CHEMISTRY CREST

EAMCET 2010(ENGINEERING)

Maximum Marks: 40

Question paper format and Marking scheme: 1. This question paper has 40 questions of equal weight age. Each question is allotted 1 mark for each correct response. 2. No deduction from the total score will be made if no response is indicated for an item in the answer sheet. 3. There is only one correct response for each question. Filling up more than one response in each question will be treated as wrong response

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121.

EAMCET 2010(ENGINEERING)

Which one of the following transitions of an electron in hydrogen atom emits radiation of the lowest wavelength? (1) n 2 = to n1 = 2 (2) n 2 = 4 to n1 = 3 (3) n 2 = 2 to n1 = 1 (4) n 2 = 5 to n1 = 3 (3) Radiation of lowest wavelength has highest energy. So it is of Lyman series. As we go away from the nucleus, difference in energy between adjacent levels goes on decreasing. Which one of the following conditions is incorrect for a well behaved wave function ( ) ? (1) must be finite (3) must be infinite (2) must be single valued (4) must be continuous

Sol.

n 2 = 2 to n1 = 1
122.

Sol.

(3) Inorder to be an acceptable solution, must be finite The electron affinity values of elements A, B, C and D are respectively 135, -60, -200 and -348 kJ mol1 . The outer electronic configuration element B is: (1) 3s 2 3p5 (2) 3s 2 3p 4 (3) 3s 2 3p3 (4) 3s 2 3p 2 (3)

123.

Sol.

3s 2 3 p 3 configuration has lowest E.A.since it has half filled p sublevel

124. Match the following: List I (Molecule) (A) (B) (C) (D) List II (Number of lone pairs on central atom) (i) (ii) (iii) (iv) (v) Two Three Zero Four One

3 H O 2 XeF 2 CH 4

NH

The correct answer is: A B C D (1) v i iii (2) iii i ii (3) v i ii (4) i v iii
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ii v iii iv
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Sol. (3) Molecule NH 3 H O 2 XeF 2 CH 4 125. No. of lone pairs 1 2 3 0

EAMCET 2010(ENGINEERING)

The ratio of anion radius to cation radius of a crystal is 10 : 9.3. Then, the coordination number of the cation in the crystal is: (1) 2 (2) 4 (3) 6 (4) 8 (4)

Sol.

r 9.3 Limiting radius ratio = cation = = 0.93 r 10 anion Since, the limiting radius ratio is > 0.73, it is cubic. Coordination number is 8.
126. The number of molecules of CO2 liberated by the complete combustion of 0.1 gram atom of graphite in air is: (1) 3.011022 (2) 6.02 1023 (3) 6.02 1022 (4) 3.011023 (3)
C + O CO 2 2 1 gram atom 1mole = 6.02 10 23 molecules 0.1 gram atom Carbon liberates = 6.02 1022 molecules of CO2

Sol.

127.

CH4 diffuses two times faster than a gas X. The number of molecules present in 32 g of gas X is: (N is Avogadro number) N N N (1) N (2) (3) (4) 2 4 16 (2) Let 1 be CH4 and 2 be X r1 M2 = r2 M1
2 M2 = 1 16 M 2 = 64

Sol.

No. of moles of gas X =

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32 1 = 64 2

No. of molecules of X =

N 2

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128.

EAMCET 2010(ENGINEERING)

The BaCl2 ionizes to an extent of 80% in aqueous solution, the value of Vant Hoff factor is: (1) 2.6 (2) 04 (3) 0.8 (4) 2.4 (1)

Sol.

BaCl2 Ba 2+ + 2Cl
80 = 0.8 100 i 1 n 1

n = 3

For dissociation, =

0.8 =
129.

i 1 = 2.6 3 1

X is a non-volatile solute and Y is a volatile solvent. The following vapour pressures are observed by dissolving X in Y: X/mol lit-1 0.10 0.25 0.01 Y/mm of Hg P1 P2 P3

The correct order of vapour pressures is: (1) P1 < P2 < P3 (3) Sol. (4)
Vapour pressure 1 Concentration of solute particles

(2) (4)

P3 < P1 < P2

P3 < P2 < P1 P2 < P1 < P3

P2 < P1 < P3
130. At a certain temperature and at infinite dilution, the equivalent conductances of sodium ohm 1 cm 2

benzoate, Hydrochloric acid and sodium chloride are 240, 349 and 229 equiv1 respectively. The equivalent conductance of benzoic acid in ohm-1 cm2 equiv1at the same condition is: (1) 80 Sol. (3)

(2) 328

(3) 360

(4) 408

C H COOH = C H COONa + HCl NaCl 0 6 5 0 6 5 0 0 = 240 + 349 229 = 360 ohm 1 cm 2 equiv 1

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131.

EAMCET 2010(ENGINEERING)

A solution of concentration C g equiv/litre has a specific resistance R. The equivalent conductance of the solution is: 1000 1000R (1) R/C (2) C/R (3) (4) RC C (3) Equivalent conductance =
Sp.conductance 1000 1x1000 1000 = = Normality of solution RC RC

Sol.

132.

Assertion (A) : White tin is an example of tetragonal system Reason (R) : For a tetragonal system a = b = c and = = = = 900 . The correct answer is: (1) Both A and R are true and R is the correct explanation of A (2) Both A and R are true but R is the correct explanation of A (3) A is true but R is not true (4) A is not true but R is true (3) (A) White tin is an example of tetragonal system (R) For a tetragonal system a = b c What is the slope of the straight line for the graph drawn between ln k and 1/T, where k is the rate constant of a reaction at temperature T? E E (1) (2) 2.303R R E R (3) (4) R E

Sol.

133.

Sol.

(2) Arrhenius equation, E E 1 ln K = ln A - a is a straight line with negative slope , a Plot of ln K and RT T R

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134. If the equilibrium constant for the reaction

EAMCET 2010(ENGINEERING)

2 HI is K +I 2( g ) 2 ( g ) (g) What is the equilibrium constant of 1 1 HI + I H2 (g) 2 ( g ) 2 2( g ) 1 (1) (2) K K H

Sol. (4) Given reaction is reversed and divided by 2 1 1 So , K 2 = = K K1

(3) K

(4)

1 K

135.

The pH of 0.01 M solution of acetic acid is 5.0. What are the values of H + and K respectively? a (1) 1105 M , 1108 (2) 1105 M , 1109

(3) 1104 M , 1108

Sol. (1)

(4) 1103 M , 1108

pH = log H + or 5 = 1105 M = 10

H + = 10 pH

Concentration of solution = 1102 M H+ = C 1105 = = 1103 2 110 K a = C . 2 2 = 1108 = 1102. 1103

136.

A system is provided with 50 Joules of heat and the work done on the system is 10 Joules. What is the change in internal energy of the system in Joule? (1) 60 (2) 40 (3) 50 (4) 10 (1) Heat absorbed by the system is taken as +ve. Work is done on the system is taken as +ve As per 1st law, E = Q + W = 50 + 10 = 60 Joules

Sol.

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137.

EAMCET 2010(ENGINEERING)

A micelle formed during the cleansing action by soap is: (1) A discrete particle of soap (2) Aggregated particles of soap and dirt (3) A discrete particle of dust (4) An aggregated particle of dust and water (2) Aggregated particles of soap and dirt form a micelle. The orange coloured compound formed when H2O2 is added to TiO2 solution acidified with conc. H2SO4 is (1) Ti O (2) H Ti O (3) H TiO (4) H TiO 2 3 2 2 8 2 3 2 4 (4) The orange coloured compound formed when H2O2 is added to TiO2 solution acidified with conc. H2SO4 is Pertitanic acid ( H2TiO4)
Ti SO + H O + 2 H O H TiO + 2 H SO 4 2 2 2 2 2 4 2 4 Orange colour

Sol.

138.

Sol.

( )

139.

Solvay process is used in the manufacture of: (1) K CO (2) KHCO (3) Na CO 2 3 3 2 3

(4) CaCl 2

Sol.

(3) Ammonia Soda or Solvay process is used for the manufacture Na2CO3 Diborane reacts with ammonia under different conditions to give a variety of products. Which one among the following is not formed in these reactions? (1) B H , 2 NH (2) B H (3) B N H (4) ( BN )n 2 6 3 12 12 3 3 6 (2) In the reactions, B H is not formed. 12 12 Which one of the following is the mineral for tin? (1) Galena (2) Cerussite (3) Cassiterite (3) Cassiterite or Tinstone ( SnO2)is a mineral of tin. The oxide of nitrogen formed in thermal decomposition of NH4NO3is (1) NO (2) N2O (3) N2O5 (4) NO2 (2) Thermal decomposition of NH4NO3 gives Nitrous oxide or Laughing gas NH NO N O + 2 H O 4 3 2 2 Page 7

140.

Sol.

141.

(4) Anglesite

Sol.

142.

Sol.

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143. Which one of the following is more acidic? (1) H2O Sol. (2) H2S

EAMCET 2010(ENGINEERING)

(3) H2Te

(4) H2Se

(3) Order of acidic nature of hydrides of VI A group elements is H Te > H Se > H S > H O 2 2 2 2 Which one of the following is formed apart from sodium chloride when chlorine reacts with hot concentrated sodium hydroxide? (1) NaOCl (2) NaClO3 (3) NaClO2 (4) NaClO4 (2) Cl2 reacts with Hot, Conc NaOH and forms Sodium chloride and Sodium chlorate hot , conc. 6 NaOH + 3Cl 5 NaCl + NaClO + 3H O 2 3 2 Helium mixed with oxygen is used in the treatment of: (1) Beri beri (2) Burning feet (3) Joints burning (4) Helium mixed with O2 is used in treatment of asthama. Which of the following is a correct statement? (1) Aqueous solutions of Cu+ and Zn2+ are colorless (2) Aqueous solutions of Cu2+ and Zn2+ are colorless (3) Aqueous solution Fe3+ is green in color (4) Aqueous solution of MnO4 is colorless (1) Aqueous solutions of Cu + and Zn 2+ are colorless since they have no unpaired e-. Both have [Ar] 3d10 configuration. The chemical reaction that involves roasting process is:

144.

Sol.

145.

(4) Asthma

Sol.

146.

Sol.

147.

(1) Fe O + 3CO 2 Fe + 3CO 2 3 2

(3) 2 ZnS + 3O 2 ZnO + 3SO 2 2 Sol.

(2) 2 Al + Fe O 2 Fe + Al O 2 3 2 3
(4) FeO + SiO FeSiO 2 3

(3) Roasting is process in which an ore is heated in the presence of air below its melting point
2 ZnS + 3O 2 ZnO + 3SO 2 2

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148.

EAMCET 2010(ENGINEERING)

The acceptable level of carbon monoxide gas (CO) in the atmosphere is ppm level is: (1) 9 (2) 250 (3) 49 (4) 850 (1) The acceptable level of CO gas in atmosphere is 9 ppm. The conversion of o-acylated phenol in presence of AlCl3 to C-acylated phenol is an example for this type of organic reaction: (1) Addition reaction (2) Substitution reaction (3) Molecular rearrangement (4) Elimination reaction (3) The given reaction is molecular rearrangement, called Fries rearrangement :

Sol.

149.

Sol.

150.

Diels-Alder reaction will not take place with which of the following reactants?

and

and
(2)

(1)

and
and

(2)
Sol.

(4)

(1) Diels-Alder reaction is a reaction between a conjugated diene and an ene.( dienophile) In (1), the reactant is not a conjugated diene. So reaction does not occur. In which of the following, ortho / para substitution by an electrophile is very facile? (1) Nitrobenzene (2) Phenol (3) Benzoic acid (4) Acetophenone (2) Phenol is ortho, is an ctivating group and an o,p - directing group. Which one of the following pairs of 2, 3-butane diol is enantiomeric? (1) 2R, 3R and 2S, 3S (2) 2S, 3S and 2S, 3R (3) 2R, 3S and 2R, 3S (4) 2S, 3S and 2R, 3S (1) (2R, 3R) 2, 3-butan diol and (2S, 3S) -2-3-butane diol are enantiomers of each other. Page 9

151.

Sol.

152.

Sol.

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EAMCET 2010(ENGINEERING)

Note : If the configuration at the two carbons is same in both, the resultant is homomer of original If the configuration at the two carbons is changed, the resultant is enantiomer of original If the configuration at one of the carbons is same but the other is changed, the resultant is diastereomer of original 153. The two enantiomers of secondary butyl chloride differ from each other in which one of the following properties? (1) Boiling point (2) Specific rotation (3) Density (4) C-Cl bond length (2) Enantiomers differ only in specific rotation. Identity the product (A) of the following reaction: BF /1500C 3 C H O C H + CO A 2 5 2 5 500 atm (1) Ethyl alcohol (2) Ethyl propionate (3) Ethanoic acid (2)
BF /1500C 3 C H O C H + CO C H COOC H 2 5 2 5 2 5 2 5 500 atm Ethyl propionate

Sol.

154.

(4) Ethyl acetate

Sol.

155.

Which one of the following gives yellow precipitate with iodine and NaOH solution? (1) CH CHO (2) C H COC H 3 6 5 6 5 (4) CH OH (3) HCHO 3 (1) Iodoform test is given by compounds containing a) Methyl keto ( CH3 CO) group or b) Methyl carbinol ( CH3 CH(OH)- ) group

Sol.

156.

Identify A, B and C in the following reactions:

C H OH/H + KCN Hydrolysis 2 5 CH Cl A B C 3 H O 3

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A (1) B

EAMCET 2010(ENGINEERING)
C C | CH N C H 3 2 5 | CH 3 CH CO H 3 2 CH CO C H 3 2 2 5

CH NC 3

CN NHCH 3 3

(2) (3) (4)

Sol. (3)

CH CN 3 CH CN 3 CH CN 3

CH CONH 3 2 CH CO H 3 2 CH CO H 3 2

( CH3CO)2 O

KCN C H OH / H + +H O ( aq ) CH CN CH COOH CH COOC H 2 5 2 CH Cl 3 3 3 3 2 5 +O H 3 A B

157.

Reduction of nitrobenzene with Zn and alcoholic KOH solution results in the formation of the following compound (1) Hydrazobezene (2) Azobenzene (3) Aniline (4) Phenyl hydroxyl amine (1)
Zn+KOH ( alc ) 2C H NO +10 [ H ] 6 5 2
NN

Sol.

Hydrazobenzene

158.

If the number average molecular weight and weight average molecular weight of a polymer are 40,000 and 60,000 respectively. The polydispresity index of the polymer will be (1) > 1 (2)< 1 (3) 1 (4) zero (1)
Polydispersity Index (PDI) =

Sol.

( ) = 60, 000 =1.5 Number average Mol.Wt ( M ) . 40, 000

Weight average Mol.Wt M W
N

159.

The AT/GC ratio in human beings is (where A = adenine, T = thymine, G = Guanine, C = Cytosine) (1) 1 (2) 1.52 (3) 9.3 (4) 2 (2) AT/GC ratio is 1.52 in human beings Page 11

Sol.

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160.

EAMCET 2010(ENGINEERING)

Identify the non-narotic analgesic from the following: (1) Diazepam (2) Ibuprofen (3) Formalin (2) Ibuprofen is a non-norcotic analgesis

(4) Terpineol

Sol.

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