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Important factors: polyester dyeing in HTHP dyeing machines. 1.Water quality Traces of soluble copper and iron salts can affect the shade of some disperse dyes quite markedly due to the formation of coordination complexes.The presence of calcium and magnesium cations can interfere with the anionic dye dispersing agents/leveling agents and wetting agents present in the dyebath. To overcome these problems a small amount of chelating agents might be added to the dyebath. 2.pH of the dyebath Ideally the pH of the dyebath should be buffered by use of a quality pH regulator, in the range of 4.5-5.5 to minimize the possibility of dye hydrolysis. 3.Use of Surfactants in dyeing There are a multitude of purposes for which anionic surface active agents are used in dyebaths, such as wetting, penetrating and deareation etc. anionic surface active are also used to stabilize the diluted dispersions of the dye.This is necessary particularly when dyeing paler shades where dyebath concentration of surfactant introduced with the dye itself is small. The non ionic surfactants are generally used to control the rate of exchange of dyebath to the fiber. 4.Temperature For most cost effective dyeing of polyester depends on factors such as starting temperature ,rate of heating ,dyeing temperature and duration of dyeing which should result into well exhausted bath ,satisfactory color uniformity and batch to batch shade consistency. A general rule of thumb , the starting temperature of dyeing is 70-80 degrees , the rate of rise of temperature is 1.5-2 deg.Celsius /min and the dyeing temperature is between 115-135 deg.Celsius. 5.Time For an ideal dyeing time selection , one must take into account the exhaustion of dye bath , uniformity of the dye , satisfactory color penetration , for good color fastness and reproducibility of the dyeing results. Generally 15-60 minutes of dyeing time is followed and it is not necessary to prolong the dyeing long beyond the time of maximum exhaustion. 6.Dyes The dyes with similar dyeing characteristics must be selected for particular formulation, it is important to identify the actual dyeing rate of each component will be dependent on the concentration present in the formulation.Care should be taken that the dyeing conditions allow the slowest dyeing component to reach the effective equilibrium. 7.Oligomers
Typically polyester fibres contain between 1.5 and 3.5% by mass of low molecular esters, the principal oligomer being cyclic tris(ethylene terephthalate) with smaller quantities of a dimer, pentamer as well as traces of other compounds. when oligomers are released from the polyester fibre, after some time at 130 C, if an efficient dispersing agent not present in the bath to prevent crystallization of the oligomers, and to prevent small particles of oligomers coming together to form larger agglomerates, oligomers will deposit on the yarn and the machine. Dispersing will maintain the oligomers in a fine dispersion so that when the machine is drained more oligomer goes down the drain. Discharging the dyebath at high temperature if this is possible can also reduce oligomer deposition because any of the material soluble during dyeing at a high temperature can precipitate during cooling. 8.Reduction Clearing Reduction-clearing treatment is necessary to remove any dye remaining on the fibre surfaces, If not removed, this surface contamination can undermine the brightness of shade as well as the wash, sublimation and crock fastness results.Commonly, the dyed polyester is cleared of surface-deposited dye as well as auxiliaries (e.g. carriers, surfactants) by means of treatment with detergent or reductive or oxidative treatments, in order to secure optimum fastness of the dyeing and also to improve the brightness of shade. The usual treatment carried out, especially in heavy depth, is reduction- clearing, where the dyed fibre is treated in a strong reducing bath, usually made up of sodium dithionite and caustic soda. A treatment for 20 minutes at approximately 70-80 deg Cel, is often sufficient to clear the fibre surface, but the ease of removal varies from chromophore to chromophore and dye to dye. This treatment acts to destroy loose azo disperse dye through chemical reduction of the azo link . Anthraquinone disperse dyes are not fully destroyed by such a treatment but a degree of removal of surface dye is achieved through temporary solubilisation of the disperse dye to the alkali-leuco form. 9.Stripping Stripping of disperse dyed material can be accomplished by treating goods a. In a blank bath containing non ionic leveling agent at 130 deg.cel. b.For chemical destruction of dye use 1-2 gpl NaOH and a reducing agent or mild acidic treatment with zinc sulfoxlate-formaldehyde or sodium chlorite can reduce the shade to almost a off white back ground.
Crayons
Crayola, the maker of wax crayons for paper, also makes fabric crayons for use on polyester and other synthetics. These crayons consist of disperse dye, and can be found in most fabric or crafts stores, even in discount department stores such as Target or WalMart. You do not draw directly on the fabric; instead, you draw on paper - or have your children draw on paper! - and then iron the resulting pictures onto the fabric. (Be sure that any writing is backwards on the paper, since it will come out reversed on the fabric.) The crayons are not particularly bright on paper, but become vivid when heat-transferred to the fabric. For an example, see my page Iron-on Fabric Crayons for Synthetic Fibers.
Note that, like most dye, disperse dye is transparent. This means that you should transfer it only onto white or pale colors of fabric, so that you can see the results.
Disperse dye can be applied to paper with rubber stamps, and then ironed on to polyester, just like the crayons. You can use special, largescale fabric stamps to apply other dyes to fabric, but only disperse dyes allow such fine lines that almost any rubber stamp designed for use on paper will work, if your fabric is smooth enough. Look for a product called "Heat Set Ink" at companies that sell rubber stamping supplies. Caroline Dahl's wonderful book Transforming Fabric gives source information for this material, in addition to many project ideas and beautiful inspiring photographs of works made with disperse dye on polyester.
Here's a very simple project that can be done with disperse dye - simple in concept, that is, but very complex and beautiful in its details. As pictured in Kate Wells' Fabric Dyeing & Printing, artist Sarah Batho applied disperse dye paint to paper (you could equally well color it
heavily with Crayola fabric crayons), scattered real bird feathers across her polyester fabric, then ironed the dye right over the feathers. The feathers prevented the dye from reaching the fabric, leaving a lovely delicate design of white feathers on an intense blue background. A consistently inspiring fabric artist and author, Carolyn Dahl, wrote a book called Natural Impressions: Taking an Artistic Path Through Nature with many inspirations as to the use of natural materials in applying designs to cloth; while it does not mention disperse dyes on polyester in this book, as far as I recall, some of the leaf projects, in particular, might be perfect for a similar technique. (I love Dahl's books, and recommend them highly.)
Immersion Tie-dyeing
Traditional single-color tie-dye can be done by tying the dry garment, then dropping it into a hot immersion bath. See the links for directions for immersion dyeing, below. You can get interesting results by tying and dyeing once, washing out, and retying in a different pattern before dropping in another boiling dye bath of a different color. For example, a first dyeing of turquoise followed by another dyeing with fuschia will produce a purple garment with patterns of turquoise and fuschia where the ties prevented full penetration of one of the dyes. Interesting shiborit-like textures result from boiling tied polyester.
Some suppliers label their disperse dyes as "transfer dyes". For contact information, see Sources for Dyeing Supplies.
Sequence
of
Dyeing:
This dyeing process is developed by Du Pont Corporation in 1949. here at sufficient temperature the fibres are soften and their internal structure is opened, polymer macromolecules vibrates vigorously and dye molecules diffuse in in fibre. It requires only a few seconds to 1 min and temperature about 200-230C. The sequence of operation is: Pading Drying Thermofixing After Treatment
Dyeing
Procedure:
At first the fabric is padded with dye solution using above recipe in a three bowl padding mangle. Then the fabric is dried at 100C temperature in dryer. For dyeing, infra red drying method is an ideal method by which water is evaporated from fabric in vapor form. This eliminates the migration of dye particles. Then the fabric is passed through thermasol unit where thermo fixing is done at about 205C temp for 60-90 seconds depending on type of fibre, dye and depth of shade. In thermasol process about 75-90% dye is fixed on fabric. After thermo fixing the unfixed dyes are washed off along with thickener and other chemicals by warm water. Then soap wash or reduction cleaning is done if required.
Carrier dying Certain hydrocarbons, amino acids, amides, alcohols, phenols, and esters accelerate the rate of dyeing of polyester fibres with the disperse dyes from aqueous medium at temperature of up to 100C. the dyeing assistants alter the dispersing properties of the dyes and the physical properties of the fibre so that more of the dye transfers from the dye bath liquor to the fibre substrate. These additives are called as carriers, which swells the fibre and ultimately cause relaxation. They reducing intermolecular forces operating in the fibre and act as molecular lubricants thereby allows the dye molecule to force itself inside the fibre. The carrier that are used are also called swelling agents for the polyester fibre.
Typical dyeing procedure with carriers is as follows The dye bath is set at 60C temperature and with pH 4-5. Fabric material is run for 10 min and aqueous dispersion of dye along with carrier (3-5 gpl) is added in two stages with a gap of 15 min. Carrier is dispersed in water at least for 30 min before use to avoid insoluble particle of carrier, which may cause a carrier mark in the fabric. dyeing is continued for about 60-90 mins. Other auxiliaries such as dispersing agent 0.5to 1 mg per lit. is also added to ensure good dispersion throughout the dyeing. Disadvantages of carrier dyeing 1. Centre selvage variation may occur 2. Carrier mark problem 3. Tailing effect 4. This method is suitable only for light and medium depths 5. Complete removal of residual carrier is difficult 6. Most of carriers are toxic, gives unpleasant smell to fabric 7. Dyeing process takes more time as compare to other methods 8. It may turn out to be costly process due to high prices of carrier themselves.