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JMS 5 PAPER - 2

PAPER-2
Maximum Marks: 80

Question paper format and Marking scheme: 1. In Section I (Total Marks: 24), for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other cases, minus one (1) mark will be awarded. 2. In Section II (Total Marks: 16), for each question you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks other wise. There are no negative marks in this section. 3. In Section III (Total Marks: 24), for each question you will be awarded 4 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks otherwise There are no negative marks in this section. 4. In Section IV (Total Marks: 16), for each question you will be awarded 2 marks for each row in which you have darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks otherwise. Thus each question in this section carries a maximum of 8 Marks. There are no negative marks in this section. http://www.chemistrycrest.com/ Page 1

JMS 5 PAPER - 2
SECTION I (Total Marks : 24) (Single Correct Answer Type) This Section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. 1. Which of the following reactions moves towards the product side to the highest extent? CH OH 3 (A) CH CH F+LiCl 3 2 DMSO (B) CH CH OH+KI 3 2 acetone (C) CH C-CH -Br+NaI 3 3 2

CH CH OH 3 2 (D) CH CH CH Cl+KSCN 3 2 2

2.

Which of the following reactions cannot result into adduct formation


(A) BF3 + NH 3 (B) BCl3 + NH3

(C) CH 3 O CH 3 + BCl3 (D) H3Si O SiH 3 + BCl3 .

3.

When 9 ml of arsenious sulphide sol and 1 mL of 104 M BaCl2 are mixed turbidity due to precipitation just appears after 2 hours. The effective ion in coagulating and its coagulating value is
A) C)

Ba +2 ,10m mol/mL
Cl ,10m mol/L

B) D)

Ba +2 ,102 m mole/L Cl ,102 m mol/mL

4.

The incorrect statement regarding basicity and nucleophilicity will be? (A) Nucleophilicity is governed by size of nucleophilic atom (B) Basicity is a thermodynamic property (C) Nucleophilicity is measured by Ka (equilibrium constant) value (D) C2H5O is a weaker base than Me3CO Which of the following is a copolymer? (A) Buna-S (C) Polythene

5.

(B) PAN (D) PTFE

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JMS 5 PAPER - 2
6.
1 propyne NaNH2 (A) 1 chloro-3 bromo propane (B) 1. Mg /dry ether + O /H 2. H (C) H2 |Pd| BaSO4 (E) CrO 3 (D)

Identify (B) and (E) (A) (C) 7. Macth the following Column I (Name of reaction) (A) Cannizzaro (P) Column II (compound responding)
O
Cl OH
Br O

(B) (D)

Br O Cl O

(B) (C) (D)

Aldol condensation Reformatsky reaction Oxidation (by Tollens reagent)

(Q) (R) (S)

HCHO
CHO

A) A-P,R; B-P,Q; C-R; D-Q,S C) A-R; B-P,Q,R; C-R,S; D-R,S 8.

B) A-R,S; B-P,Q,R; C-R,Q; D-P,R,S D) A-P,Q,R; B-Q,R; C-P,R,S; D-P,Q,R,

XeO3 trioxide (XeO3) forms xenate ion in alkaline medium XeO3 + NaOH Na[HXeO4] But xenate ion slowly disproportionates in alkaline solution as Na[HXeO4] + NaOH Z + Xe + O2 + H2O The compound Z is expected to be (A) Na2XeO3 (C) Na2XeO4 (B) Na4XeO6 (D) Na4XeO4 Page 3

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JMS 5 PAPER - 2
SECTION II (Total Marks : 16)
(Multiple Correct Answer(s) Type)

This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE OR MORE may be correct. 9.
1 For the dissociation N 2 O5( g ) 2NO 2( g ) + O 2( g ) if 2 M = molecular mass of N2O5(g)

d = vapour density of equilibrium mixture Po = Initial pressure of N2O5(g), identify the wrong statement/s

(A) Equilibrium pressure can be expressed as

Po M 2d
2P o d M

(B) Equilibrium pressure can be expressed as

P o (M 2d) 3d (D) Increase in temperature will increase magnitude of degree of dissociation

(C) Degree of dissociation can be expressed on

10.

Which of the following is/are correct order of reactivity towards nucleophilic addition? (A) BrCH CHO > CH CHO > BrCH COCH 2 3 2 3 (B) Ph-CHO > CH CHO > CH COCH 3 3 3

C = NH > CH C=O 3 2 3 2 3 2 O O O O || || || || (D) CH C C CH > CH C CH > Cl CH C CH 3 3 3 3 2 3


(C) CH

C = O H > CH

11.

Hydrogen reduces

A) Heated cupric oxide C) Aqueous PdCl2

B) Boron trichloride D) Heated aluminium oxide

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JMS 5 PAPER - 2
12. Which reagent does not give oxygen as one of the products during oxidation with ozone? (A) SO2 (B) H 2 S (C) PbS (D) SnCl2 / HCl SECTION-III (Total Marks : 24) (Integer Answer Type) This section contains 6 questions. The answer to each of the questions is a single-digit integer, ranging from 0 to 9. The bubble corresponding to the correct answer is to be darkened in the ORS. 13. The difference in vibrational kinetic energy per mole of CO2 and SO2 at temperature T, according to law of equipartition of energy is equal to Z x 10-1 RT. Z is

14.
O
hot KMnO

4 C12 H16 H 3C C CH 3 + HO C C C OH

||

||

||

||

( A)
(1mole ) ( 2mole )
Numbe of bonds present in A.

( 2mole )

15.

PH of the following amino acid with one significant figure is

HOOC CH CH CH COOH 2 2

pK

= 4.25 3

NH 3
pK a

pK

a 1

= 2.19

16.

= 9.67 2 No of Michael addition reactions that occur in the following reaction is


O

O || + (iii) CH3MgBr (i) OH (iv) H+ CH3 CH = CH C CH = CH CH3 CH3 (ii) H

CH3

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JMS 5 PAPER - 2
17. Calculate the pH at which the following conversion (reaction) will be at equilibrium in basic medium.
I2 (s) I (aq.) + IO3 (aq.)
When the equilibrium concentrations at 300K are[I] = 0.10M and [IO3 ] = 0.10M

given that G 0 (I )(aq) = 50 kJ/mole G 0 (IO3 )(aq.) f f

= 123.5 kJ/mole, G 0 (H 2 O)(l ) =233 kJ/mole, f


G 0 (OH )aq = 150 kJ/mole R = f
25 log e = 2.3 3

18.

Among the sulphide ores of Ag, Hg, Pb, Fe, Cu and Zn, how many of them can be extracted by self reduction process. SECTION-IV (Total Marks : 16) (Matrix-Match Type)

This section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and five statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II. For example, if for a given question, statement B matches with the statements given q and r, then for the particular question, against statement B, darken the bubbles corresponding to q and r in the ORS.

19. Column I (Reactions)


(A) (B) (C) (D) CaCO3(s) CaO(s) +CO2(g); H = (+)ve N2(g) + 3H2(g) 2NH3(g); = ()ve PCl5(g) PCl3(g) +Cl2(g); H = (+)ve (P)

Column II (Favourable condition for formation of products)


Addition of amount of reactant Increase in temperature Increase in pressure Addition of inert gas at constant pressure Decrease in temperature

(Q) (R) (S) (T)

H2(g) + I2(g) 2HI(g); H = ()ve

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JMS 5 PAPER - 2
20. Match the reactions given in Column-I with the facts given in Column-II. Column-I (A) (B) AlCl3 FeSO4 (p) (q) Column-II Gives ppt with Na2PO4 in presence of NH4Cl and NH4OH Gives reddish brown ppt with NH4OH which dissolves in excess of NaOH Gives white ppt with NH4OH which dissolves in excess of NaOH Gives dirty green ppt with NH4OH as well as with NaOH Gives Fe||| Fe|| ( CN ) with 6 4 3

(C)

FeCl3

(r)

(D)

MgCl2

(s)

(t)

K4[Fe(CN)6]

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