. dna swal syadaraF no desab slaciremun retpahc .

yrtsimehc ortcelE . waL suballys 11 . selom fo rebmuN . retpahc . slaciremun sQCM

snoisrevnoc slaciremun

erusserp citomsO

noisserped tniop gnizeerF

noitavele .P .B

.P.V fo gnirewol

. ytilalom

alumrof

ytreporp evitagilloc retpahc .

ytiralom ,ytilamroN

seitreporp evitagilloc dna snoituloS ealumrof slaciremun II C I yrtsimehc yrtsimehc . . .nim 09 scisyhp , sQCM . I C sQCM 52

I C sQCM 05 , . scisyhp , 53 - 03 ,sQCM 05 . 05 . .

21/01

yrtsimehc

T f =

T b =

V =

Po - Ps W M = 2 1 Po M 2 W1

W2 KT M2

K f 1000 W2

M2 W1

1000 W2

M2 W1

Eocell
.

elpicnirp sreiletahc eL dna noitca ssam fo tpecnoc retpahc airbiliuqE cinoI

rebmun sordagovA , waL ssseH . alumrof TR )n ( + E snoitinifeD = H .

, sQCM 6/5

alumrof retpahc

ngis eV scimanydomreht lacimehC

xamW .

.4

.3

.2

.1

syolla tnereffid nZ

sQCM redrO .

yroeht

seulav PRS . F ,iL ,uC ,nZ ,eF ,iN

Eocell = Eooxi

Anode

Eooxi

slaciremun

Dont try to find out correct answer but try to find out correct option.

cathode

Prof. Arvind Gadgil

. sQCM II C I C , . 2 ,413.8 , 003 , 892 , 396.0 , 280.0 ,303.2 fo gol .g.e .roF . seulav gol laciremun stnatsnoc . laciremun stnatsnoc yrtsimehc . nZ . snoitcaer lacimehc noitisopmoc % noitcartxe fo dohteM stnemele kcolb d shparg no desab ytiraluceloM scitenik lacimehC . noisuf raelcun noissif raelcun ,noitatumsnart laicifitra ,ytivitcaoidar laicifitrA . , fo rebmun .E .B retpahc yrtsimehc raelcuN . sllec leuf noisorroC , nZ . uC ,nM ,rC fo noitarugifnoc cinortcelE retpahc . noitcaer redro

suballys

selcitrap

.
ts1
oreZ retpahc slaciremun . retpahc seires FME .

1.

Which of the following aqueous solutions will have the highest depression in freezing point : (a) 0.1 M urea (c) 0.1 M AlCl3 (b) 0.1 M sucrose (d) 0.1 M K4 [Fe(CN)6]

Ans : (d) Colligative molarity of 0.1 M K4[Fe(CN6)] solution is the largest (i = 5). Hence, in this solution 2. Tf will be the highest since Tf colligative molarity.

For a gaseous reaction involving the complete combustion of isobutane : (a) (c) H> H= E E (b) (d) H= H< E=0 E
( )

Ans : (d) C4H10 (g) + 6.5 O2 (g) 4 CO2 (g) + 5H2O

n = 4 7.5 = 3.5 H = E 3.5 RT H < E

3. Ksp of Ca3 (PO4)2 will be : (a) [Ca ++ ]3 [PO 4 3 ] (c) [Ca ++ ]3 [PO 3 ]2 4 Ans : (c) (b) [Ca ++ ] [PO 3 ] 4
(d) [Ca 2 + ]3 [PO 4 3 ]3

Ca 3 ( PO 4 )2
3

3 Ca +2 + 2 PO 3 4
2

K SP = Ca +2 PO 3 4
4.

Consider the following E values; E Fe+3/Fe+2 = + 0.77 V. E Sn+2/Sn = - 0.14 V. Under standard conditions the potential for the reaction :

Sn (s) + 2Fe+3 Sn +2 + 2Fe+2 (aq)

(a) 1.68 V (c) 0.91 V Ans: (c) (b) 1.40 V (d) 0.63 V
sn /sn +2

E cell = E

+ E

Fe+3 /Fe+2

= + 0.14 V + 0.77 V = + 0.91V

5.

Half-life of radium is 1580 years. Its average life will be : (a) 2.5 103 years (c) 2.275 103 years (b) 1.832 103 years (d) 8.825 102 years

Ans:

(c) Average life = 1.44 half-life = 1.44 1580 years = 2.275 103 years

6.

For a reaction k is 2.5 10-3 L mol-1 sec-1. The order of reaction is : (a) Half (c) Two (b) One (d) Three

Ans:

(c) Unit of k for the reaction is L mol-1 sec-1 which represents a second order reaction.

7.

Which one of the following equation is correct for the reaction ? N2(g) + 3H2(g) 2NH3(g) ? (a)

2d[H 2 ] 2d[N 2 ] = dt dt 2d[NH 3 ] 3d[H 2 ] (c) = dt dt

(d) For the reaction,

2d[N 2 ] 1 d[H 2 ] = dt 3 dt 3d[NH 3 ] 2d[H 2 ] (d) = dt dt

(b)

Ans:

Rate = or
8. Pt black is :

1 d[H 2 ] 1 d[NH 3 ] = . 3 dt 2 dt 2d[H 2 ] 3d[NH 3 ] = dt dt

(a) Pt metal mixed with MnO2 powder (b) Pt metal coated with black colour (c) Velvet blak powder obtained by reduction of PtCl4 (d) Pt metal mixed with iron powder Ans: (a)