DISCUSSION In this experiment was done the determination of heat solubility CuSO4.5H2O and anhydrate CuSO4.

In this experiment using calorimeter that the constant already know from the preview experiment is about 114 JoC-1. Firstly into calorimeter was entered aquades that already measured the temperature. When the temperature in calorimeter is constant, added CuSO4.5H2O is about 5.001 grams, shack it and the temperature was measure until constant. After the temperature is constant, make a graph between time and temperature. Next, from that the graph makes extrapolation and obtains the amount of T. Graph relationship of time and temperature is like this:

Graph of Time vs Temperature

27.6

Temperature (oC)

27.5 27.4 27.3 27.2 27.1 27 26.9 0 2 4 6 8 10 12

Time (minutes)
Picture 1. Graph of the relationship between time and temperature when added

CuSO4.5H2O

The next stage is to use anhydrous CuSO4. Where the calorimeter is used, the same calorimeter with the same constant is 114 JOC-1. First of all anhydrous CuSO4 made by heating until the color of CuSO4.5H2O changed to white solids CuSO4.5H2O then left in place in a desiccator to cool. CuSO4.5H2O crystals are used weighed as much as 5.001 grams. The crystal of CuSO4.5H2O after heating will be decrease mass. This is because when heating water contained in CuSO4.5H2O has evaporated so that the weight of CuSO4 will be reduced. Furthermore distilled water has been known the temperature that added in the calorimeter and then stirred and the temperature of the calorimeter is measured to obtain a constant

temperature. Then continue by entering the anhydrous CuSO4 that obtained from heating of CuSO4.5H2O. The temperature is measured from the addition of anhydrous CuSO4 until the temperature in calorimeter is constant. Graph showing the relationship between time and temperature are made and extrapolated to obtain the value of T as shown in Figure 2.

Graph of Time vs Temperature

30.5 30

Temperature (oC)

29.5 29 28.5 28 27.5 27 26.5 26 0 1 2 3 4 5 6 7 8 9

Time (minutes)

Picture 2. Graph relationship among time and temperature when added anhydrate of CuSO4

1.

Determination of heat solubility of CuSO4.5H2O = 5,001 grams = 4,18 J/gC = 114 J/C = 27 C = 27,5 C

Known - Crystal mass CuSO4.5H2O - Density of water (c) - Calorimeter capacity (C) - Initial temperature of mixture - Final temperature of mixture Calculation: Calculation of mol CuSO4.5H2O: Mol (n) CuSO4.5H2O = =
mass CuSO4 .5 H 2 O mass molarCuSO 4 .5 H 2 O

5,001 gram 249 ,54 g / mol

= 0,02 mol

Heat calculation: Q = Q water + Q calorimeter Q = m.c.T + C.T Q = (100 gram x 4,18 J/gC x 0,5 C ) + (114 J/C x 0.5C) Q = 209 J + 57 J Q = 266 J

Calculation of dissolution heat H = H =

q mol

266 J 0,02 mol

H = + 13300 J/ mol = + 13.3 kJ/ mol (endotherm)

2.

Determination of dissolution heat of CuSO4 = 4.10 gram = 4,18 J/gC = 114 J/C = 26.5 C = 30 C

Known: - Mass of CuSO4 crystal - Heat capacity of water (c) - Calorimeter capacity (C) - Initial temperature of mixture - Final temperature of mixture

Calculation: Mole calculation of CuSO4: Mol(n) CuSO4 = =

mass CuSO4 mass molarCuSO4

4.10 gram 154 .54 g / mol

= 0.026 mol Heat calculation: Q = Qwater + Q calorimeter Q = m.c.T + C.T Q = (100 gram x 4,18 J/gC x 3.5 C ) + (114 J/C x 3.5 C) Q = 1463 J + 399 J

Q = 1862 J Calculation of dissolution heat: H = H =

q mol 1862J 0.026mol

H = + 71615 J/ mol = + 71.615 kJ/ mol (endotherm)

Berdasarkan analisis data yang telah dilakukan, diperoleh bahwa nilai kalor pelarutan pada CuSO4.5H2O adalah +13.3 kJ/ mol sedangkan kalor pelarutan pada CuSO4 adalah +71.615 kJ/ mol. Dari data yang diperoleh dapat disimpulkan bahwa kalor pelarutan pada CuSO4.5H2O lebih besar dibandingkan dengan CuSO4. Jadi, dapat diartikan bahwa kalor yang diserap dalam pelarutan CuSO4.5H2O lebih besar dibandingkan dengan kalor pelarutan CuSO4.