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Learning Objectives
Comprehension of the Advances in Polyurethane and Polyurea Technology Webinar will enable the participant to: List various types of polyurethane coatings Describe the properties of polyurethane coatings List various types of polyurea coatings Describe the properties of polyurea coatings Recognize two SSPC Performance-based Paint Standards for polyurethane and polyurea coatings
the basic performance differences between polyurethane and polyurea coatings Describe the surface preparation requirements for concrete and steel Describe the coating application equipment typically employed List the common applications (when and where polyurethane and polyurea coatings are used)
Basic Chemistry/Properties
Polyurethanes
Polyurethanes are formed by the reaction between a polyisocyanate and hydroxyl (-OH) containing resin blend
Polyurethanes
Polyurethanes
Waterborne formulations
100% Solids/Elastomeric
Polyurethanes
Waterborne formulations
Level 1 (<1000 hrs or <24 months) Level 2 (<2000 hrs or < 48 months) Level 3 (>2000 hrs or > 48 months)
Polyurethanes
Typically aliphatic Slower cure Excellent color and gloss retention Good chemical/solvent resistance Good hardness/abrasion resistance
Polyurethanes
100% Solids/Elastomeric
Polyurethanes
Elongation/flexibility Excellent chemical/solvent resistance Moisture sensitive application Can be applied in low temperatures (below freezing) Low VOC
Polyureas
Formed by the reaction between an isocyanate component and an amineterminated (-NH2) resin blend
Polyureas
Aromatic resins will yellow but not crack Aliphatic resins have excellent weatherability
Wide variety of formulations possible through particular resin blend Typically 100% solids
Polyureas
Elongation/flexibility Excellent chemical/solvent resistance Not sensitive to moisture during application Can be applied in low temperatures (below freezing) Thermal shock resistance Minimize down time Low VOC
Polyureas
Resin blend based on aliphatic polyaspartic ester Can have much slower reaction time Thinner film application Typical use is analagous to conventional polyurethanes
Polyurethane/Polyurea Hybrids
Hybrid coatings are formed by the reaction between an isocyanate component and a resin blend component
Resin blend may contain amine-terminated and/or hydroxyl-terminated polymers Wider range for reaction time and performance properties
Polyureas
Fast cure Moderate cure Hybrid systems SSPC Paint Specification No. 39
Type 1: Fast Drying (less than 30 minutes) Type 2: Moderate Drying (30 minutes to 2 hours) Weathering levels
Weathering Levels
Other tests
Solvent Resistance
Pull-Off Adhesion
Average (3 pulls) 600 psi Minimum 500 psi
Polyurethane vs Polyurea
Polyureas are faster cure, e.g. seconds Polyureas not moisture sensitive Polyurethanes cure slower but are moisture sensitive May have fewer adhesion problems with polyurethanes
Surface Preparation
Steel
Abrasive blast cleaning to SSPC-SP 10, Near White Angular surface profile
Surface Preparation
Concrete
Abrasive blast cleaning Profile/roughening required Specialized primer may be necessary Check moisture content
Application Equipment
Application Equipment
Heats and mixes resin (part A) and curing agent (part B) components automatically in correct proportions Paint mixture travels directly to spray gun for immediate application
Application Equipment
Storage to deliver unmixed material Proportioning Device Pressure Pump Mixing Device
Application Equipment
Equipment as recommended by coating manufacturer Requires trained/licensed applicators Involve coating manufacturer technical representative for projects Single application (multiple passes)
Application Equipment
Application Equipment
Application Equipment
Polyurethane Applications
Roof coatings Pipe Tank interior/exterior Truck bed liners Railcars Parking decks Anti-graffiti coatings Caulk/joint/sealant materials
Polyurea Applications
Roof coatings Pipe Tank linings Truck bed liners Railcars Parking decks Caulk/joint/sealant materials
Polyurethane Systems
Polyurethane Systems
Polyurethane Systems
Tensile strength: 5950 psi Elongation: 150% Taber abrasion: <45 mg loss/1000 cycles Graffiti resistance: Level 3, ASTM D6578
Polyurethane Systems
MEK double rubs, 300+ cycles Gasoline: no effect after 7 days 50% NaOH: no effect after 24 hours 10% HCl: no effect after 24 hours Toluene: no effect after 4 hours
Polyurethane Systems
Polyurethane Systems
Polyurethane Systems
Shore A hardness: 60 Adhesion to concrete: 350 psi Elongation: 400% Tear strength: 150 psi Tensile strength: 900 psi
Polyurethane Systems
Acetic acid, 10% Hyrdochloric acid, 10% Methanol Nitric acid, 10% Phosphoric acid, 10% Sulfuric acid, 30%
Polyurea Systems
Surface preparation: SP 10, profile 3 mils Application: 100% solids aromatic elastomeric polyurea @ 60 80 mils DFT
Polyurea Systems
Shore D hardness: 50 Elongation: 250% Tensile strength: 2125 psi Tear strength: 390 psi
Polyurea Systems
Acetic acid, 10% Ammonium hydroxide, 20% Hydrochloric acid, 10% Phosphoric acid, 10% Sulfuric acid, 10%
Polyurea Systems
Polyurea Systems
Polyurea Systems
Polyaspartic properties
Abrasion resistance: 90 mg loss/1000 cycles Adhesion: 825 psi Corrosion weathering: 15 cycles ASTM D5894, Rating 10 blistering/corrosion Freeze/thaw: 30 cycles, no adhesion loss
Shore D hardness: 60 Tensile strength: 2300 psi Elongation: 100% Tear resistance: 330 psi Taber abrasion: 25 mg/1000 cycles
Polyurethanes
Thin film conventional and waterborne Single component moisture cure 100% solids thick film 100% solids thick film No moisture sensitivity Thin film polyaspartics
Polyureas
Blast cleaning generally required Plural component application for 100% solids polyurethane/polyurea May allow for low temperature applications Minimize down time
Questions?