AIEEE Solved Paper 2007

1. The displacement of an object attached to a

spring and executing simple harmonic motion
is given by x

2 10
2
cos t metre. The time
at which the maximum speed first occurs is
(a) 0.5 s (b) 0.75 s
(c) 0.125 s (d) 0.25 s
2. In an AC circuit the voltage applied is
E E t
0
sin . The resulting current in the
circuit is I I t

_
,
0
2
sin

. The power
consumption in the circuit is given by
(a) P
E I

0 0
2
(b) P zero
(c) P
E I

0 0
2
(d) P E I 2
0 0
3. An electric charge 10
3
C is placed at the origin
(0, 0) of X-Y coordinate system. Two points A
and B are situated at ( , ) 2 2 and (2, 0)
respectively. The potential difference between
the points A and B will be
(a) 9 V (b) zero
(c) 2 V (d) 4.5 V
4. A battery is used to charge a parallel plate
capacitor till the potential difference between
the plates becomes equal to the electromotive
force of the battery. The ratio of the energy
stored in the capacitor and the work done by
the battery will be
(a) 1 (b) 2
(c)
1
4
(d)
1
2
5. An ideal coil of 10 H is connected in series with
a resistance of 5 and a battery of 5 V. 2 s after
the connection is made, the current flowing (in
ampere) in the circuit is
(a) ( ) 1 e (b) e
(c) e
1
(d) ( ) 1
1

e
6. A long straight wire of radius a carries a steady
current i. The current is uniformly distributed
across its cross-section. The ratio of the
magnetic field at
a
2
and 2a is
(a)
1
4
(b) 4
(c) 1 (d)
1
2
7. A current I flows along the length of an
infinitely long, straight, thin walled pipe. Then
(a) the magnetic field is zero only on the axis
of the pipe
(b) the magnetic field is different at different
points inside the pipe
(c) the magnetic field at any point inside the
pipe is zero
(d) the magnetic field at all points inside the
pipe is the same, but not zero
8. If M
O
is the mass of an oxygen isotope
8
17
O ,
M
p
and M
n
are the masses of a proton and a
neutron, respectively, the nuclear binding
energy of the isotope is
(a) ( ) M M
O p
8
2
c
(b) ( ) M M M
O p n
8 9
2
c
(c) M
O
c
2
(d) ( ) M M
O n
17
2
c
9. In gamma ray emission from a nucleus
(a) both the neutron number and the proton
number change
(b) there is no change in the proton number
and the neutron number
(c) only the neutron number changes
(d) only the proton number changes
10. If in a p-n junction diode, a square input signal
of 10 V is applied as shown
1
Solved Paper 2007
AIEEE
(All India Engineering Entrance Examination)
Physics
AIEEE Solved Paper 2007
Then the output signal across R
L
will be
11. Pho ton of fre quency has a mo men tum
as so ci ated with it. If c is the ve loc ity of light, the
mo men tum is
(a) /c (b) hc
(c) h c /
2
(d) h c /
12. The velocity of a particle is v v gt ft + +
0
2
. If
its position is x 0 at t 0, then its
displacement after unit time ( ) t 1 is
(a) v g f
0
2 3 + + (b) v g f
0
2 3 + + / /
(c) v g f
0
+ + (d) v g f
0
2 + + /
13. For the given uniform square lamina ABCD,
whose centre is O
(a) 2 I I
AC EF
(b) I I
AD EF
3
(c) I I
AC EF
(d) I I
AC EF
2
14. A point mass oscillates along the x-axis
according to the law x x
0
cos ( / ) t 4 . If
the acceleration of the particle is written as
a A t + cos( ), then
(a) A x
0
4 , /
(b) A x
0
2
4 , /
(c) A x
0
2
4 , /
(d) A x
0
2
3 4 , /
15. Charges are placed on
the vertices of a square
as shown. Let E

be the
electric field and V the
potential at the centre.
If the charges on A and
B are interchanged
with those on D and C
respectively, then
(a) E

remains unchanged, V changes

(b) both E

and V change
(c) E

and V remain unchanged

(d) E

changes, V remains unchanged

16. The half-life period of a radioactive element X
is same as the mean life time of another
radioactive element Y. Initially they have the
same number of atoms. Then
(a) X will decay faster than Y
(b) Y will decay faster than X
(c) Y and X have same decay rate initially
(d) X and Y decay at same rate always
17. A Carnot engine, having an efficiency of
1 10 / as heat engine, is used as a
refrigerator. If the work done on the system is
10 J, the amount of energy absorbed from the
reservoir at lower temperature is
(a) 99 J (b) 90 J
(c) 1 J (d) 100 J
18. Carbon, silicon and germanium have four
valence electrons each. At room temperature
which one of the following statements is most
appropriate ?
(a) The number of free conduction electrons is
significant in C but small in Si and Ge
(b) The number of free conduction electrons is
negligibly small in all the three
(c) The number of free electrons for
conduction is significant in all the three
(d) The number of free electrons for
conduction is significant only in Si and Ge
but small in C
19. A charged particle with charge q enters a
region of constant, uniform and mutually
orthogonal fields E

and B

with a velocity v

perpendicular to both E

and B

, and comes out

without any change in magnitude or direction
of v

. Then
2
D C
O
B A
E
F
5 V
(a) (b)
(c) (d)
+5 V
10 V
10 V
A B
C D
q q
q q
5 V
5 V
R
L
(a) v E B

/ B
2
(b) v B E

/ B
2
(c) v E B

/ E
2
(d) v B E

/ E
2
20. The potential at a point x (measured in m)
due to some charges situated on the x-axis is
given by : V x x ( ) / ( ) 20 4
2
volt
The electric field E at x 4 m is given by
(a)
5
3
V/m and in the ve x direction
(b)
5
3
V/m and in the +ve x direction
(c)
10
9
V/m and in the ve x direction
(d)
10
9
V/m and in the +ve x direction
21. Which of the following transitions in hydrogen
atoms emit photons of highest frequency ?
(a) n 2 to n 6 (b) n 6 to n 2
(c) n 2 to n 1 (d) n 1 to n 2
22. A block of mass m is connected to another block
of mass M by a spring (massless) of spring
constant k. The blocks are kept on a smooth
horizontal plane. Initially the blocks are at rest
and the spring is unstretched. Then a constant
force F starts acting on the block of mass M to
pull it. Find the force on the block of mass m.
(a)
mF
M
(b)
( ) M m F
m
+
(c)
mF
m M ( ) +
(d)
MF
m M ( ) +
23. Two lenses of power 15D and +5D are in
contact with each other. The focal length of the
combination is :
(a) 20 cm (b) 10 cm
(c) +20 cm (d) +10 cm
24. One end of a thermally insulated rod is kept at
a temperature T
1
and the other at T
2
. The rod is
composed of two sections of lengths l
1
and l
2
and thermal conductivities K
1
and K
2
respectively. The temperature at the interface
of the two sections is
(a) ( )/( ) K l T K l T K l K l
2 2 1 1 1 2 1 1 2 2
+ +
(b) ( )/( ) K l T K l T K l K l
2 1 1 1 2 2 2 1 1 2
+ +
(c) ( )/(
)
K l T K l T K l K l
1 2 1 2 1 2 1 2 2 1
+ +
(d) ( )/( ) K l T K l T K l K l
1 1 1 2 2 2 1 1 2 2
+ +
25. A sound absorber attenuates the sound level by
20 dB. The intensity decreases by a factor of
(a) 1000 (b) 10000
(c) 10 (d) 100
26. If C
p
and C
V
denote the specific heats of
nitrogen per unit mass at constant pressure and
constant volume respectively, then
(a) C C R
p V
/28 (b) C C R
p V
/14
(c) C C R
p V
(d) C C R
p V
28
27. A charged particle moves through a magnetic
field perpendicular to its direction. Then
(a) the momentum changes but the kinetic
energy is constant
(b) both momentum and kinetic energy of the
particle are not constant
(c) both momentum and kinetic energy of the
particle are constant
(d) kinetic energy changes but the momentum
is constant
28. Two iden ti cal con duct ing wires AOB and COD
are placed at right an gles to each other. The
wire AOB car ries an elec tric cur rent I
1
and COD
car ries a cur rent I
2
. The mag netic field on a
point ly ing at a dis tance d from O, in a di rec tion
per pen dic u lar to the plane of the wires AOB
and COD, will be given by
(a)

0 1 2
1 2
2
I I
d
+

_
,

/
(b)

0
1
2
2
2 1 2
2 d
I I ( )
/
+
(c)

0
1 2
2 d
I I ( ) + (d)

0
1
2
2
2
2 d
I I ( ) +
29. The resistance of a wire is 5 at 50C and 6
at 100C. The resistance of the wire at 0C will
be
(a) 2 (b) 1
(c) 4 (d) 3
30. A par al lel plate con denser with a di elec tric of
di elec tric con stant K be tween the plates has a
ca pac ity C and is charged to a po ten tial V volts.
The di elec tric slab is slowly re moved from
be tween the plates and then re in serted. The
net work done by the sys tem in this process is
(a)
1
2
1
2
( ) K CV (b) CV K K
2
1 ( )/
(c) ( ) K CV 1
2
(d) zero
31. If g
E
and g
M
are the ac cel er a tions due to
grav ity on the sur faces of the earth and the
moon re spec tively and if Millikans oil drop
ex per i ment could be per formed on the two
sur faces, one will find the ra tio
electronic charge on the moon
electronic charge on the earth
to be
3
T
1
T
2
K
1
K
2
l
1
l
2
(a) 1 (b) zero
(c) g g
E M
/ (d) g g
M E
/
32. A cir cu lar disc of ra dius R is re moved from a
big ger cir cu lar disc of ra dius 2R, such that the
cir cum fer ence of the discs co in cide. The cen tre
of mass of the new disc is

R
from the cen tre of
the big ger disc. The value of is
(a)
1
3
(b)
1
2
(c)
1
6
(d)
1
4
33. A round uni form body of ra dius R, mass M and
mo ment of in er tia I, rolls down (with out
slip ping) an in clined plane mak ing an an gle
with the hor i zon tal. Then its ac cel er a tion is
(a)
g
I MR
sin
/

1
2
+
(b)
g
MR I
sin
/

1
2
+
(c)
g
I MR
sin
/

1
2

(d)
g
MR I
sin
/

1
2

34. Angular momentum of the particle rotating

with a central force is constant due to
(a) constant force
(b) constant linear momentum
(c) zero torque
(d) constant torque
35. A 2 kg block slides on a hor i zon tal floor with a
speed of 4 m/s. It strikes a un com pressed
spring, and com presses it till the block is
mo tion less. The ki netic fric tion force is 15 N
and spring con stant is 10,000 N/m. The spring
com presses by
(a) 5.5 cm (b) 2.5 cm
(c) 11.0 cm (d) 8.5 cm
36. A par ti cle is pro jected at 60 to the hor i zon tal
with a ki netic en ergy K. The ki netic en ergy at
the high est point is
(a) K (b) zero
(c) K/4 (d) K/2
37. In a Youngs dou ble slit ex per i ment the
in ten sity at a point where the path dif fer ence is

6
( be ing the wave length of the light used) is
I. If I
0
de notes the max i mum in ten sity, I I /
0
is
equal to
(a)
1
2
(b)
3
2
(c)
1
2
(d)
3
4
38. Two springs, of force con stants k
1
and k
2
, are
con nected to a mass m as shown. The
fre quency of os cil la tion of the mass is f. If both
k
1
and k
2
are made four times their orig i nal
val ues, the fre quency of os cil la tion be comes
(a)
f
2
(b)
f
4
(c) 4 f (d) 2f
39. When a sys tem is taken from state i to state f
along the path iaf , it is found that Q 50 cal
and W 20 cal. Along the path ibf Q 36 cal.
W along the path ibf is
(a) 6 cal (b) 16 cal
(c) 66 cal (d) 14 cal
40. A par ti cle of mass m ex e cutes sim ple har monic
mo tion with am pli tude a and fre quency . The
av er age ki netic en ergy dur ing its mo tion from
the po si tion of equi lib rium to the end is
(a)
2 2 2
ma (b)
1
4
2 2
ma
(c) 4
2 2 2
ma (d) 2
2 2 2
ma
41. The en er gies of ac ti va tion for for ward and
re verse re ac tions for A B AB
2 2
2 + a are
180 kJ mol
1
and 200 kJ mol
1
re spec tively.
The pres ence of a cat a lyst low ers the ac ti va tion
en ergy of both (for ward and re verse) re ac tions
by 100 kJ mol
1
. The enthalpy change of the
re ac tion ( ) A B AB
2 2
2 + in the pres ence of
cat a lyst will be (in kJ mol
1
)
(a) 300 (b) 120
(c) 280 (d) 20
42. The cell, Zn|Zn (1M)||Cu (1M)|Cu
2+ 2+

( . E
cell
1 10 V), was allowed to be completely
4
k
1
k
2
m
i
a
f
b
Chemistry
discharged at 298 K. The relative concentration
of Zn
2+
to Cu
2+
[ ]
[ ]
Zn
Cu
2
2
+
+

_
,

is
(a) antilog (24.08) (b) 37.3
(c) 10
37 3 .
(d) 9 65 10
4
.
43. The pK
a
of a weak acid ( ) H A is 4.5. The pOH of
an aqueous buffered solution of HA in which
50% of the acid ionised is
(a) 4.5 (b) 2.5
(c) 9.5 (d) 7.0
44. Consider the reaction,
2 A B + products
When concentration of B alone was doubled,
the half-life did not change. When the
concentration of A alone was doubled, the rate
increased by two times. The unit of rate
constant for this reaction is
(a) L mol s
1 1
(b) no unit
(c) mol L s
1 1
(d) s
1
45. Identify the incorrect statement among the
following
(a) d-block elements show irregular and erratic
chemical properties among themselves
(b) La and Lu have partially filled d orbitals
and no other partially filled orbitals
(c) The chemistry of various lanthanoids is
very similar
(d) 4 f and 5f orbitals are equally shielded
46. Which one of the following has a square planar
geometry ?
(a) [CoCl ]
4
2
(b) [FeCl ]
4
2
(c) [NiCl ]
4
2
(d) [PtCl ]
4
2
(At. no. Co =27, Ni 28, Fe 26, Pt 78)
47. Which of the following molecules is expected
to rotate the plane of plane-polarised light ?
48. The secondary structure of a protein refers to
(a) -helical backbone
(b) hydrophobic interactions
(c) sequence of -amino acids
(d) fixed configuration of the polypeptide
backbone
49. Which of the following reactions will yield,
2, 2-dibromopropane ?
(a) CH C CH+ 2HBr
3

(b) CH CH==CHBr + HBr
3

(c) CH CH+ 2HBr

(d) CH CH==CH + HBr
3 2

50. In the chemical reaction,
CH CH NH +CHCl 3KOH
3 2 2 3
+
( ) ( ) A B + + 3H O
2
, the compounds (A) and
(B) are respectively
(a) C H CN
2 5
and 3KCl
(b) CH CH CONH
3 2 2
and 3KCl
(c) C H NC
2 5
and K CO
2 3
(d) C H NC
2 5
and 3KCl
51. The reaction of toluene with Cl
2
in presence of
FeCl
3
gives predominantly
(a) benzoyl chloride
(b) benzyl chloride
(c) o-and p-chlorotoluene
(d) m-chlorotoluene
52. Presence of a nitro group in a benzene ring
(a) activates the ring towards electrophilic
substitution
(b) renders the ring basic
(c) deactivates the ring towards nucleophilic
substitution
(d) deactivates the ring towards electrophilic
substitution
53. In which of the fol low ing ion is ation pro cesses,
the bond or der has in creased and the mag netic
be hav iour has changed ?
(a) C C
2 2
+
(b) NO NO
+

(c) O O
2 2
+
(d) N N
2 2
+

54. The actinoids ex hibit more num ber of

ox i da tion states in gen eral than the
lanthanoids. This is be cause
(a) the 5f orbitals are more buried than the 4 f
orbitals
(b) there is a similarity between 4 f and 5f
orbitals in their angular part of the wave
function
(c) the actinoids are more reactive than the
lanthanoids
(d) the 5f orbitals extend farther from the
nucleus than the 4 f orbitals
5
CHO
H
CH OH
2
HO (a)
SH
(b)
COOH
H
H
H N
2
H N
2
Ph
H
Ph
NH
2
H
(c) (d)
55. Equal masses of methane and oxygen are
mixed in an empty container at 25C. The
fraction of the total pressure exerted by oxygen
is
(a)
2
3
(b)
1
3
273
298

(c)
1
3
(d)
1
2
56. A 5.25% so lu tion of a sub stance is iso tonic with
a 1.5% so lu tion of urea (mo lar mass 60 g
mol
1
) in the same sol vent. If the den si ties of
both the so lu tions are as sumed to be equal to
1.0 g cm
3
, mo lar mass of the sub stance will be
(a) 90.0 g mol
1
(b) 115.0 g mol
1
(c) 105.0 g mol
1
(d) 210.0 g mol
1
57. As sum ing that wa ter vapour is an ideal gas, the
in ter nal en ergy change ( ) U when 1 mole of
wa ter is vapourised at 1 bar pres sure and
100C, (Given : mo lar enthalpy of vapori sa tion
of wa ter at 1 bar and 373 K 41 kJ mol
1
and
R 8 3 . J mol
1
K
1
) will be
(a) 4.100 kJ mol
1
(b) 3.7904 kJ mol
1
(c) 37.904 kJ mol
1
(d) 41.00 kJ mol
1
58. In a saturated solution of the sparingly soluble
strong electrolyte AgIO
3
(Molecular mass
283) the equilibrium which sets in is
AgIO Ag IO
3 3
( ) ( ) ( ) s aq aq a
+
+
if the solubility product constant K
sp
of AgIO
3
at a given temperature is 1 0 10
8
.

, what is the
mass of AgIO
3
contained in 100 mL of its
saturated solution ?
(a) 28 3 10
2
.

g (b) 2 83 10
3
.

g
(c) 1 0 10
7
.

g (d) 1 0 10
4
.

g
59. A radioactive element gets spilled over the
floor of a room. Its half-life period is 30 days. If
the initial activity is ten times the permissible
value, after how many days will it be safe to
enter the room ?
(a) 1000 days (b) 300 days
(c) 10 days (d) 100 days
60. Which one of the following conformations of
cyclohexane is chiral ?
(a) Twist boat (b) Rigid
(c) Chair (d) Boat
61. Which of the following is the correct order of
decreasing S 2
N
reactivity ?
(a) R X R X R X CH C CH
2 2 3
> >
(b) R X R X R X CH CH C
2 2 3
> >
(c) R X R X R X
3 2 2
C CH CH > >
(d) R X R X R X
2 3 2
CH C CH > >
(X a halogen)
62. In the following sequence of reactions,
CH CH OH
3 2
P+I Mg
ether
HCHO 2
A B
C D
H O
2

the compound D is
(a) butanal (b) n-butyl alcohol
(c) n-propyl alcohol (d) propanal
63. Which of the following sets of quantum
numbers represents the highest energy of an
atom ?
(a) n l m s + 3 1 1 1 2 , , , /
(b) n l m s + 3 2 1 1 2 , , , /
(c) n l m s + 4 0 0 1 2 , , , /
(d) n l m s + 3 0 0 1 2 , , , /
64. Which of the following hydrogen bonds is the
strongest ?
(a) O H N K (b) F H F K
(c) O H O K (d) O H F K
65. In the reaction,
2Al 6HCl 2Al
3+
( ) ( ) ( ) s aq aq +
+ +

6Cl 3H ( ) ( ) aq g
2
(a) 6 L HCl( ) aq is consumed for every 3L H
2
( ) g
produced
(b) 33.6 L H
2
(g) is produced regardless of
temperature and pressure for every mole
Al that reacts
(c) 67.2 L H
2
( ) g at STP is produced for every
mole Al that reacts
(d) 11.2 L H
2
( ) g at STP is produced for every
mole HCl(aq) consumed
66. Regular use of which of the following fertilisers
increases the acidity of soil ?
(a) Potassium nitrate
(b) Urea
(c) Superphosphate of lime
(d) Ammonium sulphate
67. Identify the correct statement regarding a
spontaneous process
(a) For a spontaneous process in an isolated
system, the change in entropy is positive
(b) Endothermic processes are never
spontaneous
6
(c) Exothermic processes are always
spontaneous
(d) Lowering of energy in the reaction process
is the only criterion for spontaneity
68. Which of the following nuclear reactions will
generate an isotope ?
(a) Neutron particle emission
(b) Positron emission
(c) -particle emission
(d) -particle emission
69. The equivalent conductances of two strong
electrolytes at infinite dilution in H O
2
(where
ions move freely through a solution) at 25C
are given below

CH COONa
2
3
S cm /equiv 91 0 .

HCl
S cm equiv 426 2
2
. /
What additional information/quantity one
needs to calculate of an aqueous solution of
acetic acid ?
(a) of NaCl
(b) of CH COOK
3
(c) The limiting equivalent conductance of
H
H
+

+
( )
(d) of chloroacetic acid (ClCH COOH)
2

70. Which one of the following is the strongest
base in aqueous solution ?
(a) Trimethylamine (b) Aniline
(c) Dimethylamine (d) Methylamine
71. The compound formed as a result of oxidation
of ethyl benzene by KMnO
4
is
(a) benzophenone (b) acetophenone
(c) benzoic acid (d) benzyl alcohol
72. The IUPAC name of is
(a) 1, 1-diethyl-2, 2-dimethylpentane
(b) 4, 4-dimethyl-5, 5-diethylpentane
(c) 5, 5-diethyl-4, 4-dimethylpentane
(d) 3-ethyl-4, 4-dimethylheptane
73. Which of the fol low ing spe cies ex hib its the
dia mag netic be hav iour ?
(a) O
2
2
(b) O
2
+
(c) O
2
(d) NO
74. The stability of dihalides of Si, Ge, Sn and Pb
increases steadily in the sequence
(a) Ge Si Sn Pb
2 2 2 2
X X X X < < <
(b) Si Ge Pb Sn
2 2 2 2
X X X X < < <
(c) Si Ge Sn Pb
2 2 2 2
X X X X < < <
(d) Pb Sn Ge Si
2 2 2 2
X X X X < < <
75. Identify the incorrect statement among the
following
(a) Ozone reacts with SO
2
to give SO
3
(b) Silicon reacts with NaOH( ) aq in the
presence of air to give Na SiO
2 3
and H O
2
(c) Cl
2
reacts with excess of NH
3
to give N
2
and HCl
(d) Br
2
reacts with hot and strong NaOH
solution to give NaBr, NaBrO
3
and H O
2
76. The charge/size ra tio of a cat ion de ter mines its
po lar iz ing power. Which one of the fol low ing
se quences rep re sents the in creas ing or der of
the po lar iz ing power of the cationic spe cies,
K
+
, Ca
2+
, Mg
2+
, Be
2+
?
(a) Mg < Be < K <Ca
2+ 2+ + 2+
(b) Be < K <Ca < Mg
2+ + 2+ 2+
(c) K <Ca < Mg < Be
+ 2+ 2+ 2+
(d) Ca < Mg < Be < K
2+ 2+ 2+ +
77. The den sity (in g mL
1
) of a 3.60 M sulphuric
acid so lu tion that is 29% H SO
2 4
(mo lar mass
98 g mol
1
) by mass will be
(a) 1.64 (b) 1.88
(c) 1.22 (d) 1.45
78. The first and sec ond dis so ci a tion con stants of
an acid H
2
A are 1.0 10
5
and 5 0 10
10
.

re spec tively. The over all dis so ci a tion con stant
of the acid will be
(a) 5 0 10
5
.

(b) 5 0 10
15
.
(c) 5 0 10
15
.

(d) 0 2 10
5
.
79. A mix ture of ethyl al co hol and propyl al co hol
has a vapour pres sure of 290 mm at 300 K. The
vapour pres sure of propyl al co hol is 200 mm. If
the mole frac tion of ethyl al co hol is 0.6, its
vapour pres sure (in mm) at the same
tem per a ture will be
(a) 350 (b) 300
(c) 700 (d) 360
80. In conversion of limestone to lime,
CaCO CaO CO
3 2
( ) ( ) ( ) s s g +
the values of H and S are +179.1 kJ mol
1
and 160.2 J/K respectively at 298 K and 1 bar.
Assuming that H and S do not change with
temperature, temperature above which
conversion of limestone to lime will be
spontaneous is
(a) 1008 K (b) 1200 K
(c) 845 K (d) 1118 K
7
81. In a geo met ric pro gres sion con sist ing of
pos i tive terms, each term equals the sum of the
next two terms. Then the com mon ra tio of this
pro gres sion equals
(a)
1
2
1 5 ( ) (b)
1
2
5
(c) 5 (d)
1
2
5 1 ( )
82. If sin

_
,

_
,

1 1
5
5
4 2
x
cosec

, then a value of
x is
(a) 1 (b) 3
(c) 4 (d) 5
83. In the bi no mial ex pan sion of ( ) a b
n
, n 5, the
sum of 5th and 6th terms is zero, then
a
b
equals
(a)
5
4 n
(b)
6
5 n
(c)
n 5
6
(d)
n 4
5
84. The set S : { , , , . . . , } 1 2 3 12 is to be
partitioned into three sets A B C , , of equal size.
Thus, A B C S ,
A B B C A C .
The number of ways to partition S is
(a) 12!/3! ( !) 4
3
(b) 12!/3!( !) 3
4
(c) 12!/( !) 4
3
(d) 12!/( !) 3
4
85. The larg est in ter val ly ing in

_
,

2 2
, for which
the func tion
f x
x
x
x
( ) cos log(cos ) +

_
,

1
]
1

4
2
1
2
1
is defined, is
(a) [ , ] 0 (b)

_
,

2 2
,
(c)

_
,

4 2
, (d) 0
2
,

_
,

86. A body weighing 13 kg is suspended by two

strings 5 m and 12 m long, their other ends
being fastened to the extremities of a rod 13 m
long. If the rod be so held that the body hangs
immediately below the middle point. The
tensions in the strings are
(a) 12 kg and 13 kg (b) 5 kg and 5 kg
(c) 5 kg and 12 kg (d) 5 kg and 13 kg
87. A pair of fair dice is thrown independently
three times. The probability of getting a score
of exactly 9 twice is
(a) 1/729 (b) 8/9
(c) 8/729 (d) 8/243
88. Con sider a fam ily of cir cles which are pass ing
through the point (1, 1) and are tan gent to
x-axis. If ( , ) h k are the co or di nates of the cen tre
of the cir cles, then the set of val ues of k is given
by the in ter val
(a) 0 1 2 < < k / (b) k 1 2 /
(c) 1 2 1 2 / / k (d) k 1 2 /
89. Let L be the line of in ter sec tion of the planes
2 3 1 x y z + + and x y z + + 3 2 2. If L
makes an an gle with the pos i tive x-axis, then
cos equals
(a) 1 3 / (b) 1 2 /
(c) 1 (d) 1 2 /
90. The dif fer en tial equa tion of all cir cles pass ing
through the or i gin and hav ing their cen tres on
the x-axis is
(a) x y xy
dy
dx
2 2
+
(b) x y xy
dy
dx
2 2
3 +
(c) y x xy
dy
dx
2 2
2 +
(d) y x xy
dy
dx
2 2
2
91. If p and q are pos i tive real num bers such that
p q
2 2
1 + , then the max i mum value of ( ) p q +
is
(a) 2 (b)
1
2
(c)
1
2
(d) 2
92. A tower stands at the cen tre of a cir cu lar park.
A and B are two points on the bound ary of the
park such that A B a ( ) sub tends an an gle of
60 at the foot of the tower and the an gle of
el e va tion of the top of the tower from A or B is
30. The height of the tower is
(a)
2
3
a
(b) 2 3 a
(c)
a
3
(d) a 3
8
Mathematics
93. The sum of the series
20
0
20
1
20
2
20
3
20
10
C C C C C + + + K K is
(a)
20
10
C (b)
1
2
20
10
C
(c) 0 (d)
20
10
C
94. The nor mal to a curve at P x y ( , ) meets the
x-axis at G. If the dis tance of G from the or i gin
is twice the ab scissa of P, then the curve is a
(a) ellipse (b) parabola
(c) circle (d) hyperbola
95. If | | z + 4 3, then the maximum value of
| | z + 1 is
(a) 4 (b) 10
(c) 6 (d) 0
96. The re sul tant of two forces P N and 3 N is a
force of 7 N. If the di rec tion of the 3 N force
were re versed, the re sul tant would be 19 N.
The value of P is
(a) 5 N (b) 6 N
(c) 3 N (d) 4 N
97. Two aeroplanes I and II bomb a target in
succession. The probabilities of I and II scoring
a hit correctly are 0.3 and 0.2, respectively. The
second plane will bomb only if the first misses
the target. The probability that the target is hit
by the second plane is
(a) 0.06 (b) 0.14
(c) 0.2 (d) 0.7
98. If D x
y
+
+
|
|
|
|
|
|
1
1
1
1
1
1
1
1
1
for x y 0 0 , , then
D is
(a) divisible by neither x nor y
(b) divisible by both x and y
(c) divisible by x but not y
(d) divisible by y but not x
99. For the hy per bola
x y
2
2
2
2
1
cos sin
, which of
the fol low ing re mains con stant when var ies ?
(a) Eccentricity
(b) Directrix
(c) Abscissae of vertices
(d) Abscissae of foci
100. If a line makes an an gle of

4
with the pos i tive
di rec tions of each of x-axis and y-axis, then the
an gle that the line makes with the pos i tive
di rec tion of the z-axis is
(a)

6
(b)

3
(c)

4
(d)

2
101. A value of C for which the con clu sion of Mean
Value The o rem holds for the func tion
f x x
e
( ) log on the in ter val [1, 3] is
(a) 2
3
log e (b)
1
2
3 log
e
(c) log
3
e (d) log
e
3
102. The func tion f x x x ( ) tan (sin cos ) +
1
is an
in creas ing func tion in
(a) ( / , / ) 4 2 (b) ( / , / ) 2 4
(c) ( , / ) 0 2 (d) ( / , / ) 2 2
103. Let A

1
]
1
1
5
0
0
5
0
5
5

If | | A
2
25 , then | | equals
(a) 5
2
(b) 1
(c)
1
5
(d) 5
104. The sum of the se ries
1
2
1
3
1
4 ! ! !
+ K upto
in fin ity is
(a) e
2
(b) e
1
(c) e

1
2
(d) e
+
1
2
105. If
$
u and
$
v are unit vec tors and is the acute
an gle be tween them, then 2 3
$ $
u v is a unit
vec tor for
(a) exactly two values of
(b) more than two values of
(c) no value of
(d) exactly one value of
106. A par ti cle just clears a wall of height b at a
dis tance a and strikes the ground at a dis tance c
from the point of pro jec tion. The an gle of
pro jec tion is
(a) tan
1
b
ac
(b) 45
(c) tan
( )

1
bc
a c a
(d) tan
1
bc
a
107. The average marks of boys in a class is 52 and
that of girls is 42. The average marks of boys
and girls combined is 50. The percentage of
boys in the class is
(a) 40 (b) 20
(c) 80 (d) 60
9
108. The equation of a tangent to the parabola
y x
2
8 is y x + 2 . The point on this line
from which the other tangent to the parabola is
perpendicular to the given tangent is
(a) ( , ) 1 1 (b) (0, 2)
(c) (2, 4) (d) ( , ) 2 0
109. If (2, 3, 5) is one end of a diameter of the
sphere x y z x y z
2 2 2
6 12 2 + + + 20 0,
then the coordinates of the other end of the
diameter are
(a) ( , , ) 4 9 3 (b) (4, 3, 3)
(c) (4, 3, 5) (d) (4, 3, 3)
110. Let a i j k b i j k

+ + +
$ $ $
,
$ $ $
2 and
c i j k

+ x x
$
( )
$ $
2 . If the vector c

lies in the
plane of a

and b

, then x equals
(a) 0 (b) 1
(c) 4 (d) 2
111. Let A h k ( , ), B( , ) 1 1 and C( , ) 2 1 be the vertices of
a right angled triangle with AC as its
hypotenuse. If the area of the triangle is 1, then
the set of values which k can take is given by
(a) { , } 1 3 (b) {0, 2}
(c) {1, 3} (d) {3, 2}
112. Let P Q ( , ), ( , ) 1 0 0 0 and R ( , ) 3 3 3 be
three points. The equation of the bisector of the
angle PQR is
(a) 3 0 x y + (b) x y +
3
2
0
(c)
3
2
0 x y + (d) x y + 3 0
113. If one of the lines of
my m xy mx
2 2 2
1 0 + ( ) is a bisector of the
angle between the lines xy 0, then m is
(a)
1
2
(b) 2
(c) 1 (d) 2
114. Let F x f x f
x
( ) ( ) +

_
,

1
, where
f x
t
t
dt
x
( )
log
.
+

1
1
Then F e ( ) equals
(a)
1
2
(b) 0
(c) 1 (d) 2
115. Let f R R : be a function defined by
f x x x ( ) min { ,| | } + + 1 1 . Then which of the
following is true ?
(a) f x ( ) 1 for all x R
(b) f x ( ) is not differentiable at x 1
(c) f x ( ) is differentiable everywhere
(d) f x ( ) is not differentiable at x 0
116. The function f R R : /{ } 0 given by
f x
x e
x
( )

1 2
1
2
can be made continuous at x 0 by defining
f ( ) 0 as
(a) 2 (b) 1
(c) 0 (d) 1
117. The solution for x of the equation
2 2
1
2
x
dt
t t

is
(a) 2 (b)
(c) 3 2 / (d) 2 2
118.

+
dx
x x cos sin 3
equals
(a)
1
2 2 12
log tan
x
c +

_
,

(b)
1
2 2 12
log tan
x
c

_
,

(c) log tan

x
c
2 12
+

_
,

(d) log tan

x
c
2 12

_
,

119. The area enclosed between the curves y x

2

and y x | | is
(a)
2
3
sq unit (b) 1 sq unit
(c)
1
6
sq unit (d)
1
3
sq unit
120. If the difference between the roots of the
equation x ax
2
1 0 + + is less than 5, then
the set of possible values of a is
(a) ( , ) 3 3 (b) ( , ) 3
(c) ( , ) 3 (d) ( , ) 3
10
11
Answers
PHYSICS
1. (a) 2. (b) 3. (b) 4. (d) 5. (d) 6. (c) 7. (c) 8. (b)
9. (b) 10. (d) 11. (d) 12. (b) 13. (c) 14. (d) 15. (d) 16. (b)
17. (b) 18. (d) 19. (a) 20. (d) 21. (c) 22. (c) 23. (b) 24. (c)
25. (d) 26. (a) 27. (a) 28. (b) 29. (c) 30. (d) 31. (a) 32. (a)
33. (a) 34. (c) 35. (a) 36. (c) 37. (d) 38. (d) 39. (a) 40. (a)
CHEMISTRY
41. (d) 42. (c) 43. (c) 44. (a) 45. (d) 46. (d) 47. (a) 48. (a)
49. (a) 50. (d) 51. (c) 52. (d) 53. (b) 54. (d) 55. (c) 56. (d)
57. (c) 58. (b) 59. (d) 60. (c) 61. (b) 62. (c) 63. (b) 64. (b)
65. (d) 66. (d) 67. (a) 68. (a) 69. (a) 70. (c) 71. (c) 72. (d)
73. (a) 74. (c) 75. (d) 76. (c) 77. (c) 78. (c) 79. (a) 80. (d)
MATHEMATICS
81. (d) 82. (b) 83. (d) 84. (c) 85. (d) 86. (c) 87. (d) 88. (b)
89. (a) 90. (c) 91. (d) 92. (c) 93. (b) 94. (a,d) 95. (c) 96. (a)
97. (*) 98. (b) 99. (d) 100. (d) 101. (a) 102. (b) 103. (c) 104. (b)
105. (d) 106. (c) 107. (c) 108. (d) 109. (a) 110. (d) 111. (c) 112. (a)
113. (c) 114. (a) 115. (c) 116. (d) 117. (*) 118. (a) 119. (c) 120. (a)
Note. None of the option is match (*).
1. x t

( )cos 2 10
2

Here, a

2 10
2
m 2 cm
At t 0, x 2 cm, i.e., the object is at positive
extreme, so to acquire maximum speed (ie, to
reach mean position) it takes
1
4
th of time
period.
Required time
T
4
where


2
T
T 2s
So, required time
T
4
2
4
0 5 . s
2. For given circuit current is lagging the voltage
by /2, so circuit is purely inductive and there
is no power consumption in the circuit. The
work done by battery is stored as magnetic
energy in the inductor.
3. Potential at A due to charge at O
V
OA
A

1 10
0
3

( )

1
4
10
2 2 0
3
2 2

( )
( ) ( )
Potential at B due to charge at O
V
OB
B

1
4
10
0
3

( )

1
4
10
2
0
3

( )
So, V V
A B
0
4. Ratio of energy stored in the capacitor and the
work done by the battery

1
2
1
2
qV
qV
5. Rise of current in L-R circuit is given by
I I e
t


0
1 ( )
/
where I
E
R
0

5
5
1 A
Now,
L
R
10
5
2s
After 2s, ie, at t 2s
Rise of current I e

( ) 1
1
A
6. Current density J
i
a

2
From Amperes circuital law
B dl i

0 enclosed
For r a <
B r J r 2
0
2

B
i
a
r

0
2
2
At r a /2 B
i
a
1
0
4

For r a >
B r i B
i
r
2
2
0
0

At r a 2 , B
i
a
2
0
4

So,
B
B
1
2
1
7. Using Amperes circuital law the magnetic field
at any point inside the pipe is zero.
8. Binding energy
BE
nucleus nucleons
( ) M M c
2
( ) M M M c
O p n
8 9
2
12
r
a
10H 5
5V
Y
B
A
X
(0,0)
(2,0)
3
10 c
O
2, 2 ) )
Hints & Solutions
Physics
9. In gamma ray emis sion the en ergy is re leased
from nu cleus, so that nu cleus get sta bi lised.
10. For V
i
< 0
the diode is reverse biased and hence offer
infinite resistance, so circuit would be like as
shown in Fig. (2) and V
o
0.
For V
i
> 0, the diode is forward biased and
circuit would be as shown in Fig. (3) and
V V
o i
.
Hence, the opitcal (d) is correct.
11. The momentum of the photon
p
h h
c

12. + + v gt ft
0
2
or
dx
dt
v gt ft + +
0
2
dx v gt ft dt + + ( )
0
2
So,
0 0
1
0
2
x
dx v gt ft dt

+ + ( )
x v g f + +
0
2 3 / /
13. Let the each side of square lamina is d.
So, I I
EF GH
(due to symmetry)
and I I
AC BD
(due to symmetry)
Now, according to theorem of perpendicular
axis,
I I I
AC BD
+
0
2
0
I I
AC
(i)
and I I I
EF GH
+
0

2
0
I I
EF
(ii)
From Eqs. (i) and (ii), we get I I
AC EF

I I
md
AD EF
+
2
4
+
md md
2 2
12 4
as I
md
EF

_
,

2
12
So, I
md
I
AD EF

2
3
4
14. x x t
0
4 cos( / )
Acceleration, a
d x
dt

2
2

_
,

2
0
3
4
x t cos
+

_
,

2
0
3
4
x t cos
So, A x
2
0
and

3
4
15. Direction of E

reverses while magnitude

remains same and V remains unchanged.
16. T X Y
1 2 /
( ) ( )

0 693 1 .

X Y



Y
X

0 693 .

Y X
>
So, Y will decay faster than X.
17. For Carnot engine using as refrigerator
W Q
T
T

_
,

2
1
2
1
It is given
1
10
1
2
1
T
T

T
T
2
1
9
10

So, Q
2
90 J (as W 10 J)
18. The number of free electrons for conduction is
significant only in Si and Ge but small in C, as C
is an impurity.
13
V
i
V
o
Fig. (2)
V
i
V
o
Fig. (3)
5V
5V
R
L
V
i
V
o
Fig. (1)
D
G
A
E
B
H
C
F
d
O
19. As v

of charged particle is remaining constant,

it means force acting on charged particle is
zero.
So, q q ( ) v B E


v B E


v
E B

B
2
20. E i j k

V
x
V
y
V
z
$ $ $
E
V
x
x

1
]
1
d
dx x
20
4
2

40
4
2 2
x
x ( )
E
x
at x 4
10
9
m V/m
and is along positive x direction.
21. Emission spectrum would be when electron
makes a jump from higher energy level to
lower energy level.
Frequency of emitted photon is proportional to
change in energy of two energy levels, i.e.,

_
,

RcZ
n n
2
1
2
2
2
1 1
22. Acceleration of system, a
F
m M

+
So, force acting on mass m ma

+
mF
m M
23. Power of a lens is reciprocal of its focal length.
Power of combined lens is
P P P +
1 2
+ 15 5 10 D
f
P

1 100
10
cm
f 10 cm
24. Let temperature at the interface is T.
For part AB,
Q
t
T T K
l
1 1 1
1

( )
For part BC,
Q
t
T T K
l
2 2 2
2

( )
At equilibrium,
Q
t
Q
t
1 2

( ) ( ) T T K
l
T T K
l
1 1
1
2 2
2

T
T K l T K l
K l K l

+
+
1 1 2 2 2 1
1 2 2 1

25. Let intensity of sound be I and I.
Loudness of sound initially

1
0
10

_
,
log
I
I
Later,
2
0
10

_
,
log
I
I
Given,
2 1
20
20 10

_
,

log
I
I

I I 100
26. According to Mayers relation,
C C
R
m
R
p V

28
27. In case of motion of a charged particle
perpendicular to the motion, i.e.,
displacement, the work done
W Fds


F ds cos 0 (as 90 )
and by work-energy theorem, W KE, the
kinetic energy and hence speed v remains
constant. But v

changes, so, momentum changes.

28. The magnetic field induction at a point P, at a
distance d from O in a direction perpendicular
to the plane ABCD due to currents through AOB
and COD are perpendicular to each other, is
14
m M
k
F
T
1
l
1
l
2
T
2
K
1
K
2
A
B
C
T C
A
P
D
B
d
I
1
I
2
O
Hence, B B B +
1
2
2
2

_
,

_
,

1
]
1

0 1
2
0 2
2
1 2
4
2
4
2 I
d
I
d
/
+

0
1
2
2
2
2 d
I I ( )
29. From R R t
t
+
0
1 ( )
5 1 50
0
+ R ( ) (i)
and 6 1 100
0
+ R ( ) (ii)

5
6
1 50
1 100
1
200

+
+

Putting value of in Eq (i), we get
5 1 50 1 200
0
+ R ( / )
R
0
4
30. On in tro duc tion and re moval and again on
in tro duc tion, the ca pac ity and po ten tial re main
same. So, net work done by the sys tem in this
process
W U U
f i


1
2
1
2
2 2
C V C V
0
31. According to Millikans oil drop experiment,
electronic charge is given by,
q
r v v
E

+ 6
1 2
( )
which is independent of g.
So,
electronic charge on the moon
electronic charge on the earth
1
32. In this question distance
of centre of mass of new
disc from the centre of
mass of remaining disc is
R.
Mass of remaining disc
M
M M
4
3
4
+
3
4 4
0
M
R
M
R

1
3
NOTE In Q.No. 32, the given distance must be R for real
approach to the solution.
33. Assuming that no energy is used up against
friction, the loss in potential energy is equal to
the total gain in the kinetic energy.
Thus, Mgh I v R Mv +
1
2
1
2
2 2 2
( / )
or
1
2
2 2
v M I R Mgh ( / ) +
or v
Mgh
M I R
gh
I MR
2
2 2
2 2
1

+

+ / /
If s be the distance covered along the plane,
then
h s sin
v
gs
I MR
2
2
2
1

+
sin
/

Now, v as
2
2
2
2
1
2
as
gs
I MR

+
sin
/

or a
g
I MR

+
sin
/

1
2
34. Ac cord ing to the prin ci ple of con ser va tion of
an gu lar mo men tum, in the ab sence of ex ter nal
torque, the to tal an gu lar mo men tum of the
sys tem is constant.
35. a
F
m
k

15
2
7 5 . m/s
2
Now, ma kx
1
2
2
or 2 7 5
1
2
10000
2
. x
or x
2 3
3 10

or x 0 055 . m
x 5 5 . cm
36. Kinetic energy at highest point
(KE)
H
mv
1
2
2 2
cos
K cos
2

K(cos ) 60
2

K
4

15
h

C
s
C
3
v
R
O
O
1
O
2
R
37. Phase difference
2

path difference
i e,
2
6

3

As, I I
max
cos ( / )
2
2
or
I
I
max
cos ( / )
2
2
or
I
I
0
2
6

_
,

cos

3
4
38. f
k k
m

+ 1
2
1 2

and f
k k
m
f
+

1
2
2 2
1 2

39. From first law of thermodynamics,

Q U W +
For path iaf ,
50 20 + U
U U U
f i
30 cal
For path ibf ,
Q U W +
or W Q U
36 30 6 cal
40. Average kinetic energy of particle

1
4
2 2
ma

1
4
2
2 2
ma ( )

2 2 2
ma
41. A B AB
2 2
+ 2 a
E
a
( ) forward kJ mol
1
180
E
a
(backward) 200 kJ mol
1
In the presence of catalyst :
E
a
(forward) 180 100 80 kJ mol
1
E
a
(backward) 200 100 100 kJ mol
1
H E
a
(forward) E
a
(backward)
80 100
20 kJ mol
1
42. Cell is completely discharged, it means
equilibrium gets established, E
cell
0
Zn/Zn (1M)||Cu (1M)|Cu
2+ 2+
cell reaction : Zn +Cu Zn +Cu
2+ 2+
a
K
eq

[Zn ]
[Cu
2+
2+
]
We know,
E E
n
K
eq cell cell

0 0591 .
log
E
n
K
eq

cell
0 0591 .
log
or 1 10
0 0591
2
.
.
log K
eq
K
eq

[Zn ]
[Cu ]
=antilog
2+
2+
2 20
0 0591
.
.
antilog 37.3
43. Aqueous buffered solution of H A
50% H A is ionised
[H ] [ A A

]
Buffer solution of weak acid H A acidic
buffer
pH=p + log
[ ]
[H ]

K
A
A
a
or pH p K
a
4 5 .
pOH p pH K
w

pOH 14 4 5 9 5 . .
44. 2 A B + products
[B] is doubled, half-life didnt change
Half-life is independent of change in conc.
of reactant First order
First order w.r.t. to B
[A] is doubled, rate increased by two times
First order w.r.t A
Hence, net order of reaction + 1 1 2
Unit for the rate constant conc.
( ) 1 1 n
t


( )

mol L s
1 1 1
L mol s
1 1
45. 4 f and 5f belongs to different shell, experience
different amount of shielding.
46. Cl

is a weak ligand but Cl

cause the pairing of

electron with large Pt
2+
and consequently give
dsp
2
hybridisation and square planar geometry.
16
Chemistry
47. The molecule, which is optically active, has
chiral centre, is expected to rotate the plane of
polarised light.
One chiral centre optically active
Two chiral centres, but plane of symmetry
within molecule optically inactive
48. Primary structure involves sequence of -amino
acids polypeptide chain.
Secondary structure involves -helical and
-pleated sheet like structures.
49. CH C CH+ HBr CH C
Br
==CH
3 3 2

|

|
|

HBr
+
Rearrangement
3 2
H C CH
Br
CH
|
+
CH C
Br
Br
CH CH C
Br
CH
3 3
Br
3
+
dibromopropane

|
|

|

2 2 ,
3
more stable
carbocation

CH CH==CHBr
3

HBr
3 2 2
CH CH CHBr
CH CH CH CHBr
2HBr
3 2

CH CH==CH CH CHBr CH
3 2
HBr
3 3

50. CH CH NH +CHCl + KOH 3H O
3 2 2 3 2
+ + A B
CHCl + KOH CCl + KCl + H O
3 2 2

CH CH NH + CCl CH CH NC + 2HCl
3 2 2 2 3 2
carbylamine

51.
52.
NO
2
group withdraw electron from the ring,
shows M effect makes ring electron deficient,
thus, deactivates ring for electrophilic
substitution.
53. NO NO
+

(NO)
+
Total e

14
1 1 2 2 2
2 2 2 2 1 1
s s s s p
x
* * +

+
2 2
1 1 2
p p
y z

Diamagnetic
Bond order

10 4
2
3
(NO) Total e

15
1 1 2 2
2 2 2 2
s s s s
* *
, 2 2 2
2 1 1 1 1
p p p
z x y
+ +

*
2 2
1
p p
x y

Paramagnetic
Bond order

10 5
2
2 5 .
Electron is taken away from non-bonding
molecular orbital, thats why bond order
increases.
54. The actinoid (5f-elements) exhibits more
number of oxidation states in general than the
lanthanoid because 5f-orbitals extend farther
from the nucleus than the 4 f -orbitals.
55. Suppose the equal mass of methane and
oxygen w 1 g
Mole fraction of oxygen
+
w
w w
/
/ /
32
32 16

1
32
3 32
1
3 /
Let the total pressure p
17
H N
2
H
Ph Ph
H
NH
2
HO
CHO
*
H
CH OH
2
N
+
O
O

Cl FeCl
2, 3
+
(Cl )
CH
3
Cl
CH
3
Cl
CH
3
toluene p-chloro toluene
o-chloro toluene
+
chlorination
electrophilic
substitution
Pressure exerted by oxygen (partial pressure)
X P
O total
2
P
1
3
56. Solution is isotonic.
C RT C RT
1 2

C C
1 2

Density of both the solutions are assumed to be

equal to 1.0 g cm
3
molality molarity
5.25%
in 100 g 5.25 g of substance therefore, in
1000 g 52.5 g of substance
Hence,
52 5 15
60
.
M
,
M molecular mass of the substance
M

52 5 60
15
210
.
57. H O H O( )
2 2
( ) l g
n 1 0 1
E H nRT


41 1 8 3 373 10 8 3 10
3 3
. ( . ) R
37 9 . kJ mol
1
58. AgIO Ag IO
3 3
( ) ( ) ( ) s aq aq a
+
+
Let solubility of AgIO
3
be S
K
sp
[Ag ][IO ]
+
3

1 0 10
8 2
.

S or S

1 10
4
mol/L
In 1000 mL mol of AgIO
3
dissolved


1 10
4
mol
In 100 mL of mole of AgIO
3
dissolved


1 10
5
mol
Mass of AgIO
3
in 100 mL

1 10 283
5


2 83 10
3
.
59. Activity N
N
N
n
0
1
2

_
,

or
1
10
1
2

_
,

n
or 10 2
n
Taking log on both sides
log log 10 2 n
n
1
0 301
3 32
.
.
time n half-life
3 32 30 . 99 6 . days
60.
Chair form is unsymmetrical and absence of
any element of symmetry.
61. S 2
N
reactions are greatly controlled by steric
factor.
R X

CH
2
1
> R X
2
2
CH

> R X
3
3
C

S 2
N
reactivity decreases as bulkyness of alkyl
group increases.
62.
63. n l + 5 maximum.
64. Hydrogen bond is strongest in HF due to higher
electronegativity of F.
65. 2Al 6HCl 2Al Cl
mol
( ) ( ) ( ) ( ) s aq aq aq + +
+
6
3
6
+

3H
22.4 L
2
3
( ) g
3
2
22.4 L H ( ) g at STP is produced for 6 mole
HCl
hence, 11.2 L H
2
( ) g at STP is produced for
1 mole HCl
66. (NH ) SO 2NH SO
4 2 4
+
4
4
2
acidic
+
67. In an isolated system where either mass and
energy are not exchanged with surrounding for
the spontaneous process, the change in entropy
is positive.
68.
Z
A
Z
A
X X n +
1
0
1
Isotopes are species having same number of
proton, but different number of neutron.
69. We know from Kohlrauschs law
+
CH COOH CH COONa HCl NaCl
3 3

70. In aqueous solution, basicity order :

Dimethylamine> methylamine
2 1
> trimethylamine> aniline
3
18
CH CH OH
3 2
CH CH
3 2
__ __
CH CH CH
3 2 2
CH CH CH + Mg(OH)I
3 2 2
OMgI
OH
O
CH CH MgI
3 2
__
I
P + I
2
A
B C
D
n-propyl alcohol
H O
2
Mg, ether
__ __
H C H
71. Any aliphatic carbon with hydrogen attached
to it, in combination with benzene ring, will be
oxidised to benzoic acid by KMnO /H
4
+
.
72.
73. The correct option is O
2
2
. This species has 18
electrons, which are filled in such a way that all
molecular orbitals are fully filled, so
diamagnetic.
1 1 2 2
2 2 2 2
s s s s
* *
, 2
2
p
z
, 2 2
2 2
p p
x y
,

* *
2 2
2 2
p p
x y

74. Due to inert pair effect, the stability of +2

oxidation state increases as we move down this
group.
Si <Ge <Sn < Pb
2 2 2 2
X X X X
75. Br
2
reacts with hot and strong NaOH to give
NaBr, NaBrO
3
and H O
2
.
6NaOH + 3Br 5NaBr + NaBrO
conc. and hot
2 3

+ 3H O
2
76. Higher the charge/size ratio, more is the
polarising power.
K <Ca < Mg < Be
+ 2+ 2+ 2+
77. Molarity =
10 density wt. of solute
mol. wt. of the solute

density

3 60 98
10 29
1 21
.
.
78. K k k
1 2


1 0 10 5 0 10
5 10
. .


5 10
15
79. According to Raoults law :
P P X P X
A A B B
+
290 200 0 4 0 6 + . . P
B
P
B
350
80.

S
H
T

S 160 2 . J/ K
H J Mol 179 1 10
3
. /
T
179 1 10
160 2
3
.
.
J/ Mol
J/K
1117 97 1118 . K K
1118 K.
81. Since, each term is equal to the sum of the next
two terms.
ar ar ar
n n n +
+
1 1
1
2
+ r r r r
2
1 0 +
r
5 1
2
Q r

_
,

5 1
2
82. Since, sin

_
,

_
,

1 1
5
5
4 2
x
cosec

sin sin

_
,

_
,

1 1
5
4
5 2
x
sin sin

_
,

_
,

1 1
5 2
4
5
x
sin cos

_
,

_
,

1 1
5
4
5
x

sin sin

_
,

_
,

1 1
5
3
5
x

x 3.
83. Since, in binomial expansion of ( ) a b
n
, n 5,
the sum of fifth and sixth term is equal to zero.

n n n n
C a b C a
4
4 4
5
5 5
5 0

+ ( ) ( )

n
n
a b
n
n
a b
n n
!
( )! !
!
( )! !

4 4 5 5
0
4 4 5 5

n
n
a b
a
n
b
n
!
( )! !

_
,

5 4 4 5
0
5 4

a
b
n

4
5
.
84. Required number of ways
12
4
8
4
4
4
C C C

12
8 4
8
4 4
1
!
! !
!
! !

12
4
3
!
( !)
.
85. 4
2
x
is defined for

_
,

2 2
, .
cos

_
,

1
2
1
x
is defined if 1
2
1 1
x
.
19
7
6
5
4
3
2
1
3-ethyl-4, 4-dimethylheptane
Mathematics
0
2
2
x
0 4 x
and log (cos ) x is defined, if cos x > 0
< <

2 2
x
Hence,
f x
x
x
x
( ) cos log (cos ) +

_
,

+

4
2
1
2
1
is defined, if x

_
,

0
2
, .

86. Since, OC CA CB
AOC OAC and COB OBC
sin sin A
5
13
and cos
12
13
Now by Lamis theorem
T T
1 2
180 90 sin ( ) sin ( )

+

T T
1 2
sin cos

T T
1 2
cos sin
T T
1 2
12
13
5
13

_
,

_
,

T T
1 2
5
12

_
,

.
Also, T T
1 2
13 sin cos +
T
2
5
12
5
13
12
13
13 +

_
,

T
2
169
12 13
13

_
,

T T
2 1
12 5 kg and kg.
87. Prob a bil ity of get ting score 9 in a sin gle throw

4
36
1
9
.
Probability of getting score 9 exactly twice

_
,

3
2
2
1
9
8
9
8
243
C .
88. Equa tion of cir cle which touches x-axis and
coordinates of centre are ( , ), h k is
( ) ( ) x h y k k +
2 2 2
Q It is passing through ( 1, 1), then
( ) ( ) + 1 1
2 2 2
h k k
h h k
2
2 2 2 0 + +
Since, h is real, therefore
D 0
2 1 0
1
2
k k .
89. If di rec tion co sines of L be l, m, n, then
2 3 0 l m n + + K(i)
and l m n + + 3 2 0 K(ii)
On solving Eqs. (i) and (ii), we get
l m n
3 3 3

l m n : : : :

_
,

1
3
1
3
1
3
l
1
3
cos .
1
3
90. Gen eral equa tion of all such cir cles which pass
through the origin and whose centre lie on
x-axis, is
x y gx
2 2
2 0 + + . K(i)
On differentiating w.r.t. x, we get
2 2 2 0 x y
dy
dx
g + +
2 2 2 g x y
dy
dx
+

_
,

On putting the value of 2g in Eq. (i), we get

x y x y
dy
dx
x
2 2
2 2 0 + +

_
,

x y x xy
dy
dx
2 2 2
2 2 0 +
y x xy
dy
dx
2 2
2 +
Which is required equation.
91. Using AM GM,

p q
pq
2 2
2
+

pq
1
2
(Q p q
2 2
1 + )
20
/2

/2

T
2
T
1
5 m
12 m
T sin
2
O T cos
1
13 kg
A
C
B
1
3
m
Now ( ) p q p q pq + + +
2 2 2
2
( ) p q pq + +
2
1 2
( ) p q + +
2
1 1
p q + 2 .
92. Let h be the height of a tower,
Q AOB 60
OAB is equi lat eral.
OA OB AB a
Now in OAC,
tan 30
h
a

1
3

h
a
h
a

3
.
93. We know that
( ) . . . 1
20 20
0
20
1
20
10
10
+ + + + + x C C x C x
. . . +
20
20
20
C x
On putting x 1, we get
0
20
0
20
1
20
9
20
10
20
11
+ + + C C C C C . .
. . .+
20
20
C
0
20
0
20
1
20
9
20
10
+ + C C C C . . .
+ +
20
9
20
0
C C . . .
0 2
20
0
20
1
20
9
20
10
+ + ( . . . . . ) C C C C

20
10
20
0
20
1
20
10
2 C C C C + + ( . . . )

20
0
20
1
20
10
20
10
1
2
C C C C + + . . . . .
94. Equa tion of nor mal is Y y
dx
dy
X x ( )
G x y
dy
dx
+

_
,

, 0
According to question
x y
dy
dx
x + 2
y
dy
dx
x or y
dy
dx
x 3
y dy x dx or y dy x dx 3

y x
c
2 2
2 2
+ or
y x
c
2 2
2
3
2
+
x y c
2 2
2 or 3 2
2 2
x y c + .
95. From the Ar gand di a gram max i mum value of
| | z + 1 is 6.
Alternative
| | | | | | | | z z z + + + + 1 4 3 4 3 6
Thus maximum value of | | z + 1 is 6.
96. 7 3 2 3
2 2 2
+ + P P cos ... (i)
and ( ) ( ) ( ) cos 19 3 2 3
2 2 2
+ + P P
...(ii)
On adding Eqs. (i) and (ii), we get
68 2 18 5
2
+ P P N
97. The de sired prob a bil ity
= (0.7) (0.2) + (0.7) (0.8) (0.7) (0.2) +
(0.7) (0.8) (0.7) (0.8) (0.7) (0.2) + .....
+ + + 0 14 1 0 56 0 56
2
. [ ( . ) ( . ) . . . . ]

_
,
0 14
1
1 0 56
0 14
0 44
7
22
0 32 .
.
.
.
. .
From above it is clear that no option is correct.
98. Given, D x
y
+
+
1 1 1
1 1 1
1 1 1

Applying C C C C C C
2 2 1 3 3 1
and

1 0 0
1 0
1 0
x
y
xy .
Hence, D is divisible by both x and y.
99. The given equation of hyperbola is
x y
2
2
2
2
1
cos sin
.

Here, a
2 2
cos and
b
2 2
sin
21
P
7
3 O

3
19
(7, 0) (4, 0) (1, 0)
y
x
O
B
A
C
30
30 a
a
a
Coordinates of foci are ( ae, 0).
Q e
b
a
+ 1
2
2
e + + 1 1
2
2
2
sin
cos
tan

e sec .
Hence, abscissae of foci remain constant when
varies.
100. Since, a line makes an angle of

4
with positive
direction of each of x-axis and y-axis, therefore

4 4
,
We know that cos cos cos
2 2 2
1 + +
cos cos cos
2 2 2
4 4
1

+ +

1
2
1
2
1
2
+ + cos
cos
2
0 90 .
101. Using Mean Value theorem

f c
f f
( )
( ) ( ) 3 1
3 1


1 3 1
2 c
e e

log log
c e
e

2
3
2
3
log
log .
102. Since, f x ( ) tan
1
(sin cos ) x x +

+ +
f x
x x
x x ( )
(sin cos )
(cos sin )
1
1
2

+

_
,

+ +
2
4
1
2
cos
(sin cos )
x
x x

f (x) is increasing, if < + <

2 4 2
x
< <
3
4 4

x
Hence, f (x) is increasing when x

_
,

2 4
, .
103. Since, A

1
]
1
1
1
5 5
0
0 0

5
5
A
2
5 5
0 5
0 0 5
5 5
0 5
0 0 5

1
]
1
1
1

1
]
1
1
1





+ +
+

1
]
1
1
1
25 25 5 10 25
0 5 25
0 0 25
2 2
2 2


| | A
2
2 2
2 2
25 25 5 10 25
0 5 25
0 0 25

+ +
+



+
25
25 25 5
0
2
2

625
2

But | | A
2
25
625 25
2
| | .
1
5
104.
1
2
1
3
1
4 ! ! !
+ K
+ + 1 1
1
2
1
3
1
4 ! ! !
K

e
1
.
105. Let (
$ $
) 2 3 u v is a unit vector. Then
|
$ $
| 2 3 1 u v
6|
$ $
u | v | | | sin | = 1
sin
1
6
Hence, there is exactly one value of for which
(2 3
$ $
u v ) is a unit vector.
106. a u t ( cos ) and b u t gt ( sin )
1
2
2
b a
ga
u
tan
cos

1
2
2
2 2
Also, c
u
g

2
2 sin
b a
a g
cg

_
,
tan
sin
sec

2
2
2
2
b a
a
c
tan tan
2
2
2
a
a
c
b

_
,

2
tan
tan
( )
.

bc
a c a

tan
( )
1
bc
a c a
107. Let the number of boys and girls are x y and .
52 42 50 x y x y + + ( )
22
u
B
D
A
a
C
b
c
52 42 50 50 x y x y + +
2 8 x y x y 4
Total number of students in the class
+ + x y y y y 4 5
Required % of boys
4
5
100 80
y
y
108. The point of intersection of two perpendicular
tangents to the parabola lies on direct of the
parabola.
Since, equation of directrix is y x + 2
So, point is ( , ). 2 0
109. Equation of sphere is
x y z x y z
2 2 2
6 12 2 20 0 + + +
whose co or di nates of cen tre are (3, 6, 1).
Let the coordinates of the other end of
diameter are (, , ),
then
+

2
2
3
3
2
6
5
2
1 , ,
Hence 4 9 , and 3.
Thus the coordinates of other point are
(4, 9, 3).
110. Since, a i j k

+ +
$ $ $
, b i j k

+
$ $ $
2
and c i j k

+ x x
$
( )
$ $
2 are coplanar

x x

2 1
1 1 1
1 1 2
0
3 2 2 0 x x + +
2 4 x
x 2.
111. Since, A h k B ( , ), ( , ) 1 1 and C( , ) 2 1 are the
vertices of a right angled triangle ABC.
Now, AB h k + ( ) ( ) 1 1
2 2
BC + ( ) ( ) 2 1 1 1
2 2
and CA h k + ( ) ( ) 2 1
2 2
Using, Pythagorus theorem
AC AB BC
2 2 2
+
h h k k
2 2
4 4 1 2 + + +
+ + + + h h k k
2 2
1 2 1 2 1
5 4 3 2 h h
h 1 K(i)
Now, given that area of the triangle is 1.
Then, area ( ) ABC AB BC
1
2
1
1
2
1 1 1
2 2
+ ( ) ( ) h k
2 1 1
2 2
+ ( ) ( ) h k K(ii)
On putting h 1 from Eq. (i), we get
2 1
2
( ) k
On squaring both the sides, we get
4 1 2
2
+ k k
k k
2
2 3 0
( )( ) k k + 3 1 0
k 1 3 ,
Thus, the set of values of k is {1, 3}.
112. Slope of QR 3,
So, PQR 120
Slope of the line QM tan
2
3
3

Hence equation of line QM is y x 3
or 3 0 x y + .
113. Equa tion of bi sec tors of lines xy 0 are y x .
Put y x in my m xy mx
2 2 2
1 0 + ( ) , we
get
mx m x mx
2 2 2 2
1 0 + ( )
( ) 1 0
2 2
m x m 1.
114. Since, f x
t
t
dt
x
( )
log

1
1
and F e f e f
e
( ) ( ) +

_
,

1
23
A(h, k)
Y
O
X
C(2, 1)
B(1, 1)
/3 /3
P
M
Q (0, 0)
x
y
R (3, 3 3)
(1, 0)
x'
y'
2/3
F e
t
t
dt
t
t
dt
e e
( )
log log
/

+
+
+

1 1
1
1
1

+
+
+

log log
( )
t
t
dt
t
t t
dt
e e
1 1
1 1

1
]
1
log (log ) t
t
dt
t
e
e
2
1 1
2

1
2
1
2 2
[(log ) (log ) ] e
1
2
115. f x x x ( ) min { , | | } + + 1 1
f x x x R ( ) . + 1
f x ( ) is differentiable every where.
116. lim
x
x
x e

,
0
2
1 2
1

lim
( )
x
x
x
e x
x e
0
2
2
1 2
1


+

lim
( )
x
x
x x
e
e xe
0
2
2 2
2 2
1 2

+

lim
x
x
x x
e
e xe
0
2
2 2
4
4 4
1
f x ( ) is continuous at x 0, then
lim ( ) ( )
x
f x f

0
0
1 0 f ( ).
117. Given question is wrong.
118.
dx
x x cos sin +

_
,

1
2 3
sec x dx

_
,

+
1
2 2 6 4
log tan
x
c

+

_
,

+
1
2 2 12
log tan .
x
c

119. Required area, A x x dx

( )
0
1

1
]
1
2
3 2
3 2
2
0
1
x
x
/

2
3
1
2
1
6
sq unit
120. Let and be the roots of equation
x ax
2
1 0 + + , then
+ a and 1
Now | | ( ) +
2
4
| | a
2
4
According to question,
a
2
4 5 <
a
2
4 5 <
a
2
9 0 <
a ( , ). 3 3
24
(1, 0)
O
x
y'
x'
y
y = x y = x
2
y = x