CHEMISTRY CREST

AIEEE ACHIEVER 1

Maximum Marks: 120

Question paper format and Marking scheme: 1. This question paper has 30 questions of equal weight age. Each question is allotted 4(four) marks for each correct response. 2. (one fourth) of total marks allotted to each question i.e., 1 mark will be deducted for indicating incorrect response 3. No deduction from the total score will be made if no response is indicated for an item in the answer sheet. 4. There is only one correct response for each question. Filling up more than one response in each question will be treated as wrong response and marks for wrong response will be deducted accordingly.

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1.

AIEEE ACHIEVER 1

A solution containing 0.1g of a non-volatile organic substance P (molecular mass 100) in 100 g of benzene raises the boiling point of benzene by 0.20C, while a solution containing 0.1 g of another non-volatile substance Q in the same amount of benzene raises the boiling point of benzene by 0.4 0 C. What is the ratio of molecular masses of P and Q (1) 1 : 2 (2) 2 : 1 (3) 1 : 4 (4) 4 : 1

2.

The correct order of rates of nitration in the following is

D D D

NO2

Cl

D D

II

III

IV

1) II < III < I < IV < V 3) IV < I = III < V < II

2) IV < V < I = III < II 4) I < III < II < V < IV

3.

Consider the following molecular structures of [Pt(NO2)(Py)(NH3) (NH2OH)]+

O2 N Pt H3N Py HOH2N NH2OH

O2N Pt

Py

O2N Pt

Py

O2 N Pt

NH3

NH3

H3N

NH2OH

Py

NH2OH

II

III

IV

Choose the incorrect statement among the following (1) I,II and III are geometrical isomers (2) III and IV are identical structures (3) I ,II and III are diastereoisomers (4) II and IV are enantiomeric pair 4. In a fossil 97.56% of initial concentration of C-14 was present when analyzed in the year 2004. The fossil is likely to originate in which of the following battle. (t1/2 for C-14 is 5760 year; use log 12.5/12.195 = 0.01072) (1) Battle of Kalinga 361 BC which turned emperor Ashoka towards Buddhism (2) Ist battle of Panipat 1526, Babar defeats Ibrahim Lodi (3) IInd battle of Panipat 1556, Akabar defeats Hemu . (4) Battle of Pyramids 1798, Napoleon defeats Mamelkus in Egypt

5.

on reaction with NBS in CCl4 gives the major product (1)

Br

(2)
CHBr

(3)
Br

(4)
CH2Br

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6. 1) 3) 7. Most powerful reducing agent among the following is; Pyrophosphoric acid Hypophosphorous acid 2) 4)

AIEEE ACHIEVER 1

Hypophosphoric acid Orthophosphorous acid

COCl + Cl2 COCl2 + Cl (slow) (1) (3) . 8. 9. Rate = k [CO] [Cl2] Rate = k [CO] [Cl2]3/2

For the formation of phosgene from CO(g) and chlorine (g) as , CO( g ) + Cl2 ( g ) COCl2 ( g ) the possible mechanism is Cl2 2Cl (fast) Cl + CO COCl (fast)

The rate law expression can be written as

(2) (4) Rate = k [CO]1/2 [Cl2] Rate = k [CO] [Cl2]1/2

Glucose on reduction with Na/Hg and water gives ? (1) Sorbitol (2) Fructose (3) Saccharic acid The decreasing order of second ionisation enthalpy of Mg, Al, Si is (1) Mg > Al > Si (2) Al > Si > Mg (3) Si > Al > Mg (4) Si > Mg > Al.

(4) Gluconic acid

10.

Two elements X and Y combine to form two compounds XY2 and X3Y2. When 0.1 mole of former weighs 10 grams while 0.05 moles of the latter weighs 9grams. Then the weight of 0.2 moles of X2Y is (1) 11 grams (2) 22 grams (3) 2.2 grams (4) 1.1 grams

11.

Which is incorrect product (1)

Na / Liq.NH 3 CH3 C C CH 3

H3C C C

CH3

H (cis) H

(2)
CH 3 C C CH 3
H2 Pd / BaSO4

H3C C H
CH3

CH3 C H
(cis)

(3)

CH3
Br2

CH3 H Br Br H CH3

Br H

H Br CH3

CH3

cis-But-2-ene

( ) -2, 3-Dibromobutane

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(4)
H CH3
Br2

AIEEE ACHIEVER 1
CH3 H H Br Br CH3
Meso -2, 3-dibromobutane

H3C

trans-But-2-ene

12.

Which of the following pairs have same hybridization about the central atom? (1) SF4/SiF4 (2) NO3 / NF3
2 2 (3) S2 O8 / S2 O3

(4) BrF5 / IF7

13.

Coagulation values of the electrolytes AlCl3 and NaCl for As 2S3 solution are 0.093 and 52 respectively. How many times nearly AlCl3 has greater coagulating power than NaCl ? (1) 930 (2) 520 (3) 560 (4) 1000

14.

The treatment of benzene with isobutene in the presence of sulphuric acid gives : (1) isobutyl benzene (2) tert-butyl benzene (3) n-butyl benzene (4) no reaction The wrong statement about N2O is : (1) It is nitrous oxide (2) It is least reactive oxide of nitrogen (3) It is not a linear molecule (4) It is known as laughing gas n containers having volumes v, 2v, 3v..nv containing gaseous moles n, 4n, 9n,..n3 respectively are connected with stopcock at same temperature. If pressure of first container is P, then the final pressure when all the stopcocks are opened is (1) (3)
n ( 2n + 1) P 3

15.

16.

(2) (4)

( 2n + 1) P
3n

( 2n + 1) P
6n

( 2n + 1) P
3

17.
OH OH OH OH OH

NO2 (I)

Cl (II)

Me (III)

OMe (IV)

(V)

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Correct order of Acidic strength is (1) I > II > III > IV > V (3) I > II > III > V > IV 18. (2) I > II > V > III > IV (4) I > II > V >IV > III

AIEEE ACHIEVER 1

In electrolysis of Al2O3 byHall-Heroult process: (1) cryolite Na3[AlF6] lowers the melting point of Al2O3 and increases its electrical conductivity. (2)Al is obtained at cathode and probably CO2 at anode (3) both (1) and (2) are correct. (4) none of the above is correct. At equilibrium N 2O4( g ) 2 NO2 ( g ) the observed molecular weight of N 2O4 is 80 g mol 1 at 350K. The percentage dissociation of N 2O4 (g) at 350 K is : 1) 10% 2) 15% 3) 20%
4) 18%

19.

20.

Arrange following in order of reactivity toward SN1 reaction

Cl Cl Cl Cl

(I)

(II)

(III)

(IV)

(1) I > II > III > IV (3) IV > II > I > III

(2) IV > I > II > III (4) IV > III > II > I

21.

The following acids have been arranged in order of decreasing acid strength. Identify the correct order. ClOH (), BrOH ( IOH ( ), )
(1) > > (2) > > (3) > > (4) > >

22.

Electrolysis of an acetate solution produces ethane according to the Kolbe reaction : 2CH 3COO C2 H 6 + 2CO2 + 2e What volume of ethane is produced at 270C and 740 mm Hg, if a current of 0.500 A were passed through the solution for 7 h and the electrode reaction is 82% efficient? (1) 2.70 L (2) 5.4 L (3) 1.35L (4) 0.65 L Which of the following compound gives N-nitrosoamine on reaction with nitrous acid
(1)

23.

CH2
N

NH2

(2)

H3C

NH2

(3)

(4)

NH

CH3

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24.

AIEEE ACHIEVER 1

Which of the following ore can be concentrated by froth floatation process : (1) Epsom (2) Silver glance (3) Haematite (4)All The enthalpy of neutralization of a weak monoprotic acid, HA in 1 M solution with a strong base is -55.95 kJ/mol. If the unionized acid requires 1.4 kJ/mol heat for its complete ionization and enthalpy of neutralization of the strong monobasic acid with a strong monoacidic base is -57.3 kJ/mol. Then % ionization of the weak acid in molar solution is (1) 1.2 % (2) 3.57 % (3) 6.07 % (4) 12.01 % Which will not perform iodoform reaction? (1) CH3COCH2CH3 (2) CH3CONH2

25.

26.

(3) C6H5COCH3

(4) CH3CHO

27.
.

Which of the following species will paramagnetic in nature, ifHund's rule is violated while writing their molecular orbital configuration : (1) O2 (2) C2 (3) B2 (4) N2 --Calcium lactate is a salt of weak acid i.e., lactic acid having general formula Ca ( Lac )2 . Aqueous solution of salt has 0.3 M concentration. pOH of solution is 5.60. If 90 % of the salt is dissociated then what will be the value of pK a ? (1) 2.8 log ( 0.54 )

28.

(2) 2.8 + log ( 0.54 )

(3) 2.8 + log ( 0.57 )

(4) None of these

29.

Identify the reagent in the following reaction

(1) Conc. HCl

(2) HCl , ZnCl2

(3) SOCl2

(4) Aqueous KOH

30.

The ion that cannot be precipitated by both HCl and H2S is (1) Pb2+ (2) Cu+ (3) Ag+

(4) Sn2+

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