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A c
= =
|
`
|
A c
) \ .
=
A =
A ~
}
}
0
2
1
2
1
( ) lim
( )
( )
( )
P
T
P
T
P
T
T
P
T
H H
C T p
T T
d H C T dT
H C T dT
H V P C T dT
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A c
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Expressed in any unit of energy per unit
amount per unit temperature interval
Example:
J/(mol.K) or Btu/(lbm.F)
Function of temperature and are expressed in
polynomial form:
Cp = a + bT + cT
2
+ dT
3
Simple relationship between CpCv in two
cases:
Liquids and solids: CpCv
Ideal gases: Cp=Cv + R
Where:
R=gas constant
Polynomial expression for Cp:
Refer Table B.2
Usually based on experimental data for
listed compounds
Provide a basis for accurate calculations of
enthalpy changes
Kopps rule:
A simple empirical method for estimating
the heat capacity of a solid or liquid at or
near 20C
Cp for a molecular compound is the sum
of contributions (given in Table B.10) for
each element in the compound
(Cp)ca(OH)2 =(Cpa)ca + 2(Cpa)o+2(Cpa)H
= [26+(2 X 17) +(2X 9.6)]J/(molC)
= 79 J/(mol.C)
1.The heat capacity at constant pressure of
hydrogen cyanide is given by the expression
/( . ) 35.3 0.0291 ( ) p C J mol c T c
(
=
+
a) Write an expression for heat capacity at
constant volume for HCN, assuming ideal gas
behavior
b)Calculate H(J/mol) for the constant
pressure process
( , 25 , 0.80 ) ( ,100 , 0.80 ) HCN V C atm HCN V C atm
c) Calculate U( J/mol) for the constant volume
process
( , 25 , 50 3/ ) ( ,100 , 50 3/ ) HCN V C m kmol HCN V C m kmol