   A
b)
 d   D
c)
 a   A
d) if D,d are not necessarily positive then roots of
2 2
ax bx c 0 and Ax Bx C 0 + + + +
may not be equal
26) If ( )
2
1 1 x
2f x xf 2f 2 sin x 4cos x cos , x R {0}
x 4 2 x
_
_ _ _
+ + +
, , ,
,
then which of the
following statement(s) is/are true?
a) ( )
1
f 2 f 1
2
_
+
,
b) ( ) ( ) f 2 f 1 0 +
c) ( ) ( )
1
f 2 f 1 f
2
_
+
,
d) ( ) ( )
1
f 1 f f 2 1
2
_
,
27) If each of a, b, c is orthogonal to the sum of the other two vectors and
a 3, b 4, c 5
then
which of the following statement(s) is/are true
a) if
a
makes angles of equal measures with x,y,z axes, then tangent of this angle is
2 t
b) range of [ ]
 a b  is 1, 7 c) range of [ ]
 b c  is 1, 9 d)  a b c  =2 5 + +
28) Which of the following is true.
a) There exists a point in the plane of a parabola through which no real normal can be drawn to the
parabola.
b) If P,Q,R are conormal points of a parabola then circumcircle of
PQR
passes through the
vertex of the parabola.
c) The circum circle of triangle formed by three tangents of a parabola passes through focus of the
parabola.
d) length of subnormal at any point on a parabola is equal to latus rectum of the parabola.
SECTION III
Matrix Match Type
This section contains 3 questions. Each question contains statements given in two
columns which have to be matched. Statements (A, B, C, D) in Column I have to be
matched with statements (p, q, r, s, t) in Column II. Any statement in Column I can
have correct matching with ONE OR MORE statement(s) in column II. The answers to
these questions have to be appropriately bubbled as illustrated in the following example.
If the correct matches are A p, A t, B p, B q, Bs, Bt, C p, C r Ct, and D q
then the correctly bubbled matrix should be as shown:
Space for rough use
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CODE : Magna HYDHG/SR IIT
SPARK/PAPER2
29. We are given M urns, numbered 1 to M and n balls (n<M) and P(A) denote the probability that
each of the urns numbered 1 to n, will contain exactly one ball.
Column I Column II
(A) If the balls are different and any
number of balls can go to any urn
then P(A)=___
(p)
M
n
1
C
(B) If the balls are identical and any
number of balls can go to any urn
then P(A)=___
(q)
( ) M n 1
M 1
1
C
+
(p) Rational
(B)
( )
( )
( )
2
1 2cos x
Let g x dx and g 0 0
cos x 2
then g ___
2
+
+
(q) Irrational
(C) If real numbers x and y satisfy
( ) ( )
2 2
2
x 5 y 12 14 + + then minimum value
of
2 2
x y is ___ +
(r) Integral
(D)
( )
( )
( )
( )
2
3
3 3
x 1 dx
1
Let k x and k 1
2
x 3x 6
then k 2 _____
+
+ +
(s) Prime
Space for rough use
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CODE : Magna HYDHG/SR IIT
SPARK/PAPER2
SECTION IV
Integer Answer Type Questions
This section contains 8 questions. The answer to each of the questions is a single digit
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
numbers in the ORS have to be darkened. For example, if the correct answers to
questions numbers 1, 2, 3, 4 and 5 (say) are 2, 1, 4, 2 and 3, respectively then the correct
darkening of bubbles will look like the following.
31) Number of pairs of positive integers (p,q) whose LCM (Least common multiple) is 8100, is K.
Then number of ways of expressing K as a product of two coprime numbers is ____
32) If
2 2
tan x 4 tan x
sin 4x e dx c Acos x.e then A=___
+
equals to ( ) y a b then a+b=___
38) If 
1 2 3
2 2
< < < < , then number of values of
,
2 2
_
,
satisfying
( ) ( ) ( )
( ) ( ) ( )
1 2 3
1 2 3
tan tan tan tan tan tan
tan tan tan tan tan tan 0 is___
Space for rough use
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CODE : Magna HYDHG/SR IIT
SPARK/PAPER2
Part III : P H Y S I C S
SECTION I
Straight Objective Type
This section contains 4 multiplechoice questions. Each question has 4 choices (A), (B), (C) and (D), out
of which ONLY ONE is correct.
39. Two coherent radio point sources separated by 4.0m are placed at points A and B along a straight
line as shown. Both are emitting waves in phase of 1.0 m wave length. A
detector moves in a circular path around the two sources in a plane containing
them.
Point A and B lie on the diameter of the circle and they are at equidistant from
the center of the circle O as shown. Find the number of maxima counted by the
detector in one full circle.
a) 9 b) 10 c) 15 d) 16
40. A resistor and an inductor in series are connected to a battery through a
switch. After the switch has been closed, what is the magnitude of current
flowing when the rate of the increase of magnetic energy stored in the coil
is at a maximum?
a)
V
4R
b)
V
3R
c)
V
2R
d)
V
R
41. Four charges of equal magnitudes but different signs are arranged at the corners of a square, as
shown here. In which arrangement is the magnitude of the electric field at point P a maximum? (P
is the mid point of the side).
a) b) c) d)
42. A particle is dropped along the axis from a height
f
2
on a concave mirror of
focal f length f as shown in the figure. The acceleration due to gravity is g.
Find the maximum speed of image.
a) gf b)
3
3fg
4
c) 2gf d)
1
2gf
4
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CODE : Magna HYDHG/SR IIT
SPARK/PAPER2
SECTION II
Multiple Correct Answer Type
This section contains 5 Multiple correct answer(s) type questions. Each question has 4 choices (A), (B),
(C) and (D), out of which ONE OR MORE THAN CORRECT ANSWER
43. A man stretches a horizontal spring attached to the front wall of a railway carriage over a distance
l in a train moving with uniform velocity. During this time, the train covers a distance L. The
man stretches the spring opposite to the direction of motion of the train. The coordinate system
attached to earth is
1
s
and the coordinate system attaches to train is
2
s
. Then the work preformed
by man in stretching the spring is
a)
2
1
1
kl in s
2
b)
2
2
1
kl in s
2
c)
1
1
kl(L l) in s
2
d)
2
1
1
k(L l) in s
2
44. Find the true statements
a) it is easier to launch a satellite into an eastward orbit than into a westward one.
b) effect of friction on an orbiting satellite (assuming the height of the orbit is small so that
atmosphere is present) would finally result in increasing its speed.
c) An astronaut feels weightlessness as the astronauts acceleration is zero.
d) The earth is in free fall under the action of the net gravitational force of the sun and the planets
(neglect the effect of other astronomical objects)
45. Charge Q is uniformly distributed on a thin insulating ring of mass m; Which is initially at rest. A
magnetic field perpendicular to the plane of the ring which can attain its maximum value B is
switched on. Let the final angular velocity attained by ring be
. then
(neglect magnetic field produced by the rotating ring)
a) Magnitude of
n
m
a
, then find the
product mn.
54. A radioactive material consists of nuclides of 3 isotopes which decay by emission ,
emission
and deuteron emission respectively. Their half lives are
1 2 3
T 400sec, T 800sec and T 1600sec
respectively. At t=0, probability of getting
,
and
deuteron from radio nuclide are equal. If the probability of
=
12
n
radian, then find the value of n.
57. A parallel plate capacitor consists of two square plates of side length
a=6 cms. There is dielectric slab in the shape of a cylinder of parabolic
crosssection between the plates, as shown in figure. The dielectric
constant of the material is K=2. The length of latus rectum of the parabola
is equal to the side length of the plate. Then the capacitance is given by
2
0
4 N 10