JMS 5 PAPER 1

PAPER-1
Maximum Marks: 80

Question paper format and Marking scheme: 1. In Section I ( Total Marks: 21), for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other cases, minus one (1) mark will be awarded. 2. In Section II (Total Marks: 16), for each question you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks other wise. There are no negative marks in this section. 3. In Section III (Total Marks: 15), for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other cases, minus one (1) mark will be awarded. 4. In Section IV (Total Marks: 28), for each question you will be awarded 4 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks otherwise. There are no negative marks in this section.

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JMS 5 PAPER 1
SECTION I (Total Marks : 21) (Single Correct Answer Type) This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. 1. Resonance energy of C6H6 using Kekule formula for C6H6 from the following data: (1) H 0 for C6H6 = 358.5 kJ mol1 (2) Heat of atomisation of C = 716.8 kJ mol1 (3) Bond energy of C__H, C = C, and H__H are 490, 340, 620 and 436.9 kJ mol1

A) 140 kJ
2.

B) 150 kJ

C) 160 kJ

D) 170 kJ

Which of the following oxidation reactions incorrectly matched?

(a)
(b)

Cr ( VI ) CH -CH OH CH CHO 3 2 3 H O+ 3
CrO , H SO 3 2 4 CH - CH C C CH CH CH CH C C C CH 3 2 2 3 3 2 2 3 propanone, O OH

(c)
CH CH 3

CH OH CH 2 3 PCC, H Cl 2 2 CH 3

CHO

(d)

MnO 2 CHCl , 25 0C 3
3. Chromyl chloride test is employed for the detection of chloride ions. A similar test can be employed for (A) Br (B) I (C) Both (D) None of these D fructose is a ketose, but it reduces Tollens reagent. It can be explained on the basis of
(A) Mutarotation (C) Amadori reararangement (B) Reimer Tiemann reaction (D) Lobry de Bruyn Van Ekenstein rearrangement

4.

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JMS 5 PAPER 1
5. Chlorine evolved by the reaction of 45.31 g of pyrolusite (impure) and excess of HCl is found to combine completely with the hydrogen produced by the reaction of 10 g of magnesium and excess of dilute hydrochloric acid. Hence, the percentage purity pyrolusite sample is A) 80.56% B) 60.56% C) 40.56% D) 90.56% An optically pure compound X gave an [ ]D = 20.00 . A mixture of (X) and its enantiomer (Y) gave
25

6.

[ ]D

25

= +10.00 . Select the True / False statements regarding this mixture.

(1) It has 50% dextrorotatory isomer (2) It has 25% laevorotatory isomer (3) It has 50% optical purity (A) TTF (B) FFT 7. Match the following ListI (Crystal System)
1) Trigonal 2) Monoclinic 3) Rhombic 4) Hexagonal

(C) FTT

(D) TFT

List II (axial distances)

P) a b c Q) a = b c R) a = b = c

ListIII (axial angles)

a) b) c) d)

List IV (unit cells possible)

i) P, F, E, B ii) Primitive
o

= = 90 o
= = = 90 o = = 90 , 120
o

iii) Primitive
o

= = 90 o , = 120

iv) P, E

A) 1 - P, a, iii; 2 - R, b, iv; 3 - P, d, i; 4 - Q, c, iii B) 1 - R, b, i; 2 - P, c, ii; 3 - P, a, iii; 4 - Q, d, iv C) 1 - Q, a, iii; 2 - P, b, iv; 3 - R, d, ii; 4 - P, c, i D) 1 - R, a, ii; 2 - P, c, iv; 3 - P, b, i; 4- Q, d, iii

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JMS 5 PAPER 1
SECTION II (Total Marks : 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE OR MORE may be correct. 8. Lucas test is used to distinguish 10, 20 and 30 alcohols. Correct options regarding this are
2 ROH + HCl RCl
conc.

anhydrous ZnCl

White turbidity

+ H2O

A) ROH behaves as a Lewis base B) Greater the value of pKa (alcohol), greater the reactivity with conc. HCl and thus faster the formation of white turbidity. C) Alcohol which readily reacts with Na metal, will give turbidity readily D) Alcohol which gives red colour in Victor Meyer test, will give turbidity at slower rate than those giving blue or white colour in Victor Meyer test.

9.

The values of E0 of some reactions are givenbelow. I2 + 2e 2I E0 = 0.54 volts Sn+4 + 2e Sn2+ E0 = 0.152 volts Cl2 + 2e 2Cl E0 = 1.36 volts Fe+3 + e Fe2+ E0 = 0.76 volts Ce+4 + e Ce3+ E0 = 1.6 volts Hence (A) Fe3+ oxidizes Ce+3 (B) Ce4+ can oxidize Fe2+ (C) Sn2+ will reduce Fe3+ to Fe2+ (D) Cl2 will be liberated from KCl by passing I2. Which of the following reactions generate tertiary alcohol function
(A)

10.

O
CH 3 3 CH

CH O 3 H 2O CH OH 3

(B)
CH CH 3 3

CH O 2 CH Cl Ag + 2

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JMS 5 PAPER 1
(C)
CH
Br

H O 2 Ag +

(D)

CH

CH MgBr + 3 H3O CH 3

11.

Which of the following on hydrolysis produces ammonia (A) CaNCN (B)Borazine (C) Li3N (D) NCl3

SECTION-III (Total Marls : 15)

(Paragraph Type)

This section contains 2 paragraphs. Based upon one of paragraphs 2 multiple choice questions and based on the other paragraph 3 multiple choice questions have to be answered. Each of these questions has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. Paragraph for Question Nos. 12 to 13 Estimation of Carbon and Hydrogen in an organic compound can be carried out by liebigs method and nitrogen by either Dumas method or by Kjeldahls method. Although Kjeldahls method is easy to carry out in the laboratory, it is not of general applicability.

12.

0.50g of an organic compound was Kjeldahlised and the NH3 evolved was absorbed in 50ml of 0.5 M H2SO4. The residual acid required 60ml of 0.5 M NaOH. The percentage of nitrogen in the organic compound is A) 14 B) 28 C) 56 D) 42 0.46g of an organic compound containing carbon, hydrogen and oxygen was heated strongly in a stream of N2 gas. The gaseous mixture thus obtained was passed first over heated coke at 1373 K and then through a warm solution of iodine pentoxide when 1.27 g of I2 was liberated. The percentage of oxygen present in the organic compound is A) 87.4 B) 86.96 C) 47.38 D) 38.47

13.

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JMS 5 PAPER 1
Para. Q. Nos (14 - 16) Addition of a non-volatile solute to a solvent lowers its vapour pressure. Therefore, the vapour pressure of a solution (i.e., V.P. of solvent in a solution) is lower than that of pure solvent, at the same temperature. A higher temperature is needed to raise the vapour pressure upto one atmosphere pressure, when boiling point is attained. However increase in b.pt. is small. For example 0.1 molal aqueous sucrose solution boils at 100.05oC. Sea water, an aqueous solution, which is rich in Na+ and Cl ions, freezes about 1OC lower than frozen water. At the freezing point of a pure solvent, the rates at which two molecules stick together to form the solid and leave it to return to liquid state are equal when solute is present. Fewer solvent molecules are in contact with surface of solid. However, the rate at which the solvent molecules leave the surface of solid remains unchanged. That is why temperature is lowered to restore the equilibrium. The freezing point depression in a dilute solution is proportional to molality of the solute. 14. The freezing point of benzene solution was 5.4oC. The osmotic pressure of same solution at 10oC is (boiling point of benzene = 5.5oC). Assume solution to be dilute. [Kf for C6H6 is 4.9 K molality A) 0.274 atm B) 0.474 atm 15. 1]. C) 0.674 atm D) 0.874 atm

The amount of ice separated out on cooling a solution containing 50 g ethylene glycol in 200 g water to 9.3oC is [Kf for H2O = 1.86 K molality1] A) 38.71g B) 61.29g C) 138.71g D) 161.29g 2 g of benzoic acid dissolved in 25 g of C6H6 shows a depression in f.pt. equal to 1.62 K. Kf for C6H6 is 4.9 K molality1. The percentage association of acid if it forms doubls molecules in solution is A) 0.8% B) 99.2% C) 90.2% D) 9.8% SECTION-IV (Total Marks : 28)
(Integer Answer Type)

16.

This section contains 7 questions. The answer to each of the questions is a single digit integer, ranging from 0 to 9. The bubble corresponding to the correct is to be darkened in the ORS. 17. Co-ordination number of Cr in CrCl3.5H2O is six. The volume of 0.1 N AgNO3 needed to ppt. the chlorine in outer sphere in 200 ml of 0.01 M solution of the complex is/are indicated . (1) 140 ml (2) 40 ml (3) 80 ml (4) 20 ml Sum of the correct options is The number of products obtained when propane is subjected to vapour-phase nitration is

18.

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JMS 5 PAPER 1
19. A chemical reaction takes place in three steps having rate constant k1, k2, k3 respectively. If kk E ,E and E are 50, 40 and 30 respectively in kJ and the overall rate constant, k= 1 3 . a a a k2 1 2 3 The overall energy of activation is x x 10 kJ. x is 20.
300 C high Green vitriol anhydrous salt L + M + N . If oxidation state of the central atom in temp
O

L,M,N are X,Y,Z respectively (X<Y<Z). The value of Y + Z X is ___ 21.

Na 24 (half-life = 15 hrs) is known to contain some radioactive impurity (half-life = 3 hrs) in a sample. This sample has an initial activity of 1000 counts per minute, and after 30 hrs it shows an activity of 200 counts per minute. Percent of the initial activity that was due to the impurity is Z x 10. Z is
11

22.

A hydrogen like species (atomic number Z) is present in a higher excited state of quantum number n. this excited atom can make a transition to the first excited state by successive emission of two photons of energies 10.20 eV and 17.0 eV respectively. Alternatively, the atom from the same excited state can make transition to the second excited state by successive emission of two photons of energy 4.25eV and 5.95 eV respectively. Value of Z is There are 100 persons sitting at equal distance in a row XY . N2O (laughing gas) is released from the side X and tear gas (molar mass = 176) from side Y at the same moment and at the same temperature. The person who will have a tendency to laugh and weep simultaneously is at z from side Y. Unit place of z is

23.

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