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\
|
=
T
T
V
p b
m
. .
3
8 . 3
exp
10 4
q
For molecular liquids where bonding forces are Van der Waals type :
AG* ~ 0.41 AE
evaporation
However, these two equations are not valid for liquid metals, polymers,
and chain-like molecules.
Amadeo Avogadro
1776-1856 Max Ludwig Planck
1858-1947
2
Copyright 2011 Cneyt Arslan, All rights reserved.
Copyright 2011 Cneyt Arslan, All rights reserved.
H
2
O
3
Copyright 2011 Cneyt Arslan, All rights reserved.
LAMINAR FLOW
We have defined the term fluid flow as the flow of parallel plates, creating a
velocity profile, caused by the shear stress applied to the fluid.
This velocity profile is defined as THE REASON or THE POTENTIAL of the
momentum transfer from one plate to another.
In this section, we will derive ordinary differential equations (ODEs) for the
momentum transfer in specific flows, such as: flow between parallel plates, flow
in an open channel, flow on an inclined plane, flow in a tube, etc.
These derivations will utilize the concepts of viscosity and momentum balance
to aid you to derive even more complex formulae.
Copyright 2011 Cneyt Arslan, All rights reserved.
MOMENTUM BALANCE
Momentum balance is applied to a small control volume of the fluid in order to
develop a differential equation, describing the whole flow system.
Solutions of these differential equations, when fitted to the physical restrictions
(boundary conditions), turn into algebraic relations which can be used to determine
the engineering characteristics of the system.
These solutions present the velocity distributions, from which the characteristics
can be developed such as, the shear stress on the fluid-solid interface.
4
Copyright 2011 Cneyt Arslan, All rights reserved.
For a steady-state flow:
0
system the
on acting
Forces
OUT
Momentum
of Rate
IN
Momentum
of Rate
=
|
|
|
.
|
\
|
+
|
|
|
.
|
\
|
|
|
|
.
|
\
|
\
|
2
2
Boundary conditions:
# 1: V
y
= 0 when y = 0
# 2: dV/dy = 0 when y = a
0 < y < a
( )
2
2 y ay
x
a
V
x
A
A
=
2
g
q
meaning that the velocity profile is parabolic and the maximum velocity
being reached at the liquid surface.
Taking the integral gives:
8
Copyright 2011 Cneyt Arslan, All rights reserved.
FLOW on an INCLINED PLANE
Copyright 2011 Cneyt Arslan, All rights reserved.
Due to the Viscosity:
Rate of momentum IN.............................(L W) o
xz
|
x
(through the surface at x)
Rate of momentum OUT.........................(L W) o
xz
|
x+Ax
(through the surface at x+Ax)
Due to the Fluid Motion:
Rate of momentum IN.............................(W Ax V
z
) V
z
|
z=0
(through the surface at z = 0)
Rate of momentum OUT.........................(W Ax V
z
) V
z
|
z=L
(through the surface at z = L)
Gravitational force acting on the fluid..........(L Ax W) g cos |
MOMENTUM BALANCE
9
Copyright 2011 Cneyt Arslan, All rights reserved.
Substituting all these terms in Momentum Balance equation:
L W o
xz
|
x
L W o
xz
|
x+Ax
+ (W Ax ) ( V
z
2
|
z=0
V
z
2
|
z=L
)
+ L Ax W g cos | = 0
Since we are in a region where V
z
is not affected by the entrance & exit
point disturbances, it is independent of z. Thus, 3rd and 4th terms cancel
each other.
Dividing both sides by (L W Ax) and taking the limit when Ax goes to zero,
gives:
|
o o
cos lim
0
g
x
x
xz
x x
xz
x
=
A
A +
A
|
o
cos g
dx
d
xz
=
Copyright 2011 Cneyt Arslan, All rights reserved.
1
cos C x g
xz
+ = | o
Taking the integral gives:
Momentum Flux Equation
(defining shear stress distribution)
The integral constant C
1
can be eliminated by solving at the
boundary condition # 1: o
xz
= 0 at x = 0.
| o cos x g
xz
=
If the fluid is Newtonian,
then:
dx
z
dV
xz
q o =
solving simultaneously:
x
g
dx
dV
z
cos
|
|
.
|
\
|
=
q
|
10
Copyright 2011 Cneyt Arslan, All rights reserved.
Taking the integral gives:
2
2
2
C x
g
V
z
+
|
|
.
|
\
|
=
cos
q
|
The integral constant C
2
can be eliminated by solving at another
boundary condition # 2: V
z
= 0 at x = o, which gives:
2
2
cos
o
q
|
2
|
|
.
|
\
|
=
g
C
substituting this back:
|
|
.
|
\
|
|
.
|
\
|
|
|
.
|
\
|
=
2
2
2 o q
| o x g
V
z
1
cos
Velocity Profile Equation
Copyright 2011 Cneyt Arslan, All rights reserved.
Other properties of the system can be easily derived as:
Maximum velocity:
Average velocity:
Volumetric Flowrate:
|
|
.
|
\
|
=
q
| o
cos
2
2
max
g
V
z
|
|
.
|
\
|
= =
}
=
q
| o
o
o
3
cos
1
0 x
2
g
dx V V
z
( )
|
|
.
|
\
|
= =
q
| o
o
3
cos
3
W g
W V Q
v
Coming up next... Problem... (about Copper Smelting ?!...)
11
Copyright 2011 Cneyt Arslan, All rights reserved.
Problem: In copper smelting operations, slag is passed over matte in
order to recover all the copper it contains. Process is carried out in
reverberatory furnaces of 80 ft long and 30 ft wide.
If the slag layer flows with a volumetric rate of 80 ft
3
/h over a stationary
matte phase (a major ! simplification) calculate:
a) the velocity distribution profile within the 2 ft high slag layer, and
b) percentage of the slag that remains in the furnace twice the mean
residence time or longer.
Solution: Since the flow is laminar,
( )
|
|
.
|
\
|
= =
q
| o
o
3
cos
3
W g
W V Q
v
gives the volumetric flow rate. Arranging this equation and multiplying
both sides with 3/2 results in:
2
3
3
cos
2
3
2
|
|
.
|
\
|
=
q
| o
o
g
W
Q
Copyright 2011 Cneyt Arslan, All rights reserved.
Thus,
|
|
.
|
\
|
|
.
|
\
|
=
2
2
3
o o
x
W
Q
V
z
1
Substituting numerical values:
|
|
.
|
\
|
=
2 1 3
4
1
ft 2 ft 30 2
h ft 80 3 x
V
z
2
2
4
1 2
2 2
x x
V
z
=
|
|
.
|
\
|
=
finally,
where, x is the distance (ft) from the top and V
z
is the velocity of that point.
Right side of this equation
|
|
.
|
\
|
|
.
|
\
|
|
|
.
|
\
|
=
2
2
2 o q
| o x g
V
z
1
cos
equals to the first term of
2
3
3
cos
2
3
2
|
|
.
|
\
|
=
q
| o
o
g
W
Q
12
Copyright 2011 Cneyt Arslan, All rights reserved.
This portion remains in the
furnace > 2u.
SLAG
Matte
x = 0
x = o
x = x' V
z
= V
ave
/2
b) Mean residence time
where L is the furnace length (ft), and O is the mean residence time (h).
Thus, the portion of the slag that remains in the furnace for 2O,
corresponds to the slag layer between x = x' and x = o.
x' is the point where V
z
= V
ave
/2 .
ave
V
L
= O
o
=
W
Q
V
ave
Since
1
h ft
3
2
2 30
80
2
1
=
|
.
|
\
|
=
z
V at x = x'
Copyright 2011 Cneyt Arslan, All rights reserved.
2
2
2
x
V
z
=
Substituting this V
z
value back into the velocity profile equation:
gives x = 1.63 feet (from the top)
therefore,
The ratio is (2 1.63) / 2 = 18.5 %
SLAG
Matte
x = 0
x = 2
x
=1.63
2 1.63
2