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Hazard Tags
SPILL MANAGMENT
COMMON KINDS OF SPILL CHEMICAL SPILLS:
and drugs. These include all chemicals i.e Cidex, spirit, acids, bases
BIOLOGICAL SPILLS: These include blood & body fluids and other potentially
infectious materials.
MERCURY SPILLS: These include spills of mercury from B.P apparatus &
thermometers.
Wear appropriate personal protective equipment like Gloves, Goggles, Vapor Masks, and Respirators etc. Check with pH paper see if it is acidic or basic nature spill ( if the substance spilled is unknown). If the spill is acidic or basic then apply appropriate neutralizer to the perimeter of the spill Mix thoroughly until neutralization is complete. Check the mixture with pH paper to ensure neutralizalization is complete ( for Hypochlorite, Cidex & Spirit neutralization is not needed, just wash with water). After neutralization is done, put absorbent materials on the spill, scoop up the material & transfer mixture into red polyethylene bag and tie shut & send for incineration. Wash and clean the area with water.
Precautions
Alert people in immediate area of spill. Wear appropriate protective gloves, goggles, long sleeve lab coat. Avoid breathing vapors from the spill Confine spill to small area & absorb on absorbent pads. Clean spill area with soap & water. Collect all contaminated absorbent, gloves & residues in plastic bag lined garbage can. Label and dispose of properly.
Solvents and pesticides are examples of compounds that can be absorbed through the skin.
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Chemical Toxicity
Chronic Toxicity and Acute Toxicity
Some chemicals will only make you sick if you get an acute or high dose all at once. Example - ammonia
Some chemicals are mainly known for their chronic or long-term effects. Example - asbestos Most chemicals have both acute and chronic effects. Example carbon monoxide 17
Chemical Toxicity
Chemical Exposure Limits
Many chemicals have exposure limits, or allowable amounts of a chemical in the air.
These limits are often called PELs or TLVs. They are based on 8-hour average exposure or ceiling or peak levels.
BIOLOGICAL SPILLS
Put on 3M Face masks due to dissipation of aerosols in air then enter the area. Use specific decontaminant like Sodium Hypochlorate / Sodium Thio Sulphate [ cyto spills] let it stand for 20 min. Put absorbent materials, collect and Transfer all contaminated material into a red bag Wash area with soap / detergent, water and collect with paper towels and discard in red bag with disposable gloves and send for incineration Wash hand and the effected person thoroughly, take shower and change clothes.
1 ampoule or less than 100 ml Wear disposable chemotherapy gowns and a double layer of surgical latex gloves. Use chemical splash goggles if necessary. Clean up liquids with absorbent pads or ether absorbent materials; clean up solids by washing area twice with detergent solution decontaminant like Sodium Hypochlotate / Sodium Thio Sulphate. Follow with a clean water rinse. Place all waste items, including any broken glass, used absorbent pads, gown, gloves and any non-cleanable contaminated items in a puncture resistant chemotherapy waste container. Wash any contaminated reusable items in a sink with detergent, followed by a clean water rinse. Wear double gloves.
SMALL SPILLS:
Greater than 1 ampule or 100 ml Limit spread of spill by covering liquid with absorbent pads spill control pillows, or other absorbent materials. Cover solids with a damp cloth or towel. Care must be taken not to create aerosols. Restrict access to the spill area. Fill incident report:
LARGE SPILLS:
poisoning can result in severe health problems affecting the nervous system and other organs.
Tremors Changes in vision or hearing Sleeplessness Weakness Difficulty with memory Headaches Anger Shyness and nervousness
of exposure
Inhalation
Main
Skin absorption
Personal
MERCURY SPILLS
Evacuate the spill area, after people leave make sure that their shoes clothing and other articles are not splashed with mercury. Secure the area & restrict admission.
Lower the temperature, cooler the temperature, the less mercury vapors that will be released into the air.
Turn off ventilating / air circulating system that could circulate air from the spill area to other areas
MERCURY SPILLS
Close interior doors, leading to inside areas and open exterior doors & windows for force ventilation outside. Contain the spill, surround or block off mercury to keep it from spreading onto sloped or porous surface divert all the mercury from floor drains and cracks or crevices. Assemble clean up supplies, Hg absorb powder, or powdered sulfur, zinc, paper tissues, plastic container with lid, plastic dust pan, plastic sponge, masking tape, syringe. Gloves, Flashlight, Floor sign, Plastic box, Red Bags.
MERCURY SPILLS
Dress appropriately; remove all the jewellery from hands & wrists so that mercury does not combine with precious metals (mercury amalgamates with precious metals). Pick all the visible droplets, clean up the mercury beads using plastic squeegee / rubber sponge, index card, plastic dust pan, masking tape. Transfer mercury into unbreakable plastic container tighten the lid so that vapors do not escape. Remove dispose off contaminated carpet/ clothes and other articles that come in contact.
Sprinkle fine powder sulfur / zinc on spill site; bind any remaining mercury with these powders. Droplets may also be detected by a sodium sulfide solution; this solution may also be sprayed on an affected person (but not the eyes, mucous membranes, or the mouth). Any mercury present will show up as dark, reddish brown stains. Put in land fill site do not dispose in trash Wash hands using sulfur soaps, vinegar or hydrogen peroxide solution and the area with hypochlorite solution. Continue ventilation of the area for 2 days.
MERCURY SPILLS