INTERMEDIATE PUBLIC EXAMINATION Second year chemistry Important questions cum guess paper Maximum marks 60 LAQ 8 Marks

1. State Le Chatliers principle? Apply it for Habers process and contacts process. 2. Define rate of chemical reaction and explain the factors that effect the rate of a reaction. 3. Discuss molecular collision theory of reaction rates. Support your explanation with a relevant diagram. 4. How is ozone prepared in the laboratory? Give any three oxidation/reduction reactions of O3 5. How do you prepare hypo in the laboratory? Give any four chemical properties of hypo with proper equations. 6. Describe Whytlaw-Gray method of for the preparation of fluorine? 7. Write the chemical properties of F2 with relevant equations? 8. What is the principle of preparing Cl2 in the laboratory? Describe Nelsons method for its manufactures. Give any four equations for chemical properties of chlorine? 9. How is bleaching powder prepared industrially? Give any four chemical properties of bleaching powder with proper equations? 10. Explain the preparation of ethyle chloride from 1) Groves process 2) Ethylene 3) Ethane. 11. What happen when ethyle chloride is treated with i) Aqueous potassium hydroxide ii) Aqueous ethanolic potassium cyanide iii) Hot aqueous ethanolic silver nitrate iv) sodium ethoxide 12. Write the preparation of ethyle alcohol from (i) Molasses (ii) Starch. 13. What happen when ethyle alcohol reacts with (i) Metallic Na (ii) Acetic acid (iii) methyl magnesium bromide. 14. How is benzene converted into nitrobenzene? Explain the reduction of nitrobenzene in different media with different regents? SAQ 4 Marks 1. Define and explain Raoults law How is it useful in determining the molecular weight of a non-volatile solute. 2. Derive the equation = CRT . 3. The vapour pressure of a solution containing 108.24g of non-volatile solute, in 1000g of H 2 O at 20o C is 17.354 mm Hg. The vapour pressure of 20o C = 17.54 mm Hg. Find the mol. Wt of the substance. 4. Derive the relation between relative lowering of vapour pressure and molar mass of solute. 5. Calculate the osmotic pressure of 0.5% solution of sucrose at 300K. The density is 1.017kg/lit. 6. Derive Braggs equation. 7. Write a short note on a) Schottky defect (b) Frenkel defect.

8. Write note on tetrahedral hole and octahedral hole? 9. State Faradays law of electrolysis. 10. What is Kohlrausch law. 11. A current of 0.25 amp. Is passed through CuSO 4 solution for 45 minutes. Calculate the mass of copper deposited on the cathode (At Wt of Cu = 63.6). 12. A current of 0.965 amp. Is passed through an aqueous solution of AgNO3 for 10 minutes during electrolysis. Calculate the mass of Ag deposited at the cathode (Atmoic weight of Ag= 108). 13. What are electrolytes? Distinguish between metallic electrodes and electrolytes? 14. Give the differences between physical absorption and chemical absorption. 15. What is emulsion? Explain classification of emulsion? 16. What is catalysis? How is catalysis classified? Give two examples for each. 17. Explain Gibbs energy, enthalpy, entropy 18. State Hesss law of constant heat summation and explain it with an example. 19. Define (a) heat of formation (b) heat of neutralization(c) heat of combustion (d) heat of solution. 20. Discuss froth floatation process. 21. Write short notes on each of the following a) Roasting b) Calcination c) Smelting 22. How is superphosphate of lime prepared? Give an equation. Explain why product is a hard mass. 23. Draw the structure of P4 O6 and P4 O10. In what respects do they resemble each other? What happen when they react with H2O?. 24. Write balanced equations for the formation of NCl3 and PCl3 give there hydrolysis reactions. 25. Explain Werners theory giving suitable example? 26. Define EAN. Calculate the EAN of the following metals in their respective complexes (i) [Cu(NH3) 4](OH) 2 (ii) [Co(H2O)6](NO2)3 (iii) K4[Fe (CN)6 27. Write a short note on colour and magnetic property of transition elements? 28. Mention any four alloys and give their uses.

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