B.E.

2nd Semester
CHEMISTRY
Max.Marks:100 Note: Attempt any 5 questions. All questions carry equal marks.

Q1. (a) Prove that all spontaneous processes are accompanied by an increase of entropy. (b) State & explain carnot theorem. (c) Calculate the maximum efficiency of a steam engine operating between 110 & 25. What will be the efficiency of the engine if the boiler temperature is raised to 140 , the temperature of the sink remaining the same? (6+8+6) Q2. (a) Derive Gibbs-Helmholtz equation. (b) Show that Gibbs free energy change at constant pressure & temperature is measure of maximum useful work obtainable from a system. (c) Calculate the free energy change accompanying the compression of 1 mole of CO2 at 57 from 5 atm to 50 atm. Assume that CO2 behaves like an ideal gas. (8+6+6) Q3. (a) Explain: (i) Degree of polymerization. (ii) Condensation Polymerization. (b) In particular sample of polymer ; 100 molecules have molecular weight 103 each, 200 molecules have molecular wt. 104 each & 200

molecules have molecular wt. 105 each. Calculate the number average & wt. average molecular wt. (c) Discuss the properties & uses of polyamides. ( 6+6+8) Q4. (a) What are the various classes of chromatography? Bring out clearly the principles involved involved in each case. (b) Write short notes on: (i)HPLC (II) Gas chromatography (10+10)

Q 5. (a) Using IR spectroscopy, how will you determine the oxygen in an organic compound is present as a carbonyl or hydroxyl group? (b) Explain Frank condon principle. Explain its use in UV spectroscopy. (c) Write short notes on: (i) Chromophores (ii) Auxochrome (6+8+6)

Q6. (a) What is an absorption spectra? Explain various electronic transitions in the molecule of acetone. (b) Give various applications of IR, UV spectroscopy in elucidating the organic compound structure. (c) Derive Lambert Beers Law. (5+10+5)

Q7. (a) Explain the theory of dry & wet corrosion & also discuss their mechanism. (b) Write short notes on : (i) Stress corrosion

(ii) Differential corrosion (iii) Inter granular corrosion (8+12)

Q8. (a) Discuss the formation & depletion of ozone layer. (b) Differentiate BOD & COD. (c) What are the causes of photochemical smog & acid rain? (8+4+8)

Disclaimer: Well this looks a little stupid but we are not responsible if any portion of this paper is not relevant with todays syllabus. Due care has been taken to make this paper error free, but there always remains a chance of error so please ignore any typographical error if present..