COMPARATIVE EVALUATION OF EURASIAN NATURAL CHLORIDESULPHATE WATERS` COMPOSITION BY MEANS OF MATHEMATICAL MODEL FOR MINERAL WATERS` CLASSIFICATION

* Kornilov, N.I., ** Surdu O., *** Kornilova, E.N., * Domnitsky D.A. **Surdu T-V Stavropol State Agrarian University, Stavropol, Russia ** Ovidius University, Constanta, Romania, *** OAO "Stavropol Elektronproekt", Stavropol, Russia

Aims of the study

to establish a quantitative dependences connecting composition and properties of the regional Eurasian mineral water on the basis of a mathematical model; to assess the composition of some mineral waters, brine lakes, squeezed waters, medicinal mud/clay/sediments in Russia and Romania.

Materials

samples of chloride-sulphate mineral waters, mud/clay/peat, from Russia, Romania, Germany, France, Italy, Spain, Ukraine and other countries of the Eurasian continent

1. Methods of work

statistical methods of the linear regression equation

analytical dependences that connect characteristic indicators of the mineral waters structure ( , B, ) to independent variables of ionic composition and concentration (total salinity, ionic composition, acidbase balance, conductivity and some other characteristics)
characteristic indicators" , calculated from experimental data, refers to those functions of the system, through which, or through whose derivatives, can expresses in explicit form the composition and mass properties of water-salt systems

1.1. Parameters for the mathematical description of structure of water-salt systems

M

Cn

- the total mineralization of water (g/dm3). - the gram-equivalent of a salt system of mineral water, g/eqv - concentration of salts in solution (eqv/dm3 )

M Cn

Where

ratio of equivalent anions cloride and sulphate

function of one variable

X Cl

X SO 2
4

presented in the form of the equation

where a and b are constants corresponding to mineral water chloride-sulfate type

Cl a( X

2 SO 4

b )

1.2. characteristic indicator well-defined value of the salt solution and depends on: the nature of dissolved salts, the composition and concentration of ions, forming a salt solution the dilution of the solution with a given value of demineralized water does not change its value Solutions of different concentrations with similar values of belong to the same subgroup (class) of water. Solutions with close relation of constitute a certain class of mineralized water

1.2.characteristic indicators
Function B (g2 /eqv2)
in relation to the magnitude
of the ratio

Indicator combine mineral water in a separate class of a certain group of mineral water
A logarithmic conversion of the equation into linear regression ecuation allows us to introduce it in computer program Statistics-7 for mathematical statistics A and D are coefficients

X Cl X SO 2
4

2. Results and Discussion

2.1. Standard chloride-sulfate waters of Russia

The natural mineral waters of the chloride-sulfate type included in the GOST R are water solutions of chloride and sulfate salts of sodium, magnesium and calcium, the total content of which in solution is up to 90 eqv% or more Processing array values in total mineralization and ion composition was carried out on mean values of the variables listed in GOST R, subject to the material balance of the anions Cl-, SO42-, HCO3- and cations Ca 2+ , Mg 2+ , Na+ and K+, forming a salty solution of mineral waters.

Mineralization M and ions composition of the reference mineral chloride-sulphate waters of Russia

1 2 3 4 5 6 7

Title of water Kashinskaja Uglichskaja Bujskaja Igevskaja Irkutskaja Lipezkij bjuvet Anapskaja Lisogorskaja Don Nigne-Ivkinskaja Ergeninskaja Novo-Igevskaja Kaspij Solvichegodskaja Hilovskaja

Mineralization , M (g/dl) 2,825 4,094 11,945 4,350 2,050 3,301 3,067 18,165 2,850 7,598 5,700 15,420 6,416 8,850 3,535

Ion composition of water, mg-eqv/dl

HCO30,76 1,56 0,81 3,28 4,67 4,32 7,79

SO4 235,43 45,31 133,26 46,88 17,71 27,21 21,88

CI7,13 15,49 45,74 16,90 9,30 17,81 15,49

Ca2+
20 14,59 20 20 13 3,75 1,21

Mg2+
10,28 10,79 18,51 18,57 8,23 2,06 3,98

Na+ + K+
13,04 36,98 141,3 28,78 9,78 43,48 39,97

8
9 10 11 12 13 14 15

7,7
5,74 1,46 6,56 0,82 13,75 0,82 2,36

159,9
21,35 59,37 40,62 99,38 27,67 43,75 17,21

118,9
16,90 60,83 42,25 144,93 56,65 94,37 39,84 8,25 25 27,5 30 0,42 2,5 18,75

65,8
9,98 20,27 12,34 8,64 1,03 8,23 14,40

195,7
25,67 76,09 50 206,52 95,65 123,9 26,09

X SO and Quantity of general mineralization M , ratio characteristic indicators of composition , B and of the reference mineral chloride-sulphate waters of Russia
2 4

X Cl

1 2 3 4 5 6 7 8

Title of water Kashinskaja Uglichskaja Bujskaja Igevskaja Irkutskaja Lipezkij bjuvet Anapskaja Lisogorskaja

(g/dl) 2,825 4,094 11,945 4,350 2,050 3,301 3,067 18,165

CI- / XSO4 20,201 0,342 0,345 0,360 0,525 0,654 0,708 0,744

(g/eqv) 65,21 65,65 66,43 64,92 65,39 66,97 67,87 63,40 (g2 /

eqv2)

(g2 /

eqv2)

2126 2155 2207 2107 2138 2243 2306 2010

10580 6320 6396 5854 4072 3429 3257 2701

9
10 11 12 13 14 15

Don
Nigne-Ivkinskaja Ergeninskaja Novo-Igevskaja Kaspij Solvichegodskaja Hilovskaja

2,850
7,598 5,700 15,420 6,416 8,850 3,535

0,791
1,024 1,040 1,458 2,047 2,157 2,315

64,78
62,45 63,61 62,91 65,42 61,54 59,50

2099
1950 2023 1979 2140 1894 1770

2653
1904 1945 1357 1045 878 765

2. Results and Discussion

2.1. Standard chloride-sulfate waters of Russia

Mathematical treatment of the values of the characteristic parameter , allowed obtaining an analytical expression for the function ln in the form of a linear regression equation:

ln ln

f [ln( =

Cl

)]
SO 2 4

= 7,6302 1,0511

X Cl

X SO 2
4

r = 0,9974

where: r - correlation coefficient.

2. Results and Discussion

2.1. Standard chloride-sulfate waters of Russia.
Graphic dependence of function ln = f [ln(CI- / XSO4 2- )] for standard chloride-sulfate mineral water of Russia

2. Results and Discussion

2.2. Eurasian regional chloride-sulfate water
1 1 2 3 4 5 6 7 8 9 Title of water 2 Acqua de Cavabaa (Spain) Batalinskay (Ru) Rubeg (Ru) Lake B. Solenoje-mud (Ru) Lake Sengileevskoje (Ru)

M
(g/dl) 3 86,550 20,949 7,982 243,68 0,234 34,890 4,110 0,193 10,052

CI- / XSO4 24 0,061 0,131 0,197 0,201 0,204 0,234 0,256 0,263 0,356

(g/eqv) 5 71,20 65,82 65,28 65,13 65,21 60,32 68,94 65,87 61,54

(g2 /

eqv2) 6

41550 16540 10820 10550 11570 7770 9280 8250 5719

Kissinger Bitterwasser Heilwasser (G)

Staroeletskaja (Ru) Slanic Moldova 8-bis (Romania) Nickolina Balka (Ru)

10
11 12 13 14 15

Lake M. Solenoje (Ru)

Nezlobinskaja (Ru) Krakowianka (Pol) Feodosiiskaja (Ukr) Lake B. Tambykan, (mud mortars) (Ru) Lake B. Tambykan (Ru)

145,65
2,980 2,714 3,957 17,724 22,982

0,426
0,454 0,460 0,540 0,543 0,547

63,26
73,93 65,71 59,7 62,52 62,90

4697
6071 4693 4067 3643 3573

2. Results and Discussion

2.2. Eurasian regional chloride-sulfate water
16 17 18 19 20 21 22 23 24 25 Dax (France) Slanic-Moldova, 5 (Rom) Lake Techirghiol (mud mortars), (Rom) Kaspij Sea (Ru) Antonius Heilwasser (G) 75,346 10,547 2,136 15,499 73,238 3,197 6,926 16,031 Title of water

M
(g/dl) 0,987

CI- / XSO4 20,575 0,658 2,107 2,300 2,331 4,091 4,320 5,348 5,889 6,572

(g/eqv) 67,13

(g2 /

eqv2)

3940 3300

60,64 59,44 66,08 62,40 58,90 62,67 66,15 58,82

873 768 937 476 402 367 372 263

Press water of dark-grey clay, sample 10 (Ru)

Lake Techirghiol (Rom) Kujalnik 6 (Ukr) Maxbrunner Heilwasser (Ger) Black Sea (Ru)

26
27 28 29 30 31

Witjaevskij Liman (Ru)

Thermal Baths Scrajo (Italy) Press water of dark-grey clay, sample .11 (Ru) World`s Ocean Lake Solenoe (Ru) Lake Golybitskoe (Ru)

70,579
14,159 17,382 35,080 79,988 26,250

8,442
8,877 9,364 9,745 12,657 23,528

57,79
61,29 59,53 58,01 57,47 58,83

198
212 189 173 131 74

2. Results and Discussion 2.2. Eurasian regional chloride-sulfate water Graphic dependence of the function ln = f [ln(CI- / XSO4 2- )] for the Eurasian regional mineral waters
11
Aqua de cavabana

10
Batalinskay Lake B. Solenoje Lake Sengileevskoje Staroeletskaja Slanic-Moldova, N8 bis

Kissinger Bitterwasser Heilwasser Nezlobinskaja Nickolina Balka Krakowianka Feodosiiskaja Lake M.Solenoje
Lake (mud mortars) B. Tambykan

8 ln 7

LakeB.Tambykan

Slanic-Moldova, N5

Dax

Lake Techirhiol, mud mortars Kaspij Sea

Antonius Heilwasser

Press water of dark-grey clay number 10

Maxbrunner Heilwasser Lake Techirghiol Kujalnik N6 Black Sea Thermal Baths Scrajo
Witjaevskij Liman
Press water of dark-gray clay number 11.

World's Ocean Lake Solenoe

Lake Golubitskoe

4 -4

-3

-2

-1

0 ln (X CI-/ XSO2-) 4

2. Results and Discussion

2.3. Comparative estimate of the Eurasian regional and standard water Russia chloride-sulphate type

The coefficients A, D and r for the Eurasian regional and standard mineral waters Russia chloride-sulfate type

Coefficients

Mineral waters
The reference waters of Russia The Eurasian regional waters Association of the reference waters of Russia and Eurasia regional waters

2059 2025 2040

Correlation coefficient r D 1,0511 1,0549 1,0572 0,9974 0,9987 0,9986

2. Results and Discussion

2.3. Comparative estimate of the Eurasian regional and standard water Russia chloride-sulfate type

Statistical analysis of the data showed that in all cases r = 0,997 - 0,999, and the error of calculations does not exceed the stdv 5% (level of confidence interval). Analysis of numerical data for characteristic index , showed that natural mineral waters of different sources of the Eurasian continent, irrespective of their geographical location, form a class of waters with similar ionic composition, which shows the unity of the genesis and metamorphism of hydro mineral resources (mineral waters and mud).

Systematic of Eurasian Mineral chloridesulphate waters on the value of the characteristic indicator and the ratio
X
Cl

X
Group of mineral waters 2 I BI I Sulphate CI Index subgroup (classes) 3 Title of water, ordinal number 4 Acqua de Cavabaa (Spain) (1) Batalinskay (Ru) (2) Rubeg (Ru)( 3) Lake B. Solenoje (Ru)(4) Kashinskaja (Ru) (5) Lake Sengileevskoje (Ru)(6)

SO 2 4

M
(g/dl) 5 86,550 20,949 7,982 243,68 2,825 0,234

Cl

X
6 0,061 0,131 0,197 0,201 0,201 0,204

SO 2 4

(g2 /

eqv2) 7

41550 16540 10820 10550 10580 11570

Group of mineral waters

Index subgroup (classes)

Title of water, ordinal number

M
(g/dl)

X Cl

X SO 2
4

(g2 / eqv2)
7770
9280 8250 6320 6396 5719 5854 4697 6071 4693 4072 4067 3643 3573 3940 3429 3300 3257 2701 2653

Kissinger Bitterwasser Heilwasser (G) (7)

34,890
4,110 0,193 4,094 11,945 10,052 4,350 145,65 2,980 2,714 2,050 3,957 17,724 22,982 0,987 3,301

0,234
0,256 0,263 0,342 0,345 0,356 0,360 0,426 0,454 0,460 0,525 0,540 0,543 0,547 0,575 0,654 0,658

AII

Staroeletskaja

(Ru) (8)

Slanic Moldova 8 bis (Rom) (9) Ugeichskaja (Ru) (10)

BII

Bujskaja (Ru) (11) Nickolina Balka (Ru) (12) Igevskaja (Ru) (13) Lake M. Solenoje (Ru) (14)

CII II Chloride -sulfate

Nezlobinskaja (Ru) (15) Krakowianka (Pol) (16) Irkutskaja (Ru) (17) Feodosiiskaja (Ukr) (18)

DII

Lake (mud mortans) B. Tambykan (Ru) (19) Lake B. Tambykan (Ru) (20) Dax (France) (21)

Lipezkij bjuvet (Ru) (22)

EII

Slanic-Moldova, 5 (Rom) (23) Anapskaja (Ru) (24) 3,067 18,165 2,850

0,708 0,744 0,791

FII

Lisogorskaja (Ru) (25) Don (Ru) (26)

Group of mineral waters

Index subgroup (classes)

Title of water, ordinal number Nigne-Ivkinskaja (Ru) (27) Ergeninskaja (Ru) (28) Novo-Igevskaja (Ru) (29) Kaspij (Ru) (30) (mud mortans), (Rom) (31) Solvichegodskaja (Ru) (32) (Ru) (33) Hilovskaja (Ru(34) Antonius Heilwasser (Ger) (35)

M
(g/dl) 7,599 5,700 15,420 6,416 75,346 8,850 10,547 3,535 2,136

X Cl

X SO 2
4

(g2 / eqv2) 1904 1945 1357 1045 873 878 768 765 937

1,024 1,040 1,458 2,047 2,107 2,157 2,300 2,315 2,331

AIII

BIII CIII DIII

III

Sulfatechloride

EIII

Mineralization, Group of mineral waters Index subgroup (classes) Title of water, ordinal number

Ratio
X Cl X SO 2
4

(g/dl)

Characteristic indicator , g2 / eqv2

Press water of dark-gray clay, sample 10 (Ru) (36) AIV (Rom) (37) Kujalnik 6 (Ukr) (38) BIV Maxbrunner Heilwasser (Ger) (39) (Ru) (40) Witjaevskij Liman (Ru) (41) IV Chloride Thermal Baths Scrajo (42)

15,499 73,238 3,197 6,926 16,031 70,579 14,159

4,091 4,320 5,348 5,889 6,572 8,442 8,877

476 402 367 372 263 198 212

DIV

Press water of dark-gray clay, sample 11 (Ru)( 43) World`s Ocean ( 44)

17,382 35,080 79,988 26,250

9,364 9,745 12,657 23,528

189 173 131 74

EIV FIV

(Ru)( 45) (Ru)(46)

3. Conclusion

a) Characteristic parameters , B and with a high degree of reliability allow the identification of waters of different ionic composition and mineralization, regardless of geographical coordinates of the location of their sources; b) Characteristic parameters , B and (calculated from the experimental data of chemical analysis of water) allow to assess water quality and can be used to organize national and pan-European monitoring systems of natural waters;

3. Conclusion

) Analytical dependence of the function ln = 7,6209 1,0572

X
Cl

SO 2 4

allows the quantitative identification of the various regional water on their corresponding analogues of standard mineral waters and their subsequent certification and standardization.

Thank you for listening me !