MODEL SOLUTIONS TO IIT JEE 2012

Paper II Code 0

PART I

1 2 3 4 5 6 7 8
B A D C B C A D

9 10 11 12 13 14
C D B C D A

15 16 17 18 19 20
D A, C A, C A, B, C B, D A, B

Section I

1. k

a 2 a
4
A
2 2
(

=
= k

1
2
a
2
(

M = k

a 1
2
A
2
|

\
|
+

=

2. Let Vm = volume of material of shell
Vw = volume of water in shell
Va = volume of air in shell
Outside volume of shell,
V = Vm + Vw + Va (i)
m = density of shell material
w = density of water
a = density of air (treated as zero)
W = weight of floating body
= Vmmg + Vwwg + 0 (ii)
B = weight of water displaced
=
( )
g
2
V V V
g
2
V
w
a w m
w

+ +
= (iii)
(iii) = (ii) [Q Body floats]

[ ]
g
2
V V V
w
a w m

+ +
= Vmmg + Vwwg

[ ]
w
w
m
m
a w m
V V
2
V V V
+
|
|

\
|

=
+ +




a
w
m
m m
V V 2 V +
(
(

|
|

\
|

= 2Vw Vw = Vw
Vw =
a
w
m
m m
V V 2 V +
(
(

|
|

\
|

If 5 . 0
w
m
>

, Vw = Va Vm (where 0 < )
Vw < Va Vw is less than half the volume of
vessel.
If 5 . 0
w
m
<

, Vw = Va + Vm
Vw > Va Vw is greater than half the volume
of vessel .

3. For 0 r
2
R
, B = 0
For R r
2
R
<
B =
|
|
|
|
|

\
|
|

\
|

|
|

\
|
|

\
|


r
2
R
r
2
R
R r 2
2
2
2
0

i.e. non-linear increase with decreasing slope
|

\
|
dr
dB

For r > R, B
r
1






4.










Let the disc rotate for time t, after the body is
projected from P. The position P on the disc
comes to P, such that PP (curved path) = Rt.
But the projected part has an initial velocity
i

R i

v . Hence, in time t its x-displacement is

PP = Rt. Obviously lengthwise curved path
PP and PP (straight) are same. But P is to the
right of P because straight line motion. Also
because projectile motion (Given range
PP <
2
R
) it will land somewhere in P in the
unshaded area. Obviously Q lands in unshaded
region.

5. (L0 + e) =
4
v

L0 + e =
512 4
336

= 0.164 m
= 16.4 cm
L0 = 16.4 cm 0.3 4 (e = 0.3d)
= 15.2 cm

6. Q1 =
( )
2 1
1
C C
QC
+

=
( ) 3 2
3 80
+

= +48 C

7. In one rotation, there are two cycles of relative
velocity, with initial relative velocity = zero.

8. Constant pressure heating of a monoatomic gas
Q = nCp
= ( ) 30 35 R
2
5
2
= 25R
= 208 J

Section II

9. When anti-neutrino is at rest; electron will have
maximum velocity and maximum kinetic energy.
Since there are three particles after disintegration
of neutron (which was initially at rest), if the
electron is at rest, the linear momentum of proton
will be equal and opposite to the linear
momentum of anti-neutrino. This linear
momentum of proton will be more than the case
when the electron was having maximum velocity
and the anti-neutrino was at rest. So the KE of
proton will be more than its KE when electron
was having maximum KE. Consequently, when
electron is at rest, the KE of anti-neutrino will be
maximum but slightly less than 0.8 10
6
eV.

10. When electron is at rest (possible), its KE is zero,
which is the minimum value. If the rest mass of
anti-neutrino is not zero, the velocity attained by
electron cannot be equal to the maximum
velocity attained when rest mass of anti-neutrino
is zero. Hence the maximum KE of electron will
be less than 0.8 10
6
eV.
i.e. 0 K 0.8 10
6
eV

11. |n| =
c
v

v =
n
c


12. For meta-materials, the refracted ray emerges on
the same side of the normal as the incident ray.

13. By the time the CM completes one rotation, all
points on the disc has also completed one
rotation is same for all points (= of CM).

14.





vP = a; vC =
|
|

\
|
+
2
R
a
vQ = |

\
|
+ R 2 a
vQ vC =
2
R
' R ;
2
R
=
= =

' R
v v
C Q


Axis of rotation is vertical.

C
Q
O
a
P
2
R

2
R

Y
X
O


Q



P
P
0.7 R
0.3R
R
0.8R
P
P



Section III

15. t =
a
2l

a =
(

2
mr
1
sin g
; P > Q
ap < aq tP > tQ

|
|

\
|
+
=
2
2
mr
1
mgh
mv
2
1

KQ > KP
VQ > VP Q > P

16. The net flux linked with coil is zero, whether
current is constant or current is changing.

17. ZL = ( ) = + 2 50 50 100 5 . 0
2 2

ZC = = +
|
|

\
|


2 100 100
100 10 100
1
2
2
6

iL = A 2 2 . 0
2 50
20
Z
20
L
= = ;
iC = A
2
2 . 0
2 100
20
=
V50 = i1 50 = V 2 10 50 2 2 . 0 =
V100 = V 2 10 100
2
2 . 0
= ;
i =
200
20
200
4
50
4
i i
2
C
2
L
= + = +
=
10
1
= 0.3162 A
0.3 A

18. Due to +q and +q, q, q
E1 = 2K along OD
Due to +2q and 2q,
E2 = 4K along OD
E = E1 + E2 = 6K along OD
V at O is zero (as net charge is zero)
PR is the equatorial line of three dipoles
VPR = zero; VST is not same.

19. vesp = gR 2
= R R|

\
|

R (Q same )
RP = R, RQ = 2R (from surface areas)
RP = 9
1/3
R [RR
3
= RP
3
+ (2RP)
3
= 9R
3
]
(vesc)R > (vesc)Q > (vesc)P
Also
( )
( )
3 9
v
v
3 / 1
P esc
R esc
=

( )
( ) 2
1
R 2
R
v
v
Q esc
P esc
= =

20. i

R 3 v
O
=
(Considering instantaneous centre of rotation)
k

30 cos
2
R
i

30 sin
2
R
v
PO

=
= k

4
R 3
i

4
R
+

4
R 3
i

4
R
R 3 v v v
PO O P

+ |

\
|
= + =
= k

R
4
3
i

R
4
11
+



PART II

21 22 23 24 25 26 27 28
C C B B D D A A

29 30 31 32 33 34
B D C A C A

35 36 37 38 39 40
B, D A, C A, C, D A, C, D A, C A, B, C

Section I

21. Paramagnetic Ni
2+
complex is tetrahedral
Diamagnetic complex is square planar

22. P4+ 3NaOH + 3H2O PH3 + 3NaH2PO2
2NaH2PO2 PH3 + Na2HPO4
Oxidation number of P in PH3 is 3
Oxidation number of P in Na2HPO4 is + 5

23. Oxidising agent O2
Reducing agent Zn dust

24. -keto acids undergo decarboxylation readily on
heating

25. C2H2(g) 2C(g) + 2H(g) H = 1410 + 330 225
= 1515 kJ
x + 2 350 = 1515
x = 815 kJ mol
1


26. Xe
F
O
F
O

sp
3
d hybridised





See-Saw

27. CH
3
C CH
3
CH
2
O
CN


CH
3
C CN CH
2
O
CH
3
H
+


CH
3
C COOH CH
2
OH
- H
2
O
CH
3

CH
3
C COOH CH
CH
3
Note: In presence of conc. H2SO4, cyanide may
get hydrolysed to give amide (Option D).
28. Tb = Kb m
m = 10
M
5 . 2
76 . 0
2
2
=
M2 = 9.5

1
1
2
2
0
0
W
M
M
W
P
P P
=

100
18
5 . 9
5 . 2
760
P 760
=

760 P = 36
P = 724

Section I

29. M M
2+
+ 2e

+ +
+

+
2 2
2
M ) M 001 . 0 ( M
M 2e M) (0.001 M

Ecell =
3
sp
3
4 / K
10
log
2
059 . 0


(For MX2 M
2+
+ 2X


S 2S
Ksp = 4S
3
)
0.059 =
3
sp
3
4 / K
10
log
2
059 . 0



2
3
sp
3
10
4 / K
10
=

Ksp = 4 10
15






30. G = nFE
= 2 96500 0.059 J
= 11.4 kJ mol
1


31.
2 2 2 2
Cl O H CaAc HAc 2 CaOCl + + +
2KI + Cl2 2KCl + I2
2Na2S2O3 + I2 2NaI + Na2S4O6
Number of moles of CaOCl2 =
2
1
number of
moles of Na2S2O3
=
3
10 25 . 0 48
2
1


Molarity of (CaOCl2) bleach solution
=
25 2
25 . 0 48

= 0.24

32. CaOCl2 is the salt of HCl and HOCl with Ca(OH)2
The anhydride of HOCl is Cl2O
2HOCl Cl2O + H2O

33.
CHO
(CH
3
CO)
2
O
CH
3
COONa
(I)



CH CH COOH
(i) H
2
/ Pd - C
(ii) SOCl
2



anhy.AlCl
3
CH
2
CH
2
C
O
Cl



CH
2
CH
2
C
O
(K)


34. The compound (I) is benzaldehyde

Section I

35. Graphite has higher electrical conductivity than
diamond (A). Graphite has higher CC bond
order than diamond.

36. Graphs I and III represent physisorption and
graphs II and IV represent chemisorption

37. T1 = T2, since isothermal
T3 < T1, since adiabatic expansion
Uisothermal = 0
Uadiabatic expansion = ve

38. 3KI + 2K3Fe(CN)6 2K4Fe(CN)6 + KI3

4
ZnSO
Zn2Fe(CN)6 + KI3

Filter
residue, Zn
2
Fe(CN)
6
filtrate, KI
3
(brown)

Zn2Fe(CN)6+ 8NaOH 2Na2[Zn(OH)4]
Soluble
+ Na4[Fe(CN)6]
KI3 + starch blue colour

39.
O
O
(T)
LiAlH
4
CH
2
OH
CH
2
OH



CHO
CHO
(V)
CH
2
OCOCH
3
CH
2
OCOCH
3
(W)
CrO
3
excess
(CH
3
CO)
2
O


40. (A), (B), (C)



PART III

41 42 43 44 45 46 47 48
A C C A B D D B

49 50 51 52 53 54
B C A B D A

55 56 57 58 59 60
A, B A, B, C, D B, D B, C A, D A, B

Section I

41. Eq. of plane x + 2y +33 2 + (x y+z-3) = 0
(1+) x +(2)y +(3+)z 2 3 = 0 -----(1)
Distance from (3, 1, 1) to Eq (1) is
3
2

Clearly distance from (3, 1, 1)
to Choice (A) is
3
2
only satisfies

42. ( ) 29 b a
2
=
29 b . a 2 b a
2
2
= + +
Let k 4 j 3 i 2 c + + =
Given b c c a =
= ( ) c b
( ) 0 c b a = +
b a + is parallel to c
b a + = ( ) k 4 j 3 i 2 + + \
(2) (7) + (3) (2) + (4)3 = (14+6+12)
4
2
+ 9
2
+16
2
= 29
= 1
Choice (C)

43.
p 2 sin p sin 2
p 2 sin p sin 2
+

{ }
{ } p cos 1 ) p sin 2 (
p cos 1 ) p sin 2 (
+

cosp =
2
5
2
7
2
4
4
25
4
49

+


35
29
70
58
=

32
3
64
6
35
29
1
35
29
1
29 sin p sin 2
p 2 sin p sin 2
= =
+

=
+

S = |

\
|
+
5
+ 2
2 2
7
2
1
= 4
S a =
2
1

S b =
2
3

S c = 2
= 6 2
2
3
2
1
4 =

2
= 6
Choice (C)

44. D1, D2, D3, D4
Total number of choices = 6
4


6 6 6
5 5 5
4 4 4
3 3 3
2 2 2
1 1 1
D D D
3 2 1
6 1 = 6
Total cases 5 6 3 2 = 180

4 3 1
3 2 1
D D D
3 2 1

------------------- Total cases 6 5 4 3= 360
Favorable cases = 6+180+360
= 546
= 6 91
Probability =
216
91
6
91 6
4
=

Choice (A)

45.

\
|

+
+
2
2
2
2
2
x cos
x
x
log x cos x
R
2
Q
P
2
5
2
7

+
2
0
2
0 xdx cos x 2
2 ( )
|
|
|

\
|

xdx sin x 2 x
2
0
x sin 2

2 ( )
|
|
|

\
|
+

) xdx cos x cos x 2

4
2
0
2

= ( )
|
|
|

\
|

2
0
2
x sin 2
4
2
= 4
2
2
4
2
2 2

=
|
|

\
|

46. + = P 2 P
T
-------(1)
Taking transpore
P = 2 +
T
P -------(2)
P ( ) P P 2 P
T T
=
P
T
= P
P is symmetric
P
T
= 2P +
P = 2P +
P =
PX = X
Choice (D)

47. A1, A2, --------Corresponding A. P
A1 =
25
1
A ,
5
1
20
=
d 19
5
1
25
1
+ =
d =
19 25
4

An =
19 25
n 4 99

n 4 99
19 25
P . H of term n
th

=
99 4n < 0
4n > 99
N > 24
4
3

Min value = 25
Choice (D)

48. =
2
1
1 a 1 6
1
1 a 1 3
1 a 1 6

+ +
=
+
+
as a 0+
lim() = =
+
+
1 a 1 3
1 a 1
lim
3
2
2
1
) a 1 (
3
1
) a 1 (
2
1

+
+


2
3
=
So Choice (C)

Section II

49. f (x) 0 for all x
and g(x) =
( )
) x ( f x cos
1 x
1 x 2
(

Consider x cos
1 n
4
2 x cos
1 x
) 1 x ( 2

+
=
+

Derivative =
( )
x
1
1 x
4
2

+

=
( )
( )
2
2
1 x x
1 x x 4
+
+
< 0
< 0 in {(1, )}
g(x) is decreasing in (1, )
Choice (B)

50. P (1 x)
2
sin
2
x +x
2
+2x = 2 (1+x
2
)
(1x)
2
sin
2
x = x
2
2x +2
= (1 x)
2
+1
Sin
2
x =
( )
( )
2
2
x 1
1 x 1

+
> 1 y x 1
no x exists P is false
Q = 2(1 x)
2
sin
2
x +2x
2
+1 = 2x +2x
2
\
Sin
2
x =
( )
1
x 1 2
1 x 2
2

If 2x 1 2 ( 1 2x +x
2
)
ie 2x
2
6x +3 0
which could be simplified\
Q is True

51. a1 = 1
a2 :
0 1
1 1
2
a3 :

0 1 1
1 0 1
1 1 1
3
a4 : 5
1 0 1 0 1
3 0 1 1 1
1 1 1 1 1

a5

3 : zeros two
4 : zero one
1 : ones all
8
We note that for a positive integer x,
an+1 = an +an1
Hence Choice (A)




52. b6

all ones 1
one zero 4
two zeros 3
Total 8 cases
Choice (B)

53. x = 4 is not tangents to the first circle
y = 2 is not a tangent to the 2
nd
circle
x + 3 y = 4 is not a tangent to the 2
nd
circle
x + 2 2 y = 6 is tangent to both
Choice (D)

54. L is of the form x 3 y = k
and x 3 y = 1
is tangent to 2
nd
equation
Choice (A)

Section III

55. P(x) P(Y|X) = P (XY)
P(X) =
2
1
3
1
6
1
=
P(Y) =
3
1
2
1
6
1
=
P(X) P(Y) =
6 3
1
2
1 1
= = P(XY), X, Y are
independent .
=
3
2
6
1
3
1
2
1
= +
(A) and (B) are true & (C) is false
X
C
, Y are independent
P(X
C
Y) =
3
1
6
1
3
1
2
1
1 = |

\
|

Choice (A) & (B)

56. f(x) = ( )( )

x
0
t
dt 3 t 2 t e
2

fx= ( )( ) 3 x 2 x e
2
x

f(x) = ( )( ) ( ) 3 x e 3 x 2 x x 2 e
2 2
x x
+
( ) 2 x e
2
x
+
= ( )( ) [ ] 5 x 2 3 x 2 x x 2 e
2
x
+
= ( ) 5 x 12 x 10 x 2 e
2 3 x
2
+
f(x) = 0 x = 2, 3

It is obvious that f(x) = 0 at atleast one c (2, 3)
x (, 2) f (x) > 0
x (2, 3) f (x) < 0
x (3, ) f(x) > 0
Choice (A), (B), (C) & (D)

57. = bn1 + cosx (2n 3, 2n 2)
f(x) = an 1 +sinx for x [2n-2, 2n 1]
= bn + cosx for x (2n1, 2n]
= an + sinx for x {2n, 2n+1]
= bn+1 + cosx for x (2n+1, 2n+2)
= an+1 +sinx for x (2n+2, 2n+3)
At 2n 2 bn1 +1 = an 1 bn1 = 1
At 2n1
an1 = bn 1 an1 bn = 1
At 2n1
bn+1 = an an bn = 1
at2n+1 an bn+11 an bn+1 = 1
Thus (B) & (D)

58. Since the line are Coplanar
0
k 2 5
2 k 2
0 0 2
=

2 (k
2
4) = 0
k
2
=4 k = 2
Equation plane is 0
2 2 5
2 2 2
z 1 y 1 x
=

+

y z = 1 and y +z = 1
Choice B and C



59. |adjP| = IP|
n 1

|adjA| = 4
|P|
2
= 4
|P| = 2
A and D are true

60. f(cos4) =
1 cos 2
cos 2
2
2

+
2 cos
1 2 cos

f ( 2cos
2
2 1) =

+
2 cos
1
1
f (2x
2
1) =
x
1
1+
Where 2x
2
1 =
3
2
x
3
1
2
=
x =
2
3
x
1
3
2
=
f
2
3
1
3
1
= |

\
|

Choice (A) and (B) + +
2 3
1 1