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Metallurgy of Welding
Mr. R.D.Pennathur
Metallurgy of Welding
Introduction Welding and heat treatment Physical changes Metallurgical property changes Conclusion
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Joining of Materials
Joining
Mechanical
Fasteners Soldering
Metallurgical
Brazing Welding
Bolting
Riveting
Adhesive Bonding
Mr. R.D.Pennathur
Welding Metallurgy
Prior to welding as a useful fabrication, riveting was extensively used for joining
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Joining of Materials
Mechanical Joining- Demerits Interfaces- fretting fatigue, fretting corrosion, crevice corrosion. Extra manufacturing steps Additional weight- energy inefficient Cost- materials, manufacturing and above all. Stress concentration!
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Joining of Materials
Metallurgical Joining- Scores over Mechanical joining due to No interface Less weight Faster Ease of operation, in situ welding.. Suitable for different joint types Cost effective
Mr. R.D.Pennathur
Welding Metallurgy
Welding dispenses with the disadvantages Is it totally free of disadvantages? No, but advantages often outweigh such demerits- faster, safer, cost effective
Mr. R.D.Pennathur
Welding Metallurgy
Welding almost always requires application of heat
Mr. R.D.Pennathur
Welding Metallurgy
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Is grain size change/orientation only the change? Does not heat treatment take place? Yes!
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Cooling Rate
Cooling rate depends on
R 1/T0*H
Where R is cooling rate, C/sec T0 is preheat temperature, C H is Heat Input, kJ/mm
Mr. R.D.Pennathur
kJ / mm
For other welding process divide by following factors SAW ( single wire ) - 0.8 GTAW - 1.2 GMAW - 1.0
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Mr. R.D.Pennathur
In metals the atoms are arranged in well defined geometric arrangements/ patterns that get repeated in all three directions. These are called crystal structures
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Single Crystal
Unit Cell
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Poly-crystal
Grain boundary
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Grain Boundary
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Structural Changes
Metal/alloy may be of:
Single crystal structure up to melting point More than one structure within the solid state
It is pertinent to discuss only STEEL here since it is the most important industrial alloy extensively used for welding
Mr. R.D.Pennathur
Body centered cubic crystal (BCC)Structure of iron at RT- iron up to 910 deg C
Face centered cubic crystal (FCC) High temperature structure of iron iron between 910 deg and 1400deg C Reverts back to BCC ( iron) between 1490 and 1530 deg C Melts at 1530 deg C
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Either they can substitute the iron atoms in their equilibrium sites or can settle in the gaps between the iron atoms.
Substitutional and interstitial solid solutions
Mr. R.D.Pennathur
Crystal Structure
Is there a limit to solid solubility? What happens if it is limited? What happens beyond its solid solubility? Alloying elements beyond solubility limits are present as different phases/compounds/precipitates The limit varies with temperature
Mr. R.D.Pennathur
Mr. R.D.Pennathur
STEEL
The uniqueness of steel as the most widely used engineering material depends on its ability to get heat treated to different levels of strength and toughness! Heat treatment itself is made possible because of two factors: Different crystal structures in solid state Solubility variation of these structures
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Mr. R.D.Pennathur 48
Preheating helps reduce hardness of HAZ by extending time it spends between 800-500deg C
Mr. R.D.Pennathur
Carbon 0.80%
Slow cooling condition is called equilibrium rate of cooling. But, do we get such condition in heat treatment or welding? Far from that!!
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Heat treatment enables different structures to be obtained from the same material
Figure 2 Microstructure of medium carbon steel resulting from normalizing heat treatment, showing ferrite and pearlite
Figure 4 Martensite microstructure of medium carbon steel resulting from water quenching
Mr. R.D.Pennathur
Heat Treatment
Normalized
After Spheroidizing
Martensite : Very hard and brittle phase. Formed on rapid cooling below Ms temperature Tempered Martensite : However has a good combination of strength and toughness and is a useful structure and is developed by reheating martensite Hardness depends on carbon content of steel
Carbon % Hardness Rc 0.1 38 0.2 44 0.3 50 0.4 57
Martensite
0.5 60
0.6 63
0.8 65
Mr. R.D.Pennathur
Bainite
Formed in alloyed steels when austenite is cooled rapidly passed the nose of the C-curve . Extremely fine mixture of ferrite + carbide but not lamellar like pearlite Formed between 500 220 C Upper Bainite or lower Bainite depending on temp. Has higher hardness and toughness than pearlite
Mr. R.D.Pennathur
Mr. R.D.Pennathur
0.20
1.50
0.50
0.05 Nb
0.25
1.50
0.50
410 min
540 - 660
SAILMA 450
0.25
1.50
0.50
450 min
570 - 720
SAILMA 450HI
0.20
1.50
0.50
Nb+V+Ti =0.20
450 min
TISTEN 60
0.20
1.80
0.50
0.20
440 min
Mr. R.D.Pennathur
Introduction of higher strength steels to reduce weight and cost of structure Alloying elements added to develop strength Lead to more complex metallurgical changesMr. R.D.Pennathur
Toughness
Welded structures require good toughness, ability to absorb impact Measured by Charpy test Charpy values are specified for welds requiring good toughness RT as well as at subzero temperatures
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Hydrogen Cracking
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Weldability
Steels with Carbon Equivalent (C.E.) value less than 0.40% have good weldability This means that no detrimental hard microstructures result in WZ and HAZ Such steels do not require any pre or post heating C.E.> 0.40% require either pre or post heating or both.
Mr. R.D.Pennathur
Why Preheating?
The cooling rate, particularly from 800 deg to 500 deg C (T800-500), is important that decides the microstructure, from TTT diagrams The nose of the TTT curve is shifted towards right for hardenable steels and hence harder microstructures tend to form
Mr. R.D.Pennathur
Post Heating
When martensite cannot be avoided, post heating is carried out PWHT reduces the brittleness by tempering the martensite
Mr. R.D.Pennathur
Weldability is defined as the capacity of a metal to be welded under the fabrication conditions imposed, into a suitable designed structure, and to perform satisfactorily in the intended service Weldability is the ease with which a metal can be welded to give the required service Weldability is the number of problems you face to weld a material
Weldability
Mr. R.D.Pennathur 77
WELDABILITY PROBLEMS
Cracking - In the weld solidification cracks -- micro-fissuring - In the HAZ Hydrogen cracking - Liquation cracks Porosity Oxidation of reactive metals Reduced joint strength - In the weld - In the HAZ Reduced corrosion resistance
Mr. R.D.Pennathur
Mr. R.D.Pennathur
Solidification Cracking
Lamellar Tearing
Is generally associated with welding of fairly large highly restrained structures Occurs predominantly in plate material Due to presence of non metallic inclusions Difficult to detect by NDT techniques. Maybe assessed by STRA of tensile test in short transverse direction Cracks can occur in parent plate / HAZ and generally run parallel to the plate surface
Mr. R.D.Pennathur
Lamellar tearing
Prevention: Use joint designs that minimise transverse constraint & butter with a softer layer
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Sensitization in SS Welding
Chromium in solid solution gives corrosion resistance If slow cooled from 950 to 400 deg C, Cr23 C6 precipitates and segregates to grain boundaries depleting the matrix of Cr, particularly close to GBsensitization
Mr. R.D.Pennathur
Sensitization in SS Welding
Normally SS is quenched from high temperature to retain the Cr23C6 in solid solution- called solution annealing The treatment is carried out at 1050 deg C in vacuum or hydrogen atmosphere If SS is welded and allowed to slow cool, Cr23C6 precipitates If assembly permits, it can be resolutionized
Mr. R.D.Pennathur
Sensitization in SS Welding
HAZ of weld of 316 where the grain Boundaries show Cr23 C6 precipitation.600X
Mr. R.D.Pennathur
Sensitization in SS Welding
If it is not possible, use low carbon or extra low carbon SS grades, to prevent Cr23 C6 formation Alternately use stabilized grades having Nb or Ti These with better affinity for C forms the respective carbides which h precipitate within the grains and Cr is not affected
Mr. R.D.Pennathur
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