FORMATIVE TEST 4 CHEMISTRY UPPER 6 (40 MINUTES) NAME : FORM : ...

Section A [10 marks] Four suggested answers labelled A, B, C, and D is given for each question. Choose one correct answer.
1.

Carbon monoxide forms a 1:1 complex with haemoglobin. If the concentration of haemoglobin in human blood is 3.0 x 10-7 mol kg-1, how much carbon monoxide is needed to poison haemoglobin in 4.5 kg of blood? [Relative atomic mass: C =12, O = 16] 1.89 x 10-5 1.89 x 10-6 3.78 x 10-5 5.67 x 10-5

A B C D

2. Which of the following cannot be obtained from a mass spectrometer?

A B

The number of isotopes Relative molecular mass

C D

Relative abundance of isotopes The electron configuration in an atom

3. When a hydrogen atom in a discharge tube is given a high potential difference, the excited electrons fall to a lower energy level and the excess energy is lost in the form of rays. Which electron transition forms the longest wavelength? A B C D n= 7 n = 6 n= 6 n = 5 n= 5 n = 4 n= 7 n = 1

4. The enthalpy change of vapourisation for three elements, magnesium, silicon and sulphur

are shown in the table below. Which matches the value of H vapourisation with its element correctly? 9 Si S Mg S H vapourisation / kJ mol -1 196 377 S Mg Mg Si Si S Si Mg
1

A B C D

1. A covalent molecule, ABn has the following properties: 5. When 60 cm3 of a hydrocarbon were burnt completely in oxygen, 240 cm3 of carbon dioxide

and 0.0125 mol of water were produced. What is the molecular formula of the hydrocarbon? (i) It is a polarised molecule. (The volumes of all gases were measured at room conditions. The molar volume of any gas (ii) It is a molecule with a trigonal pyramidal shape. at room conditions is 24.0 dm3) (iii) It can form a coordinate bond (dative) with the boron triflouride molecule (BF3) A C2H6 C C3H6 Which of the following is not true about the ABn molecule? B C3H8 D C4H10 A B C D The ABn molecule has one lone-pair electrons. The ABn molecule acts as a Lewis base. Element A is more electronegative than element B. Element A is in Group 15 of the Periodic Table and undergoes sp2 hybridisation to form a bond with element B.

6. A manometer is a device for measuring gas pressures. A sample of nitrogen gas is placed in a close-end manometer at 25C until there is an increase of 0.100 g in its mass. The diagram below shows the height of mercury in the manometer.

What is the volume of the nitrogen gas in the manometer? [Relative atomic mass: N=14.0; molar gas constant = 8.31 J K1 mol1; 760 mm Hg = 101 kPa] A B 95 cm3 111 cm3 C D 133 cm3 266 cm3

7. The diagram below shows the crystalline lattice structure of a compound

Which of the following types of unit cells represents the lattice structure? A B C D Monoclinic Triclinic Orthorhombic Rhombohedral

8. The bond angles of a 2-hydroxyethanamide molecule are labelled as a, b,

c and d as follows.

Which of the following is the arrangement of bond angles in ascending order? A a, b, d, c C b, d, c, a B a, d, b, c D d, b, c, a 9. Which of the following is the most accurate definition of transition elements? A B C D Elements Elements Elements Elements states with with with with variable oxidation states high melting and boiling points ability to form coloured compounds partially filled d orbitals at zero or normal oxidation

1 2

3 4

5 6

7 8

9 10

Section B. [15 marks]

3

Answer all questions in the spaces provided. All working should be shown. For numerical answers, units should be quoted wherever they are appropriate. 1.(a) Sodium-24 isotope is used in medicine to study the blood circulatory system. (i) Write the electronic configuration of sodium-24 isotope. (1 mark) (ii) How many orbitals of sodium-24 isotope are fully filled? (1 mark)
(iii) State the orbitals of sodium-24 ion which contain valence electrons.

(1 mark)
(iv) State one reason why sodium-24 isotope is rarely found in its natural

state. ..(1 mark) (b) Sulphur tetrafluoride is a reactive, stable and highly poisonous gas.
(i) Draw the Lewis structure of sulphur tetrafluoride.

(1 mark)

(ii) What is the shape of a sulphur tetrafluoride molecule? ..(1 mark)

4

(iii) Is sulphur tetrafluoride a polar or non-polar molecule?

..(1 mark) (c) Cyanide ion, CN, can act as a monodentate ligand. Draw an orbital overlap diagram for a cyanide ion. (3 marks)

2. (a) An aqueous solution containing X2+ ions forms a white precipitate when an aqueous solution of sodium sulphate is added to it. The solubility of the white precipitate is 2.33 x 103 g dm3 and its solubility product is 1.00 x1010 mol2 dm6 at 25C. (i) Calculate the relative formula mass of the precipitate.

(3 marks ) (ii) Name the precipitate formed. (1 mark) (b) Ammonia is prepared in industry by using the Haber process and it is used to manufacture chemical fertilisers.
(i) State one physical property of ammonium salt that makes it suitable

as a chemical fertiliser.
5

..(1 mark)

MARKING SCHEME FOR FORMATIVE TEST 4 2011 Section A 1 2 3 4 5 C D A B D 6 7 8 9 10 D C B B D

Section B No 1 Answer Mark 1 1 1 1 Total marks

1 1
6

10

1 1

2 1 1 1 5

(b) (i) It is soluble in water

1 15