Solved 540 541 AIEEE Past 5 Years’ Papers

540 541 AIEEE Past 5 Years Papers: Solved 540 541 AIEEE Past 5 Years Papers: Solved
1 (4) 2 (2) 3 (4) 4 (2) 5 (3) 6 (1) 7 (2) 8 (3) 9 (4) 10 (2)
11 (1) 12 (1) 13 (2) 14 (2) 15 (3) 16 (1) 17 (3) 18 (3) 19 (1) 20 (4)
21 (1) 22 (2) 23 (2) 24 (3) 25 (2) 26 (3) 27 (3) 28 (2) 29 (1) 30 (4)
31 (2) 32 (1) 33 (3) 34 (2) 35 (2) 36 (1) 37 (2) 38 (4) 39 (2) 40 (2)
41 (3) 42 (3) 43 (2) 44 (3) 45 (3) 46 (1) 47 (4) 48 (1) 49 (1) 50 (1)
51 (3) 52 (1) 53 (3) 54 (1) 55 (3) 56 (4) 57 (3) 58 (3) 59 (2) 60 (4)
61 (1) 62 (4) 63 (3) 64 (1) 65 (4) 66 (4) 67 (1) 68 (2) 69 (1) 70 (3)
71 (4) 72 (1) 73 (3) 74 (1) 75 (1) 76 (2) 77 (2) 78 (3) 79 (4) 80 (4)
81 (1) 82 (3) 83 (1) 84 (4) 85 (2) 86 (2) 87 (4) 88 (1) 89 (3) 90 (2)
91 (4) 92 (4) 93 (3) 94 (1) 95 (4) 96 (2) 97 (1) 98 (1) 99 (4) 100 (4)
101 (4) 102 (4) 103 (4) 104 (2) 105 (3) 106 (3) 107 (3) 108 (2) 109 (4) 110 (1)
111 (1) 112 (1) 113 (1) 114 (4) 115 (1) 116 (3) 117 (3) 118 (2) 119 (3) 120 (4)
121 (2) 122 (4) 123 (4) 124 (2) 125 (4) 126 (3) 127 (4) 128 (2) 129 (3) 130 (3)
131 (1) 132 (3) 133 (4) 134 (2) 135 (3) 136 (3) 137 (4) 138 (1) 139 (1) 140 (2)
141 (2) 142 (4) 143 (3) 144 (4) 145 (3) 146 (1) 147 (3) 148 (3) 149 (3) 150 (2)
PHYSICS
1. Kirchhoffs Ist law or KCL states that the algebraic sum of currents meeting at any junction is
equal to zero. In other words we can say that the sum of all the currents directed towards a
junction in a circuit is equal to the sum of all the currents directed away from that junction.
Thus, no charge has been accumulated at any junction ie., charge is conserved, and hence,
we can say that KCL (i = 0) is based on conservation of charge. Kirchhoffs IInd law or KVL
states that algebraic sum of changes in potential around any closed resistor loop must be
zero. In other words around any closed loop, voltage drops are equal to voltage rises. No
energy is gained or lost in circulating a charge around a loop, thus, we can say that KVL is
based on conservation of energy.
2. Ferromagnetic substance has magnetic domains whereas paramagnetic substances have
magneticdipoleswhichgetattractedtoamagneticfeld.
Diamagnetic substances do not have magnetic dipole but in the presence of external magnetic
feldduetotheirorbitalmotionthesesubstancesarerepelled.
3. Resistance of a wire
( )
2
l
R
D / 2
where l = length of a wire, D = diameter of a wire, =specifcresistanceofawire.

Given
B
= 2
A
, D
B
= 2 D
A
and R
A
= R
B
Since, R
A
= R
B
,

( ) ( )
A A B B
2 2
A B
l l
D / 2 D / 2

=

AIEEE 2006 SOLUTION
( )
2 2
A B A A A
2 2
B A A B
A
l D 2 D 1
l 2 D
2D

= = =

B
A
l 2
l 1
=
4. Let E
and B
be along X-axis. When a charged particle is released from rest, it will experience
anelectricforcealongthedirectionofelectricfeldoroppositetothedirectionofelectricfeld
depending on the nature of charge. Due to this force, it acquired some velocity along X-axis.
Due to this motion of charge, magnetic force can not have non-zero value because angle
between v
and B
would be either 0 or 180.

So, only electric force is acting on particle and hence, it will move along a straight line.
5.
Theelectricfeldwillbedifferentatthelocationofforceonthetwocharges.Thereforethe
two charges will be unequal. This will result in a force as well as torque.
6.
dx
Velocity v x
dt
= =

dx
dt
x
=
Integrating it, we get
dx
dt
x
=

2x
1/2
= t
x t
2
.
7. Here momentum of the system is remaining conserved as no external force is acting on the
bomb (system).

initial momentum (before explosion) = Final momentum (after explosion)
Let velocity of 4 kg mass is v m/s. From momentum conservation we can say that its direction
is
opposite to velocity of 12 kg mass.
From
i f
P P =

0=1244v
v = 12 m/s

( )
2
4 12
KEof 4kgmass 288J
2
= =
8.
s
v
v' v
v v
(
=
(

300
10000 9500
300 v
(
=
(

300v=3000.95
v=3000.05=15ms
-1
9. Work done = Fl sin 45
Gaininpotentialenergy=Mg(llcos45)
work done = gain in potential energy
Flsin 45=Mgl(1cos45)

( )
1
Mg 1
2
F Mg 2 1
1 / 2
| |
|
\ .
= =

10. The height (h) traversed by particle while going up is

2
25
h
2g 2 9.8
= =
Work done by gravity force = mg.h

25
0.1 g cos180
2 9.8
=

[Angle between force and displacement is 180]
25
W 0.1 1.25J
2
= =
11. V
max
= a
max
2
V a
T
=
3
max
2 a 2 3.14 7 10
T 0.01s
V 4.4

= =
12. A body oscillates simple harmonically with a time period 2 s.
2 2
rad / s
T 2

= =
The velocity of a body is given by v = acost, where a = amplitude
Kinetic energy of a body is
2
1
K.E mv
2
=

2 2 2
1
m cos t
2
=
Total energy of a body is
2 2 2
max
1 1
E mv m
2 2
= =
As per question,
75
K.E. E
100
=

2 2 2 2 2
1 3 1
m cos t m
2 4 2
=
2
3
cos t
4
=

3
cos t
2
=
cos t cos
6
=
t
6
=

1
t sec
6 6 6

= = =

13. From Stefans law, the rate at which energy is radiated by sun at its surface is

P = 4R
2
T
4

[Sun is a perfectly black body as it emits radiations of all wavelengths and so for it e = 1.J.
The intensity of this power at earths surface
[Under the assumption r > >r
0
] is

2 4 2 4
2 2 2
P 4 R T R T
I
4 r 4 r r

= = =

The area of earth which receives this energy is only one-half of total surface area of earth,
whose projection would be
2
0
r
Total radiant power as received by earth
2
0
r I =

2 2 4
0
2
r R T
r

=

2 2 4
0
2
r R T
r

=
14. Mutual inductance
BA
I I
= =

1 1 2
2 2
1
MT Q L
[Henry] ML Q
QT

(

= =
(

15. The work done by the hand = F : s
Butthisisequaltothemaximumpotentialenergyoftheball.
mgh = Fs
0.2102=F0.2

0.2 10 2
F 20N
0.2

= =
16. Forstringfxedatboththeends,resonantfrequencyaregivenby
nv
f
2L
= , where symbols
have their usual meanings. It is given that 315 Hz and 420 Hz are two consecutive resonant
frequencies, let these are nth and (n + 1) th harmonics.

nv
315 ....(i)
2L
=

( )
n 1 v
420 ....(ii)
2L
+
=
Eq. (i) Eq (ii)
315 n
420 n 1
=
+

n = 3
From Eq. (i), lowest resonant frequency

0
v 315
f 105Hz
2L 3
= = =
17.

( )
1 1 2 2
1 2
m x m x
0
m m
+
=
+
m
1
x
1
= m
2
x
2
.(i)
Finally,

0 = m
1
(dx
1
) + m
2
(x
2
d)
0 = m
1
dm
1
x
1
+ m
2
x
2
m
2
d
1
2
m
d' d From(i).
m
= (

18. Impulse = change in momentum
= m(uv)=0.15(200)=3kgms
-1

Impulse=forcetime
impulse 3
Force 30N
time 0.1
= = =
19.
C
B
I
I
= and I
E
= I
C
+ I
B

C
E C
I 5.488
49
I I 5.60 5.488
= = =

20. Atcoldjunction,currentfowsfromAntimonytoBismuth(becausecurrentfowsfrommetal
occurring earlier in the series to metal occurring later in the thermoelectric series).
21. Maximum kinetic energy of electrons,
K.E.
max
= eV
s
= 5 eV
According to Einsteins photoelectric equation
E = K.E.
max
+
Where E = energy of incident radiation, = work function
E = 5 + 6.2 = 11.2 eV
Wavelength of incident radiation, = hc/E

( )
6
1.240 10
eVm
E eV

=

6
6
1.240 10
0.1107 10 m
11.2

= =

=110710
-10
m = 1107 A
The incident radiation lies in ultraviolet region.

22. Since, here nuclear target is heavy it can be assumed safely that it will remain stationary and
will not move due to the Coulombic interaction force.
At distance of closest approach relative velocity of two particles is v. Here target is considered
as stationary, so -particle comes to rest instantaneously at distance of closest approach. Let
required distance is r, then from work-energy theorem.

2
0
mv 1 Ze 2e
0
2 4 r

1
r
m

2
1
v

Ze
2
23. The order of time is nano second.
24. Let the emitted particle be
A
Z
X

7 1 8 A
3 1 4 Z
Li H Be X + +
According to conservation of charge number
3 + 1 = 4 + Z
Z = 0
According to conservation of mass number
7 + 1 = 8 + A
A = 0
The emitted particle has Z = 0 and A = 0. Therefore, emitted particle will be gamma
photon.
25. Theequivalentcircuitofthenetworkisasshowninfgure.

It is a balanced Wheatstones bridge hence no current will fow through resistance of arm
BC.
The equivalent resistance between A and D is

eq
1 1 1 1 1 3 1
R 5 10 10 20 15 30 30 10
= + = + = =
+ +

R
eq
= 10 .

eq
E 5
Current I 0.5A
R 10
= = =
26. The range of energy of -particles is from O to some maximum value as shown in option
(3).
27. At resonance,
1
L
C
=

Currentfowingthroughthecircuit,
R
V 100
I 0.1A
R 1000
= = =
So, voltage across L is given by
V
L
= I X
L
= IL
But,
1
L
C
=

L 6
I 0.1
V 250V
C 200 2 10
= = =

28. Given R
100
= 100
= 0.005C
-1
, R
t
= 200
R
100
= R
0
[1+ 0.005 (100)]
100 = R
0
[1+0.005100].(i)
R
t
= R
0
[1 + 0.005t]
200 = R
0
[1 + 0.005t] .(ii)
Divide (i) by (ii), we get
1 0.005 100
100
200 1 0.005t
+ (

=
+ (

1 + 0.005t = 2 + 1
t = 400C
29.
2
1
eV mv
2
=
19
31
2eV 2 1.6 10 20
v
m 9.1 10

= =

=2.6510
6
m/s.
30. The emf generated would be maximum when fux (cutting) would be maximum ie, angle
between area vector of coil and magnetic feld is 0. The emf generated is given by [as a
function of time]
e=NBA cos t
e
max
=NAB
31. A solid which is transparent to visible light and whose conductivity increases with temperature
is formed by covalent binding.
32. For a thin prism, D = (1)A
Since
b
<
r

r
<
b
D
1
< D
2

A m
sin
2
A
sin
2
+ | |
|
\ .
=
33. I = n
e
Av
d

( )
( )
e d
e e
h h d
h
n v
I
I n v
Here,
e e
h h
n I 7 7
,
n 5 I 4
= =
( )
( )
d
e
d
h
v
7 7
4 5 v
=
( )
( )
d
e
d
h
v
5 7 5
v 7 4 4
= =
34. In a balanced Wheatstones bridge,

P R
Q S
=
Given
1 2
1 1 1
S S S
= + (Since, S
1
and S
2
are in parallel)

1 2
1 2
S S 1
S S S
+
=

( )
1 2
1 2
R S S
P
Q S S
+
=
35.
d
e
dt
=
=(20t50)
e
t=3
=10 V
36. Magneticfeldduetoalongsolenoidisgivenby
B=
0
ni
Fromgivendata,6.2810
-2
=
0
200 10
2
i.(i)
andB=
0
10010
2
(i/3)....(ii)
Solving Eqs. (i) and (ii), we get
2 2
B 1.05 10 Wb / m

37. Since diode D
1
is reverse biased, therefore it will act like an open circuit.
Effective resistance of the circuit is R = 4 + 2 = 6 .
Current in the circuit is I = E/R = 12/6 = 2 A.
38. p is connected to low potential and n is connected to high potential.
39. According to the photoelectric effect in a photocell, if a light of wavelength is incident
on a cathode, then electrons are emitted, which constitute the photoelectric current.
Photocell is based on the principle of photoelectric effect. As the wavelength of light changes,
there is no change in number of electrons emitted and hence, no change in current (plate
current of photocell) Thus, the two wavelengths of incident light and plate current are
independent to each other. Plate current depends on intensity of light used.
40. The reaction is
7 4
3 2
p Li 2 He +
Binding energy of
7
3
Li 7 5.60 39.2Mev = =
Bindingenergy of
4
2
He 4 7.06 28.24MeV = =
Energy of proton
( ) ( )
4 7
p 2 3
E 2 B.E. He B.E Li =
=228.2439.2=17.28MeV.
41. Resistance of electric bulb
2
V
R
P
= where subscripts denote for rated parameters.

( )
2
220
R
100
=
Power consumed at 110 V,
2
consumed
V
P
R
=
( )
( )
2
consumed 2
110
P 25W
220 / 100
= =
42. The risk posed to a human being by any radiation exposure depends partly upon the absorbed
dose, the amount of energy absorbed per gram of tissue. Absorbed dose is expressed in
rad. A rad is equal to 100 ergs of energy absorbed by 1 gram of tissue. The more modern,
internationally adopted unit is the gray (named after the English medical physicist L.H. Gray)
; one gray equals 100 rad.
43. The coin will be just leaving the contact at the lowest position when
m
2
A mg
A (g/
2
) [where A = amplitude]
44.

( )
2
2
nn'
I 2 m m 2
2
| |
= +
|
\ .

2 2 2
m 2m 3m = + =
45. Torque r F = =

F Fk;r i j = =

( ) ( )
i j k
r F 1 1 0 i F j F
0 0 F
= =

( )
Fi F j F i j = + = +

46. Velocity is max. when K.E. is max.
For min. P.E.,
dv
0
dx
=
3
x x 0 =
x 1 =
1 1 1
Min.P.E.
4 2 4
= =
K.E. + P.E. = 2 (Given)
1 9
K.E. 2
4 4
= + =
2
1
K.E. mv
2
=
2
1 9
1 v
2 4
=
3
v
2
=
47. As no external torque is acting about the axis, angular momentum of system remains
conserved.

I
1
= I
2

mR
2
= (mR
2
+ 2 MR
2
)
m
'
m 2M
| |
=
|
+
\ .
48. Youngs modulus
W L
Y
A l
=

WL
l
AY
=
When wire goes over a pulley and weight W is attached at each free end of wire on each side,
the tension is Mg but the length of the wire is half.
The total elongation for both sides together is l.
49. Initially, when steady state is achieved,

E
i
R
=
Let E is short circuited at t = 0. Then
At t = 0,
0
E
i
R
=
Letduringdecayofcurrentatanytimethecurrentfowingis
di
L iR 0
dt
=
di R
dt
i L
=
0
i t
i 0
di R
dt
i L
=

e
0
i R
log t
i L
=
R
t
L
0
i i e
=
3
3
100 10
100 10
100 1
e
100 e
= =
50. Whenthetwoconductingspheresareconnectedbyaconductingwire,chargewillfowfrom
one sphere (having higher potential) to other (having lower potential) till both acquire the
same potential.

2
0
1 q
E .
4 r
=

So,
2
1 2
2 1
E r
4:1
E r
| |
= =
|
\ .
51. U = 0
( )
f 0 f 0
5 3 7
R T T 1 R T T 0
2 2 3
| |
+ =
|
\ .

f 0
3
T T
2
=
52.
nR T
W
1

=

1000 8.3 7
146000
1

=

58.1
1
146
=
58.1
1 1.4
146
= + =
53. If lattice constant of semiconductor is decreased, then E
c
and E
v
decrease but E
g
increases.
54. Total average energy density of electromagnetic waves is

2 2
0 r.m.s
0
1 1
u E B r.m.s
2 2
= +

2
2 r.m.s r.m.s
0 r.m.s r.m.s 2
0
E E 1 1
E B
2 2 c c
| |
= + =
|
\ .

2
2 2 0 0 r.m.s
0 r.m.s
0 0 0
E 1 1
E c
2 2
| |
= + =
|

\ .

2 2 2
0 r.m.s 0 r.m.s 0 r.m.s
1 1
E E E
2 2
= + =
=8.8510
-12
(720)
2

(Since,
0
=8.8510
-12
C
2
N
-1
m
-2
)
=4.5810
-6
J/m
3
55.
( )
2
1 2
T
2r d d g
V
9

( )
2
T
V 10.5 1.5
0.2 19.5 1.5

2
T
9
V 0.2
18
=

2
T
V 0.1m/ s =
CHEMISTRY
56. Methyl vinyl ether is a very reactive gas. It is hydrolysed rapidly by dilute acids at room
temperature to give methanol and aldehyde.
However, under anhydrous conditions at room temperature, it undergoes many addition
reactions at the double bond.

57.

Unsaturation (double bond) is given priority over halogen, then lowest set of locants. So the
correct IUPAC name is 3-bromo-1-chlorocyclohexene.
58. Addition of HCN to carbonyl compounds is nucleophilic addition reaction. The order of reactivity
of carbonyl compounds is
Aldehydes (smaller to higher) Ketones (smaller to higher), Then
HCHO > CH
3
COCH
3
>Ph.COCH
3
> PhCOPh
59. 1 mole of Mg
3
(PO
4
)
2
3 mole of Mg atom + 2 mole of P atom + 8 mole of O atom
8 mole of oxygen atoms are present in = 1 mole of Mg
3
(PO
4
)
2
0.25 mole of oxygen atoms are present in
1 0.25
8
=
=3.12510
-2
moles of Mg
3
(PO
4
)
2.
60. Angular momentum of an electron,

nh
mvr
2
=

When n = 5
Angular momentum of electron
5h 2.5h
2
= =

61.
2
2
O

(Total number of electrons = 18)
2 2 2 2 2 2
z x
1s , *1s , 2s , *2s , 2p , 2p
2 2 2
y x y
2p , *2p *2p = =
62. In case of a face-centred cubic structure, since four atoms are present in a unit cell, hence
volume

3 3
4 16
V 4 r r
3 3
| |
= =
|
\ .
63. Rate = K[CO]
2
, this is rate law equation
New rate = K[2CO]
2
= 4K[CO]
2
increases by a factor of 4.
64.
1 6 0 4
2
2 4 2 2
2HI H SO I SO 2H O
+ +
+ + +
2 4 2
Oxidi sing
agent
H SO Reducedto CO
65. [Co(NO)
2
(NH
3
)
5
]Cl
2
pentammine nitro-N-cobalt (III) chloride
66. Due to cyclic hemiacetal or cyclic hemiketal structures, all the pentoses and hexoses exist in
two stereoisomeric forms i.e. a form in which the OH at C
-1
in aldoses and C
-2
in ketoses lies
towards the right and form in which it lies towards left. Thus glucose exists in two forms
-D-glucose and -D-glucose.

D ( ) equilibriummixture D ( )
glucose glucose
+ +
Asaresultofcyclizationtheanomeric(C-1)becomesasymmetricandthenewlyformedOH
group may be either on left or on right in Fischer projection thus resulting in the formation of
twoisomers(anomers).TheisomershavingOHgrouptotheleftoftheC-lisdesignated
-D-glucoseandotherhavingOHgroupontherightas-D-glucose.

67.
238 234 4 0
92 92 2 1
U U He 2 e
+ +
68. CH
3
OH + C
6
H
5
MgBr CH
3
O.MgBr+C
6
H
6
69. If the nucleophilic atom or the centre is same nucleophilicity parallels basicity, i.e. more basic
the species stronger is the nucleophile.
CH
3
O
-
> HO
-
> PhO
-
> AcO
-
Here, the nucleophilic atom i.e. O is same in all these species. This order can be easily
explained on the general concept that a weaker acid has a stronger conjugate base.
70. In DNA, cytosine and thymine are pyrimidine bases.
71. For positive iodoform test, alcohol molecule must have
group
72. The order of stability of free radicals
( ) ( ) ( ) ( )
6 5 6 5 3 3
3 2 3 2
C H C C H CH CH C CH CH

> > >
Thestabilizationoffrsttwoisduetoresonanceandlasttwoisduetoinductiveeffect.
73. According to Heisenbergs uncertainty principle
h
x p
4
=

( )
h
x. m. v
4
=

h
x
4 m. v
=

Here,
3 1
0.001
v 300 3 10 ms
100

= =
34
31 3
6.63 10
x
4 3.14 9.1 10 3 10
=

=1.92 10
-2
m.
74.
( )
x x
5 3 2
1 x
PCl (g) PCl (g) Cl (g)

Total number of moles at equilibrium
=(1x)+x+x
= 1 + x
3
PCl
x
p p
1 x
(
=
(
+

75. The standard enthalpy of formation of CH
4
is given by the equation :
C(s) + 2 H
2
(g) CH
4
(g)
Hence, dissociation energy of hydrogen and enthalpy of sublimation of carbon is required.
76. Dipole-dipole interactions occur among the polar molecules. Polar molecules have permanent
dipoles. The positive pole of one molecule is thus attracted by the negative pole of the other
molecule. The magnitude of dipole-dipole forces in different polar molecules is predicted on
the basis of the polarity of the molecules, which in turn depends upon the electronegativities
of the atoms present in the molecule and the geometry of the molecule (in case of polyatomic
molecules, containing more than two atoms in a molecule).
77.
78. Metal atom in the lower oxidation state forms the ionic bond and in the higher oxidation state
forms the covalent bond. Hence MCl
2
is more ionic than MCl
4.
79. Higher is the oxidation state of the central atom, greater is the acidity.
Hence, HClO
4
is a stronger acid than HClO
3
. HNO
3
is a stronger acid than HNO
2
. Now, greater
is the electronegativity and higher is the oxidation state of the central atom, greater is the
acidity. Hence H
2
SO
3
is a stronger acid than H
3
PO
3.
DuetohigherdissociationenergyofHFbondandmolecularassociationduetohydrogen
bonding in HF, HF is a weaker acid than HCl.
80. According to Kohlrauschs law.

3
3
CH COO
CH COO H
....(i)
+

= +
0
HCl
H Cl
....(ii)
+

= +
3
3
CH COONa
CH COO Na
....(iii)
+

= +
thus on adding Eqs. (ii) and (iii) if
Na Cl
and
+

are subtracted we can obtain the value of
HOAc
.
Thus, additional value required is
NaCl
.
81. Isoelectronic species have same number of electrons.
K
+
, Cl
-
, Ca
2+
, Sc
3+
each contains 18 electrons.
82. Effect of substituent on the acid strength of aliphatic acids :
(i) Acidity decreases as the +I-effect of the alkyl group increases.
HCOOH > CH
3
COOH > (CH
3
)
2
CHCOOH > (CH
3
)
3
CCOOH
(ii) AciditydecreasesastheI-effectaswellasnumberofhalogenatomsdecreases.
FCH
2
COOH > ClCH
2
COOH>BrCH
2
COOH > ICH
2
COOH > CH
3
COOH
F
3
CCOOH > F
2
CHCOOH > FCH
2
COOH > CH
3
COOH
(iii)Electron donating substituents like R, OH, NH
2
etc. tend to decrease while
electron withdrawing substituents tend to increase the acid strength of substituted acid.
On the basis of given information the relative order of increasing acid strength of the
given compounds :
(CH
3
)
2
COOH < CH
3
COOH < CH
3
OCH
2
COOH < CF
3
COOH
83. In SF
4
the hybridisation is sp
3
d and the shape of molecule is

84. 3HOCl 2HCl + HClO
3
85.
Number of unpaired electrons = 2
Geometry = tetrahedral.
86. Metal carbonyl organometallic compounds possess both and characters.
87. The correct order of ionization enthalpies is
F>P>S>B
88. If a gas was to expand by a certain volume reversibly, then it would do a certain amount
of work on the surroundings. If it was to expand irreversibly it would have to do the same
amount of work on the surroundings to expand in volume, but it would also have to do work
againstfrictionalforces.Therefore,theamountofworkhavegreatermodulusbutvesign.
W
irrev
> W
rev
; T
f irrev
> T
f rev.
89. Assuming the formation of a monolayer of the adsorbate on the surface of the
adsorbent, it was derived by Langmuir that the mass of the gas adsorbed per gram
of the adsorbent is related to the equilibrium pressure according to the equation :

x aP
m 1 bP
=
+
90. k = Ae
-E/RT

E is activation energy, it is that energy, which molecule must have to give the product.
91.
Nuclear substitution will not take place.
92.
It follows E2 mechanism.
Hughes and Ingold proposed that bimolecular elimination reactions take place when the two
groups to be eliminated are trans and lie in one plane with the two carbon atoms to which
they are attached i.e. E2 reactions are stereoselectively trans.
93. HOCH
2
CH
2
F

Gauche conformation is comparatively more stable due to hydrogen linkage in between F and
H (at O-atm), hence order is Eclipse, Anti (staggered), Gauche.
94. Since the compound on treatment with Br
2
-water gives a tribromoderivative, therefore, it
must be m-cresol, because it has two ortho and one para position free with respect to OH
group and hence can give tribromoderivative.

95. NH
3
> PH
3
< AsH
3
> SbH
3

As the electronegativity of central atom increases, bonded electron polarize towards central
atom more, so, repulsion increases and bond angle increases.
96. Hofmanns rule : When theoretically more than one type of alkenes are possible, the alkene
containing least alkylated double bond is formed. Hence,

97. Ni
2+
= [Ar] 3d
8

Number of unpaired electrons = 2
Hence, magnetic moment
( )
n n 2 = +
8 2.84 = =
98. Equilibrium constant for the reaction :
2 2 3
1
SO (g) O SO (g)
2
+

c 2
1
K
4.9 10

and for
2 2 3
2SO O 2SO (g) +

2
c 2
1
K
4.9 10
| |
=
|
\ .

( )
4
2
10
416.49
4.9
= =
99. Alkali metals reactivity increases down the group as electropositivity increases, but for
halogens F
2
is more reactive as moving down molecular stability increases.
100. (i) Ag Ag
+
+ e
-
E = -0.800 V
(ii) Ag + I
-
AgI + e
-
E = 0.152 V
(I)(II)wehave
AgI Ag
+
+ I
-
E=0.952V
0.952=0.059log[Ag
+
] [I
-
]

sp
0.952
logK
0.059
=
16.13 = log K
sp
101.
(g) 2(g) 2
NO Br NOBr (g) +

2(g) (g) (g)
NOBr NO 2NOBr + [rate determining step]
Rateofthereaction(r)=k[NOBr
2
] [NO]
Where[NOBr
2
] = K
C
[NO][Br
2
]
r = k. K
C
.[NO][Br
2
][NO]
r = K [NO]
2
[Br
2
]
The order of the reaction with respect to NO
(g)
= 2.
102. As we proceed from one element to the next element in the lanthanide series, the nuclear
charge, i.e. atomic number increases by one unit and the addition of one electron occurs
at the same time in 4f-energy shell. On account of the very diffused shapes of f-orbitals,
the 4f-electrons shield each other quite poorly from the nuclear charge. Thus, the effect of
nuclear charge increase is somewhat more than the changed shielding effect. This brings the
valence shell nearer to the nucleus and hence the size of atom or ion goes on decreasing as
we move in the series. The sum of the successive reductions is equal to the total lanthanide
contractions.
103.
l
x ;
R.a
=
cell constt.
1
1.29 100 129
a
| |
= =
|
\ .

Again conducting of 0.02 M solution
1
x 129
520
=
m
x 1000 129 1000
M 520 0.02
= =
=1.2410
-4
S m
2
mol
-1
104.
( )
M aq. M aq
hydratedcation
+
+
( +

The extent of hydration depends upon the size of the ion. Smaller the size of the ion, more
highly it is hydrated and hence greater is its ionic mobility. Thus the order of the ionic mobility
is Li
+
< Na
+
< K
+
< Rb
+
.
105. Molality,
2
M
m 1000
1000d MM
=

where M = molarity, d = density, M
2
= molecular mass
1
2.05
m 2.28molkg
1000 1.02 2.05 60

= =

106.
2(s) 2(g)
I Cl 2ICl(g) +
2
ICl I I Cl Cl I (s)
H 2H 2H 2H H

= + + +
=2211.3+151.0+242.3+62.67
= 33.46

( )
o
f
33.46
H ICl 16.73kJ / mol
2
= =
107. EDTA, which has four donor oxygen atoms and two donor nitrogen atoms in each molecule
forms complex with Ca
2+
ion. The free acid H
4
EDTA is insoluble and the disodium salt Na
2
H
2
EDTA
is the most used reagent.
Ca
2+
+ [H
2
EDTA]
2-
[Ca(EDTA)]
2-
+ 2H
+
108.
3 3 2
3 2
CHCl OH CCl H O
CCl CCl Cl

+ +
+

109. Moles of glucose

18
0.1
180
= =
Moles of water
178.2
9.9
18
= =
Total moles = 0.1 + 9.9 = 10
2
H O
9.9
P Molefraction Totalpressure 760
10
= =
= 752.4 Torr.
110. HU = n
g
RT
C + 1/2 O
2
CO

g
1 1
n 1 1
2 2
| |
= + =
|
\ .

1
1
H U 8.314 298 1238.78Jmol
2

= =
MATHEMATICS
111. Since, tan 30 and tan 15 are the roots of equation x
2
+ px + q = 0.
tan 30 + tan 15=p
and tan 30 tan15 = q
Therefore,
2+qp=2+tan30 tan 15 + (tan 30 + tan 15)
2+qp=2+tan30 + tan 15+1tan30 + tan 15
tan30 tan15
tan45
1 tan30 tan15
| | +
=
|

\ .
2+qp=3
112.
6
3
x
I dx
9 x x
=
+

6
3
9 x
I dx
9 x x
=
+

6
3
2I dx 3 = =

3
I
2
=
113. Given relation R such that
R = {(x, y) WW|thewordxandyhaveatleastoneletterincommon}whereWdenotes
set of words in English dictionary
Clearly (x, x) R x W
(x, x) has every letter common
Risrefexive
Let (x, y) R then (y, x) R as x and y have atleast one letter in common
R is symmetric.
Now, let x = DON, y = NEST, Z = SHE
then (x, y) R and (y, z) R.But(x,z) R.
Risrefexive,symmetricbutnottransitive.
So, R is not transitive.
114.

2 sin
2
x+5sinx3=0
(sinx+3)(2sinx1)=0

1
sinx
2
= and sin x 3
In [0, 3], x has 4 values.
115. Given A
2
B

2
=(AB)(A+B)
A
2
B
2
= A
2
B
2
+ABBA
AB=BA
116.
10
k 1
2k 2k
sin i cos
11 11
=
| |
+
|
\ .

10 10
k 1 k 1
2k 2k
sin i cos
11 11
= =

= +

=0+i(1)=i.
117. Since,
( ) ( )
a b c a b c =

( ) ( ) ( ) ( )
a.c b b.c a a.c b a.b c =

( ) ( )
b.c a a.b c =

a
is parallel to c
.
118. Given equation x
2
2mx+m
2
1=0
(xm)
2
1=0
(xm1)(xm+1)=0
x=m1,m+1
-2<m1andm+1<4
m>1andm<3
1<m<3.
119. Magnitude of Resultant

2 2
2 2
1 1 AB AC
AB AC AB.AC
+ | | | |
= + =
| |
\ . \ .

BC BC 1
AB.AC AD.BC AD
= = =

120. Since, variance is independent of change of origin. Thus, variance of observations 101, 102,
.., 200 is same as variance of observation 151, 152, .., 250.
V
A
= V
B

A
B
V
1
V
=
121.
( ) ( )
2
3
2
3
2
I x cos x 3 dx
(
= + + +

Put x + = t
2 2
3 2 2
0
2
I (t cos t)dt 2 cos tdt

= + =

( )
2
0
1 cos2t dt 0
2
= + = +
122. Given that, 2ae = 6 and 2b = 8

ae = 3 and b = 4
ae 3
b 4
=
2
2
2
9 b
e
16 a
| |
=
|
\ .

( )
2
2 2 2
2
9 b
e 1 e 1 e
16 a
| |
= =
|
\ .

2
16 9
e 1
9
+ | |
=
|
\ .

3
e
5
=

123. Given family of parbolas
3 2 2
a x a x
y 2a
3 2
= +
2
2
3 3 3
y a .3 2a
x x
a / 3 2.a a / 3
= +
2
3 3 2 2
3y 6a 3 9 9
x 2 x
4a a a 16a 16a
| |
+ = + +
|
\ .

2
3 3 2
3y 6a 9 3
x
4a a a 16a
| |
+ + = +
|
\ .

2
3 2 2
3y 6 9 3
x
4a a a 16a
| |
+ + = +
|
\ .

2
3 2
3 3y 105
x
4a a 16a
| |
+ = +
|
\ .

2
3
3 3 35
x y a ....(i)
4a 16 a
| | | |
+ = +
| |
\ . \ .

Let
3
x X
4a
+ = and
35
y a Y
16
+ =
equation (i) reduces to
2
3
3
X Y
a
=
vertex X = 0, Y = 0
3
x 0
4a
+ =
3
x
4a
= and
35
y a 0
16
+ =
35
y a
16
=
3 35 105
xy a
4a 16 64
| |
= =
|
\ .

required locus is:
105
xy
64
=
124. The equation of axes is xy = 0
Hence the equation of the line is
x.4 y.3
12
2
+
=
4x + 3y = 24
125. Since, positionofvectorsofA,B,Care
2i j k +

,
i 3j 5k

and
ai 3j k +

respectively.
( )

( )
AC ai 3j k 2i j k = + +

( )
a 2 i 2j =

and
( )

( )
BC ai 3j k i 3j 5k = +

( )

a 1 i 6k = +

Since, the ABCisright angled at C, then
AC.BC 0 =

{(a 2)i 2j}.{(a 1)i 6k} 0 + =

(a2) (a1) = 0
a = 1 and 2
126. Let
0
I x f (sinx)dx ....(i)
=

0
I ( x)f (sin( x))dx

0
I ( x)f (sinx)dx ....(ii)
Adding (i) and (ii) we get

0
2I f (sinx)dx

0
I f (sinx)dx
2

=

/2
0
I .2 f (sinx)dx
2

=

/2
0
I f sin x dx
2
| | | |
=
| |
\ . \ .

/2
0
I f (cosx)dx
=

127. Equation of lines
x b z d
y
a c

= =
x b' z d'
y
a' c'

= =
Lines are perpendicular
aa + 1 + cc = 0
128. Total number of ways
10 10 10 10
1 2 3 4
C C C C + + +
= 10 + 45 + 120 + 210
= 385
129. Given expansion of
2 n
0 1 2 n
1
isa a x a x ....a x ....
(1 ax)(1 bx)
.... (i)
+ + + +

( ) ( )
1
1 2 2
2 2
1 ax (1 bx) 1 ax a x ....
(1 bx b x ....) ....(ii)

= + + +
+ + +

coeffcientofx
n
in (i) and (ii)
n n 1 2 n 2 n 1 n
n
a b ab a b ....a b a

= + + + +
n 1 n 1
b a
b a
+ +

n 1 n 1
n
b a
a
b a
+ +
130. (1y)
m
(1 + y)
n

m m 2 n n 2
1 2 1 2
1 C y C y .... 1 C y C y ....1 ( ( = + + + +

( )
2
m(m 1) n(n 1)
1 n m y mn y ....
2 2

= + + + +
`
)

a
1
=nm = 10
and
2 2
2
m n m n 2mn
a 10
2
+
= =
So, n m=10
and(mn)
2
(m+n)=20
m + n = 80
m = 35, n = 45
131. Let the magnitude of two velocities be u.
We know that
2 2 2
R u u 2u cos = + +
R 2u 1 cos = +
R 2ucos
2
=

We know that by angle bisector theorem
AB BD
AC DC
=
u
1
2ucos
2
=

1
cos cos
2 2 3

= =
= 120.
132. According to Poisson distribution
m r
e m
P(X r)
r!
= =
P(X 1) = P(X = 0) + P(X = 1)
m
m
e .m
e
1!
= +
Given m = mean = 5
( )
5 5 5
5
6
P(x 1) e 5 e e 1 5
e

= + = + =
133. Using
2
1
h gt
2
=
and
2
1
h 400 g(t 4)
2
+ = +

Subtracting, we get 400 = 8g + 4gt
t = 8 sec
1
h 10 64 320m
2
= =
Desired height = 320 + 400 = 720 m
134. Since,
x
f (x)
1 x
=
+

Let
g(x) x
f (x)
h(x) 1 x
= =
+
Itisclearthatg(x)=xandh(x)=1+|x|aredifferentiableon(,)and(, 0) (0, )
respectively.
Thus,f(x)isdifferentiableon(, 0) (0, ) .
For x = 0,
( ) ( )
h 0 h 0
h
0
f h f 0
1 h
LHD lim lim 1
h h

+
= = =

h 0 h 0
h
0
f (0 h) f (0)
1 h
RHD lim lim 1
h h

+
+
= = =
Thus,f(x)isdifferentiableon(,).
135. Given
1 2 a 0
A ,B
3 4 0 b
( (
= =
( (

1 2 a 0 a 2b
AB
3 4 0 b 3a 4b
( ( (
= =
( ( (

a 0 1 2 a 2a
BA
0 b 3 4 3b 4b
( ( (
= =
( ( (

NowAB=BA
3a = 3b and 2b = 2a
a = b
AB=BAonlywhena=b.
136.
2
1
2
1
p
[2a (p 1)d]
p
2
q
q
[2a (q 1)d]
2
+
=
+

( )
( )
1
1
2a p 1 d
p
2a q 1 d q
+
=
+

1
1
p 1
a d
p 2
q 1 q
a d
2
| |
+
|
\ .
=
| |
+
|
\ .

For
6
21
a
,
a
p = 11, q = 41
6
21
a 11
a 41
=
137. Since,
x 2
f(x)
2 x
= +
( )
2
1 2
f ' x
2 x
=
For maxima or minima, put f(x) = 0
2
1 2
0
2 x
=
x
2
= 4
x 2 =
Now,
3
4
f "(x)
x
=
4 1
f "(2) 0
8 2
= = >
and
4 1
f "( 2) 0
8 2
= = <
f (x) is minimum at x = 2.
138. Given equation of curve y = x
2

5x+6
dy
2x 5
dx
=
Now
( )
1
2,0
dy
1 m
dx
| |
= =
|
\ .

( )
2
3,0
dy
1 m
dx
| |
= =
|
\ .

Since, m
1
m
2
=1
angle between the tangents at (2, 0) and (3, 0) of the curve y = x
2
5x+6is
2
139.
2
2
3x 9x 17
y
3x 9x 7
+ +
=
+ +

3x
2
(y1)+9x(y1)+7y17 = 0
D 0
since, x is real
81(y1)
2
43(y1)(7y17) 0
(y1)(y41) 0
1 y 41
140. The area of isosceles triangles is maximum when it is right angled triangle.
Giventhat,AB=AC=x

We know that area of isosceles triangle is maximum, if it is right angled triangle.
Maximum area of triangle
2
1
x
2
=
141. Given that (a, a
2
) falls inside the angle made by the lines
x
y ,
2
= x > 0 and y = 3x, x > 0
a
2
3a<0and
2
a
a 0
2
>
1
a 3
2
< <
142. x
m
. y
n
= (x + y)
m+n
Takinglogarithmsonbothsides,wegetmlnx+nlny=(m+n)ln(x+y)Bydifferentiatingon
both sides,

m n dy m n dy
1
x y dx x y dx
+ | |
+ = +
|
+
\ .

m m n m n n dy
x x y x y y dx
| | | | + +
=
| |
+ +
\ . \ .

( ) ( )
my nx my nx dy
x x y y x y dx
| |

= |
|
+ +
\ .

dy y
dx x
=
143. The intersection points of diameters of a circle is the centre of a circle.
The given equations of diameters are
3x4y7=0.(i)
and2x3y5=0.(ii)
On solving Eqs. (i) and (ii), we get
x=1andy=1
Centreofcircleis(1,1)
Let r be the radius of circle, then
r
2
= 49
r = 7 unit
Equation of required circle is
(x1)
2
+ (y + 1)
2
= 49
x
2
+ y
2
2x+2y+1+1=49
x
2
+ y
2
2x+2y47=0
144. Image of point (x, y, z) in ax + by + cz + d = 0 is
( )
2 2 2
2 ax' by' cz' d
x x' y y' z z'
a b c a b c
+ + +

= = =
+ +

( )
2 1 6
x 1 y 3 z 4
1 2 0 5

+
= = =

9 13
x , y , z 4
5 5
= = =
145. Ax
2
+By
2
= 1 . (1)
dy
Ax By 0 ....(2)
dx
+ =
2
2
2
d y dy
A By B 0 ....(3)
dx dx
| |
+ + =
|
\ .

From (2) and (3)
2
2
2
d y dy dy
x By B By 0
dx dx dx

| |
+ =
`
|
\ .

)

2
2
2
d y dy dy
xy x y 0
dx dx dx
| |
+ =
|
\ .
146. Since,
a 2 3 a
1 1 2 [a]
[x]f '(x)dx f '(x)dx 2f '(x) .... [a]f '(x)dx = + + +

= [a]f(a){f(1)+f(2)+.+f([a])}
147. LetABischordofcircleandM(h,k)bemidpointofAB.AOM = 60
NowOA=OB=3and
OM AB(Bypropertiesofcircle)
Now
2 2
OM h k , = + OM = r cos

2 2
h k 3cos60 + =
2 2
3
h k
2
+ =
2 2
9
h k
4
+ =
2 2
9
x y
4
+ =
148.
2 1 3 2
1 1 1 1
........
a a a a
= =
n n 1
1 1
d(say)
a a

= =
Then
2 3 1 2 n 1 n
1 2 2 3 n 1 n
a a a a a a
a a , a a ,......a a
d d d

= = =
1 2 2 3 n 1 n
a a a a ..... a a
+ + +
2 3 1 2 n 1 n
a a a a a a
.....
d d d

= + + +
1 2 2 3 n 1 n
1
a a a a ..... a a
d

= + + + (

1 n
a a
d
=
Also,
( )
n 1
1 1
n 1 d
a a
= +
( )
1 n
1 n
a a
n 1 a a
d
=
149. Given equation is
z
2
+ z + 1 = 0
z = ,
2
Now,
2 2 2
2 3
2 3
2 2 2
4 5 6
4 5 6
1 1 1
z z z
z z z
1 1 1
z z z
z z z
| | | | | |
+ + + + +
| | |
\ . \ . \ .
| | | | | |
+ + + + + +
| | |
\ . \ . \ .
= ( +
2
)
2
+ (
2
+ )
2
+ (
3
+
-3
)
2
+ ( +
2
)
2
+ (
2
+ )
2

+ (
6
+
-6
)
2
=(1)
2
+(1)
2
+ (1 + 1)
2
+(1)
2
+(1)
2
+ (1+1)
2

= 1 + 1 + 4 + 1 + 1 + 4 = 12
150. Given
1
cosx sinx
2
+ =
Squaring both sides
1
1 sin2x
4
+ =
3
sin2x
4
= x is obtuse and
2
2tanx 3
4 1 tan x
=
+

3 tan
2
x + 8 tan x + 3 = 0
8 64 36 4 7
tanx
6 3

= =

since, tan x < 0
4 7
tanx
3

Solved 540 541 AIEEE Past 5 Years’ Papers

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Solved 540 541 AIEEE Past 5 Years’ Papers

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540 541 AIEEE Past 5 Years Papers: Solved 540 541 AIEEE Past 5 Years Papers: Solved

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