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JMS 3 PAPER - 2

PAPER-2
Maximum Marks: 80

Question paper format and Marking scheme: 1. In Section I (Total Marks: 24), for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other cases, minus one (1) mark will be awarded. 2. In Section II (Total Marks: 16), for each question you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks other wise. There are no negative marks in this section. 3. In Section III (Total Marks: 24), for each question you will be awarded 4 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks otherwise There are no negative marks in this section. 4. In Section IV (Total Marks: 16), for each question you will be awarded 2 marks for each row in which you have darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks otherwise. Thus each question in this section carries a maximum of 8 Marks. There are no negative marks in this section. http://www.chemistrycrest.com/ Page 1

JMS 3 PAPER - 2
SECTION I (Total Marks : 24) (Single Correct Answer Type) This Section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. 1. The plot of compressibility factor (Z) versus pressure for the same gas given at different temperatures.
T4
T3

T2 T1

Z 1.0

Ideal gas

P(atm)

The correct order of temperatures is A) T4 > T3 > T2 > T1 C) T1 > T2 > T3 > T4 Sol. B) T2 > T3 > T1 > T4 D) T3 > T2 > T1 > T4

(C) As the temperature increased, minima of the curve shifts upwards. Dipole moment of the following molecules are in the order
CH

2.

3
H

Cl
C = C

H C 3

Cl
C = C
NO
(2)

H
(1)

Cl
H

H C 3

Cl
C = C

Cl
C = C
H

Cl
(3)
(A) 1 > 4 > 2 > 3 (C) 3 > 2 > 4 > 1

Cl

Cl
(4)
(B) 2 > 3 > 1 > 4 (D) 2 > 4 > 1 > 3 Page 2

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JMS 3 PAPER - 2
Sol. (B)
H C 3

Cl
C = C

H C 3
2

Cl
C = C

Cl
(2)

NO

Cl
(3)

Cl

(Net vector in the direction of NO 2)

(Net vector in the direction of Cl)

- NO2 is a stronger - I group than Cl . For 4, dipole moment is zero due to cancellation of bond moments two C Cl bonds as they are oriented in opposite direction. 3.

Cl2 ( g ) + Ba ( OH )2 X ( aq ) + BaCl2 + H 2O
X + H 2 SO4 Y + BaSO4
Y Z + H 2O + O2 >365K

Y, Z respectively and magnetic behaviour exhibited by Z are A) HClO4 , ClO2 , diamagnetic C) HClO3 , Cl2O , diamagnetic Sol. (B)
Cl2 + 2 Ba ( OH ) 2 Ba ( ClO3 )2 + 5 BaCl2 + 6 H 2O
(X )

B) HClO3 , ClO2 , paramagnetic D) HClO4 , Cl2O7 , paramagnetic

Ba ( ClO3 ) 2 + H 2 SO4 2 HClO3 + BaSO4


2 HClO3 2ClO2 + H 2O + O2 > 365 K

(Y )

(Z )

Z has odd e- .So, exhibits paramagnetism

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JMS 3 PAPER - 2
4.

NH4Cl crystallizes in a body-centred cubic lattice with edge length of unit cell equal to 387 pm. If the radius of the Cl ion is 181 pm, radius for NH4+ ion is (A) 154.1 pm (B) 92.6 pm (C) 366.3 pm (D) none of these
(A) In body centred cubic lattice, oppositely charged ions touch each other along the body diagonal.

Sol.

2rc + 2ra = 3a rc + ra = = 3 a 2

3 a 2 3 = 387 = 335.15 pm 2 given ra =181 pm rc = 335.15 181.0 = 154.15 pm


5. The isomers given are
CH3

CH2 CH3
H Cl and

HO H

HO H
CH3

H Cl

CH2 CH3

(A) Identical (C) Enantiomers


Sol.

(B) Diastereomers (D) none of the above

(A) Configuration at both the chiral carbons is same. So, they are identical or homomers If Configuration at both the chiral carbons is opposite, they are enatiomers. ( R, R & S,S ) If Configuration at one of the chiral carbons is opposite and same at the other carbon , they are diastereomers. ( R, S & S,S or R, R & R ,S )
3 CH 1 HO 2
H 4

4 R H

1 R HO
H 4 R

CH CH 2 3
H

Cl 1

Cl 1

CH CH 3 2 3

CH 3

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JMS 3 PAPER - 2

6.

560 K 470 K Z X Y inert atmosphere under pressure

The three allotropes ' X ', ' Y ' and ' Z ' of phosphorus in the above changes are respectively, A) white, black and red C) red, black and white Sol. (A) X = White phosphorus Y = Black phosphorus Z = Red phosphorus An optically active Aldose A upon treatment with NaBH 4 is converted into an optically inactive alditol (B). A on Ruff degradation gives C whose alditol (D) is optically inactive. Ruff degradation of C gives optically active D-glyceraldehyde A,B,C & D are A) -D- Glucopyranose, D-glucitol, D-ribose, ribitol B) D- ribose, ribitol, D-erythrose, erythritol C) D glucopyranose, L-Dlucitol, L-ribose, ribitol D) D fructofuranose, D-Manitol, D-ribose, ribitol (B) B) black, white and red D) red, violet and black

7.

Sol.

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JMS 3 PAPER - 2
8. Acidic hydrolysis is minimum in
O OCR
O OCR

O COR

O COR
| NO2
| OC2H5

(A) Sol.

(B)

NO2

(C)

(D)

(D) In acid catalysed hydrolysis. the mechanism operated is

If G is Electron withdrawing group then it functions as a good leaving group. SECTION II (Total Marks : 16)
(Multiple Correct Answer(s) Type)

This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE OR MORE may be correct. 9. The major products of following reaction sequence are :
H SO LiAlH 2 4 4 (I) (II) H (II) 1) ( ( 2) ( 3)

(A) I = http://www.chemistrycrest.com/

(B) I =

(C) III =

(D) III = Page 6

JMS 3 PAPER - 2
Sol. (B, D)

H SO 2 4 (1) Pinacol (Pinacolone Rearrangment)

( H 2O )
10.
HCl ( aq ) Mg3B2 [X] + MgCl
HCl ( aq ) [X] + H2O [Y] + H2

(3) H

Regarding [X] and [Y], the correct option/s is/are

(A) [X] is BCl3 and [Y] is H3BO3 (B) [X] is B2H6 and [Y] is H3BO3 (C) [X] on reaction with air and [Y] on strong heating (red heat) give same compound. (D) In [Y], B attains octet by accepting OH from water

Sol

(B, C, D)

(A) (B) (C)

HCl ( aq ) Mg3B2 MgCl2 + B2H6 [X], X is not BCl3, it B2H6

2H BO [Y] + H , B2H6 + 6H2O 3 3 2

Both [X] and [Y] gives B2O3 ; B2H6 + 3O2 Red hot H3BO3 B2O3

B2O3 + 3H2O ;

(D)

B(OH) + H O+ (aq) B(OH)3(aq) + 2H2O 4 3

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JMS 3 PAPER - 2

11.

Which one of the following is/are optically active? (A)


H C 3

(B)

Cl
NO

CH
2

H C 3

Cl

H C 3

(C)

(D)
H

H C 3
C=C=C
H

CH

3
H

CH

Br

3 CH 3

Br

Sol.

(C, D) A) has no asymmetric carbons and also plane of symmetry.In tetra ortho-substituted compounds, the planes of the rings are perpendicular to each other. B) does not have any asymmetric carbon. C) does not have any plane of symmetry. D) has asymmetric carbon and has no plane symmetry.It can be represented as
CH
H Br

3
Br H

CH

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JMS 3 PAPER - 2
12. The true statements among the following are A) Magnesium with dil. HNO3 produces hydrogen B) Sodium nitrate on heating at 500C gives oxygen C) Sodium carbonate liberates CO2 on heating at 100oC D) Sodium when heated in excess of oxygen gives sodium monoxide. (A, B) Mg + 2 HNO3 Mg ( NO3 )2 + H 2 2 NaNO3 2 NaNO2 + O2 Na2CO3 does not decompose on heating 2 Na + O2 (excess ) Na2O2 SECTION-III (Total Marks : 24) (Integer Answer Type) This section contains 6 questions. The answer to each of the questions is a single-digit integer, ranging from 0 to 9. The bubble corresponding to the correct answer is to be darkened in the ORS. 13. Sol. Amongst the following , no of molecules that are coloured due to charge transfer phenomenon are
CrO2 , Cr2 O72 , MnO , Cu2O, ZnO, CuSO4, MnS 4 4

Sol.

(4)
CrO 2 , Cr2 O 7 2 , MnO , Cu2O are coloured due to charge transfer phenomenon 4 4

14.

The standard reduction potential of H2O2 is 1.776V and standard oxidation potential of H2O2 is 0.682V. The overall cell potential for disproportionation of H2O2 is almost equal to (1)
For H2O2 disproportionation, H O + 2 H + + 2e 2 H O; E 0red = 1.776 V 2 2 2 H O O + 2 H + + 2e ; E 0 = ( 0.682 ) 2 2 2 oxi

Sol.

2 H O 2 H O + 2O ; E 0 = E 0 + E 0 = 1.094V 2 2 2 2 red ox

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JMS 3 PAPER - 2
15. Amongst the following , no of species having linear shape is
I3 , ICl2 , BeCl 2 , XeF2 , XeF6 , BrF5 , HC CH
Sol : (5)

16.

In 2HI(g) H2 (g) + I2 (g), 2 mole HI, 4 mole H2 and 4 mole of I2 are found at equilibrium. If some hydrogen is now introduced into the container such that at equilibrium concentration of HI and I2 become equal. Unit place of number of moles of H2 added is (0)
keq = 4 4

Sol.

( 2)

=4

H2 + 2Hi Av.eq. 2 4 After addition 2 4+x Av. New eq. 2+2y 4+x-y So, 2+2y=4-y y = 2/3

I2 4 4 4-y

And

10 10 + x 3 3 = 4 k eq = 4 = 10 10 3 3

10 10 30 So , x = 4 = = 10 moles 3 3 3
17.

C3 H 7 Br ( A ) gives C3 H 6 ( B ) with alcoholic potash. (B) on oxidation gives C2 H 4O2 ( C ) + carbon


dioxide and water, (B) with hydrobromic acid gives (D), an isomer of (A). The difference in the positions of Br in (A) and (D) is

Sol.

(1)
alc.KOH CH CH CH Br CH CH=CH 3 2 2 3 2
1-bromopropane (A) (B)

CH CHBrCH 3 3

2-bromopropane (D)

CH COOH+CO +H O 3 2 2
(C)

Difference in position of Br in (A) and (D) is = 2 1 = 1


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JMS 3 PAPER - 2
18. An electron is accelerated from rest and it has wavelength of 1.41 . Unit place of potential that should be dropped so that wavelength associated with electron becomes 1.73 . (5) For an e-,

Sol.

150 0 A V
150 = 75V = 50V

V1 =

(1.41)

and V2 =

150

(1.73)

Hence potential should be dropped by 25 V.

SECTION-IV (Total Marks : 16) (Matrix-Match Type) This section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and five statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II. For example, if for a given question, statement B matches with the statements given q and r, then for the particular question, against statement B, darken the bubbles corresponding to q and r in the ORS. 19. Column-I (A) (B) (C) (D)
Acetone + CHCl3 CS2 + Acetone Phenol and aniline
Toluene + Benzene

Column-II (P) (Q) (R) (S) (T)


P total < PA + PB

Vmix > 0
H mix is not equal to 0

Maximum boiling azeotropes A - B Interaction =A-A&B-B

Sol.

A-P, R, S ; B-Q, R ; C-P, R ,S; D-T

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JMS 3 PAPER - 2

(A & C)

Acetone + CHCl3 shows ve deviation Phenol + aniline shows ve deviation For a non ideal solution with ve deviation. A - B Interaction > A - A & B B P total < PA + PB Vmix < 0 <0 H mix It forms a max boiling azeotrope

(B)

CS2 + Acetone shows + ve deviation


For a non ideal solution with + ve deviation.

A - B Interaction < A - A & B B P total > PA + PB


Vmix > 0
>0 mix It forms a min boiling azeotrope H

(D)

Toluene + Benzene is an ideal solution

For an ideal solution,


A - B Interaction = A - A & B B P total = PA + PB

Vmix = 0
=0 mix Do not form azeotropes H

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JMS 3 PAPER - 2

20.

Match the reactions in column I with appropriate types of steps/reactive intermediate involved in these reactions as given in column II. Column-I (A)
m CPBA

Column-II (P) product contains one ring

(B)

Br2 H 2O

aq NaOH

(Q)

product contains two rings

(C)

H3C CH = CH 2
CH 2 I 2 Zn / Cu ether

(R)

product is an epoxide

(D)

h H 2 C = CH ( CH 2 )3 CHN 2

(S) (T)

product is a hydrocarbon A carbene (or) carbene like species participates

Sol.

A - Q, R ; B - Q,R ; C - P, S, T ; D - Q, S,T

(A) m- CPBA is m-Chloro per benzoic acid.


m CPBA

(B) Anti addition


OH

Br 2 H O 2

aq. NaOH
Br

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JMS 3 PAPER - 2
(C) Simmons-Smith reaction in which a carbene participates
2 CH I 2 2 H C CH = CH H C CH CH 3 2 3 2 CH

(D)

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