Robie 1995

The
amic Properties
-stances at 298.
U.S. GEOLOGICAL SURVE^ BULLETIN 2131
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Thermodynamic Properties of Minerals and

Related Substances at 298.15 K and 1 Bar
(105 Pascals) Pressure and at Higher Temperatures
By Richard A. Robie and Brace S. Hemingway
U. S. GEOLOGICAL SURVEY BULLETIN 2131

A summary of the thermodynamic data for minerals at
298.15 K together with calculated values for the Junctions
CP>T , AfH?, AfG?, S?, (H? - HgJT1. and (G? at temperatures up to 1800 K
UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1995
U.S. DEPARTMENT OF THE INTERIOR

BRUCE BABBITT, Secretary
U.S. GEOLOGICAL SURVEY
GORDON P. EATON, Director
For sale by U.S. Geological Survey, Information Services

Any use of trade, product, or firm names in this publication is for descriptive purposes only and
does not imply endorsement by the U.S. Government.
Published in the Eastern Region, Reston, Va.

Manuscript approved for publication March 23, 1995.
Library of Congress Cataloging in Publication Data

Robie, Richard A., 1928Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar (10
Pascals) pressure and at higher temperatures / by Richard A. Robie and Bruce S.
Hemingway.
p. cm. (Geological Survey bulletin ; 2131)
Includes bibliographical references and indexes.
Supt.ofDocs.no.: I 19.3:82131
1. Minerals Tables. 2. Thermodynamics Tables. I. Hemingway, Bruce S. II. Title. III.
Series: U.S. Geological Survey bulletin ; 2131.
QE75.B9no. 2131
[QE366.8]
557.3 s dc20
[549'. 12]
95-19844
CIP
CONTENTS
Abstract........................................................................................................................... 1
Introduction..................................................................................................................... 1
Physical Constants and Atomic Weights......................................................................... 2
Reference States.............................................................................................................. 3
Methods of Calculation................................................................................................... 3
Additional Comments..................................................................................................... 4
Thermodynamic Properties at 298.15 K......................................................................... 5
Elements................................................................................................................ 5
Sulfides and Sulfosalts.......................................................................................... 11
Oxides and Hydroxides......................................................................................... 15
Multiple Oxides .................................................................................................... 21
Halides.................................................................................................................. 23
Carbonates and Nitrates........................................................................................ 25
Sulfates andBorates.............................................................................................. 28
Phosphates, Molybdates, and Tungstates.............................................................. 30
Ortho and Ring Structure Silicates ....................................................................... 31
Chain and Band Structure Silicates....................................................................... 34
Framework Structure Silicates.............................................................................. 36
Sheet Structure Silicates ....................................................................................... 39
Coefficients for Heat Capacity Equations....................................................................... 41
Elements................................................................................................................ 41
Sulfides and Sulfosalts.......................................................................................... 45
Oxides and Hydroxides......................................................................................... 47
Multiple Oxides .................................................................................................... 51
Halides.................................................................................................................. 53
Carbonates and Nitrates........................................................................................ 55
Sulfates and Phosphates........................................................................................ 56
Ortho and Ring Structure Silicates ....................................................................... 58
Chain and Band Structure Silicates....................................................................... 61
Framework Structure Silicates.............................................................................. 63
Sheet Structure Silicates ....................................................................................... 65
Thermodynamic Properties at High Temperature of Individual Phases ......................... 67
References Cited.............................................................................................................397
Namelndex.....................................................................................................................454
Formula Index.................................................................................................................458
TABLE
1. Atomic weights of the elements for 1985..................................................................
HI
iv
CONTENTS
SYMBOLS, CONSTANTS, AND CONVERSION FACTORS

T Temperature in Kelvins.
Ttm Temperature of transition in Kelvins.
K Kelvin, the unit of temperature. It is the fraction 1/273.16 of the thermodynamic temperature of the triple point of water.
J Joule, the unit of energy (or work). One joule = 1/4.1840 thermochemical calories or
10 cm3bar.
mol Mole, the amount of substance of a system that contains as many elementary entities
as there are atoms in 0.012 kilograms of carbon 12. It is identical with the gfw (gram
formula weight),
p Pressure in bars. One bar = 105 Pascals or 0.1 MPa. The standard atmosphere is equal
to 101325 Pascals. The kilogram-cm"2 is equal to 98065.5 Pascals.
0 Superscript indicates that the substance is in its standard state, 1 bar (105 Pascals) for
a condensed phase.
HT- H298 Enthalpy at temperature T relative to 298.15 K in J'mol"1, also called the heat content.
(HJ - H^g)"!"1 Enthalpy function in JnnoH'K"1 (See note below).
ST Entropy at temperature T, in J-mor^K"1.
Gibbs energy function in JnnoH'K"1 .
Heat capacity at constant pressure in Jmior^K"1.
Volume of 1 mol of a substance at 1 bar pressure and at 298.15 K, in cm3, or J'bar"1.
AfuSH Enthalpy of melting at 1 bar pressure in J'mol"1.
AfcnH0 Enthalpy of transition at 1 bar pressure in J'mol"1.
AVapH Enthalpy of vaporization to the ideal gas at 1 bar pressure at the normal boiling point
in J^mol"1.
AfH Enthalpy of formation from the elements in their reference states in J'mol"1 .
AfG Gibbs energy of formation from the elements in their reference states in J^mol"1 .
Kf Equilibrium constant of formation.
R Gas constant, 8.314510.00007 I-K^-mol"1 .
F Faraday constant, 96,485.3090.029 I-V^-mol"1.
NA Avogadro constant, (6.02213670.0000036) x 1023mor1.
log Common logarithm, base 10.
In Natural logarithm, base e = 2.71828...
atm Standard atmosphere.
m=l The standard state for an electrolyte in aqueous solution is the hypothetical ideal solution at unit activity and with the ions at infinite dilution.
When multiple units appear in the denominator of the symbol (for example, enthalpy function), the
SI system does not recommend a particular order. For example, the units for entropy are given as J
mol-1 K"1 in table 2.11 and as J K"1 mol"1 in table 3.5 of the Greenbook (278).
Thermodynamic Properties of Minerals and Related Substances

at 298.15 K and 1 Bar (105 Pascals) Pressure
and at Higher Temperatures
By Richard A. Robie and Bruce S. Hemingway
ABSTRACT
Selected values for the entropy (S), molar volume
(V), and for the enthalpy and Gibbs energy of formation
(AfH and AfG) are given for 50 reference elements, 55 sulfides, 93 oxides and hydroxides, 141 silicates, and 154 other
minerals and related substances at 298.15 K. For those minerals for which high-temperature heat-capacity or heatcontent data are also available (Hf - H^T"1, Sj, (Gf H^g)!"1, CJ, AfHT.AfGjand log Kf>T are tabulated at
100 K intervals for temperatures up to 1800 K.
INTRODUCTION
In the 17 years since the predecessor to this bulletin
was published, an enormous body of new thermochemical
and equilibrium measurements for minerals has been published, personal computers have become almost universally
available, and a number of "internally consistent thermodynamic property databases" (ICTDB) have been published
(37, 67, 117, 149,150,159,187, 188, 374). (In this section,
references are indicated by numbers in parentheses.) This
report is an updated revision and expansion of U.S. Geological Survey (USGS) Bulletin 1452 (361) and entirely supersedes it. As an example of growth of the thennodynamic
properties of mineral database, USGS Bulletin 1452 contained data for 58 silicate minerals whereas in the current
set of tables this number has been increased to 141.
The purpose of these tables is to present a critical summary of the available thennodynamic data for minerals and
related substances in a convenient form for the use of earth
scientists. To make the tables as useful as possible, we have
tried (1) to include enough auxiliary data so that a single set
of tables would suffice for most calculations, (2) to ensure
internal consistency, and (3) to provide the means for rapid
revision and expansion as new data become available.
The tables in this compilation are divided into three
sections. In the first section, values are given for the entropy
(8293), molar volume (Vigg), enthalpy of formation
, Gibbs energy of formation (AfG^g), and the logarithm of the equilibrium constant of formation (log Kft29g)
for the reference elements, minerals, and other substances
of geological interest (properties at 298.15 K and 1 bar). In
the second section, coefficients for the polynomial used to
represent the heat capacity at high temperature are tabulated
together with the temperature limits of applicability. In the
third section, values are given for the thennodynamic properties at 100 K intervals for temperatures up to 1800 K. The
data are arranged in order of their conventional mineralogical groups. Within each group (for example, the oxides) the
listing is by alphabetical order of the chemical symbol of
the principal cation.
The data have been taken from the original literature,
recent critical evaluations, or have been evaluated by the
present authors and estimated uncertainties have been
assigned to the thennodynamic properties at 298.15 K. The
primary sources of data are indicated numerically in the
thennodynamic table of properties at 298.15 K, as "S" for
the reference to the data for the entropy, "H/G" for the reference to the formation properties, and "C" to references to
measured heat capacities above 298.15 K. The references
are listed in complete form following the tables. The
entropy and heat-capacity values tabulated are based almost
exclusively on calorimetric measurements whereas the values for the enthalpy or Gibbs energy of formation were
obtained from both equilibrium and calorimetric measurements. The values for the thennodynamic properties of the
reference elements have been taken from the JANAF tables
(67), the CODATA (85) recommended values, or in the case
of calcium, from measurement at the USGS (360). For those
silicate glasses for which Sf - S has been determined calorimetrically and for which the enthalpy of fusion of the
crystalline equivalent could be evaluated, the residual
entropy (that is, SQ) of the glass has been evaluated and
added to the calorimetric entropy to obtain the correct
entropy for use in thennodynamic calculations. Glasses and
other phases for which Sj - SQ has been measured but for
which the residual entropy has not been evaluated are indicated by a "+" sign and the user must be aware that the
THERMODYNAMIC PROPERTIES OF MINERALS AND RELATED SUBSTANCES
value tabulated does not include the configuration^

entropy.
Although a number of different forms of equations for
the representation of the heat capacity at high temperatures
have been proposed over the past 10 years, for example
Berman (37), Fei and Saxena (104), Richet and Piquet
(342), we have retained the form adopted in the previous
version of these tables,
Cp = A! + A2 T + A3-T-2 +
This equation can not be extrapolated beyond its upper
limit Inasmuch as most users will have access to a personal
computer, the conversion from one form of equation to an
alternative form is possible and is left up to the individual
user's preference. The entropies listed in the table of coefficients for the Cp polynomials corresponds to the temperature at the lower limit of the temperature range for the
polynomial. This is usually 298.15 K.
For several phases, the existence of multiple transitions at high temperature makes it impractical to provide a
simple polynomial expression for the heat capacity. For
such phases, for example Fe, Cui.gS, and several pyrrhotites, we have listed only the heat capacity at 298. 15 K.
For these phases, one must go to the high-temperature
table for the particular phase (if tabulated) to get the heat
capacity (and entropy) above room temperature.
Internally consistent thermodynamic property data sets
for silicate minerals have been published by Haas et al.
(149), Holland and Powell (187, 188), Berman (37), Halbach and Chatterjee (150), and Saxena and Chatterjee (374)
among others. Inasmuch as most of the authors relied on the
same sources of calorimetric and equilibrium data to derive
their adopted values, it is surprising that significant differences in their listed values for such important phases as
grossular, anorthite, phlogopite and muscovite exist. For
example, between the most frequently cited ICTDB, those
of Berman (37) and Holland and Powell (188), the values of
calculated from their listed values of S^g and
differ by 5.7, 3.7 and 3.7 kJTnoH for grossular,
anorthite, and muscovite, respectively, and for analbite and
muscovite the tabulated entropies differ by 4.4 and 9.1
JmioH'K"1, respectively. The point is, of course, that internal consistency does not imply that the derived values are
accurate.
The reason for these discrepancies is most likely in the
assumptions that the individual compiler makes concerning
the state of internal Al/Si order. For a 1:3 AJ/Si compound
such as the alkali feldspars or micas the complete random
mixing of the 3 Si and 1 Al over the 4 tetrahedral sites leads
to a contribution to the entropy of 18.7 Jmol~1K~1. However, if the aluminum-avoidance model is valid, the configurational entropy will be considerably smaller and of the
order of 13 to 14 J'mol'^K"1. The aluminum-avoidance
model has not been calculated exactly and only approxi-
mate values are available. The values for the configurational entropies that have been derived from phase
equilibrium studies by Holland and Powell (188) and by
Berman (37) are 12.6 and 17.0 J'moH-K-1 for analbite and
16.0 and 15.1 JnnoH'K"1 for sanidine, respectively. It
appears that these calculated values for the entropy of disorder do not unequivocally support the aluminum-avoidance
model but rather tend to yield a configurational entropy that
is greater than that estimated by the aluminum-avoidance
value, but definitely less than the fully random model. Any
value of AS greater than that calculated from aluminumavoidance would presumably mean that this model was
inapplicable at high temperatures; for example, at temperatures greater than 1300 K for analbite the disordering
entropy would approach 18.7 JmioH'K"1. Moreover Goldsmith and Jenkins (123) have shown that the Al/Si disorder
in NaAlSi3Og is a continuous function of the temperature
and that it occurs over a range of several hundred degrees
(500-1050 K) and occurs without change in symmetry.
As a consequence of these points the question arises
whether one can extract meaningful (unique) values for the
entropy of the disordered phase of an alumino-silicate from
phase equilibrium studies without having additional information on the Al/Si distribution. For this reason, we have
adopted the fully random model for tabulating the hightemperature properties for the Al/Si disordered feldspars
and micas. For an extended discussion of the contribution to
the entropy of silicate minerals arising from Al/Si or magnetic spin disorder, see Ulbrich and Waldbaum (413).
The differences in the derived values for the thermodynamic properties of phases in the CASH system is due in
part to the existence of two calorimetric values for the
entropy of grossular which differ from one another by 4.6
J-moH-K-1. The value of Westrum et al. (438) was determined on a natural sample and involved a substantial correction for impurities. The value given by Haselton and
Westrum (157) was derived from measurements on a synthetic sample. The heat capacity of the synthetic sample
used by Haselton and Westrum (157) was later remeasured
at the USGS by the present authors (359), who found an
entropy S(Ca3Al2Si3Oi2, 298.15 K) of 259.9 J-moH-K-1
which agrees with the Haselton and Westrum value to
within 0.2 Jnnol^K"1 (0.08 percent). For this reason we
have accepted the Haselton-Westrum value for the entropy
of grossular in evaluating the thermodynamic properties of
phases in the CASH system.
PHYSICAL CONSTANTS AND ATOMIC

WEIGHTS
The symbols and constants used to prepare these tables
are listed in the table of contents. The units adopted for
reporting the thermodynamic properties are those of the
International System of Units (SI). A formal description of
METHODS OF CALCULATION
the SI system is given by Goldman and Bell (122). The recommended symbols and terminology used are those from
the International Union of Pure and Applied Chemistry
(IUPAC), "Quantities, Units and Symbols in Physical
Chemistry", by Mills et al. (278) and commonly called the
"Greenbook". The Greenbook is also a convenient source
for the CODATA values of the fundamental physical constants, the 1985 atomic weights of the elements, and contains a detailed description of the SI system of units.
Values for the gas constant (R), the Faraday constant
(F), and the Avogadro constant (A) used in the calculations
are those adopted by the CODATA Task Group from the
least squares evaluation of Cohen and Taylor (75). For convenience, we also give values for the atomic weights for
1985 (scale C12 = 12.000, Mills et al. (278)) in alphabetical
order by their chemical symbol in table 1.
or that species for which the best thennodynamic data are

available as the reference state.
The reference states for AfH, AfG, and log Kf of the
compounds are the elements in their standard states at 1 bar
pressure and the stated temperature.
METHODS OF CALCULATION
Having chosen what we believe are the currently "best
available" values for Hf - H&g, or Cj (T), S&g and either
AfHlgg or AfGsgg, we have calculated the Gibbs energy
function, and the enthalpy, Gibbs energy, and the equilibrium constant of formation at 100 K intervals using the following relations:
- ST
REFERENCE STATES
= AfH^g + TA[(GT The reference pressure for the standard state adopted
for these tables is 1 bar, that is 105 Pascals. For a gaseous
phase, C, (HT - H^g)!"1, and AfH are independent of
pressure, but the numerical values of 8, (Gf - H^gyT"1,
AfG depend upon the choice of pressure. The change in
pressure from p = 1 atm (1.0135 bar) to 1 bar yields AS =
0.11 Jnnol-^K"1. For a condensed phase (liquid or solid), it
can be shown that the effect of changing the reference pressure from 1 atm to 1 bar has only a trivial effect upon all the
thennodynamic properties tabulated in this report except for
AfG, where a change will occur if one of the reference elements (usually oxygen) is a gas.
The standard states for the condensed elements are the
most stable form at 1 bar pressure and the stated temperature. For gaseous elements, the standard state is the ideal
gas at 1 bar pressure. Data are listed for the elements in their
standard reference states, and for a few in nonstandard
states; for example, S2 gas and the diamond form of carbon.
The reference state adopted for an element above its normal
boiling or sublimation temperature is not necessarily its
equilibrium state. Thus, at equilibrium, liquid sulfur boils at
1 bar pressure and approximately 716.9 K to a gas composed of S, 82, 84, 85, Sg, etc., but for our reference table,
we have assumed the gas phase to be only 82. For the reference state table for sulfur we have followed the JANAF
(67) tables procedure using 882.12 K as the fictive boiling
temperature at which liquid sulfur is in equilibrium with 82
gas at 1 bar pressure. Because of the convenience of using
diatomic sulfur gas in calculations of sulfide mineral equilibria we have included a second set of high-temperature
tables for which the reference state for calculating AfG,
and AfH and log Kf for the sulfide phase is 82 gas. The user
is cautioned not to intermix values from the two different
reference states in their calculations. In other ambiguous
cases, we have chosen either the dominant species in the gas
and
log Kf;r =AfGx(2.30258 RT)'1 = -AfG^gC^.HST)-1
These values together with Cj, Sj and (H| - H^g)!"1 are
tabulated in the third section.
Transitions in heat capacity are treated in the standard
manner: heat capacity curves are fit to the experimental values above and below the transition; values calculated from
an extrapolation of the equation to the transition temperature are compared to the experimental values; and differences are summed to give an enthalpy of transition that is
applied at the transition temperature.
The uncertainties assigned to the properties apply only
to the values at 298.15 K. The principal source has been the
original report of the experimental data. By convention, the
uncertainty interval reported for calorimetric measurements
is twice the standard deviation of the mean; that is,
5 = 2[Z(xi -xm)2/n(n-l)]*
where xj is the value for an individual measurement, xm is
the arithmetic mean of all the measurements, and n is the
number of measurements.
For generating the high-temperature tables, the input
data supplied to the computer are the identifying name of
the substance, the entropy, the enthalpy of formation at
298.15 K, the number of atoms of each element in the
chemical formula, and the coefficients for the heat capacity
equation. A commercial spreadsheet is used to compute the
formula weight of the compound and values for Sf,
AfGT, log Kf,x, CJ, (HT - HSwyr1. and (GT at 100 K intervals up to 1800 K. Auxiliary data such as the
melting and boiling points and enthalpies of melting and
vaporization are also included. In addition, coefficients
THERMODYNAMC PROPERTIES OF MINERALS AND RELATED SUBSTANCES
from a regression performed on the calculated values of

are included. The equation adopted is:
The coefficients for the equations are listed, in scientific

notation, at the bottom of the page for the individual hightemperature tables. The equations are given only for those
minerals for which the regression yielded a fit of better than
1 percent.
ADDITIONAL COMMENTS
Small numbers of some groups are presented with
other groups for convenience and economy. Examples
include tellurides, selenides and arsenides that are included

with sulfides and sulfosalts, and methane, cohenite, and
ammonia that are included with the elements.
The data available in this publication are also available
on diskette for a nominal fee through the Generic Mineral
Technology Center for Pyrometallurgy at the University of
Missouri at Rolla as a part of the FREED database. FREED
is a thennodynamic database program for storing, retrieving, editing, and manipulating thennodynamic data on a
computer. FREED was developed with support from the
U.S. Department of Interior's Mineral Institute Program,
administered by the U.S. Bureau of Mines, and the U.S.
Department of Energy through the Westinghouse Savannah
River Plant.
Table 1. Atomic weights of the elements for 1985.

Element
Actinium ....................... ................
Silver............................. ................
Aluminum..................... ................
Americium .................... ................
Argon............................ ................
Arsenic .......................... ................
Astatine ......................... ................
Gold.............................. ................
Boron............................ ................
Barium .......................... ................
Beryllium ...................... ................
Bismuth......................... ................
Bromine ........................ ................
Carbon........................... ................
Calcium......................... ................
Cadmium....................... ................
Cerium .......................... ................
Chlorine ........................ ................
Cobalt............................ ................
Chromium ..................... ................
Cesium .......................... ................
Copper........................... ................
Dysprosium................... ................
Erbium .......................... ................
Europium ...................... ................
Fluorine......................... ................
Iron.............................. . ................
Francium ....................... ................
Gallium ......................... ................
Gadolinium ................... ................
Germanium ................... ................
Hydrogen ...................... ................
Helium...........................................
Hafnium ........................ ................
Mercury..........................................
Holmium ........................................
Iodine.............................................
Indium........................... ................
Indium .......................... ................
Potassium.......................................
Krypton ......................... ................
Lanthanum.....................................
Lithium ..........................................
Lutetium... ..................... ................
Magnesium ................... ................
Manganese .....................................
Molybdenum..................................
Nitrogen .........................................
Symbol
Atomic Weight
Element
Symbol
Atomic Weight
Ac
Ag
Al
Am
Ar
As
At
Au
B
Ba
Be
Bi
Br
C
Ca
Cd
Ce
Cl
Co
Cr
(227)
107.8682
26.98154
(243)
39.948
74.92159
(210)
196.96654
10.811
137.327
9.01218
208.98037
79.904
12.011
40.078
112.411
140.115
35.4527
58.9332
51.9961
Sodium........................... ...............
Niobium ......................... ...............
Neodymium.................... ...............
Neon............................... ...............
Nickel............................. ...............
Neptunium...................... ...............
Oxygen........................... ...............
Osmium.......................... ...............
Phosphorus ..................... ...............
Protactinium ................... ...............
Lead................................ ...............
Palladium ....................... ...............
Polonium........................ ...............
Promethium.................... ...............
Praseodymium................ ...............
Platinum......................... ...............
Plutonium....................... ...............
Radium........................... ...............
Rubidium........................ ...............
Rhenium......................... ...............
Na
Nb
Nd
Ne
Ni
Np
O
Os
P
Pa
Pb
Pd
Po
Pm
Pr
Pt
Pu
Ra
Rb
Re
22.98977
92.90638
144.24
20.1797
58.69
(237)
15.9994
190.2
30.97376
231.03588
207.2
106.42
(209)
(145)
140.90765
195.08
(244)
(266)
85.4678
186.207
Cs
Cu
Dy
Er
Eu
F
Fe
Fr
Ga
Gd
Ge
H
He
Hf
Hg
Ho
I
In
Ir
K
Kr
La
Li
Lu
Mg
Mn
Mo
N
132.90543
63.546
162.50
167.26
151.965
18.99840
55.847
(223)
69.723
157.25
72.61
1.00794
4.00260
178.49
200.59
164.93032
126.90447
114.82
192.22
39.0983
83.80
138.9055
6.941
174.967
24.3050
54.93805
95.94
14.00674
Rhodium......................... ...............
Radon............................. ...............
Ruthenium...................... ...............
Sulfur.............................. ...............
Antimony ....................... ...............
Scandium........................ ...............
Selenium ........................ ...............
Silicon ............................ ...............
Samarium....................... ...............
Tin.................................. ...............
Strontium........................ ...............
Tantalum ........................ ...............
Terbium .......................... ...............
Technetium..................... ...............
Tellurium........................ ...............
Thorium.......................... ...............
Titanium......................... ...............
Thallium......................... ...............
Thulium.......................... ...............
Uranium ......................... ...............
Vanadium ....................... ... ........ .
Tungsten......................... ...............
Xenon............................. ...............
Yttrium........................... ...............
Ytterbium....................... ...............
Zinc ................................ ...............
Zirconium....................... ...............
Rh
Rn
Ru
S
Sb
Sc
Se
Si
Sm
Sn
Sr
Ta
Tb
Tb
Te
Th
Ti
Tl
Tm
U
V
W
Xe
Y
Yb
Zn
Zr
102.90550
(222)
101.07
32.066
121.75
44.95591
78.96
28.0855
150.36
118.710
87.62
180.9479
158.92534
(98)
127.60
232.0381
47.88
204.3833
168.93421
238.0289
50.9415
183.85
131.29
88.90585
173.04
65.39
91.224
ELEMENTS
THERMODYNAMIC PROPERTIES OF ELEMENTS IN THEIR REFERENCE STATE AT 298.15 K
NAME AND FORMULA
WEIGHT
ENTROPY
VOLUME
ENTHALPY
S
mot-1 -IT1
V
cJ
M
kJ-mol 1
107.868
42.55
0.21
107.868
73.45
0.40
ALUMINUM (REFERENCE STATE)

Al
26.982
28.30
0.08
Al3*
(AQUEOUS ION)
STD. STATE, M = 1
26.982
ARSENIC (REFERENCE STATE)

As
74.922
35.69
0.84
GOLD (REFERENCE STATE)

All
196.967
BORON (REFERENCE STATE)

B
BARIUM (REFERENCE STATE)
SILVER (REFERENCE STATE)
Ag
Ag*
(AQUEOUS ION)
STD. STATE, M 1
10.272
0.002
9.999
0.001
-332
10
REFERENCES
FREE
ENERGY
M
kJ-mol 1
LOG(K)
0.0
0.0
0.00
85
105.8
0.1
77.1
0.1
-13.50
0.02
85
0.0
0.0
0.00
67
92
H/G
85
85
92
67
-538.4
1.5
-489.4
1.4
12.963
0.020
0.0
0.0
0.00 361
47.49
0.21
10.215
0.002
0.0
0.0
0.00 361
10.811
5.83
0.08
4.386
0.007
0.0
0.0
0.00
67
85
67
85
137.327
62.42
0.84
38.21
0.02
0.0
0.0
0.00 361
361
137.327
8.40
0.50
-532.5
1.0
-555.4
1.0
97.30
0.18
54
9.012
9.50
0.08
4.880
0.002
0.0
0.0
0.00
85
67
85
67
BISMUTH (REFERENCE STATE)

Bi
208.980
56.74
0.42
21.31
0.01
0.0
0.0
0.00 361
361
127
BROMINE (REFERENCE STATE)

Br2
(LIQUID)
159.808
152.20
0.30
54.58
0.20
0.0
0.0
0.00
85
67
BROMINE (IDEAL GAS)

Br2
159.808
245.47 24789.7
0.05
0.2
30.9
0.1
3.1
0.3
-0.55
0.05
85
85
Br~
(AQUEOUS ION)
STD. STATE, M = 1
79.904
82.55
0.20
-121.4
0.2
-103.8
0.2
18.18
0.04
85
85
GRAPHITE (REFERENCE STATE)

C
12.011
5.74
0.10
5.298
0.001
0.0
0.0
0.00
85
DIAMOND
C
12.011
2.38
0.20
3.417
0.001
1.9
0.0
2.9
0.1
Ba
Ba2* (AQUEOUS ION)
STD. STATE, M = 1
BERYLLIUM (REFERENCE STATE)
Be
86.11 85 85
0.79 170 330
361
54
67
85
-0.51 419 419 419

0.02

NAME AND FORMULA
WEIGHT
g
CALCIUM (REFERENCE STATE)
Ca
40.078
Ca2*
(AQUEOUS ION)
STD. STATE, * = 1
40.078
ENTROPY
VOLUME
ENTHALPY
V
c.3
A,H
kJ-mol 1
J moi-'-r1
FREE
ENERGY
A.G'
kJ-mol 1
LOG(K)
REFERENCES
0.00 360
0.0
0.0
-543.0
1.0
-553.6
0.0
0.0
0.00
85
-75.9
0.6
-77.6
0.6
-13.59
0.11
85
20.77
0.02
0.0
0.0
0.00 419
223.08 24789.7
0.01
0.2
0.0
0.0
0.00
67
85
-167.1
0.1
-131.2
0.1
22.99
85
42.90
0.10
26.19
0.04
-56.2
1.0
CADMIUM (REFERENCE STATE)

Cd
112.411
Cd2* (AQUEOUS ION)

STD. STATE, M - 1
112.411
-72.8
1.5
CERIUM (REFERENCE STATE)

Ce
140.115
72.0
4.0
51.80
0.15
13.005
0.003
96.99
85
70.905
Cl"
(AQUEOUS ION)
STD. STATE, M = 1
35.453
56.60
0.20
COBALT (REFERENCE STATE)

Co
58.933
30.04
0.42
6.670
0.002
0.0
0.0
0.00 361
CHROMIUM (REFERENCE STATE)

Cr
51.996
23.62
0.21
7.231
0.001
0.0
0.0
0.00
67
CESIUM (REFERENCE STATE)

Cs
132.905
85.23
0.40
69.73
0.40
0.0
0.0
0.00
85
Cs* (AQUEOUS ION)

STD. STATE, M = 1
132.905
-258.0
0.5
-291.5
1.0
51.07
0.18
85
0.0
0.0
71.7
0.1
50.0
0.1
64.9
1.0
65.1
0.1
-11.40
0.02
85
0.0
0.0
0.00
67
85
-335.4
0.7
-281.5
0.7
49.32
0.12
85
COPPER (REFERENCE STATE)

Cu
63.546
33.14
0.03
Cu* (AQUEOUS ION)

STD. STATE, n = 1
63.546
40.60
0.40
Cu2* (AQUEOUS ION)

STD. STATE, M = 1
63.546
-98.0
4.0
FLUORINE (REFERENCE STATE)

F2
(IDEAL GAS)
37.997
202.79 24789.7
0.2
0.02
F"
(AQUEOUS ION)
STD. STATE, M = 1
18.998
-13.8
0.8
7.113
0.003
117
85
419
CHLORINE (REFERENCE STATE)

C1 2
(IDEAL GAS)
132.1
0.5
H/G
85
85
361
67
85
85
361
67
85
443
67
0.00 365
-8.76 419 419

0.02
85
67
85
85
ELEMENTS
NAME AND FORMULA
WEIGHT
FREE
ENERGY
M
kJ-mol 1
LOG(K)
0.0
0.0
0.00
ENTROPY
VOLUME
ENTHALPY
AfH
kJ-mol 1
J-nr1 'ir1
H/G
90
67
90
67
55.847
Fe2* (AQUEOUS ION)

STD. STATE, M = 1
55.847
-107.1
2.0
-91.1
3.0
-90.0
2.0
15.77 411 411

0.35
Fe3*
(AQUEOUS ION)
STD. STATE, M = 1
55.847
-280.0
13.0
-49.9
5.0
-16.7
2.0
2.93 411 411

0.35
GERMANIUM (REFERENCE STATE)

Ge
72.61
13.630
0.005
0.0
0.0
0.00
85
361
130.68 24789.7
0.02
0.2
0.0
0.0
0.00
67
85
67
85
361
2.016
H* (AQUEOUS ION)
STD. STATE, M = 1
1.008
31.09
0.15
7.092
0.004
IRON (REFERENCE STATE)

Fe
HYDROGEN (REFERENCE STATE)

H2 (IDEAL GAS)
27.09
0.13
a?
REFERENCES
0.00
0.0
0.0
0.00
75.90
0.12
14.822
0.002
0.0
0.0
0.00
85
170.2
0.2
163.5
0.2
-28.64
0.04
85
85
166.9
0.5
153.6
0.5
-26.91
0.09
85
85
67
MERCURY (REFERENCE STATE)

Hg (LIQUID)
200.59
Hg2* (AQUEOUS ION)

STD. STATE, M = 1
200.59
Hgf*
(AQUEOUS ION)
STD. STATE, M = 1
401.18
65.74
0.80
IODINE (REFERENCE STATE)

'2
253.809
116.14
0.30
51.29
0.06
0.0
0.0
0.00
85
IODINE
'2
253.809
260.69 24789.7
0.02
0.2
62.4
0.1
19.3
0.1
-3.39
0.01
67
126.904
106.45
0.30
-56.8
0.1
-51.7
0.1
9.06
0.02
85
POTASSIUM (REFERENCE STATE)

K
39.098
64.67
0.20
0.0
0.0
0.00
85
67
K*
(AQUEOUS ION)
STD. STATE, M * 1
39.098
101.20
0.20
-252.1
0.1
-282.5
0.1
49.48
0.01
85
LITHIUM (REFERENCE STATE)

Li
6.941
29.09
0.20
0.0
0.0
0.00
67
Li* (AQUEOUS ION)

STD. STATE, M = 1
6.941
12.24
0.15
-278.5
0.1
-292.9
0.1
51.31
0.01
85
(IDEAL GAS)
I~ (AQUEOUS ION)
STD. STATE, m = 1
-36.2
0.8
45.36
0.09
13.017
0.007
67
67
85
85
67
85
67
85
85

NAME AND FORMULA
WEIGHT
g
MAGNESIUM (REFERENCE STATE)
24.305
Mg
REFERENCES
FREE
ENERGY
M
kJ-mol 1
LOG(K)
0.0
0.0
0.00
85
67
-467.0
0.6
-455.4
0.6
79.78
0.11
85
0.0
0.0
0.00
91
-220.8
0.5
-228.1
0.5
9.387
0.005
0.0
0.0
0.00
91
91
191.61 24789.7
0.02
0.2
0.0
0.0
0.00
67
85
67
85
0.0
0.0
0.00
67
85
67
85
-240.3
0.1
-261.5
0.1
45.81
0.01
85
0.0
0.0
0.00
67
-54.0
0.9
-45.6
0.9
205.15 24789.7
0.02
0.2
0.0
0.0
17.3
0.3
0.0
0.0
18.267
0.006
0.0
ENTROPY
VOLUME
ENTHALPY
V
cm3
A,H
kJ-mol 1
nol-'-lf1
32.67
0.10
Mg2* (AQUEOUS ION)

STD. STATE, m = 1
24.305
MANGANESE (REFERENCE STATE)

Mn
54.938
32.01
0.08
Mn2* (AQUEOUS ION)

STD. STATE, m = 1
54.938
-73.60
1.00
MOLYBDENUM (REFERENCE STATE)

Mo
95.94
28.66
0.21
NITROGEN (REFERENCE STATE)

"2
28.013
SODIUM (REFERENCE STATE)

Na
22.990
51.46
0.20
Ma* (AQUEOUS ION)

STD. STATE, M = 1
22.990
58.45
0.15
NICKEL (REFERENCE STATE)

Ni
58.69
29.87
0.08
Ni 2* (AQUEOUS ION)
STD. STATE, m = 1
58.69
OXYGEN (REFERENCE STATE)

02 (IDEAL GAS)
31.999
PHOSPHORUS (REFERENCE STATE)

P
(WHITE)
30.974
13.996
0.007
-137.0
4.0
7.354
0.007
23.81
0.01
6.588
0.003
-128.9
2.0
41.09
0.25
H/G
85
85
91
39.96 419 419

0.09
85
67
7.99 419 419

0.15
85
67
85
0.00
85
85
0.0
0.00
67
67
0.9
0.3
-24.2
0.2
4.24
0.04
85
0.00
67
LEAD (REFERENCE STATE)

Pb
207.2
64.8
0.5
Pb2* (AQUEOUS ION)

STD. STATE, M * 1
207.2
18.5
1.0
PLATINUM (REFERENCE STATE)

Pt
195.08
41.63
0.21
9.091
0.004
0.0
0.0
0.00 361
361
32.05
0.05
15.511
0.005
0.0
0.0
0.00
67
85
67
SULFUR (REFERENCE STATE)

S ORTHORHOMBIC
32.066
85
ELEMENTS
NAME AND FORMULA
WEIGHT
ENTROPY
VOLUME
ENTHALPY
S
mol-1 -*-1
M
kJ-mol 1
a?
SULFUR
S NONOCLINIC
32.066
33.03
0.05
S2" (AQUEOUS ION)

STD. STATE, M 1
32.066
-14.6
1.0
DIATOMIC SULFUR
S2 (IDEAL GAS)
64.132
228.17 24789.7
0.02
0.2
FREE
ENERGY
LOG(K)
W
kJ-mol'1
REFERENCES
H/G
67 419
67
0.3
0.1
0.0
33.1
1.0
85.8
1.0
-15.03 419 419

0.18
128.6
0.3
79.7
0.3
-13.96
0.05
0.00
67
67
67
ANTIMONY (REFERENCE STATE)

Sb
121.75
45.52
0.21
18.178
0.009
0.0
0.0
0.00 361
361
SELENIUM (REFERENCE STATE)
78.96
42.27
0.05
16.42
0.01
0.0
0.0
0.00
62
126
SILICON (REFERENCE STATE)

Si
28.086
18.81
0.08
12.056
0.002
0.0
0.0
0.00
67
85
67
H4Si04 (AQUEOUS ION)

STD. STATE, M * 1
96.115
-1460.0
1.7
-1307.5
2.1
229.12
0.37
TIN (REFERENCE STATE)

Sn (UNITE, TET.)
118.710
51.18
0.08
16.29
0.01
0.0
0.0
0.00
85
85
STRONTIUM (REFERENCE STATE)

Sr
87.62
55.69
0.20
33.92
0.02
0.0
0.0
0.00
39
67
Sr2* (AQUEOUS ION)

STD. STATE, M = 1
87.62
-550.9
0.5
-563.8
0.8
98.78
0.14
55
Se
180.0
4.2
-31.5
2.0
179 422
285 414
55
TELLURIUM (REFERENCE STATE)

Te
127.60
49.71
0.20
20.48
0.01
0.0
0.0
0.00 361
361
THORIUM (REFERENCE STATE)

Th
232.038
51.83
0.50
19.79
0.01
0.0
0.0
0.00 319
319
TITANIUM (REFERENCE STATE)

Ti
47.88
30.76
0.10
10.63
0.01
0.0
0.0
0.00
67
67
URANIUM (REFERENCE STATE)

U
238.029
50.2
0.2
12.50
0.02
0.0
0.0
0.00
85
85
VANADIUM (REFERENCE STATE)

V
50.942
28.94
0.42
8.350
0.004
0.0
0.0
0.00
67
67
32.65
0.10
9.545
0.004
0.0
0.0
0.00
67
67
TUNGSTEN (REFERENCE STATE)

U
183.85
10

NAME AND FORMULA
WEIGHT
ZINC (REFERENCE STATE)

Zn
65.39
Zn2* (AQUEOUS ION)

STD. STATE, M = 1
65.39
ZIRCONIUM (REFERENCE STATE)

Zr
91.224
METHANE
CH4
16.043
(IDEAL GAS)
COHENITE
FejC
179.552
ENTROPY
S
J-mol'-K 1
41.63
0.15
VOLUME
ENTHALPY
M"
kJ-mol 1
cJ
9.162
0.007
0.0
FREE
ENERGY
A**
kJ-mol 1
LOG(K)
0.0
0.00
REFERENCES
H/G
67
67
85
-153.4
0.2
-147.3
0.2
25.79
0.04
85
14.016
0.007
0.0
0.0
0.00
67
186.26 24789.7
0.21
0.2
-74.8
0.3
-50.7
0.4
23.23
0.01
24.9
1.3
19.7
1.7
-45.9
0.4
-16.4
0.4
2.87
0.06
67
67
-133.3
0.3
-79.4
0.3
13.91
0.05
85
85
-109.8
0.5
38.87
0.20
104.4
3.4
AMMONIA (IDEAL GAS)

Nil;
17.031
192.77 24789.7
0.03
0.2
NH4* (AQUEOUS ION)

STD. STATE, = 1
18.039
111.17
0.40
85
67
8.88 419 419

0.07 67 67
67
-3.45 361 361 361

0.30
67
SULFIDES AND SULFOSALTS
11
THERMODYNAMIC PROPERTIES OF SULFIDE MINERALS AT 298.15 K
LOG(K)
REFERENCES
ENTROPY
VOLUME
ENTHALPY
FREE
ENERGY
or1 -if1
V
*
kJ-mol 1
kJ-mol 1
247.802
142.9
0.3
34.19
0.04
-32.0
1.0
-39.7
1.0
6.96 141 121 141

0.18
52 306
REALGAR
AsS
106.988
63.5
0.6
29.80
0.24
-30.9
5.0
-29.6
5.0
5.19 429 419 270

0.88
270
ORPIMENT
246.041
163.6
1.6
70.51
0.25
-91.6
4.2
-90.4
4.2
15.84 372
0.74
50 210
514.159
200.4
3.3
75.52
0.04
-135.2
2.4
-132.4
2.6
23.20 372
0.46
52
800.761
261.1
5.0
101.85
0.09
-78.7
2.1
-78.2
2.6
72.144
56.7
1.3
27.72
0.09
-474.9
2.1
-469.5
2.1
82.25
0.37
67
67
279
GREENOCKITE
CdS
144.477
72.2
0.3
29.93
0.02
-149.6
1.3
-146.1
1.3
25.60
0.23
38
CATTIERITE
CoS2
123.065
74.8
0.2
25.52
0.01
-150.9
4.9
-145.1
4.9
25.42 399 60 326

376
0.86
LINNAEITE
C3S4
305.064
176.0
0.4
62.55
0.02
-347.5
7.3
-334.9
7.3
58.66 399
1.28
COVELLITE
CuS
95.612
67.4
0.1
20.42
0.02
-54.6
0.3
-55.3
0.3
9.69 109 337 109

442
0.05 442
ANILITE
^LTS8
143.272
107.5
0.2
25.79
0.02
-73.3
0.3
-78.5
0.3
13.76 133 337 133

140
0.05
DIGENITE
CU1.80S
146.449
109.6
0.2
25.63
0.05
-73.0
0.5
-78.3
0.5
13.72 133 337 133

0.09
DJURLEITE
CU1.95S
155.981
114.8
0.2
26.89
0.02
-78.8
0.4
-84.2
0.4
14.75 394 337 394

0.07
CHALCOCITE
CUgS
159.158
116.2
0.2
27.48
0.02
-83.9
1.1
-89.2
1.1
15.62 142 369 109

0.19 109 48 142
CHALCOPYRITE
CuFeS2
183.525
124.9
0.2
43.92
0.02
-194.9
1.6
-195.1
1.6
34.18 371 369 325

371 369
0.28
BORNITE
ClIeFeS,
501.841
398.5
0.8
98.73
0.05
-371.6
2.1
-394.7
2.1
69.32 369 369 325

369
0.37
NAME AND FORMULA
HEIGHT
ACANTHITE (ARGENTITE)
Ag2s
**zh
BISMUTHINITE
B12h
TELLUROBISMUTHITE
Bi 2Te3
OLDHAMITE
CaS
N/G
13.71 201 279

0.46
38
60
98
12

NAME AND FORMULA
WEIGHT
g
CUBAN ITE
CuFe^
271.438
NUKUNOAMITE
Cu5.5 FeS6.5
613.779
ENTROPY
VOLUME
ENTHALPY
V
c*3
M
kJ-mol 1
J or1 -*1
205.0
0.8
FREE
ENERGY
A.G"
kJ-mol 1
LOG(K)
REFERENCES
H/G
280
388
67.44
0.06
278.0
0.5
-564.5
3.4
98.90
0.59
17.75 143
0.26 347
369
TROILITE
FeS
87.913
60.3
0.2
18.20
0.03
-101.0
1.5
-101.3
1.5
PYRRHOTITE
Fe.875S
80.932
60.7
0.2
17.49
0.05
-97.5
2.0
-98.9
2.0
17.33 143 131 131

0.35
PYRRHOTITE
Fe.90S
82.328
63.2
0.1
16.88
0.10
-97.6
2.0
-99.6
2.0
14.45 135 375 135

0.35
119.979
52.9
0.1
23.94
0.01
-171.5
1.7
-160.1
1.7
28.05 138 409

0.30
67
MARCASITE
FeS2
119.979
53.9
0.1
24.58
0.02
-169.5
2.1
-158.4
2.1
27.75 139 139 139

0.37
LOELLINGITE
FeAs2
205.690
80.1
0.7
27.51
0.02
-57.8
5.0
-52.3
5.0
FERROSELITE
FeSe2
213.767
86.9
0.3
29.96
0.05
FROHBERGITE
311.047
100.2
0.2
38.43
0.05
-72.4
4.2
-64.6
4.2
205.8 24789.70
0.20
0.2
-20.6
0.6
-33.4
0.6
5.86
0.11
85
67
85
67
16.3
0.2
44.8
0.3
-7.86
0.05
85
85
PYRITE
FeS2
FeTe2
9.17 332
0.88
69 79
3 131
79
25
138
11.31 437 279

0.74
85
67
HYDROGEN SULFIDE (IDEAL GAS)

H2S
34.082
HS" (AQUEOUS ION)

STD. STATE, m = 1
33.074
67.0
0.9
CINNABAR
HgS
232.656
82.5
2.1
28.42
0.02
-54.3
2.1
-40.7
2.7
7.13 233 326

279
0.47
NETACINNABAR
HgS
232.656
96.2
4.2
30.17
0.02
-46.7
1.5
-43.3
0.8
7.59 217 120

0.15
NININGERITE
56.371
50.3
0.4
21.17
0.02
-345.7
4.2
-341.4
4.2
59.81
0.74
87.004
80.3
0.8
21.46
0.01
-213.9
0.8
-218.7
0.9
38.31 279
3 79
0.17
375 203
Mgs
ALABANDITE
MnS
67
67
67
13

NAME AND FORMULA
WEIGHT
ENTROPY
VOLUME
ENTHALPY
V
*
AfH
kJ-mol 1
FREE
ENERGY
LOG(K)
REFERENCES
kJ-mol 1
H/G
279
HAUERITE
MnS2
119 .070
99.9
0.1
34 .20
0 .01
-223.8
10.0
-224.6
10.0
39.35 441
1.75
MOLYBDENITE
NoS2
160 .072
62.6
0.2
32 .02
0 .02
-271.8
4.9
-262.8
4.9
46.04 275 305

0.86
90 .756
53.0
0.4
16 .89
0 .01
-91.0
3.0
-63.9
3.0
HEAZLEWOOOITE
Ni 3S2
240 .202
133.2
0.3
40 .95
0 .02
-216.3
3.0
-210.2
3.0
PENTLANDITE
Mi4.5 F4.5S8
771 .944
155 .40
0 .20
-837.4
14.6
59
VIOLARITE
<Mi .7Fe.3>3S4
301 .775
63 .80
0 .30
-378
11.8
59
GALENA
PbS
239 .266
91.7
0.7
31 .49
0 .01
-98.3
2.0
-96.8
2.0
16.96 67 397 67
0.35 326 245 326
CLAUSTHALITE
PbSe
286 .160
102.5
2.1
34 .61
0 .01
-100.1
2.3
-98.7
2.1
17.30 279 279

0.37
ALTAITE
PbTe
334 .800
110.0
2.1
40 .60
0 .01
-70.7
1.4
-69.4
1.5
12.15 217 419

0.27
COOPERITE
PtS
227 .146
55.1
0.1
22 .15
0 .01
-82.4
3.4
-76.9
3.4
13.46 136 136

0.59
STIBNITE
SbgSj
339 .698
182.0
3.3
73 .41
0 .04
-151.4
2.3
-149.9
2.1
26.26 234 382 211

0.37
53 51
HERZENBERGITE
SnS
150 .776
77.0
0.8
29 .01
0 .02
-106.5
1.5
-104.6
1.5
18.33 229 347 315

0.26
BERNDTITE
SnS2
182 .842
87.5
0.2
40 .96
0 .02
-149.8
5.0
-141.5
5.0
24.79 229 326 315

0.88
TUNGSTEN I TE
247 .982
67.8
0.3
32 .07
0 .02
-241.6
2.5
-233.0
2.5
40.82 304 303 304

304
0.44
SPHALERITE
ZnS
97.456
58.7
0.2
23 .83
0 .01
-204.1
1.5
-199.6
1.5
34.97 398 378 324

0.26
WURTZITE
ZnS
97.456
58.8
0.2
23 .85
0 .01
-203.8
1.5
-199.3
1.5
34.92 398 338 324

0.26
MILLERITE
NiS
us2
114
14.97 429 58 271

271 98
0.53
36.83 395
0.53
58 107
67 276
14

NAME AND FORMULA
WEIGHT
ENTROPY
VOLUME
ENTHALPY
FREE
ENERGY
CM3
kJ-mol 1
kJ-mol 1
LOG(K)
REFERENCES
.l-mol"1 -*"1
H/G
PROUST I TE
AgjAsSj
494.724
303.7
0.5
88.42
0.02
146
SMITHITE
AgA8S2
246.922
150.5
0.2
50.12
0.30
146
ENARGITE
CU3A8S4
393.824
257.6
0.6
88.24
0.12
381
ARSENOPYRITE
FeA81 .08S0.92
166.263
68.8
0.4
26.42
0.07
331
LIVINGSTONITE
HgSb4Sg
944.118
470.5
1.5
192.90
-373.2
6.5
-360.2
6.5
63.10 145 454

1.14
BERTHIERITE
FeSb2S4
427.611
245.0
1.0
92.22
0.20
-256.2
6.5
-255.8
6.5
44.82
1.14
CHALCOSTIBITE
CuSbS2
249.428
149.2
3.8
50.06
0.10
-130.8
4.4
-132.7
4.2
23.25 382 382 382

0.74
Fe-TENNANTITE
1463.698
1024.2
332.10
380
Fe-TETRAHEDRITE
Cu1QFe2Sb4Sl3
1651.012
1061.0
336.70
380
Zn-TENNANTITE
1482.784
1025.6
332.10
380
Zn-TETRAHEDRITE
1670.098
1062.4
336.70
380
97 382 382
PYRARGYRITE
AgjSbSj
541.553
92.56
0.04
-131.5
3
51
MIARGYRITE
293.750
52.03
0.09
-95.8
2.6
51
380.980
54.44
0.10
-165.3
8
52
a-AgSbS2
MATILDITE
B-AgBiS2
OXIDES AND HYDROXIDES
15
THERMODYNAMIC PROPERTIES OF OXIDE AND HYDROXIDE MINERALS AT 298.15 K
NAME AND FORMULA
WEIGHT
ENTROPY
S"
VOLUME
FREE
ENERGY
kJ-nol 1
kJ not'1
LOG(K)
REFERENCES
yo
<**
J-
ENTHALPY
277.20
0.23
H/G
93 268
94 85
94
57
CORUNDUM
A123
101.961
50.9
0.1
25.58
0.01
-1675.7
1.3
-1582.3
1.3
BOEHMITE
AIO(OH)
59.988
37.2
0.1
19.54
0.03
-996.4
2.2
918.4
2.2
160.90 176 176

0.39
12
DIASPORE
AIO(OH)
59.988
35.3
0.2
17.76
0.03
-1001.3
2.2
922.7
2.1
161.53 334 12
0.88 230 176
GIBBSITE
Al(OH)3
78.004
68.4
0.1
31.96
0.02
-1293.1
1.2
-H154.9
1.2
ARSENOLITE
A823
197.841
107.4
0.1
51.12
0.07
-657.0
1.7
576.0
1.9
100.90
0.33
61 419
CLAUDE T I TE
A823
197.841
113.3
0.1
47.26
0.03
-654.8
1.7
575.6
1.1
100.83
0.18
61
DIBOROH TRIOXIDE
B23
69.620
54.0
0.3
27.26
0.06
-1273.5
1.4
-1194.4
1.4
209.24
0.25
85
BARIUM MONOXIDE
BaO
153.326
72.1
0.4
25.59
0.01
-548.1
2.1
520.4
2.1
91.17
0.37
85
25.012
13.8
0.1
8.31
0.03
-609.4
2.5
580.1
2.5
101.63
0.44
85
465.959
151.5
2.1
49.73
0.06
-573.9
1.3
493.5
1.5
86.45 419 419 319

0.26
269
BROMELLITE
BeO
B I SMITE
Bi 23
202.33 178 171 178

212
0.21
85
67
67
77 85
111 262
85
67
418
CARBON MONOXIDE
CO (IDEAL GAS)
28.010
197.3 24789.70
0.0
0.20
-110.5
0.2
-137.1
0.2
24.01 67 67 67
0.03 117 117 117
CARBON DIOXIDE
CC^ (IDEAL GAS)
44.010
213.8 24789.70
0.0
0.20
-393.5
0.1
-394.4
0.2
69.09 67 67 67
0.03 117 117 117
COj"" (AQUEOUS ION)

STD. STATE, - 1
60.009
-50.0
1.0
-675.2
0.1
-527.0
0.3
92.33
0.05
85
36
85
36
HCOj" (AQUEOUS ION)

STD. STATE.
= 1
61.017
98.4
0.5
-689.9
0.2
-586.8
0.3
102.81
0.04
85
36
85
36
H2COj (UN- I OH I ZED)

STD. STATE.
= 1
62.025
184.7
0.9
-699.7
0.1
-623.2
0.1
109.17 419 419

0.02
LINE
CaO
56.077
38.1
0.4
-635.1
0.9
-603.1
0.9
105.66 67 67 67
0.16 117 117 117
16.76
0.01
16
IHERMODYNAMIC PROPERTIES OF MINERALS AND RELATED SUBSTANCES

THERMOOYNAHIC PROPERTIES OF OXIDE AND HYDROXIDE MINERALS AT 298.15 K
NAME AND FORMULA
UEIGHT
ENTROPY
S-
VOLUME
FREE
ENERGY
kJ-mor1
kJ-nor1
LOG(K)
REFERENCES
yo
<**
ENTHALPY
H/G
157.33 67 67 67
0.23 158 158 117
PORTLAND I TE
Ca(OH)2
74.093
83.4
0.4
33.06
0.02
-986.1
1.3
-898.0
1.3
MONTEPONITE
CdO
128.400
54.8
1.5
15.59
0.01
-258.4
0.4
-228.7
0.6
CERIANITE
CeOj
172.114
62.3
0.1
23.85
0.03
-1088.7
1.5
-1025.4
1.9
74.933
52.8
0.3
11.64
0.02
-237.9
1.3
-214.1
1.3
37.52 287 308 319

0.23
45 125
TR I COBALT TETRAOXIDE
C34
240.797
109.3
0.3
39.77
0.02
-918.8
2.0
-802.2
2.0
140.54 222 319 319

0.35
307
ESKOLAITE
Cr23
151.990
81.2
1.3
29.09
0.03
-1134.7
8.4
-1053.1
8.4
DICESIUM MONOXIDE
Cs20
281.810
146.9
. 0.4
59.62
0.07
-346.0
1.2
-308.4
1.2
54.02 112 384 112

0.21
TENOR I TE
CuO
79.545
42.6
0.2
12.22
0.03
-156.1
2.0
-128.3
2.0
22.48
0.35
CUPRITE
143.091
92.4
0.3
23.44
0.02
-170.6
0.1
-147.8
0.1
25.89 67 190 272

0.02 310 272 67
UUSTITE
Fe .947
68.887
56.6
0.4
12.04
0.04
-266.3
0.8
-244.9
0.8
42.91 67 198
0.14 132 148
83
67
FERROUS OXIDE (STOICHIOMETRIC)

FeO
71.846
60.6
1.7
12.00
0.05
-272.0
2.1
-251.4
2.2
44.05 67
0.38 132
67
HEMATITE
Fe23
159.692
87.4
0.2
30.27
0.01
-826.2
1.3
-744.4
1.3
130.41 137 161 83

0.23 67 310 130
MAGNETITE
231.539
146.1
0.4
44.52
0.01
-1115.7
2.1
-1012.7
2.1
177.42 440 161 161

0.37 22 310 134
GOETHITE
FeO(OH)
88.854
60.4
0.6
20.82
0.04
-562.6
2.1
-491.8
2.1
86.16 235 221

18
0.12
WATER
H20 (LIQUID)
18.015
70.0
0.1
18.07
0.00
-285.8
0.1
-237.1
0.1
41.55
0.01
85
85 117
67
OH' (AQUEOUS IOH)

STD. STATE. = 1
17.007
-10.7
0.2
-230.0
0.1
-157.3
0.1
27.56
0.02
85
85
COBALT MONOXIDE
CoO
40.07
0.11
85
179.64 436
0.34
184.49
1.47
67
67
85
267
14 227
67
267
67
67 272
272
67
17

THERNOOYNAMIC PROPERTIES OF OXIDE AND HYDROXIDE MINERALS AT 298.15 K
NAME AND FORMULA
WEIGHT
J<
ENTROPY
VOLUME
ENTHALPY
FREE
ENERGY
V
on3
kJ-mol 1
kJ-nor1
or1 -IT1
188.8 24789.70
0.0
0.20
LOG(K)
40.05
0.02
REFERENCES
H/G
85
85
67
117
-241.8
0.0
-228.6
0.1
20.82
0.01
-1117.6
1.3
-1061.1
1.3
70.3
0.3
19.32
0.02
-90.8
0.1
-58.5
0.1
10.25
0.01
85
85
415
67
94.196
94.1
6.3
40.38
0.20
-363.2
2.1
-322.1
2.8
56.43
0.49
67
67
67
POTASSIUM HYDROXIDE
KOH
56.106
78.9
0.8
27.45
0.02
-424.7
0.6
-378.9
0.6
66.39
0.11
67
67
254
67
DILITHIUM MONOXIDE
Li 20
29.881
37.6
0.3
14.76
0.01
-597.9
2.1
-561.2
2.1
98.31 319 209 319

0.37 419 67
PERICLASE
HgO
40.304
26.9
0.2
11.25
0.00
-601.6
0.3
' -569.3
0.3
BRUCITE
Mg(OH>2
58.320
63.2
0.1
24.63
0.07
-924.5
0.4
-833.5
0.4
146.02 419 419 228

193
0.07
MANGANOSITE
HnO
70.937
59.7
0.4
13.22
0.00
-385.2
0.5
-362.9
0.5
63.58 319 419 391

319
0.09
PYROLUSITE
Hn02
86.937
52.8
0.1
16.61
0.02
-520.0
0.7
-465.0
0.7
81.47 357 357 357

0.12
BIXBYITE
"^
157.874
113.7
0.2
31.37
0.05
-959.0
1.0
-882.1
1.0
154.53 357 357 357

0.18
HAUSMANNITE
Mnj04
228.812
164.1
0.2
46.95
0.06
-1384.5
1.4
-1282.5
1.4
224.68 357 357 357

0.25
BRAUNITE
MivSiO^
604.645
416.4
0.8
125.08
0.05
-4260.0
4.0
-3944.7
4.0
691.08 367 367 367

0.70
MOLYBDITE
MoO;
143.938
77.7
0.4
30.56
0.04
-745.2
0.4
-668.1
0.4
117.04
0.07
85
85
85
200
33.1
0.4
51.2
0.4
-8.98
0.07
67
67
67
-206.9
0.4
-110.8
0.4
19.42
0.07
85
85
STEAM
H20 (IDEAL GAS)
18.015
HAFNIUM DIOXIDE
Hf02
210.489
59.3
0.4
MONTROYDITE
HgO
216.589
DIPOTASSIUM MONOXIDE
K2
NITROGEN DIOXIDE
N02 (IDEAL GAS)
46.006
240.1 24789.70
0.1
0.20
NOj" (AQUEOUS ION)

STD. STATE.
= 1
62.005
146.7
0.4
185.90 319 256 319

0.23
319
99.74
0.05
85 85 418
67 321 117
18

THERMODYNAMIC PROPERTIES Of OXIDE AND HYDROXIDE MINERALS AT 298.15 1C
NAME AND FORMULA
ENTROPY
WEIGHT
S9
VOLUME
FREE
ENERGY
kJ-nol'1
kJ-mor1
LOG(K)
REFERENCES
yo
<**
ENTHALPY
H/G
DISODIUM MONOXIDE
Ma20
61.979
75.3
0.8
25.88
0.08
-414.8
0.3
-376.0
0.4
65.87
0.07
67 302
SODIUM HYDROXIDE
NaOH
39.997
64.4
0.8
18.78
0.06
-425.8
0.1
-379.6
0.3
66.50
0.05
67
BUNSENITE
NiO
74.689
38.0
0.2
10.97
0.02
-239.3
0.4
-211.1
0.4
36.99 271 161 161

0.07 419 191 319
PHOSPHORUS PENTOXIDE
P25
141.945
114.4
0.4
59.40
0.20
-1504.9
0.5
-1361.6
0.5
238.54 319 319

0.10 67 67
P04~~~ (AQUEOUS ION)

STD. STATE, * 1
94.971
-222.0
4.2
-1259.6
0.9
-1001.6
0.9
175.47 419 419

0.15
LITHARGE (RED)
PbO
223.199
66.5
0.2
23.91
0.05
-219.0
0.8
-188.9
0.8
33.10 72 419 319

0.14 419
MASSICOT (YELLOW)
PbO
223.199
68.7
0.2
23.15
0.03
-217.3
0.3
-187.9
0.3
32.92 419 15 319

0.06
419
PLATTNERITE
Pb02
239.199
71.8
0.4
25.01
0.01
-277.4
2.9
-218.3
2.9
38.25 319 419 319

0.51
MINIUM
685.598
212.0
6.7
76.81
0.09
-718.7
6.3
-601.6
6.6
105.40
1.16
67
67
419
67
85
Pbj04
67
419 115
67
419
67
SULFUR DIOXIDE
SOg (IDEAL GAS)
64.065
248.2 24789.70
0.1
0.20
-296.8
0.2
-300.1
0.2
52.57
0.04
85
67
117
SULFUR TR I OX IDE
SOj (IDEAL GAS)
80.064
256.8 24789.70
0.8
0.20
-395.7
0.7
-371.0
0.7
64.99 419 419

0.12 67 67
67
SOj" (AQUEOUS ION)

STD. STATE. * 1
80.064
-29.0
4.2
-635.5
0.9
-486.5
0.9
85.23 419 419

0.15
S04" (AQUEOUS ION)

STD. STATE. * 1
96.064
18.5
0.4
-909.3
0.4
-744.0
0.4
130.34
0.07
291.498
123.0
2.5
50.01
0.05
-708.6
2.9
-626.4
3.0
109.75 319 419

0.53
211.6 24789.70
0.8
0.20
-100.4
8.4
-127.3
8.4
-910.7
1.0
-856.3
1.0
VALENTINITE
SbfcOj
SILICON MONOXIDE
SiO (IDEAL GAS)
44.085
QUARTZ
SiOj
60.084
41.5
0.1
22.69
0.00
22.30
1.47
85
67
85
67
67
150.01 435 444 160

0.18 317 419 341
19
NAME AND FORMULA
WEIGHT
ENTROPY
Sol-'-lf1
J-
VOLUME
ENTHALPY
FREE
ENERGY
V
<**
kJ-ol 1
kJ-nol 1
LOG(K)
REFERENCES
H/G
179 422
285 414
-1460.0
1.7
-1307.8
2.1
25.74
0.03
-908.4
2.1
-854 .6
2 .1
149.71 435 67 286

0.37 404 341 341
43.9
0.4
26.53
0.20
-907.5
2.4
-853 .8
2 .4
149.58 361
0.43
286
404
60 .084
38.5
1.0
20.64
0.01
-907.8
2.1
-852 .5
2 .1
149.35
6
0.37 189
6 361
423
STISHOVITE
Si02
60 .084
27.8
0.4
14.01
0.01
-861.3
2.1
-802 .8
2 .1
140.65
6 189 361
0.37 189
SILICALITE
Si02
60 .084
46.3
0.2
33.29
0.5
-905.2
0.8
-852 .2
0 .8
149.30 213 213

0.14
SILICA GLASS
Si02
60 .084
48.5
1.0
27.27
0.10
-901.6
2.1
-849 .3
2 .1
148.79 341 341 341

0.37 435 444
CASSITERITE
Sn02
150 .709
49.0
0.2
21.55
0.03
-577.6
0.2
-515 .8
0 .2
90.36 449
0.04
85
16
STRONTIUM OXIDE
SrO
103 .619
55.5
0.4
20.69
0.01
-591.3
1.0
-560 .7
1 .0
98.22
0.18
46 67
77 262
TELLURITE
Te2
159 .599
70.4
0.3
27.75
0.02
-319.7
3.0
-264 .8
3 .1
46.39 333 419 319

78
0.54
THORIANITE
Th2
264 .037
65.2
0.2
26.37
0.01
-1226.4
3.5
-1169 .2
3 .5
204.84 419 419 417

389
0.61
RUTILE
TI02
79 .879
50.6
0.6
18.82
0.01
-944.0
0.8
-888 .8
1 .0
155.70
0.14
85 85
67 294
ANATASE
TJ02
79 .879
49.9
0.3
20.52
0.03
-938.7
2.1
-883 .2
2 .1
154.74
0.37
67
DITITANIUN TR I OX IDE
TfgOj
143 .758
77.3
1.0
31.43
0.02
-1520.9
8.4
-1433 .9
8 .4
251.21
1.47
67
URANINITE
U02
270 .028
77.0
0.2
24.62
0.01
-1084.9
1.0
-1031 .7
1 .0
180.75 199 419 113

0.18 248 248 128
KARELIANITE
V23
149 .881
98.1
1.3
29.85
0.03
-1218.8
6.3
-1139 .0
6.3
199.55
1.11
H4Si04 (UN- IONIZED)

STD. STATE. * 1
96 .115
180.0
4.2
CRISTOBALITE
Si 2
60 .084
43.4
0.1
TRIDYMITE
SIC,,
60 .084
COESITE
Si02
229.12
0.37
67
67
85
67
85
67 294
419
67
67
67
294
76
20

NAME AND FORMULA
WEIGHT
ENTROPY
VOLUME
ENTHALPY
S-
vo
<**
M"
kJ-ml -i
r-
FREE
ENERGY
A.G-
LOG(K)
kJ-nol i
REFERENCES
H/G
67
TUNGSTEN DIOXIDE
*>2
215.849
50 .6
0 .3
20.03
0.05
-589 .7
0 .9
-533. 9
0. 9
93.53
0.16
67
67
TUNGSTEN TRIOXIDE
WOj
231.848
75 .9
1 .3
31.61
0.10
-842 .9
0 .8
-764. 1
0. 9
133.86
0.16
67
67 236
81.389
43 .2
0 .1
14.34
0.01
-350 .5
0 .3
-320. 4
0. 3
56.12 352
0.05
85 352
319
123.223
50 .4
0 .3
21.15
0.01
-1100 .6
1 .7
-1042. 9
1. 7
ZINCITE
ZnO
BADDELEYITE
ZrO,
182.70 319 196

0.30 419 419
82
MULTIPLE OXIDES
21
THERMOOYNAHIC PROPERTIES OF MULTIPLE OXIDE MINERALS AT 298.15 K
NAME AND FORMULA
WEIGHT
ENTROPY
VOLUME
ENTHALPY
S-
V
cm3
M"
kJ-nol 1
FREE
ENERGY
LOG(K)
kJ-nor'
REFERENCES
H/G
43
361
TIALITE
AlgTiOs
181 .840
109.6
0.8
48.75
0.05
CHRYSOBERYL
BeAl 204
126 .973
66.3
0.1
34.32
0.02
-2298.5
2.8
-2176. 2
2. 8
381.3 116 164 164

0.5 164
CALCIUM FERRITE
CaFe204
215 .770
145.4
0.8
44.98
0.05
-1520.3
0.2
-1412. 4
0. 2
247.4 419 419

0.0
42
D I CALCIUM FERRITE
Ca2Fe25
271 .847
188.8
1.3
67.18
0.10
-2138.3
0.9
-1999. 9
0. 9
350.4 419 419

0.2
42
PEROVSKITE
CaTiOj
135 .956
93.6
0.4
33.63
0.01
-1660.6
1.7
-1574. 8
1. 8
275.9 419 419 295

0.3
HERCYNITE
FeAl 204
173 .808
117.0
3.0
40.75
0.05
-1950.5
8.5
-1838. 1
10. 0
322.0 373 188 450

1.8 188
CHROMITE
FeCr204
223 .837
146.0
1.7
44.01
0.10
-1445.5
5.0
-1344. 5
6. 0
235.5 361 373 292

1.1
ILMENITE
FeTiOj
151 .725
108.9
0.3
31.69
0.08
-1232.0
2.5
-1155. 5
2. 5
202.4
0.4
11
11
295
ULVOSPINEL
Fe2Ti04
223 .572
180.40
2.5
46.82
0.05
-1493.8
2.0
-1399. 9
2. 1
245.3 216 216

0.4 312
43
PSEUDOBROOKITE
Fe2Tl"5
239 .571
156.5
1.3
54.53
0.05
SPINEL
142 .266
88.7
4.0
39.71
0.03
-2299.1
2.0
-2176. 6
2. 3
381.3
0.4
192 .295
106.0
0.8
43.56
0.05
-1783.6
0.9
-1669. 1
0. 9
292.4 373 373 292

0.1
199 .997
121.8
2.0
44.57
0.05
-1441.5
3.0
-1329.6
3. 1
232.9 290 373

249
0.5
GEIKIELITE
HiTiOj
120 .183
74.6
0.2
30.86
0.07
-1572.8
1.2
-1484. 4
1. 2
260.1 352 425 352

295
0.2
PYROPHANITE
MnTJOj
150 .816
104.9
0.2
32.77
0.05
-1360.1
4.0
-1280. 9
4. 0
224.4 393 103 103

0.7
102 102
TREVORITE
NiFe?0,
234 .382
140.9
5.0
43.65
0.05
-1070.5
2.0
-965. 1
2. 5
169.1 450 271 271

0.4
290
MgAl 204
MAGNESIOCHROMITE
Mgcr2o4
MAGNESIOFERRITE
MgFe204
11
43
67
37
67 44
64 386
42
22

THERMOOYNAHIC PROPERTIES OF MULTIPLE OXIDE MINERALS AT 298.15 K
NAME AND FORMULA
WEIGHT
ENTROPY
VOLUME
ENTHALPY
FREE
ENERGY
S-
V
<**
kJ-nol 1
kJ-ol 1
j-aor'-ic1
LOG(K)
REFERENCES
H/G
21
FRANKLINITE
ZnFe24
241.082
150.7
0.3
44.94
0.05
-1188.1
4.0
-1082.1
4.0
189.6 439 290

0.7
HETAEROLITE
ZnMn24
239.264
149.7
0.5
45.57
0.05
-1337.0
4.0
-1227.8
4.0
215.1
0.7
ZINC TITANIUM SPINEL

ZruTiO/
242.658
143.1
3.0
45.58
0.02
-1652.1
2.0
-1538.4
2.0
269.5 406 290

0.4
71 290
43
HALIDES
23
THERMODYNANIC PROPERTIES OF HALIDE MINERALS AT 298.15 K
NAME AND FORMULA
WEIGHT
ENTROPY
VOLUME
S-
yo
ENTHALPY
FREE
ENERGY
kJ-mol 1
kJ-mol'1
LOG(K)
REFERENCES
H/G
BROMARGYRITE
AgBr
187 .772
107.1
0.4
28 .99
0 .01
-100.4
0.2
-97.0
0.2
16.99 419 419 361

320 318
0.03
POTASSIUM BROMIDE
KBr
119 .002
95.9
0.2
43 .28
0 .01
-393.8
0.2
-380.4
0.2
66.65 419 419 67

320
0.03
CHLORARGYRITE
AgCl
143 .321
96.2
0.2
25 .73
0 .01
-127.1
0.1
-109.8
0.1
19.24
0.02
85
85 361
320 318
HYDROPHILITE
CaCl 2
110 .983
104.6
1.3
50 .75
0 .01
-795.8
0.7
-747.7
0.8
130.99
0.14
67
67 320
284
NANTOKITE
CuC I
98 .999
86.2
2.0
23 .92
0 .04
-137.2
10.0
-119.9
10.0
21.01 419 419

1.75
LAURENCITE
FeCl 2
126 .752
118.0
0.4
39 .46
0 .21
-341.7
0.4
-302.2
0.4
52.95
0.07
67
MOLYSITE
FeClj
162 .205
142.3
0.4
57.86
0.10
-399.5
0.4
-334.0
0.4
58.51
0.07
67 250 284
419
186.9 24789 .70

0.0
0 .20
-92.3
0.1
-95.3
0.1
16.70
0.02
85
67
85
67
85
85
HYDROGEN CHLORIDE
HCl (IDEAL GAS)
36 .461
67 284
250 67
67
85
CALOMEL
HgCl
236 .043
95.8
0.4
32 .94
0 .08
-132.7
0.2
-105.2
0.2
18.43
0.04
SYLVITE
KCl
74 .551
82.6
0.2
37 .52
0 .00
-436.5
0.2
-408.6
0.2
71.58 117 117 117

0.04 85 85 67
CHLOROMAGNESITE
95 .210
89.6
0.8
40 .81
0 .10
-641.3
0.7
-591.8
0.7
103.68
0.13
67 320 284
85
125 .844
118.2
0.2
42 .11
0 .17
-481.3
0.8
-440.5
0.8
77.17
0.14
73 250 284
419
SALAMMONIAC
NH4Cl
53 .491
94.6
0.4
35 .06
0 .05
-314.4
0.3
-202.9
0.3
35.55 419 419

0.05 67
HALITE
MaC I
58 .442
72.1
0.2
27 .02
0 .00
-411.3
0.1
-384.2
0.1
67.30 419 419 67

320
0.02
NICKELOUS CHLORIDE
NiCl 2
129 .595
98.2
0.2
36 .70
0 .07
-304.9
2.0
-258.8
2.0
45.33
0.35
67
67
419
COTUNNITE
PbCl,
278 .105
136.0
2.1
47 .09
0 .05
-359.4
0.3
-314.1
0.7
55.03
0.12
67
67 67
419 320
Mac 1 2
SCACCHITE
67
80
24
THERNOOYNAMIC PROPERTIES OF HALIDE MINERALS AT 298.15 K
NAME AND FORMULA
WEIGHT
ENTROPY
S-
w HH/%
VOLUME
ENTHALPY
yo
^
FLUOR I TE
CaF2
78.075
HYDROGEN FLUORIDE
HF (IDEAL GAS)
20.006
SELLAITE
62.302
57.2
0.5
41.988
CRYOLITE
Na3AlF6
**
kJ-mol 1
FREE
ENERGY
4,6"
kJ-mol 1
LOG(K)
REFERENCES
H/G
117 117 293
24.54
0.01
-1228. 0
2. 0
-1175. 3
2. 0
205 .90
0 .35
173.8 24789.70
0.0
0.20
-273. 3
0. 7
-275. 4
0. 7
48 .25
0 .12
19.61
0.01
-1124. 2
1. 2
-1071. 1
1. 2
187 .64 117 117 117

0 .21
51.5
0.1
14.98
0.01
-573. 6
0. 7
-543. 4
0. 7
95 .20 419 419 300

67
0 .12
209.941
238.5
0.5
70.81
0.20
-3316. 8
6. 0
-3152. 1
6. 0
CHIOLITE
Na5Al3Fu
461.871
515.3
0.8
154.08
0.10
-7546. 3
20. 0
-7174. 7
20. 0
1256 .95 400 400 400

3 .50
IODARGYRITE
234.773
115.5
1.7
41.30
0.04
-61. 8
1. 7
-66. 2
1. 8
11 .60 419 419 320

0 .31
MARSH I TE
Cul
190.450
96.6
33.35
0.02
-67. 8
5. 0
-69. 4
5. 0
12 .16 320 320 108

0 .88
COCCINITE
454.399
180.0
6.3
71.84
0.10
-105. 4
1. 7
-101. 7
2. 6
MgF2
VILLIAUMITE
NaF
Agl
Hgl 2
68.9
0.3
552 .22
1 .05
67 117
85
85
67
67
10
10 10
301 300
17 .82 419 419

0 .45 67 67
67
CARBONATES AND NITRATES
25
THERHOOYNAHIC PROPERTIES OF CARBONATE AND NITRATE MINERALS AT 298.15 K
NAME AND FORMULA
HEIGHT
ENTROPY
VOLUME
ENTHALPY
V
C-5
A.H*
kJ-wol 1
FREE
ENERGY
Lfi*
kJ-wol 1
LOG(K)
198.35
0.39
REFERENCES
H/G
1 262
112.1
2.1
45.81
0.06
-1210.9
2.2
-1132.2
100.087
88.0
0.2
34.15
0.05
-1207.4
1.4
-1127.4
1.5
197.51 392 336

0.26
CALCITE
CaCOj
100.087
91.7
0. 2
36.93
0.01
-1207.4
1.3
-1128.5
1.4
197.70 392 246 202

0.24
336
VATERITE
CaCOj
100. 087
-1125.5
1.5
197.19
0.26
MONOHYDROCALCITE
CaCOj-H^
118. 102
131. 1
3. 0
-1498.3
1.2
-1361.6
1.1
238.54 197 197

0.20
IKAITE
CaC03- 6M2
208. 179
-
370. 0
5. 0
-2954.1
5.0
-2540.9
5.0
445.15 273 273 273

0.88
DOLOMITE
CaMo(C03)2
184. 401
155. 2
0. 3
64.34
0.03
-2324.5
1.5
-2161.3
1.7
378.64 396 175 257

0.29
HUNTITE
353. 030
299. 5
0. 9
122.58
0.10
-4529.6
1.6
-4203.1
1.6
736.34 168 169

253
0.29
OTAVITE
CdCOj
172. 419
92. 5
5. 5
34.30
0.02
-750.6
2.5
-669.4
2.6
117.28
0.46
MALACHITE
CU2(C03> (OH >2
221. 116
166. 3
2. 5
54.86
0.08
-1054.0
2.1
-890.2
2.2
155.96 241 339

0.39
AZURITE
CU3(OH>2(C03>2
344. 671
254. 4
3. 8
91.01
0.13
-1632.2
2.0
-1391.4
2.2
243.75 241 419

0.39
SIDERITE
FeCOj
115. 856
95. 5
0. 2
29.38
0.01
-755.9
5.5
-682.8
5.5
119.63 351 351 351

0.96
MAGNESITE
84. 314
65. 1
0. 1
28.02
0.01
-1113.3
1.3
-1029.5
1.4
180.36 178 347 359

0.24
NESQUEHONITE
MgCOj-SHgO
138. 360
195. 6
0. 6
75.47
0.05
-1977.3
0.3
-1723.8
0.5
301.99 353 354

0.09
HYDROMAGNESITE
4MgC03 -M9(OH)2 .4H20
467.638
503. 7
1. 6
211.10
0.10
-6514.9
1.1
-5864.2
1.1
1027.37 353 354

0.19
ARTINITE
Mg9(OH)9CO,-3H90
196.680
232. 9
0. 7
96.43
0.10
-2920.6
0.7
-2568.4
0.8
449.95 168 169

0.13
UITHERITE
BaCOj
197.336
ARAGONITE
CaCOj
CaMg3(C03)4
nlAn
37.63
0.40
48.70
0.40
2.2
54
336
412
63 419
63
26

THERMODYNAMIC PROPERTIES OF CARBONATE AND NITRATE MINERALS AT 296.15 K
NAME AND FORMULA
UEIGNT
ENTROPY
VOLUME
ENTHALPY
V
c-5
kJ-Hor1
j -nor1 -if1
FREE
ENERGY
A*'
LOG(K)
REFERENCES
H/G
114.947
98.0
0.1
31.07
0.01
-892.9
0.5
-819.1
0.6
143.50 351 351 283

0.10
84.007
102.1
1.7
38.08
0.25
-949.0
0.2
-851.2
0.6
149.12
0.10
THERMONATRITE
Ma2C03 -H20
124.004
168.1
0.8
54.99
0.27
-1429.7
0.4
-1286.1
0.5
TRONA
Na2C03 -NaHC03 *2H20
226.026
107.00
0.50
-2682.1
0.4
416
UEGSCHEIDERITE
Na2C03 -3JaHC03
358.010
153.30
0.80
-3984.0
0.8
416
SODIUM CARBONATE
105.989
135.0
0.6
41.60
-1129.2
0.3
-1045.3
0.4
183.13 424
0.06 36
DAUSONITE
NaAlC03(OH)2
143.995
132.0
0.5
59.30
0.30
-1964.0
2.9
-1786.0
3.0
312.89 110 110 110

0.52
GASPEITE
NiCOj
118.699
85.4
2.0
27.05
0.02
CERUSSITE
PbCOj
267.209
131.0
3.4
40.59
0.06
-699.2
1.2
-625.5
1.6
STROHTIANITE
SrCOj
147.629
97.1
1.7
39.01
0.06
-1218.7
1.5
-1137.6
1.5
SMITHSONITE
ZnCOj
125.399
81.2
0.2
28.28
0.01
-817.0
3.1
-735.3
3.1
128.82 352 153 153

0.54
NITROBARITE
Ba(N03)2
261.337
213.8
0.9
80.58
2.10
-992.1
2.5
-796.6
0.4
139.55 419 419 361

0.08
CALCIUM NITRATE
164.088
193.3
0.4
66.09
0.03
-938.4
1.5
-742.6
1.8
130.10 419 419 361

0.31
NITER
KMOj
101.103
133.1
0.7
48.04
0.06
-494.5
0.4
-394.6
0.5
69.13 419 419 361

0.08
MAGNESIUM NITRATE
148.315
164.0
1.6
62.93
0.03
-790.6
1.3
-589.2
1.4
103.22 419 419 361

0.25
80.043
151.1
0.2
46.49
0.10
-365.6
0.8
-183.8
0.9
32.20 419 419 361

0.15
RHODOCHROSITE
MnCOv
NAHCOLITE
NaHCOj
AMMONIA-NITER
NH'NO,
36
225.32 424
0.09 36
36
36 129
36
255
109.58 217 419

0.27
4
199.29
0.26
55
55 262
27
THERHOOYMAMIC PROPERTIES OF CARBONATE AND NITRATE MINERALS AT 298.15 K
NAME AND FORMULA
HEIGHT
g
SODA-NITER
NaNOj
STRONTIUM NITRATE
Sr<NO),
ENTROPY
VOLUME
ENTHALPY
S-
V
c-5
FREE
ENERGY
A*'
kJ-HOl'1
kJ-HOl'1
j-Hor'-r1
LOG(K)
REFERENCES
H/G
84.995
116.5
0.7
37.60
0.02
-468.0
0.4
-367.1
0.4
64.32 419 419 361

0.07
211.630
194.6
0.5
70.93
0.04
-978.2
1.0
-779.0
1.3
136.47 419 419 361

0.23
28

THERMODYNAMIC PROPERTIES OF SULFATE AND BORATE MINERALS AT 298.15 1C
NAME AND FORMULA
WEIGHT
ENTROPY
VOLUME
ENTHALPY
V
cm3
kJ-HOl'
A.H"
FREE
ENERGY
A*"
kJ-nor1
LOG(K)
REFERENCES
H/G
ALUMINUM SULFATE
A12(S04 )3
342. 154
239.3
1.2
73.41
0.20
-3441.8
1.8
-3100.6
1.9
543.20
0.33
88
88
88
BARITE
BaS04
233. 391
132.2
0.8
52.10
0.06
-1473.6
1.0
-1362. 5
1.3
238.70
0.23
88
88
419
88
ANHYDRITE
CaS04
136. 142
107.4
0.2
46.01
0.01
-1434.4
4.2
-1321.8
4. 3
231.57 368 88 368

419
0.75
GYPSUM
CaS04 '2H20
172. 172
193.8
0.3
74.69
0.22
-2023.0
4.3
-1797. 0
4. 4
314.82 368
0.77 88
CHALCOCYANITE
CuS04
159. 610
109.5
0.6
40.88
0.03
-771.4
1.3
-662. 3
1. 4
CHALCANTHITE
CuS04 '5H20
249. 686
301.2
0.6
108.97
0.22
-2279.7
3.4
-1880. 0
3. 6
329.36
0.63
BROCHANTITE
Cu4 (S04 )(OH)6
452. 292
-1818. 0
2. 5
318.49
0.44
FERRIC SULFATE
Fe2(S04 )3
399. 885
-2254. 4
3. 0
394.96 328
0.52
SZOMOLNOKITE
FeS04 'H20
169. 926
MELANTERITE
FeS04 '7H20
278. 018
113.60
0.20
88
4 106
116.03 106
0.25 87 419
87
87
419
26
419
19 328
130.80
0.20
-2581.9
2.9
55.90
0.40
-1244.3
0.5
409.2
1.3
146.50
0.30
-3014.3
0.6
-2509. 5
1. 3
98. 080
156.9
0.2
53.57
0.07
-814.0
0.4
-690. 0
0. 5
ARCANITE
K2S04
174. 260
175.6
0.4
65.50
0.07
-1437.7
0.5
-1319. 6
0. 5
231.18
0.09
K-Al SULFATE
KAl(S04 )2
258. 207
204.6
1.3
92.33
0.08
-2470.9
1.3
-2240. 4
1. 4
392.50 419 419 217

0.24
ALUNITE
KA1 3(OH)6(S04 )2
414. 214
321.0
5.0
293.60
0.40
-5176.5
2.4
-4663. 5
2. 4
817.00 452 452 219

0.42
219
LANGBEINITE
K2Mg2(S04 )3
414. 997
389.3
1.0
146.95
0.04
-4071.0
3.0
-3733. 4
3. 0
654.05 368 419 368

0.52 40
MAGNESIUM SULFATE
MgSO,
120.369
91.4
0.8
-1284.9
0.6
-1170. 5
0. 8
205.07
0.14
SULFURIC ACID (LIQUID)

H2S04
282.8
0.9
439.64
0.23
87
2
87
87
2
87
120.88 419 419

124
0.08
67
67 387
67
67 247
88
67
SULFATES AND BORATES
29
THERMODYNAMIC PROPERTIES OF SULFATE AND BORATE MINERALS AT 298.15 K
NAME AND FORMULA
WEIGHT
ENTROPY
S
rnol-'-IC1
J
VOLUME
ENTHALPY
yo
c-5
FREE
ENERGY
A*'
LOG(K)
kJ-Hor'
REFERENCES
H/G
372.0
4.0
146.80
0.20
-3388.7
0.1
2871 .2
0.9
503.01
419 419
88
88
151. 002
127.0
1.5
43.62
0.04
-1065.7
1.1
-962 .1
1 .5
168.56 450 87
377
0.26
87
MASCAGNITE
(NH4 )2S04
132. 141
220.5
1.3
74.68
0.09
-1182.7
1.3
-903 .5
1 .6
158.29 419 88 387

0.28 88 419 219
THENARDITE
Na2S04
142. 043
149.6
0.1
53.33
0.06
-1387.8
0.4
-1269 .8
0 .4
222.46 88 88
0.07 419 419
MIRABILITE
Na2S04 '10H20
322. 196
591.9
0.6
219.80
0.40
-4327.3
4.0
-3645 .8
3 .4
638.71
0.59
NICKELOUS SULFATE
NiS04
154. 754
101.3
0.3
38.57
0.03
-873.2
1.0
-762 .7
1 .0
RETGERSITE (ALPHA, GREEN)

NiS04 -6H?0
262. 845
334.5
0.4
126.60
0.20
-2683.4
0.5
-2225 .1
0 .5
389.82
0.09
87
87
419
MORENOSITE
NiS04 -7H20
280. 861
378.9
0.4
143.80
0.50
-2976.5
0.5
-2461 .9
0 .5
431.30
0.09
87
87
419
ANGLES I TE
PbS04
303. 264
148.5
0.6
47.95
0.06
-920.0
0.4
-813 .1
0 .5
142.44
0.09
85
85
CELESTITE
SrS04
183. 684
117.0
4.2
46.25
0.06
-1453.2
4.2
-1339 .6
4 .4
ZINKOSITE
ZnS04
161. 454
110.5
1.3
41.57
0.07
-980.1
0.8
-868 .7
0 .9
152.20
0.16
87
BIANCHITE
ZnS04 -6H20
269. 545
363.6
1.3
130.20
0.50
-2777.8
1.0
-2324 .6
1 .0
407.26
0.18
87
87
419
GOSLARITE
ZnS04 -7H20
287.561
388.7
1.3
145.80
0.10
-3077.5
0.1
-2562 .3
0 .1
448.89
0.02
87
87
419
BORAX
381.372
586.0
2.3
222.70
0.20
-6288.6
8.5
-5516 .2
8 .5
966.39 419 419

1.49
EPSOMITE
MgS04 -7H20
246. 476
MANGANESE SULFATE
NnS04
0.15
47
81
47
81
133.61 401 401 401

4
88
234.69 419 419

129
0.77
87 87
4 192
30

THERMODYNAMIC PROPERTIES OF PHOSPHATE, MOLYBDATE AND TUNGSTATE MINERALS AT 298.15 K
NAME AND FORMULA
HEIGHT
LOG(K)
ENTROPY
VOLUME
ENTHALPY
FREE
ENERGY
V
c*>
kJ-Hor1
kJ-Hor'
j-aor'-ir'
REFERENCES
H/G
90.8
0.2
46.58
0.10
-1733.8
5.0
-1617.9
5.0
283.44 419 419 181

181
0.88
310.177
236.0
0.8
97.62
0.09
4120.8
5.0
-3883.6
5.0
680.38 419 419 361

0.88
FLUORAPATITE
C^(P04)3F
504.302
387.9
1.7
157.56
0.12
6872.0
5.0
-6489.7
5.0
1136.95 419 419

0.88
99
HYDROXYAPATITE
C^<P04)3ON
502.311
390.4
1.7
159.60
0.20
-6738.5
5.0
-6337.1
5.0
1110.22 419 419

0.88
99
STRENGITE
FcP04 '2H20
186.849
171.3
1.3
64.50
0.30
1888.2
0.9
-1657.5
1.0
290.37 100 419 100

0.18
POWELLITE
CaMo04
200.016
122.6
0.8
47.00
0.09
-1541.4
0.9
-1434.7
0.9
251.34 431 419

12
0.15
UULFENITE
PbMo04
367.138
166.1
2.1
53.86
0.10
-1051.9
0.9
-951.2
1.2
166.65 320 419

89
0.20
SCHEELITE
CaU04
287.926
126.4
0.8
47.05
0.09
-1645.2
0.9
-1538.0
0.9
269.51 232 419

0.16
17
FERBERITE
FeW04
303.695
131.8
1.7
40.38
0.05
-1154.8
8.5
-1054.0
8.5
184.64 430 419

1.49 265
7
HUEBNERITE
NnU04
302.786
132.5
0.2
41.89
0.06
-1337.6
7.0
-1235.4
7.1
216.44 304
1.24
STOLZITE
PbU04
455.048
168.2
2.1
54.10
0.06
-1127.2
2.0
-1026.0
2.0
179.74 428
0.35
89
SANMARTINITE
313.238
119.3
0.3
39.79
0.04
-1232.6
1.3
-1123.7
1.4
196.86 260 266 260

266
0.25
BERLINITE
MP04
121.953
WHITLOCKITE
Ca3(P04 )2
znuo*
ORTHO AND RING STRUCTURE SILICATES
31
THERMQDYNAMIC PROPERTIES OF ORTHO AND RING STRUCTURE SILICATE MINERALS AT 296.15 K
NAME AND FORMULA
WEIGHT
ENTROPY
VOLUME
ENTHALPY
A,H
kJ-mol 1
FREE
ENERGY
A.GkJ-mol 1
LOG(K)
REFERENCES
H/G
24
23
24
24
TOPAZ
Al 2Si04F2
184.043
105.4
0.2
51.53
0.03
-3084.5
4.7
-2910.6
4.7
509.9
0.8
KYANITE
Al 2Si5
162.046
82.8
0.5
44.15
0.05
-2593.8
2.0
-2443.1
2.0
428.0 355 177 177

0.4 177 407 322
ANDALUSITE
AlîOg
162.046
91.4
0.5
51.52
0.05
-2589.9
2.0
-2441.8
2.0
427.8 355 177 177

0.4 177 407 322
SILLIMANITE
162.046
95.4
0.5
49.86
0.05
-2586.1
2.0
-2439.1
2.0
427.3 355 177 177

0.4 177 407 322
MULLITE
Al6Si 213
426.052
275.0
5.0
134.55
0.07
-6819.2
10.0
-6441.8
10.0
1128.6 67
1.8 329
DUMORTIERITE
565.938
334.9
5.0
168.4
0.4
-9109.0
20.0
-8568.2
20.0
1501.1 163 163 163

3.5
EUCLASE
BeAlSi04(OH)
145.084
89.1
0.4
46.86
0.06
-2532.9
3.0
-2370.2
3.0
415.2 164 164 164

238
0.5
PHENAKITE
Be2Si04
110.107
63.4
0.3
37.18
0.02
-2143.1
4.0
-2028.4
4.0
355.4 164 164 164

379
0.7
BERYL
Be3Al 2(Si 618>
537.502
346.7
4.7
203.3
0.1
-9006.6
7.0
-8500.5
6.4
1489.2 164 164 164

238
1.1
BERTRANDITE
Be4Si 207(OH) 2
238.230
172.1
0.8
91.8
0.1
-4580.5
5.5
-4295.1
5.5
752.5 164 164 164

238
1.0
EPIDOTE
Ca2Al 2FeSi 3012(OH)
483.223
328.9
2.5
138.1
0.6
LAUSONITE
CaAl 2 [S1 207(OH)2]H20
314.238
230.0
2.1
101.32
0.12
-4869.0
2.1
GEHLENITE
Ca^SiCV
274.200
210.1
0.6
90.15
0.02
ZOISITE
Ca2Al3Si 312(OH>
454.357
295.9
0.6
GROSSULAR
Ca3Al 2Si 312
450.446
GLASS
Ca,AUSi,0, 7
450.446
AljjSiOg
Al6.75"o.25si 3B017.25<OH >.75
67 67
86 329
147
239
243
-4512.9
2.1
790.6 335
0.4 68
68 335
-3985.0
5.0
-3785.5
5.0
663.2 172
0.9 420
66 323
136.5
0.4
-6901.1
3.3
-6504.5
3.3
1139.5 335 239 335

0.6
260.1
0.5
125.28
0.05
-6640.0
3.2
-6278.5
3.2
1099.9 157 68 258

0.6 251 237 438
329.2+
158.8
0.3
345
32

THERNOOYNAMIC PROPERTIES OF ORTHO AND RING STRUCTURE SILICATE MINERALS AT 298.15 K
NAME AND FORMULA
WEIGHT
ENTROPY
VOLUME
ENTHALPY
FREE
ENERGY
V
cm3
kJ-Hor'
kJ-mol 1
LOG(K)
REFERENCES
H/G
DATOLITE
CaB(Si04)(OH)
159 .979
110.2
0.6
53.32
0.05
-2477.8
2.3
-2318.1
2.3
406.1 448 383 274

0.4
5
ILVAITE
CaFe2Fe(Si 207)0(OH)
408 .793
292.3
0.6
101.07
0.10
-3692.8
5.0
-3437.0
5.0
602.1 349 349 349

0.9
ANDRADITE
Ca3Fe2Si312
508 .177
316.4
2.0
132.04
0.05
-5771 .0
5 .9
-5427.0
5.9
950.8 348 281 348

1.0
242 244
MONT I CELL I TE
CaMgSi04
156 .466
108.1
0.3
51.3
0.1
-2251 .0
3 .0
-2132.8
3.1
373.6 385 49 385

0.5
385
AKERMANITE
272 .628
212.5
0.4
92.54
0.02
-3864 .8
2 .0
-3667.5
2.0
642.5 165 165 165

0.4 427 49 323
MERUINITE
Ca3Mg(Si04 >2
328 .705
253.1
2.1
98.5
0.1
-4536 .2
3 .0
-4307.7
3.0
754.7 427
0.5
TITANITE (SPHENE)
CaTiSiOj
196 .041
129.2
0.8
55.74
0.07
-2596 .6
3 .0
-2454.6
3.2
430.0 406 37 361

0.6
188
LARNITE
-Ca2Si04
172 .239
127.6
0.8
51.60
0.30
-2306 .7
1 .5
-2191.2
1.5
383.9 225
0.3
CALCIO-OLIVINE
172 .239
120.5
0.8
58.01
0.04
-2316 .5
2 .5
-2198.9
2.5
385.2 149 149 149

0.4 405
84
HATURITE (ALITE)
CajSiOj
228 .317
168.6
0.3
72.74
0.05
-2933 .1
2 .5
-2786.5
2.5
488.2 149 410 149

0.4 405
RANKINITE
Ca3Si 27
288.401
210.6
2.9
96.51
0.05
-3949.0
10.0
-3748.1
10.0
656.6 149 410 149

1.8
ROSENHAHNITE
Ca3Sf 38(OH>2
366.500
281.8
3.0
126.46
0.05
-5198.1
3.0
-4882.1
3.0
855.3
0.5
SPURRITE
Cas (Si04 )2C03
444.565
331.0
2.0
146.97
0.30
-5840.2
5.7
-5525.6
5.9
968.0 450 188 450

1.0 188 410
TILLEYITE
Ca5Si 207(C03)2
488.575
394.0
4.0
170.5
0.3
-6372.2
5.7
-6013.5
6.0
1053.5 450 188 450

410
1.1
COBALT-OLIVINE
Co2Si04
209.950
142.6
0.2
44.49
0.01
-1412.0
2.0
-1308.7
2.0
229.3 364 215 363

0.3
308
FAYALITE
Fe2Si04
203 .777
151.0
0.2
46.31
0.01
-1478.2
1.3
-1379.1
1.3
241.6 350 350 350

0.2
309 314
68
49 323
149
68
84
149
68
33
THERHOOYNAHIC PROPERTIES OF ORTHO AND RING STRUCTURE SILICATE MINERALS AT 298.15 K
NAME AND FORMULA
HEIGHT
ENTROPY
S
ALNANDINE
F3Al 2Si312
STAUROLITE
ENTHALPY
A,H
C-5
497.753
342.6
1.4
115.32
0.04
1703.727
985.0
4.0
445.9
1.7
F4Al 18Si 846(OH >2

OSUMILITE
KMg^ljKi^lgOjoJ.HgO
VOLUME
1001.468
-5264.7
3.0
FREE
ENERGY
A.G'
kJ-wol 1
-4942.0
3.3
LOG(K)
REFERENCES
H/G
9 69 447
865.8
0.6 277 445 151
172
172
180
379.2
0.3
-9161.5
5.9
-8651.1
5.9
1515.6 427 297 323

1.0
584.953
407.2
3.8
233.22
0.22
SAPPHIRINE
N^Z*Wf4>
344.616
197.5
2.0
98.9
0.7
FORSTERITE
140.693
94.1
0.1
43.65
0.03
-2173.0
2.0
-2053.6
2.0
359.8 364 364 364

240 119
0.4
PYROPE
MgjAlgSijO^
403.127
266.3
0.8
113.12
0.15
-6285.0
4.0
-5934.5
4.0
1039.7 157 188 453

298
0.7
GLASS
Mg3Al 2Si 3012
403.127
346.3
12.0
146.1
0.2
-6163.0
15.0
-5836.3
15.0
1022.5 402 402 402

2.6
PYROPE-GROSSULAR 88.
<H1.8Ca1.2>Al 2Si 312
422.055
268.3+
0.5
118.35
0.05
GLASS
(M1.5Ca1.5>Al2Si312
426.787
311.8+
0.6
152.5
0.2
TEPHROITE
Mn2Si04
201.959
155.9
0.5
48.99
0.03
-1731.5
3.0
-1631.0
3.0
285.7 364 364 364

0.5
LIEBENBERGITE
Mi2Si04
209.463
128.1
0.2
42.57
0.02
-1396.5
3.0
-1288.9
3.0
225.8 363 363 363

308
0.5
Ni 2Si04-SPINEL
Ni 2Si04
209.463
124.1
0.4
39.81
0.01
-1389.7
3.5
-1280.9
3.5
224.4 363 363 423

0.6
UILLEMITE
Zn2Si04
222.863
131.4
0.8
52.42
0.08
-1636.7
5.0
-1523.1
5.0
266.8 405 223

0.9
ZIRCON
183.307
84.0
1.3
39.26
0.07
-2034.2
3.1
-1919.7
3.1
336.3 361 101 361

379
0.5
CORDIERITE
Mg2Al3(AlSi 5018)
Mg2Si04
ZrSi04
186
157 298
345
34

THERMODYNAMIC PROPERTIES OF CHAIN AND BAND STRUCTURE SILICATE MINERALS AT 298.15 K
NAME AND FORMULA
WEIGHT
ENTROPY
VOLUME
ENTHALPY
V
cm3
M"
kJ-mol 1
FREE
ENERGY
A*'
kJ-Hol'1
LOG(K)
REFERENCES
H/G
UOLLASTONITE
CaSi&j
116.162
81.7
0.1
39.90
0.03
-1634.8
1.4
-1549.0
1.4
271.4 259 348 389

0.2 257 149 344
PSEUDOUOLLASTONITE
CaSiOg
116.162
87.2
0.9
40.08
0.14
-1627.6
1.4
-1543.5
1.4
270.4 149 344 344

0.2 344 149 149
GLASS
CaSiOg
116.162
94.8
3.0
40.13
0.15
-1608.7
3.0
-1526.8
3.0
267.5 344 344 344

0.5
Ca-Al PYROXENE
CaAl 2Si06
218.123
141.0
2.0
63.57
0.01
-3306.3
2.5
-3129.6
2.6
548.3 154
0.5
GLASS
CaAl 2Si06
218.123
155.3+
0.3
78.13
0.08
154
FERROBUSTAMITE
248.092
180.5
0.3
73.00
0.02
156
HEDENBERGITE
CaFeSi 206
248.092
174.2
0.3
67.95
0.01
GLASS
248.092
185.7+
0.4
216.550
142.7
0.3
66.09
0.10
-3201.5
2.0
-3026.8
2.0
530.3 259 165 257

0.4
GLASS
CaMgSi^
216.550
166.0
3.0
76.09
0.20
-3156.1
5.0
-2988.4
5.1
523.5 343 340 343

340
0.9
FERROSILITE
FeSiOj
131.931
94.6
0.3
33.00
0.02
-1195.2
3.0
-1118.0
3.0
195.9
0.5
a-SPODUMENE
LiAlSi 206
186.090
129.3
0.8
58.37
0.02
-3053.5
2.8
-2880.2
3.0
504.6 327 171 327

0.5
20 28
B-SPOOUHENE
LiAlSi 206
186.090
154.4
1.2
78.25
0.04
-3025.3
2.8
-2859.5
3.0
501.0 327 171 327

0.5
20
ENSTATITE
NgSiOj
100.389
66.3
0.1
31.31
0.02
-1545.6
1.5
-1458.3
1.6
255.5 259 37 257

0.3
408 188
GLASS
100.389
74.1
0.2
36.60
0.25
-1542.5
2.0
-1457.5
2.0
255.3 345 345

0.4
100.389
67.9
0.4
31.28
0.02
-1545.0
1.5
-1458.1
1.6
255.5 361 296 361

0.3
311
CaFeSi 206
CaFeSi 206
DIOPSIDE
CaMgSi^
MgSiOj
CLINOENSTATITE
MgSiOj
-2839.9
3.0
-2676.3
3.0
68 154
65 403
156
468.9 156 281 156

0.5
156 29
156
41
41 188
291 423
35
CHAIN AND BAND STRUCTURE SILICATES

THERMODYNAMIC PROPERTIES OF CHAIN AND BAND STRUCTURE SILICATE MINERALS AT 298.15 1C
NAME AND FORMULA
WEIGHT
ENTROPY
VOLUME
ENTHALPY
V
cm5
A,HkJ-mol 1
J-
FREE
ENERGY
A,G
kJ-mol 1
LOG<K>
REFERENCES
H/G
105
MgSiOj-PEROVSKITE
MgSiOj
100 .389
63.6
3.0
24.50
0.05
-1445.1
5.0
-1357. 0
5. 0
237.7 105
0.9
MgSiOj-ILMENITE
MgSiOj
100 .389
60.4
3.0
26.36
0.02
-1486.6
5.0
-1397.5
5.0
244.8 105 13
288
0.9
HYPERSTHENE
(Mg 85 Fe ,5)8103
105 .120
69.0
0.2
31.53
0.05
RHODONITE
MnSiOj
131 .022
100.5
1.0
34.94
0.05
-1321.6
2.0
-1244. 7
2. 2
218.0 367 367 390

289 224
0.4
PYROXMANGITE
MnSiOj
131 .022
99.4
2.0
34.72
0.02
-1322.3
2.0
-1245. 0
2. 4
218.1 367 367

32
0.4
JADEITE
NaAlSi 206
202 .139
133.5
1.3
60.40
0.10
-3029.3
3.6
-2850. 6
4. 0
499.4 220 166 220

184
0.7
GLASS
NaAlSi 206
202 .139
170.5
0.4
ACMITE
NaFeSi 206
231 .004
170.6
0.8
64.60
0.11
-2584.5
4.0
-2417. 2
4. 2
TREMOLITE
812 .366
548.9
1.3
272.90
0.73
-12303.0
7.0
-11574. 6
7. 0
2027.8 370 205 257

426
1.2
GRUNERITE
Fe7Si 8022(OH)2
1001 .614
725.0
7.0
278.7
0.5
-9623.0
10.0
-8964. 8
10. 2
1570.6 264 264 252

8 34
1.8 252
ANTHOPHYLLITE
Mg7Si 8022(OH)2
780 .820
534.5
3.5
265.4
0.4
-12070.0
8.0
-11343.4
8.5
RIEBECKITE
935 .900
691.0
6.0
274.7
0.9
GLAUCOPHANE
Na2Mg3Al 2Si 8022(OH)2
783 .543
541.2
3.0
262.1
0.2
-11964.0
9.0
-11230. 8
10. 0
1967.6 362
1.8
PARGASITE
835 .825
582.0
4.0
272.0
0.2
-12719.8
22.0
-11981. 5
19.0
2099.1 433 188

3.3 186 433
839 .807
583.0
5.0
270.6
0.2
-12800.5
14.0
-12102. 2
14.0
2120.2 450 434

2.5 434
Ca2Mg5Si8022(OH)2
Na2Fe3Fe2Si 8022(OH)2
NaCa2Mg4Al(Al2Si 6)022(OH)2
FLUOR -PARGASITE
NaCa5Mg,Al(AUSi,)055F,
13
367
345
423.5 248 31
0.7 33 188
1987.3 162
1.5
31
162 162
70
450
188 185
118
36
THERMODYNAMIC PROPERTIES OF FRAMEWORK STRUCTURE SILICATE MINERALS AT 298.15 1C
NAME AND FORMULA
WEIGHT
ENTROPY
VOLUME
ENTHALPY
V
cm5
A,H
kJ-mol 1
J-raol-'-lf1
FREE
ENERGY
kJ-mol 1
EOINGTONITE (ordered)
BaAl 2Si 3010 '3H20
489.586
434.8
1.5
180.40
0.60
ANORTHITE
CaAljjSigCfc
278.207
199.3
0.3
100.79
0.05
HEXAGONAL ANORTHITE
CaAl2Si' 2Og
278.207
214.8
1.3
99.85
0.79
CaAl2$i 208-glass
CaAl 2Si 208
278.207
237.3
2.5
103.0
0.2
-4163 .2
4 .0
-3948 .4
4 .0
805.9
1.6
333.4
1.0
-11038 .0
6 .6
-10146 .0
6 .6
HEULANDITE
707.942
767.2
Ca0.59Sr0.18Ba0.06Na0.38IC0 .13AI 2.16S!6.84'|8.6H20
317.6
1.0
-10594 .6
10 .2
-9779 .0
10 .2
UAIRAKITE
CaAl2Si 4012 -2H20
434.406
190.4
0.5
LAUMONTITE
CaAl 2Si 4012 '4H20
470.437
SCOLECITE
CaAl 2Si 31o' 3H2
392.337
367.4
0.7
172.3
0.5
LEONHAROITE
Ca2Al4Si824' 7H2
922.859
922.2
10.9
409.3
2.0
BICCHULITE
Ca2Al2Si06(OH)2
292.216
213.1
5.0
103.68
0.10
-4341 .2
5 .0
-4073 .0
5.0
MEIONITE (Al/Si ordered)

Ca^Si^COj
934.709
715.2
1.0
340.36
0.08
-13881 .4
6 .2
-13131.8
6.2
OANBURITE
CaB2Si 208
245.866
155.3
0.4
82.20
0.40
-3902.8
2.9
-3677 .0
2.9
STILBITE
714.893
Ca1.02Ma0.14IC.01 (Al 2.18Si 6 .8218) " 7- 33H2
440.0
10.0
-4234 .0
2.0
207.2
0.4
83.0
2.0
MICROCLINE
KAlSijOg
278.332
214.2
0.4
108.72
0.10
-4007.9
2.0
H/G
702.2 366 150 446

0.4 56 68 258
231
171
691.7 366 450 258

0.7
1777.5 195 195
1.2 74
1713.2 208 208 208
1.8
74
159
-6772 .0
7 .0
211.3
1.0
245.488
<C8 .65Na .19Rb.03 )Al2si 412 H20
REFERENCES
27
-6049 .0
5 .0
-5597 .6
5 .0
195
1186.4
1.2
980.7 207 207

0.9
231
CLINOPTILOLITE
2701.506
2872.3+ 1267.6
(Ma0.56IC0.98Ca1.50M8l.23><Al6.7Fe0.3)Si 2972' 22H20
7.0
POLLUCITE
LOG(K)
713.6
0.9
68
68
144
68
2300.6 282 282 450

1.1
644.2 448 383
0.5 274
173
214
30
-3974.6
3.9
-3749.3
3.9
656.8 313 166 167

0.6
FRAMEWORK STRUCTURE SILICATES
37
NAME AND FORMULA
WEIGHT
ENTROPY
S
J c ol-'-IC-1
VOLUME
ENTHALPY
yo
A,HkJ-mol'1
cm5
FREE
ENERGY
i.G"
kJ-mol 1
LOG(K)
REFERENCES
H/G
232.8
109.05
0.5
0.10
-3965.6
4.1
-3745.8
4.1
656.2 313 166 167

0.7 155 194
278.332
261.6
1.8
116.50
1.00
-3920.8
4.2
-3709.6
4.2
649.9 366 166 258

0.6
421
KALIOPHILLITE (KALSILITE)
KAlSi04
158.163
133.3
1.2
59.89
0.05
-2124.7
3.1
-2008.8
3.1
351.9 220 188 317

0.5
LEUCITE
KAlSijjOa
218.247
200.2
1.7
88.27
0.05
-3037.8
2.7
-2875.1
2.7
503.7 220 188 317

263
0.5
EUCRYPTITE
LiAlSi04
126.006
103.8
0.8
53.63
0.08
-2123.3
2.0
-2009.2
2.0
352.0 327 171 327

20
0.4
PETAL I TE
LiAlSi401Q
306.259
233.2
0.6
128.40
0.50
-4886.5
6.3
-4610.7
6.3
807.8 180 180 180

1.1 35 28 35
ALBITE
NaAlSi3Og
262.223
207.4
0.4
100.07
0.13
-3935.0
2.6
-3711.6
2.6
650.2 313 166 167

0.5 123 171 220
ANALBITE
NaAlSi 3Og
262.223
225.6
0.4
100.43
0.09
-3923.6
2.6
-3705.6
2.6
649.2 313 166 167

0.5 155 171
GLASS
NaAlSi 3Og
262.223
251.9
1.5
110.10
0.20
-3875.5
3.7
-3665.3
3.7
642.1 366 421 258

0.6
NA-K FELDSPAR SS.

< Ma0.85K0.15>AlSi38
264.639
231.3
0.4
102.18
0.10
-3932.1
4.0
-3715.2
4.0
650.9 155 155

0.7
NA-K FELDSPAR SS.
269.472
237.0
0.4
105.22
0.10
-3945.1
4.0
-3728.7
4.0
653.2 155 155

0.7
NA-K FELDSPAR SS.

<Na0.25K0.75>AlSi38
274.304
237.4
0.4
107.37
0.10
-3954.5
4.0
-3737.1
4.0
654.7 155 155

0.7
NEPHELINE
NaAlSi04
142.054
124.4
1.3
54.19
0.06
-2090.4
3.9
-1975.8
3.9
346.1 220 188 220

183
0.7
CARNEGIEITE
NaAlSi04
142.054
118.7
0.3
56.03
0.02
-2104.3
4.0
-1988.0
4.0
348.3 346 450 220

0.7
GLASS
NaAlSi04
142.054
134.5
0.5
56.86
0.06
-2089.0
4.0
-1977.4
4.0
346.4 346 346 346

0.7
ANALCIME
NaAlSi 206'H20
220.154
227.7
0.3
97.4
0.2
-3310.1
-3090.0
3.3
541.3 206 206 206

0.6
SANIDINE
KAlSijOg
278.332
GLASS
KAlSijOg
<Na0.55-K0.45>AlSi 38
3.3
38
NAME AND FORMULA
WEIGHT
ENTROPY
VOLUME
ENTHALPY
Se
V
of
A.H"
kJ-mol 1
>
FREE
ENERGY
4,6"
kJ-mol 1
LOG<K>
REFERENCES
H/G
-2983.1
3.5
-2816.0
3.5
493.4 206 206 317

206
0.6
-5718.6
5.0
-5316.5
5.0
931.4 207 207

0.9
DEHYDRATED ANAL C I ME
NaAlSi 206
202.139
172.5
0.2
NATROLITE
NagAlgSi^Q^HgO
380.224
359.7
0.7
169.2
0.2
PHILLIPSITE
<"a1.1K0.8>Al 1.9Si6.116- 6H20
643.236
771.9+
2.4
303.0
8.0
MESOLITE
388.050
Ma0.68Ca0.66(Al 1 .99Si3.01 010)-2.65H20
363.0+
2.0
171.1
0.4
-5947.1
5.4
-5512.7
6.0
965.8 207 207

1.1
MORDENITE
Ma0.36Ca0.29Al0.94s '"5.06012' 3- 47H2
486.5+
1.0
209.8
1.2
-6736.7
4.5
-6227.9
4.5
1091.1 212 212

0.8
DEHYDRATED MORDENITE
Na0.36Ca0.29Al0.94Si5.0612
379.367
299.1+
0.6
-5642.3
4.6
-5318.9
4.6
931.8 212 212

0.8
MERLINOITE
239.967
282.4+
0.4
150.6
0.5
-3591.2
2.9
-3312.0
2.9
580.2
0.5
95
Na/tU.OI
otK/tMm ioAlSl
a/Oc no" 2.13H20
IT
I.TH JmOO
95
96
MERLINOITE
244.028
IC0.80Na0.20AlSi 1 .945.88" 1.81H20
276.6+
0.4
152.2
0.5
-3519.0
2.9
-3258.0
2.9
570.8
0.5
95
95
96
MERLINOITE
^'"I.WOS.M' 1 - 69^
245.088
274.3+
0.4
151.2
0.5
-3481.8
3.0
-3227.6
3.0
565.4
0.5
95
95
96
MERLINOITE
233.057
274.6+
0.4
153.6
0.5
-3488.3
2.8
-3212.0
2.8
562.7
0.5
95
95
96
237.629
260.5+
0.4
151.5
0.5
-3387.3
2.8
-3131.1
2.8
548.5
0.5
95
95
96
237.277
259.7+
0.5
149.8
0.5
-3360.0
2.8
-3110.2
2.8
544.9
0.5
95
95
96
441.880
Na0.81 IC0.19AlSi 1.8105.62" 2.18H20

MERLINOITE
*T) 91
0 09^
1 81^5 &?* 1.79H20
MERLINOITE
KAlSiimO,. A,M.69H,0
173
39
SHEET STRUCTURE SILICATES

THERMODYNAMIC PROPERTIES OF SHEET STRUCTURE SILICATE MINERALS AT 298.15 1C
NAME AND FORMULA
ENTROPY
WEIGHT
S
9
VOLUME
ENTHALPY
A,H
kJ-mol 1
C*3
FREE
ENERGY
kJ-mol 1
LOG(K)
REFERENCES
H/G
197.1
1.3
98.56
0.04
-4118.5
2.0
-3796.0
2.1
665.0 230 171 149

149
0.4
258.160
200.4
0.5
99.34
0.01
-4119.0
1.5
-3797.5
1.5
665.3 358 179 179

0.3 198 68
HALLOYSITE
Al 2Sf 25 (OH>4
258.160
203.0
1.3
-4101.5
10.0
-3780.7
10.0
662.4 230 171

1.8
PYROPHYLLITE
Al2Si4010(OH)2
360.314
239.4
0.4
128.10
0.08
-5640.0
1.5
-5266.2
1.5
922.6 365 258 258

68
0.3
1553.665
1104.2
2.5
577.00
10.00
MARGARITE
CaAl 2 [Al 2Si 2010](OH)2
398.184
263.6
0.3
129.63
0.06
-6244.0
2.6
-5858.9
2.6
1026.4 335
0.5
68 335
PREHNITE
Ca2Al[AlSi 3010](OH)2
412.384
292.8
0.7
141.10
0.10
-6202.6
2.0
-5824.7
2.0
1020.4 335
0.4
68 335
MUSCOVITE (Al/Si disordered)

KAl2 [AlSi3010](OH)2
398.308
306.4
0.6
140.81
0.10
-5974.8
4.9
-5598.8
4.9
980.9 365 166 258

0.9 432 152 316
MUSCOVITE (Al/Si ordered)

KAl2 [AlSi3010](OH)2
398.308
287.7
0.6
140.81
0.10
-5990.0
4.9
-5608.4
4.9
982.6 365 166 258

0.9 432 152 316
ANNITE
ICFe3 [AlSi3010](OH)2
511.886
415.0
10.0
154.30
0.50
-5149.3
4.0
-4798.3
4.0
840.6 186 188 188

0.7 174
PHLOGOPITE (Al/Si disordered)
417.260
334.6
1.0
149.65
0.10
-6226.0
6.0
-5846.0
6.0
1024.2 356 356 356

1.0
417.260
315.9
1.0
149.65
0.10
-6246.0
6.0
-5860.5
6.0
1026.7 356 356 356

01.0
FLUORPHLOGOPITE (Al/Si disorder)421.242

W^WlSijO^Fg
336.3
2.1
146.52
0.10
-6355.5
4.0
-6015.7
4.2
1053.9 218 171 218

434
0.7
FLUORPHLOGOPITE (Al/Si ordered) 421.242

KM93 CAlSi3010]F2
317.6
2.1
146.52
0.10
-6375.5
4.0
-6030.1
4.2
1056.4 218 356 218

0.7
TALC
H95Si 4010(OH)2
379.266
260.8
0.6
136.20
0.20
-5900.0
2.0
-5520.2
2.1
967.1 370 162 257

0.4
CHRYSOTILE (ANTIGORITE)
Mg^SiÔcCOH),
277.112
221.3
0.8
107.50
0.40
-4360.0
3.0
-4032.4
3.1
706.4 226 171 226

0.5
DICKITE
Al2Sf 25 (OH>4
258.160
KAOLINITE
Al 2Si 205(OH)4
ILLITE
K3(Al7Mg)(Al2Si 14)040(OH)8
KM93 CAlSi 3010](OH)2
PHLOGOPITE (Al/Si ordered)

KMg3 [AlSi 301Q](OH)2
365
40

THERMODYNAMIC PROPERTIES OF SHEET STRUCTURE SILICATE MINERALS AT 298.15 1C
NAME AND FORMULA
WEIGHT
ENTROPY
VOLUME
ENTHALPY
V
<**
kJ-mol 1
J-ol 1 -IC1
M"
FREE
ENERGY
A*
kJ-mol 1
LOG(K)
REFERENCES
H/6
CLINOCHLORE
Mg5Al(AlSi 3010 )(OH)8
555.797
421.0
15.0
211.00
0.50
-8919.0
20.0
-8255.8
20.0
1446.3 180 182 182

3.5
204
PARAGON I TE (Al/Si disordered)

NaAl 2 [AlSi3010](OH)2
382.200
295.8
0.9
132.1
0.1
-5933.0
3.8
-5555.7
3.9
973.3 356 356 356

0.7
PARAGONITE (Al/Si ordered)
382.200
277.1
0.9
132.1
0.1
-5949.3
3.8
-5568.5
3.9
975.6 356 356 356

37
0.7
NaAU[AlSi,Oin](OH),
41
ELEMENTS
COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR SELECTED ELEMENTS
NAME AND FORMULA
ENTROPY
J-mol-'-lf1
A1
A2
(T)
A3
(T z)
A4
(f0*)
AS
(T2)
T range
K
T^
1C
298
1235
1234.9
11.95
298
933.5
933.5
10.70
1337.3
12.36
SILVER
Ag (crystal)
42.55
0.21
1.126E+01
1.169E-02
-2.124E+05
2.253E+02
ALUMINUM
Al (crystal)
28.30
0.08
4.132E+01
-1.988E-02
-1.265E+05
-1.816E+02
ARSENIC
As
35.69 2.0845E+01
0.84
6.3265E-03 -9.8777E+04
5.2398E+01
GOLD
Au (crystal)
47.49
0.21
4.197E+01
-1.770E-02
-2.161E+02
1.123E-05
298
1337.3
BORON
B (crystal)
5.83
0.08
4.758E+01
-5.227E-03
-5.903E+04
-5.899E+02
1.372E-06
298
2350
BERYLLIUM
Be (crystal)
9.50 1.8735E+01
0.08
9.293E-03
-4.502E+05
56.74 2.6852E+01
0.42
-1.7289E-02
BISMUTH
Bi
1.93E-05
298
875
298
1550
4.1802E-05
298
544.52
249.34
0.05
4.211E+01
-2.470E-03
-3.021E+04
-8.739E+01
9.370E-07
332.5
2200
GRAPHITE
C (crystal)
5.74
0.10
6.086E+01
-1.024E-02
7.139E+05
-9.922E+02
1.669E-06
298
2500
DIAMOND
C (crystal)
2.38
0.20
9.845E+01
-3.655E-02
1.217E+06
-1.659E+03
1.098E-05
298
1800
CALCIUM
Ca (a- crystal)
42.90 -2.659E+01
0.10
5.236E-02
-4.877E+05
7.442E+02
-9.772E-06
298
716
CADMIUM
Cd (crystal)
51.80
0.15
-3.8115E-02 -1.3402E+05
3.0044E+02
-1.4336E-05
298
594.18
CERIUM
Ce (crystal)
72.00 1.4017E+01
4.00
1.9292E-02 -1.0802E+05
1.4469E+02
-3.699E-03
-4.094E+04
-1.811E+02
1.009E-06
298
2500
4.1844E-02 -1.5646E+05
2.6875E+02
-1.6498E-05
298
700
8.032E+02
1.232E-06
298
2100
BROMINE
Br2 (ideal gas)
CHLORINE
C12 (ideal gas)
223.08
0.02
4.591E+01
COBALT
Co (crystal)
30.04
0.42
CHROMIUM
Cr (ci rstal)
23.62 -1.625E+01
0.21
2.293E-02
-1.222E+06
A^H0
kJ-Mol'1
298
999
42

NAME AND FORMULA
ENTROPY
J-mol'-lf1
A1
COPPER
Cu (crystal)
33.14
0.03
6.084E+01
COPPER
Cu (liquid)
83.95
0.50
3.280E+01
202.79
0.02
4.057E+01
FLUORINE
F2 (ideal gas)
GERMANIUM
Ge (crystal)
HYDROGEN
H2 (ideal gas)
MERCURY
Hg (liquid)
31.09 2.4033E+01
0.15
A2
(T)
-2.875E-02
A3
(T 2)
A4
(r06)
3.331E+05
-5.671E+02
AS
(T2)
1.420E-05
T range
K
T^
1C
298
1357.8
1357.8
-1.489E+02
-4.836E-07
298
2500
3.049E-03 -1.5714E+05 0.84921E+00
-2.5E-08
298
1211.4
1.792E-03
-1.004E+05
1.335E-02
-5.617E+05
4.583E+02
-1.825E-06
298
2500
75.90 1.6815E+01
0.12
3.623E-03
-7.956E+04
1.860E+02
2.168E-06
298
629
MERCURY
Hg (ideal gas)
174.97
0.02
2.079E+01
IODINE
I 2 (ideal gas)
116.14
0.30
1.3122E+01
298
1800
9.111E-03
-1.0131E+06
-1.5E-07
457.7
1800
3.1329E+02 -1.3745E-05
298
923
5.3419E+02
MAGNESIUM
Mg (crystal)
32.67
0.10
MAGNESIUM
Mg (liquid)
73.23
0.15
3.431E+01
923
1366
MAGNESIUM
Mg (ideal gas)
148.65
0.02
2.079E+01
298
2000
MANGANESE
Mn (a-crystal)
32.01
0.08
MOLYBDENUM
Mo (crystal)
28.66
0.21
191.61
0.02
NITROGEN
N2 (ideal gas)
SODIUM
Na (liquid)
SODIUM
Na (ideal gas)
4.1345E-02 -2.7217E+05
4.1345E-02 -2.7217E+05
3.1329E+02 -1.3745E-05
4.167E+01
-9.165E-03
1.082E+05
-2.882E+02
2.479E+01
9.648E-03
1.459E+05
64.92 3.7482E+01
0.20
-1.9183E-02
153.72
0.02
2.079E+01
13.14
1357.8
2500
4.783E+00
130.68
0.02
A^H0
kJ-mol 1
298
980
4.904E-06
298
2500
-2.003E-06
298
2500
1.0644E-05
371
1170.5
298
2500
59.2
629
923
8.48
ELEMENTS
43
NAME AND FORMULA
NICKEL
Ni (crystal)
OXYGEN
02 (ideal gas)
ENTROPY
J-niol'-IC1
A1
29.87 1.5121E+02
0.08
A2
(T)
A3
(T 2)
-2.049E-01
6.856E+05
AS
(T2)
T range
1C
-1.3746E+03
1.742E-04
298
600
-5.780E+02
1.113E-06
298
2500
205.15
0.02
5.658E+01
PHOSPHORUS
P (liquid)
42.58
0.25
2.632E+01
LEAD
Pb (crystal)
64.80
0.30
2.266E+01
1.0089E-01
-8.717E+04
4.0666E+01
PLATINUM
Pt (crystal)
41.63 2.0046E+01
0.20
7.415E-03
-1.298E+05
8.738E+01
SULFUR
S (ortho-crystal)
32.05
0.05
2.270E+01
228.17
0.02
3.751E+01
2.173E-03
ANTIMONY
Sb (crystal)
45.52 5.2603E+01
0.21
-3.2904E-02
SILICON
Si (crystal)
18.81
0.08
2.431E+01
SILICON
Si (liquid)
91.56
0.5
2.720E+01
TIN
Sn (crystal)
51.18 -6.8705E+01
0.08
STRONTIUM
Sr (crystal)
55.69 2.3369E+01
0.03
1.066E-02
TELLURIUM
Te (crystal)
49.71 1.9124E+01
0.20
2.2061E-02
Thorium
TH (crystal)
51.83 2.27467E+01
0.50
9.338E-03 -3.00023E+03 1.27357E+01
-9.09E-08
298
1650
TITANTIUM
Ti (a-crystal)
30.76 2.01595E+02 -1.4675E-01 1.97328E+06 -2.7691E+03

0.10
6.28E-05
298
1166
URANIUM
U (crystal)
50.20 3.2944E+01
0.20
2.860G-05
298
942
SULFUR
S2 (ideal gas)
-5.255E-03
A4
(r08)
T^
K
A^H"
kJ-nol'1
317.3
1000
298
600.6
-4.798E-07
600.6
4.81
298
1800
298
3.003E-03
-6.575E+01
-7.275E-08
298
2500
1.2617E+05 -3.6512E+02
2.4691E-05
298
904
2.330E-07
298
1685
-1.645E+05
-3.185E+05
-2.831E+01
1685
2500
298
505.1
7.2961E-02 -1.2938E+06 1.53013E+03
-7.800E-03
298
820
2.233E+04
298
723
-9.500E+01
1685
50.02
44

NAME AND FORMULA
ENTROPY
J-MOl-'-lf1
Al
A2
(T)
A3
(T 2)
A4
(T*6)
AS
(T2)
T range
K
VANADIUM
V (crystal)
28.94
0.42
3.440E+00
1.334E-02
-6.971E+05
4.369E+02
2.020E-07
298
2200
TUNGSTEN
U (crystal)
32.65
0.10
3.814E+01
-5.430E-03
2.183E+05
-2.568E+02
2.552E-06
298
2500
ZINC
Zn (crystal)
41.63
0.15
2.909E+01
-3.507E-03
-6.366E+01
1.161E-05
298
692.7
ZINC
Zn (liquid)
75.16
0.30
3.138E+01
692.7
1180.2
160.99
0.03
2.079E+01
1180.2
2500
ZINC
Zn (ideal gas)
ZIRCONIUM
Zr (o-crystal)
38.87 -2.585E+01
0.20
ZIRCONIUM
Zr (0-crystal)
79.48 2.1943E+01
-9.032E+05
8.778E+02
-6.585E-06
298
1135
-6.37E-03 -1.1452E+06
2.7991E+02
4.81E-06
1135
2000
-2.090E+03
-5.000E-06
298
1800
3.6755E-02
METHANE
CH4
186.26
0.04
1.194E+02
2.055E-02
COHENITE
Fe3C
104.40
3.40
1.073E+02
1.253E-02
AMMONIA
NH3
192.77
0.03
5.139E+01
2.660E-02
2.814E+06
298
1800
7.584E+05
-5.480E+02
-4.900E-06
298
1800
T^
1C
692.7
1135
A^H0
kJ-mol 1
7.30
4.02
45

COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR SULFIDE AND SULFOSALT MINERALS
NAME AND FORMULA
ENTROPY
J-mol'-IC1
A1
A2
(T)
A3
(T 2)
A4
(T'06)
AS
(T2)
T range
K
142.9
0.3
7.531E+01
298
REALGAR
AsS
63.5
0.6
4.702E+01
298
GREENOCKITE
CdS
72.2
0.3
3.538E+01
1.503E-02
-5.333E+05
CATTIERITE
CoS2
74.8
0.2
6.582E+01
3.032E-02
-5.870E+05
298
1000
COVELLITE
CuS
67.4
0.2
4.3049E+01
2.023E-02 -1.39938E-05 4.35838E-01
298
780
CHALCOCITE
116.2
0.1
7.684E+01
CHALCOPYRITE
CuFeS2
124.9 -5.8753E+02
0.2
3.7073E-01
ISS (intermediate ss)

CuFeS,
250.5 -1.01845E+03
1.358E+00
BORNITE
398.5
0.8
2.429E+02
298
TROILITE
FeS
60.3
0.2
5.049E+01
298
PYRRHOTITE
Fe .875
60.7
0.2
4.988E+01
298
5.084E+01
298
5.123E+01
298
5.095E+01
298
ACANTHITE (ARGENT I TE)
Ag2s
PYRRHOTITE
Fe >89S
PYRRHOTITE
Fe .90S
63.2
0.1
PYRRHOTITE
Fe .98S
2.357E+02
-2.400E-06
298
1100
298
-1.4721E+07
298
820
1.275E+04
820
930
PYRITE
FeSo
52.9
0.1
-2.032E+01
5.030E-02
-3.200E+06
1.787E+03
HARCASITE
FeS2
53.9
0.1
3.832E+02
-3.173E-01
1.676E+06
-4.488E+03
298
1015
1.676E-04
298
700
T^,
K
A^H0
kJ-mol 1
46

COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR SULFIDE AND SULFOSALT MINERALS
NAME AND FORMULA
A2
(T)
A3
(r2)
A4
(T* 6)
205.8
0.2
2.636E+01
2.650E-02
2.660E+05
-4.356E+01
-6.024E-06
298
1800
ALABANDITE
MnS
80.3
0.8
1.353E+02
-5.775E-02
1.169E+06
-1.435E+03
2.087E-05
298
1800
MOLYBDENITE
MoS2
62.6
0.2
1.045E+02
-4.812E-03
-6.291E+03
-6.817E+02
MILLERITE
NiS
53.0
0.4
4.711E+01
133.2
0.3
1.057E+03
-8.988E-01
91.7
0.7
4.460E+01
1.640E-02
182.0
3.3
1.705E+02
-4.860E-03
7.539E+05
-9.978E+02
298
829
HERZENBERGITE
SnS
77.0
0.8
-1.559E+02
1.219E-01
-3.548E+06
3. 604E +03
298
875
HERZENBERGITE
SnS
135.1
1.0
2.672E+01
3.035E-02
BERNDTITE
SnS2
87.5
0.2
2.004E+01
3. 823E- 02
- 9. 602E+05
TUNGSTEN I TE
67.8
0.3
7.633E+01
5.561E-04
-1.137E+06
ws2
SPHALERITE
ZnS
58.7
0.8
6.151E+01
7.631E-04
-7.963E+04
-2.604E+02
298
1300
WURTZITE
ZnS
58.8
0.2
4.191E+01
7.619E-03
-6.603E+05
1.577E+02
298
1300
BERTHIERITE
245.0
1.0
1.000E+01
7.930E-02
-6.416E+06
3.691E+03
298
836
CHALCOSTIBITE
CuSbS2
149.2
3.8
8.810E+01
4.040E-02
HEAZLEUOODITE
Ni3S2
GALENA
PbS
STIBNITE
AS
<T2)
T range
K
A1
HYDROGEN SULFIDE
H2S (IDEAL GAS)
ENTROPY
J-mol'-IC1
298
1200
298
8.139E+06
-1.388E+04
4.660E-04
298
840
298
900
875
1153
298
1000
8. SUE+02
1.408E-06
298
1500
298
826
Tw
K
A^M0
kJ-mol 1
47

COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR OXIDE AND HYDROXIDE MINERALS
NAME AND FORMULA
ENTROPY
J-mor'-IC1
A1
A2
(T)
A3
(T 2)
A4
(T* 6)
AS
(T2)
T range
K
298
2250
CORUNDUM
A123
50.9
0.1
1.612E+02
-1.352E-03
-1.815E+06
-1.059E+03
BOEHMITE
AIO(OH)
37.2
0.1
2.057E+02
-3.492E-02
1.027E+06
-2.635E+03
DIASPORE
AIO(OH)
35.3
0.2
5.333E+01
298
GIBBSITE
Al(OH)3
68.4
0.1
9.170E+01
298
D I BORON TRIOXIDE
B23
54.0
0.3
1.847E+02
D I BORON TRIOXIDE
B23 ^ llclu' c|)
160.9
0.5
1.297E+02
BARIUM MONOXIDE
BaO
72.1
0.4
5.722E+01
5.370E-03
-1.669E+05
-1.668E+02
BROMELLITE
BeO
13.8
0.2
8.274E+01
-7.301E-03
-4.158E+05
-8.718E+02
B I SMITE
Bi 23
151.5
2.1
1.036E+02
3.336E-02
CARBON MONOXIDE
CO (ideal gas)
197.3
0.0
3.976E+01
3.188E-03
5.292E+05
-3.013E+02
CARBON DIOXIDE
C02 (ideal gas)
213.8
0
8.811E+01
-2.698E-03
7.232E+05
-1.007E+03
LIME
CaO
38.1
0.4
5.185E+01
2.444E-03
-9.340E+05
PORTLAND I TE
Ca(OH)2
83.4
0.4
1.867E+02
-2.191E-02
CERIANITE
Ce02
62.3
0.1
8.029E+01
5.699E-03
COBALT MONOXIDE
CoO
52.8
0.3
-3.0A7E+01
109.3
0.3
1.316E+02
TR I COBALT TETROXIDE
Co0,
7.108E-03
6.441E+05
5.381E-07
298
600
298
723
-2.270E+03
723
2200
298
1800
1.845E-06
298
2000
298
800
-8.078E-07
298
2500
298
2200
298
2500
-1.600E+03
298
700
-7.294E+05
-2.099E+02
298
1800
2.946E-02
-4.166E+06
1.932E+03
298
1800
6.602E-02
-2.480E+06
298
1000
T.,
K
2345
A...H0
kJ-wol 1
48

COEFFICIENTS FOR NEAT CAPACITY EQUATIONS FOR OXIDE AND HYDROXIDE MINERALS
NAME AND FORMULA
ENTROPY
J-mor'-IC1
A1
A2
(T)
A3
(T 2)
A4
(r06)
AS
(T2)
T range
K
ESKOLAITE
Cr23
81.2
1.2
1.190E+02
9.496E-03
-1.442E+06
-3.405E+00
298
1800
TENORITE
CuO
42.6
0.2
3.097E+01
1.374E-02
-1.258E+06
3.693E+02
298
1400
CUPRITE
92.4
0.3
4.260E+02
-2.508E-01
4.898E+06
-6.078E+03
Cu2o
UUSTITE
Fe.947
56.6
0.4
-1.930E+01
3.017E-02
-2.533E+06
1.501E+03
298
1652
FERROUS OXIDE
FeO (fictive)
60.6
1.7
3.908E+01
8.574E-03
-7.325E+05
2.466E+02
298
1800
HEMATITE
Fe23
87.4 1.50147E+03 -1.2146E+00

0.2
1.4123E+07 -2.1493E+04
9.244E-05
5.690E-04
298
950
950
1800
243.8 -1.0957E+03
1.0
MAGNETITE
Fe34
146.1 2.65911E+03 -2.5215E+00

0.4
2.0734E+07 -3.6455E+04
MAGNETITE
Fe34
369.1
0.6
9.6823E+01
5.2733E-02
5.6413E+07
900
1800
STEAM
H20 (ideal gs)
188.8 2.7057E+01
0.04
1.7584E-02
2.7696E+05 -2.7656E+01 -2.5097E-06
298
2500
298
2000
3.396E+04
1.3677E-03
298
800
94.1
6.3
7.450E+01
3. 965E- 02
-2.346E+05
DILITHIUM MONOXIDE
Li 20
37.6
0.8
6.133E+01
3.568E-02
-1.168E+06
-7.050E+01
-7.318E-06
298
2000
PERICLASE
MgO
26.9
0.2
6.653E+01
-6.143E-03
-6.093E+05
-3.592E+02
2.451E-06
298
2500
BRUCITE
Mg(OH)2
63.2
0.1
1.022E+02
1.511E-02
-2.617E+06
MANGANOSITE
MnO
59.7
0.1
6.028E+01
3.510E-03
PYROLUSITE
MnO,
52.8
0.1
2.904E+02
-1.442E-01
298
900
-2.975E+02
2.012E+06
-3.787E+03
298
2000
4.541E-05
A^H0
kJ-ol'
298
1500
HEMATITE
Fe23
2.7267E-01 -1.0239E+08
T^,
K
298
850
950
1.24
49
NAME AND FORMULA
ENTROPY
J-mor'-IC1
A1
A2
(T)
A3
(T 2)
A4
(T"06)
AS
(T2)
T range
K
325
1400
BIXBYITE
113.7
0.2
1.624E+02
1.211E-02
1.046E+06
-1.317E+03
HAUSMANNITE
164.1
0.3
-7.432E+00
9.487E-02
-6.712E+06
3.396E+03
BRAUNITE
416.4
0.8
4.301E+02
1.110E-01
-7.325E+06
MOLYBOITE
MoOj
77.7
0.4
6.433E+00
6.278E-02
-2.460E+06
1.337E+03
NITROGEN DIOXIDE
N02
240.1
0.1
1.018E+02
-1.121E-02
1.218E+06
-1.300E+03
DISODIUM MONOXIDE
Na20
75.3
0.8
1.1397E+02
7.4857E-03
BUN SEN I TE
NiO
38.0
0.2
4.1107E+03 -5.3024E+00 2.43067E+07 -5.3039E+04
3.5206E-03
298
519
BUNSENITE
NiO
67.7
0.5
-8.776E+00
4.223E-02
3.607E+06
-7.526E-06
519
1800
LITHARGE
PbO
66.5
0.2
5.102E+01
1.027E-02
-7.387E+05
298
1000
PLATTNERITE
Pb02
71.8
0.4
7.312E+01
7.484E-03
-1.261E+06
298
1200
MINIUM
212.0
6.7
1.779E+02
3.326E-02
-2.926E+06
298
1800
SULFUR DIOXIDE
S02 (IDEAL GAS)
248.2
0.1
9.890E+01
-1.161E-02
8.465E+05
-1.127E+03
1.788E-06
298
2500
SULFUR TRIOXIDE
$03 (IDEAL GAS)
256.8
0.8
1.478E+02
-1.898E-02
1.079E+06
-1.794E+03
2.763E-06
298
2500
SILICON MONOXIDE
SiO (IDEAL GAS)
211.6
0.8
5.686E+01
-5.616E-03
4.922E+05
-5.335E+02
8.5943E-07
298
2500
QUARTZ
Si02
41.5
0.1
8.1145E+01
1.828E-02
-1.810E+05
-6.985E+02
5.406E-06
298
844
QUARTZ
Si02
104.6
0.2
5.796E+01
9.330E-03
1.835E+06
3.462E-06
T*,
K
298
1400
298
1500
298
1074
1.461E-06
298
1000
-8.1335E+02
7.873E+02
298
2500
844
1700
1074
A^H0
kJ-nol'1
50

NAME AND FORMULA
ENTROPY
J-mol'-IC1
A1
A2
(T)
A3
(T 2)
A4
<r 6)
7.168E+04
AS
(T2)
T range
K
T^,
K
A^H'
kJ'Ml'1
298
523
CRISTOBALITE
Si02
43.4
0.1
-4.160E+03
2.548E+00
-6.286E+07
CRISTOBALITE
Si02
76.3
1.0
7.275E+01
1.300E-03
-4.132E+06
COESITE
Si02
38.5
1.0
2.331E+02
-7.777E-02
2.604E+06
-3.375E+03
1.924E-05
298
1800
STISHOVITE
Si02
27.8
0.4
1.474E+02
-4.027E-02
-2.834E+05
-1.559E+03
1.203E-05
298
1800
SILICA GLASS
Si02
48.5
1.0
7.464E+01
-7.259E-03
-3.114E+06
5.570E-06
298
1700
CASSITERITE
Sn02
49.0
0.1
7.604E+01
7.364E-03
-2.224E+06
STRONTIUM MONOXIDE
SrO
55.5
0.4
5.365E+01
5.982E-03
-3.666E+05
THORIANITE
Th02
65.2
0.2
7.138E+01
7.556E-03
-1.053E+06
RUTILE
50.6
0.2
8.462E+01
5.990E-04
-1.101E+06
-2.957E+02
298
2100
ANATASE
49.9
0.3
4.396E+01
1.374E-02
-2.595E+06
6.294E+02
298
1300
URANINITE
77.0
0.2
5.845E+01
1.606E-02
-1.867E+06
3.689E+02
uo2
298
1800
KARELIANITE
V23
98.1
1.3
5.799E+01
4.120E-02
-3.872E+06
1.351E+03
298
1800
TUNGSTEN DIOXIDE
50.6
0.3
6.638E+01
1.326E-02
-1.294E+06
Z INCITE
ZnO
43.2
0.1
4.350E+01
7.658E-03
-7.573E+05
5.456E+01
298
1800
BADDELEYITE
50.4
0.3
1.073E+02
-5.011E-03
-2.203E+05
-8.141E+02
298
1478
BADDELEYITE
ZrOj,
167.1
1.5
7.448E+01
523
1800
298
1500
-1.019E+02
298
2500
298
1200
298
2500
1478
2000
1478
8.08
MULTIPLE OXIDES
51
COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR MULTIPLE OXIDE MINERALS
NAME AND FORMULA
A2
(T)
A3
<T'2)
A4
(T"06)
109.6
0.8
2.111E+02
1.461E-02
-3.625E+06
-6.610E+02
66.3
0.1
3.627E+02
-8.353E-02
-6.798E+04
-4.034E+03
CALCIUM FERRITE
CaFe204
145.4
0.8
9.588E+01
4.666E-02
-3.360E+06
1.410E+03
298
1510
D I CALCIUM FERRITE
188.8
1.3
2.223E+02
9.728E-03
-5.661E+06
5.420E+02
298
1750
PEROVSKITE
CaTiO
93.6
0.4
1.250E+01
4.516E-02
-6.302E+06
2.462E+03
298
1530
HERCYNITE
FeAl 204
116.0
3.0
2.247E+02
4.480E-03
-1.581E+06
-1.370E+03
298
1200
CHROMITE
FeCr204
146.0
1.7
3.018E+02
-4.157E-02
4.877E+05
-2.803E+03
1.147E-05
298
1800
ILMENITE
FeTiOj
108.9
0.3
2.627E+02
-7.999E-02
3.827E+05
-2.538E+03
3.388E-05
298
1000
ULVOSPINEL
Fe2Ti04
168.9
2.5
-1.026E+02
1.425E-01
-9.145E+06
5.271E+03
298
1800
PSEUDOBROOKITE
Fe2Ti05
156.5
1.3
2.136E+02
1.625E-02
-2.3A5E+06
-4.795E+02
298
1800
84.5
0.04
2.229E+02
6.127E-03
-1.686E+06
-1.551E+03
298
1800
MAGNESIOCHROMITE
MgCr204
106.0
0.8
1.961E+02
5.398E-03
-3.126E+06
-6.169E+02
298
1800
MAGNESIOFERRITE
MgFe204
123.8
0.8
1.782E+02
1.275E-02
665
1230
MAGNESIOFERRITE
MgFe204
379.2
3.0
1.066E+02
5.716E-02
1230
1800
GEIKIELITE
MgTiOj
74.6
0.2
2.225E+02
-5.274E-02
PYROPHANITE
MnTiOj
104.9
0.3
1.217E+02
9.288E-03
CHRYSOBERYL
SPINEL
MgAl2o4
- 6. 092E+05 -1.8746E+03
-2.188E+06
AS
(T2)
T range
K
A1
TIALITE
ENTROPY
J-aor'-IC1
298
1800
2.248E-05
1.878E-05
298
1800
298
1800
298
1600
T^
K
A^M0
kJ-ol 1
52

COEFFICIENTS FOR NEAT CAPACITY EQUATIONS FOR MULTIPLE OXIDE MINERALS
NAME AND FORMULA
ENTROPY
A1
j-aoi-'-ir1
A2
A3
A4
AS
T range
TM
A^N0
(T>
<r2>
<r 6>
<T2>
ic
kj-aor1
TREVORITE
165.0
3.0
9.559E+01
1.705E-01
3.9927E+04
298
1000
FRANKLINITE
ZnFe204
150.7
0.3
1.995E+02
3.045E-02
-1.352E+06
298
600
143.1
2.613E+02
-5.138E-03
-4.317E+05
Zn2Ti04
0.3
-2.095E+03
298
1800
53
HALIDES
COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR HALIDE MINERALS
NAME AND FORMULA
A2
(T)
107.1
0.4
3.317E+01
6.443E-02
POTASSIUM BROMIDE
KBr
95.9
0.2
-4.392E+01
5.855E-02
-1.839E+06
CHLORARGYRITE
AgCl
96.2
0.2
5.996E+01
7.620E-03
-1.017E+06
HYDROPHILITE
CaCl2
104.6
1.3
-4.725E+00
4.504E-02
-2.037E+06
HYDROPHILITE
CaCl2 (liquid)
230.2
5.0
1.025E+02
LAURENCITE
FeCl2
118.0
0.4
-1.123E+02
8.951E-02
-5.115E+06
MOLYSITE
FeCl3
142.3
0.4
-2.56E+02
1.1755E+00
7.89E+06
HYDROGEN CHLORIDE
HCl (ideal gas)
186.9
0.03
1.738E+01
1.165E-02
-7.597E+03
1.477E+02
SYLVITE
KCl
82.6
0.2
-2.452E+01
4.852E-02
-1.605E+06
1.371E+03
CHLOROMAGNESITE
MgCl2
89.6
0.8
7.690E+01
8.496E-03
- 7. 463E+05
298
987
118.2
0.2
7.626E+01
1.191E-02
-6.048E+05
298
923
SALAMMONIAC
NH4Cl
95.0
0.4
8.410E+01
HALITE
NaCl
72.1
0.2
4.515E+01
1.797E-02
298
1074
170.3
2.2
7.2008E+01
-3.2228E-03
1074
1791
97.7
0.2
-5.078E+01
5.748E-02
136.0
2.1
1 .229E+02
SCACCHITE
MnCl2
HALITE
NaCl (liquid)
NICKELOUS CHLORIDE
NiCl2
COTUNNITE
PbCU
A3
(T 2)
A4
(T* 6)
AS
<TZ)
T range
K
A1
BROMARGYRITE
AgBr
ENTROPY
J-Bol'-IC1
T,.,
K
A...H0
kJ-wol'1
298
703
298
1000
1.717E+03
298
728
298
1045
1.5036*03
1045
1800
298
950
3.790E+03
-9.738E-04
298
577
-2.052E-06
298
2500
298
1043
298
-4.064E+06
2.608E+03
298
1303
-8.585E+02
298
768
1045
28.54
54

COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR HALIDE MINERALS
NAME AND FORMULA
ENTROPY
J-mol-'-r1
A1
A2
(T)
A3
(T 2)
A4
(T-06)
AS
(T2)
T range
K
kJ-nol'1
68.9
0.3
2.033E+03
-1.436E+00
2.988E+07
-3.312E+04
5.040E-04
298
1400
173.8
0.04
6.845E+00
1.301E-02
-4.108E+05
4.007E+02
-1.911E-06
298
2500
SELLAITE
MgF2
57.3
0.4
9.474E+01
1.595E-04
-7.328E+05
-4.322E+02
298
1536
1536
58.16
VILLIAUMITE
NaF
51.5
0.1
-2.612E+00
3.347E-02
-1.402E+06
9.542E+02
298
1269
1269
33.14
298
836
836
8.20
836
1153
1153
1.8
1153
1290
1290
113.75
298
1010
1010
80.83
FLUOR I TE
CaF2
HYDROGEN FLUOR IDE
HF (ideal gas)
CRYOLITE
238.5 4.04227E+03 -3.8582E+00

0.5
CRYOLITE
512.4
2.5
2.3669E+02
CRYOLITE
605.5
2.5
3.0041E+02
CHIOLITE
515.3
0.8
5.099E+02
8.768E-02
IODARGYRITE
115.5
1.7
2.4351E+01
1.0083E-02
Agl
MARSHITE
Cul
96.6 -1.6941E+03
0.5
3.4071E+07 -5.5876E+04
4.7986E-02
-7.301E+06
1.0046E+00 -2.8543E+07
2.004E-03
298
423
3.0558E+04
298
643
55
COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR CARBONATE AND NITRATE MINERALS
NAME AND FORMULA
ENTROPY
J-niol'-lf1
A1
A2
(T)
A3
(T 2)
A4
(T*6)
3.760E+03
AS
(T2)
T ranee
K
T^
K
A^H*
kJ-mol 1
298
1079
WITHER I TE
BaCO;
112.1
2.1
-9.936E+01
1.258E-01
-6.274E+06
ARAGONITE
CaCOj
88.0
0.2
8.153E+01
4.567E-02
-1.141E+06
298
1000
CALCITE
CaCC^
91.7
0.2
9.972E+01
2.692E-02
-2.158E+06
298
1200
DOLOMITE
155.2
0.3
5.479E+02
-1.676E-01
2.840E+06
-6.548E+03
SIDERITE
FeCOj
95.5
0.2
2.574E+02
-4.620E-02
1.523E+06
- 3. 082 E +03
MAGNESITE
MgCOj
65.1
0.1
8.112E+01
5.225E-02
-1.832E+06
RHOOOCHROSITE
MnCOj
98.0
0.1
1.497E+02
1.876E-02
1.417E+05
THERMONATRITE
168.1
0.8
7.240E+01
2.607E-01
-1.258E+05
298
380
DAUSONITE
NaAlC03(OH)2
132.0
0.5
3.441E+01
3.347E-04
7.464E+02
298
500
STRONTIANITE
SrCOj
97.1
1.7
-1.618E+02
1.2795E-01
-9.018E+06
5.294E+03
298
1197
SMITHSONITE
ZnCOj
81.2
0.2
1.4838E+02
2. 835 E- 02
4.796E+05
-1.419E+03
298
1200
NITROBARITE
213.8
0.8
1.255E+02
1.497E-01
-1.670E+06
CALCIUM NITRATE
Ca(N03)2
193.3
0.4
7.815E+01
1.734E-01
-2.778E+06
MAGNESIUM NITRATE
164.0
0.8
5.8417E+01
2.7292E-01
1.8949E+05
SODA NITER
NaNOj
116.5
0.7
2.570E+01
2.237E-01
1.161E+01
298
549
STRONTIUM NITRATE
Sr(NO,),
194.6
0.5
1.3389E+03
-3.79E-01
2.5757E+07 -2.3582E+04
298
900
7.708E-05
298
1100
298
600
298
1000
-1.3142E+03
298
600
298
800
8.722E+02
298
800
298
600
1197
18.82
56

COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR SULFATE AND PHOSPHATE MINERALS
NAME AND FORMULA
ENTROPY
J-mol-'-lf1
A1
A2
(T)
A3
(T 2)
A4
(r B)
AS
(T2)
T range
-8.615E+03
298
1100
-3.507E+06
298
1300
ALUMINUM SULFATE
A12(S04)3
239.3
1.2
7.877E+02
BARITE
BaS04
132.2
0.8
1.412E+02
ANHYDRITE
CaS04
107.4
0.2
3.728E+02
-1.574E-01
CHALCOCYANITE
CuS04
109.5
0.6
1.615E+02
4.796E-02
-3.192E+06
298
1200
FERRIC SULFATE
Fe2(S04)3
282.8
0.8
2.553E+02
2.269E-01
-4.260E+06
298
800
ARCANITE
175.6
0.4
1.2037E+02
9.958E-02
-1.782E+06
298
856
ARCANITE
360.9
1.0
-8.445E+02
6.845E-01
3.499E+08
856
1342
K-Al SULFATE
KAl(S04)2
204.6
1.3
2.370E+02
7.828E-02
-5.988E+06
298
1000
ALUNITE
KA13(OH)6(S04 )2
321.0
5.0
5.145E+03
1.1375E-01
-1.5635E+07
298
700
LANGBEINITE
389.3
0.8
5.359E+02
1.101E-01
-1.020E+06
MAGNESIUM SULFATE
MgS04
91.4
0.8
1.056E+02
4.717E-02
-2.129E+06
298
1400
MANGANOUS SULFATE
MnS04
127.0
2.0
1.203E+02
3.999E-02
-2.818E+06
298
1000
NASCAGNITE
(NH4 )2S04
220.5
1.3
1.0436E+02
2.788E-01
298
600
THENARDITE
Na2S04 (hexagonal)
239.7
1.0
1.2193E+02
8.141E-02
514
1155
THENARDITE
Na2S04 (liquid)
424.6
2.0
2.011E+02
-3.941E-03
1155
1800
NICKELOUS SULFATE
NiSO,
101.3
0.2
1.240E+02
3.062E-02
-9.899E-02
1.695E+06 -4.3308E+03
-3.150E+06
-4.040E+03
7.99E-05
-4.909E-05
298
1000
298
1000
298
1200
TU,
A^H*
SULFATES AND PHOSPHATES
57
COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR SULFATE AND PHOSPHATE MINERALS
NAME AND FORMULA
ENTROPY
A1
A2
(T)
A3
(T 2)
A4
<r 6>
AS
(T2)
T range
K
ANGLE SITE
PbS04
148.5
0.6
4.683E+01
1.278E-01
1.724E+06
298
1100
ZINKOSITE
ZnS04
110.5
1.3
4.019E+01
1.243E-01
2.389E+06
298
1100
BERLINITE
AlP04
90.8
0.2
1.9833E+03 -1.64948E+00
2.0607E+07 -2.93193E+04
7.72E-04
298
830
UHITLOCKITE
236.0
0.8
1.929E+02
1.742E-01
-1.174E+06
FLUORAPATITE
Ca5(P04)3(F)
387.9
1.7
7.543E+02
-3.026E-02
- 9. 084E+05
-6.201E+03
298
1600
HYDROXYAPATITE
Cas (P04)3(OH)
390.4
1.7
3.878E+02
1.186E-01
-1.270E+07
1.811E+03
298
1500
298
1373
T^
K
A^H0
kJ-aol'1
58

COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR ORTNO AND RING STRUCTURE SILICATE MINERALS
NAME AND FORMULA
ENTROPY
J-Bor'-IT1
TOPAZ
Al2Si04F2
A1
A2
(T)
A3
<T 2>
A4
<r 6>
AS
<T2)
T range
K
105.4
0.2
4.714E+02
-8.165E-02
1.270E+06
-5.486E+03
298
1000
KYANITE
Al2Si05
82.8
0.5
2.794E+02
-7.124E-03
-2.056E+06
-2.289E+03
298
2000
ANDALUSITE
Al2Si05
91.4 2.77306E+02
0.1
-6.588E-03 -1.9141E+06 -2.2656E+03
298
2000
SILLIMANITE
Al2Si05
95.4
0.6
2.8019E+02
-6.900E-03
-1.376E+06
-2.399E+03
298
2000
275.0
5.0
7.546E+02
-2.943E-02
-3.454E+06
-6.576E+03
298
1800
334.9 1.43871E+03
5>0
-2.427E-01
3.860E+06
-1.682E+04
4. 884E- 05
298
1800
MULLITE
Al6Si213
DUMORTIERITE
)H) .75
PHENAKITE
Be2Si04
63.4
0.3
4.2849E+02
-9.958E-02
2.083E+06 -5.6705E+03
1.989E-05
298
1800
BERYL
346.7
4.7
1.625E+03
-4.252E-01
6. 825 E +06
-2.018E+04
1.203E-04
298
1800
BERTRANDITE
Be4Si 207(OH)2
172.1
0.8
8.253E+02
-9.965E-02
3.662E+06
-1.057E+04
EUCLASE
BeAlSi04(OH)
89.1
0.4
5.329E+02
-1.507E-01
2.198E+06
-6.726E+03
EPIDOTE
328.9
2.5
3.676E+02
LAWSONITE
CaAl2Si207(OH)2H20
230.0
0.4
2.7732E+02
2.341E-01
-6.389E+06
GEHLENITE
Ca2Al2Si07
210.1
0.6
4.057E+02
-7.099E-03
-1.188E+06
ZOISITE
295.9
0.3
1.134E+03
-4.523E-01
GROSSULAR
260.1
0.5
1.5293E+03
-6.990E-01
GLASS
Ca3M2Si312
329.9+
0.7
3.392E+02
298
1400
4.122E-05
298
1800
298
7.443E+06
298
600
298
1800
-3.174E+03
-1.157E+04
2.391E-04
298
750
-1.894E+04
2.530E-04
298
1200
298
T,.,
K
A^N'
kJ-mol 1
59
COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR ORTHO AND RING STRUCTURE SILICATE MINERALS
NAME AND FORMULA
ENTROPY
J'Bor'-lf'
A1
A2
(T)
A3
(T 2)
A4
<r 6>
4.0191E+05
-2.0305E+03
A5
(T2)
T range
1C
DATOLITE
CaB(Si04)(OH)
110.2
0.6
ILVAITE
CaFejCSiÔCOH)
292.3
0.6
8.569E+03 -5.2407E+00
9.6449E+07 -1.3456E+05
ANDRADITE
316.4
2.0
8.092E+02
-7.025E-02
-6.789E+05
-7.403E+03
MONT I CELL I TE
CaMgSi04
108.1
0.3
2.314E+02
-8.531E-04
-1.247E+06
-1.623E+03
-1.333E-06
298
1000
AKERMANITE
Ca^gSi^
212.5
0.4
7.8146E+01
1.6573E-01
-6.7905E+06
2.8646E+03
-3.3437E-05
298
1731
MERUINITE
Ca3Mg(Si04 )2
253.1
2.1
6.508E+02
-1.816E-01
-6.053E+03
7.036E-05
298
1600
TITANITE (Sphene)
CaTiSiOj
129.2
0.8
1.767E+02
2.385E-02
-3.991E+06
LARNITE
a-Ca2Si04
127.6
0.8
2.487E+02
-8.315E-04
-9.077E+04
BREDIGITE
a'-Ca2Si04
314.2
1.0
1.3456E+02
4.611E-02
CALCIO-OLIVINE
Y~Ca2Si04
120.5
0.8
1.327E+02
5.251E-02
-1.905E+06
HATURITE (ALITE)
CajSiOj
168.6
0.3
3.339E+02
-4.651E-03
-6.526E-KK
-2.766E+03
298
1800
RANKINITE
Ca3Si 207
210.6
2.9
4.732E+02
-4.207E-02
3.397E+05
-4.319E+03
298
1400
ROSENHAHNITE
Ca3Si 38(OH>2
281.8
3.0
3.650E+02
5.419E-02
-8.161E+06
SPURRITE
Cas (Si04)2C03
331.0
2.0
TILLEYITE
Ca5Si 207(C03)2
394.0
4.0
7.417E+02
-5.345E-03
-1.435E+06
-5.879E+03
COBALT-OLIVINE
Co2Si04
142.6
0.2
3.0583E+02
-3.195E-02
2.693E+05
-2.865E+03
1.9446E+02
6.141E+02
1.8447E-01
-3.508E-03
-1.01E-04
0.68
298
1000
298
970
298
1200
298
1800
-4.168E+03
357.9
290
376
970
1710
-2.493E+06
A^H0
kJ-mol 1
298
1000
298
1670
-2.052E+03
T^,
K
298
1300
298
1200
298
1100
60
COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR ORTHO AND RING STRUCTURE SILICATE MINERALS
NAME AND FORMULA
ENTROPY
J-mol-'-IT1
A1
A2
(T)
A3
(T 2)
A4
(T^ 6)
AS
(T2)
T range
1C
FAYALITE
Fe2Si04
151.0
0.2
1.7602E+02
-8.8086-03
-3.889E+06
ALMANDINE
342.6
1.4
8.629E+02
-8.288E-02
1.697E+06
-8.875E+03
298
1200
STAUROLITE
Fe4Al 18Si 8046(OH)2
985.0
4.0
2.7986+03
7.921E-02
-9.952E+06
-2.474E+04
298
1000
5.842E+02
1.2766+00
-3.967E+06
-1.556E+03
OSUMILITE
2.471E-05
-6.497E-04
298
1490
8.123E+02
4.334E-02
-8.211E+06
-5.000E+03
FORSTERITE
94.1
0.1
8.7366+01
8.717E-02
-3.699E+06
8.4366+02
-2.237E-05
298
1800
PYROPE
Mg3Al2Si 3o12
266.3
0.8
8.730E+02
-1.374E-01
4.500E+03
-8.794E+03
3.341E-05
298
1570
GLASS
346.3
12.0
5.1386+02
7.119E-02
-5.857E+05
-2.439E+03
6. 3006+02
3.50E-02
298
1020
1083
1863
PYROPE-GROSSULAR ss
268.3+
0.5
3.2806+02
298
GLASS
(Mg, 5Ca1>5 )Al 2Si 3012
311.8+
0.6
3.329E+02
298
TEPHROITE
155.9
0.5
2.613E+02
-1.3786-02
LIEBENBERGITE
Ni 2Si04
128.1
0.2
2.897E+02
-2.402E-02
1.310E+05
Ni 2Si04-SPINEL
Ni 2Si04
124.1
0.4
1.654E+02
1.412E-02
-4.345E+06
UILLEMITE
Zn2Si04
131.4
0.8
1.233E+02
84.0
1.3
2.370E+02
ZIRCON
ZrSiO4
-2.218E+03
298
1600
-2.779E+03
298
1300
350
800
298
-1.788E-02
-1.496E+05
-2.268E+03
1490
298
1700
407.2
3.8
GLASS
Mg3Al 2Sl* 3012
A^H*
kJ-mol'1
298
1000
CORDIERITE
Mg2Si04
T^
K
298
1600
1570
241.0
61
CHAIN AND BAND STRUCTURE SILICATES

COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR CHAIN STRUCTURE SILICATE MINERALS
NAME AND FORMULA
ENTROPY
J-aor'-lf1
A1
A2
(T)
A3
(T 2)
A4
<r 6>
AS
(T2)
T range
1C
A^N"
kJ-nol'1
298
1400
1398
5.93
298
1821
1821
. 57.30
1668
137.70
UOLLASTONITE
CaSiOj
81.7
0.1
2.0078E+02
-2.589E-02
-1.579E+05
-1.826E+03
PSEUDOUOLLASTONITE
CaSiOj
87.2
0.9
1.578E+02
-1.045E-03
-6.396E+05
-1.077E+03
GLASS
CaSiOj
94.8
3.0
9.689E+01
3. 425 E- 02
-1.804E+06
Ca-Al PYROXENE
CaAl2Si06
141.0
2.0
4.652E+02
-7.838E-02
6.729E+05
GLASS
CaAl2Si06
155.3
0.3
1.661E+02
FERROBUSTAMITE
CaFeSigOg
180.5
0.3
4.038E+02
-4.444E-02
HEDENBERGITE
CaFeSi2Og
174.2
0.3
3.1046E+02
1.257E-02
GLASS
CaFeSi206
185.7+
0.4
1.732E+02
DIOPSIDE
CaMgSi206
142.7
0.3
4.7025E+02
-9.864E-02
2.454E+05
-4.823E+03
2.813E-05
298
1700
GLASS
CaMgSi^
166.0
3.0
1.041E+03
-6.358E-01
6.677E+06
-1.351E+04
2.724E-04
298
1400
FERROSILITE
FeSiOj
94.6
0.3
1.243E+02
1.454E-02
-3.3786+06
a-SPODUMENE
LiAlSi206
129.3
0.8
4.212E+02
-2.401E-02
1.910E+06
B-SPODUMENE
LiAlSi 206
154.4
1.2
3.628E+02
-3.684E-03
ENSTATITE
MgSiOj
66.3
0.1
3.507E+02
-1.472E-01
GLASS
MgSiOj
74.1
0.2
8.205E+01
CLINOENSTATITE
MgSiOj
67.9
0.4
2.056E+02
7.434E-06
T,
1C
298
1821
-4.941E+03
1.934E-05
298
1000
298
-3.757E+03
-1.846E+06
1.597E-05
298
1600
298
1300
-2.040E+03
298
1.769E+06
298
800
-4.776E+03
298
1200
- 3. 435 E +03
298
1700
-4.296E+03
5.826E-05
298
1000
298
-1.280E-02
1.193E+06
-2.298E+03
298
1600
1834
73.20
62

COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR CHAIN STRUCTURE SILICATE MINERALS
NAME AND FORMULA
ENTROPY
j-nor'-lf'
A1
A2
(T)
A3
(T 2)
A4
(T^ 6)
AS
(T2)
T range
1C
298
700
MgSi03-ILMEMITE
MgSiOj
60.4
3.0
6.912E+01
7.330E-02
1.037E+06
HYPERSTHENE
(Hg .85 Fe.15 )Si3
69.0+
0.2
2.079E+02
-1.489E-02
1.921E+05
-2.135E+03
298
1000
RHODONITE
MnSiOj
100.5
1.0
9.904E+01
1.915E-02
-3.041E+06
2.745E+02
298
1500
JADEITE
NaAlSi 206
133.5
1.3
3.011E+02
1.014E-02
-2.239E+06
- 2. 05 5 E +03
298
1300
GLASS
NaAlSi 206
170.5
0.4
1.663E+02
ACMITE
NaFeSi 206
170.6
0.8
1.994E+02
6.197E-02
-4.267E+06
TREMOLITE
Ca2Mg5Si8022(OH)2
548.9
1.3
6.131E+03
-4.189E+00
5.139E+07
GRUNERITE
Fe7Si 8022 (OH)2
725.0
7.0
7.555E+02
3.620E-01
-1.621E+07
ANTHOPHILLITE
Mg7Si8022(OH)2
534.5
3.5
1.260E+03
1.888E-02
-1.164E+07
RIEBECKITE
691.0
6.0
7.721E+02
2.827E-01
-1.598E+07
541.2
3.0
1.718E+03
-1.21 IE-01
7.075E+06
Na2Fe3Fe2Si8022 (OH)2
GLAUCOPHANE
Na,Mg,Al,SiftO,3<OH>,
298
298
1300
-8.566E+04
1.757E-03
298
1100
298
900
-8.127E+03
298
1200
298
1000
-1.927E+04
298
1200
T^,
K
A^H0
kJ-mol 1
63
FRAMEWORK SRUCTURE SILICATES

COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR FRAMEWORK STRUCTURE SILICATE MINERALS
NAME AND FORMULA
ENTROPY
J-niol'-lf1
A1
A2
(T)
A3
(T 2)
A4
(T* 6)
AS
(T2)
T range
1C
EDINGTONITE (ordered)
434.8
1.5
4.220E+02
ANORTHITE
199.3
0.3
5.168E+02
-9.249E-02
-1.408E+06
-4.589E+03
CaAl2Si' 2Og-glass
237.3
2.5
3.752E+02
3.197E-02
-2.815E+06
-2.459E+03
BICCHULITE
213.1
5.0
2.803E+02
8.204E-02
-5.679E+06
298
1800
MEIONITE (ordered)
715.2
1.0
9.103E+02
1.9435E-01
-2.300E+07
298
1000
DAN BUR I TE
CaB2Si 28
155.3
0.4
1.488E+02
2.173E-01
-3.280E+06
298
1000
POLLUCITE
207.2
(Cs 65Na 19Rb 03)Al 2Si 412' H2 ' 4
1.128E+02
1.876E-01
4.556E+05
298
700
MICROCLINE
KAlSi308
214.2
0.4
7.595E+02
-2.171E-01
4.746E+06
-9.527E+03
6.433E-05
298
1400
SANIDINE
KAlSi 308
232.8
0.5
6.934E+02
-1.717E-01
3.462E+06
-8.305E+03
4.919E-05
298
1400
GLASS
KAlSijOg
261.6
1.8
6.295E+02
-1.084E-01
2.496E+06
-7.210E+03
-1.928E-05
298
1300
KALIOPHILLITE
KAlSi04
133.3
1.2
1.889E+02
5.519E-02
LEUCITE
KAlSi 206
200.2
1.7
1.4842E+02
1.343E-01
-2.165E+06
298
955
LEUCITE
KAlSi^
450.1
2.0
1.9647E+02
2.7666E-02
1.2261E+07
955
1800
EUCRYPTITE
LiAlSi04
103.8
0.8
2.470E+02
PETAL I TE
LiAlSi401Q
233.2
0.6
8.763E+02
ALBITE
NaAlSijOg
207.4
0.4
5.839E+02
T^
K
r,
298
4.188E-05
298
1800
298
1500
298
810
-1.479E+03
298
1300
-1.290E+06
-2.058E+03
-2.079E-01
4.033E+06
-1.069E+04
5.301E-05
298
1300
-9.285E-02
1.678E+06
-6.424E+03
2.272E-05
298
1400
1830
133.0
4.0
1500
54.0
810
0.5
64

COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR FRAMEWORK STRUCTURE SILICATE MINERALS
NAME AND FORMULA
ENTROPY
J-Bor'-lf1
A1
A2
(T)
A3
<r2)
A4
<T" 6>
AS
<T2)
T range
K
ANALBITE
NaAlSijOg
225.6
0.4
6.714E+02
-1.467E-01
3.174E+06
-7.974E+03
3.659E-05
298
1400
GLASS
NaAlSijOg
251.9
1.5
9.180E+02
-3.824E-01
5.280E+06
-1.151E+04
1.474E-04
298
1200
NEPHELINE
NaAlSi04
124.4
1.3
2.774E+01
2.954E-01
298
457
1.1209E+02
6.71 IE-02
457
1180
1180
1525
NEPHELINE
NaAlSi04
NEPHELINE
NaAlSi04
338.3
2.0
1.720E+02
5.520E-03
CARNEGIEITE
NaAlSi04
118.7
0.3
1.1613E+02
8.595E-02
CARNEGIEITE
NaAlSi04
311.1
1.5
1.5232E+02
2.883E-02
GLASS
NaAlSi04
134.5
0.5
3.171E+02
-4.320E-02
1.121E+02
6.711E-02
NEPHELINE
<Ma .78K.22>AlSi4
273
966
-2.000E+06
966
1700
4.163E+05
-3.244E+03
272
1033
467
1180
ANALCIME
NaAlSi 206 'H20
227.7
0.3
1.3438E+02
2.5415E-01
1.845E+05
298
700
DEHYDRATED ANALCIME
NaAlSi,0A
172.5
0.2
1.9211E+02
8. 0735 E- 02
- 4. 723 E +06
298
1000
T^
1C
1393
966
A..H8
kJ-nol'1
64.5
8.5
65
SHEET STRUCTURE SILICATES

COEFFICIENTS FOR NEAT CAPACITY EQUATIONS FOR SHEET STRUCTURE SILICATES
NAME AND FORMULA
ENTROPY
A1
A2
A3
(T 2)
A4
(T^06)
DICKITE
Al 2Si 205 (ON)4
197.1
1.3
9.084E+02
-2.113E-01
3.804E+06
-1.120E+04
KAOLINITE
Al 2Si 25 (OH>4
200.4
0.5
1.4303E+03
-7.885E-01
8.334E+06
-1.852E+04
HALLOTSITE
A12S1*25(OH>4
203.0
2.463E+02
PYROPHYLLITE
Al2Si 4010(OH)2
239.4
0.4
7.468E+02
1104.2
1.291E+03
ILLITE
K3(Al 7Mg)(Al 2Si 14 )040(OH)8
AS
(Ta)
T range
K
298
1000
3.034E-04
298
800
298
1.3
-7.578E+03
-5.345E-02
1.986E-05
298
800
298
2.5
MARGARITE
CaAl 2 [Al 2Si201Q](OH)2
263.6
PREHNITE
292.8
0.7
9.460E+02
-1.1506E-01
MUSCOVITE (disordered)
KAl 2 [AlSi 3010l(OH) 2
306.4
0.6
9.177E+02
-8.111E-02
MUSCOVITE (ordered)
KAl 2 [AlSi 3010HOH) 2
287.7
9.177E+02
ANNITE
KFe3 [AlSi 301Q](OH)2
415.0
10.0
PHLOGOPITE (disordered)
KMg3 [AlSi 3010](OH)2
334.6
PHLOGOPITE (ordered)
KMg3 CAlSi 3010](OH)2
8.265E+02
298
-8.7274E+03
-5.040E-01
1200
0.3
-1.056E+04
298
1200
2.834E+06
-1.035E+04
298
1000
-8.111E-02
2.834E+06
-1.035E+04
298
1000
6.366Ef02
8.208E-02
-4.860E+06
-3.731Ef03
298
1000
8.639E+02
-7.6076E-02
3.5206E+05
-8.470E+03
298
1000
315.9
1.0
8.639E+02
-7.6076E-02
3.5206E+05
-8.470E+03
298
1000
FLUORPHLOGOPITE (disordered) 336.3

KMg3 [AlSi 301Q]F2
2.1
4.9288E+02
4.910E-02
-6.599E+06
-1.569E+03
298
1670
FLUORPHLOGOPITE (ordered)
317.6
2.1
4.9288E+02
4.910E-02
-6.599E+06
-1.569E+03
298
1670
TALC
M93Si 410(OH>2
260.8
0.6
5.654E+03
-5.272E+00
4.021E+07
-7.693E+04
CHRYSOTILE
Mg3Si 205 (OH)4
221.3
0.8
8.996E+02
-1.448E-01
4.500E+06
-1.093E+04
2.755E+06
0.6
1.0
2.729E-03
298
800
298
900
T,.,
K
kJ-M>r
66

COEFFICIENTS FOR HEAT CAPACITY EQUATIONS FOR SHEET STRUCTURE SILICATES
NAME AND FORMULA
ENTROPY
J-iiol-'-ir1
A1
A2
(T)
A3
(T 2)
A4
(t06)
AS
(T2)
3.6206E-03
T range
1C
CLINOCHLORE
Mg5Al(AlSi3010)(OH)8
421.0 9.47951E+03 -7.8834E+00 8.31194E+07 -1.3594E+05

15.0
298
800
PARAGON I TE (disordered)
MaAl 2 [AlSi3010](OH)2
295.8
0.9
6.6844E+02
3.627E-02
-1.860E-K)6
-5.816E--03
298
800
PARAGON I TE (ordered)
NaAl 2 [AlSi3010](OH)2
277.1
0.9
6. 6844 E +02
3.627E-02
-1.860E+06
-5.816E+03
298
800
tm
K
THERMODYNAMIC PROPERTIES AT HIGH TEMPERATURE OF INDIVIDUAL PHASES
67
Thermodynamic Properties at High Temperature of Individual Phases

Formula wt
SILVER (REFERENCE STATE)
Ag:
107.868
Face-centered cubic crystals 298.15 to melting point 1234.9 K; liquid 1234.9 to 1800
K.
FORMATION FROM THE ELEMENTS
CP
Temp.
ST
<HT-H$98 )/T
-(GT-H|98 )/T
A H
298.15
300
400
500
600
700
800
900
1000
1100
1200
1234.9
1234.9
1300
1400
1500
1600
1700
1800
Melting T
25.40
25.41
25.87
26.33
26.88
27.52
28.24
29.03
29.86
30.73
31.64
31.96
33.47
33.47
33.47
33.47
33.47
33.47
33.47
42.55
42.71
50.08
55.90
60.75
64.94
68.66
72.03
75.14
78.02
80.73
81.73
90.88
92.52
95.00
97.31
99.47
101.50
103.41
1234. 9 K
0.00
0.16
6.53
10.44
13.14
15.14
16.73
18.06
19.19
20.20
21.12
21.41
30.57
30.71
30.91
31.08
31.23
31.36
31.48
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
-1
J-mol'^K" 1 -
A fG
42.55
42.55
43.55
45.46
47.62
49.80
51.93
53.98
55.94
57.82
59.62
60.32
60.31
61.81
64.09
66.23
68.24
70.14
71.93
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
A^H
AtaH*
Molar Vol .
UO
298
kJ
11.94 kJ
UO
*t A C
1 T
/4d KJ
1 .0272
10 .272
J-bar'1
cm3
6/18/92
68
Formula wt
ALUMINUM (REFERENCE STATE)
Al:
26.982
Face-centered cubic crystals 298.15 to melting point 933.5 K. Liquid 933.5 to 1800 K.
Temp.
ffO
ST
CP
--1
298.15
300
400
500
600
700
800
900
933.5
933.5
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
(HT-H$ 98 )/T
24.21
24.25
25.76
26.84
27.90
29.12
30.57
32.30
32.96
31.75
31.75
31.75
31.75
31.75
31.75
31.75
31.75
31.75
31.75
28.30
28.45
35.65
41.52
46.50
50.89
54.87
58.57
59.74
71.21
73.40
76.43
79.19
81.73
84.08
86.27
88.32
90.25
92.06
933. 5 K
0.00
0.15
6.38
10.37
13.20
15.38
17.19
18.77
19.26
30.73
30.81
30.89
30.96
31.00
31.08
31.12
31.16
31.19
31.23
-(Gf-H2 98 )/T
A fH
28.30
28.30
29.27
31.15
33.31
35.51
37.69
39.80
40.48
40.48
42.59
45.54
48.23
50.73
53.00
55.15
57.16
59.06
60.83
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJ
10.71 kJ
Molar Vol.
H298~H6
Log Kf
kJmol""*
-1
A^H
AtoH
A fG
4.565 kJ
0 .9999 J-bar'1
9 .999 cm3
4/22/92
Formula wt
ARSENIC (REFERENCE STATE)
As:
69
74.922
Ideal tetratomic gas 875 to
Rhombohedral crystals 298.15 to sublimation point 875 K.

1800 K.

Temp.
CP
ST
(H$-H2gg)/T
T.__.1 ~l-r
298.15
300
400
500
600
700
800
875
875
900
1000
1100
1200
24.65
24.67
25.38
25.96
26.51
27.05
27.60
28.03
20.60
20.61
20.64
20.67
20.69
35.69
35.84
43.04
48.77
53.55
57.68
61.33
63.82
103.62
104.14
106.31
108.28
110.08
Melting T
0.00
0.15
6.37
10.23
12.90
14.88
16.43
17.31
57.11
56.14
52.59
49.68
47.26
-(6T-H^9 8 )/T
A fH
1.T-
35.69
35.69
36.66
38.54
40.65
42.80
44.89
46.51
46.51
48.00
53.72
58.59
62.81
A fG
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
.1 "I
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
875
34.828
K
kJ
kJ
Molar Vol.
5.130 kJ
1.2963 J-bar'1
12.963
cm3
6/10/92
70
Formula wt
GOLD (REFERENCE STATE)
Au:
196.967
Face-centered cubic crystals 298.15 to melting point 1336.15 K.

Temp.
CP
CO
om
/UO_CTO
V /(It
\**T *298''
_//iO_tTQ
\**T
\ It*
298''
A H
AfG
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1.Y..~.1 ~1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1336.15
1336.15
1400
1500
1600
1700
1800
Melting T
25.18
25.19
25.88
26.26
26.57
26.91
27.36
27.93
28.67
29.57
30.66
31.95
32.47
33.54
32.75
31.49
30.81
30.81
30.81
47.49
47.65
55.00
60.82
65.63
69.76
73.38
76.63
79.61
82.38
85.00
87.51
88.55
97.94
99.34
101.54
103.54
105.39
107.15
1336.15
0.00
0.16
6.51
10.43
13.09
15.04
16.55
17.78
18.83
19.77
20.63
21.45
21.80
31.20
31.23
31.28
31.25
31.21
31.19
47.49
47.49
48.49
50.39
52.54
54.71
56.83
58.85
60.78
62.62
64.37
66.06
66.74
66.74
68.11
70.26
72.29
74.18
75.96
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
kJ
12.55
kJ
Molar Vol.
H2*98~H6
6.017 kJ
1.0215 J'bar'1
10.215
cm3
01/07/93
71
Formula wt
BORON (REFERENCE STATE)
B:
10.811
Rhombohedral crystals 298.15 to melting point 2350 K.
Temp.
CO
ST
(Hf-H298 )/T
-<GT-H298 )/T
AfH
J-mol^-K"1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
11.32
11.42
15.84
18.69
20.69
22.18
23.33
24.25
25.01
25.66
26.21
26.71
27.16
27.57
27.96
28.33
28.69
5.83
5.90
9.84
13.71
17.30
20.61
23.65
26.45
29.05
31.46
33.72
35.83
37.83
39.72
41.51
43.22
44.85
2350 K
0.00
0.07
3.51
6.28
8.52
10.37
11.92
13.24
14.38
15.38
16.26
17.04
17.75
18.39
18.98
19.52
20.02
AfG-
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJ-mol"1
5.83
5.83
6.34
7.43
8.78
10.24
11.72
13.21
14.66
16.08
17.46
18.79
20.08
21.33
22.53
23.70
24.83
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
K
kJ
22.55 kJ
Molar Vol
H2*98~H6
1.22 kJ
0.4386 J-bar'1
4.386 cm3
6/10/93
72
Formula wt
BARIUM (REFERENCE STATE)
Ba:
137.327
a-crystals (body-centered cubic) 298.15 to lambda-anomaly in heat capacity at 582 K.

p-crystals 582 to second-order lambda-anomaly in heat capacity at 768.13 K. y-cryatals
768.13 to melting point 1002 K. Liquid 1002 to boiling point 2169 K.
Temp.
CP
Sf
(HT-H 98 )/T
-(Gf-H 98 )/T
AfH
J-mol'^K"1 -
298.15
300
400
500
582
582
600
700
768
768
800
900
1000
1002
1002
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
28.09
28.14
33.23
43.74
54.43
32.47
33.94
42.36
48.10
39.07
39.07
39.07
39.07
39.07
40.62
40.37
40.12
39.86
39.61
39.36
39.10
38.85
38.60
62.42
62.59
71.24
79.72
86.71
87.13
88.16
94.02
98.02
98.34
99.81
104.41
108.52
109.34
117.07
120.60
124.20
127.44
130.38
133.08
135.58
137.92
140.13
1002 K
0.00
0.17
7.68
13.78
18.19
18.61
19.18
21.89
23.64
23.96
24.56
26.17
27.46
27.87
35.61
36.13
36.57
36.86
37.08
37.20
37.30
37.37
37.44
AfG
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJ-mol'1
62.42
62.42
63.56
65.94
68.52
68.52
68.97
72.13
74.38
74.38
75.24
78.24
81.06
81.46
81.46
84.48
87.64
90.58
93.30
95.88
98.28
100.55
102.69
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
kJ
7.749 kJ
Molar Vol
H298"H6
6.912 kJ
3.821 J-bar'
38.21 cm3
6/12/92
73
THERMODYNAMIC PROPERTIES AT fflGH TEMPERATURE OF INDIVIDUAL PHASES
Formula wt
BERYLLIUM (REFERENCE STATE)
Be:
9.012
Hexagonal close-packed crystals 298.15 to 1550 K; beta crystals 1550 to melting point
1560 K; liquid 1560 to 1800 K.

Temp.
<%
ST
Melting T
-<GT-H2 98 )/T
A fH
kJ-
.-1-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1550
1550
1560
1560
1600
1700
1800
(H*-H598 )/T
16.44
16.52
19.64
21.58
23.06
24.32
25.47
26.54
27.58
28.59
29.57
30.55
31.52
32.47
32.95
30.00
30.00
30.00
30.00
30.00
30.00
9.50
9.60
14.83
19.43
23.50
27.15
30.47
33.54
36.39
39.06
41.59
44.00
46.30
48.51
49.58
50.94
51.13
59.20
59.96
61.78
63.50
1560 K
0.00
0.10
4.64
7.84
10.26
12.18
13.77
15.13
16.32
17.39
18.37
19.27
20.11
20.90
21.28
22.64
22.68
30.76
30.74
30.70
30.66
9.50
9.50
10.19
11.59
13.24
14.97
16.71
18.41
20.07
21.67
23.23
24.73
26.19
27.61
28.30
28.30
28.45
28.44
29.22
31.08
32.84
A 6
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
I" 1
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
Aô
Afo.H0
kJ
12 .21 kJ
Molar Vol t
H298-H5
1.95 kJ
0.488 J'bar'1
4 . 88 cm3
6/18/92
74
Formula wt
BISMUTH (REFERENCE STATE)
Bi:
Rhombohedral crystals 298.15 to melting point 544.5 K.
208.980
Liquid 544.5 to 1800 K.

Temp.
CP
T--.~l
298.15
300
400
500
544.52
544.52
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
25.41
25.43
26.62
28.66
29.83
30.48
29.61
28.61
28.02
27.67
27.45
27.31
27.24
27.19
27.17
27.17
27.18
27.19
27.21
56.74
56.90
64.36
70.50
73.40
94.15
96.64
101.13
104.90
108.18
111.08
113.69
116.07
118.25
120.26
122.13
123.89
125.54
127.09
544.52 K
A fH
A fG
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1. V~l
0.00
0.16
6.61
10.80
12.39
33.14
32.76
32.24
31.74
31.31
30.93
30.61
30.33
30.09
29.88
29.70
29.54
29.41
29.28
56.74
56.74
57.75
59.70
61.01
61.01
63.88
68.89
73.16
76.87
80.15
83.08
85.74
88.16
90.38
92.43
94.35
96.14
97.81
Boiling T
AVH
A^H0
K
kJ
11.299 kJ
Molar Vol.
H298~H5
1835
6.43 kJ
2.131 J-bar'1
21 .31 cm3
4/23/92
Formula wt
BROMINE (REFERENCE STATE)
Br2 :
75
Liquid 298.15 to boiling point 332.5 K; ideal diatomic gas, P

to 2200 K.
159.808
1 bar, 332.5

Temp.
Sf
(Hf-HS98 )/T
-(Gf-H2 98 )/T
A H
Melting T
75.67
75.60
75.30
36.33
36.71
37.08
37.31
37.48
37.60
37.70
37.78
37.87
37.95
38.04
38.14
38.24
38.36
38.49
38.63
152.20
152.67
160.43
249.34
256.09
264.33
271.11
276.87
281.89
286.32
290.30
293.90
297.20
300.24
303.06
305.70
308.17
310.50
312.70
265.9 K
0.00
0.47
7.79
96.70
86.55
76.62
70.05
65.39
61.91
59.21
57.06
55.31
53.86
52.64
51.60
50.71
49.93
49.26
48.66
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJ-mol' 1
.1-1
298.15
300
332.5
332.5
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A fG
152.20
152.20
152.64
152.64
169.54
187.71
201.06
211.49
219.98
227.11
233.23
238.59
243.34
247.60
251.46
254.99
258.24
261.24
264.04
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
332.5
29.56
K
kJ
10.57 kJ
Molar Vol.
24.51 kJ
5.458 J'bar'1
54.58 cm3
4/23/92
76
Formula wt
GRAPHITE (REFERENCE STATE)
C:
12.011
Hexagonal crystals 298.15 to 2500 K.

Temp.
cp
CO
ST
<H*-H598 ,/T
-(Gf-H2 98 )/T
A fH
8.52
8.59
11.88
14.64
16.79
18.47
19.77
20.80
21.63
22.29
22.83
23.27
23.64
23.95
24.22
24.46
24.67
5.74
5.79
8.72
11.68
14.55
17.27
19.82
22.21
24.45
26.54
28.51
30.35
32.09
33.73
35.29
36.76
38.17
Melting T
0.00
0.05
2.60
4.75
6.58
8.17
9.54
10.73
11.78
12.71
13.53
14.26
14.92
15.51
16.05
16.54
16.98
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJmol~*
-1-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A fG
5.74
5.74
6.12
6.93
7.97
9.10
10.29
11.48
12.67
13.83
14.98
16.09
17.17
18.22
19.24
20.23
21.18
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
ApH
K
kJ
kJ
Molar Vol.
1.05 kJ
0.5298 J'bar'1
5.298 cm3
4/23/92
77
Formula wt
DIAMOND
C:
12.011
Cubic crystals 298.15 to 1600 K.
Temp.
CP
S$
i(HT-H2 98 )/T
T --!
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
6.14
6.21
10.24
13.60
16.12
18.02
19.48
20.65
21.63
22.52
23.36
24.20
25.08
26.04
27.08
2.38
2.42
4.76
7.43
10.14
12.77
15.28
17.64
19.87
21.98
23.97
25.87
27.70
29.46
31.18
Melting T
-(GT-H$ 98 )/T
A fH
1 -1^ 1
0.00
0.04
2.09
4.07
5.88
7.48
8.90
10.14
11.24
12.23
13.12
13.94
14.70
15.43
16.12
1. T . ,. 1
2.38
2.38
2.67
3.35
4.26
5.29
6.38
7.50
8.63
9.75
10.85
11.93
13.00
14.04
15.05
A fG
Log Kf
2.9
2.9
3.3
3.7
4.1
4.6
5.0
5.5
5.9
6.4
6.8
7.3
7.7
8.2
8.6
-0.51
-0.51
-0.43
-0.38
-0.36
-0.34
-0.33
-0.32
-0.31
-0.30
-0.30
-0.29
-0.29
-0.28
-0.28
1.9
1.9
1.7
1.6
1.5
1.4
1.4
1.3
1.3
1.4
1.4
1.5
1.6
1.8
2.0
Boiling T
A^0
K
kJ
kJ
Molar Vol.
H298"H5
0.523 kJ
A= 1.37E+00
B= 0.453E-02
0.3417 J-bar'1
3.417 cm3
C* 1.547E+04
11/18/92
78
Formula wt
CALCIUM (REFERENCE STATE)
Ca:
40.078
a-crystale (face-centered cubic) 298.15 to 716 K. 0-crystals (body-centered cubic) 716

to melting point 1115 K. Liquid 1115 to boiling point 1755 K. Ideal monatomic gas, P
* 1 bar, 1774 to 1800 K.
Temp.
CP
CO
ST
(HT-H2 98 )/T
-(Gf-H, 98 )/T
A fH
A fG
Log Kf
42.90
42.90
43.93
45.90
48.17
50.52
50.90
50.90
52.99
55.41
57.75
60.03
60.37
60.32
62.76
65.40
67.84
70.13
72.28
74.31
75.73
75.73
77.43
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
J-mol" 1 ^" 1 -
298.15
300
400
500
600
700
716
716
800
900
1000
1100
1115
1115
1200
1300
1400
1500
1600
1700
1774
1774
1800
Melting T
25.77
25.79
26.95
28.48
30.34
32.41
32.74
31.50
33.82
36.71
39.71
42.76
43.23
35.00
35.00
35.00
35.00
35.00
35.00
35.00
35.00
20.84
20.84
42.90
43.06
50.63
56.80
62.16
66.98
67.73
69.03
72.65
76.80
80.82
84.75
85.33
92.99
95.55
98.36
100.95
103.37
105.63
107.75
109.23
193.25
193.55
1115 K
0.00
0.16
6.71
10.90
13.98
16.46
16.83
18.13
19.65
21.39
23.07
24.72
24.96
32.62
32.79
32.96
33.11
33.24
33.35
33.44
33.50
117.52
116.12
Boiling T
A^0
Aft.H0
330.915 kJ
8.54 kJ
Molar Vol.
H298"H8
1774
5.707 kJ
2. 619 J'bar'1
26. 19 cm3
6/12/92
CADMIUM (REFERENCE STATE)
Cd:
79
Formula wt
Hexagonal close packed crystals 298.15 to melting point 594.18 K.

boiling point 1039 K. Ideal monatomic gas 1039 to 1800 K.
112.411
Liquid 594.18 to

Temp.
ST
(Hf-H2 98 )/T
-(GT-H$ 98 )/T
A fH
J-mol'^K" 1 -
298.15
300
400
500
594.18
594.18
600
700
800
900
1000
1039
1039
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
25.98
26.00
27.14
28.37
29.53
29.71
29.71
29.71
29.71
29.71
29.71
29.71
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
51.80
51.96
59.59
65.78
70.79
81.21
81.48
86.06
90.03
93.53
96.66
97.97
193.90
194.88
196.69
198.35
199.89
201.33
202.67
203.93
205.12
594.18
0.00
0.16
6.76
10.95
13.81
24.23
24.28
25.05
25.64
26.09
26.45
26.52
122.45
116.81
108.81
102.04
96.23
91.20
86.80
82.92
79.47
A fG
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJ-mol"" 1
51.80
51.80
52.83
54.82
56.98
56.98
57.19
61.00
64.39
67.44
70.21
71.44
71.44
78.06
87.88
96.31
103.65
110.12
115.86
121.01
125.65
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T 1039
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
K
99.667 kJ
6.19 kJ
Molar Vol.
6.25 kJ
1.3005 J-bar'1
13.005 cm3
6/10/92
80
Formula wt
CERIUM (REFERENCE STATE)
Ce:
a-crystale (face-centered cubic) 298.15 to 999 K.

K. Liquid 1071 to 1800 K.
140.115
|J-crystals 999 to melting point 1071

Temp.
ST
<Hf-H2 98 )/T
-<Gf-H2 98 )/T
A fH
J-mol"1 ^"1 -
298.15
300
400
500
600
700
800
900
999
999
1000
1071
1071
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
26.93
26.96
28.29
29.70
31.20
32.77
34.40
36.07
37.76
37.61
37.61
37.61
37.70
37.70
37.70
37.70
37.70
37.70
37.70
37.70
37.70
72.00
72.17
80.10
86.57
92.11
97.04
101.52
105.67
109.35
112.46
112.55
115.19
120.29
121.24
124.52
127.53
130.33
132.93
135.36
137.65
139.80
1071
0.00
0.17
7.03
11.42
14.59
17.07
19.14
20.93
22.34
25.45
25.52
26.32
31.41
31.58
32.09
32.53
32.89
33.21
33.49
33.74
33.96
72.00
72.00
73.07
75.14
77.52
79.96
82.38
84.74
87.01
87.01
87.03
88.88
88.88
89.66
92.43
95.00
97.44
99.72
101.87
103.91
105.84
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
K
kJ
5.46 kJ
Molar Vol.
H298"H8
Log Kf
kJ-mol"1
oA _uO
n
AftH
AfG
7.28 kJ
2. 077 J'bar1
20. 77 cm3
6/17/92
81
THERMODYN AMIC PROPERTIES AT HIGH TEMPERATURE OF INDIVIDUAL PHASES
Formula wt
CHLORINE (REFERENCE STATE)
C12 :
70.905
Ideal diatomic gas 298.15 to 2500 K.

Temp.
ST
<HT-H2 98 )/T
-(Gf-H$ 98 )/T
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
33.95
33.98
35.28
36.05
36.55
36.89
37.13
37.31
37.45
37.57
37.67
37.76
37.85
37.94
38.03
38.13
38.24
223.08
223.29
233.26
241.22
247.84
253.50
258.45
262.83
266.77
270.34
273.62
276.64
279.44
282.05
284.50
286.81
288.99
172.16
6.406
0.00
0.21
8.83
14.20
17.89
20.58
22.63
24.26
25.57
26.65
27.57
28.35
29.02
29.61
30.14
30.61
31.03
223.08
223.08
224.43
227.02
229.95
232.92
235.81
238.58
241.20
243.69
246.05
248.29
250.41
252.44
254.37
256.21
257.97
9.18
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
239.1
A^0
20.41 kJ
kJ
Molar Vol.
3ft
Log Kf
_-l
Jmol~*K~* -
A 6
A fH
kJ
2478.97 J-baT1
24789.7 cm3
6/18/92
82
Formula wt
COBALT (REFERENCE STATE)
Co:
58.933
a-crystals (hexagonal close packed) 298.15 to 700 K. p-crystals (face-centered cubic)

700 to melting point 1768 K. Liquid 1768 to 1800 K. Curie point at 1394 K.
Temp.
O
Cp
CO
Srp
/tlO_UO
% /IP
(Hfp-H^ 98 )/T
//~O tlO 98 \)/T

/T
-(GT-H2
A fH
1. T-.~ 1
298.15
300
400
500
600
700
700
800
900
1000
1100
1200
1300
1394
1400
1500
1600
1700
1768
1768
1800
Melting T
24.81
24.85
26.56
28.19
29.70
31.05
30.51
32.58
34.55
36.85
39.77
43.52
48.26
53.70
44.22
39.75
38.28
37.78
37.74
40.50
40.50
30.04
30.19
37.58
43.68
48.96
53.64
54.27
58.50
62.45
66.20
69.84
73.46
77.12
80.67
80.88
83.72
86.23
88.53
90.00
99.16
99.98
1768 K
0.00
0.15
6.54
10.71
13.75
16.13
16.78
18.63
20.28
21.82
23.31
24.83
26.45
28.15
28.24
29.12
29.73
30.21
30.50
39.66
39.68
30.04
30.04
31.04
32.97
35.21
37.51
37.49
39.88
42.17
44.38
46.53
48.63
50.67
52.52
52.64
54.61
56.50
58.32
59.50
59.50
60.30
A fG
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
K
kJ
16.19 kJ
Molar Vol.
H298~H8
4.766 kJ
0.667 Jbar"
6.67 cm3
Formula wt
CHROMIUM (REFERENCE STATE)
Cr:
83
Body-centered cubic crystals 298.15 to melting point 2130 K.
51.996
Neel temperature 311.5 K.

Temp.
cp
Sf
<Hf-H298 )/T
-<GT-H298 )/T
AfH
Melting T
23.47
23.53
23.81
25.64
26.56
27.35
28.27
29.37
30.65
32.09
33.67
35.38
37.19
39.11
41.11
43.19
45.35
47.57
23.62
23.77
24.66
30.88
36.71
41.62
45.90
49.75
53.28
56.58
59.71
62.71
65.62
68.44
71.21
73.93
76.61
79.27
2130
0.00
0.14
0.98
6.31
10.27
13.05
15.16
16.86
18.32
19.63
20.83
21.97
23.07
24.15
25.21
26.27
27.33
28.39
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJmol"^
~1 V~l
J .mnl
IDOJ.
*JX
298.15
300
311.50
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
AG
23.62
23.62
23.64
24.58
26.44
28.57
30.75
32.89
34.96
36.96
38.88
40.75
42.55
44.30
46.00
47.66
49.28
50.88
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
A^H
2945
344.31
K
kJ
16.933 kJ
Molar Vol.
4.058 kJ
0.7231 J'bar'1
7.231 cm3
5/26/93
84
Formula wt
CESIUM (REFERENCE STATE)
- - ->-
" ssrssr
i
132.905
Temp.
Sf
(T-H298)/T
-<Gf-H2 98 )/T
AfH
AfG
V.T . m<*\
Log Kf
i-l ___
*** -*UWA
. _
298.15
300
301.55
301.55
400
500
600
700
800
900
947.96
947.96
1000
1100
1200
1300
1400
1500
1600
1700
1800
.____
Melting T
32.19
32.35
32.50
32.39
31.51
31.15
30.99
30.94
30.93
30.95
30.97
20.78
20.78
20.78
20.79
20.79
20.81
20.84
20.88
20.95
21.04
85.23
85.43
85.60
92.52
101.54
108.53
114.20
118.97
123.10
126.75
128.36
199.73
200.84
202.82
204.63
206.29
207.84
209.27
210.62
211.89
213.09
-^^_____
301.55 K
i -
-______________________ ..
0.00
0.16
0.33
7.25
13.34
16.94
19.29
20.96
22.21
23.18
23.57
94.95
91.09
84.70
79.37
74.86
71.00
67.66
64.73
62.16
59.87
85.23
85.27
85.27
85.27
88.20
91.59
94.90
98.01
100.89
103.57
104.78
104.78
109.75
118.12
125.26
131.43
136.83
141.61
145.88
149.73
153.22
_
____^^ *_^
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
^ ^__^__
Boiling T
.__
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
____
942
67.71
K
kJ
2.09 kJ
Molar Vol.
H298~H8
7.71 kJ
6.973 J'bar'1
69.73 cm3
6/11/92
Formula wt
COPPER (REFERENCE STATE)
Cu:
85
63.546
Face-centered cubic crystals 298.15 to melting point 1357.8 K. Liquid 1357.8 to

1800 K.

Temp.
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1357.8
1357.8
1400
1500
1600
1700
1800
Melting T
O
ST
CP
24.43
24.45
25.34
25.99
26.48
26.92
27.40
27.97
28.69
29.57
30.65
31.93
32.77
32.80
32.80
32.80
32.80
32.80
32.80
33.14
33.29
40.45
46.18
50.96
55.08
58.70
61.96
64.94
67.72
70.34
72.84
74.25
83.94
84.95
87.21
89.32
91.32
93.19
1357.8 K
/UO_ttQ
\ /ip
(HT-HJJgg)/T
/*"*<> Hfi
\ Irn
-(GT-H2g3)/T
AfH
AfG
Log Kf
0.00
0.15
6.34
10.21
12.88
14.85
16.39
17.65
18.71
19.66
20.53
21.35
21.82
31.51
31.55
31.63
31.70
31.77
31.82
33.14
33.14
34.11
35.97
38.08
40.22
42.31
44.31
46.23
48.06
49.81
51.48
52.43
52.43
53.40
55.58
57.62
59.55
61.37
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
K
kJ
13.14 kJ
Molar Vol
ift
5.00 kJ
0.7113 J* bar1
7.113 cm3
5/28/93
86
Formula wt
FLUORINE (REFERENCE STATE)
F2 :
37.997
Ideal diatomic gas at P 1 bar 298.15 to 2500 K.
Temp.
CP
ST
i(HT-H 9g)/T
-(GT-H2 98 )/T
AfH
r.^.^.1 *~1 .tr*"!
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
31.31
31.35
33.14
34.28
35.11
35.75
36.27
36.70
37.07
37.38
37.66
37.89
38.10
38.28
38.44
38.57
38.69
202.79
202.98
212.27
219.80
226.12
231.59
236.40
240.69
244.58
248.13
251.39
254.42
257.23
259.87
262.34
264.68
266.89
53.48 K
0.00
0.19
8.23
13.33
16.89
19.54
21.60
23.26
24.62
25.77
26.75
27.60
28.34
29.00
29.58
30.11
30.58
A fG
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
i. T --. .1 "!
202.79
202.79
204.04
206.47
209.23
212.04
214.79
217.43
219.96
222.36
224.64
226.82
228.89
230.87
232.76
234.57
236.31
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
84.95
6.54
K
kJ
0.51 kJ
Molar Vol.
8.82 kJ
2478.97 J-bar'1
24789.7 cm3
6/03/93
87
IRON (REFERENCE STATE)
Fe:
Formula wt
55.847
Body-centered cubic crystals 298.15 to 1185 K. Curie point 1043 K; face-centered cubic
crystals 1185 to 1667 K; body-centered cubic crystals 1667 to melting point 1809 K.
Temp.
CP
S*
(HT-H^ 98 )/T
-(6T-H^ 98 )/T
A fH
AfG
Log Kf
27.09
27.24
34.80
41.15
46.76
51.89
56.72
61.46
66.50
69.14
71.91
75.01
75.77
76.19
78.94
81.56
84.06
86.45
88.01
88.52
89.32
91.78
0.00
0.16
6.69
11.06
14.35
17.06
19.45
21.76
24.39
25.97
27.31
28.33
29.10
29.16
29.56
29.97
30.38
30.81
31.09
31.60
31.78
32.41
27.08
27.08
28.10
30.09
32.41
34.83
37.27
39.70
42.11
43.18
44.60
46.67
46.67
47.04
49.38
51.59
53.67
55.65
56.92
56.92
57.54
59.37
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
K
298.15
300
400
500
600
700
800
900
1000
1043
1100
1185
1185
1200
1300
1400
1500
1600
1667
1667
1700
1800
Melting T
25.08
25.13
27.43
29.64
32.01
34.62
37.92
43.16
54.46
83.77
44.35
40.00
33.78
33.90
34.81
35.75
36.69
37.63
38.26
40.40
41.45
44.65
1809 K
Boiling T
Av^H 0
AfiH
13 .81 kJ
Molar Vol.
HS98"H6
4.51 kJ
kJ
0.7092 J'bar*1
7.092 cm3
4/29/92
88
Formula wt
GERMANIUM (REFERENCE STATE)
Ge:
72.61
Liquid 1211.4 to
Face-centered cubic crystals (diamond structure) 298.15 to 1211.4 K.

boiling point 3107 K.
Temp.
298.15
300
400
500
600
700
800
900
1000
1100
1200
1211.4
1211.4
1300
1400
1500
1600
1700
1800
Melting T
CP
23.22
23.25
24.31
24.96
25.45
25.87
26.24
26.59
26.93
27.25
27.57
27.61
27.60
27.60
27.60
27.60
27.60
27.60
27.60
S mo
\ /n
(/uo__uo
**m *298''
/ r* o _ uo
\ /*P
l**T
**298''
A fH
A fG
Log Kf
31.09
31.23
38.08
43.58
48.18
52.13
55.61
58.72
61.54
64.12
66.51
66.77
97.34
99.29
101.33
103.24
105.02
106.69
108.27
0.00
0.14
6.06
9.78
12.36
14.26
15.73
16.92
17.90
18.74
19.46
19.54
50.11
48.57
47.07
45.78
44.64
43.64
42.75
31.09
31.09
32.02
33.80
35.82
37.88
39.88
41.80
43.64
45.39
47.05
47.23
47.23
50.72
54.26
57.46
60.38
63.05
65.52
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1211.4 K
Boiling T
3107
330.92
K
kJ
37.03 kJ
Molar Vol.
4.64 kJ
1.363 J-bar'1
13.63 cm3
6/12/92
89
2.016
Formula wt
HYDROGEN (REFERENCE STATE)
Ideal diatomic gas at P - 1 bar 298.15 to 2500 K.

Temp.
CP
ST
<Hf-H2 98 )/T
_!
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
17
1800
Melting T
28.82
28.84
29.24
29.25
29.29
29.41
29.62
29.90
30.24
30.61
31.01
31.43
31.86
32.29
32.71
33.12
33.53
130.68
130.86
139.23
145.76
151.09
155.61
159.55
163.06
166.23
169.13
171.81
174.31
176.65
178.86
180.96
182.96
184.86
13.80 K
0.00
0.18
7.41
11.78
14.69
16.78
18.38
19.64
20.68
21.57
22.34
23.02
23.64
24.20
24.72
25.20
25.65
-<Gf-H2 98 )/T
A fH
_!
A fG
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJ'mol" 1
130.68
130.68
131.82
133.98
136.40
138.83
141.18
143.42
145.54
147.56
149.47
151.28
153.01
154.66
156.24
157.75
159.21
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
20.27
0.904 kJ
0.117 kJ
Molar Vol.
8.468 kJ
2478.97
24789.7
J'bar'1
cm3
4/29/92
90
Formula wt
MERCURY (REFERENCE STATE)
Hg:
Liquid 298.15 to boiling point 629.0 K.
200.59
Ideal monatonic gas at P * 1 bar, 629.0 K,
Temp.
CP
**
<H*-H3 98 )/T
-1
298.15
300
400
500
600
629.0
629.0
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
27.96
27.95
27.41
27.17
27.14
27.17
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
75.90
76.07
84.03
90.12
95.07
96.35
190.49
192.71
195.48
197.93
200.12
202.10
203.91
205.58
207.12
208.55
209.89
211.15
212.34
234.32 K
0.00
0.17
7.04
11.09
13.76
14.38
108.52
99.62
89.77
82.10
75.97
70.96
66.78
63.24
60.21
57.58
55.28
53.25
51.45
-<Gf-H2 98 )/T
A fH
A fG
Log K
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJ-mol~l
_1
75.90
75.90
76.99
79.03
81.31
81.97
81.97
93.09
105.71
115.83
124.15
131.14
137.14
142.34
146.91
150.97
154.61
157.90
160.89
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
629.0
59.214 kJ
2.297 kJ
Molar Vol.
9.343 kJ
1.4822 J-bar'1
14.822 cm3
01/07/93
Formula wt
IODINE (REFERENCE STATE)
I2 :
91
253.809
Crystals 298.15 to melting point 386.8 K; liquid 386.8 to boiling point 457.7 K; ideal
diatomic gas, P-l bar, 457.7 to 2200 K.
Temp.
298.15
300
386.8
386.8
400
457.7
457.7
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
CP
54.44
54.51
63.54
80.67
80.67
80.67
37.39
37.48
37.53
37.55
37.62
37.76
37.96
38.23
38.56
38.93
39.34
39.79
40.27
40.78
41.31
ST
116.14
116.48
131.22
171.34
174.06
184.93
276.61
279.93
286.77
292.56
297.58
302.01
306.00
309.63
312.97
316.07
318.97
321.70
324.29
326.74
329.09
386. 8 K
(HT-H 98 )/T
0.00
0.34
13.32
53.44
54.35
57.67
149.35
139.88
122.82
110.63
101.50
94.41
88.75
84.15
80.34
77.14
74.42
72.10
70.09
68.35
66.84
-(GT-H2 98 )/T
A fH
A fG
Log Kf
116.14
116.14
117.90
117.90
119.71
127.26
127.26
140.06
163.96
181.93
196.08
207.61
217.25
225.48
232.64
238.94
244.55
249.61
254.19
258.39
262.25
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
A^0
Afa.H 0
41.96
K
kJ
15.52 kJ
Molar Vol.
^298~"^0
457. 7
13.20 kJ
5. 129 J'bar'1
51. 29 cm3
4/29/92
92
Formula wt
POTASSIUM (REFERENCE STATE)
K:
39.098
Crystals 298.15 to melting point 336.4 K; liquid 336.4 to boiling point 1039.5 K; ideal
monatomic gas, P=l bar, 1039.5 to 1800 K.

Temp.
ST
CP
<Hf-H2 98 )/T
""(Gm HgQ ) /T
AfH
, ,....,
298.15
300
336.4
336.4
400
500
600
700
800
900
1000
1039.5
1039.5
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
Aft.H 0
29.50
29.57
34.57
32.14
31.50
30.70
30.14
29.82
29.76
29.94
30.36
30.60
20.79
20.79
20.79
20.79
20.79
20.80
20.81
20.84
20.87
64.67
64.85
68.37
75.31
80.82
87.76
93.31
97.92
101.90
105.41
108.59
109.77
186.30
187.48
189.28
190.95
192.49
193.92
195.27
196.53
197.72
336 .4 K
0.00
0.18
3.49
10.43
13.83
17.28
19.47
20.97
22.07
22.93
23.65
23.91
100.44
96.07
89.78
84.48
79.93
75.99
72.54
69.50
66.80
64.67
64.67
64.88
64.88
66.99
70.48
73.84
76.95
79.83
82.48
84.94
85.86
85.86
91.41
99.50
106.47
112.56
117.93
122.73
127.03
130.92
l- -r -
AfG
Log K
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
- 1 ~1
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
1039. 5
A,^H 0
79.92
kJ
2.33 kJ
Molar Vol.
H2*98~H6
7. 09 kJ
4. 536 J-bar'1
45. 36 cm3
4/29/92
Formula wt
LITHIUM (REFERENCE STATE)
Li:
93
6.941
Crystals 298.15 to melting point 453.2 K; liquid 453.7 K to boiling point 1620 K; ideal
monatomic gas, P*l bar, 1620 to 1800 K.
Temp.
e
ST
(HT-H$98 )/T
.T.m/il
298.15
300
400
453.7
453.7
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1620
1620
1700
1800
Melting T
24.62
24.67
27.61
29.39
30.39
30.13
29.54
28.99
28.94
28.89
28.84
28.79
28.74
28.70
28.62
28.54
28.45
28.43
20.79
20.80
20.81
29.09
29.24
36.70
40.29
46.90
49.84
55.28
59.79
63.66
67.07
70.11
72.85
75.36
77.66
79.78
81.75
83.59
83.95
173.97
174.97
176.16
453.2 K
-(Gf-H2 98 )/T
AfH
l.lf 1
0.00
0.15
6.62
9.21
15.82
17.16
19.27
20.70
21.73
22.53
23.16
23.67
24.10
24.45
24.75
25.01
25.23
25.27
115.30
110.85
105.85
1. T.
29.09
29.08
30.08
31.08
31.08
32.69
36.01
39.10
41.93
44.54
46.95
49.18
51.26
53.20
55.02
56.74
58.36
58.68
58.67
64.12
70.31
^l
AfG
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
1620
145.84
K
kJ
3.00 kJ
Molar Vol.
H298"H8
4.62 kJ
1.3017 J-bar'1
13.017 cm3
4/29/92
94
Formula wt
MAGNESIUM (REFERENCE STATE)
Mg:
24.305
Hexagonal close-packed crystals 298.15 to melting point 923 K. Liquid 923 to boiling
point 1366.1 K. Ideal monotomic gas, P 1 bar, 1366.1 to 1800 K.
Temp.
CO
ST
/UO MUO
\ /rn
\ Aim **O Q Q j f X
-(GT-H2 98 )/T
A fH
A fG
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1""
298.15
300
400
500
600
700
800
900
923
923
1000
1100
1200
1300
1366.1
1366.1
1400
1500
1600
1700
1800
Melting T
24.87
24.90
26.14
27.18
28.20
29.29
30.51
31.90
32.24
34.31
34.31
34.31
34.91
34.31
34.31
20.79
20.79
20.79
20.79
20.79
20.79
32.67
32.82
40.17
46.11
51.16
55.58
59.57
63.25
64.05
73.23
75.98
79.25
82.24
84.98
86.69
180.29
180.80
182.23
183.57
184.83
186.02
923 K
0.00
0.15
6.50
10.54
13.39
15.59
17.37
18.91
19.23
28.42
28.87
29.36
29.78
30.12
30.33
123.93
121.43
114.72
108.85
103.67
99.07
32.67
32.67
33.66
35.58
37.76
40.00
42.20
44.34
44.82
44.82
47.11
49.89
52.46
54.86
56.36
56.36
59.34
67.49
74.72
81.16
86.95
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
1361.1
127.87
K
kJ
8.477 kJ
Molar Vol
H298~H8
5.00 kJ
1.3996 J'bar'1
13.996 cm3
4/29/92
Formula wt
MANGANESE (REFERENCE STATE)
Mn:
95
54.938
a-crystals 298.15 to 980 K. ^-crystals 980 to 1360 K. y-crystals 1360 to 1410 K. Acrystals 1410 to melting point 1517 K. Liquid 1517 to boiling point 2335 K.

Temp.
cp
S*
(Hf-H2 98 )/T
-(Gf-H2 98 )/T
A fH
J-mol'^K' 1 -
298.15
300
400
500
600
700
800
900
980
980
1000
1100
1200
1300
1360
1360
1400
1410
1410
1500
1517
1517
1600
1700
1800
Melting T
26.19
26.23
28.30
30.16
31.89
33.49
34.93
36.18
37.04
37.59
37.68
38.11
38.54
38.97
39.15
42.41
43.43
43.51
45.23
45.97
46.11
46.02
46.02
46.02
46.02
32.01
32.17
40.01
46.53
52.18
57.22
61.79
65.98
69.05
71.40
72.12
75.73
79.07
82.17
84.01
84.97
86.75
87.07
88.41
91.21
91.86
99.81
102 . 13
104.92
107.55
1517 K
0.00
0.16
6.95
11.40
14.68
17.25
19.37
21.17
22.35
24.70
24.96
26.14
27.15
28.04
28.52
29.48
30.47
30.56
31.89
32.72
32.87
40.81
41.08
41.38
41.63
A fG
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJ-mol" 1
32.01
32.01
33.07
35.13
37.50
39.97
42.42
44.81
46.70
46.70
47.16
49.59
51.92
54.13
55.49
55.49
56.28
56.51
56.52
58.49
59.00
59.00
61.05
63.55
65.92
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
2335
K
kJ
Afo.H 0
12.06 kJ
Molar Vol.
^29'B~"^8
4.996 kJ
0.7354 J-bar'1
7.354 cm3
1/31/92
96
Formula wt
MOLYBDENUM (REFERENCE STATE)
Mo:
95.94
Body-centered cubic crystals 298.15 to 2500 K.

Temp.
CP
ST
Melting T
A^H'
-<G*-HJ 98 ,/T
A fH
A fG
Log Kf
28.66
28.66
29.61
31.45
33.54
35.66
37.74
39.74
41.65
43.47
45.20
46.86
48.45
49.97
51.44
52.85
54.21
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
J-mol" 1 -^1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
<Hf-H2 98 )/T
23.90
23.92
25.05
25.86
26.47
26.99
27.46
27.92
28.40
28.92
29.49
30.11
30.80
31.56
32.40
33.31
34.30
28.66
28.81
35.86
41.54
46.31
50.43
54.06
57.32
60.29
63.02
65.56
67.95
70.20
72.35
74.42
76.41
78.34
2890 K
0.00
0.15
6.24
10.09
12.77
14.76
16.32
17.58
18.64
19.55
20.36
21.08
21.75
22.38
22.98
23.56
24.13
0.0
0.0
0.0
Boiling T
4912
AV*H
598.07
32. 54 kJ
Molar Vol.
H598~H8
4 .594 kJ
K
kJ
0.9387 J bar'1
9.387 cm3
4/29/92
Formula wt
NITROGEN (REFERENCE STATE)
N2 :
97
28.013
Ideal diatomic gas at P = 1 bar 298.15 to 2500 K.

Temp.
cp
ST
(HT-H2 98 )/T
-<Gf-H2 98 )/T
A fH
Melting T
29.13
29.13
29.24
29.70
30.26
30.86
31.45
32.03
32.58
33.10
33.58
34.03
34.45
34.82
35.16
35.45
35.71
191.61
191.79
200.17
206.74
212.21
216.91
221.07
224.81
228.22
231.35
234.25
236.95
239.49
241.88
244.14
246.28
248.31
63.14 K
0.00
0.18
7.42
11.83
14.85
17.09
18.85
20.29
21.49
22.52
23.42
24.22
24.94
25.58
26.17
26.71
27.20
Log K
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
-1
Jmol"~*K""* -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
AfG
191.61
191.61
192.75
194.92
197.35
199.82
202.22
204.53
206.73
208.83
210.83
212.73
214.55
216.30
217.97
219.57
221.11
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
0.0
0.0
0.0
0.0
77.35
5.586 kJ
0.720 kJ
H98"H8
8.669 kJ
Molar Vol. 2478.97

24789.7
Jbar'1
cm3
6/19/92
98
Formula wt
SODIUM (REFERENCE STATE)
Na:
22.990
Body-centered cubic crystals 298.15 to melting point 371 K; liquid 371 to fictive
boiling point 1170.5 K. Ideal monotomic gas, P=l bar, 1170.5 to 1800 K.
Temp.
CP
CO
ST
(Hf-H298 )/T
-(Gf-H2 98 )/T
A fH
A fG
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJ-mol" 1
298.15
300
371
371
400
500
600
700
800
900
1000
1100
1170.5
1170.5
1200
1300
1400
1500
1600
1700
1800
Melting T
AftH
28.15
28.20
31.83
31.83
31.51
30.55
29.81
29.27
28.94
28.84
28.94
29.26
29.61
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
51.46
51.63
57.90
64.92
67.30
74.22
79.73
84.28
88.16
91.56
94.61
97.38
99.21
182.09
182.61
184.28
185.82
187.25
188.59
189.85
191.04
371 K
0.00
0.17
5.80
12.82
14.18
17.54
19.66
21.06
22.06
22.82
23.43
23.94
24.28
107.16
105.04
98.56
93.01
88.19
83.97
80.26
76.96
51.46
51.46
52.10
52.10
53.12
56.68
60.07
63.22
66.10
68.74
71.18
73.44
74.93
74.93
77.57
85.72
92.81
99.06
104.62
109.59
114.08
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
1170.5
A^0
97.610 kJ
2. 598 kJ
Molar Vol.
H298-H6
6.460 kJ
2.381 Jbar~l
23.81 cm3
4/29/92
Formula wt
NICKEL (REFERENCE STATE)
Ni:
99
58.69
Face-centered cubic crystals (magnetic) to Curie point 631 K; nonmagnetic 631 to

melting point 1728 K; liquid 1728 to 1800 K.
Temp.
cp
ST
(HT-H2 98 )/T
-(Gf-H2 98 )/T
A fH
Melting T
25.99
26.05
28.38
30.82
34.85
39.83
30.79
31.00
31.59
32.22
32.93
33.68
34.52
35.40
36.32
37.28
38.28
38.54
38.91
38.91
29.87
30.03
37.87
44.45
50.39
52.26
55.58
59.10
63.38
66.74
69.85
72.74
75.47
78.06
80.53
82.91
85.20
85.83
95.75
97.34
1728 K
0.00
0.16
6.95
11.46
15.00
16.08
17.63
19.29
20.62
21.75
22.73
23.61
24.42
25.17
25.88
26.57
27.23
27.41
37.34
37.40
29.87
29.87
30.92
32.99
35.40
36.19
37.94
39.81
42.76
44.99
47.11
49.13
51.05
52.89
54.65
56.34
57.97
58.42
58.42
59.94
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
K
kJ
17 .16 kJ
Molar Vol
H298-H5
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
AV*H
AjJH0
Log Kf
J-mol"1 ^' 1 -
298.15
300
400
500
600
631
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1728
1728
1800
AfG
4.79 kJ
0. 6588 J-bar'
6. 588 cm3
4/29/92
100
Formula wt
OXYGEN (REFERENCE STATE)
31.999
Ideal diatomic gas at P 1 bar 298.15 to 2500 K.

Temp.
CP
ST
(Hf-H2 98 )/T
_
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
29.35
29.35
30.04
31.12
32.14
33.00
33.72
34.33
34.85
35.29
35.67
36.00
36.31
36.58
36.84
37.08
37.32
205.15
205.33
213.85
220.67
226.43
231.45
235.91
239.92
243.56
246.90
249.99
252.86
255.54
258.05
260.42
262.66
264.79
54.35 K
-<Gf-H2 98 )/T
A fH
,-!_-!
0.00
0.18
7.54
12.15
15.40
17.85
19.79
21.37
22.70
23.82
24.79
25.64
26.39
27.06
27.67
28.21
28.71
205.15
205.15
206.31
208.52
211.04
213.60
216.12
218.54
220.86
223.08
225.20
227.22
229.14
230.99
232.75
234.45
236.08
A fG
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1-1
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
90.18
6.816 kJ
0.444 kJ
Molar Vol.
H298~H8
8.682 kJ
2478.97 J-bar'1
24789.7 cm3
4/29/92
Formula wt
PHOSPHORUS (REFERENCE STATE)
P:
101
Crystals (white, a) 298.15 to melting point 317.3 K,

1180 K. Ideal diatomic gas 1180 to 1800 K.
30.974
Liquid 317.3 to sublimation point
Temp.
CP
-(GT-H| 98 )/T
A fH
500
600
700
800
900
1000
1100
1180
1180
1200
1300
1400
1500
1600
1700
1800
Melting T
23.82
23.87
24.35
26.32
26.32
26.32
26.32
26.32
26.32
26.32
26.32
26.32
26.32
18.54
18.55
18.60
18.64
18.68
18.72
18.75
18.77
41.09
41.22
42.57
44.65
50.75
56.62
61.42
65.48
68.99
72.09
74.87
77.38
79.22
133.23
133.54
135.03
136.41
137.70
138.91
140.04
141.11
317.3 K
0.00
0.14
1.45
3.53
8.24
11.86
14.27
15.99
17.28
18.29
19.09
19.75
20.19
74.20
73.27
69.07
65.46
62.34
59.62
57.21
55.08
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJ-mol' 1
T-_-.1 ~l-r l
298.15
300
317.3
317.3
400
A fG
41.08
41.08
41.12
41.12
42.51
44.76
47.15
49.49
51.71
53.80
55.78
57.63
59.03
59.03
60.27
65.96
70.95
75.36
79.29
82.83
86.03
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
0.0
0.0
0.0
0.0
0.0
1180
63.84 kJ
0.659 kJ
Molar Vol.
5.36 kJ
1.73 Jbar
17.3 cm3
6/18/92
102
Formula wt
LEAD (REFERENCE STATE)
Pb:
Face-centered cubic crystals 298.15 to melting point 600.6 K.

point 2021 K.
207.2
Liquid 600.6 to boiling

Temp.
CP
-(GT-H2 98 )/T
A fH
J-mol"1 ^'1
298.15
300
400
500
600
600.6
600.6
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
(HT-H^9g)/T
26.65
26.67
27.79
28.78
29.74
29.74
30.63
30.31
29.98
29.66
29.37
29.17
28.90
28.73
28.60
28.51
28.46
28.45
28.48
64.80
64.96
72.80
79.10
84.44
84.47
92.48
97.15
101.17
104.68
107.79
110.58
113.10
115.41
117.54
119.50
121.34
123.07
124.70
Melting T
600.65 K
AtoH
4.81 kJ
0.00
0.16
6.94
11.21
14.22
14.23
22.24
23.41
24.25
24.87
25.34
25.69
25.97
26.19
26.36
26.51
26.63
26.74
26.84
6.870 kJ
Log Kf
kJ-mol"1 -
64.80
64.80
65.86
67.89
70.22
70.24
70.24
73.74
76.92
79.81
82.45
84.89
87.13
89.22
91.18
92.99
94.71
96.33
97.86
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
2021
A^H0
177.7
Molar Vol.
HS98-H6
A fG
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJ
1.8267 J'bar'1
18.267 cm3
6/17/92
103
Formula wt
PLATINUM (REFERENCE STATE)
Ft:
195.08
Face-centered cubic crystals 298.15 to melting point 2042 K.
Temp.
CP
Sf
K
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
<Hf-H2 98 )/T
*
25.81
25.83
26.49
27.02
27.53
28.04
28.56
29.08
29.61
30.15
30.69
31.22
31.76
32.29
32.82
33.34
33.86
41.63
41.79
49.32
55.29
60.26
64.54
68.32
71.71
74.80
77.65
80.30
82.78
85.11
87.32
89.42
91.42
93.34
2042 K
UIW4.
0.00
0.16
6.67
10.68
13.45
15.50
17.10
18.40
19.49
20.44
21.27
22.02
22.69
23.31
23.89
24.43
24.94
(GT-H2 98 )/T
AfH
AfG
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJ-mol' 1
*V
41.63
41.63
42.65
44.60
46.81
49.04
51.22
53.31
55.31
57.21
59.03
60.76
62.42
64.00
65.53
66.99
68.40
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
A^H
AftH0
kJ
19. 648 kJ
Molar Vol.
H298~H8
5.724 kJ
0 .9091 J-bar'1
9 .091 cm3
01/07/93
104
Formula wt
SULFUR (REFERENCE STATE)
S:
32.066
Orthorhombic crystals 298.15 to 368.3 K; monoclinic crystals 368.3 to melting point

388.36 K? liquid 388.36 K to fictive boiling point 882.1 K. Ideal diatomic gas, P-l
bar, 882.1 to 1800 K.
Temp.
CP
ST
<HT-H2 98 )/T
-(Gf-H298 )/T
AfH
A6
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJ'mol"1
298.15
300
368.3
368.3
388.36
388.36
400
500
600
700
800
882.1
882.1
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
22.70
22.74
24.24
24.77
25.17
31.06
32.16
37.98
34.31
32.68
31.70
31.66
18.47
18.51
18.68
18.85
19.00
19.15
19.28
19.42
19.55
19.67
19.79
32.05
32.19
37.01
38.10
39.43
43.86
44.79
53.53
60.08
65.24
69.53
72.62
133.08
133.45
135.41
137.20
138.85
140.37
141.80
143.13
144.39
145.58
146.71
388.36 K
0.00
0.14
4.47
5.56
6.57
11.00
11.60
17.13
20.25
22.14
23.39
24.16
84.61
83.29
76.82
71.55
67.16
63.46
60.30
57.57
55.19
53.10
51.24
32.05
32.05
32.54
32.54
32.86
32.86
33.19
36.40
39.82
43.10
46.14
48.47
48.47
50.16
58.59
65.65
71.69
76.91
81.50
85.56
89.20
92.48
95.46
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
0.0
882.1
53.32
K
kJ
1.72 kJ
Molar Vol.
H298"H8
4.412 kJ
1.5511 Jbar'1
15.511 cm3
6/18/92
105
S2 (gas)
S2 :
Formula wt
64.132
Ideal diatomic gas, P = 1 bar, 298.15 to 2500 K.

Temp.
CP
ST
(HT-H2 98 )/T
-(GT-H2 98 )/T
A fH
1~1. K' 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
32.49
32.53
34.05
34.98
35.65
36.17
36.62
37.01
37.37
37.69
38.00
38.29
38.57
38.84
39.09
39.34
39.59
228.17
228.37
237.96
245.66
252.10
257.64
262.50
266.84
270.75
274.33
277.62
280.68
283.53
286.20
288.71
291.09
293.34
0.00
0.20
8.49
13.70
17.31
19.97
22.02
23.66
25.02
26.16
27.13
27.98
28.72
29.39
29.99
30.53
31.03
AfG
Log K
79.7
79.4
-13.96
-13.82
-8.27
-5.12
-3.09
-1.68
-0.66
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJ-mol' 1
228.17
228.17
229.47
231.96
234.80
237.67
240.48
243.17
245.74
248.18
250.49
252.70
254.80
256.81
258.72
260.56
262.32
128.6
128.6
122.7
118.3
114.7
111.6
108.8
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
63.4
49.0
35.5
22.6
10.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
Av*H
Aft.H
kJ
Molar Vol .
HJ98-H8
9. 124 kJ
kJ
2478. 97 J'bar'1
24789. 7 cm3
11/18/92
106
Formula wt
ANTIMONY (REFERENCE STATE)
Sb:
121.75
Liquid 904 to 1800 K.

Temp.
CP
CO
ST
<HT-H2 98 )/T
-<GT-H298 >/T
A H
Melting T
25.25
25.27
25.91
26.48
27.17
28.09
29.32
30.92
30.99
31.38
31.38
31.38
31.38
31.38
31.38
31.38
31.38
31.38
31.38
45.52
45.69
53.04
58.88
63.77
68.02
71.85
75.39
75.54
97.53
100.68
103.67
106.40
108.91
111.24
113.40
115.41
117.33
119.12
904
0.00
0.16
6.52
10.45
13.18
15.24
16.92
18.38
18.41
40.42
39.55
38.81
38.19
37.66
37.22
36.83
36.49
36.18
35.92
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJ-mol"" 1
J-mol"1 ^"1
298.15
300
400
500
600
700
800
900
904
904
1000
1100
1200
1300
1400
1500
1600
1700
1800
A fG
45.52
45.52
46.52
48.43
50.59
52.78
54.93
57.01
57.11
57.11
61.12
64.86
68.21
71.24
74.02
76.57
78.94
81.14
83.20
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
1860
86.525
K
kJ
19.874 kJ
Molar Vol.
5.870 kJ
1.8178 J-bar*1
18.178 cm
6/10/92
THERMODYNAMC PROPERTIES AT HIGH TEMPERATURE OF INDIVIDUAL PHASES
107
Formula wt
SELENIUM (REFERENCE STATE)
Se: Crystals 298.15 to melting point 494 K.

diatomic gas 957 to 1800 K.
Liquid 494 to boiling point 957 K.
78.96
Ideal

Temp.
CP
Sf
(Hf-H 98 )/T
-<Gf-H2 98 )/T
A H
Melting T
25.06
25.06
26.44
27.30
35.95
35.85
34.37
33.54
33.29
33.93
34.78
19.27
19.31
19.41
19.52
19.62
19.73
19.83
19.94
20.04
20.15
42.27
42.42
49.83
55.51
67.97
68.38
74.79
80.03
84.48
88.43
90.50
146.44
147.29
149.13
150.82
162.39
153.84
155.21
156.49
157.70
158.85
494 K
0.00
0.15
6.56
10.45
22.91
23.06
25.07
26.34
27.21
27.92
28.30
84.28
81.48
75.83
71.14
67.17
63.78
60.84
58.28
56.03
54.03
Log Kf
kJ-mol' 1
T . _^1 ~1 - r~l
298.15
300
400
494
494
500
600
700
800
900
957
957
1000
1100
1200
1300
1400
1500
1600
1700
1800
A 6
42.27
42.27
43.27
45.06
45.06
45.32
49.72
53.69
57.27
60.51
62.19
62.19
65.81
73.30
79.68
85.22
90.06
94.37
98.21
101.67
104.82
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
957
53.57
K
kJ
6.16 kJ
Molar Vol.
H298~H5
5.52 kJ
1.642 J-bar'1
16.42 cm3
12/14/92
108
Formula wt
SILICON (REFERENCE STATE)
28.086
Si: Cubic crystals 298.15 to melting point 1685 K; liquid 1685 to 1800 K.
Temp.
CO
ST
CP
Melting T
-(G|-H2 98 )/T
A fH
1- <r -
J-mol'^K" 1 -
K
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1685
1685
1700
1800
20.00
20.06
22.14
23.33
24.16
24.81
25.36
25.86
26.33
26.78
27.21
27.63
28.05
28.47
28.88
29.22
27.20
27.20
27.20
18.81
18.93
25.02
30.10
34.43
38.21
41.56
44.57
47.32
49.85
52.20
54.40
56.46
58.41
60.26
61.75
91.55
91.79
93.35
1685 K
0.00
0.12
5.40
8.87
11.36
13.23
14.71
15.93
16.94
17.82
18.58
19.26
19.87
20.43
20.95
21.35
51.15
50.94
49.62
18.81
18.81
19.63
21.23
23.08
24.97
26.84
28.65
30.38
32.04
33.62
35.13
36.58
37.98
39.31
40.40
40.40
40.85
43.73
A fG
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
.1 ~1
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
A H
AtoH0
kJ
50.2 kJ
Molar Vol.
H598-H8
3.218 kJ
1.2056 J'bar*1
12.056 cm3
6/19/92
109
Formula wt
TIN (REFERENCE STATE)
Sn:
Crystals 298.15 to melting point 505.1 K.
118.710

Temp.
ST
fo
1ft
(HT-H2 98 )/T
-i(Gf-H298 )/T
A H
Melting T
27.11
27.15
28.90
31.03
31.16
29.42
28.66
28.25
28.04
27.96
27.95
27.98
28.04
28.13
28.23
28.34
28.46
28.58
28.70
51.18
51.35
59.40
66.06
66.38
80.63
85.62
90.00
93.76
97.06
100.00
102.67
105.10
107.35
109.44
111.39
113.22
114.95
116.59
505.1
0.00
0.17
7.13
11.69
11.88
26.13
26.58
26.85
27.01
27.12
27.20
27.27
27.33
27.39
27.44
27.50
27.56
27.61
27.67
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJmol""*
J-mol'^K' 1 -
298.15
300
400
500
505.1
505.1
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A fG
51.18
51.18
52.27
54.37
54.50
54.50
59.04
63.15
66.75
69.94
72.80
75.40
77.77
79.96
82.00
83.89
85.66
87.34
88.92
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
2876
295.77
Afi,H
7.195 kJ
Molar Vol.
H2*98~H5
6.323 kJ
K
kJ
1. 629 J-bar'1
16. 29 cm3
6/17/92
110
Formula wt
STRONTIUM (REFERENCE STATE)
87.62
Sr: a-crystals (face-centered cubic) 298.15 to 820 K; y-crystals (body-centere cubic) 820 to
melting point 1050 K; liquid 1050 to boiling point 1685.5 K; ideal monatomic gas, P-l
bar, 1685.5 to 1800 K.
Temp.
<p
00
ST
Melting T
-(Gf-H2 98 )/T
A fH
J-mol" 1 ^" 1
K
298.15
300
400
500
600
700
800
820
820
900
1000
1050
1050
1100
1200
1300
1400
1500
1600
1685.5
1685.5
1700
1800
(HT-H2 98 )/T
26.79
26.81
27.77
28.78
29.82
30.87
31.93
32.15
29.79
30.13
30.45
30.75
39.46
39.46
39.46
39.46
39.46
39.46
39.46
39.46
20.84
20.84
20.88
55.69
55.86
63.70
70.00
75.34
80.02
84.21
85.01
86.03
88.81
92.01
93.51
100.58
102.42
105.85
109.01
111.94
114.66
117.20
119.26
200.65
200.83
202.02
1050 K
0.00
0.17
6.94
11.21
14.23
16.53
18.39
18.72
19.74
20.65
21.62
22.05
29.12
29.59
30.42
31.11
31.71
32.23
32.68
33.02
114.41
113.62
108.46
1, T-
55.69
55.69
56.75
58.79
61.12
63.49
65.82
66.28
66.29
68.17
70.39
71.46
71.46
72.82
75.44
77.90
80.23
82.43
84.53
86.24
86.24
87.21
93.56
A G
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
1685
137.18
kJ
7.42 kJ
Molar Vol.
6.36 kJ
3.392 J-bar'1
33.92 cm3
6/19/92
Formula wt
TELLURIUM (REFERENCE STATE)
Te:
Crystals 298.15 to melting point 723 K.

diatomic gas 1261 to 1800 K.
111
127.600
Ideal
Temp.
CP
ST
(HT-H2 98 )/T
-<GT-H2 98 )/T
A H
A6
Log K
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
kJ-mol" 1
298.15
300
400
500
600
700
723
723
800
900
1000
1100
1200
1261
1261
1300
Melting T
25.70
25.74
27.95
30.15
32.36
34.57
35.07
37.66
37.66
37.66
37.66
37.66
37.66
37.66
18.66
18.66
49.71
49.87
57.58
64.05
69.74
74.90
76.43
100.62
104.04
108.48
112.44
116.03
119.31
121.18
161.10
161.67
723
0.00
0.16
6.83
11.27
14.60
17.30
17.86
42.05
41.63
41.19
40.83
40.54
40.30
40.18
80.10
78.25
49.71
49.71
50.75
52.78
55.14
57.60
58.57
58.57
62.41
67.29
71.60
75.48
79.01
81.00
81.00
83.41
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
1261
50.341 kJ
17.489 kJ
Molar Vol.
H2*98~H5
6.121 kJ
2.048 J'bar'1
20.48 cm3
6/17/92
112
THORIUM (REFERENCE STATE)
Th:
Formula wt
a-crystals (face-centered cubic) 298.15 to 1650 K.

1650 to melting point 2023 K.
232.038
p-crystals (body-centered cubic)

Temp.
CP
ST
<Hf-H2 98 )/T
/ - UIWA
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1650
1650
1700
1800
Melting T
26.23
26.24
27.09
27.95
28.83
29.71
30.60
31.50
32.39
33.29
34.19
35.08
35.98
36.88
37.77
38.20
35.42
36.02
37.21
51.80
51.99
59.66
65.79
70.97
75.48
79.50
83.16
86.52
89.65
92.59
95.36
97.99
100.51
102.91
104.08
106.21
107.27
109.36
2023 K
0.00
0.16
6.79
10.93
13.84
16.05
17.81
19.28
20.55
21.67
22.67
23.59
24.44
25.24
25.99
26.35
28.48
28.69
29.13
-(Gf-H2 98 )/T
AH
AfG
Log Kf
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
V Trmi-kl ""1
*x
51.83
51.83
52.87
54.86
57.12
59.43
61.69
63.88
65.98
67.99
69.92
71.77
73.55
75.26
76.92
77.73
77.73
78.58
80.23
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
AV*H
AH,H
Molar Vol.
H298~H8
kJ
kJ
6.350 kJ
1 .979
19 .79
J'bar'1
cm3
6/12/92
Formula wt
TITANIUM (REFERENCE STATE)
Ti:
113
a-crystals (hexagonal close packed) 298.15 to 1166 K,

1166 to melting point 1939.
47.88
p-crystals (body-centered cubic)

Temp.
CP
298.15
300
400
500
600
700
800
900
1000
1100
1166
1166
1200
1300
1400
1500
1600
1700
1800
Melting T
T-___l
25.25
25.27
26.82
27.98
28.59
29.01
29.57
30.52
32.05
34.30
36.22
29.24
29.46
30.18
31.02
32.00
33.12
34.36
35.74
30.76
30.92
38.39
44.51
49.67
54.11
58.02
61.55
64.84
68.00
70.06
73.64
74.48
76.86
79.13
81.30
83.40
85.45
87.45
1939 K
A fH
A fG
Log K
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1 . V~l
0.00
0.16
6.62
10.79
13.71
15.87
17.54
18.92
20.16
21.33
22.12
25.70
25.80
26.10
26.43
26.76
27.12
27.52
27.93
30.76
30.76
31.77
33.72
35.96
38.25
40.48
42.63
44.69
46.66
47.94
47.94
48.68
50.76
52.70
54.54
56.28
57.93
59.52
Boiling T
AV*H
AftH 0
14 .15 kJ
Molar Vol.
HJ98-H5
4.83 kJ
kJ
1. 063
10. 63
J'bar'1
cm3
6/17/9
114
Formula wt
URANIUM (REFERENCE STATE)
U:
238.029
a-crystals (orthorhombic) 298.15 to 942 K. ^-crystals (tetragonal) 942 to 1049 K. ycrystals (body-centered cubic) 1049 to melting point 1408 K. Liquid 1408 to 1800 K.
Temp.
ST
(Hf-H2 98 )/T
-(Gf-H2 98 )/T
A fH
AfG
Log Kf
50.20
50.37
58.60
65.46
71.51
77.10
82.40
87.54
89.69
92.64
95.17
97.20
101.71
103.52
106.86
109.92
112.76
112.98
119.17
122.20
125.30
128.22
130.99
0.00
0.17
7.29
11.99
15.53
18.49
21.15
23.66
24.69
27.64
28.50
29.15
33.66
33.87
34.24
34.55
34.82
34.84
41.03
41.45
41.86
42.23
42.58
50.20
50.20
51.31
53.47
55.98
58.60
61.25
63.88
65.00
65.00
66.67
68.05
68.05
69.65
72.62
75.37
77.94
78.14
78.14
80.75
83.44
85.99
88.41
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
K
298.15
300
400
500
600
700
800
900
942
942
1000
1049
1049
1100
1200
1300
1400
1408
1408
1500
1600
1700
1800
Melting T
27.66
27.69
29.65
31.95
34.68
37.91
41.65
45.92
47.88
42.40
42.40
42.40
38.30
38.30
38.30
38.30
38.30
38.30
47.74
47.91
48.12
48.36
48.60
1408 K
Boiling T
AV*H
Afl.H 0
kJ
8. 720 kJ
Molar Vol.
H298"H8
6.364 kJ
1 .250 J-bar'1
12 .50 cm3
6/11/92
Formula wt
VANADIUM (REFERENCE STATE)
V:
115
50.942
Body-centered cubic crystals 298.15 to 2175 K,
Temp.
CP
ST
(HT-H^99)/T
-(GT-H2 9 g)/T
A fH
Melting T
24.90
24.94
26.30
26.91
27.42
27.97
28.60
29.31
30.10
30.96
31.87
32.83
33.83
34.88
35.95
37.06
38.19
28.94
29.09
36.49
42.43
47.38
51.65
55.42
58.83
61.96
64.87
67.60
70.19
72.66
75.03
77.31
79.52
81.67
2175 K
0.00
0.15
6.55
10.57
13.33
15.38
16.99
18.32
19.46
20.47
21.38
22.22
23.01
23.77
24.50
25.20
25.89
28.94
28.94
29.94
31.86
34.05
36.26
38.43
40.51
42.50
44.40
46.22
47.97
49.64
51.26
52.81
54.32
55.78
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
Aô
AfiH0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
K
kJ
20. 928 kJ
Molar Vol.
H298~H5
Log K
kJ-mol" 1
K
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A 6
4.64 kJ
0.835 J-bar'1
8.35 cm3
4/30/92
116
Formula wt
TUNGSTEN (REFERENCE STATE)
W:
183.85
Body-centered cubic crystals 298.15 to 2500 K.
Temp.
cp
O
Sm
/IT_H9
1 tlm IlOQO \) //T
J.
/r10
( Vm Ufi
tlOQO \/ //T
!
A fH
1.T--.-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
24.33
24.34
24.90
25.45
25.92
26.33
26.69
27.03
27.36
27.69
28.04
28.40
28.79
29.20
29.65
30.13
30.65
32.65
32.80
39.88
45.49
50.18
54.20
57.74
60.91
63.77
66.39
68.82
71.08
73.20
75.20
77.10
78.91
80.64
3680 K
0.00
0.15
6.27
10.05
12.66
14.58
16.07
17.27
18.26
19.11
19.84
20.48
21.06
21.59
22.08
22.54
22.97
32.65
32.65
33.61
35.45
37.52
39.62
41.67
43.64
45.51
47.29
48.98
50.60
52.14
53.61
55.02
56.37
57.67
A G
Log K
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
kJ
35.397 kJ
Molar Vol
H298~H5
4.979 kJ
0.9545 J-bar'1
9.545 cm3
4/30/92
Formula wt
ZINC (REFERENCE STATE)
Zn:
117
65.390
Hexagonal close-packed crystals 298.15 to melting point 692.7 K. Liquid 692.7 to

boiling point 1180.2 K. Ideal monatomic gas 1180.2 to 2000 K.
Temp.
CP
eo
ST
(HT-H2 98 )/T
-(GT-H| 98 )/T
A fH
A G
Log K
41.63
41.63
42.64
44.57
46.78
48.88
48.88
49.16
52.70
55.90
58.81
61.47
63.46
63.46
65.55
75.18
83.54
90.89
97.41
103.23
108.48
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
K
298.15
300
400
500
600
692.7
692.7
700
800
900
1000
1100
1180.2
1180.2
1200
1300
1400
1500
1600
1700
1800
25.39
25.41
26.36
27.39
28.57
29.81
31.38
31.38
31.38
31.38
31.38
31.38
31.38
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
41.63
41.79
49.23
55.22
60.31
64.50
75.07
75.40
79.59
83.29
86.59
89.58
91.79
189.50
189.84
191.51
193.05
194.48
195.82
197.08
198.27
0.00
0.16
6.59
10.64
13.53
15.62
26.19
26.24
26.89
27.39
27.78
28.11
28.33
126.04
124.29
116.33
109.51
103.59
98.41
93.85
89.79
Boiling T
Melting T
1080.2
115.30
K
kJ
7.32 kJ
Molar Vol.
H298"H5
5.648 kJ
0.9162 J'bar'1
9.162 cm3
4/30/d:
118
Formula wt
ZIRCONIUM (REFERENCE STATE)
Zr:
a-crystals (hexagonal close packed) 298.15 to 1135 K.

cubic) 1135 to melting point 2125 K.
91.224
0-crystals (body-centered

Temp.
ST
(Hf-H2 98 )/T
-(Gf-H2 98 )/T
Melting T
Log Kf
kJ-mol' 1
298.15
300
400
500
600
700
800
900
1000
1100
1135
1135
1200
1300
1400
1500
1600
1700
1800
A6
AfH
25.20
25.23
26.04
26.52
27.16
27.99
28.96
30.04
31.18
32.33
32.74
28.33
28.51
28.88
29.35
29.93
30.62
31.41
32.31
38.87
39.03
46.42
52.28
57.17
61.42
65.22
68.69
71.91
74.93
75.94
79.48
81.06
83.36
85.51
87.56
89.51
91.39
93.21
2125 K
0.00
0.16
6.55
10.49
13.21
15.26
16.91
18.31
19.54
20.65
21.02
24.56
24.76
25.07
25.35
25.64
25.93
26.23
26.54
38.87
38.87
39.87
41.79
43.96
46.15
48.30
50.38
52.37
54.29
54.92
54.92
56.30
58.29
60.16
61.92
63.58
65.16
66.67
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Boiling T
A^H
Aft.H0
kJ
Molar Vol
H298-H6
kJ
5.497 kJ
1. 4016
14. 016
J-bar'1
cm3
11/30/92
119
Formula wt
METHANE
CH4 :
16 .043
Ideal gas, P - 1 bar, 298.15 to 1800 K
Temp.
sT
CP
QO
Melting T
-(GT-H$ 98 )/T
35.70
35.72
39.91
46.21
52.42
58.08
63.14
67.65
71.67
75.26
78.48
81.36
83.95
86.26
88.33
90.17
91.80
186.26
186.48
197.22
206.79
215.77
224.29
232.38
240.08
247.42
254.43
261.11
267.51
273.64
279.51
285.14
290.56
295.76
0.00
0.22
9.52
16.22
21.74
26.54
30.80
34.65
38.16
41.37
44.33
47.07
49.61
51.98
54.19
56.25
58.18
AfG
Log Kf
-50.7
8.88
8.80
5.48
3.41
1.98
0.93
0.13
-0.51
-1.03
-1.45
-1.82
-2.12
-2.39
-2.62
-2.82
-3.00
-3.16
A fH
J-mol"1 ^" 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
<H*-HJ98 )/T
kJ-mol' 1
186.26
186.26
187.70
190.57
194.03
197.75
201.58
205.43
209.27
213.05
216.78
220.44
224.02
227.53
230.95
234.30
237.57
-74.8
-74.9
-78.0
-80.8
-83.3
-85.4
-87.2
-88.6
-89.8
-90.7
-91.5
-92.0
-92.4
-92.7
-92.9
-92.9
-93.0
-50.6
-42.0
-32.7
-22.8
-12.5
-2.0
8.8
19.7
30.7
41.7
52.9
64.0
75.2
86.4
97.6
108.8
Boiling T
Aô
AfiH
Molar Vol.
H298-H6
kJ
kJ
10 .025 kJ
2478 .97 J-bar'1

24789 .7
cm3
2/25/94
120
Formula wt
COHENITE
Fe3C:
179.552
Orthorhombic crystals 298.15 to 1800 K.
Temp.
CP
CO
ST
(Hf-H2 98 )/T
-(GT-H 98 )/T
A fH
A fG
Log Kf
J-mol" 1 ^' 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
111.04
111.06
112.31
113.57
114.82
116.07
117.32
118.58
119.83
121.08
122.34
123.59
124.84
126.10
127.35
128.60
129.85
104.40
105.09
137.21
162.40
183.22
201.01
216.59
230.49
243.04
254.52
265.11
274.95
284.16
292.82
300.99
308.75
316.14
0.00
0.68
28.43
45.34
56.81
65.19
71.63
76.77
81.02
84.60
87.69
90.41
92.82
95.00
96.98
98.80
100.49
104.40
104.40
108.77
117.07
126.41
135.83
144.97
153.71
162.03
169.92
177.42
184.55
191.34
197.82
204.01
209.95
215.64
24.9
24.9
27.2
28.6
29.2
29.0
27.9
25.6
21.0
13.8
8.9
8.6
8.1
7.4
6.5
2.7
0.2
Boiling T
AVIPHO
Aft.H0
-3.45
-3.43
-2.29
-1.56
-1.06
-0.70
-0.43
-0.24
-0.10
-0.02
0.03
0.06
0.08
0.10
0.12
0.13
0.13
K
kJ
kJ
Molar Vol.
H298"H5
19.7
19.7
17.6
15.0
12.2
9.3
6.6
4.1
1.9
0.4
-0.7
-1.5
-2.3
-3.0
-3.6
-4.2
-4.5
kJ
2. 323 J-bar'1
23. 23 cm3
01/06/93
Formula wt
AMMONIA
NH3 :
121
17.031
Ideal gas, P 1 bar, 298.15 to 1800 K.

Temp.
cj
ST
<HT-H$98 )/T
J
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
35.68
35.72
38.59
41.99
45.32
48.44
51.34
54.03
56.52
58.82
60.96
62.94
64.77
66.45
68.00
69.42
70.71
192.77
192.99
203.63
212.60
220.56
227.78
234.44
240.65
246.47
251.96
257.18
262.13
266.87
271.39
275.73
279.90
283.90
-< 0*-H598 >/T
]_.
1~1K""1
0.00
0.22
9.43
15.60
20.28
24.08
27.31
30.13
32.65
34.92
37.01
38.93
40.71
42.37
43.92
45.38
46.75
192.77
192.77
194.20
197.01
200.28
203.70
207.13
210.51
213.82
217.04
220.17
223.21
226.16
229.03
231.81
234.52
237.15
A6
Log Kf
-16.4
-16.2
-5.9
4.8
15.9
27.2
38.7
50.3
61.9
73.7
85.4
97.2
109.0
120.8
132.5
144.3
156.1
2.87
2.82
0.78
-0.50
-1.38
-2.03
-2.53
-2.92
-3.24
-3.50
-3.72
-3.91
-4.07
-4.21
-4.33
-4.43
-4.53
A fH
-45.9
-45.9
-48.1
-49.9
-51.4
-52.6
-53.6
-54.4
-55.0
-55.4
-55.8
-55.9
-56.0
-56.0
-55.9
-55.7
-55.5
,-;L
Boiling T
Aô
Afo.H
kJ
kJ
Molar Vol.
H298~H5
10. 045 kJ
2478 .97 J-bar*1

24789 .7 on3
11/18/92
122
Formula wt
247.802
Ag2S: Monoclinic crystals 298.15 to 451.3 K; cubic crystals (argentite) 451.3 to 865 K.
y phase 865 to 1000 K. Reference state for sulfur is orthorhombic sulfur.

Temp.
eo
ST
CP
<Hf-H2 98 )/T
-<GT-H298 )/T
J-mol"1 ^"1 -
298.15
300
400
500
600
700
800
900
1000
75.31
75.39
80.47
87.26
86.03
84.80
84.69
80.38
80.57
142.89
143.35
165.67
193.79
209.59
222.75
234.05
244.84
253.28
Melting T
0.00
0.46
19.78
41.08
48.67
53.91
57.75
61.53
63.38
A fG
Log Kf
-39.7
-39.7
-42.2
-44.7
-47.5
-50.3
-53.0
-54.7
-51.5
6.95
6.92
5.52
4.67
4.14
3.75
3.46
3.17
2.69
A fH
kJ mol" 1
142.89
142.89
145.89
152.71
160.92
168.84
176.30
183.31
189.90
-32.0
-32.0
-34.0
-30.5
-30.7
-31.0
-31.3
-84.1
-83.8
Boiling T
kJ
kJ
Molar Vol.
H298~H8
17.132 kJ
3.419 J-bar'1
34.19 cm3
9/30/92
Formula wt
REALGAR
AsS:
123
106.988
Monoclinic crystals 298.15 to melting point 580 K; liquid 580 to 800 K.

Reference state for sulfur is orthorhombic sulfur.
Temp.
CP
ST
K
298.15
300
400
500
600
700
800
Melting T
<Hf-H2 98 )/T
*r -
47.02
47.08
49.32
51.18
67.12
71.48
77.50
63.50
63.80
77.68
88.88
110.35
121.00
130.90
580 K
_1
-<Gf-H2 98 )/T
Log Kf
-29.6
-29.6
-29.1
-27.9
-26.7
-26.4
-26.3
5.19
5.16
3.80
2.92
2.33
1.97
1.72
kJ-mol" 1
1 - r 1
0.00
0.29
12.29
19.88
36.84
41.46
45.57
A fG
A fH
63.50
63.51
65.39
69.00
73.51
79.54
85.33
-30.9
-30.9
-33.2
-34.6
-28.7
-27.8
-26.3
Boiling T
K
kJ
Aft.H'
6.668 kJ
Molar Vol.
kJ
2.980 J-bar'1
29.80 cm3
9/30/92
124
Formula wt
GREENOCKITE
CdS:
144.477

Temp.
cp
cO
ST
<HT-H2 98 )/T
-<GT-H2 98 )/T
J-mol"1 -*"1 -
298.15
300
400
500
600
700
800
900
1000
1100
47.30
47.36
49.46
50.70
51.68
52.55
53.37
54.16
54.93
55.67
72.18
72.47
86.42
97.60
106.93
114.96
122.03
128.37
134.11
139.38
Melting T
0.00
0.29
12.35
19.90
25.12
28.98
31.98
34.40
36.41
38.13
A fG
Log Kf
-146.1
-146.1
-144.8
-142.8
-140.5
-136.9
-133.2
-128.4
-118.5
-102.9
25.60
25.44
18.91
14.92
12.23
10.22
8.70
7.45
6.19
4.89
A fH
1. T
72.18
72.18
74.07
77.69
81.81
85.99
90.06
93.97
97.70
101.25
-149.6
-149.6
-152.0
-153.7
-161.2
-162.3
-163.2
-217.1
-216.5
-314.8
Boiling T
kJ
kJ
Molar Vol
H298~H5
8.818 kJ
2.993 J-bar'1
29.93 cm3
9/30/92
Formula wt
CATTIERITE
0082:
125
123.065
Reference state for sulfur is orthorhombic sulfur,

Temp.
CO
ST
CP
(HT-H2 98 )/T
-(GT-H$ 98 )/T
J-mol"1 ^""1
298.15
300
400
500
600
700
800
900
1000
Melting T
68.26
68.39
74.28
78.63
82.38
85.85
89.16
92.38
95.55
74.80
75.22
95.76
112.82
127.50
140.46
152.14
162.83
172.72
0.00
0.42
18.20
29.87
38.31
44.86
50.19
54.70
58.63
A fG
Log Kf
-145.1
-145.1
-143.0
-139.5
-135.5
-131.2
-126.7
-120.0
-103.5
25.42
25.26
18.67
14.57
11.80
9.79
8.27
6.97
5.41
A fH
kJ mol' 1
74.80
74.80
77.56
82.96
89.18
95.60
101.95
108.13
114.10
-150.9
-150.9
-155.5
-158.5
-160.5
-161.8
-163.1
-269.8
-267.7
Boiling T
K
kJ
kJ
Molar Vol
12.301 kJ
2.552 J-bar'1
25.52 cm3
9/30/9!
126
Formula wt
COVELLITE
CuS;
95.612
Hexagonal crystals 298.15 to 800 K. Reference state for sulfur is orthorhombic sulfur,

Temp.
CP
CO
ST
<HT-H2 98 )/T
-<Gf-H2 98 )/T
J-aiol"1 -*'1 -
298.15
300
400
500
600
700
800
Melting T
47.53
47.59
50.29
52.62
54.82
56.94
59.03
67.40
67.69
81.77
93.24
103 . 03
111.64
119.38
7801 K
0.00
0.29
12.47
20.27
25.84
30.14
33.62
A fG
Log Kf
-55.3
-55.3
-55.4
-54.9
-54.2
-53.3
-52.4
9.68
9.62
7.23
5.74
4.72
3.98
3.42
A H
kJ
67.40
67.40
69.30
72.98
77.19
81.51
85.77
-54.6
-54.6
-56.8
-58.1
-59.0
-59.4
-59.5
Boiling T
kJ
kJ
Molar Vol.
9.45 kJ
2.042 J-bar'1
20.42 cm3
9/30/92
Formula wt
CHALCOCITE
159 .158
Orthorhombic crystals 298.15 to 376 K; hexagonal crystals 376 to 710 K; cubic

crystals 710 to melting point 1403 K. Reference state for sulfur is orthorhombic
sulfur.

Temp.
cp
ST
(H*-HJ98 ,/T
Jmol
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
Melting T
76.84
77.01
98.83
95.31
92.30
89.79
82.76
82.50
85.02
85.02
85.02
85.02
85.02
116.20
116.67
151.07
172.84
189.93
203.97
216.94
226.66
235.65
243.77
251.17
257.95
264.23
1403 K
-<GT-H2 98 )/T
UT
"K
0.00
0.47
31.14
44.33
52.56
58.06
62.85
65.04
67.02
68.68
70.03
71.71
72.15
116.20
116.20
119.93
128.51
137.37
145.91
154.09
161.62
168.63
175.09
181.14
186.24
192.08
A G
Log Kf
-89.2
-89.2
-91.3
-93.9
-96.7
-99.5
-102.5
-104.5
-101.5
-98.6
-95.7
-92.2
-89.2
15.62
15.53
11.92
9.81
8.42
7.43
6.69
6.06
5.30
4.68
4.17
3.71
3.33
A H
-83.9
-83.9
-81.1
-80.5
-79.9
-79.5
-78.5
-132.1
-131.1
-130.3
-129.7
-128.7
-155.6
mol" 1
Boiling T
kJ
kJ
Molar Vol
H298~H8
15.80 kJ
2.748 J-bar^
27.48 cm3
9/30/92
128
Formula wt
CHALCOPYRITE
CuFeS2 :
183.525
Tetragonal crystals 298.15 to 820 K; tetragonal crystals 820 to 930 K; cubic

crystals 930 to 1200 K. Reference state for sulfur is orthorhombic sulfur.
Above 820 K, the phase is called ISS (intermediate solid solution).
Temp.
cp
CO
ST
flO
<H*-HS98 ,/T
-<GT-H2 98 )/T
K
298.15
300
400
500
600
700
800
900
1000
1100
1200
Melting T
A fG
Log Kf
-195.1
-195.1
-195.0
-193.8
-192.1
-190.1
-188.2
-185.0
-173.0
-161.5
-150.6
34.18
33.97
25.47
20.24
16.72
14.19
12.29
10.74
9.04
7.67
6.55
A H
1. T
95.80
96.24
106.26
109.15
114.53
123.84
136.83
203.75
172.49
172.49
172.49
124.90
125.49
155.01
179.02
199.34
217.64
234.99
264.70
285.00
301.44
316.45
0.00
0.59
26.15
42.45
53.97
63.24
71.59
91.48
101.42
107.88
113.27
124.90
124.90
128.86
136.57
145.38
154.41
163.40
173.22
183.58
193.56
203.18
-194.9
-194.9
-199.0
-201.5
-203.2
-204.0
-203.8
-298.0
-290.2
-285.3
-279.8
Boiling T
K
kJ
Aft.H 0
kJ
Molar Vol.
H298~H8
18.34 kJ
4.392 J'bar"1
43.92 cm3
9/30/92
Formula wt
BORNITE
Cu5FeS4 :
129
501.841
Orthorhombic crystals 298.15 to 470 K; cubic crystals 470 to 535 K; cubic

crystals 535 to 1200 K. Reference state for sulfur is orthorhombic sulfur.

Temp.
ST
CP
(H*-H298 ,/T
--I
298.15
300
400
500
600
700
800
900
1000
1100
1200
242.90
243.20
260.60
369.45
327.89
323.50
325.20
327.30
332.90
340.00
348.30
398.50
400.00
472.40
549.41
615.63
665.90
709.20
747.53
782.29
814.34
844.27
Melting T
0.00
1.50
64.09
121.22
161.33
184.73
202.19
215.89
227.29
237.21
246.12
-<GT-H2 98 )/T
A G
Log Kf
-394.7
-394.8
-402.3
-407.9
-414.9
-422.6
-430.5
-434.4
-419.1
-404.3
-390.1
69.15
68.75
52.54
42.62
36.12
31.53
28.11
25.21
21.89
19.20
16.98
A H
kJ-mol~
-1
398.50
398.50
408.31
428.19
454.30
481.17
507.01
531.64
555.00
577.13
598.15
-371.6
-371.6
-379.9
-376.3
-370.6
-368.2
-365.8
-576.1
-569.5
-563.5
-556.7
Boiling T
K
kJ
kJ
Molar Vol
H298~H6
53.011 kJ
9.873 J-bar4
98.73 cm3
9/30/92
130
Formula wt
TROILITE
FeS:
87.913
Hexagonal crystals (NiAs structure) 298.15 to a complex transition at 411 K and a Neel
temperature at 590 K; paramagnetic 590 to melting point at 1468 K; liquid 1468 to 1800
K. Reference state for sulfur is orthorhombic sulfur.
Temp.
CP
ST
(Hf-H2 98 )/T
-<GT-H2 98 )/T
Melting T
50.49
50.64
70.02
72.06
67.33
58.13
57.73
58.65
60.64
62.00
62.99
63.99
64.99
71.13
71.13
71.13
71.13
60.30
60.62
76.87
102.86
116.98
126.32
134.00
140.86
147.13
152.82
158.17
163.32
168.22
194.95
199.51
203.82
207.88
1468 K
0.00
0.31
14.44
34.29
41.52
44.23
45.90
47.27
48.49
49.52
50.52
51.56
52.60
75.20
74.94
74.72
74.52
Log Kf
-102.9
-102.9
-103.0
-103.6
-104.5
-105.5
-106.3
-106.0
-100.6
-95.0
-89.3
-83.7
-78.2
-73.4
-70.2
-67.1
-64.0
18.03
17.92
13.46
10.83
9.10
7.87
6.94
6.15
5.25
4.51
3.89
3.36
2.92
2.56
2.29
2.06
1.86
I 1
J-mol'^K' 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A fG
A fH
60.30
60.31
62.43
68.57
75.46
82.09
88.10
93.59
98.64
103.30
107.65
111.76
115.62
119.75
124.57
129.10
133.36
-102.6
-102.6
-104.1
-99.5
-98.4
-99.1
-100.1
-154.6
-155.3
-156.8
-157.5
-156.5
-155.3
-121.7
-120.3
-119.8
-119.0
Boiling T
AV*H
AftH
H2*98~H6
32. 34 kJ
Molar Vol.
9 .351 kJ
kJ
1. 820 J-bar'1
18. 20 cm3
2/17/93
Formula wt
PYRRHOTITE
Fe .875S:
131
80.932
Monoclinic crystals 298.15 to combined structural and magnetic transition at 590

K; hexagonal crystals (Ni-As-type) 590 to 1000 K. Reference state for sulfur is
orthorhombic sulfur.
Temp.
c
CP
ST
(HT-H2 98 )/T
-(GT-H2 98 )/T
UT
J-mol^-K" 1
298.15
300
400
500
600
700
800
900
1000
49.88
50.01
56.24
63.56
67.35
65.30
57.42
57.19
58.38
60.70
60.70
76.28
89.57
104.51
114.53
122.64
129.39
135.46
Melting T
0.00
0.31
13.53
22.76
32.47
37.37
40.28
42.17
43.71
60.70
60.39
62.75
66.81
72.04
77.16
82.36
87.22
91.75
AG
Log Kf
-98.9
-98.8
-99.4
-99.5
-99.8
-100.0
-100.3
-99.6
-93.8
17.33
17.21
12.98
10.39
8.69
7.46
6.55
5.78
4.90
A fH
mol"" 1
-97.5
-97.4
-99.0
-99.5
-97.7
-97.2
-97.6
-151.6
-151.9
Boiling T
Av^H0
K
kJ
kJ
Molar
H298"H8
9.21 kJ
Vol. 1.749 J'bar'1

17.49 cm3
1/13/93
132
Formula wt
PYRITE
FeS2 :
119.979
Temp.
CP
ST
(HT-H2 98 )/T
-<GT-H2 98 )/T
52.90
53.29
72.34
88.10
101.39
112.94
123.21
132.55
141.18
0.00
0.38
16.88
27.64
35.20
40.87
45.38
49.15
52.43
52.90
52.90
55.45
60.45
66.20
72.07
77.83
83.40
88.75
A fH
A fG
Log Kf
-160.1
-160.1
-155.9
-150.3
-144.0
-137.3
-130.2
-120.6
-101.1
28.05
27.87
20.36
15.70
12.54
10.24
8.50
7.00
5.28
K
298.15
300
400
500
600
700
800
900
1000
Melting T
62.17
62.39
69.15
71.95
73.93
75.90
78.10
80.57
83.29
1015i K
-171.5
-171.6
-176.7
-180.4
-183.3
-185.9 ,
-188.2
-296.8
-297.1
Boiling T
K
kJ
kJ
Molar Vol
H298~H8
9.63 kJ
2.394 J-bar'1
23.94 cm3
9/30/92
133
Formula wt
MARCASITE
PeS2 :

sulfur.
119.979
Reference state for sulfur is orthorhombic

Temp.
CO
ST
<HT-H2 98 )/T
-(GT-H2 98 )/T
J-mol^-K"1 -
298.15
300
400
500
600
700
62.43
62.60
69.17
72.44
74.59
77.00
53.90
54.29
73.31
89.13
102.53
114.20
0.00
0.39
16.86
27.68
35.32
41.10
A fG
Log Kf
-158.4
-158.3
-154.3
-148.8
-142.6
-136.0
27.75
27.56
20.15
15.54
12.41
10.14
A H
kJ mol"1
53.90
53.90
56.45
61.45
67.21
73.11
-169.5
-169.5
-174.7
-178.3
-181.2
-183.7
Boiling T
Melting T
K
kJ
kJ
Molar Vol
9.74 kJ
2.458 J-bar 1
24.58 cm3
3/6/92^
134
Formula wt
HYDROGEN SULFIDE
H2 S:
Ideal gas at p
sulfur.
1 bar, 298.15 to 1800 K.
34.082
Reference state for sulfur La orthorhombic

Temp.
CP
CO
ST
/tlO__UQ
V /fit
^ *lm tin QQ / / A
-(G*-H298 )/T
J-mol'^-K' 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
A^0
34.20
34.21
35.48
37.22
39.05
40.85
42.58
44.21
45.72
47.13
48.41
49.58
50.62
51.55
52.35
53.04
53.60
205.80
206.01
216.01
224.11
231.05
237.21
242.78
247.89
252.63
257.05
261.21
265.13
268.84
272.37
275.72
278.92
281.96
0.00
0.21
8.85
14.35
18.31
21.40
23.94
26.11
27.99
29.67
31.18
32.55
33.80
34.96
36.02
37.00
37.91
A fG
Log Kf
-33.4
-33.5
-37.5
-40.3
-42.5
-44.3
-45.8
-46.0
-41.1
-36.2
-31.3
-26.3
-21.4
-16.4
-11.5
-6.5
-1.6
5.86
5.84
4.89
4.21
3.70
3.31
2.99
2.67
2.15
1.72
1.36
1.06
0.80
0.57
0.37
0.20
0.05
A fH
kJ-mol" 1
205.80
205.80
207.15
209.76
212.74
215.81
218.83
221.78
224.63
227.38
230.03
232.58
235.04
237.41
239.70
241.91
244.06
-20.6
-20.6
-24.7
-27.9
-30.6
-32.9
-34.9
-89.7
-90.1
-90.4
-90.6
-90.7
-90.8
-90.8
-90.8
-90.8
-90.7
kJ
Av*H
kJ
Molar Vol.
H298-H&
Boiling T
9.96 kJ
2478 .97 Jbar'!

cm3
24789 .7
9/30/92
ALABANDITE
MnS:
135
Formula wt
87.004

Temp.
Sf
(Hf-H2 98 )/T
-<Gf-H2 98 )/T
Melting T
49.98
49.99
51.10
52.14
52.83
53.25
53.55
53.84
54.21
54.73
55.44
56.39
57.60
59.10
60.91
63.04
65.51
80.30
80.61
95.13
106.65
116.22
124.40
131.53
137.85
143.55
148.74
153.53
158.00
162.22
166.24
170.11
173.87
177.54
0.00
0.31
12.86
20.62
25.93
29.81
32.76
35.08
36.98
38.56
39.94
41.17
42.30
43.36
44.40
45.43
46.48
Log Kf
-218.7
-218.8
-220.3
-221.2
-221.7
-222.0
-222.1
-220.9
-214.7
-208.3
-201.9
-195.5
-188.9
-182.2
-174.7
-167.0
-159.4
38.32
38.09
28.77
23.10
19.30
16.56
14.50
12.82
11.22
9.89
8.79
7.85
7.05
6.34
5.70
5.13
4.62
J-mol'^K""1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A fG
A H
80.30
80.30
82.27
86.04
90.29
94.59
98.78
102.77
106.57
110.17
113.59
116.83
119.93
122.88
125.71
128.43
131.06
-213.9
-213.9
-216.2
-217.9
-219.3
-220.6
-221.9
-276.3
-278.7
-278.9
-279.1
-279.3
-281.7
-284.2
-296.9
-297.3
-297.4
Boiling T
Av*H
AftH
kJ
Molar Vol.
H598-H8
kJ
K
kJ
2. 146 J'bar'1
21. 46 cm3
9/30/92
136
Formula wt
MOLYBDENITE

sulfur.
160.072

Temp.
CP
ST
(Hf-H2 98 )/T
-<Gf-H2 98 )/T
-1-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
63.51
63.63
68.45
71.58
73.77
75.35
76.54
77.44
78.12
78.65
79.04
62.60
62.99
82.01
97.65
110.90
122.40
132.54
141.61
149.81
157.28
164.14
Melting T
0.00
0.39
16.85
27.50
35.04
40.69
45.10
48.65
51.56
54.00
56.07
1_ T
62.60
62.60
65.16
70.14
75.86
81.70
87.44
92.96
98.24
103.28
108.07
A 6
Log Kf
-262.8
-262.7
-259.5
-254.7
-249.4
-243.7
-237.7
-229. 5
-211.3
-193.2
-175.3
46.04
45.75
33.88
26.61
21.71
18.18
15.52
13.32
11.03
9.17
7.63
A fH
-271.8
-271.8
-276.8
-280.2
-282.7
-284.6
-286.2
-393.7
-392.5
-391.3
-390.1
mol'1
Boiling T
K
kJ
kJ
Molar Vol.
H298~H8
8.82 kJ
3.202 J'bar'1
32.02 cm3
9/30/92
Formula wt
MILLERITE
NiS:
137
90.756
Rhombohedral crystals 298.15 to 623 K; hexagonal crystals 623 to melting point 1066 K.
Temp.
CP
ST
(H*-H298 >/T
-<Gf-H2 98 )/T
AfH
1. T
298.15
300
400
500
600
700
800
900
1000
1100
Melting T
47.11
47.24
50.79
53.68
56.27
59.45
62.55
65.65
68.74
71.13
52.97
53.26
67.36
79.04
89.04
102.68
110.79
118.37
125.44
159.58
1066 K
0.00
0.29
12.55
20.42
26.22
34.91
38.18
41.05
43.68
72.73
52.97
52.97
54.81
58.62
62.82
67.77
72.61
77.32
81.76
86.85
A6
Log Kf
-88.3
-88.3
-87.3
-85.6
-83.6
-81.7
-80.3
-77.0
-69.2
-62.5
15.47
15.38
11.40
8.94
7.27
6.10
5.24
4.47
3.61
2.97
mol"1
-91.0
-91.0
-93.4
-95.1
-96.4
-94.4
-94.6
-147.6
-145.9
-114.7
Boiling
K
kJ
kJ
Molar Vol.
H98~H8
8.47 kJ
1.689 J-bar'1
16.89 cm3
9/30/92
138
Formula wt
HEAZLEWOODITE
240.202
Ni3S2 : Hexagonal crystals 298.15 to 834 K; cubic crystals 834 K to incongruent melting point
1064 K; liquid 1064 to 1400 K. Reference state for sulfur is orthorhombic sulfur.
Temp.
cp
ST
(Hf-H2 98 )/T
_
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
Melting T
118.24
118.45
129.01
136.05
141.59
148.35
158.39
189.15
191.81
189.12
189.12
189 . 12
189.12
133.20
133.93
169.52
199.12
224.42
246.72
267.14
355.52
375.52
411.84
428.28
443.42
457.44
1064 K
-<Gf-H2 98 )/T
k_
,-1 _-l
0.00
0.73
31.54
51.79
66.29
77.51
86.95
159.38
162.41
182.56
183.11
183.57
183.97
133.20
133.20
137.98
147.34
158.12
169.22
180.20
196.14
213.11
229.28
245.17
259.85
273.47
A fG
Log Kf
-210.2
-210.1
-207.8
-204.1
-199.7
-194.8
-191.1
-187.1
-177.3
-168.7
-161.7
-155.1
-148.9
36.82
36.59
27.14
21.32
17.38
14.53
12.48
10.86
9.26
8.01
7.03
6.23
5.56
A H
-216.3
-216.3
-221.3
-224.7
-227.8
-230.1
-230.5
-278.4
-272.8
-247.9
-242.7
-237.9
-233.3
.- 1
Boiling T
K
kJ
A*.**'
19 .66 kJ
Molar Vol.
H2*98~H8
21.50 kJ
4. 095 J'bar'1
40. 95 cm3
9/30/92
Formula wt
GALENA
PbS:
134
239.26

Temp.
CP
CO
ST
<Hf-H2 98 )/T
-<Gf-H2 98 )/T
A fH
J-mol'^K" 1 -
298.15
300
400
500
600
700
800
900
Melting T
49.49
49.52
51.16
52.80
54.44
56.08
57.72
59.36
91.70
92.01
106.48
118.07
127.84
136.36
143.95
150.84
0.00
0.31
12.81
20.65
26.14
30.30
33.63
36.40
1400 K
A fG
Log Kf
-96.8
-96.8
-96.1
-94.9
-93.3
-90.8
-88.1
-84.3
16.95
16.85
12.55
9.91
8.12
6.77
5.75
4.90
1. T
91.70
91.70
93.66
97.42
101.70
106.05
110.32
114.45
-98.3
-98.3
-100.6
-102 . 1
-103.3
-109.0
-109.5
-162.9
Boiling
K
kJ
H (fusion)
kJ
Molar Vol.
H298~H8
11.51 kJ
3.149 J'bar'f
31.49 cm*
9/30/9:
140
Formula wt
STIBNITE
Sb2S3 :

sulfur.
339.698

Temp.
CP
0O
ST
<HT-H2 98 )/T
-<Gf-H2 98 )/T
J-mol'^K"1 298.15
300
400
500
600
700
800
900
Melting T
119.75
119.81
123.38
126.46
128.94
130.92
132.51
133.80
182.00
182.74
217.70
245.58
268.86
288.89
306.48
322.17
829 K
0.00
0.74
30.96
49.76
62.76
72.36
79.78
85.72
A 6
Log Kf
-149.8
-149.8
-149.0
-146.3
-142.7
-138.6
-134.1
-126.2
26.25
26.09
19.46
15.28
12.42
10.34
8.76
7.33
A fH
kJ mol"1
182.00
182.00
186.74
195.82
206.10
216.53
226.70
236.45
-151.4
-151.4
-158.1
-162.7
-166.0
-168.6
-170.8
-332.2
Boiling T
K
kJ
kJ
Molar Vol.
H298~H8
kJ
7.341 J-bar'
73.41 cm3
10/1/92
Formula wt
HERZENBERGITE
SnS:
141
150.776
Orthorhombic crystals 298.15 to 875 K; cubic crystals 875 to melting point 1153 K.
Liquid 1153 to 1300 K. Reference state for sulfur is orthorhombic sulfur.

Temp.
CP
ST
<Hf-H2 98 )/T
-<Gf-H2 98 )/T
1-1--1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
Melting T
49.25
49.32
50.87
52.02
54.51
58.40
63.50
54.04
57.07
60.11
75.61
75.61
77.00
77.30
91.76
103.22
112.91
121.50
129.71
137.47
143.32
148.90
181.98
188.03
1153 K
0.00
0.30
12.81
20.52
25.96
30.30
34.12
37.81
39.59
41.32
69.64
70.10
A G
Log K
-104.6
-104.6
-103.9
-102.5
-99.3
-96.0
-92.7
-88.1
-78.9
-69.7
-62.0
-55.9
18.33
18.22
13.57
10.70
8.65
7.16
6.05
5.11
4.12
3.31
2.70
2.25
A H
V TfmrO ""1
77.00
77.00
78.95
82.70
86.95
91.20
95.59
99.66
103.73
107.58
112.34
117.93
-106.5
-106.5
-108.9
-110.6
-119.0
-119.6
-119.5
-171.8
-170.9
-169.7
-136.3
-133.5
Boiling T
kJ
31 .59 kJ
Molar Vol.
H298~H8
kJ
2 .901 J'bar'1
29 . 01 cm3
10/1/92
142
Formula wt
BERNDTITE
SnS2 :

sulfur.
182.842

Temp.
CP
ST
_1
298.15
300
400
500
600
700
800
900
1000
(Hf-H2 98 )/T
70.12
70.17
72.05
73.52
75.19
77.13
79.33
81.74
84.33
87.50
87.93
108.41
124.64
138.19
149.92
160.36
169.84
178.59
Melting T
0.00
0.43
18.13
29.06
36.60
42.25
46.75
50.50
53.75
-(Gf-H$ 98 )/T
-1
1. T
87.50
87.50
90.28
95.58
101.59
107.67
113.61
119.34
124.84
A fG
Log Kf
-141.5
-141.5
-138.4
-134.0
-127.5
-120.6
-113.5
-104.0
-84.7
24.79
24.63
18.08
14.00
11.10
9.00
7.41
6.04
4.42
AfH
-149.8
-149.8
-154.7
-158.2
-168.1
-170.0
-171.4
-278.6
-276.9
mol"1
Boiling T
K
kJ
kJ
Molar Vol
H2*98~H8
kJ
4.096 J-bar'1
40.96 cm3
10/1/92
Formula wt
TUNGSTENITE
WS2 :

sulfur.
143
247.982

Temp.
CP
ST
-(GT-H| 98 )/T
A fH
J-mol'^K" 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
Melting T
63.83
63.99
69.67
72.41
74.01
75.09
75.90
76.57
77.16
77.71
78.24
78.76
79.29
79.83
67.80
68.20
87.50
103.37
116.72
128.22
138.30
147.28
155.38
162.76
169.54
175.82
181.68
187.17
0.00
0.39
17.10
27.92
35.48
41.06
45.37
48.80
51.61
53.95
55.96
57.69
59.21
60.57
1. T
67.80
67.80
70.39
75.45
81.25
87.15
92.93
98.48
103.77
108.80
113.58
118.13
122.47
126.60
A fG
Log Kf
-233.0
-232.9
-229.8
-225.2
-220.0
-214.5
-208.8
-200.7
-182.7
-164.9
-147.1
-129.5
-111.9
-94.5
40.81
40.55
30.00
23.53
19.16
16.01
13.63
11.65
9.54
7.83
6.40
5.20
4.18
3.29
mol' 1
-241.6
-241.6
-246.5
-249.8
-252.2
-254.1
-255.6
-363.1
-361.9
-360.6
-359.4
-358.2
-357.0
-355.8
Boiling T
A^0
K
kJ
kJ
Molar Vol.
H298~H8
11.01 kJ
3.207 J
32.07 cor
10/1/92
144
Formula wt
SPHALERITE
ZnS:
cubic crystals 298.15 K to 1300 K.
97*456

Temp.
CP
Sf
(HT-H2 98 )/T
_1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
Melting T
45.76
45.82
48.30
49.93
51.12
52.04
52.79
53.42
53.96
54.43
54.85
55.23
58.70
58.98
72.53
83.50
92.71
100.66
107.66
113.92
119.57
124.74
129.49
133.90
0.00
0.28
12.00
19.43
24.62
28.47
31.47
33.87
35.85
37.52
38.95
40.19
-<GT-H2 98 )/T
1_T
58.70
58.70
60.53
64.06
68.09
72.19
76.19
80.04
83.72
87.22
90.54
93.71
AfG
Log Kf
-199.6
-199.6
-198.0
-195.6
-193.0
-190.1
-186.0
-180.7
-170.4
-160.2
-148.1
-128.2
34.97
34.75
25.85
20.44
16.80
14.18
12.14
10.49
8.90
7.61
6.45
5.15
A fH
-204.1
-204.1
-206.6
-208.3
-209.6
-218.0
-219.1
-273.2
-272.8
-272.4
-387.1
-385.6
mol'1
Boiling T
K
kJ
kJ
Molar Vol.
8.82 kJ
2.383 J'bar'1
23.83 cm3
10/1/92
Formula wt
WURTZITE
ZnS:
145
Hexagonal crystals 298.15 to 1300 K,

sulfur.
97.456

Temp.
CP
8}
<HT-H2 98 )/T
-(Ofr.HJ 9,)/l
Melting T
45.89
45.96
48.72
50.13
51.09
51.86
52.55
53.21
53.86
54.50
55.15
55.80
58.80
59.08
72.74
83.77
93.00
100.94
107.91
114.13
119.77
124.94
129.71
134.15
0.00
0.28
12.09
19.57
24.75
28.57
31.52
33.90
35.86
37.52
38.97
40.24
Log Kf
-199.4
-199.3
-197.7
-195.4
-192.8
-189.8
-185.8
-180.6
-170.3
-160.1
-148.0
-128.2
34.93
34.71
25.82
20.41
16.78
14.17
12.13
10.48
8.90
7.60
6.44
5.15
kJ mol"1
J-mol'^K' 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
A 6
A fH
58.80
58.80
60.64
64.20
68.25
72.37
76.38
80.24
83.91
87.41
90.74
93.91
-203.8
-203.8
-206.2
-207.9
-209.2
-217.7
-218.8
-272.9
-272.5
-272.1
-386.8
-385.2
Boiling T
A^0
K
kJ
kJ
Molar Vol.
8.85 kJ
2.385 J-bar'1
23.85 cm3
10/1/92
146
Formula wt
BERTHIERITE
FeSb2 S4 :

sulfur.
427.611

Temp.
Sf
(Hf-H$ 98 )/T
-(GT-H$ 98 )/T
1-1. K' 1
298.15
300
400
500
600
700
800
900
175.23
175.60
186.17
189.05
190.44
191.92
193.91
196.48
245.00
246.09
298.40
340.31
374.90
404.37
430.12
453.10
Melting T
0.00
1.08
46.33
74.64
93.83
107.73
118.37
126.91
A fG
Log K
-255.8
-255.8
-255.4
-252.8
-249.1
-244.9
-240.2
-230.9
44.81
44.54
33.36
26.40
21.69
18.27
15.68
13.40
A fH
kJ mol" 1
245.00
245.00
252.06
265.67
281.07
296.63
311.74
326.20
-256.2
-256.2
-264.1
-269.1
-272.9
-276.0
-279.0
-494.4
Boiling T
K
kJ
kJ
Molar Vol.
kJ
9.222 J'bar'1
92.22 cm3
2/17/93
Formula wt
CHALCOSTIBITE
CuSbS2 :
Orthorhombic crystals 298.15 tO 826 K.

sulfur.
147
249.428

Temp.
CP
ST
(Hf-H2 98 )/T
-<GT-H2 98 )/T
J-mol"1 ^' 1 -
298.15
300
400
500
600
700
800
900
Melting T
100.15
100.22
104.26
108.30
112.34
116.38
120.42
124.46
149.20
149.82
179.20
202.90
223.01
240.63
256.43
270.85
826 K
0.00
0.62
26.02
42.07
53.45
62.15
69.18
75.10
A6
Log Kf
-132.7
-132.7
-133.3
-132.6
-131.5
-130.3
-129.0
-125.5
23.25
23.11
17.40
13.85
11.45
9.72
8.42
7.29
A H
kJ
149.20
149.20
153.18
160.83
169.56
178.48
187.25
195.75
-130.8
-130.8
-134.8
-137.2
-138.7
-139.3
-139.5
-245.5
Boiling T
kJ
kJ
Molar Vol
H2*98~H6
kJ
5.006 J*bar'!
50.06 cm3
2/17/93
148
Formula wt
Ag2S:
247.802
Monoclinic crystals 298.15 to 451.3 K; cubic crystals (argentite) 451.3 to 865 K.

y phase 865 to 1000 K. Reference state for sulfur is ideal S2 gas at p = 1 bar.

Temp.
cp
CO
ST
<H*-H298 )/T
-<Ofr.HS98 )/T
J-mol'^K'1 -
298.15
300
400
500
600
700
800
900
1000
75.31
75.39
80.47
87.26
86.03
84.80
84.69
80.38
80.57
142.89
143.35
165.67
193.79
209.59
222.75
234.05
244.84
253.28
0.00
0.46
19.78
41.08
48.67
53.91
57.75
61.53
63.38
A fG
Log Kf
-79.5
-79.4
-73.9
-69.2
-65.3
-61.6
-58.1
-54.7
-51.5
13.93
13.83
9.65
7.23
5.68
4.60
3.79
3.17
2.69
A fH
kJ- mol" 1
142.89
142.89
145.89
152.71
160.92
168.84
176.30
183.31
189.90
-96.3
-96.3
-95.3
-89.6
-88.1
-86.7
-85.7
-84.1
-83.8
Boiling T
Melting T
K
kJ
kJ
Molar Vol
H2*98~H8
17.132 kJ
A -8.355E+01
B* 3.273E-02
3.419 J-bar'1
34.19 cm3
O -5.14E+05
9/24/92
Formula wt
REALGAR
AsS:
149
106.988
Monoclinic crystals 298.15 to melting point 580 K; liquid 580 to 800 K.

Reference state for sulfur is ideal 82 gas at p = 1 bar.

Temp.
298.15
300
400
500
600
700
800
Melting T
CP
47.02
47.08
49.32
51.18
67.12
71.48
77.50
eo
om
63.50
63.80
77.68
88.88
110.35
121.00
130.90
/uo_uo
{iim **298 * /*!*
_//"*o_uo
\ /P
\^*T 298''
0.00
0.29
12.29
19.88
36.84
41.46
45.57
63.50
63.51
65.39
69.00
73.51
79.54
85.33
A H
A G
Log Kf
-95.2
-95.2
-94.5
-93.8
-86.0
-83.6
-80.7
-69.5
-69.3
-60.8
-52.4
-44.5
-37.7
-31.4
12.17
12.07
7.94
5.48
3.87
2.82
2.05
Boiling T
580 K
K
kJ
6.668 kJ
Molar Vol
H298~H5
kJ
-84.07
B= 0.06734
2.980 J-bar1
29.80 cm3
C -4.98E+05
3/25/9:!
150
Formula wt
GREENOCKITE
CdS:

bar.
144.477
Reference state for sulfur is ideal S2 gas at p = 1

Temp.
ST
i(Hf-H2 98 ,/T
.-!_-!
298.15
300
400
500
600
700
800
900
1000
1100
47.30
47.36
49.46
50.70
51.68
52.55
53.37
54.16
54.93
55.67
72.18
72.47
86.42
97.60
106.93
114.96
122.03
128.37
134.11
139.38
0.00
0.29
12.35
19.91
25.12
28.98
31.98
34.40
36.41
38.13
1r T
72.18
72.18
74.07
77.69
81.81
85.99
90.06
93.97
97.70
101.25
A6
Log Kf
-186.0
-185.8
-176.5
-167.4
-158.2
-148.2
-138.3
-128.4
-118.5
-102.9
32.58
32.35
23.05
17.48
13.78
11.06
9.03
7.45
6.19
4.89
AfH
-<GT-H2 98)/T
mol"1
-213.9
-213.9
-213.4
-212.8
-218.6
-218.1
-217.6
-217.1
-216.5
-314.8
Melting T
Boiling T
kJ
kJ
Molar Vol
H2*98~H5
8.81 kJ
-2.177E+02
B= 9.880E-02
2.993 J-bar'1
29.93 cm3
C= 2.109E+05
9/24/92
THERMOD YNAMIC PROPERTIES AT HIGH TEMPERATURE OF INDIVIDUAL PHASES
Formula wt
CATTIERITE
CoS2 :

1 bar.
151
123.065
Reference state for sulfur is ideal S2 gas at p -

Temp.
CP
ST
(HT-H 98 )/T
-<GT-H298 )/1
Jmol"~*K~* -
298.15
300
400
500
600
700
800
900
1000
68.26
68.39
74.28
78.63
82.38
85.85
89.16
92.38
95.55
74.80
75.22
95.76
112.82
127.50
140.46
152.14
162.83
172.72
0.00
0.42
18.20
29.87
38.31
44.86
50.19
54.70
58.63
A fG
Log Kf
-224.8
-224.5
-206.3
-188.5
-171.0
-153.8
-136.8
-120.0
-103.5
39.38
39.08
26.94
19.69
14.89
11.48
8.93
6.97
5.41
A fH
. . kJT mol" 1
74.80
74.80
77.56
82.96
89.18
95.60
101.95
108.13
114.10
Melting T
-279.5
-279.5
-278.2
-276.8
-275.1
-273.4
-271.9
-269.8
-267.7
Boiling T
kJ
kJ
Molar Vol
H598~H8
12.30 kJ
A -2.710E+02
B 1.682E-01
2.552 J-bar'1
25.52 cm3
O -3.57E+05
3/26/92
152
Formula wt
COVELLITE
CuS:

1 bar.
95.612
Reference state for sulfur is ideal 82 gas at p
Temp.
cP
sf
(Hf-H2 98 )/T
-(GT-H2* 98 )/T
A 6
Log Kf
-95.1
-95.0
-87.1
-79.4
-71.9
-64.6
-57.5
16.66
16.53
11.37
8.30
6.26
4.82
3.75
A fH
kJ-mol" 1
298.15
300
400
500
600
700
800
Melting T
47.53
47.59
50.29
52.62
54.82
56.94
59.03
67.40
67.69
81.77
93.24
103.03
111.64
119.38
0.00
0.29
12.47
20.27
25.84
30.14
33.62
67.40
67.40
69.30
72.98
77.19
81.51
85.77
-118.9
-118.9
-118.1
-117.3
-116.3
-115.2
-113.9
Boiling T
7801 K
K
kJ
kJ
Molar Vol
H298"H5
9.45 kJ
A -1.148E+02
B 7.208E-02
2.042 J-bar'1
20.42 cm3
O -1.60E+05
3/26/92
153
Formula wt
CHALCOCITE
Cu2 8:
159.158
Orthorhombic crystals 298.15 to 376 K; hexagonal crystals 376 to 710 K; cubic crystals
710 to melting point 1403 K. Reference state for sulfur is ideal S2 gas at p = 1 bar.

Temp.
CP
ST
(Hf-HJ98 )/T
-(OJ-HJ98 )/1
-1-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
Melting T
76.84
77.01
98.83
95.31
92.30
89.79
82.76
82.50
85.02
85.02
85.02
85.02
85.02
116.20
116.67
151.07
172.84
189.93
203.97
216.94
226.66
235.65
243.77
251.17
257.95
264.23
0.00
0.47
31.14
44.33
52.56
58.06
62.85
65.04
67.02
68.68
70.03
71.71
72.15
1> T
116.20
116.20
119.93
128.51
137.37
145.91
154.09
161.62
168.63
175.09
181.14
186.24
192.08
AfG
Log Kf
-129.1
-129.0
-123.0
-118.5
-114.5
-110.8
-107.6
-104.5
-101.5
-98.6
-95.7
-92.2
-89.2
22.61
22.45
16.06
12.38
9.97
8.27
7.02
6.06
5.30
4.68
4.17
3.71
3.33
A fH
-148.2
-148.2
-142.5
-139.7
-137.3
-135.3
-132.9
-132.1
-131.1
-130.3
-129.7
-128.7
-155.6
mol" 1
Boiling T
1403 K
K
kJ
kJ
Molar Vol.
H298~H8
15.80 kJ
A -1.304E+02
B- 2.957E-02
2.748 J'bar'1
27.48 cm3
0 -6.73E+05
01/13/9]
154
Formula wt
CHALCOPYRITE
CuFeS2 :
183.525
Tetragonal crystals 298.15 to 820 K; tetragonal crystals 820 to 930 K; cubic

crystals 930 to 1200 K. Reference state for sulfur is ideal S2 gas at p = 1 bar,
Above 820 K, phase is called ISS (intermediate solid solution).
Temp.
cp
ST
(Hf-H2 98 )/T
-(GT-H2 98 )/ T
Log Kf
-274.8
-274.5
-258.4
-242.8
-227.6
-212.7
-198.2
-185.0
-173.0
-161.5
-150.6
48.14
47.79
33.74
25.37
19.81
15.87
12.94
10.74
9.04
7.67
6.55
kJ-mol"1
K
298.15
300
400
500
600
700
800
900
1000
1100
1200
A fG
A fH
95.80
96.24
106.26
109.15
114.53
123.84
136.83
203.75
172.49
172.49
172.49
124.90
125.49
155.01
179.02
199.34
217.64
234.99
264.70
285.00
301.44
316.45
0.00
0.59
26.15
42.45
53.97
63.24
71.59
91.48
101.42
107.88
113.27
124.90
124.90
128.86
136.57
145.38
154.41
163.40
173.22
183.58
193.56
203.18
Melting T
-323.5
-323.5
-321.7
-319.8
-317.9
-315.6
-312.6
-298.0
-290.2
-285.3
-279.8
Boiling T
kJ
kJ
Molar Vol
H298"H8
18.34 kJ
A= -2.9995E+02
1.2712E-01
4.392 J'bar'1
43.92 cm3
O -1.19E+06
3/26/92
Formula wt
BORNITE
Cu5FeS4 :
155
501.841
Orthorhombic crystals 298.15 to 470 K; cubic crystals 470 to 535 K; cubic

crystals 535 to 1200 K. Reference state for sulfur is ideal $2 gas at p 1 bar.

Temp.
CP
ST
/tlO tjO
\ Iff
\tlrn **298 ' 1
-(Gf-H2 98 )/T
_1 _1
298.15
300
400
500
600
700
800
900
1000
1100
1200
242.90
243.20
260.60
369.45
327.89
323.50
325.20
327.30
332.90
340.00
348.30
398.50
400.00
472.40
549.41
615.63
665.90
709.20
747.53
782.29
814.34
844.27
0.00
1.50
64.09
121.22
161.33
184.73
202.19
215.89
227.29
237.21
246.12
1. T
398.50
398.50
408.31
428.19
454.30
481.17
507.01
531.64
555.00
577.13
598.15
A G
Log K
-554.1
-553.6
-529.1
-506.0
-485.9
-467.7
-450.6
-434.4
-419.1
-404.3
-390.1
97.07
96.39
69.09
52.86
42.30
34.90
29.42
25.21
21.89
19.20
16.98
A H
-628.8
-628.7
-625.3
-612.9
-600.0
-591.4
-583.4
-576.1
-569.5
-563.5
-556.7
mol" 1
Boiling T
Melting T
kJ
kJ
Molar Vol
H298~H8
53.01 kJ
-5.714B-t-02
B- 1.542E-01
9.873 J-bar'1
98.73 cm3
C= -2.625B+06
3/26/92
156
TROILITE
FeS:
Formula wt
87.913
Hexagonal crystals (NiAs structure) 298.15 to a complex transition at 411 K and a Neel
temperature at 590 K; paramagnetic 590 to melting point at 1468 K; liquid 1468 to 1800
K. Reference state for sulfur is ideal 82 gas at p = 1 bar.

Temp.
cp
o
ST
/ Hf-H5 98 )/T
(
-<G*-H298 >/1J
Melting T
50.49
50.64
70.02
72.06
67.33
58.13
57.73
58.65
60.64
62.00
62.99
63.99
64.99
71.13
71.13
71.13
71.13
60.30
60.62
76.87
102.86
116.98
126.32
134.00
140.86
147.13
152.82
158.17
163.32
168.22
194.95
199.51
203.82
207.88
0.00
0.31
14.44
34.29
41.52
44.23
45.90
47.27
48.49
49.52
50.52
51.56
52.60
75.20
74.94
74.72
74.52
Log Kf
-142.8
-142.6
-134.7
-128.1
-122.3
-116.8
-111.4
-106.0
-100.6
-95.0
-89.3
-83.7
-78.2
-73.4
-70.2
-67.1
-64.0
25.01
24.83
17.59
13.39
10.65
8.71
7.27
6.15
5.25
4.51
3.89
3.36
2.92
2.56
2.29
2.06
1.86
-1
J mol^-lT1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A 6
A fH
60.30
60.31
62.43
68.57
75.46
82.09
88.10
93.59
98.64
103.30
107.65
111.76
115.62
119.75
124.57
129.10
133.36
-166.9
-166.9
-165.5
-158.7
-155.8
-154.9
-154.5
-154.6
-155.3
-156.8
-157.5
-156.5
-155.3
-121.7
-120.3
-119.8
-119.0
Boiling T
1468 K
kJ
Av*H
A&.H 0
32. 34 kJ
Molar Vol.
H298~H8
18.20
9 .351 kJ
A- -1.488E+02
1.820
B* 4.910E-02
J-bar'1
cm3
O -8.05E+05
2/17/93
157
Formula wt
PYRRHOTITE
Fe .875S:
80.932
Monoclinic crystals 298.15 to combined structural and magnetic transition at 590

K; hexagonal crystal (NiAs-type) 590 to 1000 K. Reference state for sulfur is
ideal S2 gas at p 1 bar.
Temp.
cp
ST
/IlO_tlO
\ /IP
(HT-H298//
T
_/f O_tlQ
\ /IP
-(Gip-HJgsJ/T
J-mol'^-K"1
298.15
300
400
500
600
700
800
900
1000
49.88
50.01
56.24
63.56
67.35
65.30
57.42
57.19
58.38
60.70
60.70
76.28
89.57
104.51
114.53
122.64
129.39
135.46
0.00
0.31
13.53
22.76
32.47
37.37
40.28
42.17
43.71
A fG
Log Kf
-138.8
-138.5
-131.1
-124.0
-117.5
-111.2
-105.4
-99.6
-93.8
24.31
24.12
17.12
12.95
10.23
8.30
6.88
5.78
4.90
A HO
AfH
i, T mol"1
60.70
60.39
62.75
66.81
72.04
77.16
82.36
87.22
91.75
-161.8
-161.7
-160.4
-158.6
-155.0
-153.0
-151.9
-151.6
-151.9
Boiling T
Melting T
kJ
Molar Vol
H298"H8
9.21 kJ
A- -1.513E+02
B- 5.811E-02
1.749 J-bar'1
17.49 cm3
0 -4.30E+05
01/13/93
158
Formula wt
PYRITB
FeS2 :

1 bar.
119.979
Reference state for sulfur is ideal S2 gas at p
Temp.
fo
1ft
o
ST
/IH*-HJ 98) /T
-(GT-H2 98 )/T
A fG
Log Kf
-239.8
-239.4
-219.3
-199.3
-179.5
-159.8
-140.2
-120.6
-101.1
42.01
41.69
28.64
20.82
15.63
11.93
9.15
7.00
5.28
A H
kJ mol'1
298.15
300
400
500
600
700
800
900
1000
Melting T
62.17
62.39
69.15
71.95
73.93
75.90
78.10
80.57
83.29
52.90
53.29
72.34
88.10
101.39
112.94
123.21
132.55
141.18
0.00
0.38
16.88
27.64
35.20
40.87
45.38
49.15
52.43
52.90
52.90
55.45
60.45
66.20
72.07
77.83
83.40
88.75
10151 K
-300.1
-300.1
-299.5
-298.7
-298.0
-297.4
-297.0
-296.8
-297.1
Boiling T
K
kJ
kJ
Molar Vol
H298"H8
9.63 kJ
A= -2.967E+02
B= 1.958E-01
2.394 J-bar"1
23.94 cm3
C= -1.36E-05
9/25/92
Formula wt
MARCASITE

p 1 bar.
159
119.97$
Reference state for sulfur is ideal 82 gas a'

Temp.
CP
ST
(Hf-H298 ,/T
-(GT-H2 98 )/T
.-1-1
298.15
300
400
500
600
700
62.43
62.60
69.17
72.44
74.59
77.00
53.90
54.29
73.31
89.13
102.53
114.20
0.00
0.39
16.86
27.68
35.32
41.10
1. T
53.90
53.90
56.45
61.45
67.21
73.11
AG
Log Kf
-238.1
-237.7
-217.7
-197.8
-178.1
-158.5
41.71
41.39
28.42
20.66
15.50
11.83
A fH
-298.1
-298.1
-297.4
-296.6
-295.9
-295.2
mol'1
Boiling T
Melting T
kJ
Molar Vol
9.74 kJ
A- -2.952E+02
B= 1.955E-01
2.458 J'bar'1
24.58 cm3
O -1.08E-f05
9/25/92
160
Formula wt
HYDROGEN SULFIDE
Ideal gas at p 1 bar, 298.15 to 1800 K.

at p * 1 bar.
34.082
Reference state for sulfur L0 ideal S2 gas
Temp.
CP
**
(HT-H2 98 )/T
-(Gf-H2 98 )/T
A fH
J-mol"1 -^1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
34.20
34.21
35.48
37.22
39.05
40.85
42.58
44.21
45.72
47.13
48.41
49.58
50.62
51.55
52.35
53.04
53.60
205.80
206.01
216.01
224.11
231.05
237.21
242.78
247.89
252.63
257.05
261.21
265.13
268.84
272.37
275.72
278.92
281.96
Melting T
0.00
0.21
8.85
14.35
18.31
21.40
23.94
26.11
27.99
29.67
31.18
32.55
33.80
34.96
36.02
37.00
37.91
A G
IrT
205.80
205.80
207.15
209.76
212.74
215.81
218.83
221.78
224.63
227.38
230.03
232.58
235.04
237.41
239.70
241.91
244.06
mol"1
-73.3
-73.2
-69.1
-64.8
-60.3
-55.6
-50.8
-46.0
-41.1
-36.2
-31.3
-26.3
-21.4
-16.4
-11.5
-6.5
-1.6
-84.9
-84.9
-86.0
-87.0
-87.9
-88.7
-89.2
-89.7
-90.1
-90.4
-90.6
-90.7
-90.8
-90.8
-90.8
-90.8
-90.7
12.84
12.75
9.03
6.77
5.25
4.15
3.32
2.67
2.15
1.72
1.36
1.06
0.80
0.57
0.37
0.20
0.05
K
Boiling T
Log Kf
kJ
kJ
Molar Vol.
H298"H8
9.96
kJ
A -9.067E+01
B= 4.942E-02
2478.97
24789.7
Jbar'1
cm3
O 2.447E+05
3/26/92
Formula wt
ALABANDITE
MnS:

bar.
87.004
Temp.
CP
CO
ST
(HT-H2 98 )/T
1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
49.98
49.99
51.10
52.14
52.83
53.25
53.55
53.84
54.21
54.73
55.44
56.39
57.60
59.10
60.91
63.04
65.51
80.30
80.61
95.13
106.65
116.22
124.40
131.53
137.85
143.55
148.74
153.53
158.00
162.22
166.24
170.11
173.87
177.54
0.00
0.31
12.86
20.62
25.93
29.81
32.76
35.08
36.98
38.56
39.94
41.17
42.30
43.36
44.40
45.43
46.48
-(Gf-H| 98 )/T
A G
A fH
kJ*mol -1
_1
80.30
80.30
82.27
86.04
90.29
94.59
98.78
102.77
106.57
110.17
113.59
116.83
119.93
122.88
125.71
128.43
131.06
-258.6
-258.5
-252.0
-245.7
-239.4
-231.3
-227.1
-220.9
-214.7
-208.3
-201.9
-195.5
-188.9
-182.2
-174.7
-167.0
-159.4
-278.2
-278.2
-277.5
-277.0
-276.6
-276.4
-276.3
-276.3
-278.7
-278.9
-279.1
-279.3
-281.7
-284.2
-296.9
-297.3
-297.4
kJ
kJ
Molar Vol.
HJ98-H8
45.30
45.00
32.91
25.66
20.84
17.41
14.83
12.82
11.22
9.89
8.79
7.85
7.05
6.34
5.70
5.13
4.62
Boiling T
ApH
Afo.H0
Log Kf
kJ
A- -2 . 807E+02
B* 6.621E-02
2.146
21.46
J*bar*
cm3
0 2. 459E+05
3/26/92
162
Formula wt
MOLYBDENITE
MoS2 :

p = 1 bar.
160.072
Reference state for sulfur is ideal S
gas at
Temp.
Sf
(Hf-H2 98 )/T
T- ~l
298.15
300
400
500
600
700
800
900
1000
1100
1200
Melting T
63.51
63.63
68.45
71.58
73.77
75.35
76.54
77.44
78.12
78.65
79.04
62.60
62.99
82.01
97.65
110.90
122.40
132.54
141.61
149.81
157.28
164.14
-(GT-H2 98 )/T
l_r 1
0.00
0.39
16.85
27.50
35.04
40.69
45.10
48.65
51.56
54.00
56.07
1, T.._1
62.60
62.60
65.16
70.14
75.86
81.70
87.44
92.96
98.24
103.28
108.07
A fG
Log K
-342.5
-342.1
-322.8
-303.8
-284.9
-266.3
-247.8
-229.5
-211.3
-193.2
-175.3
60.00
59.57
42.16
31.73
24.80
19.87
16.18
13.32
11.04
9.17
7.63
A fH
-400.4
-400.4
-399.6
-398.5
-397.4
-396.2
-395.0
-393.7
-392.5
-391.3
-390.1
Boiling T
kJ
kJ
Molar Vol
8.818 kJ
A= -3.933E+02
B 1.822E-01
3.202
32.02
J-bar'1
cm3
C -3.21E+05
3/26/92
Formula wt
MILLERITE
NiS:
163
90.756
Rhombohedral crystals 298.15 to 623 K; hexagonal crystals 623 to melting point

at 1066 K. Reference state for sulfur is ideal $2 gas at p * 1 bar.
Temp.
CP
CO
ST
(HT-H298 )/T
__1
298.15
300
400
500
600
700
800
900
1000
1100
Melting T
47.11
47.24
50.79
53.68
56.27
59.45
62.55
65.65
68.74
71.13
52.97
53.26
67.36
79.04
89.04
102.68
110.79
118.37
125.44
159.58
0.00
0.29
12.55
20.42
26.22
34.91
38.18
41.05
43.68
72.73
-(GT-H298 )/T
AfG
Log Kf
-128.2
-128.0
-119.0
-110.1
-101.3
-93.0
-85.4
-77.0
-69.2
-62.5
22.45
22.29
15.53
11.50
8.82
6.94
5.57
4.47
3.61
2.97
A fH
-1
kJ ,__i 1
52.97
52.97
54.81
58.62
62.82
67.77
72.61
77.32
81.76
86.85
-155.3
-155.3
-154.8
-154.2
-153.8
-150.2
-149.0
-147.6
-145.9
-114.7
Boiling T
1066 K
K
kJ
kJ
Molar Vol
H298"H8
53.01 kJ
A* -1.434E+02
7.351E-02
1.689 J-bar'1
16.89 cm3
O -6.29B+05
4/1/92^
164
Formula wt
HEAZLEWOODITE
Ni3S2 :
240.202
Hexagonal crystals 298.15 to 834 K; cubic crystals 834 K to incongruent melting

point 1064 K; liquid 1064 to 1400 K. Reference state for sulfur is ideal S2 gas at
p = 1 bar.
Temp.
CP
**
<H*-H298) /T
-<Gf-H2 98 )/T
A fG
Log Kf
-289.9
-289.5
-271.2
-253.1
-235.2
-217.3
-201.1
-187.1
-177.3
-168.7
-161.7
-155.1
-148.9
50.78
50.41
35.41
26.44
20.47
16.22
13.13
10.86
9.26
8.01
7.04
6.23
5.56
A fH
mol' 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
Melting T
118.24
118.45
129.01
136.05
141.59
148.35
158.39
189.15
191.81
189.12
189.12
189.12
189.12
133.20
133.93
169.52
199.12
224.42
246.72
267.14
355.52
375.52
411.84
428.28
443.42
457.44
0.00
0.73
31.54
51.79
66.29
77.51
86.95
159.38
162.41
182.56
183.11
183.57
183.97
133.20
133.20
137.98
147.34
158.12
169.22
180.20
196.14
213.11
229.28
245.17
259.85
273.47
1064 K
-344.9
-344.9
-344.0
-343.0
-342.5
-341.7
-339.3
-278.4
-272.8
-247.9
-242.7
-237.9
-233.3
Boiling T
kJ
19.66 kJ
Molar Vol
H298~H8
21.501 kJ
-2.815E+02
B 1.016E-01
4.095 J'bar'1
40.95 cm3
O -3.71B+06
4/1/92
Formula wt
GALENA
PbS:

bar.
165
239.266
Reference state for sulfur is ideal S2 gas at p = 1

Temp.
cp
ST
i\ **fp""**l*S Qfl / / *
1 * IDOl
298.15
300
400
500
600
700
800
900
Melting T
49.49
49.52
51.16
52.80
54.44
56.08
57.72
59.36
91.70
92.01
106.48
118.07
127.84
136.36
143.95
150.84
*K
0.00
0.31
12.81
20.65
26.14
30.30
33.63
36.40
-(GT-H2 98 )/1
A fG
Log K
-136.6
-136.4
-127.8
-119.4
-111.0
-102.0
-93.1
-84.3
23.93
23.76
16.69
12.47
9.67
7.61
6.08
4.90
A fH
kJ mol" 1
91.70
91.70
93.66
97.42
101.70
106.05
110.32
114.45
-162.6
-162.6
-161.9
-161.3
-160.6
-164.8
-163.9
-162.9
Boiling
1400 K
K
kJ
kJ
Molar Vol.
A* -1.640E+02
B- 8.830E-02
3.149 J-bar'1
31.49 cm3
0 9.946E+04
9/25/92
166
Formula wt
STIBNITE

at p * 1 bar.
339.698
Reference state for sulfur is ideal 82 gas
CP
Temp.
CO
ST
(HT-H2 98 )/T
-(GT-H2 98 )/T
298.15
300
400
500
600
700
800
900
119.75
119.81
123.38
126.46
128.94
130.92
132.51
133.80
Melting T
182.00
182.74
217.70
245.58
268.86
288.89
306.48
322.17
0.00
0.74
30.96
49.76
62.76
72.36
79.78
85.72
Log Kf
-269.4
-269.8
-244.1
-219.8
-195.9
-172.4
-149.2
-126.2
47.19
46.82
31.88
22.96
17.06
12.87
9.74
7.33
kJ mol' 1
J-mol" 1 -*"1 -
A 6
A fH
182.00
182.00
186.74
195.82
206.10
216.53
226.70
236.45
-344.3
-344.3
-342.2
-340.1
-338.0
-335.9
-334.0
-332.2
Boiling T
829 K
K
kJ
kJ
Molar Vol
H2*98~H6
kJ
A = -3.338E+02
B - 2.315E-01
7.341 J-bar'1
73.41 cm3
C - -4.19E+05
4/1/92
Formula wt
HERZENBERGITE
SnS:
167
150.776
Orthorhombic crystals 298.15 to 875 R; cubic crystals 875 to melting point 1153 K.
Liquid 1153 to 1300 R. Reference state for sulfur is ideal S2 gas at p 1 bar.

Temp.
CP
o
ST
Melting T
/T
-(GT-H2 98 )/T
A fH
j mol" 1 ^ -1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
/
I
49.25
49.32
50.89
52.03
54.52
58.41
63.50
54.04
57.07
60.11
75.61
75.61
77.00
77.30
91.76
103.22
112.91
121.50
129.71
137.47
143.32
148.90
181.98
188.03
0.00
0.30
12.81
20.52
25.96
30.30
34.12
37.81
39.59
41.32
69.64
70.10
1-T-
77.00
77.00
78.96
82.70
86.95
91.20
95.59
99.66
103.73
107.58
112.34
117.93
-170.8
-170.8
-170.2
-169.8
-176.4
-175.4
-173.9
-171.8
-170.9
-169.7
-136.3
-133.5
AfG
Log Rf
-144.5
-144.3
-135.6
-127.0
-117.1
-107.3
-97.7
-88.1
-78.9
-69.7
-62.0
-55.9
25.31
25.13
17.71
13.26
10.19
8.00
1-1
Boiling T
1153 R
H298~H5
kJ
A* -1.696E+02
B* 8. 9 4 IE-02
5.11
4.12
3.31
2.70
2.25
kJ
31 .59 kJ
Molar Vol.
Â
wo
Av*H
AHH O
2.901
29.01
J-bar'1
cm3
0 -1.74E+05
4/1/92
168
Formula wt
BERNDTITE
SnS2 :

p = 1 bar.
182.842
Reference state for sulfur is ideal S2 gas at

Temp.
CP
Sf
(HT-H2 98 )/T
-(GT-H2 98 )/T
-1-1
298.15
300
400
500
600
700
800
900
1000
Melting T
70.12
70.17
72.05
73.52
75.19
77.13
79.33
81.74
84.33
87.50
87.93
108.41
124.64
138.19
149.92
160.36
169.84
178.59
0.00
0.43
18.13
29.06
36.60
42.25
46.75
50.50
53.75
1. T
87.50
87.50
90.28
95.58
101.59
107.67
113.61
119.34
124.84
A fG
Log K
-221.2
-220.8
-201.8
-183.0
-163.1
-143.2
-123.5
-104.0
-84.7
38.75
38.45
26.35
19.12
14.19
10.69
8.06
6.04
4.42
A fH
-278.4
-278.4
-277.4
-276.6
-282.8
-281.6
-280.2
-278.6
-276.9
mol"1
Boiling T
K
kJ
kJ
Molar Vol
H2*98"H5
kJ
A- -2.818E+02
1.973E-01
4.096 J-bar'1
40.96 cm3
C= 1.613E+05
4/1/92
Formula wt
TUNGSTENITE
WS2 :

1 bar.
169
247.982

Temp.
CP
ST
(HT-H$ 98 )/T
-,G5-HJ 98 )/1
-1-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
Melting T
63.83
63.99
69.67
72.41
74.01
75.09
75.90
76.57
77.16
77.71
78.24
78.76
79.29
79.83
67.80
68.20
87.50
103.37
116.72
128.22
138.30
147.28
155.38
162.76
169.54
175.82
181.68
187.17
0.00
0.39
17.10
27.92
35.48
41.06
45.37
48.80
51.61
53.95
55.96
57.69
59.21
60.57
A fG
Log Kf
-312.7
-312.3
-293.1
-274.2
-255.6
-237.1
-218.8
-200.7
-182.7
-164.9
-147.1
-129.5
-111.9
-94.5
54.77
54.37
38.28
28.65
22.25
17.69
14.29
11.65
9.54
7.83
6.40
5.20
4.18
3.29
A fH
kJ mol" 1
67.80
67.80
70.39
75.45
81.25
87.15
92.93
98.48
103.77
108.80
113.58
118.13
122.47
126.60
-370.2
-370.2
-369.3
-368.1
-366.9
-365.6
-364.4
-363.1
-361.9
-360.6
-359.4
-358.2
-357.0
-355.8
Boiling T
239.1
A^0
20.41
K
kJ
kJ
Molar Vol.
H298~H5
11.01 kJ
A* -3.610E+02
B= 1.782E-01
3.207
32.07
J-bar'1
cm3
C -4.51E+05
4/l/d2
170
Formula wt
SPHALERITE
ZnS:
97.456
Cubic crystals to 1300 K. Wurtzite is the stable form of ZnS above 1300 K.
Reference state for sulfur is ideal S2 gas at p 1 bar.

Temp.
cp
ST
(HT-H$ 98 )/T
-(GT-H2 98 )/T
45.76
45.82
48.30
49.93
51.12
52.04
52.79
53.42
53.96
54.43
54.85
55.23
58.70
58.98
72.53
83.50
92.71
100.66
107.66
113.92
119.57
124.74
129.49
133.90
0.00
0.28
12.00
19.43
24.62
28.47
31.47
33.87
35.85
37.52
38.95
40.19
Log Kf
-239.5
-239.3
-229.7
-220.2
-210.7
-201.3
-191.0
-180.7
-170.4
-160.2
-148.1
-128.2
41.95
41.66
29.99
23.00
18.35
15.02
12.47
10.49
8.90
7.61
6.45
5.15
kJ mol"1
J-mol" 1 ^" 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
A fG
A fH
58.70
58.70
60.53
64.06
68.09
72.19
76.19
80.04
83.72
87.22
90.54
93.71
Melting T
-268.4
-268.4
-267.9
-267.4
-266.9
-273.8
-273.5
-273.2
-272.8
-272.4
-387.1
-385.6
Boiling T
kJ
kJ
Molar Vol
H298~H8
8.82 kJ
A* -2.821E+02
B- 1.131E-01
2.383 J'bar'1
23.83 cm3
0 8.609E+05
01/06/93
Formula wt
WURTZITE
ZnS:

1 bar.
97.456

Temp.
cp
ST
/UO _U O
\ T
\ /T
-(GT-H$ 98 )/T
298 '
Jmol~*K~* -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
Melting T
45.89
45.96
48.72
50.13
51.09
51.86
52.55
53.21
53.86
54.50
55.15
55.80
58.80
59.08
72.74
83.77
93.00
100.94
107.91
114.13
119.77
124.94
129.71
134.15
0.00
0.28
12.09
19.57
24.75
28.57
31.52
33.90
35.86
37.52
38.97
40.24
kJ
58.80
58.80
60.64
64.20
68.25
72.37
76.38
80.24
83.91
87.41
90.74
93.91
AfG
Log Kf
-239.2
-239.0
-229.4
-219.9
-210.5
-201.2
-190.9
-180.6
-170.3
-160.1
-148.0
-128.2
41.91
41.62
29.96
22.97
18.33
15.01
12.46
10.48
8.90
7.60
6.44
5.15
A H
mol"1
-268.1
-268.1
-267.6
-267.1
-266.6
-273.5
-273.2
-272.9
-272.5
-272.1
-386.8
-385.2
Boiling T
A^0
kJ
Molar Vol.
H298"H5
8.85 kJ
A= -2.8172E+02
B- 1.1284E-01
K
kJ
2.385 J-bar i
23.85 cm3
C- 8.613E+06
01/06/93
172
Formula wt
BERTHIERITE

at p = 1 bar.
427.611
Reference state for sulfur is ideal 82 gas

Temp.
cp
CO
ST
(HT-H2 98 )/T
-(GT-H2 98 )/T
J-mol'^K"" 1 -
298.15
300
400
500
600
700
800
900
Melting T
175.23
175.60
186.17
189.05
190.44
191.92
193.91
196.48
245.00
246.09
298.40
340.31
374.90
404.37
430.12
453.10
0.00
1.08
46.33
74.64
93.83
107.73
118.37
126.91
kJ*mQ i
245.00
245.00
252.06
265.67
281.07
296.63
311.74
326.20
A fG
Log Kf
-415.2
-414.6
-382.2
-350.8
-320.1
-290.0
-260.3
-230.9
72.75
72.18
49.91
36.65
27.87
21.64
17.00
13.40
A fH
-513.4
-513.3
-509.5
-505.8
-502.3
-499.2
-496.6
-494.4
Boiling T
kJ
kJ
Molar Vol
kJ
A- -4.957E+02
B- 2.954E-01
9.222
92.22
J'bar'
cm3
0 -6.84E+05
2/17/93
Formula wt
CHALCOSTIBITE

at p = 1 bar.
173
249.428
Reference state for sulfur is ideal $2 gas
Temp,
CP
ST
J-mol" 1 ^' 1
K
298.15
300
400
500
600
700
800
900
Melting T
100.15
100.22
104.26
108.30
112.34
116.38
120.42
124.46
149.20
149.82
179.20
202.90
223.01
240.63
256.43
270.85
0.00
0.62
26.02
42.07
53.45
62.15
69.18
75.10
A fG
Log Kf
-212.4
-212.1
-196.6
-181.6
-167.0
-152.9
-139.0
-125.5
37.21
36.93
25.68
18.97
14.54
11.41
9.08
7.29
A fH
(HT-H$ 98 )/T
kJ*mol
149.20
149.20
153.18
160.83
169.56
178.48
187.25
195.75
-259.4
-259.4
-257.5
-255.5
-253.3
-250.9
-248.3
-245.5
"1
Boiling T
826 K
K
kJ
AK..H'
kJ
Molar Vol
kJ
A= -2.486E+02
B= 1.377E-01
5.006 J-bar
50.06 cm3
C -4.38E+05
2/17/9J3
174
Formula wt
CORUNDUM
A123 :
101.961
Rhombohedral crystals 298.15 to 1800 K.
Temp.
ST
CP
Melting T
-<GT-H298 )/'r
79.10
79.53
96.45
106.04
112.31
116.79
120.19
122.88
125.08
126.93
128.52
129.91
131.13
132.23
133.23
134.14
134.99
50.92
51.41
76.87
99.51
119.43
137.10
152.93
167.24
180.31
192.32
203.43
213.78
223.45
232.53
241.10
249.21
256.90
0.00
0.49
22.60
38.40
50.23
59.43
66.82
72.91
78.02
82.38
86.16
89.48
92.41
95.03
97.39
99.52
101.47
A fG
Log Kf
-1582.3
-1581.7
-1550.2
-1518.7
-1487.3
-1456.1
-1424.9
-1393.9
-1361.5
-1328.3
-1295.3
-1262.3
-1229. 5
-1196.8
-1164.1
-1131.5
-1099.0
277.20
275.39
202.43
158.66
129.48
108.65
93.04
80.90
71.12
63.08
56.38
50.72
45.87
41.67
38.00
34.77
31.89
AfH
_1
J-mol'1 ^" 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
<HT-H298 )/T
50.92
50.92
54.28
61.11
69.21
77.67
86.10
94.34
102.29
109.93
117.27
124.30
131.04
137.51
143.72
149.68
155.43
2345 K
-1675.7
-1675.7
-1676.3
-1676.0
-1675.3
-1674.4
-1673.5
-1672.7
-1693.4
-1692.3
-1691.2
-1690.0
-1688.8
-1687.4
-1686.0
-1684.5
-1683.0
Boiling T
kJ
kJ
Molar Vol.
H2*98~H6
10.016 kJ
A- -1.686E+03
B* 3.257E-01
2.558 J-bar1
25.58 cm3
C- 6.538E+05
4/4/92
Formula wt
BOEHMITE
AIO(OH):
175
59.988

Temp.
ST
298.15
300
400
500
600
(HT-H298 )/T
-(GT-H298 )/T
A H
J-mol"1 ^" 1
54.24
54.50
66.40
74.51
80.03
37.20
37.54
54.95
70.70
84.80
Melting T
0.00
0.34
15.46
26.51
35.00
A 6
Log Kf
-918.4
-917.9
-891.6
-865.2
-838.8
160.90
159.82
116.43
90.38
73.02
kJ-mol" 1
37.20
37.20
39.49
44.19
49.80
-996.4
-996.4
-997.3
-997.3
-997.0
Boiling T
A^0
A^H0
kJ
kJ
Molar Vol.
H298~H5
8.83 kJ
A~ -9.976E+02
B 2.646E-01
1.954 J-bar'1
19.54 cm3
C 2.644E+04
8/27/92
176
Formula wt
DIBORON TRIOXIDE
B23 :
69.620
Hexagonal crystals 298.15 to melting point 723 K.

Temp.
ST
CP
Melting T
Afc.H0
-<6T-H 98 )/T
62.60
62.93
54.00
54.39
74.68
93.37
110.46
126.13
175.88
191.16
204.83
217.19
228.47
238.86
248.47
257.42
265.79
273.65
281.06
78.07
89.31
98.08
105.19
129.70
129.70
129.70
129.70
129.70
129.70
129.70
129.70
129.70
129.70
129.70
723
0.00
1. T.
54.00
54.00
56.67
62.17
68.81
75.90
86.33
97.14
107.25
116.68
125.53
133.86
141.71
149.13
156.16
162.84
169.20
0.39
18.02
31.20
41.65
50.23
89.55
94.02
97.58
100.51
102.94
105.00
106.76
108.29
109.63
110.81
111.86
AfG
Log Kf
-1194.4
-1193.9
-1167.3
-1140.8
-1114.3
-1088.0
-1064.5
-1042.1
-1020.1
-998.4
-976.9
-955.6
-934.5
-913.5
-892.6
-871.9
-851.2
209.24
207.87
152.43
119.17
97.01
81.19
69.50
60.48
53.28
47.41
42.52
38.39
34.86
31.81
29.14
26.79
24.70
A H
J-mol'^K"1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
<HT-H$ 98 )/T
ntol"1
-1273.5
-1273.5
-1273.6
-1273.3
-1272.6
-1271.6
-1244.7
-1241.6
-1238.7
-1236.1
-1233.6
-1231.3
-1229.2
-1227.1
-1225.2
-1223.5
-1221.8
Boiling T
kJ
24. 07 kJ
Molar Vol.
H298-H8
9.30 kJ
A* -1.240E+03
2.148E-01
2 .722 J-bar'1
27 .22 cm3
C -2. 28E+06
9/9/92
177
Formula wt
BARIUM MONOXIDE
BaO:
153.326

Temp.
CP
CO
ST
(HT-H$ 98 )/T
-(Gf-H2 98 )/T
Melting T
47.28
47.35
49.98
51.78
53.17
54.33
55.36
56.29
57.15
57.96
58.73
59.48
60.19
60.89
61.58
62.25
62.90
72.07
72.36
86.37
97.73
107.30
115.58
122.91
129.48
135.46
140.94
146.02
150.75
155.18
159.36
163.31
167.07
170.64
0.00
0.29
12.41
20.11
25.51
29.55
32.71
35.28
37.42
39.25
40.85
42.25
43.51
44.64
45.68
46.63
47.52
Log Kf
-520.4
-520.2
-511.0
-501.8
-492.5
-483.1
-473.6
-464.1
-454.6
-444.3
-434.0
-423.7
-413.4
-403.1
-392.9
-382.6
-372.4
91.17
90.58
66.73
52.42
42.87
36.05
30.92
26.94
23.75
21.10
18.89
17.02
15.42
14.04
12.83
11.76
10.81
-1
J-mol'^KT 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A fG-
A fH
72.07
72.07
73.96
77.62
81.79
86.04
90.20
94.20
98.03
101.69
105.17
108.50
111.68
114.72
117.63
120.43
123.12
-548.1
-548.1
-547.7
-548.0
-548.9
-549.0
-549.5
-549.5
-549.5
-557.8
-557.8
-557.8
-557.6
-557.2
-556.8
-556.3
-555.8
Boiling T
2286 K
kJ
kJ
Molar Vol.
9.98 kJ
- -5.518E+02
B= 9.893E-02
2.559 J-bar"
25.59 cm3
C 2.781E-01
8/27/92
178
Formula wt
BROMELLITE
BeO:
25.012

Temp.
CP
ST
(HJ-H298 )/T
-<Gf-H2 98 )/T
Melting T
25.56
25.76
33.93
38.90
42.28
44.73
46.61
48.09
49.30
50.31
51.18
51.94
52.62
53.24
53.82
54.37
54.90
13.77
13.93
22.57
30.71
38.12
44.83
50.93
56.51
61.64
66.39
70.81
74.93
78.81
82.46
85.91
89.19
92.32
0.00
0.16
7.68
13.46
18.00
21.65
24.66
27.18
29.33
31.20
32.83
34.27
35.55
36.71
37.77
38.73
39.61
Log Kf
-580.1
-579.9
-570.0
-560.1
-550.2
-540.4
-530.6
-520.9
-511.2
-501.6
-492.0
-482.4
-472.9
-463.4
-453.5
-443.1
-432.7
101.63
100.97
74.44
58.51
47.90
40.32
34.64
30.23
26.70
23.82
21.41
19.38
17.64
16.14
14.80
13.61
12.56
mol" 1
J-mol^-K" 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A 6
A fH
13.77
13.77
14.89
17.25
20.12
23.18
26.28
29.33
32.31
35.19
37.98
40.66
43.25
45.75
48.15
50.47
52.71
-609.4
-609.4
-609.7
-609.6
-609.4
-609.0
-608.6
-608.2
-607.7
-607.3
-606.9
-606.6
-606.3
-606.0
-620.3
-619.7
-619.1
Boiling T
2681 K
K
kJ
kJ
Molar Vol
H298~H6
2.88 kJ
-6.089E+02
B= 9.754E-02
0.8309 J-bar'
8.309 cm3
O -4.08E-02
8/27/92
Formula wt
BISMITE
Bi2O3 :
179
465 .959
Monoclinic crystals 298.15 to melting point 1098 K.
Temp.
ST
(Hf-H2 98 )/T
T-
298.15
300
400
500
600
700
800
900
1000
Melting T
113.55
113.61
116.94
120.28
123.62
126.95
130.29
133.62
136.96
151.50
152.20
185.34
211.80
234.02
253.33
270.50
286.03
300.29
.1
-(GT-H$ 98 )/T
1.*-
l-*r 1
0.00
0.70
29.34
47.20
59.66
69.03
76.48
82.64
87.91
151.50
151.50
156.00
164.60
174.36
184.30
194.02
203.39
212.38
A fG
Log Kf
-493.5
-493.0
-466.3
-440.1
-411.9
-382.2
-352.7
-323.5
-294.7
86.45
85.83
60.89
45.98
35.86
28.52
23.03
18.78
15.39
A fH
-573.9
-573.9
-572.0
-570.2
-591.3
-589.5
-587.3
-584.7
-581.9
> 1
Boiling T
1098 K
kJ
kJ
Molar Vol
H2*98~H8
kJ
A= -5.909E+02
B= 2.957E-01
4.973
49.73
J-barf1
cm3
O 8.426E+05
8/27/9J
180
Formula wt
CARBON MONOXIDE
CO:
28.010
Ideal gas at p = 1 bar, 298.15 to 2200 K.
Temp.
ST
CP
W O M1J
5 OQ
. j\ I/ *F
\/ um
*lo
A
-<H-HS9e) /i!
29.14
29.13
29.15
29.79
30.55
31.29
31.97
32.58
33.14
33.64
34.09
34.50
34.86
35.18
35.47
35.72
35.94
Melting T
197.27
197.45
205.80
212.37
217.87
222.64
226.86
230.66
234.12
237.31
240.25
243.00
245.57
247.98
250.26
252.42
254.47
0.00
0.18
7.39
11.81
14.87
17.16
18.97
20.45
21.69
22.75
23.68
24.50
25.22
25.88
26.47
27.01
27.50
Log Kf
-137.1
-137.2
-146.2
-155.2
-164.2
-173.2
-182.2
-191.0
-199.9
-208.6
-217.3
-226.0
-234.6
-243.1
-251.6
-260.1
-268.5
24.01
23.89
19.09
16.22
14.30
12.93
11.89
11.09
10.44
9.91
9.46
9.08
8.75
8.47
8.21
7.99
7.79
-1
J-mol'^K'1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A 6
A fH
197.27
197.27
198.41
200.57
203.00
205.48
207.89
210.21
212.43
214.55
216.57
218.50
220.34
222.11
223.80
225.42
226.97
-110.5
-110.5
-110.1
-110.0
-110.2
-110.5
-110.9
-111.4
-112.0
-112.6
-113.2
-113.9
-114.6
-115.3
-116.0
-116.7
-117.4
Boiling T
68.05 K
ApH
Afc.H 0
kJ
0. 837 kJ
Molar Vol.
H298-H6
8.67
kJ
-1.131E+02
B= -8.667E-02
2478. 97 J-bar*1
24789. 7 cm3
C= 1.858E+05
4/4/92
Formula wt
CARBON DIOXIDE
CO2 :
181
44.010
Ideal gas at p = 1 bar, 298.15 to 2200 K.
Temp.
CP
CO
ST
(HT-H| 98 )/T
-(Gf-H, 98 )/T
Melting T
37.12
37.20
41.20
44.62
47.39
49.64
51.48
53.01
54.29
55.38
56.31
57.10
57.79
58.38
58.90
59.35
59.74
213.79
214.02
225.28
234.85
243.24
250.72
257.47
263.63
269.28
274.51
279.37
283.90
288.16
292.17
295.95
299.54
302.94
Log Kf
-394.4
-394.4
-394.7
-394.9
-395.2
-395.4
-395.6
-395.7
-395.9
-396.0
-396.1
-396.1
-396.2
-396.3
-396.3
-396.3
-396.3
69.09
68.67
51.54
41.26
34.40
29.50
25.83
22.97
20.68
18.80
17.24
15.92
14.78
13.80
12.94
12.18
11.50
J-mol'^K' 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A 6
A fH
0.00
0.23
9.98
16.58
21.49
25.36
28.51
31.15
33.40
35.35
37.06
38.57
39.92
41.13
42.23
43.22
44.13
213.79
213.79
215.30
218.28
221.75
225.37
228.96
232.48
235.88
239.16
242.31
245.34
248.25
251.04
253.73
256.32
258.82
-393.5
-393.5
-393.6
-393.7
-393.8
-394.0
-394.2
-394.4
-394.6
-394.8
-395.0
-395.2
-395.5
-395.7
-395.9
-396.1
-396.3
Boiling T
A**H
AfcjH0
kJ
kJ
Molar Vol.
H2*98~H5
9.36 kJ
A -3.944E+02
-1.248E-03
2478 .97 J-bar'1

24789 .7 cm3
C= 5.480E-02
12/17/91
182
LIME
CaO:
Formula wt
56.077
Temp.
ST
(H*-HS98 )/T
j.
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
42.07
42.21
46.99
49.34
50.72
51.65
52.35
52.90
53.36
53.77
54.13
54.47
54.80
55.10
55.40
55.68
55.96
38.10
38.36
51.25
62.01
71.14
79.03
85.98
92.18
97.78
102.88
107.58
111.92
115.97
119.76
123.33
126.69
129.88
-<GT-H2 98 )/T
1-1. K-l
0.00
0.26
11.43
18.80
24.01
27.90
30.91
33.32
35.31
36.97
38.38
39.61
40.68
41.63
42.48
43.25
43.95
IrT
38.10
38.10
39.83
43.22
47.13
51.14
55.07
58.85
62.47
65.91
69.19
72.32
75.29
78.13
80.84
83.44
85.94
A fG
Log Kf
-603.1
-602.9
-592.2
-581.6
-571.2
-560.8
-550.3
-539.9
-529.4
-518.9
-507.7
-496.4
-485 . 1
-473.8
-462.6
-451.3
-437.9
105.66
104.97
77.33
60.76
49.72
41.84
35.93
31.33
27.65
24.64
22.10
19.95
18.10
16.50
15.10
13.87
12.71
A fH
-635.1
-635.1
-634.7
-634.2
-633.7
-633.4
-634.0
-634.0
-634.2
-634.7
-643.3
-643.1
-643.0
-642.8
-642.6
-642.4
-790.9
mol'1
Boiling T
3200 K
K
kJ
kJ
Molar Vol.
6.75 kJ
* -6.395E+02
B= 1.105E-01
1.676 J-bar1
16.76 cm3
C= 3.497E+05
8/27/92
Formula wt
PORTLANDITE
Ca(OH) 2 :
183
74.093

Temp.
CP
ST
<Hf-H2 98 )/T
-<GT-H2 98 )/T
J-mol""1 *^1 -
298.15
300
400
500
600
700
87.51
87.75
97.94
104.19
108.23
110.89
83.40
83.94
110.71
133.29
152.67
169.57
0.00
0.54
23.73
39.24
50.43
58.89
1. T
83.40
83.40
86.98
94.05
102.24
110.68
Melting T
A fG
Log Kf
-898.0
-897.5
-868.1
-838.9
-810.1
-781.5
157.33
156.27
113.36
87.64
70.52
58.32
A fH
-986.1
-986.1
-985.3
-983.9
-982.3
-980.7
mol'1
Boiling T
kJ
kJ
Molar Vol
14.16 kJ
A= -9.810E+02
B= 2.857E-01
3.306 J-bar'1
33.06 cm3
-1.98E-I-05
4/8/92
184
Formula wt
CERIANITE
CeO2 :
172.114

Temp.
CP
eo
ST
<HT-H2 98 )/T
1""1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
61.63
61.78
67.52
70.83
73.11
74.86
76.29
77.52
78.62
79.63
80.56
81.45
82.29
83.09
83.88
84.64
85.38
62.30
62.68
81.33
96.78
109.91
121.31
131.40
140.46
148.69
156.23
163.20
169.68
175.75
181.45
186.84
191.95
196.81
0.00
0.38
16.52
27.08
34.57
40.21
44.63
48.22
51.20
53.74
55.94
57.87
59.58
61.12
62.52
63.80
64.98
-<Gf-H2 98 )/T
"*1
kJ
62.30
62.30
64.80
69.70
75.33
81.11
86.77
92.25
97.48
102.49
107.26
111.81
116.17
120.33
124.32
128.15
131.83
A fG
Log Kf
-1024.6
-1024.2
-1002.9
-981.7
-960.7
-940.0
-919.3
-898.7
-878.3
-857.4
-836.2
-815.2
-794.1
-773.1
-752.2
-731.3
-710.5
179.51
178.33
130.96
102.56
83.64
70.14
60.02
52.16
45.87
40.71
36.40
32.75
29.63
26.92
24.56
22.47
20.62
A fH
-1088.7
-1088.7
-1087.9
-1086.9
-1085.9
-1085.0
-1084.1
-1083.4
-1085.7
-1090.5
-1089.8
-1089.1
-1088.3
-1087.4
-1086.5
-1085.6
-1084.5
.-1
Boiling T
K
kJ
kJ
Molar Vol
H2*98~H5
10.37 kJ
A= -1.0865E+03
B- 2.088E-01
2.385 J'bar'1
23.85 cm3
C= -5.536E-02
8/27/92
185
COBALT MONOXIDE
CoO:
Formula wt
74.933
Temp.
CP
8T
-<Gf-H2 98 )/T
43.34
43.62
51.88
54.00
54.51
54.67
54.90
55.30
55.92
56.75
57.76
58.95
60.28
61.75
63.34
65.03
66.81
Melting T
52.83
53.10
67.04
78.90
88.80
97.22
104.53
111.02
116.87
122.24
127.22
131.89
136.30
140.51
144.55
148.44
152.21
0.00
0.27
12.37
20.53
26.16
30.22
33.29
35.71
37.70
39.39
40.88
42.22
43.46
44.63
45.75
46.84
47.90
A fG
Log Rf
-214.1
-214.0
-206.1
-198.5
-191.0
-183.8
-176.5
-169.4
-162.3
-155.2
-148.0
-140.9
-133.8
-126.6
-119.4
-112.2
-104.6
37.51
37.25
26.91
20.73
16.63
13.71
11.53
9.83
8.48
7.37
6.44
5.66
4.99
4.41
3.90
3.45
3.04
A fH
-1
J-wol"1 -*"1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
<HT-H2 98 )/T
52.83
52.83
54.68
58.37
62.64
66.99
71.24
75.30
79.17
82.85
86.34
89.67
92.84
95.88
98.80
101.60
104.31
-237.9
-237.9
-237.1
-236.0
-235.1
-234.3
-234.1
-233.6
-233.4
-233.3
-233.5
-234.1
-235.1
-234.9
-234.4
-233.6
-249.0
Boiling T
2078 R
kJ
Av*H
AftH0
kJ
Molar Vol.
H298-H6
-2.336B+02
1 .164 J-bar1
cm3
11 .64
9.45 kJ
B- 7.152E-02
C= -1.63B+05
9/9/92
186
Formula wt
TRICOBALT TETROXIDE
Co3O4 :
240.797
Cubic crystals 298.15 to 1000 K,
Temp.
CP
ST
<HT-H3 98 ,/T
_1
298.15
300
400
500
600
700
800
900
1000
Melting T
123.39
123.85
142.51
154.69
164.32
172.75
180.54
187.96
195.14
109.30
110.06
148.50
181.68
210.76
236.73
260.31
282.01
302.18
0.00
0.76
34.08
57.05
74.15
87.64
98.77
108.27
116.60
-<GT-H2 98 )/T
_1
1.T
109.30
109.30
114.42
124.63
136.61
149.09
161.54
173.74
185.58
A fG
Log Kf
-802.2
-801.5
-762.3
-723.1
-684.1
-645.4
-606.5
-567.9
-529.5
140.54
139.54
99.54
75.54
59.56
48.16
39.60
32.96
27.66
A fH
-918.8
-918.8
-919.0
-918.5
-917.5
-916.3
-916.2
-914.6
-913.1
mol"1
Boiling T
kJ
kJ
Molar Vol
H298"H5
18.13 kJ
A -9.157B+02
B= 3.866E-01
3.977 J-bar'1
39.77 cm3
0 -1.61B+05
9/9/92
187
Formula wt
ESKOLAITE
Cr2O3 :
151.990

Temp.
CP
ST
-<GT-H$ 98 )/T
<H*-H598 )/T
Melting T
105.41
105.63
113.62
117.83
120.55
122.58
124.22
125.65
126.95
128.15
129.30
130.40
131.47
132.52
133.55
134.56
135.57
81.20
81.85
113.48
139.32
161.06
179.80
196.28
211.00
224.30
236.46
247.66
258.05
267.76
276.86
285.45
293.58
301.29
0.00
0.65
28.02
45.60
57.87
66.98
74.03
79.69
84.35
88.28
91.65
94.59
97.19
99.51
101.60
103.51
105.26
Log Kf
-1053.1
-1052.6
-1025.4
-998.7
-972.4
-946.3
-920.5
-894.9
-869.4
-844.1
-818.7
-793.5
-768.2
-743.0
-717.7
-692.4
-666.9
184.49
183.26
133.90
104.33
84.65
70.62
60.10
51.94
45.41
40.08
35.64
31.88
28.66
25.87
23.43
21.27
19.35
.-1
J-mol" 1 -*'1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A fG
A fH
81.20
81.20
85.46
93.73
103.19
112.82
122.25
131.31
139.95
148.18
156.01
163.46
170.57
177.36
183.85
190.06
196.03
-1134.7
-1134.7
-1133.1
-1131.3
-1129.5
-1127.8
-1126.2
-1124.8
-1123.7
-1122.7
-1122.1
-1121.7
-1121.7
-1122.0
-1122.6
-1123.6
-1125.0
Boiling T
2603 K
kJ
kJ
Molar Vol.
9.45 kJ
A* -1.1225E+03
B= 2.533E-01
2.909 J-bar*1
29.09 cm3
C -5.635E-01
10/1/92
188
Formula wt
TENORITE
CuO:
79.545
Monoclinic crystals 298.15 to 1400 K.

Temp.
cp
ST
/ tl O _ V Q _\ /rn
\ V
OQft/ /
-(GT-H$ 98 )/T
A H
Jmol~lK~^
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
Melting T
42.30
42.44
47.07
49.32
50.80
51.98
53.05
54.09
55.13
56.18
57.25
58.33
59.43
42.60
42.86
55.80
66.57
75.70
83.62
90.63
96.94
102.69
108.00
112.93
117.56
121.92
0.00
0.26
11.47
18.83
24.04
27.95
31.02
33.53
35.64
37.46
39.06
40.50
41.81
A fG
Log Kf
-128.3
-128.2
-118.9
-109.9
-100.9
-92.2
-83.5
-74.9
-66.5
-58.1
-49.9
-41.7
-33.1
22.48
22.32
15.53
11.48
8.79
6.88
5.45
4.35
3.47
2.76
2.17
1.67
1.23
1. T
42.60
42.60
44.33
47.74
51.65
55.67
59.61
63.41
67.06
70.54
73.87
77.05
80.10
-156.1
-156.1
-155.6
-154.8
-154.0
-153.2
-152.3
-151.4
-150.5
-149.6
-148.7
-147.9
-160.2
Boiling T
K
kJ
kJ
Molar Vol
7.10 kJ
A- -1.506E+02
8.412E-02
1.222 J'bar'1
12.22 cm3
O -2.64E+05
8/28/92
189
Formula wt
CUPRITE
Cu20:
143.091

Temp.
cp
ST
(HT-H$ 98 )/T
-<Gf-H2 98 )/T
Melting T
62.54
62.59
67.18
71.49
74.27
76.00
77.28
78.60
80.33
82.76
86.10
90.51
96.12
103.03
92.40
92.79
111.37
126.85
140.16
151.74
161.98
171.15
179.52
187.29
194.62
201.68
208.59
215.45
0.00
0.39
16.47
27.07
34.72
40.50
45.02
48.68
51.75
54.46
56.95
59.35
61.77
64.28
Log Kf
-147.8
25.89
25.71
18.28
13.83
10.87
8.76
7.18
5.96
4.99
4.19
3.53
2.98
2.47
2.00
kJ-mol"1
J-mol^-K' 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
A fG
A fH
92.40
92.40
94.90
99.79
105.43
111.24
116.95
122.48
127.77
132.83
137.68
142.33
146.82
151.16
-170.6
-170.6
-170.6
-170.3
-169.8
-169.3
-168.7
-168.2
-167.6
-167.0
-166.4
-165.6
-191.0
-189.4
-147.7
-140.0
-132.4
-124.9
-117.4
-110.0
-102.7
-95.5
-88.3
-81.2
-74.1
-66.2
-57.4
Boiling T
1509 K
kJ
kJ
Molar Vol.
H598~H8
kJ
- -1 . 690E+02
B- 7.367E-02
2 .344 J-bar"1
23 .44 cm3
C -6.26E+04
8/26/92
190
Formula wt
WUSTITE
Fe .947O:
68.887
Rhombohedral crystals 298.15 to melting point 1652 K,

Temp.
cp
CO
ST
<HT-H98 )/T
-(Gf-H$98 )/T
J-mol'-'-'K"1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
Melting T
48.13
48.27
51.99
52.78
53.04
53.38
53.95
54.76
55.80
57.05
58.48
60.05
61.76
63.58
65.51
56.60
56.90
71.43
83.13
92.78
100.98
108.14
114.54
120.36
125.74
130.76
135.51
140.02
144.34
148.50
0.00
0.30
12.87
20.79
26.15
30.01
32.97
35.34
37.33
39.07
40.62
42.06
43.40
44.69
45.93
A fG
Log Kf
-244.9
-244.8
-237.8
-231.1
-224.6
-218.1
-211.8
-205.4
-199.0
-192.5
-185.9
-179.3
-172.8
-166.3
-159.9
42.91
42.62
31.05
24.14
19.55
16.28
13.83
11.92
10.40
9.14
8.09
7.20
6.45
5.79
5.22
AfH
kJmol"~^
56.60
56.60
58.56
62.34
66.64
70.97
75.18
79.20
83.03
86.67
90.14
93.45
96.62
99.65
102.58
-266.3
-266.3
-265.2
-264.2
-263.4
-262.8
-262.6
-262.7
-263.4
-264.9
-265.6
-264.7
-263.7
-262.7
-261.6
Boiling T
1652 K
AV*H
wmf
Aft.H'
kJ
kJ
Molar Vol.
H$98~H5
kJ
A -2 . 632E+02
B= 6.455E-02
1 .204 J'bar'1
12 .04 cm3
O -8.06E+04
2/5/93
191
FERROUS OXIDE (Fictive)
PeO:
Formula wt
71.846
Temp.
CP
CO
ST
<HT-H$98 )/T
-(GT-H$ 98 )/T
Melting T
A^0
47.68
47.75
50.26
51.47
52.26
52.91
53.51
54.11
54.72
55.34
55.98
56.63
57.30
57.98
58.68
59.38
60.10
60.60
60.90
75.03
86.39
95.84
103.95
111.05
117.39
123.12
128.37
133.21
137.72
141.94
145.91
149.68
153.26
156.67
0.00
0.29
12.52
20.20
25.48
29.35
32.33
34.72
36.69
38.36
39.80
41.07
42.20
43.23
44.18
45.05
45.87
Log Kf
-251.4
-251.3
-244.5
-237.9
-231.5
-225.1
-218.7
-212.3
-205.9
-199.3
-192.5
-185.7
-179.0
-172.3
-165.6
-158.8
-152.1
44.05
43.75
31.93
24.85
20.15
16.79
14.28
12.32
10.75
9.46
8.38
7.46
6.68
6.00
5.40
4.88
4.41
kJ-mol"" 1
J-mol" 1 -*"1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A fG
AfH
60.60
60.60
62.51
66.19
70.36
74.60
78.72
82.67
86.43
90.01
93.41
96.65
99.73
102.68
105.50
108.21
110.81
-272.0
-272.0
-271.2
-270.5
-269.9
-269.6
-269.6
-270.0
-271.0
-273.0
-274.1
-273.7
-273.3
-273.0
-272.7
-273.4
-273.6
Boiling T
Av^H0
kJ
kJ
Molar Vol.
H598-H5
kJ
A- -2.719E+02
B= 6.634E-02
1 .200 J-bar'1
12 . 00 cm3
C* 7.599E+04
2/24/94
192
Formula wt
HEMATITE
Fe2O3 :
159.692
Hexagonal crystals 950 to
Rhombohedral crystal 298.15 to Neel temperature 950 K.

1800 K.
Temp.
CP
CO
ST
<Hf-H 98 )/T
-(GT-H2 98 )/T
J*mol~*-K~* -
298.15
300
400
500
600
700
800
900
950
950
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
104.05
104.32
120.29
131.72
139.33
146.52
156.12
170.22
179.45
151.69
148.49
143.55
140.74
140.07
141.42
144.64
149.58
156.06
163.95
87.40
88.04
120.27
148.44
173.16
195.17
215.32
234.47
243.91
244.58
252.27
266.18
278.53
289.76
300.18
310.03
319.52
328.77
337.91
0.00
0.64
28.59
48.16
62.75
74.19
83.79
92.57
96.89
97.54
100.16
104.32
107.45
109.98
112.16
114.21
116.26
118.40
120.71
1. T
87.40
87.40
91.68
100.28
110.41
120.98
131.53
141.90
147.03
147.03
152.11
161.86
171.08
179.78
188.02
195.82
203.26
210.37
217.20
1895 K
A G
Log Kf
-744.4
-743.9
-716.6
-689.9
-663.6
-637.8
-612.4
-587.4
-575.3
-575.3
-562.8
-538.0
-513.2
-488.4
-463.8
-439.2
-414.7
-390.3
-366.0
130.41
129.51
93.58
72.07
57.77
47.59
39.99
34.09
31.65
31.65
29.40
25.55
22.34
19.62
17.30
15.29
13.54
11.99
10.62
A H
-826.2
-826.2
-824.6
-822.3
-819.6
-816.9
-814.0
-810.9
-809.3
-807.9
-808.9
-810.8
-811.9
-810.1
-808.5
-806.9
-805.2
-804.9
-803.1
mol"1
Boiling T
K
kJ
kJ
Molar Vol.
H298~H8
65.10 kJ
A= -8.089E+02
B- 2.466E-01
3.027 J-bar
30.27 cm3
-8.423E+05
9/9/92
Formula wt
MAGNETITE
Fe34-
Cubic (ferrimagnetic) crystals 298.15 to Neel temperature 845.5 K.

crystals (paramagnetic) 845.5 to 1800 K.
193
231.539
Cubic
Temp.
CP
Sf
(HT-H98 )/T
-(GT-H$ 98 )/T
J-1.--1
298.15
300
400
500
600
700
800
845.5
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
150.90
151.40
176.18
192.90
207.91
228.68
260.76
330.50
213.93
205.97
201.45
199.28
198.76
199.43
201.00
203.23
205.99
209.15
146.14
147.07
194.21
235.43
271.89
305.38
337.86
354.00
369.13
391.22
410.62
428.04
443.96
458.71
472.52
485.56
497.96
509.82
1870
0.00
0.93
41.81
70.45
92.08
110.00
126.70
135.66
142.05
148.81
153.78
157.65
160.82
163.55
165.99
168.24
170.38
172.45
A fG
Log Kf
-1012.7
-1012.1
-977.9
-944.5
-912.0
-880.3
-849.4
-835.3
-819.5
-790.0
-760.3
-730.4
-700.4
-670.6
-641.0
-611.5
-582.0
-552.4
177.42
176.21
127.70
98.67
79.40
65.69
55.46
51.60
47.56
41.27
36.10
31.79
28.14
25.02
22.32
19.96
17.88
16.03
A fH
kJ-mol' 1
146.14
146.14
152.40
164.98
179.81
195.38
211.16
218.34
227.08
242.41
256.84
270.39
283.14
295.16
306.53
317.32
327.58
337.37
-1115.7
-1114.6
-1113.0
-1109.2
-1104.8
-1099.5
-1092.7
-1087.8
-1085.1
-1085.5
-1089.1
-1091.0
-1088.6
-1086.5
-1084.6
-1082.9
-1084.1
-1083.7
Boiling T
AV*H
AHH O
kJ
kJ
Molar Vol.
H298"H8
102. 80 kJ
A -1 .086E+03
B** 2.969E-01
4 .452 J'bar'1
44 .52 cm3
c+ -1 .437E+06
9/9/92
194
Formula wt
STEAM
H2O:
Ideal gas at p
18.015
1 bar, 298.15 to 2500 K.

Temp.
c
CP
ST
(HT-H2 98 )/T
-,Gf-H5 98 )/T
Melting T
33.59
33.59
34.04
35.09
36.34
37.66
38.97
40.27
41.53
42.76
43.94
45.07
46.15
47.19
48.18
49.12
50.01
188.84
189.05
198.75
206.45
212.96
218.66
223.77
228.44
232.75
236.76
240.53
244.10
247.48
250.70
253.77
256.72
259.56
0.00
0.21
8.59
13.78
17.43
20.23
22.49
24.39
26.04
27.51
28.83
30.03
31.15
32.18
33.15
34.06
34.93
Log K
-228.6
-228.5
-223.9
-219.0
-214.0
-208.8
-203.5
-198.0
-192.6
-187.0
-181.4
-175.7
-170.1
-164.4
-158.6
-152.9
-147.1
40.05
39.79
29.24
22.88
18.63
15.58
13.28
11.49
10.06
8.88
7.90
7.06
6.35
5.72
5.18
4.70
4.27
kJ-mol~ 1
J-mol" 1 ^"1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A fG
A fH
188.84
188.84
190.16
192.67
195.52
198.43
201.28
204.05
206.70
209.26
211.71
214.06
216.33
218.51
220.62
222.66
224.63
-241.8
-241.8
-242.9
-243.9
-244.8
-245.7
-246.5
-247.2
-247.8
-248.4
-248.9
-249.4
-249.8
-250.2
-250.5
-250.7
-251.0
Boiling T
Ava|H o
AfiH0
kJ
kJ
Molar Vol.
H298"*H8
kJ
A -2.4896E+02
B= 5.632E-02
2478 .97 J'bar'1

24789 .7 cm3
C- 3.354E+05
8/26/92
195
Formula wt
K20:
94.196

Temp.
O
ST
(H*-HJ98 )/T
-<Gf-H 98 )/T
Melting T
83.68
83.79
88.89
93.39
97.64
101.78
105.85
109.90
113.92
117.92
121.92
94,10
94,62
119,45
139.77
157.17
172.54
186.39
199.10
210.88
221.93
232.36
0.00
0.52
21.99
35.83
45.78
53.48
59.77
65.12
69.80
73.99
77.82
Log Kf
-322.1
-321.9
-307.3
-292.6
-278.1
-264.0
-250.3
-237.0
-224.0
-202.1
-174.7
56.43
56.04
40.13
30.56
24.21
19.70
16.34
13.75
11.70
9.60
7.61
kJ mol" 1
J-1--1
298.15
300
400
500
600
700
800
900
1000
1100
1200
AfG
A fH
94.10
94.10
97.45
103.94
111.40
119.05
126.62
133.98
141.08
147.94
154.54
-363.2
-363.2
-367.0
-365.6
-363.7
-361.4
-358.6
-355.5
-352.0
-506.2
-500.2
Boiling T
kJ
kJ
Molar Vol
kJ
A- -3.816E+02
B- 1.640E-01
4.038 J'bar'1
40.38 cm3
1.032E+06
5/20/93
196
DILITHIUM MONOXIDE
Li2O:
Formula wt
29.881
Cubic crystals 298.15 to melting point 1700 K.

Temp.
CP
ST
(1HT~H298 ,/T
l~l.ir
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
Melting T
54.10
54.33
63.61
69.52
73.98
77.67
80.87
83.72
86.29
88.63
90.76
92.70
94.46
96.05
97.47
98.72
37.60
37.94
54.96
69.83
82.91
94.60
105.19
114.88
123.83
132.17
139.98
147.32
154.25
160.83
167.07
173.02
0.00
0.33
15.10
25.43
33.16
39.26
44.27
48.50
52.15
55.36
58.22
60.80
63.15
65.29
67.25
69.07
-(G*-H298 ,/1?
A fG
Log K
-561.2
-561.0
-548.5
-535.3
-521.2
-507.1
-493.1
-479.1
-465.3
-451.5
-437.9
-424.4
-411.0
-397.7
-384.6
-357.3
98.31
97.67
71.63
55.92
45.38
37.84
32.20
27.81
24.30
21.44
19.06
17.05
15.33
13.85
12.56
10.98
A fH
1
37.60
37.60
39.86
44.40
49.75
55.34
60.92
66.38
71.68
76.81
81.75
86.51
91.11
95.54
99.82
103.95
-597.9
-597.9
-598.7
-605.4
-605.7
-605.6
-605.2
-604.4
-603.4
-602.2
-600.7
-599.1
-597.3
-595.3
-593.2
-881.4
Boiling T
1700 K
Av*H
AtoH
kJ
kJ
Molar Vol.
H598~H8
kJ
A- -6.086E+02
B- 1.425E-01
1. 476 J'bar'1
14. 76 cm3
0 4.563E+06
12/7/92
Formula wt
PERICLASE
MgO:
197
40.304

Temp.
CP
ST
<HT-H2 98 )/T
-(GT-H$ 98 )/T
.-1-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
37.26
37.40
42.70
45.57
47.37
48.61
49.53
50.26
50.87
51.40
51.90
52.36
52.82
53.28
53.76
54.25
54.76
26.90
27.13
38.70
48.57
57.05
64.,45
71.00
76.88
82.21
87 08
91.57
95.75
99.64
103.30
106.76
110.03
113.15
0.00
0.23
10.26
17.06
21.97
25.69
28.62
30.98
32.94
34.60
36.02
37.26
38.35
39.33
40.22
41.03
41.78
1. T
26.90
26.90
28.44
31.51
35.07
38.75
42.38
45.89
49.26
52.48
55.56
58.49
61.29
63.97
66.54
69.00
71.37
A fG
Log Kf
-569.3
-569.1
-558.3
-547.4
-536.7
-526.0
-515.3
-504.7
-493.3
-481.8
-470.2
-458.6
-443.9
-423.1
-402.3
-381.7
-361.1
99.74
99.09
72.90
57.19
46.72
39.25
33.64
29.29
25.77
22.88
20.47
18.43
16.56
14.73
13.13
11.73
10.48
A fH
-601.6
-601.6
-601.6
-601.4
-601.1
-600.8
-600.5
-600.4
-608.9
-608.9
-609.0
-609.0
-736.4
-735.0
-733.5
-732.1
-730.6
mol" 1
Boiling T
3125 K
kJ
kJ
Molar Vol
H298~H8
5.17 kJ
-6.373E+02
B- 1.449E-01
1.125
11.25
Jbar4
cm3
0 2.512E+06
8/26/92
198
Formula wt
BRUCITE
Mg(OH) 2 :
58.320
Temp.
CP
s*
/ V O _ ** O
(**T
**298'\ '/ft*
63.20
63.68
88.23
109.60
128.15
144.45
158.98
172.10
0.00
0.48
21.78
36.61
47.47
55.80
62.43
67.87
/ S* O
(^*T
Zl O
298'\ '/ IP
A fH
A fG
Log K
-924.5
-924.5
-924.4
-923.4
-922.1
-920.6
-919.0
-917.3
-833.5
-832.9
-802.4
-772.0
-741.8
-711.9
-682.1
-652.6
146.02
145.02
104.78
80.64
64.58
53.12
44.54
37.88
K
298.15
300
400
500
600
700
800
900
77.27
77.66
91.89
99.29
104.00
107.44
110.20
112.57
Melting T
63.20
63.20
66.45
73.00
80.68
88.65
96.55
104.23
Boiling T
kJ
kJ
Molar Vol
H2*98~H8
11.40
kJ
A- -9.195E+02
B 2.971E-01
2.463 J-bar'1
24.63 cm3
O -2.30E+05
4/9/92
MANGANOSITE
MnO:
199
Formula wt
70.937
Temp.
CP
ST
(HJi-HJ98 )/T
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
-<G*-H598 )/T
59.71
59.98
73.07
83.74
92.76
100.60
107.55
113.80
119.48
124.70
129.53
134.04
138.26
142.23
145.98
149.54
152.93
0.00
0.27
11.60
18.84
23.95
27.80
30.83
33.30
35.37
37.13
38.67
40.02
41.23
42.31
43.31
44.21
45.05
Log K
-362.9
-362.8
-355.3
-348.0
-340.7
-333.4
-326.2
-319.0
-311.7
-304.3
-296.8
-289.4
-281.9
-274.1
-265.6
-256.9
-248.3
63.58
63.16
46.40
36.35
29.66
24.88
21.30
18.51
16.28
14.45
12.92
11.63
10.52
9.54
8.67
7.89
7.20
-1
1-1. XT-1
44.10
44.16
46.81
48.73
50.24
51.49
52.57
53.52
54.38
55.17
55.91
56.59
57.24
57.87
58.46
59.03
59.59
A fG
A fH
59.71
59.71
61.48
64.90
68.81
72.80
76.72
80.50
84.12
87.57
90.87
94.02
97.03
99.91
102.67
105.33
107.88
-385.2
-385.2
-384.9
-384.5
-384.3
-384.1
-384.0
-383.9
-386.2
-386.2
-386.3
-386.3
-388.6
-391.1
-403.8
-404.4
-404.9
Boiling T
2054 K
Av*H
Aft.H 0
kJ
kJ
Molar Vol.
HJ 98-H8
kJ
A -3.880E+02
B= 7.651E-02
1 .322 J-bar'1
13. 22 cm3
O 2.398E+05
4/9/92
200
Formula wt
PYROLUSITE
Mn02 :
86.937
Crystals 298.15 to 850 K.

Temp.
-<GT-H2 98 )/T
A fH"
J-mol^-K" 1
298.15
300
400
500
600
700
800
900
54.76
54.94
63.21
68.34
71.21
72.68
73.36
73.65
52.75
53.09
70.11
84.81
97.56
108.66
118.41
127.07
0.00
0.34
15.09
25.27
32.72
38.33
42.67
46.10
1. T --.,-. I
52.75
52.75
55.01
59.54
64.84
70.32
75.74
80.97
Melting T
-520.0
-520.0
-519.8
-519.1
-518.4
-517.7
-517.2
-516.8
A fG
Log Kf
-465.0
-464.7
-446.3
-427.9
-409.8
-391.7
-373.8
-355.9
81.47
80.91
58.27
44.71
35.67
29.23
24.40
20.65
Boiling T
kJ
kJ
Molar Vol
kJ
A= -5.172E+02
B 1.795E-01
1.661 J'bar'1
16.61 cm3
C- -1.20E+05
8/26/92
201
Formula wt
BIXBYITE
Mn203 :
157.874

Temp.
CP
CO
ST
(HT-H5 98 )/T
-(Of-HS98 ,/l!
J-mol" 1 -*" 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
101.81
101.93
108.49
114.61
120.05
124.93
129.38
133.49
137.37
141.07
144.63
148.09
151.47
113.70
114.33
144.55
169.43
190.81
209.69
226.67
242.15
256.42
269.68
282.11
293.82
304.92
0.00
0.<53
26.77
43.74
56.01
65.52
73.22
79.69
85.27
90.18
94.57
98.55
102.21
A fG
Log Kf
-882.1
-881.6
-855.9
-830.3
-804.9
-779.7
-754.5
-729.5
-704.5
-679.3
-654.1
-629.0
-604.0
154.53
153.49
111.76
86.74
70.08
58.18
49.27
42.34
36.80
32.26
28.47
25.27
22.54
A fH
kJ- mol"1
113.70
113.70
117.78
125.69
134.80
144.18
153.45
162.45
171.15
179.51
187.55
195.27
202.71
-959.0
-959.0
-958.4
-957.6
-956.9
-956.0
-955.2
-954.2
-957.7
-956.6
-955.3
-953.8
-956.7
Boiling T
Melting T
K
kJ
kJ
Molar Vol.
17.56 kJ
A- -9.550E+02
B- 2.508E-01
3.137 J'bar'1
31.37 cm3
O -1.645E+05
8/27/92
202
Formula wt
HAUSMANNITE
Mn3O4 :
228.812
Tetragonal crystals 298.15 to 1400 K.

Temp.
ST
CP
<H*-H598 )/T
-<Gf-H298 >/T
Melting T
142.02
142.52
158.37
165.03
169.49
173.64
178.04
182.86
188.12
193.77
199.78
206.12
212.72
164.10
164.98
208.55
244.68
275.18
301.61
325.08
346.33
365.86
384.05
401.17
417.41
432.92
0.00
0.88
38.62
63.30
80.64
93.63
103.90
112.40
119.71
126.18
132.06
137.51
142.65
Log Kf
-1282.5
-1281.8
-1247.7
-1214.0
-1180.5
-1147.1
-1113.8
-1080.7
-1047.4
-1013.7
-980.0
-946.5
-912.9
224.68
223.18
162.93
126.82
102.77
85.60
72.73
62.72
54.71
48.14
42.66
38.03
34.06
-1
J-mol"1 ^'1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
A fG
A fH
164.10
164.10
169.94
181.38
194.54
207.99
221.18
233.93
246.16
257.87
269.11
279.90
290.28
-1384.5
-1384.5
-1383.4
-1382.1
-1381.0
-1380.2
-1379.5
-1379.0
-1385.1
-1384.4
-1383.3
-1381.8
-1386.7
Boiling T
kJ
kJ
Molar Vol.
H298~H5
A -1.3809E+03
4. 695 J'bar'1
cm3
46. 95
24 .78 kJ
B= 3.3405E-01
C* -9.874E+05
4/10/92
203
Formula wt
BRAUNITE
Mn7 SiO12 :
604.645

Temp.
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
Melting T
CO
ST
CP
380.79
382.01
428.72
456.30
476.35
492.85
507.45
520.96
533.78
546.15
558.21
570.07
581.76
593.34
(HT-HJ| 98 )/T
416.40
418.76
535.79
634.62
719.66
794.36
861.14
921.70
977.26
1028.71
1076.75
1121.90
1164.58
1205.11
0.00
2.35
103.74
171.68
220.85
258,56
288,78
313 ,,83
33 5, .19
353, .81
370 ,.34
385, ,25
398 ,,87
411, ,45
-(GT-H2 98 )/T
416.40
416.41
432.05
462.94
498.81
535.80
572.37
607.87
642.07
674.91
706.41
736.65
765.71
793.66
A fH
AfG
Log Kf
-4260.0
-4260.0
-4258.2
-4254.9
-4251.4
-4247.8
-4244.2
-4240.7
-4252.6
-4248.9
-4244.5
-4239.4
-4249.7
-4260.6
-3944.7
-3942.8
-3837.2
-3732.3
-3628.2
-3524.6
-3421.5
-3318.8
-3216.4
-3112.9
-3009.8
-2907.1
-2804.4
-2700.4
691.09
686.48
501.08
389.91
315.86
263.00
223.40
192.62
168.00
147.82
131.01
116.81
104.63
94.04
Boiling
kJ
kJ
Molar Vol.
H98~H5
65 .68 kJ
A= -4.2437E+03
B- 1.0286E+00
12 .508 J-bar"1
125 . 08 cm3
O -6. 946E+05
02/24/94
204
Formula wt
MOLYBDITE
MoO3 :
143.938
Orthorhornbic crystals 298.15 to melting point 1074 K; liquid 1074 to 1500 K.

Temp.
CP
ST
<HT-H 98 )/T
-<GT-H 98 )/T
A fH
,-1. .-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
Melting T
74.91
75.13
83.02
87.78
91.85
95.89
100.08
104.46
109.03
126.95
126.95
126.95
126.95
126.95
77.70
78.16
101.00
120.06
136.42
150.89
163.96
176.00
187.24
197.87
207.97
217.67
227.02
236.09
0.00
0.46
20.24
33.29
42.71
50.02
56.01
61.15
65.71
69.85
73.71
77.36
80.85
84.22
A G
Log Kf
-668.1
-667.6
-641.9
-616.5
-591.4
-566.6
-542.0
-517.8
-493.8
-470.1
-446.7
-423.6
-400.8
-378.3
117.04
116.24
83.82
64.40
51.48
42.28
35.39
30.05
25.79
22.32
19.44
17.02
14.95
13.17
mol"1
77.70
77.70
80.76
86.77
93.71
100.87
107.95
114.85
121.53
128.02
134.26
140.31
146.17
151.87
1074 K
-745.2
-745.2
-744.1
-742.7
-741.1
-739.3
-737.2
-734.8
-732.2
-729.2
-725.8
-722.0
-717.9
-713.3
Boiling T
Ay_H
K
IcJ
48.91 kJ
Molar Vol.
H298~H5
12.59 kJ
A- -7.299E+02
B- 2.358E-01
3.056 J-bar'1
30.56 cm3
C- -8.02E+05
8/27/92
Formula wt
NITROGEN DIOXIDE
NO2 :
205
46.006
Ideal gas at p = 1 bar, 298.15 to 1800 K,

Temp.
CP
sf
uo_uo
\ /m
( "T
2 (38''
_/ô_tjo
\ /if
\**T
298''
A no
Hfn
Melting T
37.00
37.05
40.16
43.29
45.91
48.02
49.71
51.06
52.16
53.05
53.77
54.36
54.85
55.25
55.58
55.86
56.09
240.10
240.33
251.39
260.70
268.83
276.08
282.60
288.54
293.98
298.99
303.64
307.97
312.01
315.81
319.39
322.77
325.97
0.00
0.23
9. SI
16.20
20.94
24.66
27.69
30.22
32.36
34.20
35.80
37.21
38.45
39.56
40.55
41.44
42.25
Log Kf
51.2
51.4
57.5
63.8
70.2
76.6
83.0
89.3
95.7
102.1
108.4
114.8
121.1
127.4
133.7
140.1
146.4
-8.98
-8.94
-7.51
-6.67
-6.11
-5.71
-5.42
-5.18
-5.00
-4.85
-4.72
-4.61
-4.52
-4.44
-4.37
-4.30
-4.25
ItJ- ol""l
l~l.|r-l
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A oo
Uf\
240.10
240.10
241.59
244.50
247.89
251.41
254.91
258.32
261.62
264.79
267.84
270.76
273.56
276.26
278.84
281.33
283.72
33.1
33.1
32.5
32.2
32.0
31.9
31.9
31.9
32.0
32.1
32.3
32.4
32.5
32.6
32.8
32.9
33.0
Boiling T
Av*H
AfiH
kJ
Molar Vol.
HJ 98-H8
kJ
A= 3.210E+01
* 6.353E-02
kJ
2478 .97 J'bar'1
24789 .7 cm3
O 1.451E+04
5/06/93
206
Formula wt
DISODIUM MONOXIDE
Na2O:
61.979

Temp.
CP
Sf
{(H5-H598 ,/T
-1
298.15
300
400
500
600
700
800
900
1000
Melting T
69.10
69.26
76.30
81.34
85.26
88.47
91.20
93.60
95.74
75.30
75.73
96.68
114.27
129.46
142.85
154.85
165.73
175.71
0.00
0.43
18.57
30.64
39.43
46.21
51.67
56.20
60.05
-(Gf-H2 98 )/T
AfG
Log Kf
-376.0
-375.7
-362.3
-347.8
-333.4
-319.2
-305.1
-291.3
-277.7
65.87
65.42
47.31
36.33
29.03
23.82
19.92
16.91
14.50
A fH
kJ
75.30
75.30
78.11
83.63
90.03
96.64
103.18
109.53
115.66
-414.8
-414.8
-420.2
-420.1
-419.3
-418.2
-416.7
-414.9
-413.0
Boiling T
1193 K
kJ
kJ
Molar Vol.
H2*98~H8
12.40 kJ
A= -4.180E+02
1.407E-01
2.588 J'bar'1
25.88 cm3
C* -5.93E+03
9/10/92
207
Formula wt
BUNSENITE
NiO:
Rhombohedral (distorted cubic) crystals 298.15 to Neel temperature 519 K.

crystals 519 to 1800 K.
74.689
Cubic

Temp.
CP
S*
Jmol""
298.15
300
400
500
519
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
(Hf-H| 9Q )/T
44.49
44.70
53.00
64.90
69.15
56.01
54.22
53.66
53.83
54.43
55.29
56.29
57.37
58.48
59.57
60.62
61.61
62.52
37.99
38.27
52.38
65.25
67.74
76.07
84.55
91.74
98.06
103.76
108.99
113.84
118.39
122.68
126.76
130.63
134.34
137.89
0.00
0.28
12.52
21.59
23.25
27.86
31.73
34.50
36.63
38.38
39.88
41.20
42.40
43.51
44.55
45.52
46.44
47.30
-<GT-H2 98 )/T
AfG
Log K
-211.1
-211.0
-201.6
-192.5
-190.9
-183.6
-175.0
-166.8
-157.8
-149.3
-140.8
-132.4
-124.0
-115.7
-107.4
-99.1
-90.9
-82.0
36.99
36.73
26.33
20.11
19.21
15.99
13.05
10.89
9.16
7.80
6.69
5.76
4.98
4.32
3.74
3.24
2.79
2.38
A fH
K'
kJ-mol~l
37.99
37.99
39.86
43.66
44.49
48.21
52.82
57.24
61.43
65.38
69.11
72.64
75.99
79.17
82.21
85.11
87.90
90.59
-239.3
-239.3
-238.6
-237.3
-236.8
-236.2
-235.6
-235.1
-234.5
-234.0
-233.5
-233.1
-232.6
-232.1
-231.6
-231.1
-230.6
-247.3
Boiling T
2257 K
Av*H
AI^H*
kJ
kJ
Molar Vol.
H598"H8
6.69 kJ
A= -2.331E+02
B* 8.392E-02
1. 097 J'bar*1
10. 97 cm3
O -2.85E+05
9/9/92
208
Formula wt
LITHARGE
PbO:
223.199
Tetragonal crystals (red) 298.15 to 1000 K.
Temp.
CP
Sf
<Hf-H2 98 )/T
-<Gf-H2 98 )/T
A fH
1. T.-.-.1
298.15
300
400
500
600
700
800
900
1000
45.77
45.89
50.51
53.20
55.13
56.70
58.08
59.35
60.55
66.50
66.78
80.69
92.27
102.15
110.77
118.43
125.35
131.66
0.00
0.28
12.33
20.25
25.91
30.20
33.60
36.39
38.75
66.50
66.50
68.37
72.02
76.24
80.57
84.83
88.96
92.92
Melting T
-219.0
-219.0
-218.4
-217.5
-216.6
-220.5
-219.4
-218.3
-216.9
A fG
Log Kf
-188.9
-188.7
-178.7
-168.9
-159.3
-149.0
-138.9
-128.9
-119.0
33.10
32.86
23.34
17.65
13.87
11.12
9.07
7.48
6.22
Boiling T
kJ
kJ
Molar Vol.
H298~H8
kJ
A- -2.194E+02
B= 1.004E-01
2.391 J'bar*1
23.91 cm3
C* 4.877E+04
9/9/92
Formula wt
PLATTNERITE
PbO2 :
209
239.199
Tetragonal crystals 298.15 to 1200 K,
Temp.
fO
OO
/ tj O ^17 Q
\ /T
^ / O O ^17 Q
\ /T
J*mol, -1X K-.1x
298.15
300
400
500
600
700
800
900
1000
1100
1200
Melting T
61.17
61.35
68.23
71.82
74.11
75.79
77.14
78.30
79.34
80.31
81.23
71.80
72.18
90.90
106.54
119.85
131.41
141.62
150.77
159.08
166.69
173.71
0.00
0.38
16.59
27.31
34.93
40.65
45.13
48.75
51.76
54.31
56.52
A *f
Log Kf
-218.3
-218.0
-198.3
-178.8
-159.6
-139.8
-120.2
-100.7
-81.4
-62.2
-43.2
38.25
37.95
25.89
18.68
13.89
10.43
7.85
5.84
4.25
2.96
1.88
TI^
,kJ*mol
,
.-I*
71.80
71.80
74.31
79.23
84.92
90.76
96.49
102.02
107.32
112.37
117.20
-277.4
-277.4
-276.6
-275.4
-274.2
-277.8
-276.5
-275.1
-273.7
-272.1
-270.5
Boiling T
kJ
kJ
Molar Vol.
36.78 kJ
-2.752E+02
B* 1.937E-01
2.501 J'bar'1
25.01 cm3
C -7.72E+04
9/9/92
210
Formula wt
MINIUM
Pb3O4 :
685.598

Temp.
cp
ST
<HT-H2 98 )/T
-(GT-H2 98 )/T
._
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
A^H0
154.90
155.37
172.92
182.83
189.73
195.21
199.94
204.22
208.23
212.07
215.78
219.41
222.97
226.49
229.97
233.43
236.86
212.00
212.96
260.35
300.08
334.06
363.73
390.11
413.91
435.64
455.66
474.28
491.69
508.08
523.59
538.31
552.36
565.80
0.00
0.96
42.01
69.25
88.78
103.61
115.36
125.00
133.12
140.13
146.28
151.76
156.72
161.26
165.44
169.34
173.00
212.00
212.00
218.35
230.83
245.27
260.12
274.75
288.91
302.51
315.54
328.00
339.93
351.36
362.33
372.87
383.02
392.80
A fG
Log Kf
-601.6
-600.9
-562.0
-523.7
-486.2
-446.9
-408.1
-369.8
-332.1
-294.9
-258.1
-221.9
-186.1
-150.7
-115.8
-81.4
-47.4
105.40
104.62
73.38
54.71
42.33
33.35
26.65
21.46
17.35
14.00
11.24
8.91
6.94
5.25
3.78
2.50
1.37
AfH
-718.7
-718.7
-716.3
-713.0
-709.5
-720.3
-716.3
-711.8
-707.0
-701.8
-696.2
-690.2
-683.9
-677.3
-670.4
-663.1
-655.6
.- 1
Boiling T
Av*H
kJ
kJ
Molar Vol.
H298"H8
kJ
- -6.975E+02
B= 3.642E-01
7. 681 J'bar'1
76. 81 cm3
C* -1.26E+06
8/21/92
211
Formula wt
SULFUR DIOXIDE
64.065
Temp.
ST
Melting T
-<GT-H2 98 )/T
39.85
39.92
43.48
46.53
48.92
50.78
52.23
53.38
54.29
55.01
55.60
56.07
56.46
56.79
57.06
57.29
57.49
248.20
248.45
260.42
270.47
279.17
286.86
293.74
299.96
305.63
310.84
315.65
320.12
324.29
328.20
331.87
335.34
338.62
0.00
0.25
10.61
17.50
22.55
26.45
29.59
32.17
34.34
36.19
37.78
39.17
40.39
41.47
42.44
43.31
44.09
kJ-
248.20
248.20
249.81
252.96
256.62
260.40
264.15
267.78
271.29
274.65
277.87
280.95
283.90
286.72
289.43
292.03
294.53
AfG
Log Kf
-300.1
-300.1
-300.9
-300.8
-300.3
-299.4
-298.3
-296.0
-288.6
-281.3
-274.0
-266.7
-259.3
-252.1
-244.8
-237.4
-230.2
52.57
52.25
39.30
31.43
26.14
22.34
19.48
17.18
15.08
13.36
11.93
10.71
9.68
8.78
7.99
7.30
6.68
A fH
1-l.v-l
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
<Hf-H2 98 )/T
-296.8
-296.8
-300.2
-302.7
-304.7
-306.3
-307.7
-362.1
-362.0
-361.9
-361.8
-361.7
-361.6
-361.5
-361.5
-361.4
-361.4
1~1
Boiling T
A^'
AftJH0
kJ
kJ
Molar Vol.
H298~H8
10.55 kJ
A = -3.536E+02
B= 6.628E-02
2478 .97 J'bar'1

24789 .7 can3
0 3.246E+06
9/9/92
212
Formula wt
SULFUR TRIOXIDE
SO3 :
80.064
Temp.
CP
o
ST
Melting T
-(Gf-H2 98 )/T
50.63
50.77
57.69
63.09
67.16
70.26
72.64
74.49
75.93
77.07
77.96
78.68
79.25
79.71
80.08
80.38
80.64
256.80
257.11
272.70
286.18
298.06
308.66
318.20
326.87
334.80
342.09
348.83
355.10
360.96
366.44
371.60
376.46
381.06
0.00
0.31
13.82
23.16
30.17
35.69
40.16
43.88
47.02
49.70
52.02
54.04
55.82
57.40
58.81
60.07
61.20
A fG
Log Kf
-371.0
-370.8
-362.2
-352.6
-342.6
-332.3
-321.9
-310.2
-293.6
-277.0
-260.5
-244.0
-227.6
-211.2
-194.8
-178.5
-162.2
64.99
64.56
47.30
36.84
29.83
24.80
21.02
18.00
15.34
13.15
11.34
9.80
8.49
7.35
6.36
5.48
4.71
A fH
1 _-l
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
(Hf-H$ 98 )/T
kJ-mol" 1
256.80
256.80
258.88
263.02
267.89
272.97
278.04
282.99
287.78
292.39
296.82
301.06
305.13
309.04
312.79
316.39
319.86
-395.7
-395.7
-399.3
-401.8
-403.6
-405.0
-406.0
-460.0
-459.6
-459.0
-458.5
-458.0
-457.4
-456.9
-456.3
-455.8
-455.3
Boiling T
Av^
A^H0
kJ
kJ
Molar Vol.
H298~H8
kJ
A -4.504E+02
B= 1.580E-01
2478. 97 J'bar'1
24789. 7 cm3
C* 3.103E+06
4/9/92
Formula wt
SILICON MONOXIDE
SiO:
213
44.085

Temp.
CP
CO
ST
(Hf-HJ 98 ,/T
-(Gf-H2 98 )/T
-1-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
29.90
29.92
31.15
32.38
33.39
34.19
34.82
35.33
35.72
36.04
36.30
36.51
36.67
36.81
36.93
37.03
37.11
211.60
211.79
220.55
227.64
233.64
238.85
243.45
247.59
251.33
254.75
257.90
260.81
263.52
266.06
268.44
270.68
272.80
0.00
0.18
7.77
12.57
15.96
18.51
20.51
22.13
23.47
24.60
25.56
26.40
27.13
27.77
28.34
28.84
29.30
VT
211.60
211.60
212.79
215.07
217.68
220.34
222.95
225.46
227.86
230.15
232.33
234.41
236.40
238.29
240.10
241.84
243.50
A fG
Log Kf
-127.3
-127.5
-136.4
-145.2
-153.8
-162.4
-170.8
-179.2
-187.4
-195.6
-203.7
-211.8
-219.7
-227.6
-235.5
-242.8
-247.5
22.30
22.19
17.81
15.17
13.39
12.12
11.15
10.40
9.79
9.29
8.87
8.51
8.20
7.93
7.69
7.46
7.18
A fH c
mol" 1
-100.4
-100.4
-101.0
-101.6
-102.3
-103.0
-103.7
-104.4
-105.2
-106.0
-106.9
-107.8
-108.7
-109.7
-110.7
-162.0
-162.8
Boiling T
Melting T
kJ
kJ
Molar Vol.
H2"98~H8
8.71
kJ
A= -1.084E+02
B= -7.908E-02
2478.97 Jbar'1
24789.7
cm3
C 4.562E+05
4/10/92
214
Formula wt
QUARTZ
SiO2 :
60.084
Trigonal crystals 298.15 to a-0 transition at 844 K. ^-crystals 844 to 1700.

The melting point is estimated to be 1700 K. Liquid 1700 to 1800 K.
Temp.
CP
ST
(HT-H$ 98 )/T
-<GT-H2 98 )/T
A fH
J'mol'^K* 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
44.59
44.78
53.27
59.68
65.04
69.82
74.25
68.62
69.12
69.74
70.43
71.17
71.96
72. 77
73.60
74.45
81.37
41.46
41.74
55.85
68.45
79.82
90.21
99.83
109.00
116.25
122.87
128.96
134.63
139.93
144.92
149.65
154.14
164.31
0.00
0.28
12.52
21.34
28.18
33.80
38.58
42.93
45.52
47.69
49.56
51.19
52.65
53.96
55.16
56.27
62.89
A fG
Log Kf
-856.3
-855.9
-837.7
-819.4
-801.2
-783.2
-765.3
-747.7
-730.2
-712.8
-695.4
-678.1
-660.9
-643.7
-626.6
-609.0
-589.6
150.01
149.03
109.38
85.60
69.75
58.44
49.97
43.39
38.14
33.85
30.27
27.25
24.66
22.41
20.46
18.71
17.11
kJ
41.46
41.46
43.33
47.11
51.64
56.41
61.25
66.07
70.73
75.18
79.40
83.44
87.28
90.96
94.49
97.87
101.42
Melting T
-910.7
-910.7
-910.9
-910.5
-909.8
-908.8
-907.4
-905.6
-904.8
-904.1
-903.3
-902.5
-901.8
-901.0
-900.2
-949.6
-938.5
Boiling T
kJ
kJ
Molar Vol.
H298~H8
6.916 kJ
A -9.047E+02
B- 1.744E-01
2.269 J'bar'1
22.69 cm3
O -3.39E+05
01/06/93
Formula wt
CRISTOBALITE
SiO2 :
215
Tetragonal crystals, a, 298.15 to 523 K.
60.084
Cubic crystals, P, 523 to 1800 K.

Temp.
CP
CO
ST
(HT-HJ 98 )/T
-(GT-H| 98 )/T
A fH
J'mol" 1 ^' 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
44.95
45.15
50.73
68.59
62.06
65.23
67.34
68.82
69.92
70.77
71.44
72.00
72.47
72.87
73.22
73.53
73.82
Melting T
43.40
43.70
57.93
70.56
84.60
94.42
103.28
111.30
118.61
125.32
131.50
137.24
142.60
147.61
152.32
156.77
160.98
0.00
0.28
12.63
21.48
29.96
34.78
38.73
41.99
44.74
47.07
49.07
50.81
52.34
53.70
54.91
55.99
56.98
A fG
kJ-mol" 1
43.40
43.42
45.31
49.08
54.64
59.64
64.55
69.31
73.87
78.26
82.43
86.43
90.26
93.91
97.41
100.78
104.00
-854.6
-854.2
-836.1
-818.1
-800.7
-783.1
-908.4
-908.4
-908.5
-908.2
-906.5
-905.8
-905.0
-904.2
-903.3
-902.4
-901.6
-900.7
-899.9
-899.1
-898.3
-947.8
-946.8
-765.7
-748.3
-731.0
-713.8
-696.7
-679.7
-662.7
-645.8
-628.9
-611.7
-591.9
Boiling T
1996 K
A^H
AftH
Log K
149.71
148.73
109.19
85.46
69.71
58.44
49.99
43.43
38.18
33.90
30.33
27.31
24.73
22.49
20.53
18.79
17.18
kJ
kJ
Molar Vol.
7.04 kJ
H298-H8
-9.029E+02
B= 1.719E-01
2 .574 J-bar1
25 .74 cm3
C- -2.62E+05
01/06/93
216
Formula wt
COESITE
SiO2 :
60.084
Temp.
CP
ST
i(HJ-HJ 98 )/T
/T
-(G
45.46
45.58
52.60
58.51
62.81
65.84
67.94
69.41
70.45
71.23
71.86
72.45
73.06
73.75
74.56
75.54
76.71
38.50
38.78
52.85
65.26
76.33
86.25
95.19
103.28
110.65
117.40
123.63
129.40
134.79
139.86
144.64
149.19
153.54
Melting T
AftH
H2*98~H5
0.00
0.28
12.48
21.12
27.73
32.97
37.22
40.72
43.64
46.12
48.24
50.08
51.70
53.14
54.46
55.67
56.80
Log Kf
-852.5
-852.2
833 . 6
-815.0
-796.5
-778.1
-759.8
-741.6
-723.6
-705.6
-687.7
-669.9
-652.1
-634.4
-616.8
-598.8
-578.2
149.35
148.37
108.85
85.14
69.34
58.06
49.61
43.04
37.79
33.50
29.93
26.91
24.33
22.09
20.14
18.40
16.78
-1
-1-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A fG
A fH
38.50
38.50
40.37
44.13
48.59
53.28
57.97
62.56
67.01
71.28
75.39
79.33
83.10
86.71
90.19
93.52
96.74
-907.8
-907.8
-908.0
-907.7
-907.2
-906.5
-905.6
-904.7
-903.8
-902.9
-902.0
-901.1
-900.2
-899.3
-898.5
-947.7
-946.6
Boiling T
AV*H
kJ
Molar Vol
2 .064 J-bar'1
20. 64 cm3
kJ
6 .89 kJ
A* -9.036E+02
B 1.799E-01
0 -2.39E+05
8/28/92
217
Formula wt
STISHOVITE
SiO2 :
60.084
Temp.
cp
ST
(Hf-H| 98 )/T
-(GT-H2 9Q )/T
A G
Log Kf
-802.8
-802.4
-782.8
-763.1
-743.6
-724.1
-704.8
-685.6
-666.4
-647.4
-628.4
-609.5
-590.6
-571.8
-553.1
-534.0
-512.4
140.65
139.72
102.22
79.72
64.73
54.03
46.02
39.79
34.81
30.74
27.35
24.49
22.04
19.91
18.06
16.41
14.87
A H
kJ*mo i-l
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
42.99
43.24
53.50
59.42
63.14
65.60
67.32
68.58
69.58
70.42
71.20
71.97
72.79
73.68
74.68
75.80
77.06
27.78
28.05
42.04
54.67
65.85
75.78
84.66
92.67
99.95
106.62
112.78
118.51
123.87
128.92
133.71
138.27
142.64
0.00
0.27
12.42
21.28
27.97
33.18
37.34
40.75
43.58
45.99
48.05
49.86
51.47
52.92
54.25
55.48
56.65
27.78
27.78
29.62
33.39
37.89
42.61
47.32
51.92
56.36
60.63
64.72
68.64
72.40
76.00
79.46
82.79
85.99
-861.3
-861.3
-861.5
-861.2
-860.6
-859.8
-859.0
-858.2
-857.4
-856.5
-855.7
-854.9
-854.0
-853.2
-852.3
-901.6
-900.3
Boiling T
A^H
Aft.H
kJ
kJ
Molar Vol.
H2*98~H5
7.74 kJ
A= -8.572E+02
B= 1.907E-01
1. 4014 J'bar'1
14. 014 cm3
C- -2.28E+05
12/17/91
218
Formula wt
SILICA GLASS
SiO2 :
60.084
Glass 298.15 to estimated melting point 1700 K,

Temp.
CP
ST
Jmol
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
Melting T
37.94
38.36
53.17
59.95
63.64
65.93
67.53
68.77
69.84
70.82
71.79
72.77
73.81
74.90
76.07
77.32
48.50
48.74
62.11
74.79
86.07
96.07
104.98
113.01
120.31
127.01
133.22
139.00
144.43
149.56
154.43
159.08
-<GT-H2 98 )/T
(Hf-H2 98 )/T
K
0.00
0.24
11.89
20.90
27.74
33.04
37.26
40.69
43.56
45.99
48.10
49.96
51.63
53.14
54.54
55.84
k_
48.50
48.50
50.22
53.89
58.33
63.02
67.72
72.31
76.75
81.02
85.12
89.04
92.81
96.42
99.90
103.24
A G
Log Kf
-849.3
-849.0
-831.3
-813.7
-796.1
-778.7
-761.4
-744.2
-727.1
-710.1
-693.2
-676.3
-659.5
-642.8
-626.1
-609.1
148.79
147.81
108.56
85.00
69.31
58.11
49.71
43.19
37.98
33.72
30.17
27.17
24.61
22.38
20.44
18.71
A fH
-901.6
-901.6
-902.0
-901.7
-901.0
-900.2
-899.4
-898.6
-897.7
-896.8
-895.9
-895.0
-894.1
-893.1
-892.1
-941.2
.-1
Boiling T
1700 K
kJ
kJ
Molar Vol
H2*98~H5
6.998 kJ
A* -8.966E+02
B- 1.694E-01
2.727 J'bar1
27.27 cm3
C- -3.06E+05
2/25/93
219
Formula wt
CASSITERITE
SnO2 :
150.709
Temp.
CP
ST
(HT-H2 98 )/T
-<GT-H2 98 )/T
-1-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
Melting T
53.22
53.54
65.09
70.83
74.28
76.66
78.46
79.92
81.18
82.30
83.33
84.30
85.21
86.10
49.02
49.35
66.56
81.76
95.00
106.64
117.00
126.32
134.81
142.60
149.81
156.52
162.80
168.71
0.00
0.33
15.27
25.86
33.66
39.64
44.39
48.26
51.49
54.24
56.62
58.71
60.57
62.25
A fG
Log Kf
-515.8
-515.4
-494.7
-474.1
-452.3
-430.8
-409.4
-388.2
-367.3
-346.5
-325.9
-305.4
-285.1
-265.0
90.36
89.74
64.60
49.53
39.38
32.14
26.73
22.53
19.18
16.45
14.18
12.27
10.64
9.23
A fH
kJ mol" 1
49.02
49.02
51.29
55.90
61.34
66.99
72.61
78.07
83.32
88.36
93.19
97.80
102.22
106.46
-577.6
-577.6
-577.4
-576.6
-582.6
-581.1
-579.5
-577.8
-576.0
-574.1
-572.2
-570.2
-568.2
-566.1
Boiling T
1903 K
A^ 0
K
kJ
kJ
Molar Vol.
HJ98-H
8.38 kJ
A -5.763E+02
B- 2.084E-01
2.155 J-bar'1
21.55 cm3
O -1.755E+05
6/11/93
220
Formula wt
STRONTIUM MONOXIDE
SrO:
103.619

Temp.
CP
ST
(Hf-H2 98 )/T
-<H-HJ98 )/I?
45.41
45.49
48.66
50.62
52.06
53.24
54.26
55.19
56.04
56.86
57.63
58.38
59.11
59.83
60.53
61.22
61.90
55.52
55.80
69.37
80.45
89.81
97.93
105.10
111.55
117.41
122.79
127.77
132.41
136.76
140.87
144.75
148.44
151.96
0.00
0.28
12.02
19.55
24.86
28.83
31.95
34.48
36.59
38.40
39.97
41.36
42.60
43.72
44.75
45.70
46.58
Log Kf
-560.7
-560.5
-550.3
-540.2
-530.3
-520.5
-510.7
-501.0
-491.3
-481.3
-471.0
-460.7
-450.4
-440.1
-429.8
-418.4
-400.1
98.22
97.59
71.86
56.43
46.16
38.84
33.35
29.07
25.66
22.86
20.50
18.51
16.80
15.33
14.03
12.86
11.61
-1
J-mol"1 ^' 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A fG
A fH
55.52
55.52
57.35
60.89
64.95
69.10
73.16
77.07
80.82
84.39
87.80
91.06
94.17
97.14
100.00
102.74
105.38
Melting T
-591.3
-591.3
-590.8
-590.2
-589.5
-588.9
-588.4
-588.5
-587.7
-594.7
-594.7
-594.7
-594.5
-594.4
-594.1
-730.7
-728.5
Boiling T
kJ
kJ
Molar Vol.
H598~H8
8.675 kJ
A -5.956E+02
B- 1.047E-01
2.069 J-bar'1
20.69 cm3
C= 3.940E+05
10/2/92
Formula wt
THORIANITE
Th02 :
221
264.037

Temp.
CP
Sf
(Hf-H| 98 )/T
-<GT-H2 98 )/T
1-1. K' 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
61.79
61.95
67.82
70.95
72.99
74.52
75.78
76.88
77.88
78.82
79.72
65.20
65.58
84.31
99.81
112.94
124.31
134.34
143.34
151.49
158.96
165.85
0.00
0.38
16.60
27.18
34.66
40.25
44.61
48.14
51.06
53.54
55.69
A G
Log Kf
-1169.2
-1168.9
-1149.8
-1131.0
-1112.5
-1094.1
-1075.9
-1057.9
-1040.0
-1022.2
-1004.5
204.84
203.51
150.15
118.15
96.85
81.64
70.25
61.40
54.32
48.54
43.72
A H
kJ mol" 1
65.20
65.20
67.72
72.63
78.28
84.06
89.73
95.20
100.43
105.41
110.17
Melting T
-1226.4
-1226.4
-1225.5
-1224.4
-1223.2
-1222.0
-1220.8
-1219.7
-1218.6
-1217.5
-1216.5
Boiling T
kJ
kJ
Molar Vol.
10.56 kJ
A- -1.219E+03
B- 1.794E-01
2.637 J'bar'1
26.37 cm3
0 -3.21E+05
9/10/92
222
Formula wt
RUTILE
TiO2 :
79.879

Temp.
CP
CO
ST
<Hf-H2 98 )/T
-<GT-H2 98 )/T
J-mol"1 ^" 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
55.29
55.49
63.19
67.29
69.85
71.62
72.92
73.94
74.77
75.45
76.04
76.55
76.99
77.39
77.76
78.09
78.39
50.62
50.96
68.12
82.70
95.21
106.12
115.77
124.42
132.25
139.41
146.00
152.11
157.80
163.13
168.13
172.86
177.33
0.00
0.34
15.21
25.25
32.49
37.96
42.25
45.72
48.58
50.99
53.06
54.85
56.41
57.80
59.03
60.14
61.15
1. T
50.62
50.62
52.91
57.45
62.72
68.16
73.52
78.70
83.67
88.42
92.95
97.26
101.39
105.33
109.10
112.71
116.18
2103 K
AfG
Log Kf
-888.8
-888.4
-869.9
-851.6
-833.4
-815.4
-797.5
-779.8
-762.1
-744.5
-726.9
-709.1
-691.4
-673.7
-656.1
-638.5
-621.0
155.70
154.68
113.60
88.96
72.56
60.85
52.07
45.26
39.81
35.35
31.64
28.49
25.79
23.46
21.42
19.62
18.02
A fH
-944.0
-944.0
-943.6
-942.8
-942.0
-941.0
-940.1
-939.1
-938.3
-937.6
-941.0
-940.0
-939.0
-938.0
-937.2
-936.5
-935.9
mol~^
Boiling T
K
kJ
kJ
Molar Vol.
8.67 kJ
A- -9.385E+02
B 1.766E-01
1.882 J-bar'1
18.82 cm3
C -2.66E+05
4/5/93
Formula wt
ANATASE
TiO2 :
223
79.879

Temp.
CP
ST
(HT-H2 98 )/T
_1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
Melting T
55.32
55.59
64.71
68.60
70.69
72.07
73.15
74.10
75.01
75.91
76.82
77.74
49.90
50.24
67.69
82.60
95.31
106.32
116.01
124.68
132.54
139.73
146.37
152.56
0.00
0.34
15.47
25.76
33.09
38.56
42.82
46.24
49.07
51.47
53.55
55.37
-<H-HS98 )/i
*i
:H
A fG
Log K
49.90
49.90
52.22
56.85
62.22
67.75
73.19
78.44
83.46
88.26
92.83
97.19
-938 .7
-938 .7
-938 .2
-937 .3
-936 .3
-935 .3
-934 .3
-933 .3
-932 .5
-931 .8
-935 .2
-934 .0
-883.2
-882.9
-864.4
-846.0
-827.8
-809.8
-792.0
-774.2
-756.6
-739.1
-721.4
-703.7
154.74
153.72
112.87
88.38
72.07
60.43
51.71
44.93
39.52
35.09
31.40
28.27
_1
Boiling T
kJ
kJ
Molar Vol.
H298~H5
kJ
A- -9.331E+02
B= 1.767E-01
2 .052 J'bar'1
20 .52 cm3
C -2.60E+05
9/10/92
224
Formula wt
URANINITE
U02 :
270.028

Temp.
ST
CP
(H*-HJ98 )/T
-<GT-H2 98 )/T
A fH
A fG
Log K
-1084.9
-1084.9
-1083.9
-1082.7
-1081.5
-1080.5
-1079.7
-1079.3
-1081.6
-1085.3
-1084.1
-1082.7
-1081.2
-1089.3
-1088.5
-1087.7
-1086.8
-1031.7
-1031.4
-1013.7
-996.3
-979.2
-962.2
-945.4
-928.6
-911.7
-894.5
-877.2
-860.0
-843.0
-825.4
-807.8
-790.3
-772.8
180.75
179.58
132.38
104.08
85.24
71.80
61.72
53.89
47.62
42.48
38.18
34.56
31.45
28.74
26.37
24.28
22.43
I-mol" 1 -*" 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
63.60
63.82
71.65
75.51
77.96
79.82
81.42
82.90
84.31
85.70
87.07
88.45
89.84
91.24
92.64
94.05
95.48
Melting T
77.03
77.42
97.01
113.46
127.45
139.62
150.38
160.06
168.87
176.97
184.48
191.51
198.11
204.36
210.29
215.95
221.37
0.00
0.39
17.37
28.64
36.67
42.71
47.45
51.31
54.54
57.31
59.73
61.89
63.83
65.61
67.26
68.79
70.24
77.03
77.03
79.65
84.81
90.78
96.91
102.93
108.75
114.33
119.66
124.75
129.62
134.28
138.74
143.03
147.16
151.13
Boiling T
3151 K
A^H
AftH
K
kJ
kJ
Molar Vol.
H598~H6
11.28 kJ
-1.083E+03
B= 1.718E-01
c-
2 .4618 J-bar'1
24 .618 cm3
1.932E+04
12/17/91
225
Formula wt
KARELIANITE
V2O3 :
149.881

Temp.
CP
ST
<HT-H$ 98 )/T
Jmol
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
Aft.H
104.96
105.33
117.82
123.52
127.11
129.99
132.67
135.32
138.04
140.84
143.74
146.73
149.80
152.95
156.17
159.46
162.80
98.10
98.75
131.04
158.01
180.86
200.68
218.21
233.99
248.39
261.68
274.05
285.68
296.66
307.11
317.08
326.65
335.85
-<G*-HJ98 ,/'I
0.00
0.65
28.62
47.09
60.14
69.92
77.60
83.86
89.14
93.72
97.76
101.41
104.76
107.87
110.79
113.55
116.19
UT
98.10
98.10
102.42
110.92
120.72
130.76
140.62
150.13
159.25
167.96
176.29
184.26
191.90
199.24
206.29
213.09
219.66
A fG
Log Kf
-1139.0
-1138.6
-1112.0
-1086.0
-1060.4
-1035.3
-1010.5
-986.0
-961.7
-937.8
-914.1
-890.5
-866.3
-844.1
-821.3
-798.5
-775.9
199.55
198.23
145.21
113.45
92.32
77.25
65.97
57.22
50.24
44.53
39.79
35.78
32.36
29.39
26.81
24.53
22.52
A fH
mol" 1
-1218.8
-1218.8
-1217.1
-1214.9
-1212.6
-1210.1
-1207.7
-1205.2
-1202.6
-1200.1
-1197.4
-1194.7
-1192.0
-1189.2
-1186.2
-1183.4
-1180.4
Boiling T
kJ
kJ
Molar Vol.
H298~H5
A= -1.197E+03
2 .985 Jbar!
cm3
29 .85
kJ
- 2.355E-01
C--1. 14E+06
6/11/93
226
Formula wt
TUNGSTEN DIOXIDE
WO2 :
215.849

Temp.
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
CP
55.78
55.98
63.60
67.83
70.74
73.02
74.97
76.72
78.35
79.90
81.39
82.85
84.28
85.69
87.09
88.47
89.85
ST
50.60
50.95
68.22
82.91
95.54
106.62
116.51
125.44
133.61
141.15
148.16
154.74
160.93
166.79
172.37
177.69
182.78
(isT-H298 )/T
_ l~l.it *
~(GT-H2 98 )/1
0.00
0.34
15.32
25.43
32.75
38.35
42.81
46.48
49.58
52.27
54.63
56.75
58.66
60.42
62.04
63.56
64.98
50.60
50.60
52.90
57.48
62.79
68.28
73.70
78.96
84.02
88.88
93.53
97.99
102.26
106.37
110.32
114.13
117.80
A fG
Log Kf
-533.9
-533.5
-514.9
-496.4
-478.2
-460.2
-442.4
-424.8
-407.3
-390.0
-372.9
-355.9
-339.1
-322.3
-305.8
-289.3
-273.0
93.53
92.89
67.24
51.86
41.63
34.34
28.89
24.65
21.28
18.52
16.23
14.30
12.65
11.22
9.98
8.89
7.92
A fH
kJ-mol" 1
-589.7
-589.7
-589.1
-588.1
-586.9
-585.6
-584.1
-582.6
-581.1
-579.4
-577.7
-575.9
-574.0
-572.0
-570.0
-567.9
-565.8
Boiling T
AV*H
AtoH
kJ
Molar Vol.
H298"H8
2. 003 J-bar'1
cm3
20. 03
kJ
A= -5.776E+02
kJ
B- 1.702E-01
C* -6.726E+05
9/10/92
Formula wt
ZINCITE
ZnOt
227
81.389

Temp.
CP
S|
(HT-H$ 98 )/T
i - UIW4.
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
A^H 0
40.42
40.53
44.56
46.74
48.22
49.38
50.37
51.28
52.13
52.94
53.74
54.52
55.29
56.06
56.82
57.58
58.34
43.20
43.45
55.73
65.93
74.59
82.11
88.77
94.76
100.20
105.21
109.85
114.18
118.25
122.09
125.74
129.20
132.52
2242 K
-(GT-H$g 8 )/T
A fH
A fG
Log Kf
-350.5
-350.5
-350.3
-349.9
-349.6
-356.6
-356.4
-356.1
-355.8
-355.5
-470.2
-468.6
-467.0
-465.3
-463.6
-461.8
-460.0
-320.4
-320.2
-310.1
-300.1
-290.2
-280.2
-269.4
-258.5
-247.7
-236.9
-224.2
-203.7
-183.4
-163.1
-143.0
-123.0
-103.3
56.12
55.75
40.49
31.35
25.26
20.91
17.59
15.00
12.94
11.25
9.75
8.18
6.84
5.68
4.67
3.78
3.00
- v
0.00
0.25
10.89
17.86
22.80
26.52
29.44
31.81
33.80
35.51
36.99
38.31
39.50
40.57
41.57
42.49
43.35
43.20
43.20
44.85
48.07
51.79
55.60
59.34
62.94
66.40
69.71
72.86
75.87
78.76
81.52
84.17
86.72
89.17
Boiling T
Av*H
kJ
kJ
Molar Vol.
H298~H5
6.93 kJ
1.434 J-bar'1
14.34 cm3
10/7/92
228
Formula wt
BAODELEYITE
ZrO2 :
123.223
Tetragonal crystals 1478 to 1800 K,

Temp.
r
CP
ST
(H*-H598 )/T
-(Gf-H2 9Q )/T
kJ
J-l. ,,-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1478
1500
1600
1700
1800
Melting T
56.18
56.35
63.21
67.51
70.45
72.57
74.16
75.38
76.32
77.06
77.63
78.08
78.41
78.62
74.48
74.48
74.48
74.48
50.40
50.75
67.99
82.59
95.17
106.20
116.00
124.80
132.80
140.11
146.84
153.07
158.87
163.13
168.28
173.09
177.60
181.86
0.00
0.35
15.28
25.33
32.62
38.18
42.58
46.16
49.13
51.64
53.78
55.64
57.25
58.37
62.60
63.34
64.00
64.58
50.40
50.40
52.70
57.26
62.55
68.02
73.41
78.64
83.66
88.47
93.05
97.43
101.62
104.75
105.68
109.75
113.60
117.28
AfG
Log K
-1042.9
-1042.5
-1023.2
-1004.1
-985.1
-966.4
-947.8
-929.4
-911.0
-892.8
-874.5
-856.1
-837.8
-822.5
-819.8
-802.1
-784.4
-766.7
182.70
A H
-1100.6
-1100.6
-1100.1
-1099.2
-1098.2
-1097.1
-1095.9
-1094.8
-1093.7
-1092.7
-1095.5
-1094.2
-1092.9
-1092.2
-1085.8
-1085.0
-1084.4
-1083.8
.-1
181.51
133.61
104.89
85.76
72.11
61.88
53.94
47.59
42.40
38.06
34.40
31.26
29.07
28.55
26.18
24.10
22.25
Boiling T
3123 K
K
kJ
kJ
Molar Vol.
H98~H8
8.75 kJ
-1.0934E+03
B= 1.81734E-01
2.115 J'bar'1
21.15 cm3
O -4.273.01E+05
9/9/92
Formula wt
CHRYSOBERYL
BeAl2O4 :
229
126.973

Temp.
CP
S|
(Hf-H2 9Q )/T
-(Gf-H2 98 )/T
J-mol"1 ^"1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
105.40
106.01
130.76
145.88
155.80
162.63
167.53
171.18
174.02
176.33
178.34
180.18
181.97
183.80
185.72
187.80
190.08
66.26
66.91
101.12
132.05
159.58
184.14
206.19
226.15
244.33
261.03
276.46
290.81
304.23
316.85
328.77
340.09
350.89
0.00
Log Rf
-2176,2
-2175.5
-2134.3
-2093.0
-2051.9
-2011.1
-1970.4
-1929.9
-1888.0
-1845.5
-1803.1
-1760.7
-1718.6
-1676.5
-1634.2
-1591.3
-1548.6
381.26
378.78
278.71
218.66
178.64
150.07
128.65
112.01
98.62
87.63
78.48
70.75
64.12
58.38
53.34
48.89
44.94
kJ-mol'1
66.26
66.26
70.76
79.98
91.00
102.58
114.18
125.53
136.51
147.09
157.23
166.96
176.29
185.25
193.85
202.12
210.09
0.65
30.36
52.07
68.58
81.57
92.01
100.62
107.82
113.95
119.23
123.85
127.94
131.60
134.92
137.97
140.80
A fG
A fH
-2298.5
-2298.5
-2299.3
-2298.9
-2297.8
-2296.5
-2295.1
-2293.8
-2314.0
-2312.7
-2311.3
-2309.8
-2308.5
-2307.0
-2320.1
-2318.1
-2316.1
Boiling T
Av*H
Aft.H 0
kJ
Molar Vol.
H2"98~H8
13 .09 kJ
A -2.308E+03
4.208E-01
kJ
3. 432 Jbar'!
34. 32 cm3
5.946E+05
7/17/92
230
Formula wt
CALCIUM FERRITE
CaFe2O4 :
215.770
Orthorhombic crystals 298.15 to melting point 1510 K,

Temp.
CP
CO
ST
J*mol~ *K~
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
Melting T
153.65
153.95
164.04
168.83
172.11
174.98
177.81
180.73
183.77
186.94
190.24
193.66
197.17
200.78
145.40
146.35
192.25
229.41
260.50
287.24
310.79
331.90
351.10
368.76
385.17
400.53
415.01
428.74
-<J-HJ 98 )/!r
(HT-H 98 )/T
0.00
0.95
40.65
65.85
83.30
96.19
106.22
114.33
121.12
126.96
132.10
136.70
140.89
144.77
kJ
145.40
145.40
151.59
163.56
177.20
191.05
204.58
217.57
229.98
241.80
253.07
263.83
274.12
283.97
A fG
Log Kf
-1412.4
-1411.7
-1375.8
-1340.5
-1305.6
-1270.9
-1236.1
-1201.4
-1166.6
-1131.4
-1095.3
-1059.1
-1023.0
-987.1
247.44
245.79
179.66
140.04
113.66
94.83
80.71
69.73
60.93
53.72
47.68
42.55
38.17
34.37
AfH
-1520.3
-1520.3
-1518.1
-1516.0
-1514.4
-1513.4
-1513.8
-1514.3
-1516.4
-1520.3
-1530.6
-1529.0
-1527.2
-1525.4
mol"" 1
Boiling T
1510 K
kJ
108.2 kJ
Molar Vol.
25.42 kJ
-1.519E+03
B 3.537E-01
4.498 J-bar"1
44.98 cm3
C- 1.473E+05
5/15/92
Formula wt
DICALCIUM FERRITE
231
271.847
Orthorhombic crystals 298.15 to melting point 1750 K.

Temp.
CP
ST
J * rool
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
Melting T
192.91
193.61
217.91
228.76
234.54
238.04
240.40
242.13
243.51
244.66
245.69
246.63
247.52
248.37
249.20
250.02
188.80
190.00
249.55
299.48
341.74
378.18
410.13
438.55
464.13
487.40
508.73
528.44
546.74
563.85
579.91
595.04
-<G*-H298 >/< T
\ **T **O Q ft 9 /
0.00
1.19
52.79
87.02
111.17
129.06
142.84
153.78
162.69
170.09
176.35
181.72
186.39
190.49
194.13
197.40
A fG
A fH
k_
188.80
188.80
196.76
212.45
230.57
249.12
267.29
284.77
301.45
317.31
332.38
346.72
360.36
373.36
385.77
397.64
-2138.3
-2138.3
-2135.4
-2131.9
-2128.7
-2126.1
-2126.2
-2125.7
-2127.3
-2131.2
-2149.8
-2148.0
-2146.4
-2144.9
-2143.7
-2144.4
.-1 ___
-1999.9
-1999.1
-1953.1
-1907.9
-1863.4
-1819.4
-1775.5
-1731.7
-1687.8
-1643.7
-1598.0
-1552.1
-1506.4
-1460.7
-1415.1
-1369.5
Boiling T
1750 K
Log Kf
350.37
348.06
255.04
199.31
162.22
135.76
115.92
100.50
88.16
78.05
69.56
62.36
56.20
50.86
46.20
42.08
K
kJ
31.65 kJ
Molar Vol.
H2"98~H8
25.42 kJ
A= -2.135E+03
B= 4.491E-01
6.718 J-bar'1
67.18 cm3
1.854E+05
7/22/92
232
Formula wt
PEROVSKITE
CaTiO3 :
135.956
Orthorhombic crystals 1530 K; cubic crystals 1530 to 1800 K.

Temp.
CP
ST
/tIO_tlQ
'
J*mol
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
97.65
98.17
114.28
119.98
122.60
124.31
125.83
127.43
129.21
131.20
133.39
135.76
138.31
141.01
134.01
134.01
134.01
93.64
94.25
125.13
151.34
173.47
192.50
209.20
224.11
237.62
250.03
261.54
272.31
282.46
292.10
302.46
310.58
318.28
V /I*
298 ' /
-<GT-H2 98 )/'I
Log Kf
-1574.8
-1574.3
-1545.6
-1517.4
-1489.4
-1461.7
-1434.1
-1406.7
-1379.3
-1352.0
-1323.9
-1295.6
-1267.5
-1239.4
-1211.8
-1184.1
-1154.3
275.89
274.10
201.83
158.51
129.66
109.07
93.64
81.64
72.04
64.20
57.63
52.06
47.29
43.16
39.56
36.38
33.50
kJ mol" 1
0.00
0.60
27.38
45.42
58.09
67.43
74.63
80.41
85.20
89.29
92.87
96.08
99.00
101.71
105.26
106.95
108.47
A fG
A fH
93.64
93.64
97.74
105.92
115.38
125.07
134.56
143.70
152.43
160.74
168.67
176.23
183.46
190.38
197.20
203.63
209.81
2188 K
-1660.6
-1660.6
-1659.5
-1657.8
-1656.2
-1654.8
-1654.4
-1653.4
-1652.7
-1652.4
-1664.1
-1662.5
-1660.8
-1658.9
-1655.3
-1654.4
-1802.2
Boiling T
AM,H
kJ
kJ
Molar Vol.
H298~H8
kJ
A -1.657B+03
B 2.783E-01
3.363
33.63
J-bar'1
cm3
C -4.73E+04
5/15/92
233
Formula wt
HERCYNITE
FeAl2O4 :
173.808
Temp.
eo
ST
CP
(Hf-H| 98 )/T
-(G-T-H2-98"I
A fH
- J-mol'^K"" 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
128.91
129.38
148.11
159.35
167.07
172.83
177.38
181.11
184.28
187.01
189.43
191.59
193.55
117.00
117.80
157.85
192.20
221.97
248.18
271.56
292.68
311.93
329.62
346.00
361.25
375.52
Melting T
0.00
0.80
35.52
59.24
76.60
89.95
100.61
109.35
116.69
122.96
128.40
133.18
137.42
AfG
Log Kf
V T - mo
l~l ^^^^^^
... ,.,
IIIW J.
117.00
117.00
122.34
132.96
145.37
158.22
170.95
183.33
195.24
206.66
217.60
228.07
238.10
-1950.5
-1950.5
-1950.1
-1948.9
-1947.5
-1946.0
-1944.7
-1943.9
-1965.2
-1965.7
-1965.2
-1963.1
-1961.0
Boiling T
322.03
319.92
235.02
184.10
150.18
125.97
107.82
93.71
82.36
73.02
65.25
58.67
53.04
-1838.1
-1837.4
-1799.7
-1762.3
-1725.1
-1688.1
-1651.4
-1614.7
-1576.7
-1537.8
-1498.9
-1460.1
-1421.6
kJ
kJ
Molar Vol.
H598~H8
A=
kJ
-1.955E+03
B=
3.799E-01
C-
4.075 Jbar-I
40.75 cm3
3.842E+05
7/17/92
234
Formula wt
CHROMITE
FeCr2O4 :
223.837

Temp.
cp
f>0
eo
ST
<HT-H$98 )/T
-(Of-HJse)/!T
Jmol~*K~*
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
AtoH
133.58
133.95
149.91
160.48
167.91
173.37
177.55
180.85
183.55
185.84
187.86
189.69
191.42
193.10
194.77
196.47
198.22
146.00
146.83
187.72
222.38
252.33
278.64
302.08
323.19
342.39
359.99
376.25
391.36
405.48
418.74
431.26
443.12
454.40
0.00
0.82
36.25
60.10
77.49
90.81
101.40
110.05
117.27
123.40
128.69
133.32
137.40
141.06
144.37
147.38
150.16
A fG
Log Kf
-1344.5
-1343.9
-1310.1
-1276.6
-1243.4
-1210.5
-1177.8
-1145.3
-1112.8
-1080.4
-1047.8
-1015.3
-982.9
-950.5
-918.1
-885.7
-853.2
235.55
233.99
171.08
133.36
108.25
90.33
76.90
66.47
58.13
51.30
45.62
40.80
36.67
33.10
29.97
27.21
24.76
A fH
kJ- mol' 1
146.00
146.00
151.47
162.27
174.84
187.83
200.67
213.13
225.11
236.59
247.56
258.04
268.08
277.68
286.89
295.74
304.24
-1445.5
-1445.5
-1444.7
-1443.4
-1441.7
-1440.1
-1438.6
-1437.5
-1437.3
-1438.0
-1438.3
-1437.3
-1436.6
-1436.3
-1436.4
-1437.8
-1439.1
Boiling T
kJ
kJ
Molar Vol.
H98~H8
kJ
A -1.437E+03
B 3.242E-01
4.401
44.01
J'bar'1
cm3
C= -4. 01E+05
5/15/92
Formula wt
ILMENITE
FeTiO3 :
235
151.725

Temp.
CP
CO
ST
<HT-H2 98 )/T
J"mol
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
99.18
99.47
111.62
119.20
124.35
128.16
131.26
134.02
136.71
139.50
142.50
145.81
149.48
153.58
158.15
108.90
109.51
139.94
165.72
187.94
207.41
224.73
240.35
254.61
267.77
280.03
291.57
302.51
312.96
323.01
*K
0.00
0.61
26.97
44.72
57.58
67.41
75.20
81.58
86.96
91.61
95.72
99.45
102.89
106.13
109.23
-(Gf-H2 9Q )/T
-
1. T
108.90
108.90
112.97
121.01
130.36
140.00
149.53
158.77
167.65
176.16
184.31
192.12
199.62
206.83
213.78
Melting T
A fG
Log Kf
-1155.0
-1155.0
-1129.5
-1104.2
-1079.2
-1054.6
-1030.1
-1005.8
-981.5
-957.3
-933.0
-908.5
-884.2
-860.2
-836.3
202.43
201.10
147.49
115.35
93.95
78.69
67.26
58.37
51.27
45.46
40.61
36.50
32.99
29.95
27.30
A H
-1232.0
-1232.0
-1231.1
-1229.7
-1228.1
-1226.6
-1225.2
-1224.1
-1223.6
-1224.1
-1227.7
-1225.1
-1222.3
-1219.4
-1216.3
mol"1
Boiling T
K
kJ
kJ
Molar Vol
16.992 kJ
A= -1.224E+03
B= 2.424E-01
3.169 Jbar'1
31.69 cm3
0 -3.82E-01
5/15/92
236
Formula wt
ULVOSPINEL
Fe2 TiO4 :
223.572
Temp.
CP
CO
ST
<Hf-H2 98 )/T
-<GT-H2 9Q )/T
A G
Log Kf
-1399.9
-1399.4
-1368.1
-1337.3
-1306.8
-1276.6
-1246.6
-1216.8
-1187.0
-1157.0
-1127.0
-1096.9
-1067.2
-1037.9
-1009.0
-980.6
-952.5
245.26
243.64
178.65
139.70
113.77
95.26
81.40
70.62
62.00
54.94
49.05
44.07
39.82
36.14
32.94
30.13
27.64
A H
kJ rool'1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
142.27
142.86
160.79
167.80
172.68
177.71
183.47
190.06
197.44
205.52
214.21
223.43
233.11
243.18
253.60
264.33
275.32
Melting T
180.40
181.28
225.33
262.05
293.08
320.07
344.16
366.15
386.55
405.74
423.99
441.50
458.41
474.83
490.86
506.55
521.97
0.00
0.88
39.04
64.17
81.85
95.18
105.85
114.83
122.72
129.87
136.53
142.86
148.96
154.90
160.74
166.52
172.26
180.40
180.40
186.29
197.88
211.22
224.89
238.32
251.31
263.83
275.87
287.45
298.63
309.45
319.93
330.11
340.03
349.71
Boiling T
A^H0
-1493.8
-1493.8
-1492.2
-1490.3
-1488.6
-1487.2
-1485.9
-1485.1
-1485.4
-1486.9
-1490.4
-1485.5
-1480.1
-1473.9
-1467.1
-1461.5
-1454.1
kJ
I*
Molar Vol.
H298"H8
kJ
-1.482E+03
B= 2.956E-01
kJ
4. 682 J-bar'1
46. 82 cm3
C= -5. 73E+05
5/26/93
237
Formula wt
SPINEL
MgAl204 :
142.266
FORMATION FROM THE ELgMENTS

Temp.
CP
Sf
(1Si-H5 98 )/I'
-(Gf-H$ 98 )/T
-1-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
115.94
116.46
137.26
149.86
158.57
165.13
170.33
174.63
178.29
181.48
184.31
186.85
189.17
191.29
193.27
195.12
196.85
88.70
89.42
126.06
158.14
186.28
211.24
233.64
253.96
272.55
289.70
305.61
320.46
334.40
347.52
359.93
371.70
382.91
Melting T
0.00
0.72
32.51
54.81
71.41
84.35
94.78
103.42
110.73
117.02
122.51
127.37
131.70
135.60
139.15
142.38
145.36
A fG
Log K
-2176.6
-2175.9
-2134.6
-2093.3
-2052.1
-2011.2
-1970.3
-1929.7
-1886.9
-1843.2
-1799.7
-1756.1
-1709.8
-1657.3
-1605.1
-1553.0
-1501.2
381.32
378.84
278.74
218.68
178.65
150.07
128.65
111.99
98.56
87.52
78.33
70.56
63.79
57.71
52.40
47.72
43.56
A fH
kJ'mol" 1
88.70
88.70
93.56
103.34
114.87
126.89
138.85
150.53
161.82
172.67
183.10
193.10
202.70
211.92
220.79
229.32
237.54
-2299.1
-2299.1
-2299.8
-2299.5
-2298.6
-2297.5
-2296.5
-2295.3
-2324.3
-2323.0
-2321.6
-2320.0
-2445.7
-2442.3
-2438.9
-2435.3
-2431.6
Boiling T
Av*H
Afc.H 0
kJ
kJ
Molar Vol.
H298~H5
15.41 kJ
**
-2.3446E+03
B= 4.598E-01
3 .971 J-bar-1
39 .71 cm3
C= 3.114E+06
5/21/93
238
Formula wt
MAGNESIOCHROMITE (picrochromite)
MgCr2O4 :
192.295

Temp.
CP
Sf
(1*-"39B>/.'
-<Gf-H2 98 )/T
l-l.v-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
A^H 0
126.82
127.37
147.88
158.71
165.47
170.18
173.72
176.54
178.86
180.85
182.60
184.16
185.57
186.88
188.09
189.23
190.31
106.00
106.79
146.60
180.87
210.44
236.32
259.29
279.92
298.64
315.79
331.60
346.28
359.98
372.83
384.93
396.36
407.21
0.00
0.78
35.31
59.00
76.22
89.32
99.66
108.05
115.02
120.92
125.99
130.40
134.29
137.76
140.86
143.68
146.24
kJ-
106.00
106.00
111.29
121.87
134.22
147.00
159.63
171.87
183.62
194.87
205.61
215.87
225.68
235.07
244.06
252.69
260.97
A6
Log Kf
-1669.1
-1668.4
-1630.0
-1591.8
-1554.0
-1516.4
-1479.2
-1442.1
-1404.5
-1366.8
-1329.1
-1291.6
-1250.9
-1204.0
-1157.2
-1110.5
-1063.8
292.41
290.48
212.85
166.29
135.28
113.16
96.58
83.70
73.36
64.90
57.85
51.89
46.67
41.93
37.78
34.12
30.87
AH
-1783.6
-1783.6
-1783.2
-1781.8
-1780.1
-1778.2
-1776.5
-1774.9
-1782.1
-1781.2
-1780.4
-1779.9
-1907.2
-1905.9
-1905.0
-1904.5
-1904.3
1i-l
Boiling T
Ay^H0
kJ
kJ
Molar Vol.
H298~H8
kJ
A -1.7945E+03
B 3.960E-01
4 .356 J'bar'1
43 . 56 cm
O 1.0556E+00
5/20/92
Formula wt
MAGNESIOFERRITE
MgFe2O4 :
239
Cubic (a) crystals 298.15 to 665 K.

1230 to 1800 K.
Cubic (0) crystals 665 to 1230 K.
199.997
y-crystals

Temp.
cp
ST
(H*-HJ98 ,/T
-(Gf-H| 98 )/T
J-mol""1 ^" 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
143.72
144.10
164.30
180.83
196.01
187.13
188.40
189.68
190.95
192.23
193.50
180.93
186.64
192.36
198.07
203.79
209.50
121.80
122.62
167.06
205.54
239.86
269.98
295.05
317.31
337.36
355.62
372.40
388.05
401.67
414.74
427.34
439.52
451.33
0.00
0.71
39.35
66.02
86.43
102.86
113.47
121.87
128.71
134.43
139.30
143.60
146.47
149.34
152.21
155.07
157.94
A fG
Log Kf
-1329.6
-1328.9
-1291.6
-1254.9
-1218.8
-1182.7
-1147.6
-1112.7
-1077.1
-1041.0
-1004.9
-968.8
-929.6
-884.4
-839.3
-794.3
-749.4
232.93
A fH
IcT-mol ""^
121.80
121.91
127.71
139.52
153.43
167.12
181.58
195.44
208.65
221.19
233.10
244.45
255.20
265.40
275.13
284.45
293.39
-1441.5
-1441.5
-1439.7
-1437.0
-1433.4
-1429.3
-1427.4
-1426.5
-1435.8
-1438.4
-1439.6
-1437.5
-1564.3
-1561.9
-1559.3
-1558.1
-1555.6
Boiling T
kJ
Av*H
Afa.H0
kJ
Molar Vol.
H298"H8
kJ
- -1.464E+03
B= 3.886E-01
231.38
168.66
131.09
106.10
88.25
74.93
64.58
56.26
49.43
43.74
38.93
34.68
30.80
27.40
24.40
21.75
4.457
44.57
Jbar*1
cm3
C* 1.938E+06
5/20/93
240
Formula wt
GEIKIELITE
MgTiO3 :
120.183

Temp.
CP
ST
(HT-H2 98 )/T
-<GT-H2 98 )/T
Jmol~^K~^ -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
93.03
93.37
106.87
114.55
119.39
122.69
125.10
127.01
128.65
130.19
131.72
133.32
135.06
136.97
139.09
141.44
144.04
74.64
75.22
104.13
128.87
150.22
168.88
185.43
200.28
213.75
226.08
237.47
248.08
258.02
267.41
276.31
284.81
292.97
0.00
0.57
25.64
42.72
55.12
64.55
71.98
77.99
82.97
87.20
90.84
94.05
96.91
99.52
101.93
104.18
106.32
AfG
Log Kf
-1484.4
-1483.8
-1454.2
-1424.8
-1395.7
-1366.8
-1338.1
-1309.6
-1280.5
-1251.3
-1222.0
-1192.7
-1160.3
-1121.9
-1083.6
-1045.5
-1007.7
260.05
258.35
189.90
148.85
121.50
101.99
87.37
76.00
66.88
59.42
53.19
47.92
43.29
39.07
35.38
32.12
29.24
A fH
UT
74.64
74.64
78.49
86.16
95.10
104.33
113.46
122.29
130.77
138.89
146.63
154.03
161.11
167.89
174.39
180.63
186.65
Melting T
-1572.8
-1572.8
-1572.3
-1571.2
-1569.8
-1568.4
-1566.9
-1565.5
-1572.9
-1572.0
-1575.1
-1573.7
-1699.6
-1696.7
-1693.7
-1690.7
-1687.6
Boiling T
K
kJ
kJ
Molar Vol.
H298~H5
13.64 kJ
A= -1.601E+03
B= 3.214E-01
3.086
30.86
J-bar'1
cm
O 2.118E+06
5/20/92
241
Formula wt 150.816
PYROPHANITE
MnTiO3 :

Temp.
cp
ST
-<G*-HJ98 >/'P
<HJ-H298 )/T
99.86
100.18
111.74
117.59
121.20
123.74
125.71
127.36
128.80
130.11
131.33
132.48
133.59
134.66
135.71
104.90
105.52
136.14
161.76
183.54
202.43
219.08
233.99
247.48
259.82
271.19
281.75
291.61
300.86
309.59
0.00
0.62
27.14
44.70
57.17
66.51
73.79
79.65
84.50
88.58
92.10
95.16
97.86
100.28
102.46
Log Kf
-1280.9
-1280.4
-1254.0
-1227.8
-1201.9
-1176.2
-1150.7
-1125.3
-1099.9
-1074.5
-1048.9
-1023.2
-997.6
-971.7
-945.2
224.41
222.94
163.75
128.27
104.63
87.77
75.13
65.31
57.45
51.02
45.66
41.11
37.22
33.84
30.86
-1
J-mol^-K'1 298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
A 6
A fH
104.90
104.90
109.00
117.06
126.37
135.92
145.29
154.34
162.99
171.24
179.10
186.59
193.75
200.58
207.13
-1360.1
-1360.1
-1359.2
-1358.0
-1356.7
-1355.5
-1354.3
-1353.4
-1354.8
-1354.2
-1357.8
-1356.8
-1358.2
-1359.8
-1371.7
Boiling T
Melting T
K
kJ
kJ
Molar Vol.
H298"H8
16.69 kJ
A= -1.355B+03
B 2.557E-01
3.277 Jbar'1
32.77 cm3
C -1.72E+05
2/24/94
242
Formula wt
TREVORITE
NiFe204 :
234.382

Temp.
CP
ST
(HT-H2 98 )/T
-<GT-H2 98 )/T
A fH
J-mol'i-K" 1 -
298.15
300
400
500
600
700
800
900
1000
146.87
147.18
164.04
181.00
198.00
215.02
232.05
249.09
266.13
140.90
141.81
186.46
224.88
259.38
291.18
321.01
349.32
376.45
0.00
0.91
39.58
66.17
86.72
103.83
118.80
132.33
144.86
kJ-m Q!
140.90
140.90
146.88
158.71
172.66
187.35
202.21
217.00
231.59
Melting T
-1070.5
-1070.5
-1068.8
-1066.4
-1063.2
-1059.0
-1053.7
-1047.6
-1041.6
A 6
Log Kf
-965.1
-964.5
-929.4
-894.8
-860.7
-827.3
-795.0
-762.5
-731.1
169.08
167.93
121.36
93.47
74.93
61.73
51.91
44.25
38.19
Boiling T
K
kJ
kJ
Molar Vol
HS98~H5
kJ
A= -1.053E+03
3.232E-01
4.365 Jbar'1
43.65 cm3
C* -8.04E+05
5/26/93
Formula wt
FRANKLINITE
ZnFe2O4 :
243
241.082
Temp.
CP
ST
(Hf-H2 98 )/T
-(Gf-H2 98 )/T
Log Kf
-1082.1
-1081.5
-1046.9
-1013.9
-982.0
189.58
188.30
136.71
105.91
85.49
kJ'mol"1
K
298.15
300
400
500
600
A fG
A H
193.37
193.61
203.23
209.32
214.01
150.70
151.90
209.05
255.09
293.68
0.00
1.19
50.62
81.78
103.44
150.70
150.70
158.43
173.31
190.24
Melting T
-1188.1
-1188.0
-1181.9
-1175.7
-1169.9
Boiling T
A^0
R
kJ
kJ
Molar Vol.
H298~H8
kJ
A= -1.167E+03
B= 3.112E-01
4.494 J-bar'1
44.94 cm3
O -7.364E-t-05
2/24/94
244
Zn2TiO4 :
Formula wt
242.658

Temp.
CP
CO
ST
(Hf-H2 98 )/T
-(GT-H 98 )/T
A fH
J-mol" 1 ^" 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
133.58
134.01
151.80
163.31
171.49
177.64
182.45
186.31
189.48
192.12
194.36
196.26
197.90
199.31
200.54
201.60
202.54
Melting T
143.10
143.93
185.13
220.32
250.85
277.77
301.82
323.54
343.34
361.52
378.34
393.97
408.58
422.28
435.18
447.37
458.93
0.00
0.83
36.53
60.81
78.61
92.33
103.31
112.32
119.89
126.34
131.91
136.79
141.10
144.93
148.37
151.47
154.28
A 6
Log K
-1538.4
-1537.7
-1499.7
-1461.9
-1424.5
-1387.3
-1348.4
-1309.8
-1271.5
-1233.5
-1191.6
-1134.2
-1077.3
-1020.7
-964.4
-908.5
-852.9
269.52
267.74
195.83
152.72
124.01
103.52
88.04
76.02
66.42
58.57
51.87
45.57
40.19
35.54
31.48
27.91
24.75
kJ-mol" 1
143.10
143.10
148.60
159.51
172.25
185.44
198.51
211.21
223.45
235.19
246.42
257.18
267.48
277.35
286.81
295.90
304.64
-1652.1
-1652.1
-1651.4
-1649.9
-1647.9
-1660.3
-1658.2
-1655.8
-1653.3
-1650.9
-1882.6
-1877.3
-1872.1
-1866.8
-1861.6
-1856.4
-1851.3
Boiling T
AV*H
kJ
kJ
Aft.H
Molar Vol.
kJ
H298"H5
-1.751E+Q3
B- 4.850E-01
4. 558 Jbar'1
45. 58 cm3
C= 6.790E+06
9/11/92
245
Formula wt
BROMARGYRITE
AgBr:
187.772

Temp.
CP
ST
(Hf-H 98 )/T
-(Gf-H2 98 )/T
1-1. K' 1
298.15
300
400
500
600
700
703
800
900
1000
Melting T
52.38
52.50
58.94
65.39
71.83
78.27
78.46
62.34
62.34
62.34
107.10
107.42
123.41
137.25
149.75
161.30
162.63
182.76
190.08
196.65
0.00
0.32
14.17
23.77
31.24
37.50
37.70
52.14
53.28
54.18
A fG
Log Kf
-97.0
-96.9
-92.8
-87.5
-82.6
-78.2
-78.3
-75.4
-72.7
-70.3
16.99
16.88
12.11
9.14
7.19
5.83
5.82
4.92
4.22
3.67
A fH
IrT
107.10
107.10
109.24
113.48
118.50
123.80
124.93
130.62
136.80
142.47
-100.4
-100.4
-114.6
-112.9
-110.5
-107.6
-107.5
-96.8
-95.3
-93.9
Boiling T
703 K
kJ
9.16 kJ
Molar Vol.
kJ
A= -1.0054E+02
B= 3.173E-02
2.899
28.99
J-bar'1
cm3
C- -5.577E+05
5/20/93
246
Formula wt
POTASSIUM BROMIDE
KBr:
119.002

Temp.
CP
(H-H 98 )/T
im*d
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
52.29
52.34
53.86
54.79
56.20
58.21
60.75
63.74
67.09
69.87
69.87
69.87
69.87
69.87
69.87
95.90
96.22
111.54
123.65
133.75
142.56
150.49
157.82
164.70
196.66
202.73
208.32
213.50
218.32
222.83
Melting T
0.00
0.32
13.56
21.71
27.33
31.59
35.07
38.09
40.82
66.62
66.89
67.12
67.32
67.49
67.64
~(GT-H 98 )/T
A fH
A fG
Log Kf
-393.8
-393.8
-411.2
-410.7
-410.1
-409.2
-408.2
-406.8
-405.2
-456.6
-453.6
-450.6
-447.6
-444.6
-441.6
-380.4
-380.3
-372.3
-362.6
-353.0
-343.6
-334.3
-325.1
-316.1
-305.1
-291.4
-278.0
-264.9
-251.9
-239.2
66.65
66.22
48.61
37.88
30.73
25.64
21.83
18.87
16.51
14.49
12.68
11.17
9.88
8.77
7.81
*x
95.90
95.90
97.98
101.94
106.42
110.97
115.42
119.73
123.89
130.04
135.84
141.20
146.18
150.83
155.19
Boiling T
1007 K
kJ
A^H0
25.5 kJ
Molar Vol.
HS98"H5
*.-
-4.330E+02
4.328
43.28
12.21 kJ
B= 1.198E-01
J*bar'*
cm3
C= 1.642E+06
4/8/93
Formula wt
CHLORARGYRITE
AgCl:
247
143.321
Cubic crystals 298.15 to melting point 728 K; liquid 728 to 1000 K.

Temp.
ST
(HT-H2 98 )/T
-<Gf-H2 98 )/T
t,T..-~ <|
298.15
300
400
500
600
700
728
800
900
1000
Melting T
50.79
50.95
56.65
59.70
61.71
63.22
63.81
66.94
66.94
66.94
96.23
96.54
112.08
125.08
136.15
145.78
148.97
172.34
180.20
187.27
0.00
0.31
13.77
22.68
29.03
33.81
34.93
53.92
55.37
56.52
96.23
96.23
98.31
102.40
107.13
111.98
114.04
118.42
124.83
130.75
A fG*
Log K
-109.8
-109.7
-104.1
-98.8
-93.8
-89.1
-88.3
-85.9
-83.5
-81.3
19.24
19.10
13.59
10.32
8.17
6.65
6.33
5.61
4.84
4.25
A fH'
-127.1
-127.1
-125.9
-124.5
-122.9
-121.2
-120.7
-106.4
-104.4
-102.5
Boiling T
728 K
kJ
1289 kJ
Molar Vol
H298"H5
12.033 kJ
A= -1.102E+02
B= 3.084E-02
2.573
25.73
J-bar
cm3
O -8.08E+05
5/20/92
248
Formula wt
HYDROPHILITE
CaCl2 :
110.983

Temp.
CP
ST
/uo_uo
|Xlm **298 \'I/IP
J*mol
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
72.83
72.93
75.71
76.86
78.00
79.45
81.26
83.40
85.81
102.53
102.53
102.53
102.53
102.53
102.53
102.53
102.53
104.60
105.05
126.50
143.52
157.63
169.76
180.48
190.18
199.09
235.46
244.37
252.58
260.17
267.24
273.86
280.07
285.93
-(Gf-H2 98 )/T
Log Kf
-747.7
-747.4
-731.5
-715.9
-700.5
-685.4
-670.3
-655.3
-640.4
-627.1
-614.6
-602.2
-590.1
-578.2
-566.4
-554.9
-541.4
130.99
130.13
95.52
74.78
60.99
51.14
43.76
38.03
33.45
29.78
26.75
24.20
22.02
20.13
18.49
17.05
15.71
*K
0.00
0.45
18.99
30.46
38.28
44.06
48.59
52.34
55.56
85.12
86.57
87.80
88.85
89.76
90.56
91.26
91.89
A fG
A fH
104.60
104.60
107.51
113.07
119.35
125.71
131.89
137.84
143.53
150.34
157.80
164.78
171.32
177.48
183.30
188.81
194.04
-795.8
-795.8
-794.4
-793.1
-792.0
-790.9
-790.8
-789.8
-788.9
-758.7
-764.4
-761.4
-758.4
-755.4
-752.5
-749.5
-895.3
Boiling T
1045 K
kJ
Av*H
AUHO
28 .54 kJ
Molar Vol.
H598-H8
50.75
15.27 kJ
A= -7.714E+02
5.075
B- 1.293E-01
J'bar'1
cm3
C- -1.447E+06
3/04/94
Formula wt
LAWRENCITE
FeCl2 :
249
126.752
Rhombohedral crystals 298.15 to 950 K; liquid 950 to 1300 K.

Temp.
CP
Jmol
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
Melting T
(H*-HS98 ,/T
76.34
76.54
81.04
81.49
81.92
83.17
85.31
88.28
102.17
102.17
102.17
102.17
117.95
118.42
141.27
159.42
174.30
187.01
198.25
208.46
263.64
273.34
282.21
290.41
-<GT-H2 98 )/T
0.00
0.47
20.23
32.45
40.65
46.63
51.32
55.25
102.17
102.16
102.16
102.15
kJ
117.95
117.95
121.04
126.96
133.65
140.39
146.93
153.21
161.47
171.18
180.05
188.26
A fG
Log K
-302.2
-302.0
-289.1
-276.6
-264.4
-252.5
-240.7
-229.1
-219.8
-212.8
-206.0
-199.4
52.95
52.58
37.75
28.89
23.02
18.84
15.72
13.30
11.48
10.11
8.97
8.01
A fH
-341.7
-341.6
-339.8
-338.1
-336.6
-335.4
-334.3
-333.3
-289.4
-288.6
-287.1
-284.1
--1
Boiling T
950 K
1347
124.81
K
kJ
43.01 kJ
Molar Vol.
HS98"H5
16.27 kJ
A -3.136E+02
9.168E-02
3.946 J-bar'1
39.46 cm3
C* -1.52E+06
3/26/93
250
Formula wt
MOLYSITE
FeCl3 :
162.205
Crystals 298.15 to melting point 577 K; liquid 577 to boiling point 605 K; Ideal gas
(dimer) 605 to 700 K.
Temp.
C>Op
CO
ST
(Hf-H2 98 )/T
-(GT-H2 98 )/T
A fH
Melting T
Log Kf
-333.8
-333.4
-311.8
-290.8
-272.3
-263.3
58.47
58.04
40.71
30.38
23.71
19.64
kJ'mol' 1
K
298.15
300
400
500
600
700
AfG
96.67
96.67
107.70
119.86
133.89
71.13
142.26
142.86
171.86
197.34
294.42
344.71
0.00
0.60
25.72
43.46
128.55
154.70
142.26
142.26
146.14
153.88
165.87
190.01
-399.2
-359.4
-396.9
-393.7
-346.8
-324.5
Boiling T
577 K
605
21.88
K
kJ
43.10 kJ
Molar Vol.
H298~H5
19.71 kJ
A- -3.455E+02
B= 1.274E-01
5.786 J-bar1
57.86 cm3
C* -2.375E+06
5/21/92
251
Formula wt
HYDROGEN CHLORIDE
HC1:
36.461
Ideal gas at p - 1 bar, 298.15 to 1800 K.

Temp.
cp
ST
(H*-H298 ,/T
1
J . fflOl
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
29.14
29.13
29.05
29.27
29.64
30.10
30.60
31.12
31.64
32.16
32.66
33.15
33.61
34.05
34.46
34.83
35.17
186.90
187.08
195.44
201.94
207.31
211.91
215.96
219.60
222.90
225.94
228.76
231.40
233.87
236.20
238.41
240.51
242.52
-(GT-H2 98 )/T
k_
1 . If 1
IV
0.00
0.18
7.40
11.75
14.70
16.86
18.55
19.92
21.06
22.05
22.91
23.68
24.37
25.00
25.58
26.12
26.61
186.90
186.90
188.04
190.19
192.61
195.05
197.41
199.68
201.84
203.89
205.85
207 . 72
209.50
211.20
212.83
214.40
215.90
A fG
Log K
-95.3
-95.3
-96.3
-97.2
-98.0
-98.7
-99.4
-100.1
-100.8
-101.4
-102.0
-102.6
-103.2
-103.8
-104.4
-104.9
-105.5
16.70
16.60
12.57
10.15
8.53
7.37
6.49
5.81
5.26
4.82
4.44
4.12
3.85
3.61
3.41
3.22
3.06
A fH
-92.3
-92.3
-92.6
-92.9
-93.3
-93.6
-93.9
-94.1
-94.4
-94.6
-94.8
-94.9
-95.0
-95.2
-95.3
-95.3
-95.4
,-1
Boiling T
Melting T
kJ
kJ
Molar Vol.
8.64 kJ
-9.476E+01
B= -6.043E-03
2478.97 J'bar'1
24789.7 cm3
O 1.185E+05
3/04/93
252
SYLVITE
KC1:
Formula wt
74.551
Cubic crystals 298.15 to 1043 K, melting point; liquid 1043 to fictive boiling point
1475 K.

Temp.
CP
ST
Jmol
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
Melting T
51.29
51.36
53.41
54.63
56.10
57.99
60.26
62.87
65.75
66.94
66.94
66.94
66.94
82.59
82.91
98.01
110.06
120.15
128.93
136.82
144.07
150.84
182.80
189.20
195.10
200.54
-<G*-H298 )/1!
(H*-H598 ,/T
0.00
0.32
13.38
21.51
27.14
31.41
34.87
37.83
40.48
67.19
67.72
68.18
68.56
A fG
Log Kf
-408.6
-408.4
-398.6
-388.8
-379.0
-369.3
-359.8
-350.5
-341.3
-329.1
-315.2
-301.7
-288.4
71.58
71.10
52.06
40.61
32.99
27.56
23.49
20.34
17.83
15.63
13.72
12.12
10.76
A fH
V T mnl-1
82.59
82.59
84.64
88.56
93.00
97.52
101.95
106.23
110.36
115.61
121.48
126.92
131.98
-436.5
-436.5
-438.4
-437.9
-437.2
-436.4
-435.3
-434.0
-432.4
-482.9
-479.5
-476.1
-472.7
Boiling T
1043 K
1750
155.39
K
kJ
26.28 kJ
Molar Vol.
H298~H8
11.37 kJ
A= -4.584E+02
B= 1.207E-01
3.752 J'bar'1
37.52 cm3
C- 1.373E+06
3/26/93
Formula wt
CHLORMAGNESITE
MgCl2 :
253

1710 K.
95.210
Liquid 987 to boiling point

Temp.
ST
CP
<H*-H5 98 ,/T
-<G*-H298 ,/1?
Jmol*"*K~*
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
Melting T
71.04
71.16
75.63
78.16
79.92
81.32
82.53
83.63
92.47
92.47
92.47
92.47
92.47
92.47
92.47
92.47
89.60
90.04
111.20
128.37
142.78
155.21
166.15
175.94
228.82
237.65
245.68
253.09
259.91
266.31
272.29
277.90
987
0.00
0.44
18.74
30.39
38.51
44.53
49.20
52.97
99.37
98.74
98.22
97.78
97.40
97.07
96.78
96.53
kJmQ!
89.60
89.60
92.46
97.98
104.27
110.68
116.95
122.97
129.45
138.28
146.94
154.87
162.13
168.91
175.22
181.12
AfG
Log Kf
-591.8
-591.5
-575.0
-559.0
-543.2
-527.7
-512.4
-497.3
-482.4
-470.5
-459.4
-448.5
-434.6
-414.8
-395.1
-375.7
103.68
102.98
75.09
58.40
47.29
39.38
33.46
28.86
25.20
22.34
20.00
18.02
16.22
14.44
12.90
11.54
A fH
-641.3
-641.3
-639.9
-638.5
-637.0
-635.4
-633.9
-632.5
-596.4
-594.3
-592.3
-590.2
-715.6
-712.2
-708.8
-705.5
Boiling T
kJ
43.1
kJ
Molar Vol.
H298~H8
13.76 kJ
A= -6.293E+02
B= 1.445E-01
4.081 J-bar'
40.81 cm3
-4.868E+05
4/23/93
254
Formula wt
SCACCHITE
MnCl2 :
125.844
Rhombohedral crystals 298.15 to 923 K; liquid 923 to 1400 K.

Temp.
CP
ST
( H-H98 )/T
-<Gf-H2 98 )/T
J mol~*lr""l
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
Melting T
73.01
73.11
77.24
79.80
81.73
83.36
84.84
86.23
94.56
94.56
94.56
94.56
94.56
118.24
118.69
140.35
157.88
172.60
185.33
196.56
206.63
257.19
266.19
274.43
282.00
288.99
0.00
0.45
19.19
31.07
39.36
45.53
50.35
54.26
95.73
95.62
95.54
95.46
95.40
A fG
Log Kf
-440.5
77.17
76.65
55.73
43.21
34.89
28.96
24.53
21.09
18.51
16.44
14.73
13.29
12.05
A fH
kJ-mol"1
118.24
118.24
121.17
126.81
133.25
139.80
146.21
152.37
161.46
170.57
178.89
186.54
193.59
-481.3
-481.3
-479.9
-478.6
-477.2
-475.9
-474.6
-473.3
-436.1
-434.2
-432.3
-430.5
-431.0
-440.2
-426.8
-413.6
-400.8
-388.1
-375.7
-363.4
-354.4
-346.3
-338.4
-330.6
-322.9
Boiling T
923 K
kJ
37. 53 kJ
Molar Vol.
H298~H8
15 .071 kJ
A* -4.505E+02
B* 9.437E-02
4.211
42.11
cm3
C- -1.734E+06
3/26/93
255
HALITE
NaCl:
Formula wt
58.442
Cubic crystals 298.15 to 1073.8 K; liquid 1073.8 to fictive boiling point 1791 K,
Temp.
CP
CO
ST
<HT-H298 )/T
Jmol
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
Melting T
50.51
50.54
52.34
54.14
55.93
57.73
59.53
61.32
63.12
68.46
68.14
67.82
67.50
67.17
66.85
66.53
72.12
72.43
87.22
99.09
109.12
117.88
125.70
132.82
139.37
171.89
177.83
183.27
188.29
192.93
197.26
201.30
0.00
0.31
13.09
21.12
26.77
31.07
34.51
37.39
39.87
67.93
67.96
67.96
67.94
67.90
67.85
67.78
-<GT-H2 98 )/T
A fG
Log Kf
-384.2
-384.0
-374.8
-365.2
-355.6
-346.3
-337.0
-327.9
-319.0
-310.8
-302.4
-288.3
-274.5
-260.9
-247.4
-234.2
67.30
66.86
48.94
38.15
30.96
25.84
22.00
19.03
16.66
14.76
13.16
11.59
10.24
9.08
8.08
7.19
A H
IrT
72.12
72.12
74.12
77.97
82.35
86.81
91.19
95.43
99.50
103.96
109.87
115.31
120.35
125.03
129.41
133.52
-411.3
-411.2
-413.5
-413.0
-412.4
-411.5
-410.4
-409.1
-407.6
-377.5
-472.3
-469.5
-466.7
-463.9
-461.2
-458.5
Boiling T
1074 K
kJ
28.16 kJ
Molar Vol
H298-H5
10.61 kJ
A- -4.283E+02
B- 1.1044E-01
2.702
27.02
Jbar
cm3
0 1.132E+06
5/21/92
256
Formula wt
NICKELOUS CHLORIDE
129.595
Rhombohedral crystals 298.15 to melting point,

Temp.
CP
ST
(HT-H2 98 )/T
-(GT-H| 98 )/T
J-mol'^K" 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
Melting T
71.68
71.88
77.21
78.34
78.89
79.74
81.06
82.87
85.11
87.72
90.66
93.87
98.20
98.64
120.25
137.63
151.96
164.18
174.91
184.55
193.40
201.63
209.39
216.77
1303
0.00
0.44
19.14
30.89
38.84
44.62
49.09
52.74
55.86
58.63
61.18
63.57
A fG
Log Kf
-258.8
-258.5
-243.2
-228.3
-213.6
-199.0
-184.6
-170.3
-156.2
-142.3
-128.5
-114.9
45.33
45.00
31.76
23.85
18.59
14.85
12.05
9.89
8.16
6.76
5.59
4.62
A fH
1. T
98.20
98.20
101.11
106.74
113.12
119.56
125.82
131.82
137.54
143.00
148.21
153.20
-304.9
-304.9
-303.6
-302.3
-301.3
-300.4
-299.2
-297.8
-296.4
-294.7
-292.9
-290.9
Boiling T
kJ
77.17
kJ
Molar Vol
H298"H5
14.43
A - -2.965E+02
kJ
B - 1.403E-01
3.670 J-bar'1
36.70 cm3
C - -3.75B+05
4/8/93
257
Formula wt
COTUNNITE
PbCl2 :
278.105
Orthorhombic crystals 298.15 to 768 K; liquid 768 to 1000 K.

Temp.
CP
ST
<HT-H2 98 )/T
-<GT-H2 98 )/T
i-l-l
298.15
300
400
500
600
700
768
800
900
1000
Melting T
73.18
73.33
79.98
84.51
87.85
90.45
91.89
113.80
113.80
113.80
136.00
136.45
158.53
176.89
192.61
206.35
215.09
250.41
263.80
275.77
0.00
0.45
19.56
32.12
41.15
48.01
51.72
83.99
87.31
89.96
1v T
136.00
136.00
138.97
144.77
151.46
158.34
163.37
166.42
176.49
185.81
AfG
Log Kf
-314.1
-313.8
-298.9
-284.3
-270.2
-255.6
-246.2
-242.4
-231.7
-221.5
55.03
54.64
39.03
29.70
23.52
19.07
16.74
15.82
13.45
11.57
A fH
-359.4
-359.4
-357.9
-356.0
-354.0
-356.6
-355.0
-329.7
-325.0
-320.3
AAJ
-i-l
Boiling T
768 K
K
kJ
23.85 kJ
Molar Vol
H298"H8
16.94 kJ
A- -3.405E+02
B 1.218E-01
4.709 J'bar'1
47.09 cm3
0 -9.24E+05
5/21/92
258
Formula wt
FLUORITE
CaF2 :
78.075
Cubic crystals 298.15 K to transition at 1424 K.

Temp.
CP
CO
ST
<H*-H2 98 >/T
J*mol
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
Melting T
67.68
67.38
69.99
79.35
83.72
83.92
82.48
81.73
83.53
89.33
100.22
117.06
140.52
68.90
69.32
88.47
105.16
120.09
133.05
144.17
153.82
162.50
170.70
178.90
187.54
197.03
-<*-H598 )Ar
Log K
-1175.3
-1175.0
-1157.4
-1140.1
-1123.1
-1106.5
-1089.9
-1073.5
-1057.1
-1040.9
-1024.1
-1007.4
-991.1
205.90
204.57
151.14
119.10
97.77
82.56
71.16
62.30
55.22
49.43
44.58
40.48
36.98
kJ- mo l~l
0.00
0.42
16.98
28.58
37.48
44.13
49.02
52.68
55.65
58.41
61.40
65.00
69.51
A fG
AfH
68.90
68.90
71.49
76.58
82.62
88.92
95.15
101.14
106.85
112.29
117.49
122.54
127.52
1691 K
-1228.0
-1228.0
-1227.2
-1225.8
-1224.0
-1222.3
-1221.8
-1220.8
-1220.0
-1219.3
-1225.8
-1222.2
-1216.7
Boiling T
Av.pH 0
K
kJ
kJ
Molar Vol.
H598~H8
11.64 kJ
A* -1.221E+03
1.643E-01
2.454 J-bar'1
24.54 cm3
C= -2.93E+05
11/25/92
Formula wt
HYDROGEN FLUORIDE
HF:
259
20.006

Temp.
cp
CO
ST
Jmol
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
29.14
29.15
29.21
29.15
29.18
29.32
29.55
29.86
30.20
30.59
30.99
31.40
31.81
32.22
32.63
33.02
33.39
173.78
173.96
182.36
188.87
194.19
198.70
202.63
206.13
209.29
212.18
214.86
217.36
219.70
221.91
224.00
225.99
227.89
~(GT-H2 98 )/1?
<HT-H2 98 )/T
K
0.00
0.18
7.44
11.79
14.68
16.76
18.34
19.61
20.65
21.53
22.31
22.99
23.60
24.17
24.68
25.16
25.61
AfG
Log K
-275.4
-275.4
-276.1
-276.7
-277.3
-277.9
-278.3
-278.8
-279.2
-279.6
-279.9
-280.2
-280.5
-280.8
-281.0
-281.2
-281.5
48.25
47.95
36.05
28.91
24.14
20.73
18.17
16.18
14.58
13.28
12.18
11.26
10.47
9.78
9.17
8.64
8.17
AfH
kJ mol~*
173.78
173.78
174.93
177.09
179.51
181.94
184.28
186.52
188.64
190.65
192.56
194.37
196.10
197.75
199.32
200.83
202.28
-273.3
-273.3
-273.5
-273.7
-274.0
-274.3
-274.6
-275.0
-275.3
-275.6
-276.0
-276.3
-276.6
-276.9
-277.2
-277.5
-277.8
Boiling T
Melting T
kJ
kJ
Molar Vol.
H298~H5
8.599 kJ
A* -2.759E+02
B= -3.234E-03
2478.97 J-bar'1
24789.7 cm3
C= 1.443E+05
11/19/92
260
Formula wt
SELLAITE
MgF2 :
Tetragonal crystals 298.15 to melting point 1536 K.
62.302
Temp.
CP
ST
(HT-H2 98 )/T
-<GT-H2 98 )/T
AfH
,-!_-!
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
61.51
61.69
68.61
72.56
75.16
77.02
78.44
79.57
80.50
81.28
81.95
82.53
83.04
83.49
94.56
94.56
94.56
57.20
57.58
76.38
92.15
105.63
117.36
127.74
137.05
145.48
153.19
160.29
166.88
173.01
178.75
222.46
228.19
233.59
1536
0.00
0.38
16.67
27.48
35.22
41.07
45.66
49.36
52.43
55.02
57.24
59.16
60.85
62.34
100.45
100.10
99.80
A fG
Log Kf
-1071.1
-1070.7
-1053.0
-1035.5
-1018.2
-1001.2
-984.3
-967.5
-950.2
-932.7
-915.3
-898.0
-877.7
-851.3
-827.5
-805.2
-783.2
187.64
186.42
137.51
108.18
88.64
74.71
64.27
56.15
49.63
44.29
39.84
36.08
32.75
29.64
27.01
24.74
22.73
kJ mol~*
57.20
57.20
59.72
64.67
70.40
76.29
82.09
87.68
93.05
98.17
103.06
107.71
112.16
116.41
122.01
128.09
133.79
-1124.2
-1124.2
-1123.4
-1122.4
-1121.2
-1120.0
-1118.9
-1117.7
-1125.3
-1124.3
-1123.3
-1122.3
-1248.7
-1246.3
-1185.0
-1181.4
-1177.9
Boiling T
kJ
58.69
kJ
Molar Vol.
H298~H8
9.914
kJ
A= -1.145E+03
B= 1.963E-01
1.961 J-bar'1
19.61 cm
C= 1.628E+06
11/19/92
Formula wt
VILLIAUMITE
NaF:
261
41.988
Liquid 1269 to 1800 K,

Temp.
CP
ST
(HT-H5 98 )/T
-<GT-H 98 )/T
,-!--!
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
46.86
46.94
49.72
51.19
52.53
54.02
55.71
57.59
59.63
61.82
64.12
68.51
68.51
68.51
68.51
68.51
68.51
51.50
51.79
65.74
77.00
86.45
94.66
101.98
108.65
114.82
120.60
126.08
157.48
162.55
167.28
171.70
175.85
179.76
0.00
0.29
12.36
19.98
25.29
29.29
32.48
35.17
37.51
39.62
41.56
69.57
69.49
69.43
69.37
69.32
69.27
A fG
Log Kf
-543.4
-543.2
-532.9
-522.2
-511.5
-500.9
-490.4
-480.0
-469.8
-459.6
-447.1
-429.0
-413.7
-398.6
-383.7
-369.0
-354.5
95.20
94.58
69.59
54.55
44.53
37.38
32.02
27.86
24.54
21.82
19.46
17.24
15.44
13.88
12.53
11.34
10.29
A fH
kJ mol"1
51.50
51.50
53.38
57.02
61.16
65.37
69.49
73.48
77.31
80.98
84.52
87.91
93.06
97.85
102.33
106.53
110.49
-573.6
-573.6
-576.0
-575.7
-575.3
-574.7
-573.9
-573.0
-571.8
-570.5
-665.8
-629.2
-626.4
-623.5
-620.6
-617.8
-615.0
Boiling T
1269 K
kJ
33.14 kJ
Molar Vol
H2*98"H8
8.49 kJ
A -6.018E+02
B 1.344E-01
1.498 J-bar14.98 cm3
1.835E+06
11/19/92
262
Formula wt
CRYOLITE
209.941
Monoclinic (a) crystals 298.15 to 836 K transition to cubic (0) crystals. Cubic
crystals 836 to 1153 K. y crystals 1153 to melting point 1290 K. Liquid 1290
to 1800 K.
Temp.
CP
Sf
(HT-H2 98 )/T
-(G$-H2 98 )/T
A fH
k-T-
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
217.37
217.73
238.77
251.60
262.30
281.11
315.99
279.88
284.68
289.47
300.41
396.91
396.91
396.91
396.91
396.91
396.91
238.50
239.85
305.46
360.26
407.03
448.71
488.31
532.93
562.66
590.02
617.49
730.45
759.86
787.23
812.84
836.89
859.57
0.00
1.34
58.16
95.69
122.52
143.68
162.84
186.63
196.20
204.46
213.76
308.67
314.97
320.43
325.21
329.43
333.18
238.50
238.50
247.31
264.57
284.51
305.03
325.47
346.30
366.46
385.56
403.73
421.78
444.89
466.80
487.63
507.46
526.39
-3316.8
-3316.8
-3323.0
-3320.4
-3317.0
-3312.3
-3305.1
-3290.1
-3295.5
-3289.9
-3571.9
-3447.8
-3429.0
-3410.1
-3391.4
-3372.6
-3354.0
A fG
Log Kf
-3152.1
-3151.0
-3095.4
-3038.8
-2982.8
-2927.4
-2872.9
-2820.0
-2767.3
-2714.7
-2655.4
-2580.3
-2514.3
-2449.6
-2386.2
-2323.9
-2262.7
552.22
548.63
404.21
317.45
259.67
218.44
187.58
163.66
144.54
128.91
115.58
103.67
93.81
85.30
77.90
71.40
65.66
1""1
Boiling T
1290 K
AV*H
AIU.H"
kJ
113. 75 kJ
Molar Vol.
H298-H0
38 .223 kJ
A- -3.370E+03
B= 6.097E-01
7 .081 J-bar*1
70 .81 cm3
C* -3.62E+06
11/19/92
Formula wt
CHIOLITE
Na5Al3F 14 :
263
461.871
Tetragonal crystals 298.15 to melting point 1010 K.
Temp.
cp
ST
Melting T
AfH
A fG
Log Kf
-7546.3
-7546.3
-7556.5
-7552.3
-7546.5
-7539.6
-7532.1
-7524.1
-7547.6
-7174.7
-7172.4
-7047.1
-6920.2
-6794.3
-6669.5
-6545.7
-6422.9
-6298.8
1256.95
1248.79
920.24
722.94
591.49
497.67
427.38
372.77
329.01
- J-mol'^K""1 -
298.15
300
400
500
600
700
800
900
1000
-<GT-H 98 )/T
<HT-H298 )/T
453.91
455.08
499.34
524.54
542.23
556.38
568.64
579.80
590.28
515.30
518.11
655.82
770.16
867.43
952.11
1027.22
1094.85
1156.48
0.00
2.80
122.04
200.20
255.80
297.76
330.87
357.91
380.63
515.30
515.31
533.78
569.96
611.63
654.35
696.35
736.94
775.85
Boiling T
1010 K
kJ
80.831 kJ
Molar Vol
H2*98~H8
38.223 kJ
A= -7.5366E+03
B= 1.239E+00
15.408 J-bar'1
154.08 cm3
O -7.07E+05
11/20/92
264
Formula wt
IODARGYITE
Agl:
234.773
Hexagonal crystals 298.15 to 423 K; cubic crystals 423 to 831 K.

Temp.
CP
ST
Q
\ / ft
i1I tl TO _U 298
//
i*mol
298.15
300
400
500
600
700
800
Melting T
54.41
54.60
64.68
56.48
56.48
56.48
56.48
115.48
115.82
132.91
160.54
170.88
179.54
187.07
831
0.00
0.34
15.16
36.15
39.54
41.96
43.78
-<G$-HJ98 ,/T
A fH
AfG
Log Kf
-66.3
-66.3
-67.6
-66.3
-62.9
-59.6
-56.5
11.61
11.54
8.82
6.93
5.47
4.45
3.69
kJ mol"1
115.48
115.48
117.74
124.39
131.34
137.58
143.29
-61.8
-61.8
-69.3
-84.0
-82.8
-81.8
-80.8
Boiling T
K
kJ
kJ
Molar Vol
H298"H5
kJ
A* -9.280E+01
B 4.399E-02
4.130 J-bar'1
41.30 cm3
O 1.196B+06
11/19/92
265
Formula wt
MARSHITE
Cul:
Cubic crystals 298.15 to transition point at 643 K.

679 K. Cul melts at 868 K.
190.450
There is a second transition at

Temp.
ST
CP
(HT-H|98 )/T
-<GT-H2 98 )/T
A H
Melting T
54.06
54.14
57.20
60.59
76.90
68.62
68.62
65.75
63.45
61.43
59.68
58.20
56.99
96.60
96.93
112.92
125.89
137.85
163.05
172.22
189.35
196.15
202.11
207.38
212.09
216.36
868
0.00
0.33
14.17
22.98
30.12
49.32
51.74
62.33
62.56
62.55
62.38
62.11
61.79
Log Kf
-69.4
-69.4
-69.7
-66.3
-60.4
-55.6
-51.9
-48.8
-46.5
-44.4
-42.5
-40.5
-38.3
12.16
12.09
9.10
6.92
5.26
4.15
3.39
2.83
2.43
2.11
1.85
1.63
1.43
kJ-mol"1
J-mol'^K'1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
A fG
96.60
96.60
98.75
102.91
107.73
113.73
120.48
127.02
133.59
139.56
145.00
149.98
154.57
-67.8
-67.8
-75.5
-96.4
-94.3
-82.4
-80.1
-70.1
-68.3
-66.9
-65.8
-65.0
-77.6
Boiling T
K
kJ
7. 93 kJ
Molar Vol.
HS98-H&
kJ
A -7.665E+01
B 2.882E-02
3 .335 J-bar'1
33 .35 cm3
O -2.219E+05
11/19/92
266
Formula wt
WITHERITE
BaCO3 :
197.336
Orthorhombic crystals 298.15 to 1079 K; tetragonal crystals 1079 to 1241 K; cubic

crystals 1241 to 1600 K.

Temp.
ST
\ IT
(Iio_tiQ
T 2 98''
-<Gf-H2 98 )/T
j. mol~lK~*
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
Melting T
85.32
85.75
99.75
106.60
112.19
118.01
124.41
131.45
139.07
154.81
154.81
158.98
158.98
158.98
158.98
112.13
112.66
139.57
162.62
182.55
200.28
216.45
231.50
245.74
275.81
289.28
304.39
316.17
327.13
337.39
0.00
0.53
23.87
39.77
51.38
60.48
68.06
74.71
80.76
102.47
106.83
113.13
116.40
119.24
121.73
A G
Log Kf
-1132.2
-1131.7
-1105.5
-1079.4
-1053.5
-1027.6
-1001.8
-976.2
-950.8
-925.3
-901.3
-877.7
-854.7
-831.8
-809.3
198.35
197.05
144.36
112.77
91.71
76.68
65.41
56.65
49.66
43.94
39.23
35.27
31.89
28.97
26.42
A fH e
kJ mol"1
112.13
112.13
115.71
122.84
131.17
139.80
148.38
156.79
164.98
173.34
182.45
191.26
199.77
207.89
215.66
-1210.9
-1210.8
-1209.9
-1209.3
-1209.3
-1208.3
-1207.4
-1205.7
-1203.4
-1191.2
-1187.4
-1180.3
-1176.1
-1172.0
-1167.8
Boiling T
kJ
Aft,H
kJ
Molar Vol.
H298-H8
kJ
A -1.196E+03
4.581
45.81
B 2.438E-01
J'bar'1
cm3
C* -9 . 15E+05
9/11/92
Formula wt
ARAGONITE
CaCO3 :
267
100.087
Orthorhombic crystals 298.15 to 1000 K,
Temp.
flO
Cp
_/f<o_tiQ
\ /n*
\ T
298''
82.31
82.55
92.67
99.80
105.76
111.17
116.28
121.22
126.06
87.99
88.50
113.75
135.22
153.96
170.67
185.85
199.84
212.86
0.00
0.51
22.38
37.18
48.13
56.75
63.87
69.97
75.34
A fG
Log Kf
-1127.4
-1126.9
-1100.2
-1073.6
-1047.3
-1021.2
-995.0
-969.1
-943.2
197.51
196.21
143.66
112.16
91.17
76.20
64.97
56.24
49.27
AH
- J-mol""1 ^"1
K
298.15
300
400
500
600
700
800
900
1000
/tio_uo
\ /IP
***T
298''
CO
ST
kJ-mol" 1
87.99
87.99
91.37
98.04
105.83
113.92
121.98
129.86
137.52
-1207.4
-1207.4
-1206.7
-1205.8
-1204.8
-1203.7
-1203.4
-1202.2
-1201.0
Boiling T
Melting T
K
kJ
kJ
Molar Vol
14.31 kJ
A -1.203E+03
B 2.598E-01
3.415 J-bar'1
34.15 cm3
C- -1.96E+05
9/18/92
268
Formula wt
CALCITE
CaCO3 :
100.087

Temp.
CP
CO
ST
/HO_UO
' T
\ /rp
2 98 * /
-(Gf-H2 98 )/T
83.47
83.82
97.00
104.55
109.88
114.16
117.88
121.28
124.48
127.55
130.53
91.71
92.23
118.36
140.88
160.43
177.70
193.19
207.28
220.22
232.23
243.46
0.00
0.52
23.18
38.75
50.18
59.02
66.15
72.09
77.17
81.61
85.57
Log Kf
-1128.5
-1128.0
-1101.6
-1075.6
-1049.9
-1024.4
-999.0
-973.8
-948.7
-923.7
-898.2
197.70
196.39
143.86
112.37
91.40
76.44
65.23
56.52
49.55
43.86
39.10
~i-l
J B mol~ *K~
298.15
300
400
500
600
700
800
900
1000
1100
1200
A 6
A fH
kJ*m<?<L
91.71
91.71
95.19
102.13
110.25
118.68
127.04
135.18
143.05
150.62
157.89
Melting T
-1207.4
-1207.4
-1206.3
-1204.9
-1203.5
-1202.0
-1201.6
-1200.3
-1199.1
-1198.1
-1204.9
Boiling T
kJ
kJ
Molar Vol
14.48 kJ
A -1.200E+03
B 2.518E-01
3.693 J-bar'1
36.93 cm3
C -3.036E+05
10/14/92
Formula wt
DOLOMITE
CaMg(C03 ) 2 :
269
184.401
Temp.
CP
-(GT-H2 98 )/T
A fG
Log Kf
-2324.5
-2324.5
-2323.4
-2321.4
-2318.8
-2316.0
-2313.9
-2310.8
-2316.2
-2312.9
-2161.3
-2160.3
-2105.7
-2051.4
-1997.7
-1944.4
-1891.4
-1838.7
-1785.7
-1732.9
378.64
376.13
274.97
214.31
173.91
145.09
123.47
106.72
93.28
82.28
j-mol"1 -*"1 -
K
298.15
300
400
500
600
700
800
900
1000
1100
A fH
157.51
158.06
183.54
201.89
215.66
226.65
236.08
244.73
253.15
261.72
155.18
156.16
205.32
248.35
286.43
320.53
351.42
379.73
405.96
430.48
0.00
0.97
43.61
73.52
96.12
114.00
128.69
141.10
151.89
161.48
155.18
155.18
161.71
174.83
190.32
206.53
222.74
238.63
254.07
269.00
Melting T
Boiling T
kJ
Afi.H 0
kJ
Molar Vol.
H ^98~H6
25.98 kJ
A -2.314E+03
B 5.283E-01
6.434
64.34
J-bar'1
cm3
O -4.81E+05
5/22/92
270
Formula wt
SIDERITE
FeCO3 :
115.856
Temp.
C>Op
CO
<Hf-H2 98 )/T
ST
-(Gf-HSga)/ T
AfH
82.27
82.52
94.34
102.56
108.09
95.47
95.98
121.43
143.43
162.65
0.00
0.51
22.57
37.80
49.08
Log Kf
682.8
682.4
658.0
633.8
609.9
119.63
118.81
kJ'mol"1
- J-mol"1 ^"1
298.15
300
400
500
600
AfG
95.47
95.47
98.86
105.63
113.56
755.9
755.9
755.1
754.0
752.9
Boiling T
Melting T
85.92
66.21
53.09
kJ
kJ
Molar Vol
14.59 kJ
A= -7.525E+02
B 2.383E-01
2.938 Jbar!
29.38 cm3
C- -1.23E+05
5/22/92
Formula wt
MAGNESITE
MgC03 :
271
84.314

Temp.
CP
ST
(HT-H2 98 )/T
-(Gf-H2 98 )/T
76.09
76.44
90.57
99.92
107.38
113.96
120.06
125.88
131.54
65.09
65.56
89.67
110.94
129.83
146.89
162.51
176.98
190.54
0.00
0.47
21.39
36.20
47.46
56.50
64.07
70.61
76.42
Log Kf
-1029.5
-1029.0
-1000.9
-973.0
-945.3
-917.9
-890.7
-863.7
-836.3
180.36
179.15
130.70
101.65
82.30
68.49
58.16
50.13
43.68
i. J-mol"1
Jraol~1 -K~1 -
298.15
300
400
500
600
700
800
900
1000
A6
A fH
65.09
65.09
68.28
74.73
82.37
90.39
98.44
106.37
114.12
Melting T
-1113.3
-1113.3
-1112.9
-1111.9
-1110.6
-1109.1
-1107.3
-1105.3
-1111.6
Boiling T
kJ
kJ
Molar Vol
HS98~H5
11.63 kJ
A= -1.108E+03
2.718E-01
2.802
28.02
J-bar'1
cm3
C= -2.42E+05
5/22/92
272
Formula wt
RHODOCHROSITE
MnCO3 :
114.947
Temp.
CP
ST
(HT-H2 98 )/T
-<GT-H2 98 )/T
J-mol"1 -*,""1 -
298.15
300
400
500
600
Melting T
80.78
81.03
92.38
100.87
107.70
98.03
98.53
123.49
145.05
164.07
0.00
0.50
22.13
37.06
48.29
1. T
98.03
98.03
101.36
107.99
115.78
A 6
Log Kf
-819.1
-818.7
-794.0
-769.5
-745.2
143.50
142.54
103.68
80.38
64.87
A fH
-892.9
-892.9
-892.4
-891.6
-890.6
mol"1
Boiling T
kJ
kJ
Molar Vol
H2*98'H5
14.12 kJ
A -8.894E+02
B 2.425E-01
3.107
31.07
J-bar'1
cm3
C= -9.44E+04
5/22/92
Formula wt
DAWSONITE
NaAlC03 (OH) 2 :
273
143.995
Temp.
CP
CO
ST
(Hf-H| 98 )/T
-<G5,-H2 98 )/ T
Melting T
Log Kf
-1786.0
-1784.9
-1722.9
-1656.9
312.89
310.77
224.98
173.09
kJ'mol'1
K
298.15
300
400
500
AfG
A fH
34.52
34.52
34.55
34.58
132.00
132.21
142.15
149.86
0.00
0.21
8.79
13.95
132.00
132.00
133.35
135.91
-1964.0
-1964.2
-1980.2
-1994.4
Boiling T
kJ
kJ
Molar Vol
H298~H5
22.17 kJ
A -2.010E+03
6.937E-01
5.93 J'bar'1
59.3 cm3
C= 1.518E+06
7/17/92
274
Formula wt
STRONTIANITE
SrCO3 t
147.629
Orthorhombic crystals 298.15 to 1197 K; hexagonal crystals 1197 to 1400 K.

Temp.
CP
( HT-H298 )/T
Sf
-<GT-H2 98 )/T
Melting T
81.50
82.03
97.72
102.86
106.05
109.46
113.64
118.69
124.54
131.11
144.77
144.77
144.77
0.00
97.07
97.58
123.80
146.24
165.28
181.87
196.75
210.42
223.22
235.40
262.84
274.42
285.15
0.50
23.26
38.74
49.69
57.98
64.67
70.38
75.50
80.25
100.48
103.89
106.81
Log Kf
-1137.6
-1137.1
-1110.0
-1083.2
-1056.6
-1030.3
-1004.1
-978.0
-952.0
-925.9
-899.7
-875.1
-850.8
199.29
197.97
144.94
113.16
91.99
76.88
65.56
56.76
49.73
43.97
39.16
35.16
31.74
i-l
J mol"1 ^" 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
A fG
A fH
97.07
97.07
100.54
107.50
115.58
123.89
132.09
140.04
147.72
155.15
162.36
170.53
178.34
-1218.7
-1218.7
-1217.7
-1216.4
-1215.2
-1214.1
-1213.0
-1212.4
-1210.6
-1216.3
-1195.5
-1192.6
-1189.9
Boiling T
kJ
kJ
3. 901 J-bar'1
Molar Vol.
H298~H8
39. 01
kJ
A - -1.210E+03
B 2.577E-01
cm3
C - -4.37E+05
7/17/92
275
Formula wt
SMITHSONITE
ZnCO3 :
125.399

Temp.
cp
CO
ST
<HT-H2 98 )/T
-(GT-H2 9Q )/T
J-mol" 1 ^' 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
Melting T
80.05
80.29
91.77
101.01
108.79
115.57
121.64
127.19
132.34
137.18
141.77
81.19
81.69
106.42
127.92
147.05
164.34
180.17
194.82
208.49
221.34
233.47
0.00
0.49
21.93
36.86
48.21
57.36
65.02
71.63
77.44
82.66
87.39
1. T
81.19
81.19
84.49
91.07
98.83
106.98
115.15
123.20
131.05
138.68
146.08
A fG
Log Kf
-735.3
-734.8
-707.5
-680.4
-653.5
-626.8
-599.4
-572.2
-545.3
-518.6
-490.3
128.82
127.94
92.39
71.08
56.89
46.77
39.13
33.21
28.48
24.63
21.34
A fH
mol" 1
-817.0
-817.0
-816.4
-815.4
-814.0
-819.7
-817.9
-815.7
-813.2
-810.3
-922.2
Boiling T
A^0
kJ
kJ
Molar Vol.
H298"H5
13.49 kJ
A* -8.163E+02
B* 2.71IE-01
2.828
28.28
J-bar'1
cm3
C- 1.690E+04
5/22/92
276
Formula wt
NITROBARITE
Ba(NO3 ) 2 :
261.337
Temp.
CP
ST
-<GT-H2 9Q )/T
151.35
151.85
174.94
193.67
210.68
226.88
242.65
213.80
214.74
261.75
302.85
339.68
373.38
404.71
0.00
0.93
41.70
70.26
92.26
110.34
125.90
A fG'
Log Kf
-796.6
-795.4
-730.0
-665.2
-600.9
-537.3
-474.4
139.55
138.48
95.33
69.49
52.31
40.09
30.98
A fH
kJ-mol" 1
J-mol'^-K" 1 -
K
298.15
300
400
500
600
700
800
(HT-H2 9Q )/T
213.80
213.80
220.06
232.59
247.42
263.04
278.81
Melting T
-992.1
-992.1
-990.5
-988.0
-984.9
-979.6
-973.6
Boiling T
K
kJ
kJ
Molar Vol
H298~H5
kJ
A- -9.791E+02
B= 6.323E-01
8.058
80.58
J-bar'1
cm3
C- -5.41E+05
5/22/92
Formula wt
CALCIUM NITRATE
Ca(NO3 ) 2 :
277
164.088
Temp.
CP
CO
ST
(HT-H2 98 )/T
-(GT-H^ 98 )/T
A fH
A fG
Log Kf
-938.4
-938.4
-936.6
-933.1
-928.4
-922.5
-916.3
-742.6
-741.4
-675.9
-611.2
-547.2
-484.1
-421.8
130.10
129.08
88.27
63.85
47.64
36.12
27.54
K
298.15
300
400
500
600
700
800
Melting T
149.11
149.66
173.76
192.74
210.08
226.83
243.37
193.30
194.22
240.79
281.65
318.34
351.98
383.35
0.00
0.92
41.30
69.73
91.69
109.81
125.47
193.30
193.30
199.49
211.92
226.64
242.18
257.88
Boiling T
kJ
kJ
Molar Vol
H298~H6
kJ
A- -9.217E+02
B 6.267E-01
6.609
66.09
J-bar'1
cm3
C= -6.975+05
5/22/92
278
Formula wt
NITER
KNO3 :
101.103
Orthorhombic crystals 298.15 to 401 K; Rhombohedral crystals 401 to 610 K; liquid

610 to 700 K.

Temp.
ST
CP
(HT-H2 98 )/T
l~l
298.15
300
400
500
600
700
Melting T
96.27
96.27
108.41
120.50
120.50
123.43
133.09
133.69
163.09
204.68
226.64
262.08
610
0.00
0.60
26.05
56.74
67.36
89.73
-(GT-H2 98 )/T
A 6
Log Kf
-394.5
-393.9
-360.1
-328.1
-296.6
-267.0
69.12
68.59
47.03
34.27
25.82
19.92
A fH
-1
kJ-mol~
133.09
133.09
137.05
147.94
159.28
172.35
-494.5
-494.4
-495.6
-486.8
-484.0
-471.1
Boiling T
kJ
10.10
kJ
Molar Vol
H298~H5
kJ
A* -4.736E+02
B- 2.981E-01
4.804
48.04
J'bar'
cm3
C= -8.83E+05
5/22/92
Formula wt
MAGNESIUM NITRATE
Mg(N03 ) 2 :
279
148.315
Temp.
CP
CO
ST
-<GT-H2 9Q )/ T
A fH
A fG
Log Kf
-790.7
-790.6
-789.5
-786.0
-780.4
-589.2
-587.9
-520.5
-453.6
-387.6
103.22
102.37
67.97
47.38
33.74
- J-mol'^K' 1
K
298.15
300
400
500
600
(HT-H2 98 )/T
141.92
142.40
168.77
195.63
222.70
164.01
164.89
209.45
249.99
288.05
0.00
0.88
39.54
68.07
91.58
164.01
164.01
169.91
181.92
196.47
Melting T
Boiling T
R
kJ
kJ
Molar Vol.
H298"H5
kJ
A= -7.811E+02
B= 6.577E-01
6.293
62.93
J'bar'1
cm3
C= -3.732+05
5/22/92
280
Formula wt
AMMONIA-NITER
NH4NO3 :
K.
80.043
Ammonia-niter undergoes phase changes at 305.3, 357.4, 398.4 K. It melts at 442.8

Temp.
CP
ST
(HT-H2 98 )/T
-(GT-H 9Q )/T
A H
J-mol"1 ^"1 -
298.15
300
400
500
Melting T
139.37
139.37
190.79
161.08
151.08
151.94
208.94
260.24
0.00
0.86
51.26
86.69
A 6
Log Kf
-183.8
-182.7
-122.3
-64.5
32.20
31.81
15.97
6.74
lr T
151.08
151.08
157.68
173.55
-365.6
-365.6
-358.5
-349.1
Boiling T
442.8 K
kJ
5.44 kJ
Molar Vol
H298"H5
kJ
A* -3.384E+02
B= 5.556E-01
4.649
46.49
J'bar'1
cm3
C= -9.90E+05
5/22/92
281
Formula wt
SODA NITER
NaN03 t
84.995
a-crystals 298.15 to 549.2 K. jJ-crystala 549.2 to 583.2 K. Liquid 583.2 to 700 K.
Temp.
c
CP
**
(Hf-H2 98 )/T
!
298.15
300
400
500
600
700
93.07
93.48
115.76
138.07
154.81
154.81
116.52
117.10
147.04
175.27
234.63
258.48
0.00
0.58
26.59
46.56
94.82
103.39
-<GT-H2 98 )/T
A H
_1
A G
Log Kf
-367.1
-366.5
-332.6
-298.9
-266.7
-238.1
64.32
63.81
43.43
31.22
23.22
17.77
VT mol" 1
116.52
116.52
120.45
128.62
139.81
155.09
Melting T
-468.0
-468.0
-469.1
-465.5
-441.2
-435.1
Boiling T
K
kJ
kJ
Molar Vol
H298~H5
kJ
A- -4.447E+02
B- 2.995E-01
3.76
37.6
Jbar'
cm3
C- -1.05E+06
5/22/92
282
Formula wt
STRONTIUM NITRATE
Sr(N03 ) 2 :
211.630
Temp.
CP
CO
ST
/tIO_tIQ
\ /P
298 / /
-(Gf-H2 9Q )/T
A fG
Log Kf
-779.0
-777.8
-711.1
-644.9
-579.7
-515.5
-452.4
-390.1
136.47
135.42
92.86
67.37
50.47
38.47
29.54
22.64
A fH
kJ-
298.15
300
400
500
600
700
800
900
149.93
149.88
169.18
197.81
220.32
234.85
242.20
243.53
194.56
195.49
240.55
281.44
319.61
354.76
386.68
415.33
0.00
0.92
39.98
68.73
92.23
111.66
127.58
140.44
213.80
213.80
220.06
232.59
247.42
263.04
278.81
274.89
Melting T
-978.2
-978.2
-977.0
-973.6
-968.0
-961.1
-953.4
-946.4
Boiling T
kJ
Afc.H 0
kJ
Molar Vol.
H298~H6
kJ
A* -9.566E+02
B= 6.317E-01
7.093
70.93
J'bar'1
cm3
C= -9.810+05
5/22/92
Formula wt
ALUMINUM SULFATE
A12 (SO4 ) 3 :
283
342.154
Temp.
CP
ST
(HT-H2 98 )/T
-(GT-H2 98 )/T
K
298.15
300
400
500
600
700
800
900
1000
1100
Melting T
A fH
kJ*mol
259.26
260.62
317.35
352.93
376.60
392.79
403.92
411.44
416.28
419.06
239.30
240.91
324.34
399.26
465.84
525.19
578.41
626.45
670.07
709.89
0.00
1.60
74.05
126.52
166.35
197.62
222.75
243.33
260.40
274.71
239.30
239.30
250.30
272.74
299.49
327.57
355.66
383.12
409.67
435.18
-3441.8
-3441.9
-3449.3
-3451.1
-3449.7
-3446.5
-3442.2
-3596.9
-3609.7 .
-3600.9
A fG
Log Kf
-3100.6
-3098.5
-2983.5
-2866.9
-2750.1
-2633.7
-2517.9
-2399.4
-2265.3
-2131.3
543.20
539.48
389.60
299.49
239.41
196.53
164.40
139.25
118.32
101.20
-1
Boiling T
kJ
kJ
Molar Vol
H298~H5
40.22 kJ
-3.501E+03
B= 1.233E+00
7.341
73.41
J-bar'1
cm3
C 3.117E+06
6/10/93
284
Formula wt
BARITE
BaSO4 :
233.391

Temp.
CP
ST
<HT-H2 98 )/T
-(Gf-H2 98 )/T
J-mol"1 ^' 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
Melting T
101.75
102.23
119.28
127.17
131.46
134.04
135.72
136.87
137.69
138.30
138.76
139.12
132.21
132.84
164.94
192.50
216.10
236.57
254.59
270.65
285.11
298.27
310.32
321.44
0.00
0.63
28.47
47.51
61.17
71.41
79.35
85.68
90.85
95.13
98.75
101.84
A fG
Log Kf
-1362.5
-1361.8
-1324.4
-1286.4
-1248.0
-1209.5
-1170.9
-1131.1
-1086.5
-1041.1
-995.8
-950.6
238.70
Af H
- kJ'mol' 1
132.21
132.21
136.47
144.99
154.93
165.16
175.24
184.96
194.27
203.13
211.57
219.60
-1473 .6
-1473 .6
-1476 .0
-1477 .5
-1479 .0
-1479 .4
-1480 .1
-1533 .5
-1532 .4
-1539 .8
-1539 .1
-1538 .3
Boiling T
AV*H
AtoH
H298"H8
kJ
kJ
Molar Vol.
kJ
A= -7.496E+01
B= -9.007E-02
237.11
172.95
134.39
108.65
90.25
76.45
65.65
56.75
49.44
43.35
38.19
5.21
52.10
J'bar'1
car
O= 4.067E-01
5/22/92
Formula wt
ANHYDRITE
CaSO4 :
285
136.142
Temp.
CP
ST
<HT-H2 98 )/T
-(GT-H| 98 )/T
AfG
Log Kf
-1321.8
-1321.1
-1283.2
-1244.7
-1206.3
-1167.9
-1129.5
-1090.2
-1046.3
231.57
230.02
167.56
130.03
105.01
87.15
73.75
63.27
54.65
AfH
1, T--.-.1 "I
298.15
300
400
500
600
700
800
900
1000
Melting T
101.23
101.57
116.68
127.18
135.03
141.54
147.55
153.59
160.04
107.40
108.03
139.45
166.68
190.59
211.91
231.20
248.93
265.44
0.00
0.63
27.87
46.74
60.83
71.90
80.98
88.71
95.52
107.40
107.40
111.58
119.94
129.77
140.01
150.22
160.21
169.92
-1434.4
-1434.5
-1436.6
-1437.2
-1437.0
-1436.1
-1435.8
-1487.3
-1484.2
Boiling T
1723 K
K
kJ
28.03 kJ
Molar Vol
17.30 JcJ
A- -1.4465E+02
B 3.971E-01
4.601 J-bar'1
46.01 cm3
C= 5.860E+05
9/16/92
286
Formula wt
CHALCOCYANITE
159.610
CuS04 : Crystals 298.15 to 1200 K.
Temp.
CP
ST
(H*-H298 )/T
1*1.
298.15
300
400
500
600
700
800
900
1000
1100
1200
139.89
140.42
160.73
172.71
181.41
188.56
194.88
200.72
206.27
211.62
216.84
109.50
110.37
153.87
191.11
223.40
251.91
277.51
300.81
322.24
342.15
360.79
0.00
0.86
38.57
64.28
83.11
97.67
109.44
119.26
127.68
135.07
141.67
-(Gf-H 98 )/T
"I
1, T
109.50
109.50
115.30
126.83
140.29
154.24
168.08
181.55
194.56
207.08
219.12
Melting T
A fG
Log Kf
-662.3
-661.6
-625.5
-590.1
-555.6
-522.0
-489.3
-456.4
-419.4
-383.3
-348.1
116.03
A fH
-771.4
-771.3
-769.2
-765.1
-759.9
-753.9
-747.3
-793.4
-784.6
-775.6
-766.1
mol" 1
Boiling T
115.19
81.69
61.65
48.37
38.95
31.95
26.49
21.91
18.20
15.15
K
kJ
kJ
Molar Vol
H298~H8
16.87 kJ
A* -7.631E+02
B 3.445E-01
4.088 J-bar'1
40.88 cm3
0 -1.35E+05
11/25/92
287
Formula wt
FERRIC SULFATE
Fe2 (SO4 ) 3 :
399.885
Temp.
cp
sf
(HT-H2 98 )/T
-(GT-H2 9Q )/T
A fH
A fG
Log Kf
-2581.9
-2581.9
-2588.8
-2591.1
-2590.4
-2587.4
-2582.5
-2254.4
-2252.4
-2142.1
-2030.2
-1918.0
-1806.2
-1694.9
394.96
392.16
279.73
212.09
166.98
134.78
110.66
K
298.15
300
400
500
600
700
800
Melting T
275.03
276.04
319.44
351.71
379.61
405.44
430.16
282.80
284.50
370.29
445.15
511.78
572.26
628.02
0.00
1.70
76.08
128.08
167.72
199.85
227.10
282.80
282.81
294.21
317.07
344.07
372.41
400.92
Boiling T
K
kJ
kJ
Molar Vol
H2*98~H8
kJ
A -2.592E+03
B* 1.121E+00
13.08 J-bar'1
130.80 cm3
O 2.722E+05
6/10/93
288
Formula wt
ARCANITE
K2SO4 :
Orthorhombic crystals (a) 298.15 to 856 K.

point 1342 K. Liquid 1342 to 1700 K.
174.260
Hexagonal crystals (0) 856 to melting

Temp.
CP
Sf
-(OJ-HJss)/-r
130.01
130.44
149.06
163.03
175.17
186.44
197.25
203.55
189.91
197.63
219.88
252.38
197.61
197.61
197.61
197.61
175.56
176.37
216.62
251.43
282.25
310.11
335.71
368.88
389.40
407.72
425.78
444.61
485.93
499.57
512.32
524.30
0.00
0.80
35.70
59.81
78.04
92.73
105.12
125.49
132.41
137.86
143.69
150.77
180.08
181.25
182.28
183.18
A fG
Log Kf
-1319.6
-1318.9
-1278.2
-1236.3
-1194.5
-1152.9
-1111.7
-1069.8
-1024.5
-970.4
-910.9
-852.1
-795.0
-740.1
-685.5
-631.3
231.18
229.63
166.91
129.15
103.99
86.03
72.59
62.09
53.51
46.08
39.65
34.24
29.66
25.77
22.38
19.40
Afn
J-mol" 1 ^" 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
<Hf-H2 98 )/T
kJ mol" 1
175.56
175.56
180.93
191.62
204.21
217.38
230.59
243.39
256.99
269.86
282.09
293.84
305.85
318.32
330.04
341.12
Melting T
-1437.7
-1437.7
-1445.2
-1445.8
-1444.9
-1442.6
-1439.3
-1479.5
-1474.8
-1628.5
-1620.8
-1610.5
-1567.7
-1561.4
-1555.0
-1548.8
Boiling T
K
kJ
kJ
Molar Vol.
H298"H8
25.43 kJ
A* -1.541E+03
B*
5.285E-02
6.550 J-bar"1
65.50 cm3
0 6.26776E+06
5/27/92
289
Formula wt
K-A1 SULFATE
KA1(SO4 ) 2 :
258.207

Temp.
CP
ST
(Hf-H2 98 )/T
-(Gf-H 98 )/T
J-mol'^K"" 1 -
298.15
300
400
500
600
700
800
900
1000
192.98
193.95
230.89
252.19
267.33
279.58
290.27
300.06
309.29
204.60
205.80
267.25
321.23
368.61
410.76
448.80
483.57
515.66
0.00
1.19
54.52
92.07
120.08
142.01
159.89
174.92
187.90
A fG
Log K
-2240.4
-2239.0
-2160.8
-2081.2
-2001.4
-1921.9
-1842.6
-1761.6
-1670.5
392.50
389.83
282.17
217.42
174.24
143.41
120.31
102.24
87.25
A fH
kJ mol' 1
204.60
204.60
212.73
229.16
248.53
268.75
288.92
308.64
327.76
Melting T
-2470.9
-2470.9
-2478.5
-2480.1
-2479.7
-2477.9
-2475.2
-2577.9
-2581.9
Boiling T
kJ
kJ
Molar Vol
H298"H8
32.22 kJ
A -2.499E+03
B= 8.218E-01
9.233 J-bar'1
92.33 cm3
C= 1.235E+06
5/27/92
290
Formula wt
ALUNITE
414.214
KA1 3 (OH) 6 (S04 ) 2 : Crystals 298.15 to 700 K.
Temp.
CP
SJ
<H*-HJ 98 >,T
-(Oi-HJ 98 ,/ T
Log Kf
-4663.5
-4660.3
-4487.0
-4312.1
-4137.6
-3963.8
817.00
811.41
585.92
450.48
360.20
295.77
kJ'mol' 1
K
298.15
300
400
500
600
700
A fG
A fH
372.53
374.90
462.28
508.84
539.32
562.22
321.00
323.31
444.70
553.29
648.92
733.84
0.00
2.30
107.73
183.69
240.57
284.94
321.00
321.01
336.96
369.60
408.35
448.90
Melting T
-5176.5
-5176.6
-5185.9
-5186.2
-5183.0
-5177.7
Boiling T
A^ 0
K
kJ
kJ
Molar Vol.
kJ
A* -5.116E+03
B= 1.594E+00
29.360 J-bar'1
293.60 cm3
O -2.065E+06
11/25/92
Formula wt
LANGBEINITE
291
414.997
K2Mg2 (S04 ) 3 : Cubic crystals 298.15 to 1203 K.

Temp.
CO
ST
CP
/UO_UO
* T
\ /f
298* /
-<0*-HJ 98 )/'.r
J-mol'^-K" 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
Melting T
318.92
319.93
363.71
393.92
416.52
434.14
448.13
459.30
468.13
474.96
480.00
389.30
391.28
489.76
574.34
648.25
713.84
772.75
826.21
875.08
920.03
961.58
0.00
1.97
87.32
145.78
189 . 10
222.90
250.21
272.85
291.95
308.29
322.40
A6
Log Kf
-3733.4
-3731.3
-3616.5
-3499.1
-3381.1
-3263.3
-3145.7
-3025.2
-2889.0
-2744.0
-2593.8
654.05
649.66
472.25
365.54
294.35
243.50
205.39
175.57
150.90
130.30
112.90
AfH
kJ mol" 1
389.30
389.31
402.44
428.56
459.15
490.93
522.54
553.36
583.12
611.73
639.18
-4071.0
-4071.1
-4084.4
-4088.1
-4088.9
-4087.6
-4085.1
-4241.1
-4250.8
-4401.2
-4391.4
Boiling T
1203 K
A^0
K
kJ
kJ
Molar Vol.
H298~H8
57.066 kJ
-4.191E+03
B 1.309E+00
14.695 J'bar'1
146.95 cm3
C= 6.392E+06
11/25/92
292
Formula wt
MAGNESIUM SULFATE
120.369
MgS04 : Crystals 298.15 to 1400 K.

Temp.
CO
ST
<H*-H298 )/T
-CH-H 598 )/!I
1-1. K~l
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
Melting T
95.71
96.10
111.16
120.67
127.99
134.27
140.01
145.42
150.64
155.73
160.73
165.66
170.55
91.40
91.99
121.91
147.80
170.47
190.68
208.99
225.80
241.39
255.99
269.75
282.81
295.27
0.00
0.59
26.54
44.46
57.80
68.28
76.89
84.21
90.59
96.28
101.45
106.20
110.62
1. T
91.40
91.40
95.38
103.34
112.67
122.40
132.10
141.59
150.80
159.70
168.30
176.61
184.65
1400 K
A fG
Log Kf
-1170.5
-1169.8
-1131.3
-1092.1
-1052.7
-1013.4
-974.1
-933.9
-888.3
-842.7
-797.4
-752.4
-704.6
205.07
203.68
147.72
114.08
91.64
75.62
63.60
54.20
46.40
40.02
34.71
30.23
26.29
A fH
-1284.9
-1284.9
-1287.6
-1288.7
-1288.9
-1288.5
-1287.7
-1339.6
-1345.4
-1342.4
-1339.0
-1335.2
-1458.4
mol"1
Boiling T
K
kJ
kJ
Molar Vol.
H2*98~H6
J-bar'1
1539 kJ
A* -1.325E+03
B= 4.385E-01
C= 2.288E+06
11/25/92
Formula wt
MANGANESE SULFATE
MnSO4 :
293
151.002

Temp.
CP
ST
Jmol
298.15
300
400
500
600
700
800
900
1000
100.52
100.99
118.68
129.02
136.47
142.54
147.89
152.81
157.47
127.00
127.62
159.38
187.05
211.26
232.77
252.16
269.86
286.21
-CH-HJ 98 >/'T
(HT-H2 98 )/T
0.00
0.62
28.17
47.38
61.63
72.77
81.83
89.45
96.02
k^T-mnl
127.00
127.00
131.21
139.68
149.63
160.00
170.33
180.42
190.19
Melting T
A fG
Log K
-962.1
-961.5
-926.6
-891.3
-855.8
-820.5
-785.3
-749.2
-708.4
168.56
167.40
120.99
93.10
74.49
61.21
51.26
43.47
36.99
A fH
-1065.7
-1065.7
-1067.9
-1068.4
-1068.2
-1067.3
-1066.1
-1117.7
-1116.9
Boiling T
K
kJ
kJ
Molar Vol
H2*98~H8
kJ
-1.077E+03
B* 3.657E-01
4.362 J'bar"1
43.62 cm3
C* 5.563E+05
6/10/93
294
Formula wt
MASCAGNITE
(NH4) 2SO4 :
132.141
Temp.
CP
Sf
-<Gf-H2 98 )/T
187.48
188.00
215.88
243.76
271.64
220.50
221.66
279.56
330.73
377.64
0.00
1.16
51.35
87.05
115.49
lr T
220.50
220.50
228.21
243.68
262.15
AfG
Log K
-903.5
-901.8
-807.6
-712.4
-617.0
158.29
157.01
105.46
74.42
53.72
A fH
J-mol" 1 ^"1
298.15
300
400
500
600
<Hf-H2 98 )/T
-1182.7
-1182.7
-1187.6
-1189.3
-1188.2
mol'1
Boiling T
Melting T
Av*H
K
fcJ
kJ
Molar Vol.
H298~H8
kJ
-1.193E+03
B= 9.583E-01
7.468 J'bar'1
74.68 cm3
C* 3.227E+05
3/24/93
Formula wt
THENAROITE
Na2 SO4 :
Orthorhombic crystals (V) 298.15 to 450 K.

K. Hexagonal crystals (I) 514 to 1155 K.
295
142.043
Orthorhombic crystals (III) 450 to 514


Temp.
CP
ST
(HT-H2 98 )/T
.-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
127.28
127.63
146.82
173.30
170.78
178.92
187.06
195.20
203.34
211.48
196.37
195.98
195.58
195.19
194.80
194.40
194.01
149.60
150.35
191.96
234.89
279.30
306.23
330.66
353.16
374.15
393.91
431.72
447.42
461.93
475.41
487.99
499.79
510.89
0.00
0.79
36.81
68.03
96.29
107.51
116.95
125.19
132.60
139.40
165.14
167.53
169.54
171.27
172.75
174.04
175.16
-(GT-H 98 )/T
A fG
Log Kf
-1269.8
-1269.1
-1229.0
-1187.8
-1148.4
-1109.2
-1070.3
-1030.7
-986.7
-943.2
-895.0
-838.0
-781.5
-725.5
-669.9
-614.6
-559.6
222.46
220.96
160.49
124.09
99.97
82.77
69.88
59.82
51.54
44.79
38.96
33.67
29.16
25.26
21.87
18.88
16.24
A fH
-1
kJ-mol' 1
149.60
149.56
155.15
166.86
183.01
198.72
213.71
227.97
241.55
254.51
266.58
279.89
292.39
304.14
315.24
325.75
335.73
-1387.8
-1387.8
-1395.1
-1392.0
-1384.2
-1382.5
-1379.9
-1429.6
-1424.3
-1418.2
-1581.8
-1575.4
-1569.2
-1563.0
-1557.0
-1551.0
-1545.2
Boiling T
1155 K
Av*H
AftH 0
kJ
Molar Vol.
H2*98~H6
23.22 kJ
A = -1.482E+03
B- 5.020E-01
kJ
5 .333 J'bar'1
53 .33 cm3
6.251E+06
2/5/92
296
Formula wt
NICKELOUS SULFATE
NiSO4 :
154.754

Temp.
CP
ST
Melting T
-<GT-H2 98 )/T
97.69
98.19
116.56
126.71
133.62
139.01
143.57
147.67
151.47
155.08
158.56
101.30
101.91
132.98
160.17
183.92
204.93
223.80
240.95
256.71
271.31
284.96
0.00
0.60
27.57
46.46
60.44
71.29
80.05
87.34
93.56
98.99
103.81
A fG
Log Kf
-762.7
-762.0
-724.7
-686.9
-648.9
-611.0
-573.7
-534.5
-491.1
-448.0
-405.2
133.61
132.67
94.64
71.76
56.49
45.59
37.46
31.02
25.65
21.27
17.64
A fH
J-mol^-K"1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
<HT-H 98 )/T
kJ mol"1
101.30
101.30
105.41
113.71
123.48
133.64
143.75
153.61
163.14
172.32
181.15
-873.2
-873.3
-875.7
-876.5
-876.6
-876.2
-875.0
-926.6
-923.7
-920.5
-917.1
Boiling T
K
kJ
kJ
Molar Vol
15.94 kJ
A" -8.988E+02
B 4.077E-01
3.857 J-bar'1
38.57 cm3
O 1.381E+06
2/5/93
297
Formula wt
ANGLESITE
303.264
PbSO4 : Orthorhombic crystals 298.15 to 1100 K.

Temp.
CP
ST
<HT-H$98 )/T
-<0|-H5 98 )/1?
i-l. K-l
298.15
300
400
500
600
700
800
900
1000
1100
104.33
104.33
108.73
117.63
128.30
139.81
151.76
163.98
176.35
188.83
148.50
149.15
179.59
204.76
227.13
247.76
267.21
285.79
303.70
321.10
0.00
0.64
26.96
44.16
57.28
68.24
77.93
86.81
95.15
103.09
kJ-mQ!
148.50
148.50
152.62
160.59
169.85
179.52
189.28
198.98
208.56
218.00
Melting T
AfG
Log Kf
-813.1
-812.4
-776.4
-739.6
-702.6
-664.8
-627.2
-588.7
-545.8
-503.4
142.44
141.45
101.38
77.27
61.17
49.61
40.95
34.17
28.51
23.90
A fH
-920.0
-920.0
-922.7
-924.2
-924.8
-929.1
-927.4
-977.7
-972.4
-966.0
Boiling T
kJ
kJ
Molar Vol
H298"H6
20.05 kJ
A* -9.455E+02
B= 3.981E-01
4.795 J-bar'1
47.95 cm3
C= 1.275E+06
11/25/92
298
Formula wt
ZINKOSITE
161.454
ZnSO4 : Orthorhombic crystals 298.15 to 1100 K.

Temp.
CP
ST
(HT-H 98 )/T
-(G*-H598 >/<T
104.12
104.02
104.84
111.90
121.41
132.08
143.36
155.01
166.88
178.89
110.50
111.14
140.94
165.03
186.25
205.75
224.12
241.67
258.62
275.09
0.00
0.64
26.38
42.72
55.02
65.26
74.31
82.63
90.46
97.95
Log Kf
-868.7
-868.1
-830.5
-792.2
-753.6
-714.8
-675.1
-634.4
-589.1
-544.3
152.20
151.14
108.46
82.76
65.61
53.34
44.08
36.82
30.77
25.85
kJm ol_""
Jmol"~lK~^ -
298.15
300
400
500
600
700
800
900
1000
1100
A fG
A fH
110.50
110.50
114.56
122.31
131.23
140.50
149.81
159.05
168.16
177.14
Melting T
-980.1
-980.1
-982.9
-984.8
-985.8
-993.3
-992.5
-1043.8
-1039.6
-1034.4
Boiling T
K
kJ
kJ
Molar Vol
H298"H6
17.24 kJ
-1.010E+03
B 4.187E-01
4.157 J-bar'1
41.57 cm3
C= 1.501E+06
11/25/92
Formula wt
BERLINITE
A1PO4 : Rhombohedral crystals 298.15 to a-0 transition at 855 K.
299
121.953
jJ-crystals 855 to 1000 K,
Temp.
ST
(HT-H2 98 )/T
T. -._!
298.15
300
400
500
600
700
800
900
1000
93.96
94.15
109.86
122.79
131.82
140.83
153.40
140.70
142.50
90.80
91.38
120.53
146.53
169.75
190.72
210.29
229.96
244.88
-(GT-H2 98 )/T
1 _ r 1
0.00
0.58
25.86
44.04
57.95
69.12
78.82
88.62
93.92
\.T-
90.80
90.80
94.67
102.49
111.80
121.60
131.47
141.34
150.96
A 6
Log Kf
-1617.9
-1617.1
-1577.9
-1538.6
-1499.4
-1460.4
-1421.7
-1383.4
-1344.7
283.44
281.56
206.05
160.73
130.53
108.97
92.82
80.29
70.24
A fH
-1733.8
-1733.8
-1735.3
-1735.0
-1734.0
-1732.4
-1730.0
-1725.9
-1735.2
mol"1
Boiling T
Melting T
K
kJ
kJ
Molar Vol
14.76 kJ
A* -1.731E+03
B= 3.866E-01
4.658 J-bar'1
46.58 cm3
C* -2.087E+05
11/25/92
300
Formula wt
WHITLOCKITE
310.177
Ca3 (PO4 ) 2 : Rhombohedral crystals 298.15 to 1373 K. Monoclinic crystals 1373 to 1600 K.
Temp.
CP
Log Kf
-3883.6
-3882.2
-3802.1
-3722.1
-3642.3
-3562.8
-3483.5
-3404.6
-3326.2
-3248.4
-3167.2
-3077.8
-2989.8
-2903.0
-2816.6
680.38
675.93
496.50
388.83
317.08
265.85
227.44
197.59
173.74
154.25
137.86
123.67
111.55
101.09
91.95
kJ-mol' 1
K
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
A fG
AfH
231.63
232.12
255.24
275.30
294.16
312.44
330.43
348.23
365.93
383.55
401.12
418.67
330.54
330.54
330.54
236.00
237.43
307.49
366.64
418.51
465.23
508.13
548.08
585.69
621.39
655.52
688.32
729.26
752.05
773.38
0.00
1.43
62.09
102.76
133.10
157.42
177.92
195.86
211.98
226.78
240.57
253.60
275.09
278.79
282.02
Melting T
236.00
236.00
245.40
263.88
285.41
307.82
330.21
352.22
373.70
394.61
414.94
434.72
454.17
473.26
491.36
-4120.8
-4120.8
-4122.7
-4121.9
-4120.2
-4117.6
-4116.6
-4112.2
-4107.0
-4101.2
-4245.0
-4232.6
-4205.8
-4201.6
-4197.5
Boiling T
kJ
AitoH0
kJ
Molar Vol.
H298~H5
kJ
A*
-4.148E+03
B= 8.253E-01
9 .762 J'bar'1
97 . 62 cm3
C 1.823E+06
11/25/92
301
Formula wt
FLUORAPATITE
504.302
Ca5 (PO4 ) 3F: Hexagonal crystals 298.15 to 1600 K.

Temp.
eo
sT
CP
(HT-H2 98 )/T
-(GT-H 98 )/T
J-mol'^K"" 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
375.94
377.11
426.47
458.22
480.47
496.89
509.43
519.24
527.04
533.30
538.35
542.44
545.74
548.40
550.50
387.90
390.23
506.06
604.87
690.49
765.84
833.05
893.64
948.77
999.30
1045.93
1089.19
1129.51
1167.26
1202.72
Melting T
0.00
2.32
102 . 70
170.83
220.68
259.02
289.57
314.57
335.44
353.15
368.38
381.62
393.23
403.49
412.62
A fG
Log Kf
-6489.7
-6487.4
-6358.5
-6229.9
-6102.0
-5974.7
-5847.4
-5720.6
-5594.1
-5467.8
-5335.3
-5189.8
-5044.8
-4900.4
-4756.6
1136.95
1129.52
830.32
650.82
531.21
445.83
381.79
332.00
292.20
259.64
232.23
208.52
188.22
170.64
155.28
A fH
kJ-mol"1
387.90
387.91
403.37
434.03
469.80
506.82
543.47
579.07
613.33
646.15
677.55
707.57
736.28
763.77
790.11
-6872.0
-6872.0
-6874.0
-6871.4
-6867.7
-6863.7
-6864.1
-6860.4
-6857.7
-6856.1
-7085.0
-7077.5
-7069.7
-7061.9
-7054.1
Boiling T
K
kJ
A&.H0
kJ
Molar Vol.
HJ98-H8
63.47 kJ
>,-
-6.931E+03
B= 1.344E-fOO
15 .756 Jbar"!
157 .56 cm3
C 4.048E+06
11/25/92
302
Formula wt
HYDROXYAPATITE
502.311
Ca5 (PO4 ) 3 (OH): Hexagonal crystals 298.15 to 1500 K,

Temp.
CP
ST
<HT-H 98 )/T
-<GT-H2 98 )/T
J-mol~^K~^ 298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
385.17
386.83
446.42
477.29
497.62
513.35
526.86
539.23
550.97
562.37
573.58
584.69
595.76
606.82
390.40
392.79
513.36
616.59
705.50
783.43
852.88
915.66
973.08
1026.13
1075.54
1121.90
1165.63
1207.11
0.00
2.38
106.92
178.17
229.81
269.23
300.60
326.44
348.31
367.25
383.98
398.99
412.65
425.23
A fG
Log K
-6337.1
-6334.7
-6199.4
-6064.6
-5930.6
-5797.2
-5663.9
-5531.1
-5398.8
-5266.7
-5128.6
-4977.6
-4827.4
-4678.0
1110.22
1102.94
809.55
633.55
516.29
432.58
369.81
321.01
282.00
250.09
223.24
200.00
180.11
162.90
A fH
1. T
390.40
390.41
406.44
438.42
475.70
514.21
552.28
589.22
624.77
658.88
691.57
722.90
752.98
781.88
Melting T
-6738.5
-6738.5
-6740.1
-6736.9
-6732.7
-6728.4
-6728.4
-6724.2
-6720.7
-6717.9
-6945.1
-6935.1
-6924.2
-6912.5
Boiling T
K
kJ
kJ
Molar Vol.
H2*98"H6
64.24 kJ
A- -6.777E+03
B- 1.386E-fOO
15.960 J'bar'1
159.60 cm3
C= 2.726E+06
11/25/92
303
Formula wt
TOPAZ
Al2SiO4F2 :
184.043

Temp.
CP
s*
<HT-H2 98 )/T
-(GT-H| 98 )/T
A fH
J-mol"1 ^"1 -
298.15
300
400
500
600
700
800
900
1000
143.63
144.28
172.38
190.31
201.97
209.49
214.10
216.62
217.54
105.40
106.29
151.96
192.49
228.30
260.04
288.34
313.72
336.61
0.00
0.89
40.52
68.81
90.10
106.66
119.83
130.46
139.13
A fG
Log Kf
-2910.6
-2909.6
-2851.1
-2792.8
-2734.8
-2677.2
-2619.9
-2562.9
-2504.7
509.92
506.59
372.31
291.76
238.08
199.77
171.06
148.75
130.83
U.T
105.40
105.40
111.44
123.68
138.19
153.38
168.51
183.26
197.47
Melting T
-3084.5
-3084.5
-3084.9
-3083.7
-3081.7
-3079.3
-3076.9
-3074.6
-3093.9
Boiling T
kJ
kJ
Molar Vol
19.77 kJ
A- -3.079E+03
B 5.740E-01
5.153 J-bar'1
51.53 cm3
C -2.85E+05
7/23/92
304
Formula wt
KYANITE
Al2Si05 :
Triclinic crystals
162.046
298.15 to 1800 K.

Temp.
CP
ST
/UO_I1O
\ rim Ho OD \/ //rp
A
-*-HJ 98 )/'I
121.58
122.26
149.25
165.25
175.97
183.70
189.56
194.15
197.84
200.85
203.35
205.44
207.20
208.70
209.97
211.06
211.99
82.80
83.55
122.81
157.97
189.10
216.84
241.77
264.37
285.02
304.02
321.61
337.97
353.26
367.61
381.12
393.88
405.97
0.00
0.75
34.84
59.44
78.02
92.59
104.36
114.09
122.29
129.30
135.37
140.68
145.37
149.54
153.28
156.65
159.70
Log Kf
-2443.1
-2442.2
-2391.4
-2340.6
-2290.1
-2239.8
-2189.7
-2139.9
-2088.8
-2037.1
-1985.6
-1934.2
-1883.2
-1832.2
-1781.5
-1730.4
-1677.0
428.01
425.21
312.28
244.52
199.36
167.13
142.97
124.19
109.11
96.73
86.43
77.72
70.26
63.80
58.16
53.17
48.66
-1
J-mol'^K"1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A fG
A fH
82.80
82.80
87.97
98.53
111.08
124.24
137.40
150.27
162.73
174.72
186.24
197.29
207.89
218.06
227.84
237.23
246.27
Melting T
-2593.8
-2593.8
-2594.7
-2594.1
-2592.7
-2591.0
-2589.2
-2587.3
-2606.8
-2604.6
-2602.3
-2599.9
-2597.5
-2595.0
-2592.5
-2640.1
-2637.3
Boiling T
K
kJ
kJ
Molar Vol
H298~H6
15.86 kJ
A= -2.599E+03
B= 5.109E-01
4.415 J'bar
44.15 cm3
C= 3.358E+05
7/29/92
305
Formula wt
ANDALUSITE
Al2SiO5 :
Orthorhombic crystals
162.046
298.15 to 1800 K.
Temp.
CP
S|
-<Gf-H$ 98 )/T
A fH
A fG
Log Kf
-2589.9
-2589.9
-2590.7
-2590.1
-2588.8
-2587.2
-2585.4
-2583.6
-2603.1
-2601.0
-2598.8
-2596.4
-2594.1
-2591.6
-2589.2
-2636.8
-2634.1
-2441.8
-2440.8
-2391.0
-2341.1
-2291.4
-2241.9
-2192.7
-2143.8
-2093.5
-2042.6
-1992.0
-1941.4
-1891.2
-1841.1
-1791.1
-1740.8
-1688.2
427.77
424.98
312.22
244.56
199.48
167.29
143.17
124.42
109.35
96.99
86.71
78.01
70.56
64.11
58.47
53.49
48.99
J-mol'^K" 1 -
K
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
<Hf-H2 98 )/T
122.60
123.26
149.43
165.03
175.54
183.16
188.94
193.49
197.16
200.16
202.67
204.77
206.56
208.08
209.38
210.50
211.46
Melting T
91.39
92.15
131.57
166.71
197.79
225.45
250.30
272.83
293.41
312.35
329.88
346.18
361.43
375.73
389.20
401.93
413.99
0.00
0.76
34.98
59.54
78.05
92.55
104.25
113.92
122.07
129.04
135.07
140.36
145.02
149.18
152.90
156.26
159.30
91.39
91.39
96.59
107.17
119.74
132.90
146.05
158.90
171.34
183.31
194.80
205.83
216.40
226.55
236.30
245.67
254.69
Boiling T
Av*H
kJ
Afo.H 0
Molar Vol.
H298-H6
16. 90
kJ
A* -2.595E+03
B- 5.027E-01
kJ
5. 152 J'bar'1
51. 52 cm3
C= 3.590E+05
7/29/92
306
Formula wt
SILLIMANITE
A12 S1O5 :
162.046
298.15 to 1800 K.
Temp.
CP
**
-<Gf-H2 98 )/T
AfH
.-1-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
(Hf-H2 98 )/T
123.72
124.33
148.88
163.95
174.29
181.88
187.70
192.31
196.05
199.13
201.70
203.87
205.71
207.29
208.64
209.80
210.80
95.40
96.17
135.63
170.58
201.44
228.91
253.59
275.97
296.44
315.27
332.71
348.94
364.12
378.37
391.79
404.47
416.50
Melting T
0.00
0.76
35.01
59.40
77.73
92.09
103.70
113.29
121.39
128.32
134.33
139.60
144.26
148.41
152.13
155.49
158.54
1.
J*
95.40
95.40
100.62
111.91
123.71
136.81
149.89
162.68
175.05
186.95
198.38
209.34
219.86
229.96
239.66
248.98
257.96
-2586.1
-2586.1
-2586.9
-2586.4
-2585.2
-2583.7
-2582.0
-2580.4
-2598.0
-2598.0
-2595.9
-2593.6
-2591.4
-2589.0
-2586.6
-2634.3
-2631.7
A fG
Log Kf
-2439.1
-2438.2
-2388.8
-2339.3
-2289.9
-2240.9
-2192.0
-2143.4
-2093.4
-2042.8
-1992.5
-1942.2
-1892.3
-1842.3
-1792.7
-1742.6
-1690.3
427.32
424.52
311.93
244.38
199.35
167.21
143.12
124.39
109.35
97.00
86.73
78.04
70.60
64.16
58.52
53.54
49.05
.-1
Boiling T
A,wpH
AfaH
kJ
kJ
Molar Vol.
H298"H8
17 .44 kJ
A* -2.592E+03
B- 4.998E-01
4 .986 J-bar'1
49 . 86 cm3
0 4 .086E+05
7/29/92
307
Formula wt
MULLITE
Al6Si2O13 :
426.052
298.15 to 1800 K.

Temp.
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
cp
326.13
327.73
392.44
431.98
458.88
478.40
493.16
504.65
513.76
521.10
527.05
531.91
535.88
539.13
541.76
543.88
545.56
s*
is[T-H 9 g)/l'
J. mol"^K~^
275.00
277.02
381.04
473.17
554.45
626.72
691.61
750.39
804.05
853.37
898.98
941.36
980.93
1018.02
1052.90
1085.81
1116.95
0.00
2.02
92.29
156.55
204.83
242.59
273.03
298.15
319.27
337.30
352.87
366.46
378.43
389.04
398.50
406.99
414.65
-<Gf-H2 98 )/T
A fG
AfH
kJ-mol" 1
275.00
275.01
288.75
316.62
349.62
384.14
418.59
452.24
484.78
516.07
546.11
574.90
602.51
628.98
654.40
678.82
702.30
-6441.8
-6439.4
-6312.3
-6185.1
-6058.3
-5932.1
-5806.4
-5681.2
-5552.0
-5420.8
-5290.0
-5159.5
-5029.8
-4900.2
-4771.0
-4641.0
-4506.7
-6819.2
-6819.3
-6821.5
-6820.4
-6817.5
-6813.7
-6809.8
-6806.0
-6866.2
-6861.6
-6856.7
-6851.4
-6846.3
-6840.9
-6835.6
-6930.5
-6924.8
Boiling T
2123 K
A UO
Au^Jd
AfaH
1128.55
1121.18
824.29
646.14
527.41
442.65
379.11
329.72
290.00
257.40
230.26
207.31
187.66
170.64
155.75
142.60
130.78
kJ
kJ
Molar Vol.
H298-H6
Log Kf
46.07 kJ
A* -6.844E+03
B- 1.295E+00
13. 46 J-bar'1
134. 6 cm3
O 1.613E+06
5/4/92
308
Formula wt
DUMORTIERITE
1 A1 6.7SH ].25 si3B017.25< OH >.75 s
565.938

Temp.
CP
CO
ST
<HT-H2 98 )/T
-<Gf-H2 98 )/T
J-mol^-K" 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
440.00
442.08
532.57
592.80
634.72
664.89
687.16
703.94
716.81
726.88
734.93
741.52
747.09
751.98
756.43
760.66
764.83
334.90
337.63
478.13
603.87
715.87
816.10
906.41
988.36
1063.23
1132.04
1195.64
1254.74
1309.90
1361.61
1410.29
1456.27
1499.87
0.00
2.72
124.68
212.67
279.71
332.70
375.68
411.26
441.20
466.73
488.76
507.96
524.85
539.83
553.23
565.31
576.27
A fG
A fH
Log Kf
mol""l ____
^ |_T
KJ lUWiL
~MWM-^
334.90
334.91
353.45
391.20
436.16
483.41
530.73
577.10
622.02
665.30
706.88
746.78
785.05
821.78
857.06
890.97
923.59
-9109.0
-9109.1
-9112.5
-9111.0
-9106.7
-9100.7
-9094.2
-9087.6
-9153.0
-9145.4
-9137.5
-9129.2
-9121.2
-9112.9
-9104.6
-9246.7
-9237.7
-8568.2
-8564.9
-8382.8
-8200.4
-8018.7
-7837.8
-7657.9
-7478.7
-7295.3
-7109.9
-6925.2
-6741.0
-6557.9
-6375.0
-6192.7
-6009.4
-5819.4
Boiling T
Melting T
1501.08
1491.24
1094.65
856.67
698.07
584.85
499.99
434.04
381.06
337.61
301.44
270.85
244.67
221.99
202.17
184.64
168.87
K
kJ
kJ
Molar Vol
H298~H8
59.84 kJ
A= -9.125E-I-03
B= 1.833E+00
16.84 J-bar'
168.4 cm3
C- 1.061E+06
7/22/92
309
Formula wt
EUCLASE
BeAlSi04 (OH):
145.084

Temp.
CP
ST
(E *-H298 )/T
j.
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
126.83
127.50
156.65
175.85
188.84
197.87
204.36
209.17
212.92
216.03
218.78
221.41
224.07
226.91
230.01
233.47
237.34
89.10
89.89
130.86
168.02
201.30
231.13
258.00
282.36
304.60
325.04
343.96
361.57
378.08
393.63
408.38
422.42
435.87
unl
1.^
0.00
0.78
36.37
62.47
82.52
98.39
111.25
121.88
130.80
138.41
145.00
150.77
155.91
160.55
164.79
168.73
172.43
-<GT-H2 98 )/T
89.10
89.10
94.49
105.55
118.78
132.74
146.75
160.48
173.80
186.63
198.96
210.80
222.17
233.08
243.58
253.69
263.44
AfG
Log Kf
-2370.2
-2369.2
-2314.4
-2259.5
-2204.9
-2150.6
-2096.6
-2042.9
-1988.7
-1934.4
-1880.3
-1826.4
-1772.7
-1719.2
-1665.5
-1610.9
-1554.1
415.24
412.50
302.22
236.05
191.95
160.48
136.89
118.56
103.88
91.85
81.84
73.38
66.14
59.87
54.37
49.50
45.10
A fH
-2532.9
-2532.9
-2533.9
-2533.3
-2531.8
-2529.7
-2527.4
-2525.0
-2533.3
-2530.7
-2528.2
-2525.6
-2523.0
-2520.4
-2532.2
-2579.2
-2575.6
.-1
Boiling T
Av*H
Afa.H
kJ
kJ
Molar Vol.
H298-H6
16 .83 kJ
A= -2.529E+03
B= 5.403E-01
4 .686 J-bar'1
46 . 86 cm3
C= -2.31E-I-05
7/23/92
310
Formula wt
PHENAKITE
6628104:
110.107
Hexagonal crystals 298.15 to 1800 K. Decomposes to BeO and SiO2 above 1833 K,

Temp.
CO
ST
CP
(HT-H2 98 )/T
-(GT-H^ 98 )/T
J-mol" 1 -*"" 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
95.60
96.16
121.33
138.41
150.19
158.46
164.33
168.53
171.57
173.77
175.39
176.61
177.57
178.39
179.13
179.88
180.68
63.37
63.96
95.31
124.34
150.68
174.49
196.06
215.67
233.59
250.05
265.24
279.33
292.46
304.74
316.27
327.15
337.46
Melting T
0.00
0.59
27.84
48.35
64.40
77.28
87.82
96.56
103.92
110.18
115.55
120.20
124.26
127.85
131.03
133.88
136.46
A fG
Log Kf
-2028.4
-2027.7
-1989.0
-1950.4
-1911.9
-1873.7
-1835.7
-1798.0
-1760.5
-1723.3
-1686.2
-1649.2
-1612.4
-1575.7
-1538.3
-1499.4
-1458.0
355.36
353.04
259.74
203.75
166.44
139.81
119.86
104.35
91.96
81.83
73.39
66.27
60.16
54.87
50.22
46.07
42.31
A fH
kJ-mol' 1
63.37
63.37
67.47
75.99
86.28
97.21
108.24
119.10
129.67
139.87
149.70
159.13
168.19
176.89
185.25
193.28
201.00
-2143.1
-2143.1
-2143.9
-2143.3
-2142.1
-2140.3
-2138.3
-2136.2
-2134.2
-2132.2
-2130.3
-2128.7
-2127.2
-2125.9
-2153.9
-2202.4
-2200.6
Boiling T
A^pH0
AtoH
kJ
kJ
Molar Vol.
H298"H5
12 .16 kJ
-2.135E+03
B= 3.744E-01
3 .718 J-bar'1
37 . 18 cm3
C= -4.46E+05
7/22/92
Formula wt
BERYL
Be3Al2 (Si6O18 ):
311
537.502

Temp.
CP
ST
<HT-H298 )/T
-<Gf-H$ 98 )/T
Melting T
A^0
417.00
419.01
507.82
567.30
608.30
637.50
659.03
675.52
688.78
700.03
710.19
719.89
729.66
739.86
750.81
762.75
775.87
346.70
349.29
482.86
603.00
710.27
806.36
892.96
971.57
1043.45
1109.64
1170.99
1228.22
1281.93
1332.61
1380.71
1426.58
1470.54
0.00
2.58
118.55
202.73
267.11
318.05
359.39
393.64
422.51
447.24
468.73
487.68
504.61
519.95
534.04
547.13
559.47
Log Kf
-8500.5
-8497.3
-8326.9
1489.21
1479.48
1087.35
852.05
695.23
583.27
499.36
434.14
381.93
339.21
303.64
273.56
247.81
225.50
205.96
188.60
172.75
-1
J-mol"" 1 ^' 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A fG
A H
346.71
346.71
364.32
400.26
443.16
488.31
533.56
577.93
620.94
662.40
702.26
740.54
777.31
812.66
846.67
879.44
911.07
-9006.6
-9006.7
-9010.0
-9008.6
-9004.7
-8999.1
-8992.8
-8986.1
-9000.6
-8993.5
-8986.1
-8978.7
-8971.1
-8963.4
-8999.0
-9290.5
-9278.7
-8156.2
-7986.0
-7816.7
-7648.1
-7480.5
-7312.1
-7143.5
-6975.7
-6808.5
-6641.9
-6475.7
-6309.0
-6138.4
-5953.2
Boiling T
A^pH 0
kJ
kJ
Molar Vol.
H298-H6
64 .43 kJ
A* -8.995E+03
B= 1.683E+00
20 .33 J-bar'1
203 .3 can3
O -6.74E-I-05
7/22/92
312
Formula wt
BERTRANDITE
Be4Si207 (OH) 2 :
238.230
Temp.
CP
ST
-(GT-H2 9 g)/T
224.64
225.83
279.83
317.42
344.16
363.51
377.60
387.80
395.06
400.01
403.13
404.76
405.16
172.10
173.49
246.33
313.06
373.43
428.01
477.52
522.62
563.88
601.78
636.73
669.07
699.09
0.00
1.39
64.67
111.68
148.32
177.75
201.90
222.02
238.98
253.41
265.77
276.41
285.60
A fG
Log Kf
-4295.1
-4293.3
-4197.1
-4100.6
-4004.5
-3908.8
-3813.6
-3719.0
-3624.9
-3531.3
-3438.0
-3345.1
-3252.4
752.46
747.51
548.07
428.38
348.61
291.67
249.00
215.84
189.34
167.68
149.65
134.41
121.35
A fH
- J-mol"1 ^"1
K
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
(H$-H2 98 )/T
kJ-mol"1
172.10
172.10
181.67
201.38
225.11
250.26
275.63
300.60
324.90
348.37
370.96
392.67
413.49
Melting T
-4580.5
-4580.6
-4582.9
-4582.4
-4580.2
-4576.7
-4572.5
-4568.1
-4563.5
-4559.1
-4555.0
-4551.4
-4548.3
Boiling T
K
kJ
kJ
Molar Vol
H298~H8
31.04 kJ
A- -4.564E+03
B= 9.388E-01
9.179 J-bar'1
91.79 cm3
O -1.03E+06
7/29/92
LAWSONITE
Formula wt
CaAl2 Si207 (OH)2*H20:
313
314.238
Crystals 298.15 to 600 K,
Temp.
CP
ST
K
298.15
300
400
500
600
275.24
276.56
331.03
368.81
400.03
(Hf-H2 98 )/T
-<GT-H2 98 )/ T
- J-mol"1 ^" 1
230.00
231.71
319.37
397.47
467.54
0.00
1.70
77.78
132.37
174.43
230.00
230.01
241.59
265.10
293.10
Melting T
AfG
Log Kf
-4512.9
-4510.7
-4390.9
790.63
785.37
573.38
-4270.9
-4151.5
446.17
361.41
AfH
kJmol~^
-4869.0
-4869.1
-4871.0
-4869.7
-4866.0
Boiling T
K
kJ
kJ
Molar Vol.
H298~H8
41.36 kJ
A= -4.869E+03
B- 1.196E+00
10.132
101.32
J'bar'
cm3
C- -7.02E-I-04
7/29/92
314
Formula wt
GEHLENITE
Ca2Al2 SiO7 :
274.200
Tetragonal crystals 298.15 to incongruent melting point at 1866 K.

Temp.
CO
ST
CP
(HT-H2 98 )/T
-<GT-H2* 98 )/T
J-mol" 1 -*,"" 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
206.40
207.12
236.74
255.45
268.56
278.34
285.95
292.04
297.04
301.21
304.73
307.74
310.33
312.57
314.53
316.24
317.74
210.10
211.38
275.39
330.37
378.16
420.33
458.01
492.06
523.09
551.61
577.97
602.48
625.39
646.88
667.11
686.23
704.35
1866
0.00
1.28
56.76
94.75
122.69
144.25
161.51
175.69
187.58
197.73
206.50
214.17
220.95
226.99
232.40
237.28
241.71
A fG
Log Kf
-3785.5
-3784.3
-3717.2
-3650.2
-3583.5
-3517.0
-3450.5
-3384.2
-3316.4
-3247.9
-3178.2
-3108.3
-3038.8
-2969.3
-2900.0
-2830.3
-2753.9
663.19
A fH
kJ-rnol'1
210.10
210.10
218.63
235.62
255.48
276.08
296.50
316.37
335.52
353.88
371.47
388.31
404.43
419.89
434.71
448.95
462.64
-3985.0
-3985.0
-3985.5
-3984.6
-3983.2
-3981.6
-3981.9
-3980.8
-4001.6
-4001.2
-4016.6
-4014.6
-4012.6
-4010.3
-4008.1
-4055.9
-4350.6
658.88
485.41
381.33
311.96
262.44
225.29
196.41
173.23
154.23
138.34
124.89
113.38
103.40
94.67
86.96
79.91
Boiling T
Av*H
AfaH 0
Molar Vol.
H2 98-H5
kJ
kJ
A* -4.005E+03
9 .015 J-bar'1
cm3
90 .15
33. 21 kJ
B- 6.909E-01
O 1.392E+06
7/22/92
Formula wt
ZOISITE
Ca2Al3Si3012 (OH):
315
454.357

Temp.
CP
ST
(HT-H2 98 )/T
-(GT-H2 98 )/T
,-1 _-l
298.15
300
400
500
600
700
800
900
1000
1100
1200
Melting T
350.34
351.83
412.84
450.20
476.35
497.24
516.12
534.93
554.92
576.93
601.55
295.85
298.02
408.40
504.83
589.34
664.38
732.02
793.89
851.27
905.17
956.41
0.00
2.17
97.91
164.89
214.73
253.63
285.28
311.96
335.25
356.20
375.60
A G
Log Kf
-6504.5
-6502.1
-6368.7
-6235.4
-6102.6
-5970.4
-5838.5
-5707.2
-5574.3
-5440.7
-5306.5
1139.54
1132.08
831.65
651.39
531.27
445.51
381.21
331.23
291.16
258.35
230.98
A H
kJ mol" 1
295.85
295.86
310.49
339.94
374.61
410.74
446.74
481.93
516.02
548.97
580.81
-6901.1
-6901.2
-6902.5
-6900.8
-6897.7
-6893.8
-6891.2
-6886.4
-6913.1
-6906.3
-6914.2
Boiling T
K
kJ
kJ
Molar Vol
H298"H5
52.07 kJ
A* -6.898E+03
B= 1.325E+00
13.65 J-bar"1
136.5 cm3
C= -1.37E+05
7/22/92
316
Formula wt
GROSSULAR
Ca3Al2 Si3012 :
450.446
Temp.
cp
CO
ST
(HT-H2 98 )/T
-(GT-H2 98 )/T
,-1-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
Melting T
330.22
331.57
389.70
425.80
448.43
463.30
474.02
482.99
491.81
501.62
513.24
260.12
262.17
366.16
457.32
537.11
607.42
670.02
726.37
777.71
825.04
869.17
0.00
2.04
92.25
155.64
202.69
238.93
267.67
291.11
310.73
327.63
342.60
A G
Log K
-6278.5
-6276.2
-6154.7
-6033.4
-5912.7
-5792.6
-5672.6
-5553.0
-5432.2
-5310.8
-5187.7
1099.94
1092.77
803.71
630.29
514.73
432.24
370.37
322.28
283.74
252.18
225.81
A H
i. T mol' 1
260.12
260.13
273.91
301.68
334.41
368.49
402.34
435.27
466.98
497.41
526.57
-6640.0
-6640.1
-6640.8
-6638.6
-6635.3
-6631.6
-6630.9
-6628.0
-6647.1
-6645.2
-6666.7
Boiling T
kJ
kJ
Molar Vol
H298"H8
47.66 kJ
A= -6.637E+03
B= 1.206E+00
12.528
125.28
J-bar'1
cm3
C= -1.07E+05
7/22/92
317
Formula wt
DATOLITE
CaB(Si4 )OH:
159.979
Datolite decomposes in air at about 970 K,
Temp.
CP
CO
ST
(HT-H$ 98 )/T
-(GT-H$98 )/T
AfH
AG
Log K
-2477.8
-2477.8
-2478.7
-2478.3
-2477.0
-2475.0
-2473.6
-2471.1
-2468.9
-2318.1
-2317.1
-2263.4
-2209.6
-2155.9
-2102.6
-2049.4
-1996.6
-1944.0
406.12
403.44
295.56
230.83
187.69
156.89
133.81
115.87
101.54
J-mol'^K"" 1 -
298.15
300
400
500
600
700
800
900
1000
Melting T
127.41
127.95
153.07
172.25
187.00
198.17
206.23
211.49
214.12
110.20
110.99
151.41
187.72
220.49
250.20
277.22
301.84
324.28
0.00
0.79
35.87
61.31
81.08
97.05
110.23
121.21
130.39
110.20
110.20
115.54
126.41
139.41
153.14
166.99
180.63
193.89
Boiling T
K
kJ
kJ
Molar Vol
H298"H8
19.25 kJ
A= -2.473E+03
B 5.301E-01
5.332 J'bar'1
53.32 cm3
C= -2.53E+05
7/22/92
318
Formula wt
ILVAITE
CaFe3 Si2070(OH):
408.793
Temp.
cp
ST
(HT-H$ 98 )/T
-<GT-H2 98 )/T
Log ]
kJ-
K
298.15
300
400
500
600
700
800
900
A 6
A H
298.90
299.90
343.40
362.50
380.90
398.50
408.10
417.80
292.30
294.20
387.70
466.50
534.20
594.30
648.10
696.70
0.00
1.85
83.02
137.00
176.10
206.70
213.20
251.40
292.30
292.35
304.68
329.50
358.10
387.60
434.90
445.30
Melting T
-3692.8
-3692.8
-3689.7
-3685.5
-3681.0
-3676.1
-3686.8
-3668.6
-3437.0
-3435.4
-3350.0
-3265.6
-3182.0
-3099.2
-3031.4
-2935.3
Boiling T
602.13
598.15
437.45
341.14
277.01
231.26
197.93
170.36
kJ
kJ
Molar Vol
H298~H8
48.09 kJ
A= -3.664E+03
B= 8.052E-01
10.107 J-bar'1
101.07 cm3
C= -1.20E+06
3/5/93
Formula wt
ANDRADITE
Ca3Pe2 Si3O12 :
319
508.177

Temp.
ST
-<G*-H598 >/'r
351.88
353.17
406.71
440.29
462.94
478.83
490.20
498.37
504.17
316.40
318.58
428.17
522.80
605.20
677.82
742.55
800.78
853.61
0.00
2.17
97.19
162.68
210.95
248.15
277.74
301.82
321.78
A 6
Log K
-5427.0
-5424.9
-5309.5
-5194.7
-5080.7
-4967.3
-4854.2
-4741.5
-4629.0
950.77
944.53
693.33
542.67
442.30
370.66
316.94
275.18
241.79
AH
kJ mol" 1
J ,mol""l1f~l>
UKJX
^
~
298.15
300
400
500
600
700
800
900
1000
<H*-H598 ,/T
316.40
316.41
330.99
360.11
394.24
429.67
464.81
498.96
531.83
Melting T
-5771.0
-5771.0
-5770.1
-5766.8
-5762.7
-5758.5
-5757.4
-5754.7
-5754.2
Boiling T
kJ
A&.H0
kJ
Molar Vol
H298"H8
53.49 kJ
A= -5.756E+03
B= 1.128E+00
13.204 J-bar'1
132.04 cm3
C= -6.85E+05
7/22/92
320
Formula wt
MONTICELLITE
CaMgSi04 :
156.466

Temp.
cp
ST
(HT-H$ 98 )/T
-(GT-H$ 98 )/T
123.00
123.46
141.90
153.07
160.69
166.26
170.53
173.91
176.64
178.88
108.10
108.86
147.16
180.11
208.73
233.94
256.44
276.72
295.19
312.14
0.00
0.76
33.96
56.75
73.47
86.35
96.61
105.02
112.05
118.03
Log Kf
-2132.8
-2132.0
-2092.3
-2052.8
-2013.5
-1974.4
-1935.4
-1896.6
-1857.2
-1817.6
373.64
371.21
273.23
214.45
175.29
147.33
126.37
110.07
97.01
86.31
UT.
J-mol" 1 -*' 1 -
298.15
300
400
500
600
700
800
900
1000
1100
A G
A fH
108.10
108.10
113.20
123.37
135.26
147.60
159.82
171.70
183.14
194.11
Melting T
-2251.0
-2251.0
-2250.9
-2249.9
-2248.6
-2247.3
-2246.8
-2245.6
-2253.2
-2252.7
Boiling T
kJ
kJ
Molar Vol
H298~H8
18.76 kJ
A= -2.248E+03
B* 3.910E-01
5.13 J'bar'1
51.3 cm3
C -1.25B+05
7/22/92
Formula wt
AKERMANITE
Tetragonal crystals 298.15 to melting point at 1731 K,

357.9 K has an enthalpy of 0.68 kJ.
321
272.628
A small transition at

Temp.
ST
CP
(HT-H$ 98 )/T
-<GT-H2 98 )/T
J-mol" 1 ^""1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
214.10
214.79
239.88
253.60
263.63
272.19
280.00
287.32
294.24
300.75
306.85
312.52
317.73
322.45
326.68
330.38
382.00
212.50
213.83
281.42
336.53
383.69
424.98
461.84
495.25
525.88
554.23
580.67
605.46
628.81
650.84
671.84
691.76
784.60
0.00
1.32
58.23
96.03
123.16
143.85
160.38
174.08
185.76
195.92
204.91
212.97
220.27
226.93
233.03
238.65
315.23
A fG
Log Kf
-3667.5
-3666.3
-3600.9
-3535.2
-3469.8
-3404.6
-3339.3
-3274.2
-3208.5
-3142.6
-3075.6
-3008.5
-2938.5
-2862.5
-2786.8
-2710.5
-2629.6
642.52
638.35
470.22
369.31
302.06
254.05
218.03
190.03
167.59
149.23
133.87
120.88
109.63
99.68
90.98
83.28
76.31
A H
kJ-mol" 1
212.50
212.50
223.19
240.50
260.53
281.13
301.46
321.16
340.12
358.32
375.76
392.48
408.54
423.96
438.81
453.11
469.37
-3864.8
-3864.8
-3864.4
-3863.1
-3861.7
-3860.3
-3860.8
-3859.7
-3867.4
-3866.9
-3882.1
-3879.6
-4004.1
-3999.6
-3994.8
-4090.1
-4253.3
Boiling T
1731 K
A,,*H
A&.H0
kJ
124. 5 kJ
Molar Vol.
H298~H8
34 .91 kJ
A= -3.904E+03
B= 6.968E-01
9 .254 J-bar'1
92 . 54 cm3
C= 2. 903E+06
7/22/92
322
Formula wt
MERWINITE
Ca3Mg(SiO4 ) 2 :
Monoclinic crystals
328.705
298.15 to 1600 K.

Temp.
CP
ST
(HT-H$ 98 )/T
-<C*-H598 >/'r
Jmol~''''K
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
Melting T
252.36
253.18
286.77
306.89
320.06
329.37
336.54
342.58
348.15
353.67
359.46
365.75
372.69
380.42
389.04
253.10
254.66
332.55
398.87
456.07
506.14
550.61
590.60
626.99
660.43
691.45
720.46
747.82
773.79
798.61
0.00
1.56
69.05
114.76
147.95
173.24
193.22
209.49
223.08
234.70
244.85
253.90
262.14
269.76
276.94
kJ-
253.10
253.10
263.50
284.11
308.12
332.90
357.39
381.12
403.91
425.73
446.60
466.56
485.68
504.03
521.67
A fG
Log Kf
-4307.7
-4306.2
-4229.6
-4153.3
-4077.5
-4002.1
-3926.6
-3851.4
-3775.5
-3699.5
-3621.6
-3543.5
-3462.5
-3375.5
-3288.9
754.67
749.77
552.32
433.89
354.97
298.63
256.38
223.52
197.21
175.67
157.64
142,. 38
129.18
117.54
107.37
AH
-4536.2
-4536.2
-4535.6
-4533.6
-4531.2
-4528.9
-4529.6
-4528.1
-4535.9
-4535.9
-4559.8
-4557.3
-4681.7
-4676.9
-4671.4
]I 1
Boiling T
kJ
Aft.H0
kJ
Molar Vol.
H298~H8
kJ
A= -4.557E+03
B= 7.840E-01
9.85 J-bar'1
98.5 cm3
C= 1.573E+06
7/22/92
Formula wt
TITANITE (SPHENE)
CaTiSi05 :
Monoclinic crystals
323
196.041
298.15 to 1670 K,

Temp.
cp
ST
(HT-H$ 98 )/T
-(GT-H2 98 )/T
J-mol'^K""1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
Melting T
138.91
139.51
161.30
172.66
179.92
185.25
189.54
193.24
196.56
199.64
202.55
205.34
208.05
210.70
213.30
129.20
130.06
173.58
210.90
243.07
271.22
296.24
318.79
339.32
358.20
375.70
392.02
407.34
421.78
435.47
0.00
0.86
38.59
64.37
83.06
97.29
108.56
117.77
125.49
132.09
137.84
142.93
147.48
151.61
155.38
A 6
A H
kJ
129.20
129.20
134.99
146.54
160.01
173.93
187.68
201.02
213.83
226.11
237.86
249.10
259.86
270.17
280.08
-2596.6
-2596.6
-2596.2
-2594.9
-2593.3
-2591.6
-2590.9
-2589.3
-2588.0
-2587.1
-2598.2
-2596.0
-2593.7
-2591.3
-2588.9
I"1
-2454.6
-2453.8
-2406.2
-2358.8
-2311.7
-2264.9
-2218.3
-2171.8
-2125.4
-2079.2
-2032.3
-1985.3
-1938.4
-1891.7
-1845.1
Boiling T
1670 K
Log Kf
430.03
427.23
314.20
246.42
201.25
169.01
144.83
126.04
111.02
98.73
88.46
79.77
72.32
65.87
60.23
K
kJ
A^0
kJ
Molar Vol.
H298~H8
kJ
A* -2.591E+03
B* 4.661E-01
5. 574 J'bar'1
55. 74 cm3
C -2 .27E+05
7/22/92
324
Formula wt
LARNITE
172.239
Monoclinic crystals 298.15 to 1000 K. Bredigite (a 1 ) is the stable modification

of Ca2 Si04 between 970 and 1710 K. a-crystals 1710 to 1800 K.
Temp.
CP
ST
<HT-H2 98 )/T
-<GT-H2 98 )/T
J-mol""1 -*" 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
128.59
128.97
145.20
156.15
164.18
170.37
175.34
179.44
180.66
185.28
189.89
194.50
199.11
203.72
208.33
212.94
205.02
127.60
128.40
167.89
201.54
230.76
256.55
279.63
300.53
319.64
337.21
353.50
368.67
382.87
396.23
408.83
420.76
444.84
0.00
0.79
35.02
58.21
75.24
88.40
98.97
107.69
115.05
121.35
126.84
131.66
135.95
139.79
143.26
146.41
160.60
A fG
Log K
-2191.2
-2190.5
-2151.8
-2113.3
-2075.1
-2037.1
-1999.2
-1961.4
-1923.7
-1886.1
-1847.2
-1808.3
-1769.6
-1731.0
-1692.6
-1653.8
-1610.9
383.88
381.39
280.99
220.77
180.65
152.01
130.53
113.83
100.48
89.56
80.41
72.66
66.02
60.28
55.26
50.81
46.75
A fH
1 _1
127.60
127.60
132.88
143.33
155.52
168.15
180.66
192.84
204.59
215.86
226.66
237.01
246.92
256.44
265.57
274.35
284.24
-2306.7
-2306.7
-2306.3
-2305.1
-2303.6
-2302.1
-2302.4
-2301.1
-2300.1
-2299.6
-2315.0
-2313.0
-2310.8
-2308.6
-2306.3
-2354.1
-2628.4
Boiling T
Av*H
A^H 0
kJ
kJ
Molar Vol.
H298"H8
kJ
A* -2.308E+03
B= 3.850E-01
5.16 J-bar'1
51.6 cm3
C= 2. 243E+05
7/22/92
325
Formula wt
CALCIO-OLIVINE
Y-Ca2 SiO4 :
172.239
Temp.
CP
ST
<HT-H$ 98 )/T
-<GT-H$ 98 )/T
300
400
500
600
700
800
900
1000
1100
1200
126.93
127.29
141.80
151.34
158.91
165.57
171.73
177.61
183.31
188.89
194.39
120.50
121.29
160.08
192.80
221.08
246.09
268.60
289.17
308.18
325.91
342.58
0.00
0.78
34.39
56.87
73.26
85.98
96.32
105.03
112.57
119.26
125.29
Log K
-2198.9
-2198.2
-2158.7
-2119.4
-2080.3
-2041.3
-2002.3
-1963.3
-1924.5
-1885.7
-1845.8
385.23
382.73
281.90
221.41
181.10
152.32
130.73
113.95
100.52
89.54
80.34
jcJ*mol_~
J-mol" 1 ^' 1 -
298.15
A 6
A H
\ T -. <M
120.50
120.50
125.69
135.93
147.82
160.10
172.28
184.14
195.61
206.66
217.30
Melting T
-2316.5
-2316.5
-2316.3
-2315.5
-2314.6
-2313.6
-2314.3
-2313.3
-2312.4
-2311.7
-2326.7
Boiling T
kJ
kJ
Molar Vol
H2*98~H8
kJ
A= -2.314E+03
B= 3.898E-01
5.801
58.01
J-bar'1
cm3
C -9.84E+04
7/22/92
326
Formula wt
HATURITE (ALITE)
Ca3Si05 :
228.317
Triclinic crystals 298.15 to 1800 K.
Temp.
CP
ST
( H*-H598 )/T
-<GT-H2 98 )/T
j mol'^lT1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
171.59
172.08
193.33
207.61
218.01
225.97
232.28
237.43
241.72
245.33
248.43
251.10
253.43
255.48
257.28
258.89
260.31
168.60
169.66
222.31
267.07
305.89
340.12
370.72
398.39
423.63
446.84
468.33
488.32
507.01
524.57
541.12
556.76
571.60
0.00
1.06
46.67
77.51
100.10
117.54
131.50
143.00
152.66
160.92
168.09
174.38
179.94
184.91
189.38
193.42
197.10
kJ-mol
168.60
168.60
175.64
189.56
205.79
222.58
239.22
255.39
270.97
285.92
300.24
313.94
327.07
339.66
351.74
363.34
374.51
A fG
Log Kf
-2786.5
-2785.6
-2736.5
-2687.8
-2639.5
-2591.5
-2543.6
-2495.8
-2448.3
-2400.8
-2351.5
-2302.0
-2252.8
-2203.8
-2155.0
-2105.9
-2048.0
488.17
485.00
357.34
280.78
229.78
193.38
166.07
144.85
127.88
114.00
102.35
92.50
84.05
76.74
70.35
64.70
59.43
A H
-2933.1
-2933.1
-2932.2
-2930.3
-2928.1
-2925.9
-2926.4
-2924.6
-2923.3
-2922.8
-2946.1
-2943.4
-2940.4
-2937.4
-2934.4
-2981.4
-3424.0
-1
Boiling T
Aô
AHHO
kJ
Molar Vol.
H298~H5
kJ
kJ
A= -2.936E+03
7 .274 J-bar'1
cm3
72 .74
B= 4. 89 IE-01
C= 4. 480E+05
7/22/92
327
Formula wt
RANKINITE
Ca3Si2O7 :
288.401
Temp.
CP
ST
<Hf-H$ 98 )/T
-<GT-H2 98 )/T
A fH
J'mol'^'K"^ -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
Melting T
214.35
215.00
242.55
260.37
272.58
281.20
287.38
291.79
294.89
296.98
298.27
298.92
299.05
1633
210.60
211.93
277.86
334.03
382.65
425.35
463.33
497.44
528.36
556.57
582.47
606.38
628.54
0.00
1.32
58.46
97.17
125.45
147.12
164.29
178.22
189.74
199.41
207.60
214.60
220.63
1, T
210.60
210.60
219.41
236.86
257.20
278.23
299.04
319.22
338.61
357.16
374.88
391.78
407.91
-3949.0
-3949.0
-3948.5
-3946.9
-3944.9
-3942.9
-3943.7
-3942.4
-3941.8
-3942.2
-3966.7
-3965.3
-3964.2
AfG
Log Kf
-3748.1
-3746.9
-3679.5
-3612.4
-3545.7
-3479.4
-3413.0
-3346.7
-3280.6
-3214.4
-3146.4
-3078.1
-3009.9
656.64
652.37
480.48
377.38
308.68
259.63
222.84
194.23
171.36
152.64
136.95
123.68
112.30
mol"1
Boiling T
K
kJ
kJ
Molar Vol
kJ
A- -3.948E+03
B= 6.684E-01
9.651 J-bar
96.51 cm3
C- 5.979E+04
7/22/92
328
Formula wt
ROSENHAHNITE
Ca3Si308 (OH) 2 :
366.500
Temp.
CP
ST
Melting T
-<Gf-H2 98 )/T
289.35
290.58
335.67
359.45
374.84
386.28
395.60
403.70
411.03
417.86
424.36
430.62
436.70
442.66
448.52
454.30
460.02
281.80
283.59
374.18
451.87
518.85
577.52
629.73
676.80
719.72
759.22
795.86
830.07
862.21
892.54
921.30
948.66
974.79
0.00
1.79
80.33
133.98
172.92
202.61
226.17
245.45
261.65
275.54
287.68
298.43
308.09
316.87
324.91
332.35
339.29
A G
Log Kf
-4882.1
-4880.2
-4774.0
-4668.1
-4562.4
-4457.2
-4351.9
-4246.8
-4141.9
-4037.0
-3930.4
-3823.6
-3717.0
-3610.7
-3504.6
-3397.4
-3276.3
855.31
849.69
623.41
487.66
397.19
332.59
284.14
246.47
216.35
191.70
171.08
153.63
138.68
125.73
114.41
104.39
95.07
A H
kJ mol'1
Jmol"^K~l
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
(Hf-H2 98 )/T
281.80
281.81
293.85
317.89
345.93
374.91
403.56
431.35
458.07
483.67
508.18
531.64
554.12
575.68
596.39
616.31
635.50
-5198.1
-5198.1
-5198.5
-5197.0
-5195.0
-5192.9
-5193.5
-5191.8
-5190.7
-5190.1
-5213.4
-5210.4
-5207.2
-5203.6
-5199.8
-5346.2
-5787.1
Boiling T
A-pH
AHHO
Molar Vol.
HJ 98-Hg
kJ
kJ
A= -5.206E+03
12. 646 J'bar'1

cm3
126. 46
kJ
B 1.065E+00
C- 6. 937E+05
7/22/92
329
SPURRITE
Formula wt
Ca5 (Si04 ) 2C03 :
444.565
Temp.
CP
ST
Melting T
-<GT-H298 )/r
343.62
344.71
388.72
415.98
434.91
449.02
460.04
468.93
476.30
482.51
487.84
492.46
331.00
333.13
438.91
528.78
606.39
674.54
735.24
789.96
839.76
885.45
927.67
966.91
0.00
2.12
93.78
155.67
200.72
235.23
262.67
285.11
303.87
319.84
333.62
345.66
kJ*mol
331.00
331.01
345.13
373.11
405.67
439.31
472.57
504.85
535.89
565.62
594.05
621.24
AfG o
Log Kf
-5525.6
-5523.6
-5418.4
-5313.9
-5210.2
-5107.2
-5004.2
-4901.5
-4799.1
-4696.9
-4591.5
-4485.9
968.04
961.73
707.55
555.12
453.58
381.09
326.73
284.47
250.68
223.03
199.86
180.24
AH
J-mol'^K"" 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
(H*-H598 ,/T
-5840.2
-5840.2
-5838.1
-5834.3
-5830.1
-5826.2
-5826.9
-5824.0
-5822.2
-5821.7
-5861.1
-5857.1
-1
Boiling T
UO
fl JMlt^
kJ
Molar Vol.
H298"H5
kJ
A= -5.829E+03
B= 1.031E+00
kJ
14. 697 J'bar'1
146. 97 cm3
C* -3.84E+05
7/23/92
330
Formula wt
TILLEYITB
Ca5Si2O7 (CO3 ) 2 :
488.575

Temp.
CP
ST
CO
(HT-H5 98 )/T
-<Gf-H2 98 )/T
A fH
J-mol"1 -*' 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
383.49
384.73
436.64
470.37
494.50
512.82
527.33
539.15
549.01
557.38
564.58
394.00
396.38
514.78
616.07
704.07
781.73
851.19
914.01
971.34
1024.07
1072.88
0.00
2.37
104.98
174.89
226.25
265.94
297.74
323.92
345.95
364.80
381.16
A fG
Log Kf
-6013.5
-6011.3
-5891.3
-5772.2
-5654.1
-5536.8
-5419.8
-5303.2
-5187.1
-5071.3
-4952.5
1053.52
1046.63
769.30
603.00
492.22
413.15
353.87
307.78
270.94
240.81
215.57
vjr mol"1
394.00
394.01
409.80
441.17
477.82
515.80
553.46
590.08
625.38
659.26
691.72
Melting T
-6372.2
-6372.2
-6369.6
-6365.1
-6360.0
-6354.9
-6354.4
-6350.0
-6346.6
-6344.4
-6382.0
Boiling T
kJ
kJ
Molar Vol
H298~H8
kJ
A -6.351E+03
B= 1.165E+00
17.050 J-bar'1
170.50 cm3
C -8.90E+05
01/07/93
Formula wt
COBALT-OLIVINE
Co2SiO4 :
331
209.950
298.15 to 1300 K,

Temp.
CP
ST
(HT-H2 98 )/T
-<GT-H2 98 )/T
A H
Melting T
133.41
133.83
151.48
162.81
170.44
175.73
179.40
181.91
183.55
184.52
142.60
143.43
184.55
219.65
250.05
276.75
300.47
321.75
341.01
358.56
0.00
0.82
36.46
60.67
78.37
91.92
102.64
111.32
118.47
124.43
Log Kf
-1308.7
-1308.0
-1273.5
-1239.4
-1205.7
-1172.4
-1139.2
-1106.3
-1073.7
-1041.1
229.27
227.74
166.30
129.47
104.96
87.48
74.38
64.21
56.08
49.44
i. T mol" 1
J-mol" 1 ^" 1 -
298.15
300
400
500
600
700
800
900
1000
1100
A fG
142.60
142.60
148.09
158.98
171.68
184.82
197.83
210.43
222.54
234.12
-1412.0
-1412.0
-1410.8
-1409.0
-1406.8
-1404.5
-1403.1
-1401.1
-1399.5
-1398.4
Boiling T
1693 K
kJ
kJ
Molar Vol
H298~H8
22.52 kJ
A= -1.401E+03
B= 3.282E-01
4.449 J'bar'1
44.49 cm3
O -4.72E+05
7/22/92
332
Formula wt
FAYALITE
Fe2 SiO4 :
203.777
Orthorhombic crystals 298.15 to 1490 K. Fayalite melts incongruently at 1490 K.


Temp.
ST
CP
Melting T
-<GT-H2 98 )/T
131.84
132.39
152.14
162.24
168.83
174.03
178.71
183.31
188.03
193.02
198.33
204.03
210.14
240.60
240.60
240.60
240.60
151.00
151.82
192.99
228.12
258.31
284.74
308.29
329.60
349.16
367.31
384.33
400.43
415.77
490.58
506.10
520.68
534.43
0.00
0.81
36.51
60.73
78.23
91.55
102.16
110.92
118.39
124.95
130.84
136.25
141.30
205.80
207.98
209.89
211.60
A fG
Log K
-1379.1
-1378.5
-1345.4
-1312.7
-1280.3
-1248.1
-1216.2
-1184.4
-1152.6
-1120.7
-1088.7
-1056.8
-1025.2
-994.4
-969.4
-944.3
-916.9
241.61
A H
Jmol~^K~^
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
<H*-H298 ,/T
kJ .ntol- 1
151.00
151.00
156.48
167.39
180.09
193.19
206.13
218.68
230.77
242.36
253.49
264.18
274.46
284.78
298.12
310.79
322.83
-1478.2
-1478.2
-1477.1
-1475.5
-1473.8
-1472.3
-1471.0
-1470.4
-1470.9
-1472.9
-1473.0
-1469.6
-1466.0
-1372.5
-1366.1
-1412.0
-1406.7
Boiling T
1490 K
240.02
175.69
137.13
111.45
93.14
79.41
68.74
60.21
53.21
47.39
42.46
38.25
34.63
31.65
29.01
26.61
K
kJ
89.3 kJ
Molar Vol.
H298~H5
22.49 kJ
A -1.457E+03
3.049E-01
4.631 J-bar'1
46.31 cm3
C -1.30E+06
7/22/92
Formula wt
ALMANDINE
Fe3Al2 Si3O12 :
Cubic crystals
333
497.753
298.15 to 1200 K,
Temp.
CP
ST
<H*-H598 ,/T
-<GT-H2 98 )/T
Melting T
Log Kf
-4941.9
-4939.9
-4831.6
-4723.6
-4616.2
-4509.5
-4403.3
-4297.5
-4190.5
-4082.4
-3974.4
865.79
860.10
630.93
493.46
401.87
336.50
287.50
249.42
218.88
193.85
173.00
kJ mol" 1
K
298.15
300
400
500
600
700
800
900
1000
1100
1200
A fG
A H
343.29
344.49
396.60
431.35
455.57
472.90
485.47
494.57
501.06
505.54
508.42
342.60
344.73
451.51
543.98
624.89
696.49
760.51
818.24
870.71
918.69
962.81
0.00
2.12
94.70
158.77
206.33
243.24
272.78
296.94
317.05
334.00
348.42
342.60
342.61
356.81
385.21
418.56
453.25
487.73
521.30
553.66
584.69
614.39
-5264.7
-5264.7
-5264.5
-5262.0
-5258.5
-5254.6
-5251.0
-5248.4
-5269.5
-5271.4
-5271.3
Boiling T
1683 K
K
kJ
kJ
Molar Vol
52.74 kJ
A -5.257E+03
B= 1.068E+00
11.532 J-bar'
115.32 cm3
C- -3.13E+05
4/6/93
334
Formula wt
CORDIERITE
Mg2Al3 (AlSi5O18 ):
584.953
298.15 to 1700 K.

Temp.
CP
ST
(Hf-H2 98 )/T
-(GT-H2 98 )/T
J-mol'^K"1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
Melting T
443.28
445.39
528.32
577.52
611.37
636.90
657.37
674.50
689.32
702.43
714.27
725.11
735.16
744.56
753.44
761.87
407.20
409.95
550.66
674.23
782.68
878.92
965.35
1043.79
1115.64
1181.97
1243.60
1301.21
1355.32
1406.36
1454.70
1500.63
0.00
2.74
124.83
210.80
274.89
324.86
365.18
398.63
426.97
451.43
472.84
491.84
508.86
524.27
538.31
551.22
A fG
Log Kf
-8651.1
-8648.0
-8476.1
-8303.9
-8132.1
-7960.8
-7790.1
-7619.9
-7445.9
-7270.2
-7095.1
-6920.4
-6740.2
-6548.0
-6356.6
-6163.4
1515.61
1505.71
1106.84
867.48
707.94
594.03
508.63
442.24
388.92
345.22
308.83
278.06
251.48
228.02
207.52
189.37
A fH
kJ-mol"1
407.20
407.21
425.83
463.43
507.79
554.06
600.16
645.16
688.67
730.54
770.76
809.37
846.45
882.09
916.38
949.41
-9161.5
-9161.6
-9164.9
-9164.2
-9161.6
-9157.8
-9153.5
-9149.2
-9204.5
-9199.3
-9193.4
-9186.9
-9434.8
-9424.6
-9414.0
-9653.8
Boiling T
Aô
AftJH0
kJ
kJ
Molar Vol.
H2*98"H8
kJ
A= -9.227E+03
B= 1.785E+00
23 .322 J-bar'1
233 .22 cm3
C= 4.350E+06
7/22/92
Formula wt
FORSTERITE
Mg2SiO4 :
335
140.693
298.15 to 1800 K.
Temp.
fo
T^
ST
Melting T
-<GT-H2 98 )/T
118.61
119.10
137.71
148.28
155.77
161.75
166.83
171.25
175.14
178.56
181.54
184.08
186.21
187.92
189.21
190.08
190.53
94.11
94.85
131.97
163.92
191.65
216.12
238.06
257.97
276.22
293.08
308.74
323.38
337.10
350.01
362.18
373.68
384.56
0.00
0.73
32.92
55.01
71.21
83.73
93.81
102.17
109.28
115.42
120.81
125.58
129.84
133.66
137.09
140.19
142.97
A G
Log Kf
-2053.6
-2052.9
-2012.8
-1972.7
-1932.9
-1893.2
-1853.6
-1814.2
-1773.6
-1732.6
-1691.8
-1651.1
-1604.2
-1545.1
-1486.3
-1427.4
-1366.2
359.78
357.43
262.84
206.09
168.27
141.27
121.03
105.29
92.64
82.27
73.64
66.34
59.85
53.80
48.52
43.86
39.64
A H
J-mol~^K"^ -
K
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
(H^-H2 98 )/T
kJ-mol"1
94.11
94.11
99.05
108.91
120.44
132.39
144.25
155.80
166.94
177.65
187.93
197.79
207.26
216.35
225.09
233.49
241.59
-2173.0
-2173.0
-2173.2
-2172.6
-2171.6
-2170.5
-2169.2
-2167.9
-2183.8
-2182.7
-2181.3
-2179.8
-2433.0
-2428.5
-2424.0
-2469.7
-2465.0
Boiling T
2163 K
A^0
AfaH
kJ
kJ
Molar Vol.
H2*98~H8
17.22 kJ
A= -2.240E+03
B= 4.675E-01
4. 365 J-bar'1
43. 65 cm3
C= 4.724E+06
7/22/92
336
Formula wt
PYROPE
Mg3Al2Si3012 :
Cubic crystals
403.127
298.15 to 1570 K.

Temp.
CP
ST
Melting T
-<G*-H598 >/'T
325.76
327.12
383.71
419.39
443.59
460.82
473.55
483.27
490.92
497.14
502.37
506.94
511.10
515.01
266.27
268.29
370.83
460.56
539.30
609 . 04
671.45
727.81
779.14
826.23
869.72
910.11
947.84
983.23
0.00
2.01
90.96
153.33
199.81
235.93
264.87
288.62
308.49
325.36
339.90
352.58
363.75
373.71
1. T-
266.27
266.28
279.87
307.24
339.49
373.11
406.57
439.19
470.65
500.87
529.82
557.54
584.08
609.52
A fG
A fH
J-mol"1 ^' 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
<HT-H 98 )/T
mol- 1
Boiling T
1570 K
-5934.5
-5932.3
-5814.4
-5696.7
-5579.5
-5462.9
-5346.9
-5231.4
-5112.8
-4993.0
-4873.7
-4754.6
-4626.6
-4480.3
-6285.0
-6285.1
-6286.1
-6284.3
-6280.9
-6276.9
-6272.6
-6268.5
-6311.8
-6308.0
-6304.0
-6299.9
-6678.0
-6669.6
A^pH0
Log Kf
1039.67
1032.88
759.27
595.12
485.72
407.64
349.11
303.62
267.06
237.09
212.14
191.04
172.62
156.01
K
kJ
241.0 kJ
Molar Vol.
H298~H8
47.85 kJ
A= -6.316E+03
B= 1.208E+00
11.312 J-bar'1
113.12 cm3
C 2.167E+06
7/22/92
337
Formula wt
GLASS
403.127
Glass 298.15 to glass transition 1020 K.
Temp.
ST
CP
\ 1*M v Q ft / /
J * inol
298.15
300
400
500
600
700
800
900
1000
Melting T
387.18
387.83
416.67
437.98
455.32
470.25
483.61
495.85
507.28
346.30
348.70
464.47
559.83
641.26
712.60
776.28
833.95
886.79
-(GT-H298 )/T
*K
0.00
2.39
102.57
167.61
214.16
249.70
278.12
301.64
321.64
1. T
346.3
346.3
361.9
392.2
427.1
462.9
498.2
532.3
565.2
AG
AfH
-6163.0
-6162.9
-6159.5
-6155.1
-6150.3
-6145.2
-6140.0
-6134.8
-6176.6
mol"1
-5836.3
-5834.3
-5725.2
-5617.2
-5510.0
-5403.7
-5298.2
-5193.2
-5085.3
Boiling T
1570 K
Log Kf
1022.48
1015.82
747.62
586.81
479.68
403.22
345.93
301.40
265.62
K
kJ
kJ
Molar Vol.
H298~H8
50.09 kJ
A* -6.143E+03
B= 1.058E+00
14.61 Jbar4
146.1 cm3
C= -7.88E+05
10/15/92
338
Formula wt
TEPHROITE
201.959
298.15 to 1524 K. Tephroite melts incongruently at 1524 K.

Temp.
CP
ST
Melting T
-<GT-H2 98 )/T
128.74
129.11
144.89
155.22
162.48
167.82
171.86
174.96
177.38
179.27
180.74
181.87
182.73
183.36
155.90
156.70
196.18
229.69
258.67
284.14
306.82
327.25
345.82
362.81
378.48
392.99
406.50
419.13
0.00
0.80
35.00
58.08
74.90
87.82
98.08
106.46
113.43
119.34
124.39
128.77
132.60
135.96
155.90
155.90
161.18
171.62
183.76
196.32
208.74
220.79
232.38
243.48
254.08
264.22
273.90
283.17
1524 K
A fG
Log Kf
-1631.0
-1630.3
-1596.6
-1563.0
-1529.7
-1496.4
-1463.4
-1430.4
-1397.4
-1364.2
-1331.0
-1297.8
-1264.6
-1230.8
285.73
283.86
208.49
163.29
133.17
111.66
95.55
83.02
72.99
64.78
57.93
52.15
47.18
42.86
A fH
J-mol~^K~^ -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
(HT-H298 )/T
-1731.5
-1731.5
-1731.3
-1730.4
-1729.5
-1728.4
-1727.5
-1726.6
-1730.3
-1729.8
-1729.2
-1728.7
-1732.9
-1737.6
.-1
Boiling T
A^pH0
K
kJ
kJ
Molar Vol.
22.35 kJ
A= -1.730E+03
B= 3.321E-01
4.899 J*bar4
48.99 cm3
C= -3.65E+04
7/22/92
339
Formula wt
LIEBENBERGITE
Ni2 Si04 :
209.463
Temp.
S To
_
/ f o _ti o 98 \)/T
/T
~(G$-H2
123.07
123.50
141.96
153.93
162.20
168.12
172.44
175.61
177.93
179.60
180.74
181.48
128.10
128.86
167.13
200.18
229.02
254.49
277.24
297.74
316.37
333.41
349.09
363.59
0.00
0.76
33.93
56.82
73.73
86.81
97.26
105.80
112.90
118.89
124.00
128.40
AfG
Log Kf
-1288.9
-1288.3
-1252.1
-1216.1
-1180.1
-1144.2
-1109.5
-1073.1
-1037.9
-1002.8
-967.9
-933.1
225.81
224.30
163.51
127.04
102.73
85.38
72.44
62.28
54.21
47.62
42.13
37.49
AH
kJ-mol"^
J-mol'^K"1
K
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
/ ti o _ti o 9 g)/T
\ / ii*
(MT-M^
128.10
128.10
133.19
143.36
155.29
167.68
179.98
191.94
203.47
214.52
225.09
235.19
Melting T
-1396.5
-1396.5
-1396.7
-1396.1
-1395.6
-1394.7
-1393.0
-1391.2
-1389.4
-1387.7
-1386.2
-1384.8
Boiling T
K
kJ
kJ
Molar Vol
19.72 kJ
A= -1.391B+03
B= 3.528E-01
4.257 J-bar'
42.57 cm3
C- -3.04E+05
7/22/92
340
Formula wt
Ni2 Si04 -SPINEL
Ni2Si04 :
209.463
Temp.
CP
ST
(Hf-H2 98 )/T
-(Gf-H2 98 )/T
AfH
Log Kf
-1280.9
-1280.3
-1243.7
-1207.3
-1171.0
-1134.8
-1099.7
224.41
222.91
162.41
126.12
101.94
84.68
71.80
kJ-mol'1
K
298.15
300
400
500
600
700
800
A f6
120.73
121.36
143.89
155.08
161.80
166.42
169.91
124.10
124.85
163.28
196.71
225.63
250.93
273.39
0.00
0.75
34.09
57.28
74.18
87.05
97.19
124.10
124.10
129.19
139.43
151.45
163.89
176.20
Melting T
-1389.7
-1389.7
-1389.8
-1389.1
-1388.5
-1387.7
-1386.2
Boiling T
K
kJ
A
rjO
A^n
1. T
KJ
Molar Vol.
H298~H8
A= -1.385E+03
B- 3.578E-01
3.981 J-bar'1
39.81 cm3
O -2.19E+05
7/29/92
Formula wt
ZIRCON
ZrSiO4 :
341
183.307

Temp.
cp
ST
-(Gf-H2 98 )/T
98.64
99.03
115.51
126.03
133.27
138.46
142.28
145.12
147.25
148.83
149.97
150.76
151.28
151.55
151.63
Melting T
84.03
84.64
115.58
142.57
166.23
187.18
205.93
222.86
238.27
252.38
265.38
277.42
288.61
299.06
308.84
A G
Log Kf
-1919.7
-1919.0
-1880.6
-1842.4
-1804.4
-1766.7
-1729.3
-1692.2
-1655.3
-1618.5
-1581.8
-1545.1
-1508.6
-1472.2
-1436.0
336.32
334.12
245.58
192.47
157.08
131.83
112.91
98.21
86.46
76.86
68.85
62.08
56.28
51.27
46.88
A fH
kJ- mol" 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
( HT-H3 98 )/T
0.00
0.61
27.45
46.18
60.13
70.97
79.65
86.78
92.72
97.76
102.06
105.78
109.01
111.84
114.33
84.03
84.03
88.14
96.39
106.10
116.21
126.28
136.08
145.54
154.62
163.32
171.64
179.60
187.22
194.52
-2034.2
-2034.2
-2034.0
-2032.9
-2031.3
-2029.5
-2027.4
-2025.4
-2023.4
-2021.4
-2023.2
-2021.0
-2018.8
-2016.7
-2014.8
Boiling T
kJ
AfaH
kJ
Molar Vol.
H2-98-H5
-2.023E+03
3 .926 J-bar4
cm3
39 .26
kJ
B= 3.674E-01
C= -6. 21E+05
7/23/92
342
Formula wt
WOLLASTONITE
CaSiO3 :
116.162
Triclinic crystals 298.15 to 1400 K. Pseudowollastonite is stable above 1398 K,

Temp.
fo
Tft
Sf
Jraol
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
86.19
86.50
99.33
107.40
112.94
116.96
120.02
122.44
124.42
126.11
127.60
128.95
130.22
81.69
82.22
109.02
132.12
152.22
169.94
185.77
200.05
213.06
225.00
236.03
246.30
255.90
-<Gf-H2 98 )/T
<HT-H2 98 )/T
K
0.00
0.53
23.77
39.74
51.50
60.58
67.83
73.77
78.74
82.97
86.63
89.83
92.67
kJ-
81.69
81.69
85.26
92.38
100.71
109.36
117.94
126.28
134.32
142.03
149.41
156.47
163.23
Melting T
AfG
Log Kf
-1549.0
-1548.5
-1519.7
-1491.0
-1462.5
-1434.2
-1405.9
-1377.8
-1349.7
-1321.7
-1293.1
-1264.4
-1235.9
271.37
269.61
198.45
155.76
127.32
107.02
91.80
79.96
70.50
62.76
56.28
50.80
46.11
A fH
-1634.8
-1634.8
-1634.7
-1633.9
-1633.0
-1631.9
-1631.8
-1630.9
-1630.1
-1629.6
-1637.1
-1635.9
-1634.7
.-1
Boiling T
kJ
kJ
Molar Vol
H2*98"H8
13.84 kJ
A= -1.632E+03
B* 2.827E-01
3.990 J'bar'1
39.90 cm3
C= -1.12E+05
7/31/92
Formula wt
PSEUDOWOLLASTONITE
CaSiO3 :
343
116.162
Triclinic crystals 298.15 to melting point 1821 K.
Temp.
CP
ST
Melting T
)/T
-<GT-H, 98 )/T
87.92
88.20
99.53
106.55
111.43
115.06
117.89
120.17
122.06
123.65
125.01
126.19
127.23
128.14
128.95
129.68
130.34
87.20
87.74
114.82
137.84
157.72
175.18
190.74
204.76
217.52
229.23
240.05
250.10
259.49
268.30
276.60
284.44
291.87
0.00
0.54
24.00
39.86
51.40
60.25
67.28
73.04
77.85
81.94
85.48
88.56
91.29
93.72
95.89
97.86
99.65
1. T
87.20
87.20
90.82
97.98
106.32
114.93
123.45
131.72
139.67
147.29
154.57
161.54
168.21
174.59
180.71
186.58
192.23
A G
Log K
-1543.5
-1542.9
-1514.7
-1486.6
-1458.7
-1430.9
-1403.2
-1375.5
-1347.8
-1320.3
-1292.1
-1263.8
-1235.7
-1207.6
-1179.6
-1145.1
-1118.1
270.40
268.64
197.80
155.30
126.99
106.77
91.61
79.83
70.40
62.69
56.24
50.78
46.10
42.05
38.51
35.37
32.44
A H
j. mol' 1 '!r 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
(E
mol"1
lUWJk
-1627.6
-1627.6
-1627.4
-1626.7
-1625.8
-1625.0
-1625.0
-1624.3
-1623.8
-1623.6
-1631.3
-1630.4
-1629.4
-1628.4
-1627.5
-1676.7
-1824.1
Boiling T
1821 K
A HO
A^H 0
kJ
57.3 kJ
Molar Vol.
H98"H8
kJ
A= -1.629E+03
B= 2.815E-01
4. 008 J-bar'1
40. 08 cm3
C= 1. 853E+05
7/31/92
344
Formula wt
glass
CaSiO3 :
116.162
Glass 298.15 to 1821 K, melting point of pseudowollastonite.

Temp.
CP
ST
(H*-HJ98 ,/T
-<GT-H2 98 )/T
J-mol"1 ^' 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
86.81
87.12
99.31
106.80
112.43
117.18
121.47
125.49
129.34
133.07
136.74
140.35
143.92
147.46
150.99
154.49
157.98
94.80
95.34
122.25
145.27
165.26
182.95
198.88
213.42
226.85
239.35
251.09
262.17
272.70
282.76
292.38
301.64
310.57
0.00
0.54
23.86
39.75
51.41
60.47
67.83
74.02
79.36
84.07
88.31
92.17
95.74
99.07
102.21
105.18
108.02
1. T
94.80
94.80
98.39
105.52
113.85
122.48
131.05
139.41
147.49
155.28
162.78
170.00
176.96
183.68
190.18
196.46
202.56
1821 K
A fG
Log Kf
-1526.8
-1526.3
-1498.8
-1471.5
-1444.3
-1417.3
-1390.3
-1363.5
-1336.8
-1310.1
-1283.0
-1255.9
-1229.0
-1202.3
-1175.8
-1149.0
-1117.8
267.49
265.75
195.72
153.72
125.74
105.76
90.78
79.13
69.82
62.21
55.85
50.46
45.85
41.87
38.39
35.30
32.44
A H
-1608.7
-1608.7
-1608.5
-1607.8
-1606.9
-1605.9
-1605.7
-1604.5
-1603.4
-1602.3
-1609.0
-1606.8
-1604.3
-1601.5
-1598.5
-1645.3
-1790.2
ntoi-1
Boiling T
K
kJ
kJ
Molar Vol.
14.20 kJ
A* -1.606E+03
B= 2.698E-01
4.013 J-bar'1
40.13 cm3
0 -6.93E+04
7/31/92
Formula wt
Ca-Al PYROXENE
CaAl2SiOg:
345
218.123
Monoclinic crystals 298.15 to 1000 K,
Temp.
CP
S511
(Hf-H298 )/T
-<GT-H298 )/T
K
298.15
300
400
500
600
700
800
900
1000
AM
164 .97
165 .63
194 .10
212 .57
225 .29
234 .43
241 .23
246 .45
250 .58
141. 00
142. 02
193. 89
239. 32
279. 27
314. 72
346. 49
375. 22
401. 40
0.00
1.02
46.01
77.59
101.21
119.62
134.42
146.59
156.79
141 .00
141 .00
147 .88
161 .73
178 .06
195 .10
212 .07
228 .63
244 .61
Melting T
AfG
Log Kf
-3129.6
-3128.5
-3069.0
-3009.7
-2950.5
-2891.7
-2833.1
-2774.7
-2715.0
548.27
544.70
400.77
314.41
256.86
215.78
184.98
161.04
141.81
AfH
-3306. 3
-3306. 3
-3306. 9
-3306. 0
-3304. 3
-3302. 4
-3301. 3
-3299. 5
-3319. 2
HBV
Boiling T
K
kJ
kJ
Molar Vol.
24.40 kJ
A -3.303E+03
5.877E-01
6.357 Jbar'
63.57 cm3
O -1.73E+05
04/30/93
346
Formula wt
HEDENBERGITE
CaFeSi2Og:
248.092
Monoclinic crystals 298.15 to 1300 K. Decomposes at 1238 K.
FORMATION PROM THE ELEMENTS

Temp.
CP
Sf
J-1
K
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
<H*-H298 )/T
175.30
175.94
201.95
218.13
229.59
238.39
245.51
251.49
256.67
261.25
265.37
269.13
174.20
175.29
229.81
276.73
317.57
353.65
385.96
415.23
442.00
466.68
489.59
510.99
0.00
1.08
48.35
80.79
104.69
123.18
138.04
150.32
160.71
169.64
177.45
184.36
-<GT-H2 98 )/T
A fH
AfG.
Log Kf
-2676.3
-2675.2
-2620.4
-2565.9
-2511.7
-2457.9
-2404.4
-2351.1
-2298.0
-2244.9
-2191.3
-2137.6
468.86
465.79
342.18
268.05
218.66
183.41
156.99
136.45
120.03
106.60
95.38
85.90
t-T mol"1
--1
174.20
174.20
181.46
195.94
212.88
230.46
247.92
264.90
281.29
297.04
312.14
326.63
Melting T
-2839.9
-2839.9
-2839.3
-2837.6
-2835.4
-2833.2
-2831.8
-2829.8
-2828.6
-2828.4
-2835.2
-2831.6
Boiling T
kJ
kJ
Molar Vol
28.23 kJ
-2.830E+03
B= 5.328E-01
6.795 J-bar'1
67.95 cm3
C= -4.43E+05
7/31/92
Formula wt
DIOPSIDE
CaMgSi2Og:
Monoclinic crystals
347
216.550
298.15 to incongruent melting point at 1668 K.
Temp.
CP
S*
(H$-H598 )/T
-<Gf-H2 98 )/T
J-mol" 1 -*""1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
Melting T
166.78
167.46
195.68
213.25
224.98
233.19
239.21
243.80
247.47
250.57
253.33
255.94
258.51
261.16
263.96
142.70
143.73
196.12
241.81
281.80
317.13
348.68
377.13
403.02
426.75
448.67
469.05
488.11
506.04
522.98
1668
0.00
1.03
46.47
78.19
101.74
119.97
134.51
146.41
156.34
164.77
172.03
178.39
184.02
189.07
193.67
1. T
142.70
142.70
149.65
163.62
180.06
197.17
214.17
230.72
246.68
261.98
276.64
290.66
304.09
316.97
329.32
A fG
Log Kf
-3026.8
-3025.7
-2967.1
-2908.6
-2850.4
-2792.6
-2735.0
-2677.7
-2619.9
-2562.1
-2503.8
-2445.5
-2384.3
-2317.1
-2250.2
530.27
526.81
387.45
303.85
248.14
208.38
178.58
155.41
136.85
121.66
108.98
98.26
88.96
80.69
73.46
AfH
-3201.5
-3201.5
-3201.6
-3200.2
-3198.2
-3196.0
-3194.6
-3192.4
-3199.1
-3197.6
-3204.0
-3201.7
-3326.7
-3322.9
-3319.0
mol
Boiling T
kJ
137.7
kJ
Molar Vol.
H2*98~H0*
25.24 kJ
A* -3.213E+03
B= 5.949E-01
6.609 J-bar'1
66.09 cm3
C* 9.377E+05
7/31/92
348
Formula wt
CaMgSi2O6 GLASS
CaMgSi206 :
216.550
Glass 298.15 to 1400 K,

Temp.
ST
CP
(Hf-H2 98 )/T
-<GT-H2 98 )/T
i-l-l
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
168.31
168.93
196.43
213.62
224.44
232.22
239.22
247.01
256.65
268.92
284.36
303.39
326.34
166.00
167.04
219.69
265.52
305.50
340.70
372.17
400.78
427.28
452.30
476.33
499.82
523.12
Melting T
0.00
1.04
46.69
78.50
101.99
120.06
134.51
146.57
157.07
166.66
175.80
184.86
194.12
A fG
Log Kf
-2988.3
-2987.3
-2931.0
-2874.9
-2819.1
-2763.7
-2708.4
-2653.5
-2598.1
-2542.7
-2487.0
-2431.7
-2373.8
523.53
520.12
382.74
300.33
245.42
206.22
176.84
154.00
135.71
120.74
108.26
97.71
88.56
A fH
kJ-mol" 1
166.00
166.00
172.99
187.02
203.51
220.65
237.65
254.21
270.21
285.63
300.53
314.96
328.99
-3156.1
-3156.1
-3156.1
-3154.7
-3152.7
-3150.5
-3149.2
-3146.8
-3152.9
-3150.1
-3154.1
-3147.9
-3267.2
Boiling T
kJ
kJ
Molar Vol.
H298~H5
76.09
26 .94 kJ
A* -3.152E+03
7.609
B= 5.546E-01
J-bar'1
cm3
0 -1.44E+05
10/15/92
349
Formula wt
FERROSILITE
FeSiO3 :
131.931
298.15 to 800 K,
Temp.
S|
<H*-H598 ,/T
-<Gf-H2 98 )/T
J-1.--1
298.15
300
400
500
600
700
800
90.63
91.13
109.00
118.06
123.64
127.58
130.65
94.60
95.16
124.16
149.56
171.61
190.98
208.22
0.00
0.56
25.73
43.37
56.32
66.23
74.10
1. T
94.60
94.60
98.43
106.18
115.29
124.75
134.12
Melting T
A fG
Log Kf
-1118.0
-1117.5
-1091.7
-1066.2
-1041.1
-1016.4
-991.9
195.86
194.57
142.56
111.39
90.64
75.84
64.76
A fH
-1195.2
-1195.2
-1194.3
-1192.6
-1190.7
-1188.8
-1187.0
mol" 1
Boiling T
kJ
kJ
Molar Vol
kJ
A* -1.188E+03
B= 2.460E-01
3.300
33.00
J-bar'1
cm3
C= -2.90E+05
05/07/93
350
Formula wt
a-SPODUMENE
LiAlSi2O6 :
186.090

Temp.
CP
ST
(Hf-H2 98 )/T
-<GT-H2 98 )/T
A fH
158.93
159.48
184.73
203.25
217.12
227.78
236.12
242.75
248.07
252.37
255.84
129.30
130.28
179.81
223.13
261.47
295.77
326.75
354.96
380.82
404.68
426.79
0.00
0.98
43.93
74.03
96.78
114.76
129.43
141.67
152.05
160.98
168.75
Log Kf
-2880.2
-2879.2
-2820.8
-2762.1
-2703.2
-2644.5
-2586.0
-2527.9
-2469.4
-2410.7
-2352.3
504.59
501.29
368.36
288.55
235.33
197.33
168.85
146.71
128.98
114.47
102.39
kJ*m _i 1
J-mol'^K"1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
A fG
129.30
129.30
135.88
149.09
164.69
181.01
197.32
213.29
228.77
243.69
258.04
-3053.5
-3053.5
-3054.5
-3057.3
-3056.3
-3054.4
-3052.1
-3049.6
-3057.4
-3054.3
-3050.9
Boiling T
Melting T
K
kJ
kJ
Molar Vol
H298~H8
kJ
A= -3.054E+03
B= 5.849E-01
5.837 J-bar'1
58.37 cm3
C* -5.34E+04
9/18/92
351
Formula wt
fJ-SPODUMENE
L1A1S12O6 :
186.090
Melting point is 1696 K,
Temp.
CP
ST
(Hf-H2 98 )/T
-(GT-H2 98 )/T
A fG
Log Kf
-2859.5
-2858.5
-2802.7
-2746.7
-2690.5
-2634.7
-2579.1
-2523.9
-2468.3
-2412.6
-2357.2
-2302.1
-2247.4
-2192.9
-2138.7
-2076.7
500.96
497.69
A fH
kJ-mol~l
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
Melting T
162.77
163.37
189.58
207.34
220.36
230.39
238.41
244.98
250.49
255.18
259.22
262.74
265.84
268.58
271.03
273.23
154.40
155.41
206.27
250.60
289.60
324.36
355.66
384.14
410.24
434.34
456.72
477.61
497.20
515.63
533.05
549.55
0.00
1.01
45.11
75.88
98.93
117.02
131.71
143.94
154.33
163.29
171.12
178.03
184.20
189.73
194.74
199.29
154.40
154.40
161.16
174.71
190.68
207.34
223.95
240.19
255.91
271.05
285.60
299.58
313.00
325.90
338.31
350.25
-3025.3
-3025.3
-3025.8
-3028.2
-3026.8
-3024.7
-3022.1
-3019.3
-3026.9
-3023.5
-3019.9
-3016.0
-3012.1
-3008.0
-3003.8
-3245.1
Boiling T
1696 K
A^H
A^H0
kJ
kJ
Molar Vol.
H298-H6
365.99
286.94
234.23
196.60
168.40
146.48
128.93
114.56
102.60
92.50
83.85
76.36
69.82
63.81
kJ
A= -3.023E+03
B* 5.543E-01
7 .825 J-bar'1
78 .25 cm3
C* -2.00E+05
10/16/92
352
Formula wt
ENSTATITE
MgSiO3 :
100.389
298.15 to 1000 K.
Temp.
CP
ST
(HT-H2 98 )/T
-<Gf-H$ 98 )/T
AfG
Log Kf
-1458.3
-1457.7
-1428.4
-1399.1
-1370.1
-1341.2
-1312.6
-1284.1
-1255.1
255.48
253.81
186.52
146.16
119.27
100.08
85.70
74.52
65.56
A fH
kJ- mol"1
298.15
300
400
500
600
700
800
900
1000
Melting T
83.09
83.41
97.40
106.62
112.88
117.44
121.10
124.39
127.68
66.27
66.78
92.83
115.63
135.66
153.41
169.34
183.80
197.07
0.00
0.51
23.11
38.95
50.78
59.99
67.41
73.56
78.81
66.27
66.27
69.73
76.68
84.87
93.42
101.93
110.24
118.27
-1545.6
-1545.6
-1545.6
-1544.9
-1543.8
-1542.5
-1541.1
-1539.6
-1546.7
Boiling T
K
kJ
kJ
Molar Vol
11.99 kJ
A= -1.542E+03
B= 2.869E-01
3.131 J-bar'1
31.31 cm3
C- -1.78E+05
7/31/92
Formula wt
CLINOENSTATITE
MgSi03 :
Crystals
353
100.389
298.15 to melting point at 1830 K,
Temp.
ST
CP
<Hf-H2 98 )/T
-<Gf-H298 )/T
A fH
K
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
Melting T
1. T.
82.12
82.34
93.04
101.20
107.42
112.22
115.98
118.95
121.32
123.22
124.73
125.93
126.87
127.60
128.14
67.86
68.37
93.59
115.27
134.29
151.23
166.47
180.30
192.96
204.62
215.41
225.44
234.81
243.59
251.84
0.00
0.51
22.36
37.35
48.53
57.30
64.41
70.31
75.30
79.57
83.27
86.51
89.36
91.89
94.14
67.86
67.86
71.23
77.92
85.76
93.92
102.06
109.99
117.67
125.05
132.13
138.93
145.45
151.70
157.71
-1545.0
-1545.0
-1545.3
-1545.1
-1544.6
-1543.8
-1542.9
-1541.9
-1549.6
-1548.7
-1547.7
-1546.7
-1673.1
-1670.8
-1668.5
AfG
Log Kf
-1458.1
-1457.6
-1428.4
-1399.2
-1370.0
-1341.0
-1312.1
-1283.3
-1253.9
-1224.3
-1194.9
-1165.5
-1133.1
-1094.6
-1056.3
255.45
253.78
186.52
146.17
119.27
100.06
85.67
74.48
65.49
58.14
52.01
46.83
42.28
38.12
34.48
mol"1
Boiling T
1830 K
kJ
61.50 kJ
Molar Vol
kJ
-1.562E+03
B= 3.088E-01
3.128
31.28
J-bar*1
cm3
C= 1.138E+06
10/16/92
354
Formula wt
MgSi03-ILMENITE
100.389
Ilmenite structure form stable only at high pressure 298.15 to 700 K,
Temp.
CP
S*
<Hf-H2 98 )/T
-<Gf-H2 98 )/T
J-mol"1 ^'1 -
298.15
300
400
500
600
700
102 .64
102 .63
104 .92
109 .92
115 .98
122 .55
60.40
61.03
90.77
114.69
135.26
153.62
0.00
0.63
26.33
42.52
54.25
63.53
JCU
1 T
60 .40
60 .40
64 .44
72 .17
81 .01
90 .09
Melting T
A fG
Log Kf
-1397. 5
-1397. 0
-1367. 3
-1337. 9
-1308. 8
-1279. 9
244.83
243.23
178.54
139.77
113.94
95.51
A fH
-1486. 6
-1486. 6
-1485. 4
-1484. 2
-1482. 8
-1481. 0
mol"1
Boiling T
kJ
kJ
Molar Vol
H2*98~H5
kJ
A* -1.481E+03
B= 2.885E-01
2.636 J-bar'1
26.36 cm3
C= -1.88E+05
12/9/92
Formula wt
RHODONITE
MnSiO3 :
Triclinic crystals
355
131.022
298.15 to 1600 K. Melts incongruently at 1564 K,
Temp.
CP
Sf
(Hf-H2 98 )/T
-<GT-H2 98 )/T
J-mol"1 ^" 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
Melting T
86.44
86.84
101.42
108.73
113.29
116.61
119.31
121.67
123.83
125.87
127.83
129.75
131.63
133.50
135.35
100.50
101.04
128.30
151.79
172.04
189.77
205.52
219.71
232.64
244.54
255.58
265.89
275.57
284.72
293.39
0.00
0.53
24.18
40.43
52.21
61.19
68.29
74.09
78.96
83.13
86.77
90.01
92.91
95.56
97.99
VT
100.50
100.50
104.12
111.37
119.83
128.58
137.23
145.62
153.69
161.41
168.81
175.88
182.66
189.16
195.41
AG
Log Kf
-1244.7
-1244.2
-1218.4
-1192.7
-1167.2
-1141.9
-1116.6
-1091.5
-1066.4
-1041.3
-1016.2
-991.1
-966.1
-940.9
-915.1
218.05
216.63
159.10
124.60
101.61
85.21
72.91
63.35
55.70
49.44
44.23
39.82
36.05
32.76
29.87
AH
-1321.6
-1321.6
-1321.4
-1320.6
-1319.8
-1318.9
-1318.0
-1317.2
-1318.6
-1317.8
-1317.0
-1316.1
-1317.4
-1318.9
-1330.5
mol"1
Boiling T
1564 K
K
kJ
A^0
kJ
Molar Vol.
H298"H8
14.55 kJ
A* -1.318E+03
B- 2.513E-01
3. 494 J'bar'1
34. 94 cm3
0 -1. 87E+05
4/5/93
356
Formula wt
JADEITE
NaAlSi2O6 :
Monoclinic crystals
202.139
298.15 to 1300 K,
Temp.
CP
Sf
<HT-H2 98 )/T
-<GT-H2 98 )/T
J-mol"1 -^1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
Melting T
159.92
160.62
188.41
205.31
217.07
225.96
233.06
238.96
244.02
248.44
252.39
255.96
133.50
134.49
184.89
228.88
267.41
301.57
332.22
360.02
385.46
408.93
430.72
451.07
0.00
0.99
44.71
75.25
97.96
115.64
129.89
141.69
151.67
160.27
167.79
174.44
kJ*mol
133.50
133.50
140.19
153.63
169.45
185.93
202.33
218.33
233.79
248.66
262.94
276.63
A 6
Log Kf
-2850.6
-2849.5
-2789.1
-2728.2
-2667.4
-2606.8
-2546.5
-2486.5
-2426.0
-2365.3
-2302.4
-2234.0
499.40
496.13
364.22
285.01
232.21
194.52
166.27
144.31
126.72
112.32
100.22
89.76
A H
-3029.3
-3029.3
-3033.0
-3032.7
-3031.6
-3029.9
-3027.8
-3025.6
-3033.8
-3031.1
-3125.0
-3121.1
-1
Boiling T
Av*H
A^H"
kJ
Molar Vol.
H2*98~H6
kJ
A= -3.039E+03
B= 6.146E-01
K
kJ
6. 040 J-bar'1
60. 40 cm3
C= 4.741E+05
7/31/92
Formula wt
ACMITE
NaFeSi2O6 :
Monocltnic crystals
357
231.004
298.15 to 1300 K.

Temp.
CP
**
(H*-H298 ,/T
-<GT-H2 98 )/T
Melting T
169.88
170.58
197.52
213.32
224.73
234.07
242.31
249.91
257.10
264.04
270.80
277.44
170.57
171.62
224.81
270.70
310.65
346.01
377.81
406.80
433.50
458.33
481.60
503.54
0.00
1.05
47.17
78.93
102.32
120.49
135.21
147.54
158.13
167.45
175.78
183.35
Log Kf
-2417.2
-2416.2
-2359.8
-2303.0
-2246.4
-2190.2
-2134.3
-2078.6
-2023.2
-1968.0
-1910.5
-1847.6
423.48
420.69
308.15
240.59
195.57
163.43
139.35
120.64
105.68
93.45
83.16
74.24
kJ-mol"1
,-!.--!
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
A G
A H
170.57
170.57
177.64
191.78
208.33
225.52
242.60
259.26
275.37
290.88
305.82
320.19
-2584.5
-2584.5
-2587.4
-2586.4
-2584.9
-2582.9
-2580.6
-2578.2
-2576.2
-2574.5
-2668.5
-2662.8
Boiling T
K
kJ
kJ
Molar Vol.
H2*98~H8
26. 94 kJ
A= -2.587E+03
B= 5.648E-01
6 .460 J-bar'1
64 .60 cm3
0 9 .860E+04
7/31/92
358
Formula wt
TREMOLITE
Ca2Mg5Si8O22(OH) 2 :
Monoclinic crystals
812.366
298.15 to 1000 K.
Temp.
ST
CP
-<Gf-H2 98 )/T
655.44
657.85
774.71
850.48
895.82
926.86
956.04
992.18
1041.58
548.90
552.96
759.08
940.81
1100.21
1240.73
1366.36
1480.95
1587.91
0.00
4.05
182.86
309.46
403.71
476.31
534.42
583.18
626.42
AG
Log Kf
-11574.6
-11570.0
-11325.2
-11080.8
-10837.7
-10596.1
-10355.5
-10116.1
-9874.4
2027.77
2014.47
1478.89
1157.59
943.48
790.67
676.13
587.11
515.78
A H
kJ- mo l~l
J-1--1
K
298.15
300
400
500
600
700
800
900
1000
(HJ-HJ98 ,/T
548.90
548.91
576.22
631.36
696.50
764.42
831.94
897.77
961.49
Melting T
-12303.0
-12303.1
-12304.7
-12299.8
-12292.0
-12283.0
-12275.3
-12265.0
-12295.7
Boiling T
K
kJ
kJ
Molar Vol
H298~H8
97.63 kJ
A= -1.228E+04
B= 2.405E+00
27.290 J'bar'1
272.90 cm3
-1.24E+06
7/31/92
359
Formula wt 1001.614
GRUNERITE
Fe7Si8O22(OH) 2 :
Temp.
cp
ST
(Hf-H2 98 )/T
-<Gf-H5 98 )/T
681 .08
683 .99
798 .99
871 .66
927 .67
975 .82
1019 .77
1061 .29
725.00
729.22
943.37
1129.92
1293.95
1440.64
1573.85
1696.37
0.00
4.21
189.94
319.42
416.28
492.84
555.99
609.84
,Q!
725. 00
725. 01
753. 43
810. 50
877. 68
947. 80
1017. 86
1086. 53
Melting T
-9623 .0
-9623 .1
-9622 .2
-9616 .4
-9607 .7
-9597 .4
-9586 .0
-9574 .5
:G
Log Kf
-8964 .8
-8960 .7
-8739 .9
-8519 .9
-8301 .4
-8084 .5
-7869 .1
-7655 .1
1570.56
1560.17
1141.28
890.05
722.68
603.26
513.79
444.28
- kJ*m
J-mor^-KT 1 -
298.15
300
400
500
600
700
800
900
A frH
1
Boiling T
kJ
kJ
Molar Vol
H298~H8
kJ
-9.590E+03
B= 2.154E+00
27.870 J-bar'1
278.70 cm3
C- -1.52E-H06
9/18/92
360
Formula wt
ANTHOPHYLLITE
Mg7Si8O22 (OH) 2 :
Monoclinic crystals
780.820
298.15 to 1200 K.
Temp.
ST
CP
<HT-H2 98 )/T
-(GT-H2 98 )/T
J-mol'^K' 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
664.02
667.12
788.45
859.43
907.21
942.29
969.58
991.72
1010.24
1026.11
1039.97
534.50
538.62
748.97
933.12
1094.29
1236.89
1364.57
1480.09
1585.56
1682.61
1772.50
0.00
4.10
186.60
314.60
409.61
483.32
542.46
591.19
632.19
667.30
697.79
1. T
534.50
534.51
562.37
618.53
684.68
753.58
822.11
888.90
953.37
1015.31
1074.71
Melting T
A 6
Log Kf
-11343.4
-11338.8
-11094.9
-10851.7
-10610.1
-10370.2
-10131.9
-9895.0
-9654.6
-9413.7
-9174.0
1987.26
1974.22
1448.81
1133.64
923.67
773.82
661.53
574.28
504.29
447.01
399.32
A H
-12070.0
-12070.1
-12070.0
-12063.8
-12054.7
-12043.9
-12032.2
-12020.3
-12068.5
-12057.1
-12045.0
- _. * 1
Boiling T
K
kJ
kJ
Molar Vol
H298"H8
96.78 kJ
A= -1.204E+04
B= 2.389E+00
26.540 J-bar"1
265.40 cm3
O -1.29E+06
4/5/93
Formula wt
GLAUCOPHANE
361
783.543

Temp.
CP
ST
(Hf-H2 9Q )/T
-<GT-H2 98 )/T
J-mol"1 -*" 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
Melting T
645.48
647.73
750.28
823.97
878.30
919.33
950.88
975.41
994.60
1009.62
1021.32
541.20
545.20
746.42
922.19
1077.46
1216.07
1340.98
1454.45
1558.26
1653.79
1742.16
0.00
3.99
178.46
300.59
392.56
465.02
523.86
572.73
613.99
649.31
679.84
A fG
Log K
-11230.8
-11226.2
-10979.0
-10730.6
-10482.8
-10236.2
-9990.9
-9746.8
-9500.4
-9253.5
-9003.0
1967.54
1954.61
1433.68
1120.99
912.59
763.82
652.32
565.68
496.24
439.40
391.88
A fH
1. T
541.20
541.21
567.95
621.60
684.89
751.05
817.12
881.73
944.26
1004.48
1062.32
-11964.0
-11964.1
-11973.3
-11971.7
-11966.2
-11958.0
-11948.3
-11937.7
-11973.7
-11962.3
-12144.0
Boiling T
K
kJ
kJ
Molar Vol
H2*98~H5
95.62 kJ
A- -1.196E+04
B= 2.462E+00
26.210 J'bar'1
262.10 cm3
C* -4.11E+05
8/5/92
362
Formula wt
ANORTHITE
CaAl2 Si208 :
278.207
Triclinic (PI) crystals 298.15 to 510 K: triclinic (II) crystals 510 to melting
point 1830 K.

Temp.
cp
o
ST
(Hf-H2 98 )/T
-<G*-HJ 98 ,/'r
1-1. .-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
211.34
212.23
248.25
270.17
285.13
296.26
305.17
312.78
319.67
326.21
332.67
339.23
346.03
353.18
360.75
368.81
377.41
199.30
200.61
267.09
325.01
375.67
420.49
460.65
497.04
530.36
561.13
589.80
616.68
642.07
666.18
689.22
711.33
732.65
0.00
1.31
58.96
99.17
128.98
152.12
170.71
186.08
199.10
210.36
220.28
229.18
237.28
244.77
251.78
258.42
264.79
Log Kf
-4007.9
-4006.5
-3930.5
-3854.5
-3778.9
-3703.7
-3628.7
-3554.0
-3478.1
-3401.6
-3324.7
-3248.0
-3171.7
-3095.6
-3019.9
-2943.6
-2860.5
702.15
697.57
513.25
402.67
328.98
276.37
236.93
206.27
181.67
161.52
144.72
130.50
118.33
107.79
98.59
90.44
83.01
AH
i T _ mo i-l
199.30
199.30
208.12
225.84
246.68
268.37
289.94
310.96
331.26
350.78
369.51
387.50
404.79
421.42
437.44
452.90
467.86
1830 K
-4234.0
-4234.0
-4234.6
-4233.4
-4231.4
-4229.1
-4227.5
-4225.2
-4244.3
-4241.8
-4246.9
-4243.0
-4238.6
-4233.8
-4228.4
-4322.7
-4464.2
Boiling T
K
kJ
A^H0
133.0 kJ
Molar Vol.
H2*98~H8
33.33 kJ
A= -4.240E+03
B= 7.634E-01
10.079 J-bar'1
100.79 cm3
0 4.945E+05
7/30/92
CaAl2 Si2O8-GLASS
CaAl2 Si208 :
Formula wt
363
278.207
Glass 298.15 to 1500 K.

Temp.
f
CP
ST
Melting T
-(GT-H2 98 )/T
210.65
211.54
247.44
269.96
286.17
298.89
309.44
318.53
326.59
333.90
340.62
346.89
352.80
358.41
237.30
238.61
304.86
362.65
413.37
458.48
499.09
536.08
570.06
601.54
630.88
658.40
684.33
708.86
0.00
1.30
58.76
98.89
128.82
152.24
171.25
187.12
200.67
212.45
222.86
232.16
240.57
248.24
A fG
Log Kf
-3948.4
-3947.1
-3874.9
-3802.7
-3730.9
-3659.4
-3588.3
-3517.4
-3445.4
-3372.9
-3300.1
-3227.5
-3155.4
-3083.6
691.73
687.23
505.99
397.26
324.79
273.06
234.28
204.14
179.97
160.16
143.65
129.68
117.73
107.38
A fH
kJ-mol'1
J-mol"1 ^"1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
(Hf-H2 98 )/T
237.30
237.30
246.09
263.76
284.55
306.24
327.85
348.96
369.39
389.08
408.03
426.24
443.76
460.62
-4163.2
-4163.2
-4163.9
-4162.7
-4160.7
-4158.2
-4156.3
-4153.5
-4171.9
-4168.7
-4173.0
-4168.3
-4163.2
-4157.8
Boiling T
K
kJ
kJ
Molar Vol.
H298~H8
33 .15 kJ
A= -4.164E+03
B* 7.199E-01
10. 30 J-bar'1
103. 0 cm3
C* 1 .207E+05
9/16/92
364
Formula wt
BICCHULITE
Ca2Al2Si06 (OH) 2 :
292.216
Temp.
CP
<H*-H598 >
-0*-H*98 >,r
AfH
AG
Log Kf
-4073.0
-4071.4
-3981.2
-3891.0
-3801.0
-3711.3
-3621.5
-3532.0
-3441.2
-3349.7
-3257.2
-3164.7
-3072.7
-2981.0
-2889.7
-2798.3
-2700.6
713.56
708.87
519.88
406.48
330.90
276.93
236.46
204.99
179.74
159.06
141.78
127.16
114.64
103.80
94.34
85.98
78.37
kJ-mol -1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
240.87
241.81
277.62
298.60
313.75
326.14
337.06
347.12
356.66
365.85
374.80
383.59
392.26
400.84
409.35
417.80
426.22
213.10
214.59
289.63
353.99
409.83
459.15
503.43
543.71
580.78
615.21
647.43
677.78
706.52
733.88
760.02
785.09
809.21
0.00
1.49
66.54
111.00
143.58
168.80
189.16
206.16
220.73
233.51
244.91
255.24
264.72
273.51
281.73
289.49
296.85
213.10
213.10
223.09
243.00
266.25
290.36
314.27
337.56
360.05
381.70
402.52
422.53
441.80
460.37
478.29
495.60
512.36
-4341.2
-4341.2
-4342.2
-4341.6
-4340.3
-4338.6
-4338.6
-4336.9
-4356.6
-4354.8
-4368.4
-4364.0
-4359.1
-4353.3
-4347.0
-4390.2
-4679.6
Boiling T
Aô
AjfcH0
kJ
kJ
Molar Vol.
H298~H6
kJ
A= -4.356E+03
B= 9.167E-01
10. 368 J-bar'1

103. 68 cm3
C= 9.910E+05
7/30/92
365
Formula wt
MEIONITE (Al/Si ORDERED)
Ca4Al6Si6O24CO3 :
934.709

Temp.
cp
CO
ST
-(GT-H$ 98 )/T
709.51
713.05
844.29
915.47
963.02
999.41
1029.84
1056.82
1081.65
1105.08
1127.55
715.20
719.60
945.01
1141.70
1313.04
1464.33
1599.81
1722.70
1835.34
1939.54
2036.67
0.00
4.39
199.95
336.51
437.18
514.99
577.49
629.28
673.29
711.49
745.23
A fG
Log Kf
-13131.8
-13127.1
-12875.3
-12624.1
-12374.1
-12125.5
-11877.6
-11630.7
-11380.3
-11128.1
-10874.3
2300.58
2285.58
1681.30
1318.80
1077.24
904.80
775.51
675.01
594.43
528.42
473.33
A fH
kJ-t .-1
,-1 _-l
298.15
300
400
500
600
700
800
900
1000
1100
1200
<HT-H$ 98 )/T
715.20
715.21
745.06
805.18
875.86
949.33
1022.32
1093.42
1162.05
1228.06
1291.44
-13881.4
-13881.5
-13882.2
-13877.0
-13869.8
-13861.6
-13856.8
-13848.8
-13905.1
-13896.8
-13919.2
Boiling T
Melting T
K
kJ
kJ
Molar Vol
H298~H5
kJ
A -1.387E+04
B= 2.495E+00
34.036 J-bar'1
340.36 cm3
C -2.94E+05
7/30/92
366
Formula wt
MICROCLINE
KAlSi308 :
278.332

Temp.
CP
ST
(HT-H^ 98 )/T
T._ .t
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
Melting T
202.13
202.85
236.27
259.96
276.64
288.65
297.58
304.51
310.21
315.20
319.89
324.56
329.45
214.20
215.45
278.64
334.06
383.02
426.62
465.77
501.23
533.62
563.42
591.05
616.84
641.07
-(GT-H2> 93)/T
A fH
l.r 1
0.00
1.25
56.05
94.60
123.63
146.39
164.76
179.91
192.67
203.58
213.08
221.48
229.01
A fG
Log Kf
-3749.3
-3747.9
-3671.5
-3594.6
-3517.9
-3441.5
-3365.4
-3289.6
-3213.4
-3132.5
-3048.9
-2965.7
-2882.8
656.84
652.54
479.44
375.52
306.25
256.80
219.73
190.92
167.85
148.74
132.71
119.16
107.56
t-T. rti 1
214.20
214.20
222.59
239.46
259.39
280.22
301.01
321.32
340.95
359.84
377.97
395.37
412.06
-3974.6
-3974.7
-3978.8
-3978.7
-3977.4
-3975.3
-3972.8
-3970.2
-3978.0
-4054.0
-4049.7
-4045.3
-4040.7
Boiling T
kJ
kJ
Molar Vol.
H2*98~H6
A -4 .002E+03
10 .872 J-bar'1
cm3
108 .72
33. 99 kJ
B= 7.941E-01
C= 1.562E+06
7/30/92
Formula wt
SANIDINE
KAlSi3O8 :
367
278.332

Temp.
cp
ST
(HT-H$ 98 )/T
-(GT-H2 98 )/T
Melting T
204.55
205.29
238.98
262.28
278.65
290.48
299.30
306.15
311.72
316.51
320.85
325.03
329.24
232.80
234.07
298.03
354.02
403.37
447.26
486.65
522.32
554.87
584.81
612.54
638.39
662.63
0.00
1.26
56.74
95.66
124.87
147.73
166.15
181.34
194.11
205.02
214.49
222.84
230.29
Log Kf
-3745.8
-3744.4
-3670.0
-3595.1
-3520.4
-3446.0
-3372.0
-3298.3
-3224.2
-3145.4
-3064.0
-2982.9
-2902.2
656.23
651.95
479.24
375.57
306.47
257.14
220.16
191.42
168.41
149.36
133.37
119.85
108.28
UT
J-mol" 1 ^" 1 -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
A fG
A fH
232.80
232.80
241.30
258.36
278.50
299.54
320.51
340.98
360.76
379.79
398.04
415.55
432.34
-3965.6
-3965.6
-3969.5
-3969.2
-3967.7
-3965.4
-3962.7
-3959.9
-3967.6
-4043.4
-4039.0
-4034.5
-4029.9
Boiling T
1473 K
A^ 0
K
kJ
kJ
Molar Vol.
H298~H5
34.02 kJ
A -3.991E+03
B 7.728E-01
10.905 J-bar'1
109.05 cm3
C 1.497E+06
5/12/93
368
Formula wt
KAlSi3O8-GLASS
KAlSi308 :
278.332
Glass 298.15 to 1300 K.
Temp.
cp
ST
Melting T
-<GT-H2 98 )/'I
209.41
210.18
244.32
267.66
283.99
295.65
304.11
310.30
314.88
318.26
320.78
322.67
261.60
262.90
328.36
385.54
435.87
480.57
520.63
556.83
589.77
619.95
647.75
673.51
0.00
1.29
58.06
97.79
127.54
150.77
169.43
184.76
197.55
208.38
217.65
225.66
A fG
Log Kf
-3709.6
649.89
645.65
474.90
372.42
304.13
255.38
218.84
190.45
167.72
148.89
133.09
119.74
A fH
kJ*mol -1
-1-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
(HT-H$ 98 )/T
261.60
261.60
270.30
287.75
308.33
329.81
351.20
372.07
392.22
411.57
430.11
447.85
-3920.8
-3920.8
-3924.2
-3923.3
-3921.3
-3918.5
-3915.3
-3912.0
-3919.3
-3994.9
-3990.4
-3986.0
-3708.3
-3636.8
-3565.0
-3493.5
-3422.4
-3351.7
-3281.5
-3210.9
-3135.6
-3057.7
-2980.1
Boiling T
K
kJ
kJ
Molar Vol.
H298"H5
34 .88 kJ
A -3.937E+03
B= 7.307E-01
11. 650 J-bar'1

116. 50 cm3
C= 9.138E+05
9/16/92
Formula wt
KALIOPHILLITE (KALSILITE)
KAlSi04 :
369
158.163
High kaliophillite 810 to 1800 K.

Temp.
cp
ST
(H*-HJ 98 )/T
_1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
119.70
120.07
137.03
150.35
161.63
171.63
180.76
177.65
177.65
177.65
177.65
177.65
177.65
177.65
177.65
177.65
177.65
133.26
134.00
170.98
203.04
231.47
257.15
280.68
303.87
322.58
339.52
354.97
369.19
382.36
394.61
406.08
416.85
427.00
0.00
0.74
32.79
55.02
71.87
85.42
96.77
106.26
113.39
119.23
124.10
128.22
131.75
134.81
137.49
139.85
141.95
-(G*-H298)/.T
AfG
Log Kf
-2008.8
-2008.1
-1968.6
-1928.8
-1889.1
-1849.7
-1810.5
-1773.3
-1734.2
-1690.3
-1643.6
-1597.2
-1550.9
-1504.8
-1458.9
-1412.6
-1364.0
351.92
349.62
257.06
201.49
164.46
138.02
118.21
102.92
90.59
80.27
71.54
64.17
57.87
52.40
47.63
43.40
39.58
A fH
-1
_1
133.26
133.26
138.19
148.02
159.61
171.74
183.90
197.61
209.19
220.29
230.87
240.97
250.61
259.80
268.59
277.00
285.05
-2124.7
-2124.7
-2127.9
-2127.6
-2126.5
-2124.6
-2122.1
-2119.4
-2128.1
-2205.2
-2202.5
-2199.9
-2197.4
-2195.0
-2192.7
-2240.7
-2238.3
Boiling T
A,.^ 0
Afa.H0
kJ
kJ
Molar Vol.
H298""H5
kJ
AS -2.170B+03
B= 4.426E-01
5 .959 J-bar'1
59 .89 cm3
C 2.954E+06
1/12/94
370
Formula wt
LEUCITE
KAlSi2O6 :
218.247
Tetragonal crystals 298.15 to 955 K. Cubic crystals 955 to melting point 1959 K.

Temp.
cp
**
<HT-H$ 98 )/T
-<GT-H2 98 )/T
A fH
Melting T
164.11
164.65
188.61
206.91
222.99
238.01
252.48
266.62
236.40
237.04
238.18
239.69
241.46
243.42
245.53
247.74
250.05
200.20
201.22
252.08
296.20
335.36
370.87
403.61
434.16
462.95
484.04
504.71
523.83
541.66
558.39
574.16
589.11
603.34
0.00
1.01
45.11
75.69
98.92
117.73
133.67
147.66
160.23
165.82
171.80
176.96
181.51
185.57
189.25
192.62
195.75
Log Kf
-2875.1
-2874.0
-2818.8
-2763.2
-2707.8
-2652.8
-2598.1
-2544.0
-2489.6
-2430.5
-2368.6
-2306.9
-2245.4
-2184.0
-2122.8
-2060.8
-1994.0
503.69
500.40
368.09
288.67
235.73
197.95
169.63
147.64
130.04
115.41
103.10
92.69
83.77
76.05
69.30
63.32
57.86
i-l
J-mol"1 -*"1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
A fG
200.20
200.20
206.98
220.50
236.44
253.15
269.93
286.50
302.72
318.22
332.91
346.87
360.15
372.82
384.91
396.49
407.59
-3037.8
-3037.8
-3041.2
-3040.9
-3039.4
-3036.8
-3033.3
-3028.8
-3034.0
-3112.9
-3110.4
-3108.0
-3105.6
-3103.2
-3100.8
-3198.6
-3195.6
Boiling T
1959 K
A^H
AfajH0
kJ
kJ
Molar Vol.
H298~H5
kJ
A= -3.082E+03
B= 5.979E-01
8. 827 J-bar'1
88. 27 cm3
C= 2.833E+06
1/12/94
Formula wt
EOCRYPTITE
L1A1S104 :
371
126.006
a-eucryptite 298.15 to 1300 K. 0-eucryptite 1300 to 1600 K.

Temp.
CP
ST
(HT-H2 98 )/T
/ f* o v fi
\ /f
A w
A ^f*
Log Kf
-2009.2
-2008.5
-1970.1
-1931.4
-1892.4
-1853.7
-1815.2
-1777.0
-1738.3
-1699.4
-1660.7
-1622.3
-1584.2
-1546.2
-1508.4
352.00
349.70
257.26
201.76
164.75
138.32
118.52
103.13
90.80
80.70
72.29
65.18
59.10
53.84
49.24
kJ-mol"1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
Melting T
113.30
113.85
136.04
149.80
159.40
166.58
172.22
176.81
180.63
183.88
186.69
189.16
191.34
193.29
195.05
103.80
104.50
140.59
172.53
200.73
225.87
248.49
269.05
287.88
305.26
321.38
336.42
350.52
363.79
376.32
0.00
0.70
32.02
54.29
71.05
84.21
94.87
103.73
111.23
117.69
123.33
128.30
132.73
136.70
140.29
103.80
103.80
108.57
118.24
129.68
141.66
153.62
165.32
176.65
187.56
198.05
208.12
217.80
227.09
236.03
-2123.3
-2123.3
-2123.9
-2126.5
-2125.4
-2123.9
-2122.0
-2119.9
-2128.4
-2125.9
-2123.2
-2120.3
-2117.4
-2114.3
-2111.1
Boiling T
1670 K
kJ
AftH0
kJ
Molar Vol.
H298"H5
kJ
A= -2.123E+03
B= 3.846E-01
5 .363 J-bar'1
53 .63 cm3
C -1.10E+05
9/16/92
372
Formula wt
PETALITE
LiAlSi4O10 :
306.259
Monoclinic crystals 298.15 to 1300 K. Petalite decomposes above about 1100 K,

Temp.
CP
ST
(HT-H298 )/T
-(Gf-H2 98 )/T
Jinol~ *K~
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
245.30
246.32
292.33
323.66
345.43
360.93
372.26
380.77
387.40
392.77
397.36
401.52
233.20
234.72
312.31
381.13
442.18
496.65
545.63
589.99
630.46
667.64
702.02
733.99
0.00
1.52
68.84
116.87
153.25
181.87
205.00
224.08
240.09
253.73
265.52
275.82
1- T
233.20
233.20
243.47
264.26
288.92
314.78
340.63
365.91
390.37
413.91
436.50
458.17
Melting T
A fG
Log Kf
-4610.7
-4608.9
-4516.1
-4422.9
-4329.8
-4237.1
-4144.9
-4053.3
-3961.5
-3869.7
-3778.3
-3687.4
807.75
802.47
589.73
462.05
376.93
316.17
270.63
235.24
206.92
183.75
164.46
148.16
A fH
-4886.5
-4886.6
-4887.9
-4889.9
-4887.5
-4884.0
-4879.9
-4875.5
-4881.6
-4876.8
-4871.9
-4866.9
mol'1
Boiling T
K
kJ
kJ
Molar Vol.
38.31 kJ
A -4.879E+03
B= 9.174E-01
12.840
128.40
J-bar'1
cm3
C -5.17E+05
8/7/92
Formula wt
ALBITE
NaAlSi308 :
373
262.223
Triclinic crystals 298.15 to 1400 K,
Temp.
CP
**
Melting T
_ \ /*P
vQft* /
-<G*-H298 ,/'T
205.07
205.84
239.68
262.58
278.77
290.66
299.66
306.68
312.30
316.95
320.92
324.41
327.61
207.40
208.67
272.86
328.96
378.34
422.25
461.68
497.39
530.01
560.00
587.75
613.58
637.74
0.00
1.27
56.93
95.91
125.11
147.95
166.38
181.59
194.39
205.33
214.80
223.10
230.45
kJ- mnl
207.40
207.40
215.93
233.05
253.23
274.30
295.30
315.80
335.61
354.67
372.95
390.48
407.28
A fG
Log Kf
-3711.6
-3710.2
-3634.8
-3558.7
-3482.9
-3407.4
-3332.2
-3257.4
-3182.2
-3107.0
-3029.6
-2946.7
-2864.2
650.24
645.98
474.64
371.77
303.20
254.26
217.57
189.05
166.22
147.53
131.87
118.40
106.86
A fH
J-mol"1 ^"1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
/llO_UQ
\ V
-3935.0
-3935.0
-3939.0
-3938.6
-3937.1
-3934.7
-3931.9
-3929.0
-3936.5
-3933.1
-4026.3
-4021.9
-4017.4
Boiling T
kJ
kJ
Molar Vol
H298~H5
33.45 kJ
A= -3.949E+03
B* 7.694E-01
10.007 J-bar'1
100.07 cm3
C 7.970E+05
8/7/92
374
Formula wt
ANALBITE
NaAlSi308 :
262.223

Temp.
cp
ST
(Hf-H$98 )/T
-(Gf-H$98 )/T
Melting T
204.81
205.57
239.71
263.29
279.83
291.73
300.49
307.13
312.30
316.50
320.06
323.25
326.24
225.60
226.87
290.99
347.17
396.72
440.80
480.35
516.15
548.78
578.75
606.45
632.19
656.26
0.00
1.27
56.87
95.94
125.29
148.26
166.77
182.01
194.79
205.67
215.06
223.26
230.51
Log Kf
kJ*mol -1 ___
Jmol~*K""* -
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
AfG
A fH
225.60
225.60
234.11
251.23
271.43
292.54
313.58
334.13
353.99
373.08
391.39
408.93
425.75
-3923.6
-3923.6
-3927.6
-3927.2
-3925.5
-3923.1
-3920.2
-3917.2
-3924.7
-3921.3
-4014.6
-4010.3
-4005.9
649.19
644.95
474.10
371.53
303.16
254.36
217.78
189.35
166.58
147.95
132.34
118.90
107.40
-3705.6
-3704.2
-3630.6
-3556.4
-3482.4
-3408.7
-3335.4
-3262.5
-3189.2
-3115.8
-3040.3
-2959.3
-2878.6
Boiling T
1391 K
A^"
A^H"
kJ
Molar Vol.
H298"H5
kJ
33.42 kJ
A -3. 937E+03
10 .043 J-bar'1
cm3
100 .43
B= 7.507E-01
C 7.781E+05
8/7/92
Formula wt
NaAlSi 3O8-GLASS
NaAlSi 3O8 :
375
262.223
Glass 298.15 to 1200 K,
Temp.
CO
ST
CP
-<GT-H2 98 )/T
209.90
210.68
246.12
270.03
286.40
298.28
307.73
316.09
324.30
333.04
342.78
251.90
253.20
318.98
376.65
427.42
472.50
512.96
549.70
583.42
614.74
644.12
0.00
1.30
58.35
98.45
128.49
151.94
170.84
186.52
199.89
211.59
222.11
A fG
Log Kf
-3665.3
-3664.0
-3593.1
-3521.8
-3450.8
-3380.3
-3310.2
-3240.6
-3170.7
-3100.8
-3029.0
642 . 14
637.95
469.21
367.91
300.41
252.23
216.13
188.07
165.61
147.24
131.84
A fH
-1-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
<Hf-H298 )/T
kJ mol" 1
251.90
251.90
260.63
278.19
298.92
320.56
342.12
363.18
383.54
403.15
422.02
Melting T
-3875.5
-3875.5
-3878.9
-3877.8
-3875.5
-3872.4
-3868.9
-3865.0
-3871.5
-3866.7
-3958.1
Boiling T
K
kJ
kJ
Molar Vol
H298~H5
34.17 kJ
A* -3.871E+03
B 7.012E-01
11.010 Jbar'1
110.10 can3
O -3.14E+05
12/9/92
376
Formula wt
NEPHELINE
NaAlSiO4 :
142.054
Orthorhombic(?) crystals 298.15 to 467 K. Hexagonal crystals 467 to 1180 K,

Orthorhombic crystals 1180 to 1521 K. Carnegieite is the stable phase of
NaAlSi04 between 1521 and 1799 K.
Temp.
sT
-<GT-H2 98 )/T
A fH
115.81
116.36
145.90
145.64
152.36
159.07
165.78
172.49
179.20
185.91
178.62
179.18
179.73
180.28
Melting T
124.35
125.12
161.59
196.36
223.80
247.82
269.33
288.91
306.86
324.09
341.12
355.47
368.78
381.20
0.00
0.72
32.37
52.55
72.66
84.58
94.14
102.13
108.99
115.51
122.21
126.58
130.36
133.66
A fG
Log Kf
-1975.8
-1975.0
-1936.3
-1899.3
-1858.0
-1819.0
-1780.3
-1741.6
-1702.4
-1662.9
-1621.3
-1574.1
-1527.2
-1480.4
346.14
343.88
252.84
198.41
161.75
135.73
116.24
101.08
88.92
78.96
70.57
63.25
56.98
51.55
-1
J-mol^-K'1
K
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
(HT-H2 98 )/T
124.35
124.40
129.22
143.81
151.14
163.24
175.19
186.77
197.86
208.58
218.92
228.89
238.42
247.54
-2090.4
-2090.4
-2093.5
-2094.7
-2091.8
-2091.0
-2089.9
-2088.7
-2098.0
-2095.7
-2188.8
-2186.0
-2183.4
-2180.7
Boiling T
kJ
kJ
Molar Vol.
kJ
H298"H5
-2.118E+03
"- 4.188E-01
5 .419 J-bar'1
54 . 19 cm3
0 1.718E+06
8/7/92
Formula wt
CARNEGIEITE
NaAlSi04 :
377
142.054
Triclinic crystals 298.15 to 966 K; cubic crystals 966 to melting point 1799 K.
Temp.
p
CP
eo
ST
<HT-H, 98 )/T
_1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
Melting T
119.26
119.69
138.01
151.11
162.14
172.21
181.77
191.02
181.15
184.03
186.92
189.80
192.68
195.57
198.45
201.33
204.21
118.70
119.44
156.58
188.84
217.39
243.15
266.77
288.71
317.40
334.80
350.94
366.01
380.18
393.57
406.29
418.40
429.99
0.00
0.74
32.94
55.31
72.22
85.79
97.19
107.11
123.78
129.13
133.82
138.02
141.82
145.31
148.54
151.56
154.40
-<GT-H, 98 )/T
_1
i.
118.70
118.70
123.64
133.53
145.17
157.36
169.58
181.60
193.62
205.67
217.12
227.99
238.36
248.26
257.75
266.84
275.59
A fG
Log Kf
-1973.0
-1972.2
-1932.9
-1893.0
-1853.3
-1813.8
-1774.7
-1735.9
-1697.0
-1658.6
-1618.1
-1571.9
-1526.0
-1480.4
-1435.1
-1389.6
-1341.9
345.65
343.39
252.41
197.76
161.34
135.35
115.87
100.75
88.64
78.76
70.43
63.16
56.94
51.55
46.85
42.70
38.94
A H
-2089.3
-2089.3
-2092.5
-2092.2
-2091.0
-2089.0
-2086.4
-2083.1
-2082.1
-2079.6
-2173.7
-2170.0
-2166.2
-2162.1
-2157.9
-2203.7
-2198.8
Boiling T
1799 K
Av, HO
Afc.H0
kJ
21.7 kJ
Molar Vol.
H298"H5
19.45 kJ
A= -2. 122E+03
B- 4.276E-01
5. 603 J-bar*1
56. 03 cm3
0 2. 200E+06
1/12/94
378
Formula wt
NaAlSi04-GLASS
142.054
NaAlSiO4 : Glass-liquid 298.15 to glass transition 1000 K.

Temp.
ST
CP
(HT-H2 98 )/T
-(GT-H$98 )/T
121.03
121.47
140.22
152.09
159.90
165.10
168.50
170.60
171.73
134.50
135.25
172.98
205.64
234.11
259.17
281.46
301.44
319.48
0.00
0.75
33.46
56.09
72.78
85.62
95.79
103.99
110.72
Log Kf
-1977.4
-1976.7
-1939.0
-1900.7
-1862.7
-1824.9
-1787.2
-1749.8
-1711.9
346.42
344.17
253.20
198.56
162.16
136.17
116.69
101.56
89.42
kJ .mol"" 1
J-mol^'K' 1
298.15
300
400
500
600
700
800
900
1000
A fG
AfH
134.50
134.50
139.52
149.55
161.33
173.55
185.67
197.45
208.76
Melting T
-2089.0
-2089.0
-2092.0
-2091.5
-2090.3
-2088.8
-2087.2
-2085.7
-2094.9
Boiling T
kJ
kJ
Molar Vol
H298~H5
19.99 kJ
A= -2.089E+03
B= 3.771E-01
5.686 J'bar'1
56.86 cm3
C= -9.27E+04
9/16/92
Formula wt
ANALCIME
NaAlSi2O6 *H2O:
379
220.154
Cubic crystals 298.15 to 800 K. Analcime starts to lose H2O above 500 K,
Temp.
CP
ST
<HT-H2 98 )/T
T-.-.~I
298.15
300
400
500
600
700
800
Melting T
212.23
212.68
237.19
262.19
287.38
312.66
337.99
227.70
229.01
293.54
349.14
399.17
445.37
488.77
-<GT-H2 98 )/T
l_r 1
0.00
1.31
57.20
95.69
125.54
150.47
172.32
1. T-
227.70
227.70
236.34
253.45
273.63
294.90
316.45
AfG
Log Kf
-3090.0
-3088.6
-3014.4
-2939.8
-2865.5
-2792.0
-2719.2
541.33
537.76
393.63
307.11
249.46
208.33
177.54
A fH
-3310.1
-3310.1
-3313.3
-3312.2
-3309.3
-3304.3
-3297.3
Boiling T
K
kJ
kJ
Molar Vol
H298~H5
35.74 kJ
A= -3.306E+03
B 7.344E-01
9.680 J-bar'1
96.80 cm3
C= -2.83E+05
5/12/93
380
Formula wt
DEHYDRATED ANALCIME
NaAlSi206 :
202.139
Temp.
cp
ST
<HT-H2 98 )/T
-<G*-HS98)/.I
163.05
163.85
194.89
213.59
227.43
238.99
249.32
258.94
268.12
172.50
173.51
225.37
271.00
311.21
347.16
379.76
409 . 68
437.44
0.00
1.01
46.01
77.77
101.60
120.42
135.90
149.04
160.49
Log K
-2816.0
-2815.0
-2758.6
-2701.8
-2645.3
-2589.2
-2533.5
-2478.3
-2422.9
493.35
490.12
360.23
282.25
230.29
193.20
165.42
143.84
126.56
kJT- mr,l~l
UIUX
J-mol'^K" 1 -
298.15
300
400
500
600
700
800
900
1000
A 6
A fH
172.50
172.50
179.36
193.23
209.61
226.74
243.86
260.64
276.95
Melting T
-2983.1
-2983.1
-2986.3
-2985.3
-2983.2
-2980.3
-2976.8
-2972.8
-2978.8
Boiling T
kJ
kJ
Molar Vol
H298~H6
27.18 kJ
A= -2.978E+03
B= 5.560E-01
J-bar'1
cm3
C= -3.36E+05
5/12/93
Formula wt
DICKITE
Al2 Si2O5 (OH) 2 :
381
258.160
Triclinic crystals 298.15 to 900 K
Temp,
ST
J-mol"1 -^ 1
K
298.15
300
400
500
600
700
800
900
A H
239.56
240.64
287.65
317.09
334.95
344.93
349.32
349.59
197.10
198.59
274.77
342.38
401.91
454.38
500.78
541.97
0.00
1.48
67.60
114.78
150.12
177.32
198.59
215.39
kJ*mol
197.10
197.10
207.17
227.59
251.79
277.06
302 . 19
326.58
-4118.5
-4118.6
-4120.4
-4119.5
-4117.2
-4114.4
-4111.7
-4109.5
A fG
Log K
-3796.0
-3794.0
-3685.5
-3576.8
-3468.5
-3360.6
-3253.1
-3145.9
665.04
660.58
481.26
373.66
301.95
250.76
212.40
182.58
"1
Boiling T
Melting T
kJ
kJ
Molar Vol
H298~H5
kJ
-4.113E+03
B= 1.075E+00
9.856 J-bar1
98.56 cm3
C= -3.31E+05
7/29/92
382
Formula wt
KAOLINITE
Al2 Si205 (OH) 2 :
258.160
Triclinic crystals 298.15 to 800 K
Temp.
CP
s*
/tIO_tlQ
\ /m
(HT-H29Q)/T
_/Ô_uQ
\ / !
-(GT-H29g)/T
Log Kf
-3797.5
-3795.5
-3687.3
-3579.1
-3471.1
-3363.7
-3256.6
665.29
660.84
481.50
373.89
302.18
251.00
212.63
kJ-mol' 1
K
298.15
300
400
500
600
700
800
A 6
A H
243.37
244.40
289.53
317.00
333.50
344.03
351.92
200.40
201.91
278.90
346.72
406.10
458.35
504.82
0.00
1.50
68.31
115.53
150.60
177.53
198.85
200.40
200.40
210.59
231.19
255.50
280.82
305.97
Melting T
-4119.0
-4119.1
-4120.6
-4119.6
-4117.3
-4114.5
-4111.6
Boiling T
kJ
A..H0
kJ
Molar Vol.
H298"H5
35.75
kJ
A= -4.115E+03
B= 1.074E+00
9.934 J'bar'1
99.34 cm3
C= -2.43E+05
7/29/92
Formula wt
PYROPHYLLITE
Al2 Si4010 (OH) 2 :
383
360.314
Monoclinic crystals 298.15 to 800 K
Temp.
Melting T
A fH
293.76
295.04
349.70
386.14
412.51
432.69
448.83
239.40
241.22
334.18
416.37
489.22
554.39
613.25
0.00
1.82
82.47
139.78
183.14
217.41
245.36
AfG
Log Kf
-5266.1
-5263.8
-5138.0
-5012.1
-4886.7
-4761.9
-4637.8
922.58
916.49
670.94
523.60
425.42
355.33
302.81
kJ*mol -1
J-mol'^K""1
K
298.15
300
400
500
600
700
800
<Gf-H 98 )/T
Sf
239.40
239.41
251.71
276.59
306.08
336.98
367.89
-5640.0
-5640.1
-5641.8
-5640.6
-5637.5
-5633.1
-5628.0
Boiling T
K
kJ
kJ
Molar Vol
H298"H5
42.70 kJ
A= -5.634E+03
B= 1.246E+00
12.81 J-bar'1
128.1 cm3
O -3.54E+05
7/29/92
384
Formula wt
MARGARITE
CaAl2 [Al2 Si2 ]010 (OH) 2 :
398.184
Monoclinic crystals 298.15 to 1200 K

Temp.
CP
ST
***p *** 5 Q ft / /
w*moX
298.15
300
400
500
600
700
800
900
1000
1100
1200
323.41
324.82
384.97
424.42
452.21
472.69
488.23
500.23
509.60
516.96
522.74
263.60
265.60
367.96
458.38
538.35
609.68
673.86
732.08
785.29
834.22
879.46
*K
0.00
2.00
90.81
153.83
201.37
238.74
269.00
294.05
315.16
333.18
348.75
-<GT-H2 98 )/T
A fG
Log Kf
-5858.9
-5856.5
-5726.9
-5597.2
-5468.1
-5339.6
-5211.6
-5084.3
-4954.5
-4823.6
-4692.5
1026.43
1019.68
747.84
584.73
476.03
398.44
340.28
295.08
258.79
229.05
204.26
A H
kJ mol" 1
263.60
263.61
277.15
304.55
336.98
370.94
404.86
438.03
470.14
501.04
530.71
Melting T
-6244.0
-6244.1
-6245.9
-6244.5
-6241.1
-6236.7
-6232.8
-6228.0
-6265.9
-6260.8
-6263.4
Boiling T
A^ 0
K
kJ
kJ
Molar Vol.
H298~H8
48.14
kJ
A- -6.243E+03
B= 1.291E+00
12.963 J-bar"1
129.63 cm3
C= 6.216B+02
7/29/92
Formula wt
PREHNITE
Ca2Al[AlSi3010 ](OH) 2 :
385
412.384
Orthorhombic crystals 298.15 to 1200 K
Temp.
ST
-<GT-H2 98 )/T
331.12
332.41
389.19
427.23
453.51
471.95
484.90
493.85
499.76
503.31
505.00
292.80
294.85
398.83
490.03
570.39
641.76
705.68
763.34
815.71
863.52
907.40
0.00
2.05
92.23
155.67
203.25
240.39
270.20
294.58
314.83
331.82
346.19
A fG
Log Kf
-5824.7
-5822.3
-5695.3
-5568.3
-5442.0
-5316.4
-5191.2
-5066.5
-4940.9
-4814.8
-4687.7
1020.43
1013.73
743.71
581.71
473.76
396.70
338.94
294.05
258.08
228.63
204.05
AfH
,-!--!
298.15
300
400
500
600
700
800
900
1000
1100
1200
<H*-HJ98 ,/T
kJ mol' 1
292.80
292.81
306.60
334.36
367.14
401.37
435.48
468.76
500.88
531.71
561.21
-6202.6
-6202.7
-6203.7
-6201.7
-6198.0
-6193.4
-6190.4
-6185.9
-6203.2
-6199.7
-6212.4
Boiling T
Melting T
kJ
kJ
Molar Vol
H298~H8
50.66 kJ
A* -6.194E+03
B 1.255E+00
14.110 J'bar'1
141.10 can3
O -3.99E+05
5/14/92
386
MUSCOVITE (Al/Si disordered)
KAl2 [AlSi3010 ](OH) 2 :
Formula wt
398.308
Temp.
CP
ST
-(GT-H2* 98 )/T
325.99
327.30
385.47
425.61
454.37
475.51
491.31
503.20
512.13
306.40
308.42
411.09
501.68
581.96
653.67
718.24
776.83
830.33
0.00
2.01
91.08
154.21
201.96
239.61
270.13
295.40
316.64
1T
306.40
306.41
320.01
347.47
379.99
414.06
448.11
481.43
513.69
Melting T
AfG
Log Kf
-5598.8
-5596.4
-5469.5
-5342.2
-5215.4
-5089.5
-4964.2
-4839.8
-4713.9
980.86
974.40
714.22
558.08
454.03
379.77
324.12
280.89
246.22
A H
J-mol"1 -K~1 -
K
298.15
300
400
500
600
700
800
900
1000
(HT-H2 98 )/T
-5974.8
-5974.9
-5979.1
-5977.5
-5973.8
-5968.6
-5962.6
-5956.4
-5981.9
mol"1
Boiling T
kJ
kJ
Molar Vol
H598"H8
49.41 kJ
A* -5.966E+03
B= 1.253E+00
14.081 J-bar'1
140.81 cm3
-5.87E+05
7/15/92
MUSCOVITE (Al/Si ordered)

KAl2 [AlSi3010 ](OH) 2 :
Formula wt
387
398.308
Temp.
CP
ST
-(GT-H2 98 )/T
J-mol'^K" 1 -
298.15
300
400
500
600
700
800
900
1000
325.99
327.30
385.47
425.61
454.37
475.51
491.31
503.20
512.13
287.70
289.72
392.39
482.98
563.26
634.97
699.54
758.13
811.63
0.00
2.01
91.08
154.21
201.96
239.61
270.13
295.40
316.64
A fG
Log Kf
-5608.4
-5606.0
-5477.2
-5348.0
-5219.4
-5091.6
-4964.5
-4838.2
-4710.4
982.55
976.07
715.23
558.69
454.38
379.93
324.14
280.79
246.04
A H
IT . _>
287.70
287.71
301.31
328.77
361.29
395.36
429.41
462.73
494.99
Melting T
-5990.0
-5990.1
-5994.3
-5992.7
-5989.0
-5983.8
-5977.8
-5971.6
-5997.1
Boiling T
kJ
kJ
Molar Vol.
H2*98~H8
49.41 kJ
A* -5.981E+03
B 1.271E+00
14.081 J'bar'1
140.81 cm3
O -5.87E+05
3/5/93
388
Formula wt
ANNITE
KFe3 [AlSi3010 ](OH) 2 :
511.886
Crystals 298.15 to 1000 K

Temp.
CP
ST
(H$-H5 98 ,/T
_1
298.15
300
400
500
600
700
800
900
1000
390.32
391.81
452.51
491.34
520.03
543.12
562.76
580.11
595.84
415.00
417.42
539.23
644.64
736.87
818.82
892.65
959.96
1021.90
0.00
2.41
108.03
181.04
235.25
277.63
312.07
340.91
365.63
-<G*-HJ 98 ,/-r
A fG
Log Kf
-4798.3
-4796.1
-4678.2
-4560.7
-4444.5
-4329.5
-4215.6
-4102.6
-3989.8
840.62
835.06
610.89
476.45
386.92
323.06
275.24
238.10
208.40
AfH
k,J-mol" 1
415.00
415.01
431.20
463.60
501.62
541.19
580.58
619.05
656.28
Melting T
-5149.3
-5149.3
-5149.7
-5144.8
-5138.3
-5130.7
-5122.7
-5114.9
-5119.0
Boiling T
K
kJ
kJ
Molar Vol
H298"H8
kJ
A* -5.122E+03
B 1.135E+00
15.43 J-bar*1
154.3 cm3
O -1.31E+06
7/29/92
PHLOGOPITE (Al/Si Disordered)
KMg3 [AlSi3010 ](OH) 2 :
Formula wt
389
417.260
Crystals 298.15 to 1000 K
Temp.
CP
ST
-<GT-H2 98 )/T
354.65
355.97
412.17
448.48
473.45
491.23
504.13
513.53
520.33
334.60
336.80
447.54
543.69
627.79
702.19
768.67
828.62
883.10
0.00
2.19
98.22
164.88
214.35
252.70
283.37
308.45
329.31
A fG
Log Kf
-5846.0
-5843.7
-5715.4
-5586.8
-5458.7
-5331.2
-5204.2
-5077.8
-4949.0
1024.18
1017.45
746.74
583.64
475.21
397.81
339.79
294.70
258.50
kJ*mol'' 1
J-mol" 1 ^" 1
K
298.15
300
400
500
600
700
800
900
1000
A H
334.60
334.61
349.32
378.80
413.44
449.48
485.30
520.17
553.78
Melting T
-6226.0
-6226.1
-6230.1
-6228.8
-6225.8
-6221.8
-6217.4
-6213.1
-6245.5
Boiling T
A^pH0
K
kJ
kJ
Molar Vol.
H2*98~
54.08 kJ
A= -6.222E+03
B 1.273E+00
14.965 J'bar'1
149.65 cm3
O -3.45E+05
7/29/92
390
Formula wt
PHLOGOPITB (Al/Si ordered)
KMg3 [AlSi3010 ](OH) 2 :
417.260

Temp.
CP
ST
Melting T
-(GT-H2 98 )/T
354.65
355.97
412.17
448.48
473.45
491.23
504.13
513.53
520.33
315.90
318.10
428.84
524.99
609.09
683.49
749.97
809.92
814.40
0.00
2.19
98.22
164.88
214.35
252.70
283.37
308.45
329.31
1> T
315.90
315.91
330.62
360.10
394.74
430.78
466.60
501.47
535.08
AfG
Log Kf
-5860.5
-5858.1
-5727.9
-5597.5
-5467.5
-5338.1
-5209.2
-5081.0
-4950.3
1026.71
1019.96
747.97
584.75
475.97
398.32
340.12
294.89
258.57
AfH
J-mol"1 -^ 1 -
K
298.15
300
400
500
600
700
800
900
1000
(Hf-H298 )/T
6246.0
-6246.1
-6250.1
-6248.8
-6245.8
-6241.8
-6237.4
-6233.1
-6265.5
mol'1
Boiling T
K
kJ
kJ
Molar Vol
H298~H8
kJ
A* -6.242E+03
B= 1.291E+00
O -3.45E+05
14.962 J'bar'1
149.62 cm3
FLUORPHLOGOPITE (Al/Si disordered)
KMg3 [AlSi3O10 ]F2 :
Formula wt
391
421.242
Approximate melting point 1670 K,

Temp.
ST
CP
(HT-H2 98 )/T
-(GT-H 98 )/T
Melting T
342.42
343.70
392.83
420.87
439.96
454.48
466.38
476.62
485.76
494.13
501.92
509.29
516.32
523.09
529.64
536.01
336.30
338.42
444.81
535.72
614.23
683.18
744.67
800.21
850.90
897.60
940.93
981.40
1019.40
1055.26
1089.23
1121.53
1670
0.00
2.12
94.33
157.05
202.69
237.66
265.53
288.43
307.71
324.28
338.77
351.60
363.12
373.56
383.11
391.92
Log Kf
-6015.7
-6013.6
-5899.0
-5784.3
-5670.0
-5556.2
-5442.8
-5329.8
-5214.4
-5093.6
-4970.2
-4847.1
-4715.2
-4565.1
-4415.6
-4265.5
1053.90
1047.04
770.31
604.26
493.60
414.60
355.37
309.33
272.37
241.87
216.34
194.76
175.92
158.97
144.15
131.06
-1
J-mol" 1 -*" 1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
A 6
A fH
336.30
336.31
350.48
378.67
411.54
445.52
479.14
511.78
543.19
573.32
602.17
629.80
656.28
681.70
706.12
729.61
-6355.5
-6355.5
-6358.5
-6356.9
-6354.4
-6351.3
-6347.9
-6344.6
-6377.8
-6453.5
-6448.8
-6443.7
-6820.5
-6810.5
-6800.2
-6940.0
Boiling
A^H
Aft^H0
Molar Vol.
H2*98~H8
kJ
kJ
A= -6.476E+03
14. 652 J-bar'1

cm3
146. 52
kJ
B= 1.272E+00
c-
8.177E+06
01/14/93
392
Formula wt
FLUORPHLOGOPITE (Al/Si ordered)
KMg3 [AlSi3O10 ]F2 :
421.242
Approximate melting point 1670 K.

Temp.
CP
SJ
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
Melting T
A^H0
(Hf-H2 98 )/T
342.42
343.70
392.83
420.87
439.96
454.48
466.38
476.62
485.76
494.13
501.92
509.29
516.32
523.09
529.64
536.01
336.30
338.42
444.81
535.72
614.23
683.18
744.67
800.21
850.90
897.60
940.93
981.40
1019.40
1055.26
1089.23
1121.53
1670
-<G*-H598 )/-T
i-l. K-l
0.00
2.12
94.33
157.05
202.69
237.66
265.53
288.43
307.71
324.28
338.77
351.60
363.12
373.56
383.11
391.92
lr J-
336.30
336.31
350.48
378.67
411.54
445.52
479.14
511.78
543.19
573.32
602.17
629.80
656.28
681.70
706.12
729.61
AfG
Log Kf
-6030.1
-6028.0
-5911.5
-5794.9
-5678.7
-5563.1
-5447.8
-5333.0
-5215.7
-5093.0
-4967.7
-4842.8
-4709.0
-4557.0
-4405.7
-4253.7
1056.43
1049.54
771.95
605.38
494.37
415.11
355.70
309.51
272.43
241.84
216.23
194.58
175.69
158.69
143.83
130.70
AfH
-6375.5
-6375.5
-6378.5
-6376.9
-6374.4
-6371.3
-6367.9
-6364.6
-6397.8
-6473.5
-6468.8
-6463.7
-6840.5
-6830.5
-6820.2
-6960.0
1~1
Boiling
A -p"0
K
kJ
kJ
Molar Vol.
H298~H8
kJ
A= -6.496E+03
B- 1.2 9 IE +00
14. 652 J-bar'1

146. 52 cm3
O 8 .177E+06
01/14/93
THERMODYNAMIC PROPERTIES AT HIGH TEMPERATURE OF INfDIVIDUAL PHASES
Formula wt
TALC
Mg3Si4O10 (OH) 2 :
393
379.266
Temp.
s*
\**T **298 \' /fn
_//Ô_tiO
l**T "298 \' /m
AH
321.77
323.23
386.65
420.68
444.28
475.19
525.90
260.80
262.79
365.29
455.61
534.40
605.03
671.51
0.00
1.99
90.94
153.83
200.28
237.17
269.84
Af6
Log Kf
-5520.1
-5517.8
-5390.1
-5262.5
-5135.5
-5009.3
-4883.9
967.08
960.71
703.85
549.76
447.08
373.79
318.88
kJ-mol"1
- J-mol" 1 ^' 1
K
298.15
300
400
500
600
700
800
/UO_UO
260.80
260.81
274.35
301.78
334.12
367.85
401.68
Melting T
-5900.0
-5900.1
-5901.1
-5899.0
-5895.5
-5890.5
-5882.6
Boiling T
K
kJ
kJ
Molar Vol
H298~H8
46.88 kJ
A* -5.890B+03
B 1.260E+00
13.625 J'bar'1
136.25 cm3
O -4.84E+05
7/29/92
394
Formula wt
CHRYSOTILE (Antigorite)
Mg3Si2O5(OH) 4 :
277.112
Temp,
-<GT-H298 )/T
J-mol"1 ^' 1
K
298.15
300
400
500
600
700
800
900
AfH
274.05
275.12
323.31
356.40
379.00
394.31
404.36
410.50
221.30
223.00
309.17
385.10
452.21
511.86
565.22
613.23
0.00
1.69
76.44
129.33
169.18
200.32
225.24
245.52
AfG
Log 1
kJ<
221.30
221.31
232.73
255.77
283.03
311.54
339.97
367.71
Melting T
-4360.0
-4360.1
-4361.0
-4359.1
-4355.4
-4350.8
-4345.7
-4340.7
-4032.4
-4030.3
-3920.2
-3810.1
-3700.7
-3591.9
-3483.8
-3376.4
Boiling T
706.44
701.73
511.91
398.03
322.16
268.03
227.47
195.96
K
kJ
kJ
Molar Vol
H298~H5
kJ
A= -4.348E+03
B* 1.08IE+00
10.75 J-bar'1
107.5 cm3
O -6.03E+05
5/14/92
PARAGONITE (Al/Si disordered)
NaAl2 [AlSi3010 ](OH) 2 :
Formula wt
395
382.200
Temp,
CP
J-mol"1 ^"1
K
298.15
300
400
500
600
700
800
Melting T
AH
ST
321.50
322.86
380.52
419.03
447.59
470.21
488.92
288.80
290.79
392.22
481.51
560.55
631.30
695.35
0.00
1.99
89.98
152.15
199.12
236.29
266.73
kJ*mol
288.80
288.81
302.24
329.36
361.43
395.02
428.62
-5933.0
-5933.1
-5937.9
-5936.9
-5933.8
-5929.2
-5923.5
A fG
Log K
-5555.7
-5553.3
-5426.1
-5298.2
-5170.7
-5043.9
-4917.8
973.31
966.90
708.56
553.49
450.14
376.37
321.09
"1
Boiling T
A^
K
kJ
kJ
Molar Vol.
H298~H6
48.12 kJ
A* -5.931E+03
B- 1.268E+00
13.211 J-bar'1
132.11 cm3
C- -2.33E+05
5/14/92
396
PARAGONITB (Al/Si ordered)
NaAl2 [AlSi3010 ](OH) 2 :
Formula wt
382.200
Temp.
CP
Sf
-(GT-H2 98 )/T
321.50
322.87
380.52
419.04
447.60
470.21
488.92
277.10
279.09
380.52
469.81
548.85
619.61
683.65
0.00
1.99
89.98
152.16
199.12
236.29
266.73
A fG
Log Kf
-5568.5
-5566.1
-5437.7
-5308.7
-5180.0
-5052.0
-4924.8
975.55
969.12
710.08
554.58
450.95
376.98
321.55
A H
kJ mol'1
J-rool" 1 ^" 1 -
K
298.15
300
400
500
600
700
800
<HT-H298 )/T
277.10
277.11
290.54
317.66
349.73
383.32
416.92
Melting T
-5949.3
-5949.4
-5954.2
-5953.2
-5950.1
-5945.5
-5939.8
Boiling T
K
kJ
kJ
Molar Vol
48.12 kJ
A- -5.947E+03
B- 1.279E+00
13.211 J-bar'1
132.11 cm3
C- -2.34E+05
12/9/92
REFERENCES CITED
397
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Stubbles, J. R., and Birchenall, C. E., 1959, Redetermination of the lead-lead sulfide equilibrium between
585 and 920C K: Trans. Metal. Soc. AIME., v. 215, p. 535-539.
398.
Stuve, J. M., 1974, Low-temperture heat capacities of sphalerite and wurtzite: U.S. Bur. Mines Rept.
Inv., 7940, 8 p.
399.
Stuve, J. M., Beyer, R. P., and Brown, R. R., 1985, Thermodynamic properties of CoS0.89, CoS,^, and
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400.
Stuve, J. M., and Ferrante, M. J., 1980, Low-temperature heat capacities and high-temperature
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401.
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447
REFERENCES CITED
402.
Tequi, C., Robie, R. A., Hemingway, B. S., Neuville, D., and Richet, P.,
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403.
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404.
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405.
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406.
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407.
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409.
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448
411.
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413.
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414.
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415.
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416.
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417.
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420.
449
Waldbaum, D. R., 1973, The configurational entropies of Ca 2MgSi207-Ca2SiAI 2O7 melilites and related
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424.
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427.
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of akermanite, cordierite, gehlenite, and merwinite: U.S. Bur. Mines Rept. Inv. 6343, 7 p.
450
428.
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429.
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430.
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431.
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432.
Weller, W. W., and King, E. G., 1963, Low-temperature heat capacity and entropy at 298.15K of
muscovite: U.S. Bur. Mines Rept. Inv. 6281, 4 p.
433.
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434.
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435.
Westrum, E. F., Jr., written communication, September, 1959.
436.
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437.
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438.
451
Westrum, E. F., Jr., Essene, E. J., and Perkins, D., Ill, 1977, Thermophysical properties of the garnet,
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439.
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440.
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441.
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p. 3820-3826.
442.
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443.
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444.
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The heats of formation of silicon tetrafluoride and silica: Jour. Phys. Chemistry, v. 67, p. 815-821.
445.
Woodland, A. B., and Wood, B. J., 1989, Electrochemical measurement of the free energy of almandine
(Fe3AI2Si30 12) garnet: Geochem. Cosmochim. Acta, v. 53, p. 2277-2282.
452
446.
Wruck, B., 1987,Thermodynamic behavior of the PI ,n pnase transition in anorthite(abs): Programme

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447.
Yakovlev, B. G., and Vozianova, 0. V., 1983, Thermodynamical properties of almandine: Geokimiia,
n. 1, p. 64-75.
448.
Zhdanov, V. M., Turdakin, V. A., Arutyunov, V. S., Semenov, Yu. V., Malinko, S. V., and Kodakovsky,
I. L., 1977, Low-temperature specific heat, standard entropy, and elastic parameters of datolite and
danburyite: Geochemistry International, 14(6), p. 135-141.
449.
Zhogin, D. Yu., Kosarukina, E. A., and Kolesov, V. P., 1980, Heat capacity in the 10-300 K range and
thermodynamic functions of tetragonal tin dioxide: Zhur. Fiz. Khimii, v. 54(4), p. 916-920.
450.
Heat capacity of hercynite estimated as CP(FeAI204) = CP(FeO) + CP(AI203) by Robie. Entropy of

MnS04 and other values estimated by Robie.
451.
Enthalpies of solution of members of the nepheline-kalsilite series were reported by Hovis and Roux
(Hovis, G.L. and Roux, J., 1993, Thermodynamic mixing properties of nepheline-kalsilite crystalline
solutions: Am. Jour. Sci., v. 293, p. 1108-1127.). Using enthalpy of solution values calculated
from their equations 4 and 5, ancillary data from (166, tables 1-4), and unpublished enthalpy
of solution data for KCI from Hemingway (AH(soln) = 6.045 -0.0189t(O), we calculate AfH =
-2090.4 2.5 and-2124.7 2.5 kJ *mor1 , respectively, for nepheline and kaisilite. These results
are in good agreement with values given in (361) of -2092.1 2.4 and-2121.9 1.4kJ*mol'1 ,
respectively, but based on less pure samples (20, 171).
These results are significantly less
negative than the formation properties calculated by (188) from a limited number of phase
equilibrium experiments. The calorimetrically determined value of -3037.8 2.8 kJ*mol*1 for
leucite (171, 20) is preferred to that derived by (188) from a limited number of phase equilibrium
data (-3020.0 2.7 kJ-mor1 ).
REFERENCES CITED
452.
453
Heat capacity measurements on a synthetic alunite are combined with earlier results by Kelley et al.
(219) to estimate the entropy at 298.15 K. The reaction scheme used by Kelley et al. (219) is
recalculated using modern values for the enthalpy of formation of the reference phases. See,
Hemingway, B.S. and Robie, R.A., 1994, Heat capacity and enthalpy of formation of synthetic
alunite: U.S. Geological Survey Open-file Report 94-688, 8 p.
453.
High temperature heat capacities are derived from 244, 299, 402.
454.
The Gibbs energy of livingstonite at 298.15 K is estimated from the study of (Sorokin, V.I., Dadze, T.P.,
and Pokronskiy, V.A., 1988, The Gibbs free energy of formation of livingstonite: Geokhimiya, No.
6, 897-900).
454
INDEX OF NAMES
page
page
Acanthite (argentite)
Acmite
Akermanite
Alabandite
AIbite
Almandine
Altaite
Aluminum
Aluminum ion
Aluminum sulfate
Alunite
Ammonia
Ammonia-niter
Ammonium ion
AnaIbite
Analcime
Anatase
Andalusite
Andradite
Anglesite
Anhydrite
Anilite
Anni te
Anorthite
Anthophyllite
Antimony
Aragonite
Arcanite
Arsenic
Arsenolite
Arsenopyrite
Artinite
Azurite
Baddeleyite
Barite
Barium
Barium ion
Barium monoxide
Ber Unite
Berndtite
Berthierite
Bertrandite
Beryllium
Beryl
Bianchite
Bicarbonate ion
Bicchulite
Bi smite
Bismuth
Bismuthinite
Bixbyite
Boehmi te
Borax
Boric oxide
Bornite
Boron
Braunite
Bredigite
Brochantite
Bromargyrite
Bromellite
Bromide ion
Bromine
Bromine (ideal gas)
Brucite
Bunsenite
11
35
32
12
37
33
13
5
5
28
28
10
26
10
2
37
19
31
32
29
28
11
39
2
35
9
25
28
5
15
14
25
25
20
28
5
5
15
30
13
14
31
5
31
29
15
36
15
5
11
17
15
29
16
11
5
17
32
28
23
15
5
5
5
17
18
45 122 148
62 357
59 321
46 135 161
63 373
60 333
61 308
41 68
56 283
56 290
44 121
280
37
64
50
58
59
57
56
64 374
379
223
305
319
297
285
65
36
62
43
55
56
41
388
63 362
360
106
267
288
69
50 228
56 284
72
47
57
46
46
58
41
58
177
299
142 168
146 172
312
73
311
63 364
47 179
41 74
49 201
47 175
176
45 129 155
41 71
49 203
59
53 245
47 178
41
41
48
49
75
4
198
207
Ca-Al pyroxene
CaAUSiO glass
CaAU
glass
CaFeS ? glass
CaMgSioi glass
CaSiOj glass
Cadmum
Cadmium ion
Calcio-olivine
Calcite
Calcium
Calcium ferrite
Calcium ion
Calcium nitrate
Calomel
Carbon dioxide
Carbon monoxide
Carbonate ion
Carbonic acid (aqueous)
Carnegie jte
Cassiterite
Cattierrite
Celestite
Cerianite
Cerium
Cerussite
Cesium
Cesium ion
Chalcanthite
Chalcocite
Chalcocyanite
Cha I copy rite
Chalcostibite
Chiolite
Chlorargyrite
Chloride ion
Chlorine
Chloromagnesite
Chromite
Chromium
Chrysoberyl
Chrysotile (Antigorite)
Cinnabar
Claudetite
Clausthalite
Clinochlore
Clinoenstatite
Clinoptilolite
Cobalt
Cobalt monoxide
Cobalt-oli vine
Cocci nite
Coesite
Cohenite
Cooper ite
Copper
Copper ion
Cordierite
Corundum
Cotumite
Covellite
Cristobalite
Cryolite
Cuban ite
Cupric ion
Cuprite
Cuprous ion
34
34
36
34
34
34
31
6
6
32
25
6
21
6
26
23
15
15
15
15
37
19
11
29
16
6
26
6
6
28
11
28
11
14
24
23
6
6
23
21
6
21
39
12
15
13
40
34
36
6
16
32
24
19
10
13
6
6
33
15
23
11
19
24
12
6
16
6
61
61
63
61
61
61
58
41
345
363
348
344
79
59 325
55 268
41 78
51 230
55 277
47 181
47 180
64 377
50 219
45 125 151
47 184
41 80
84
45
56
45
46
54
53
127 153
286
128 154
147 173
263
247
41
53
51
41
51
65
81
253
234
83
229
394
61 353
41 82
47 185
59 331
50 216
44 120
42 85
60
47
53
45
50
54
334
174
257
126 152
215
262
48 189
INDEX OF NAMES
455
page
page
Danburite
Datolite
Dawsonite
Dehydrated analeime
Dehydrated mordenite
Diamond
Diaspore
Diboron trioxide
Dicalcium ferrite
Dicesium monoxide
Dickite
Digenite
Dilithium monoxide
Diopside
Dipotassium monoxide
Disodium monoxide
Dititanium trioxide
Djurleite
Dolomite
Dumortierite
36
32
26
38
33
5
15
15
21
16
39
11
17
34
17
18
19
11
25
31
63
59 317
55 273
64 380
Edingtonite
Enargite
Enstatite
Epidote
Epsomite
Eskolaite
Euclase
Eucryptite
36
14
34
31
29
16
31
37
63
Fayalite
Ferberite
Ferric ion
Ferric sulfate
Ferrobustamite
Ferroselite
Ferrosilite
Ferrous ion
Ferrous oxide
Fluorapatite
Fluoride ion
Fluorine
Fluorite
Fluor-pargasite
Fluorphlogopite (Al/Si disordered)
Fluorphlogopite (Al/Si ordered)
Forsterite
Franklinite
Frohbergite
32
30
7
28
34
12
34
7
16
30
6
6
24
35
39
39
33
22
12
60 332
Galena
Gaspeite
13
26
31
21
7
15
35
16
5
29
5
11
2
35
28
46 139 165
Gehlenite
Geikielite
Germanium
Gibbsite
Glaucophane
Goethite
Gold
Goslarite
Graphite
Greenockite
Grossular
Grunerite
Gypsum
Hafnium dioxide
Halite
Halloysite
Haturite
Hauerite
Hausmanni te
41 77
47
47 176
51 231
65 381
48196
61 347
48 195
49 206
55 269
58 308
Ikaite
Iodide ion
Iodine
Iodine (ideal gas)
Iron
Iron ion
Iron tennantite
Iron tetrahedrite
25
39
21
32
24
7
7
7
2
7
14
14
Jadeite
35 62 356
K-Al sulfate
KAISUO. glass
KaliophTUite (Kalsilite)
Kaolinite
Karelianite
Kyani te
28
37
37
39
19
31
56
63
63
65
50
58
Langbeinite
Larnite (bredigite)
Laumontite
Lawrencite
Lawsonite
Lead
Lead ion
Leonhardite
Leucite
Liebenbergite
28
31
36
23
31
8
8
36
37
33
15
11
18
7
7
14
12
56 291
58 324
Illite
Ilmenite
Ilvaite
48 187
58 309
63 371
lodargyrite
61 349
48 191
57 301
42 86
54 258
65
65
60
52
58
51
42
47
62
391
392
335
243
314
240
88
361
41 70
41
45
31
62
76
124 150
58 316
359
Lime
Lirmaeite
Litharge
Lithium
Lithium ion
Livingstonite
Loellingite
23 53 255
39 65
32 59 326
Nagnes ioch romi te

Magnesioferrite
Magnesite
Magnesium
Magnesium ion
Magnesium nitrate
Magnesium sulfate
Magnetite
13
17 49 202
Manganese
17
138 164
346
192
233
141 167
13
34
16
21
13
22
36
36
30
25
7
23
24
7
12
12
25
23
16
30
35
61 352
58
56 287
61
46
61
48
51
46
Heazlewoodite
Hedenbergite
Hematite
Hercynite
Herzenbergite
Hetaerolite
Heulandite
Hexagonal anorthite
Huebnerite
Huntite
Hydrogen
Hydrogen chloride
Hydrogen fluoride
Hydrogen ion
Hydrogen sulfide
Hydrogen sulfide ion
Hydromagnesite
Hydrophilite
Hydroxide ion
Hydroxyapatite
Hypersthene
Malachite
21
21
25
8
8
26
28
16
25
8
42 89
53 251
54 259
46 134 160
53 248
57 302
62
65
51 235
59 318
54 264
42 91
7 87
289
368
369
382
225
304
53 249
58 313
43 102
63 370
60 339
47 182
49 208
93
51
51
55
42
238
239
271
94
55 279
56 292
48 193
42 95
456
page
Manganese ion
Manganese sulfate
Manganosite
Marcasite
Margarite
Marsh ite
Mascagnite
Massicot
Mat i Id ite
Meionite (Al-Si ordered)
Melanterite
Mercuric ion
Mercurous ion
Mercury
Mer lino ite
Merwinite
Mesolite
Metacinnabar
Methane
MgSiO, glass
MgSio|-Ilmenite
MgSiOj-Perovskite
MgjA^SijO^p glass
(Mg. cCa. c)AUSi,Oi:) glass
lsi*" 9lass
Microcline
Millerite
Minium
Mirabilite
Molybdenite
Molybdenum
Molybdite
Molysite
Monohydrocalci te
Monteponite
Mont i eel I ite
Montroydite
Mordenite
Morenosite
Mull ite
Muscovite (Al/Si disordered)
Muscovite (Al/Si ordered)
NaAlSiO, glass
glass
glass
Na ?5~K 75 feldspar
Na 55-K 45 feldspar
Na* fic-K'ic feldspar
Naficolite
Nantokite
Nat ro I ite
Nepheline-Na
?9AlSiO/4
Nepheline ' 7K
n ~ Z^
Nesguehonite
NH,*
8
29
17
12
39
24
29
19
14
36
28
7
7
7
38
32
38
12
10
34
35
35
33
33
33
56
48
45
65
54
56
page
293
199
133 159
384
265
294
63 365
42 90
59 322
44 119
61
62 354
60 337
60
60
14
36 63 366
13
18
29
13
8
17
23
25
16
32
17
38
29
31
2
2
37
35
37
37
37
37
26
23
38
32
37
25
10
8
23
8
29
Nickel
Nickelous chloride
Nickelous ion
Nickelous sulfate
Niningerite
Ni ?SiO/ -spinel
Nifer
Nitrate ion
Nitrobarite
Nitrogen
Nitrogen dioxide
Nukundami te
33
26
17
26
8
17
12
Oldhamite
Orpiment
11
11
46 137 163
49 210
46
42
49
53
136 162
96
204
250
59 320
58 307
39 65 386
39 65 387
64 378
62
64 375
64
64 376
43 99
53 256
56 289
12
60 340
278
55 276
42 97
49 205
Osumilite
Otavite
Oxygen
33 60
25
8 42 100
Paragonite (Al/Si disordered)

Paragonite (Al/Si ordered)
Pargasite (Al/Si ordered)
Pentlandite
Periclase
Perovskite
Petalite
Phenakite
Phillipsite
Phlogopite (Al/Si disordered)
Phlogopite (Al/Si ordered)
Phosphate ion
Phosphorus
Phosphorus pentoxide
Platinum
Plattnerite
PolIncite
Portlandite
Potassium
Potassium aluminum sulfate
Potassium bromide
Potassium hydroxide
Potassium ion
Rowel Iite
Prehnite
Proustite
Pseudobrookite
40 66 395
40 66 396
Pyrolusite
Pyrope
Pyrope-grossular
Pyrophanite
PyrophylIi te
Pyroxmangite
Pyrrhotite
35
13
17
21
37
31
38
2
2
18
8
18
8
18
36
16
7
28
23
17
7
30
39
14
21
34
14
12
17
33
33
21
39
35
12
Quartz
18 49 214
Rankinite
Realgar
Retgersite
Rhodochrosite
Rhodonite
Riebeckite
Rosenhahnite
Rutile
32
11
29
26
35
35
Pseudotrallastonite
Pyrargyrite
Pyrite
Salammoniac
Sanidine
Sanmartinite
Sapphirine
Scacchite
Scheelite
Scoleeite
Selenium
Sellaite
Siderite
Silica glass
Silicalite
Silicic acid (aqueous)
Silicon
Silicon monoxide
Sillimanite
Silver
Silver ion
Smithite
48
51
63
58
197
232
372
310
39 65 389
39 65 390
43 101
43
49
63
47
42
56
53
103
209
183
92
289
246
65 385
51
61 343
45
48
60
60
51
65
132 158
200
336
241
383
45 131 157
59 327
45 123 149
55
62
62
32 59
19 50
272
355
328
222
23 53
2 37 63 367
30
33
23
30
36
9
24
25
19
19
9
9
53 254
43
54
55
50
107
260
270
218
19
43
18 49
31 58
5 41
5
14
108
213
306
67
457
INDEX OF NAMES
page
page
Smithsonite
Soda-niter
Sodium
Sodium carbonate
Sodium hydroxide
Sodium ion
Sphalerite
Spinel
a-spodumene
p-spodumene
Spurrite
Staurolite
Steam
Stibnite
Stilbite
Stishovite
Stolzite
Strengite
Strontianite
Strontium
Strontium ion
Strontium monoxide
Strontium nitrate
Sulfate ion
Sulfide ion
Sulfite ion
Sulfur
Sulfur (monoclinic)
Sulfur (ideal gas)
Sulfur dioxide
Sulfur trioxide
Sulfuric acid
Sylvite
Szomolnokite
26
27
8
26
18
8
13
21
34
34
32
33
17
13
36
19
30
30
26
9
9
19
27
18
9
18
3
9
3
18
18
28
23
28
55 275
55 281
42 98
Talc
Tellurite
Tellurium
Tellurobismuthite
Tenorite
Tephroite
Thenardite
Thermonatrite
Thorianite
Thorium
Tialite
Tilleyite
Tin
Titanite (sphene)
Titanium
Topaz
Tremolite
Trevorite
Tricobalt tetraoxide
Tridymite
Troilite
Trona
Tungsten
Tungsten dioxide
Tungsteni te
Tungsten trioxide
39
19
9
11
16
33
29
26
19
9
21
32
9
32
9
31
35
21
16
19
12
26
9
20
13
20
65 393
Ulvospinel
Uraninite
Uranium
21 51 236
19 50 224
9 43 114
Valentinite
Vanadium
Vaterite
Villiaumite
Violarite
18
9 44 115
25
24 54 261
13
46
51
61
61
59
60
48
46
144 170
237
350
351
329
194
140 166
50 217
55 274
43 110
50 220
55 282
8 43 104
9 43 105
49 211
49 212
53 252
43 111
48
60
56
55
50
43
51
59
43
59
43
58
62
52
47
188
338
295
221
112
330
109
323
113
303
358
242
186
45 130 156
44 116
50 226
46 143 169
Uillemite
Witherite
Wollastonite
Wulfenite
Wurtzite
Wustite
36
16
26
30
33
25
34
30
13
16
Zinc
Zinc ion
Zinc tennantite
Zinc tetrahedrite
Zinc titanium spinel
Zincite
Zinkosite
Zircon
Zirconium
Zoisite
10
10
14
14
22
20
29
33
10
31
Uairakite
Water
Uegscheiderite
Uhitlockite
57 300
60
55 266
61 342
46 145 171
48 190
44 117
52
50
57
60
44
58
244
227
298
341
118
315
458
INDEX OF FORMULAS
page
Ag
Ag+
AgAsS2
p-AgBiS2
AgBr
AgC I
Agl
o-AgSbS2
Ag2S
Ag3AsS3
Ag3sbs3
M 3+
Al(OH)3
AIO(OH)
AIP04
A1 23
A1 2 (S04 )3
Al 2Si04 F2
Al 2Si05
Al 2Si 4010 (OH) 2

Al 6Si 2013
Al 6.75 C] 0.25BSi 317.25 (OH)0.75
As
AsS
AS23
AS2S3
Au
5
5
14
14
23
23
24
14
11
14
14
5
5
15
15
30
15
28
31
31
page
41 67
53 245
53 247
54 264
45 122 148
41 68
47
47
57
47
56
58
58
299
174
283
303
304 305
306
39 65 381 382
39 65 383
21 51
31 58 307
31 58 308
5 41 69
11 45 123 149
15
11
5 41 70
Be4Si 207(OH)2
Bi
Bi 23
Bi 2S3
Bi 2Te3
Br
Br2
5
15
5
5
36
25
26
15
28
5
31
21
15
31
31
31
5
15
11
11
5
5
C
CH,
5 41 76 77
10 44 119
B
B23
Ba
Ba2+
BaAl 2Si 301Q -3H20
BaCOj
Ba(N03 )2
BaO
BaS04
Be
BeAlSi04(OH)
BeAl 204
BeO
Be2Si04
41 71
47 176
72
63
55
55
47
56
41
58
51
47
58
58
58
41
47
266
276
177
284
73
309
229
178
310
311
312
74
179
CO
C02
COj2"
Ca0.59Sr0.18Ba0.06Na0.38~
K0.13Al 2.16Si 6.8418' 6H2
Ca,
Ca2+
CaAl 2 [Al 2Si 2010](OH) 2
CaAl 2Si06
CaAl 2 [Si 207<OH) 2]-H20
CaAl 2Si 208
CaAl 2Si 301Q -3H20
CaAl 2Si 4012 -2H20
CaAl 2Si 4012 -4H20
CaB(Si04 )(OH)
CaB2Si 208
CaCOj
CaCl
CaF
CaFe204
CaFe3 (Si 207)0(OH)
CaMg(C03 )2
CaMgSi04
CaHgSi 206
CaHo04
CaO
Ca(OH) 2
CaS
CaS04
CaS04 -2H20
CaSiOj
CaTi&j
CaTiSi05
CaW04
Ca1.02Na0.14K .01 (Al 2.18Si 6.8218 )l
Ca2Al 2Si06(OH)2
C82FC25
o-Ca2Si04
(J-Ca2Si04
Y-Ca2Si04
41 75
Ca3Mg(Si04 ) 2
Ca3(P04 )2
Ca3Si05
15 47 180
15 47 181
15
36
6
6
39
34
31
36
36
36
36
32
36
25
25
25
23
24
34
21
32
25
32
34
25
30
15
16
11
28
28
34
41 78
65
61
58
63
384
345
313
362 363
59 317
63
55 267 268
53
54
61
51
59
55
59
61
248
258
346
230
318
269
320
347 348
47 182
47 183
56 285
61 342 343
344
21 51 232
32 59 323
30
36
39
31
36
31
31
36
21
32
35
31
31
32
2
32
32
30
32
385
65
58
63
58
58
364
314
315
51
59
62
58
58
59
31
59
59
57
59
231
321
358
324
324
325
58 316
319
322
300
326
INDEX OF FORMULAS
459
page
page
Ca3Si 207
Ca3Si 308(OH) 2
Ca4Al 6Si 6024C03
Ca5 (P04 ) 3 F
Ca5 (P04 )3OH
Cd
Cd2*
CdCOj
CdO
CdS
Ce
Ce02
Cl'
ci 2
Co
CoO
C34
C3S4
Cr
CP23
(Cs " 65Na 19Rb 03>AI 2S1"412' H2
Cs
Cs+
Cs20
Cu
Cu+
CU2+
CuC I
CuFeSo
Cul
CuO
CuS
CuSbS2
CUSO,
CuSO4 -5H20
Cu 1.75s
Cu'1.80s
Cu 1.95 J
Cu2 (C03 )(OH) 2
Cu20
Cu2S
Cu3(OH) 2(C03 ) 2
CU4 (S04 )(OH) 6
Cu10 Fe2Sb4S 13
Cu10Zn2As4S 13
Cu 10Zn2Sb4S 13
F"
FL
Fe .875J
Fe .90s"
^.947
32
32
36
30
30
32
32
6
6
25
16
11
6
16
6
6
6
16
11
32
16
11
6
16
36
6
6
16
6
6
6
23
11
12
24
16
11
14
28
28
11
11
11
25
16
11
14
25
28
11
14
14
14
14
6
6
12
12
16
59
59
63
57
57
59
59
41
327
328
365
301
302
329
330
79
45 124 150
41 80
47 184
41
41
47
45
59
47
81
82
185
125 151
331
186
Fe
FeAl204
FeAs1.08s0.92
FeAs2
FeCOj
FeC 1 2
FeClj
FeCr204
FeO
FeO(OH)
Fe(P04)-2H20
FeS
FeS04 -H20
FeS04 -7H20
FeS
41 83
48 187
63
84
FeSe2
FeSiOj
FeTe2
FeTiOj
FeW04
Fe23
Fe2(S04 )3
42 85
Fe2Si04
Fe2Ti04
Fe2Ti05
45 128 154
54
48
45
46
56
265
188
126 152
147 173
286
Fe3C
Fe34
Fe4Al 18Si 8046(OH> 2
Fe7Sig022(OH)2
Ge
H+
HCOj"
HCl
HF
HS"
H2
48 189
45 127 153
J2JS
H2S
H2S04
H4Si04
HfO,
45 129 155
HgCl
Hgl 2
HgO
HgS
H9|J?4S8
42 86
45 131 157
45
48 190
2
7
7
21
14
12
25
23
23
21
16
12
30
12
28
28
12
7 87
51 233
55
53
53
51
48
45
270
249
250
234
191
130 156
45 130 156
45 132 133
158 159
14 46 146 172
12
34 61 349
12
21 51 235
30
16 48 192
28 56 287
32 60 332
21 51 236
21 51
33 60 333
10 44 120
16 48 193
33 60
35 62 359
7 42 88
7
15
23
24
12
7
15
16
12
28
9
17
7
7
23
24
17
12
14
7
53 251
54 259
42 89
17 48 194
46 134 160
19
42 90
7
7 42 91
460

page
page
K0.80lla0.20Al8! 1 .945.88*
1.81H20
1"!. 81*5.62*
1.79H20
KAl(S04 )2
KAlSi0
KAlSl*1 945 88' 1 - 69H2
KAlSi 266
KAl 2 [AlSi 301Q](OH) 2
KA13 <OH)6<S04 ) 2
KBr
KCl
KFe3 [AlSi,010](OH) 2
KMg3 CAlSi 3010](OH) 2
KNOj
KOH
K2Mg2(S04 )3
K20
K2S04
K3 (Al 7Hg)(Al2Si 14 )040(OH)8
LiAlSi04
LiAlSi 206
LiAlSi 4010
Li 20
<M9.85 Fc.15>Si 3
Mg
J*
HgAl2o4
MgCOj
MgCl 2
HgCr204
MgF2
HgFe204
Ng(N03 )2
HgO
Mg(OH)2
MgS
MgS04 -7H20
MgSiOj
MgTiOj
(Ng 1 " 5Ca1 5 >Al 2Si 3012
'518>
Hg2Si04
38
7
7
28
37
38
38
37
2
39
28
23
23
39
33
39
39
26
17
28
17
28
39
7
7
37
34
37
17
Li
Li*
Mg3Si 205 (OH)4

M83Si 410 (OH)2
38
35
8
8
21
25
25
23
21
24
21
26
17
17
12
28
29
34
35
21
33
33
33
33
25
33
42 92
56 289
63 369
Ng5Al(AlSi 3010 )(OH)8

4MgC03 -Ng(OH) 2 -4H20
Hg7si 8o22(OH)2
Nn
Hn2+
NnCOj
63 370
36 37 63
366 367
65 386 387
56 290
53 246
53 252
65 388
60
65 391 392
65 389 390
278
56 291
48 195
56 288
65
93
63
61
63
48
371
350 351
372
196
62
42 94
51 237
55 271
53
51
54
51
55
48
48
253
238
260
239
279
197
198
56 292
61
62
51
60
60
60
352 353
354
240
334
60 335
MnCl2
MnO
Nn02
MnS
MnS04
NnS2
MnSiOj
MnU0
Ho
HoOj
MoS52
NH3
NH4+
NH4Cl
<NH4 ) 2S04
N02
-
(Na0.25K0.75 )AlSf 38
Na0.36Ca0.29Al 0.94S l5.0612
Na0.36Ca0.29AL 0.94Sl 5.0612'
3.47H2
(N80.55K0.45 )AlSi 38.
Na0.68Ca0.66<Al 1.99Si 3.0110)2.64H20
(Na0.78K0.22 >A [ Si 4
Na0.81 K0.19ALSi 1.815.62'
2.18H20
Na0.81 K0.19AlSi 1.945.88'
2.13H20
(Na0.85K0.15>AlSi 38
Na
Na+
NaAlC03 (OH) 2
NaAlSi04
NaAlSi 206
NaAlSi 206 -H20
NaAlSijOg
NaAl 2 [AlSi 301Q](OH)2
NaCa2Hg4Al(Al 2Si 6 )022F2
NaCa2Ng4Al(Al 2Si 6)022(OH) 2
33
39
39
40
25
35
8
8
26
23
17
17
12
29
13
35
21
30
17
33
17
17
8
17
13
10
10
23
26
29
17
17
8
37
38
60 336 337
65 394
65 393
62 360
42 95
55
53
48
48
45
56
272
254
199
200
135 161
293
62 355
51 241
49
60
49
49
42
49
46
201
338
202
203
96
204
136 162
44 121
53
280
56 294
49 205
42 97
38
37
38
32 64
38
38
37
8 42 98
8
26 55 273
37 64 376 377
378
35 62 356 380
37 64 379
2 37 63 64
373 374
40 66 395 396
35
35
INDEX OF FORMULAS
461
page
page
Nad
NaF
NaFeSi 206
NaHC&j
NaNOj
NaOH
<Ka1.1 K,8>Al 1.9Si 6.r 6H20
Na2B407-10H20
Na2C03 -NaHC03 -2H20
Na2Fe3Fe2Si 8022(OH)2
Ma2Mg3Al 2Si 8022(OH) 2
Na2C03 -3NaHC03
Na20
Na2S04
Na2S04 -10H20
NiCl 2
NiCOj
MiFe204
NiO
NiS
NiS04
NiS04 -6H20
NiS0 -7H20
< Ni .?Fc .3>3S4

Ni 2Si04
Ni 4.5 Fe4.5S8
OH"
53 255
54 261
62 357
55 281
3-
P205
Pb
Pb2+
PbCOj
PbCl 2
PbMo04
PbO
Pb02
PbS
PbS04
PbSe
PbTe
PbW04
Pb34
Pt
PtS
S2'
so2
*U.S. G.P.O.:1995-380-070:89
8
18
18
8
8
26
23
30
18
18
13
29
13
13
30
18
8
13
so4
S2
Sb
Sb23
Se
Si
SiO
Si02
55
62
62 361
49 206
56 295
54 262
54 263
43 99
53 256
52
49
46
56
242
207
137 163
289
Sn
Sn02
SnS
SnS2
Sr
Sr2+
SrCOj
SrO
SrS04
Te
Te02
Th
Th02
Ti
Ti02
Ti 23
60 339 340
46 138 164
18
18
18
3
9
18
13
9
9
18
18
49 212
9 43 105
43 106
46
43
43
49
19
214
217
43
50
46
46
43
140
107
108
213
49
215
218
109
219
141
142
110
166
50
216
9
19
167
13
168
13
9
9
26 55 274
27 55 282
19 50 220
29
9
19
9
19
9
19
19
43 111
43
50
43
50
112
221
113
222 223
uo2
9 43 114
19 50 224
V
V23
9 44 115
19 50 225
43 101
43 102
"3
WS
9 44 116
20 50 226
20
13 46 143 169
16
8 42 100
PO
23
24
35
26
27
18
38
38
29
26
26
26
35
35
26
18
29
29
24
24
8
8
23
26
21
18
13
29
29
29
13
33
13
13
53 257
49
49
46
57
208
209
139 165
297
61 308
49 210
43 103
3 8 43 104
09
18 49 211
wo2
Zn2+
ZnCOj
ZnFe204
ZnMn204
ZnO
ZnS
ZnS04
ZnS04 -6H20
ZnS04 -7H20
Zrtuo,
Zn2Si04
Zn2Ti04
Zr
Zr02
ZrSiO,
10
10
26
22
22
20
13
44 117
55 275
52 243
50 227
46 144 145
170 171
29 57 298
29
29
30
33 60
22 52 244
10 44 118
20 50 228
33 60 341

Robie 1995

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The

U.S. GEOLOGICAL SURVE^ BULLETIN 2131

AVAILABILITY OF BOOKS AND MAPS OF THE U.S. GEOLOGICAL SURVEY

OVER THE COUNTER

Books and Maps

Books and maps of the U.S. Geological Survey are available

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Thermodynamic Properties of Minerals and

U. S. GEOLOGICAL SURVEY BULLETIN 2131

UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1995

U.S. DEPARTMENT OF THE INTERIOR

For sale by U.S. Geological Survey, Information Services

Published in the Eastern Region, Reston, Va.

Library of Congress Cataloging in Publication Data

SYMBOLS, CONSTANTS, AND CONVERSION FACTORS

Thermodynamic Properties of Minerals and Related Substances

THERMODYNAMIC PROPERTIES OF MINERALS AND RELATED SUBSTANCES

value tabulated does not include the configuration^

PHYSICAL CONSTANTS AND ATOMIC

or that species for which the best thennodynamic data are

THERMODYNAMC PROPERTIES OF MINERALS AND RELATED SUBSTANCES

from a regression performed on the calculated values of

The coefficients for the equations are listed, in scientific

include tellurides, selenides and arsenides that are included

Table 1. Atomic weights of the elements for 1985.

NAME AND FORMULA

ALUMINUM (REFERENCE STATE)

ARSENIC (REFERENCE STATE)

GOLD (REFERENCE STATE)

BORON (REFERENCE STATE)

SILVER (REFERENCE STATE)

BISMUTH (REFERENCE STATE)

BROMINE (REFERENCE STATE)

BROMINE (IDEAL GAS)

GRAPHITE (REFERENCE STATE)

-0.51 419 419 419

THERMODYNAMIC PROPERTIES OF MINERALS AND RELATED SUBSTANCES

NAME AND FORMULA

CADMIUM (REFERENCE STATE)

Cd2* (AQUEOUS ION)

CERIUM (REFERENCE STATE)

COBALT (REFERENCE STATE)

CHROMIUM (REFERENCE STATE)

CESIUM (REFERENCE STATE)

Cs* (AQUEOUS ION)

COPPER (REFERENCE STATE)

Cu* (AQUEOUS ION)

Cu2* (AQUEOUS ION)

FLUORINE (REFERENCE STATE)

CHLORINE (REFERENCE STATE)

-8.76 419 419

NAME AND FORMULA

Fe2* (AQUEOUS ION)

15.77 411 411

2.93 411 411

GERMANIUM (REFERENCE STATE)

IRON (REFERENCE STATE)

HYDROGEN (REFERENCE STATE)

MERCURY (REFERENCE STATE)