Example

A 0,467 g sample containing sodium bicarbonate (a monoacidic base) and titrated with a standard solution of HCl, requairing 40,72 ml. The hydrocloric acid was standarized by titrating 0,1876 g sodium carbonate, wich required 37,86 ml. Calculate the percent sodium bicarbonate in the sample. Solution : NHCl = meq NaHCO3 = mg/BE (BM) mL HCl mL

Persen NaHCO3 = ....................

Problems

Calculate the molar concentration of all the cations and anions in a solution prepared by mixing 10.0 mL each of the following solutions: 0.100 M Mn(NO3)2, 0.100 M KNO3, 0.100 M K2SO4. Calculate the grams of each substance required to prepare the following solution: (a) 250 mL of 0.100 M KOH (b) 1.00L of 0.0275 M K2Cr2O7 (c) 500 mL of 0.500 M CuSO4 How many milliliters of concentrated hydrochloric acid, 38% (wt/wt), specific gravity 1.19, are required to prepare 1L of a 0.100 M solution

Solution

Problems

How many milliliters of 0.10 M of H2SO4 must be added to 50 mL of 0.1 M NaOH to give a solution that is 0.050 M in H2SO4? Assumes volumes are additive.

Solution

Problems

A preparation of soda ash is known to contain 98.6% Na2CO3. If a 0.678 g sample requires 36.8 ml of sulfuric acid to complete neutralization, what is the molarity of the sulfuric acid solution? A sample of USP grade citric acid (H3C6O7, three titratable protons) is analyzed by titrating with 0.1087 M NaOH. If a 0.2678 g sample requires 38.31 ml for titration, what is the purity of the preparation? (USP requires 99.5%)

Solution

Problems

A solution is prepared by dissolving 7.82 g NaOH and 9.26 g Ba(OH)2 in water and diluting to 500 ml. What is the normality of the solution as a base? What weight of arsenic trioxide, As2O3, is required to prepare 1L of 0.1000 N arsenic (III) solution? The sulfur content of steel sample is determined by converting it to H2S gas, absorbing the H2S in 10 ml of 0.00500 M I2, and then back titrating the excess I2 with 0.00200M Na2S2O3. If 2.6 ml Na2S2O3 is required for titration, how many milligrams of sulfur are contained in the sample? A potassium permanganate solution is prepared by dissolving 4.68 g KMnO4 in water and diluting to 500 ml. How many milliliters of this will react with the iron in 0.500 g of ore containing 35.6% Fe2O3?
Solution