Chemistry Section 15.

G11 T3

Weekend HW 4
I- Multiple Choices 1. Two or more thermochemical reactions can be summed to determine the overall enthalpy changes based on what law? A. B. C. D. Boyles law Hesss law Gay-Lussacs law law of conservation of energy

2. The standard enthalpy of hydrogen in its standard state A. 0.00 calories B. 0.00C C. 0.00 kilocalories D 0.00 kJ

II Answer the following questions: 1. H for the following reaction is -1789 kJ. Use this and Equation a to determine H for Equation b. 4Al(s) + 3Mn O2(s) 2A l2O3(s) + 3Mn(s) H = -1789 kJ a. 4Al(s) + 3 O2(g) 2A l2O3(s) H = -3352 kJ b. Mn(s) + O2(g) Mn O2(s) H = ? ( ) ( ) ( ) ( ) ( ) ( ) ( ) ( )

( ) ( )

Ans; -521 KJ

2. Two enthalpy of formation equations, a and b, combine to form the equation for the reaction of nitrogen oxide and oxygen. The product of the reaction is nitrogen dioxide: NO(g) + 1/2 O2(g) N O2(g) H rxn = -58.1 kJ a. 1/2 N2(g) + 1/2 O2(g) NO(g) H f = 91.3 kJ b. 1/2 N2(g) + O2(g) N O2(g) H f = ? What is H f for Equation b? Ans; 33.2 KJ 3. Use Hesss law to determine H for the reaction NO(g) + O(g) N O2 (g) H = ? given the following reactions. Show your work . O
2

(g) 2O(g) H = +495 kJ;

3

2O

(g) 3 O
3

(g) H = -427 Kj
2

NO(g) +O

(g) N O

(g) + O

(g) H = -199 kJ

( ) ( ) ( ) ( ) ( ) ( ) ( ) ( ) ( ) ( )

Ans; -233 Kj 4. Explain what is meant by Hesss law ? Hesss law states that the total energy of the system is the same regrdless of whether the reaction occurs in one or several steps.

5. Use Hesss Law to calculate the energy change for the reaction that produces SO3. (Obj. 15.4.2)

2S(s) + 3O2(g) 2SO3(g) H = -792 6. Use Hesss Law to calculate the energy change for the decomposition of hydrogen peroxide (H2O2). (Obj. 15.4.2)

2H2O2 (l) 2H2O (l) + O2 (g)

H = -196 kJ

7. Calculate the enthalpy change with the help of Hesss law for the decomposition of hydrogen peroxide, (2H O (l) = 2H O(l) + O (g)), if the enthalpy of formation of water (2H (g) +O (g)=2H2O(l)) is 512KJ and vaporization of hydrogen peroxide (H O (l) = H (g) + O (g)) is 376 kJ. (Obj. 15.4.2) ( ) () () ( ) ( ) () () ( ) ( )

136 kJ 16. Calculate the enthalpy change for the production of sulfur trioxide(2S(s)+2O (g) = 2SO (g)), the main constituent of acid rain. Given the enthalpy of the formation of sulfur dioxide(2S(g) + 2O (g) = 2SO (g)) is 581 kJ, and the vaporization of sulfur trioxide(2SO3(g) = 2SO (g)+O (g)) is 192 kJ. (Obj. 15.4.2) ( ) ( ) ( ) ( ) ( ) ( ) ( ) ( ) ( )

389 kJ 17. Calculate the enthalpy change of the reaction (Obj. 15.4.2) 2CO(g) + 2NO(g) 2CO (g) +N (g) using thermochemical equations: a) 2CO(g) + O (g) b) 2NO(g) 2CO (g) N (g) + O (g)

The enthalpy of the equation a) is 566.0 kJ and the enthalpy of the equation b) is 180.6 kJ. ( ) ( ) ( ) ( ) ( ) ( ) ( ) ( ) ( ) ( )

746.6 kJ 19. Calculate the enthalpy change of the reaction (Obj. 15.4.2) CH4 (g) + 2Cl2(g) CCl4 (l) + 2H2 (g), using thermochemical equations: a) C(s) + 2Cl2 (g) CCl4 (l) = 128 kJ b) CH4 (g) C(s) + 2H2 (g) = + 75 kJ

( ) ( ) ( ) ( )

( ) ( ) ()

() ( ) ( )

53 kJ