SRI SHANMUGHA COLLGE OF ENGINEERING AND TECHNOLOGY Pullipalayam, Morur- 637 304, Sankari Taluk, Salem District Model

Examination I Engineering Chemistry I Time: 3 Hours 22.12.2011 Total Marks: 100 Date:

b. Explain the boiler troubles suggesting the remedial methods i) Sludge and Scale ii) Caustic embrittlement. (8) 2. a. Explain the mechanism of free radical polymerization. (8) b. Discuss the preparation, properties and uses of nylon 6, 6 and SBR (8) (OR)
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Part A - Answer all the questions 10x2=20 1. What is calgon conditioning? 2. Why is water softened before using in boilers? 3. Distinguish between carbonate and non carbonate hardness. 4. A water sample contains 73 mgs of Mg(HCO3)2 per liter. Calculate in terms of CaCO3 equivalents. 5. Why thermosetting plastics cannot be remoulded? 6. What is degree of polymerization? 7. What are composites? 8. What is an adsorption isotherm? 9. What is the effect of temperature and pressure on the adsorption of a gas on a solid surface? 10. What is catalytic poisoning? Part B Answer all the questions 5x16=80

a. Give the preparation, properties uses of i) PVC ii) Polyurethanes (8) b.What is natural rubber? Explain why natural rubber needs vulcanization. How is it carried out? (8) 3. a. Describe the role of adsorbents in catalysis with examples.(8) b. Write a note on adsorption of solutes from solution. (8) (OR) a) What is the role of activated carbon in air and Water pollution control? (8) b) What are the various factors influencing the adsorption of gas on a solid (8) 4. a. Discuss the various methods involving in domestic water treatment. Explain breakpoint chlorination. (12) b. Give the difference between thermoplastics and thermosetting plastics. (4) (OR) a. Derive Freundlichs and Langmuir adsorption isotherms (16)

1. a. Describe the procedure to estimate hardness by EDTA method. (8) b. What are ion exchange resins? How are they useful in removing in hardness of water? (8) (OR) a. What is desalination? With a neat diagram describe the reverse osmosis method for the desalination of brackish water. Mention its advantages (8)

5. a. Write a note on FRP. (4) b. Explain the types of polymerization (8) c. What is boiler corrosion? How can be it prevented? (4) (OR) a. Give a detailed note on determination of alkalinity of water with calculation. (12) b. Difference physisorption. (8) between chemisorption and

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.4. b. i) Explain the properties of Refractories (8)

SRI SHANMUGHA COLLGE OF ENGINEERING AND TECHNOLOGY Pullipalayam, Morur- 637 304, Sankari Taluk, Salem District B.E/B.Tech Degree Model Examination II, Jan 2012 First Semester CY2111 - Engineering Chemistry I Time: 3 Hours Total Marks: 100 Date: 11.01.2012

ii) Explain the preparation, properties and uses of the following synthetic abrasives a) SiC b) Alundum (8)

Part A - Answer all the questions

10x2=20

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1. What is the hardness of a solution containing 0.585 gram of NaCl and 0.6 gram of MgSO4 per litre? 2. What is caustic embrittlement? 3. Explain the functionality of a monomer with a suitable example. 4. List out the difference between thermoplastics and thermosetting plastics. 5. What is the effect of increase in temperature and increase in pressure on the adsorption of gas on a solid? 6. What is Freundlich adsorption isotherm? 7. What is secondary battery? Give an example. 8. Distinguish between nuclear fission and fusion reactions? 9. What is Flash point and Pour point? 10. Under what situations solid lubricants are used? Part B Answer all the questions 5x16=80

11. a. i) What is internal conditioning of boiler feed water? Describe briefly the various methods internal conditioning of boiler feed water (8)

.2. ii) 100 ml of water sample required 20 ml of 0.01M EDTA for the titration with Erichrome Black T indicator. 100 ml of the same water sample after boiling and filtering required 10 ml of 0.01 M EDTA. Calculate the total, carbonate and non-carbonate hardness of the sample. (4) iii) A water sample is not alkaline to phenolphthalein. But 100 ml of the sample on titration with N/50 HCl required 16.7 ml to methyl orange end point. What are the types and amount of alkalinity present in the sample? (4) (OR) b. i) Explain the necessity for sterilization of domestic water and discuss the various methods of sterilization. Discuss in detail about the break point chlorination. (10) ii) Describe the reverse osmosis method for the desalination of brackish water. Mention its advantages (6) 12. a. i) Explain the mechanism of free radical polymerization. (8) ii) Give the preparation and uses of Lexan (4) iii) What is FRP? List out its preparation and uses (4) (OR) b. i) Give the preparation, properties uses of i) PVC ii) PET (8) ii) What is natural rubber? Explain why natural rubber needs vulcanization. How is it carried out? (8) ..3

.3. 13. a. i) What is the role of activated carbon in air and water pollution control? (8) ii) Describe the role of adsorbents in catalysis with examples. (8) (OR) b. i) Derive the Langmuirs adsorption isotherm and discuss the effect of pressure on the isotherm (12) ii) Distinguish chemisorption (4) between physisorption and

14. a. i) What are the components present in nuclear reactor and explain their function. Explain with neat diagram of light water nuclear power plant (12) ii) Write a note on solar cells (4)

(OR) b. i) What is reversible battery? Describe the construction and working of Lead Acid battery with reactions occurring during charging and recharging cycles (8) ii) What are fuel cells? Describe the construction and working of H2-O2 fuel cell. (8) 15. a. i) Write a note on carbon nano tubes? Explain its important applications (8) ii) What are fluid and boundary lubrication? Explain (8) (OR)

SRI SHANMUGHA COLLGE OF ENGINEERING AND TECHNOLOGY Pullipalayam, Morur- 637 304, Sankari Taluk, Salem District Model Examination II, Jan 2012 Session: FN

SRI SHANMUGHA COLLGE OF ENGINEERING AND TECHNOLOGY Pullipalayam, Morur- 637 304, Sankari Taluk, Salem District Model Examination II, Jan 2012 Session: FN

CY2111 - Engineering Chemistry I Time: 1.5 Hrs Total Marks: 50 Date: 10.01.2012

CY2111 - Engineering Chemistry I Time: 3 Hours Total Marks: 50 Date: 10.01.2012

Part A - Answer all the questions

7x2=14

Part A - Answer all the questions

7x2=14

1. What is the effect of increase in temperature and increase in pressure on the adsorption of gas on a solid? 2. What is Freundlich adsorption isotherm? 3. What is secondary battery? Give an example. 4. Distinguish between nuclear fission and fusion reactions? 5. What is Flash point and Pour point? 6. Under what situations solid lubricants are used? 7. How is arsenic poisoning removed? Part B Answer all the questions 3x12=36 i) Explain the mechanism of free radical polymerization. (8) ii) What is FRP? List out its preparation and uses (4 9. i) What is natural rubber? Explain why natural rubber needs vulcanization. How is it carried out? (8) ii) Distinguish between physisorption and chemisorption (4) 10. i) Derive the Langmuirs adsorption isotherm and discuss the effect of pressure on the isotherm (12) 8.

1. What is the effect of increase in temperature and increase in pressure on the adsorption of gas on a solid? 2. What is Freundlich adsorption isotherm? 3. What is secondary battery? Give an example. 4. Distinguish between nuclear fission and fusion reactions? 5. What is Flash point and Pour point? 6. Under what situations solid lubricants are used? 7. How is arsenic poisoning removed? Part B Answer all the questions 3x12=36 i) Explain the mechanism of free radical polymerization. (8) ii) What is FRP? List out its preparation and uses (4) 9. i) What is natural rubber? Explain why natural rubber needs vulcanization. How is it carried out? (8) ii) Distinguish between Physisorption and Chemisorption (4) 10. i) Derive the Langmuirs adsorption isotherm and discuss the effect of pressure on the isotherm. (12) 8.

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SRI SHANMUGHA COLLGE OF ENGINEERING AND TECHNOLOGY Pullipalayam, Morur- 637 304, Sankari Taluk, Salem District Model Examination II, Jan 2012 Session: AN

SRI SHANMUGHA COLLGE OF ENGINEERING AND TECHNOLOGY Pullipalayam, Morur- 637 304, Sankari Taluk, Salem District Model Examination II, Jan 2012 Session: AN

CY2111 - Engineering Chemistry I Time: 1.5Hrs Total Marks: 50 Date: 10.01.2012 Time: 1.5Hrs

CY2111 - Engineering Chemistry I Total Marks: 50 Date: 10.01.2012

Part A - Answer all the questions

7x2=14

Part A - Answer all the questions

7x2=14

1. What is break point chlorination? 2. How can prepare PET? 3. What is breeder reactor? 4. Write the overall equation for the reaction taking place in an alkaline battery 5. Write the charging and discharging reaction of lead accumulator 6. How is carborundum prepared? 7. Explain the lubrication action of graphite. Part B Answer all the questions 3x12=36 8. i) What is the role of activated carbon in air and water pollution control? (8)

1. What is break point chlorination? 2. How can prepare PET? 3. What is breeder reactor? 4. Write the overall equation for the reaction taking place in an alkaline battery 5. Write the charging and discharging reaction of lead accumulator 6. How is carborundum prepared? 7. Explain the lubrication action of graphite. Part B Answer all the questions 3x12=36 8. i) What is the role of activated carbon in air and water pollution control? (8)

ii) Describe the construction and working of H2-O2 fuel cell. (4) 9. What are the components present in nuclear reactor and explain their function. Explain with neat diagram of light water nuclear power plant (12) 10. i) Write a note on carbon nano tubes? Explain its important applications (8) ii) Explain any two properties of Refractories (4)

ii) Describe the construction and working of H2-O2 fuel cell. (4) 9. What are the components present in nuclear reactor and explain their function. Explain with neat diagram of light water nuclear power plant (12) 10. i) Write a note on carbon nano tubes? Explain its important applications (8) ii) Explain any two properties of Refractories (4) *****

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