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physical properties
partial charges
physical states
KINDS OF IMFAS KINDS OF IMFA electrostatic Ion dipole H bond Dipole-dipole Ion-induced dipole Dipole induced diploe Dispersion COMPOUNDS THAT FORMED THEM Ionic with ionic Ion with polar Polar H terminal with lone pairs of small electronegative atoms Polar with polar Ion with non polar Dipole with non polar Non polar with non polar
Examples
electrostatic NaCl NaCl
Na
H2O
ion dipole
CH 3 C = O
H- bond
CH 3
CH3 C=O
H 2O H 2O
CH3
dipole-dipole
Na
dispersion O = O O = O
IMFA and Solubility For dissolving to happen, 3 processes must occur 1. Dissolved substance (solute) must separate (IMFA breaking- endothermic heat) 2. Dissolving substance (solvent) must separate (IMFA breaking-endothermic heat) 3. Solute and solvent must mix (IMFA forming-exothermic heat)
IMFA between solute and solvent > IMFA among solute and or IMFA among solvent _
Summarized as : LIKE DISSOLVES LIKE ; polar solvent dissolves polar solute Non polar solvent dissolves non polar solute
Kinds Solid IMFA >>> Gas liquid IMFA <<< IMFA is continuously being formed and continuously being broken
KE
KE
g 100
l - g 540 cal/g
TEMP 25 0 s -4 80 cal/g
s - l
ENERGY
LATENT HEATS Heat of Fusion- amount of energy needed to melt 1 gram of a substance at its melting point H fusion water = 80 cal/g Q= mass X H fusion Heat of Freezing = energy released to change 1 gram of liquid to solid Heat of Fusion (endo) = Heat of Freezing (exo)
Heat of Vaporization amount of energy needed to evaporate 1 gram of a substance at its boiling point H vap water = 540 cal/g Q = mass X H vap Heat of Condensation= energy released to convert 1 gram of gas to liquid
SPECIFIC HEATS= Energy needed to change the temperature of 1 gram of a substance 10Celsius For water: Sp. Heat = 1 cal/g-0C