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Dr. K.C. Yadav, AVP & Head, Noida Technical Training Centre
Learning Agenda
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Thermodynamic Properties
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Thermodynamic Processes
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Thermodynamic Processes
Flow Processes
P=C, V=C T=C Poly Isent Ws=0 Q=H2-H1 U=mCvdT W=-vdP Q=U2-U1 U=mCvdT W=RTln(p2/p1) Q=W U=0 W=nm(p1v1-p2v2)/(n-1) Q=(r-n)W/n-1 U=mCvdT W=rm(p1v1-p2v2)/(r-1) Q=0 U=mCvdT
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q+hi+ci**2/2+gzi = w+he+ce**2/2+gze
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Nozzles; C2 = sq root of [2(h1-h2)+C1**2] Diffuser; C2 = sq root of [2(h1-h2)+C1**2] Centri. Pump; p2v2 - p1v1 + (C2**2 C1**2)/2 + g(z2-z1) Turbine; W = h2-h1 : Compressor; W = h2-h1 Condenser; q = h2-h1 : Boiler; h2-h1 Throttling; h2 h1 = 0 : Free Expansion; h2 h1 = 0
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Ice Water Ice Cycle Water Steam Water Cycle Steam Ice Steam Cycle Water Steam Ice Water Cycle
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Water
Steam
Steam
Ice
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Steam
Water
Ice
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Water/Steam Cycles
Natural Cycle
Carnot Cycle Rankine Cycle (Thermal Cycle)
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Carnot Cycle
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Carnot Cycle
Temp
Entropy
= 1 T /T = 1- T /T
1 2 R
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Rankine Cycle
Boiler
Turbine
Condenser
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Why Rankine Cycle for a Coal Fired Thermal Power Plant? Does not it related to:
Coal combustion problems at a desired high pressure? High erosion rate of the prime mover due to highly erosive
Metallurgical impossibility?
Techno-economic feasibility?
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Heat added He Hf Wp He Hf Wp = = He Hf Wp
He hb
He-ha (hb-ha)
He ha Wp
He Hf He ha
Cycle Efficiency is function of heat addition and rejection temperatures (Ta & Tr)
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suitably changed by
High boiler working pressure High steam temperature at boiler outlet High condenser vacuum Reheating cycle Regenerative feed heating Cycle
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Variation in water/steam properties (S, L, Cp & Cv) at higher parameters improve Cycle Efficiency
Thermal Cycle Efficiency Turbine output = Heat added to steam =
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Reheating cycle
High pressure steam cannot be heated beyond the metallurgical limits and hence reheated after temperature reduction in some of the high pressure stages. Thus the
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Two curved lines above each water pressure raising lines (b-c & d-e), represent sensible heat addition in Drain Cooler, Gland Steam Condenser, Low Pressure Heaters, Deaerator, High Pressure Hearters and Economizer
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Two curved lines (f-g & h-i) before the expansion stages, represent sensible heat addition to steam (i.e.
Two stage steam expansion processes in High Pressure Turbine and Intermediate Pressure / Low Pressure Turbines are represented by two vertical lines (g-h & i-j) at the right of TS diagram
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Properties of H2O
Density
Relative density
Specific gravity Specific heat Sensible heat Latent heat
Freezing/melting temperature
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Properties of H2O
Boiling/condensing/saturation temperature Critical temperatures Triple point temperature Vapour pressure Saturation pressure Critical pressure Triple point pressure Viscosity Electrical conductivity Thermal conductivity
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Properties of H2O
Physical Stability
Chemical Reactivity
- Non toxic - Non corrosive)
Behavior in terms absorption, adsorption and solution Cohesive and adhesive forces Surface tension Internal energy Enthalpy Entropy
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Variation in H O Properties
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No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
Ts deg C 0.1 4 15 46 100 165 200 235 250 300 350 355 360 365 370 374.15
Ps Vf Vg bar cubic meteter per Kg 0.0061 0.001 206.31 0.0081 0.001 157.27 0.017 0.001001 77.978 0.1008 0.00101 14.557 1.0133 0.001044 1.675 7.0077 0.001108 2724 15.549 0.001156 0.1272 30.632 0.001219 0.0652 39.776 0.001251 0.05 85.927 0.001404 0.0216 165.35 0.001741 0.0087 175.77 0.001809 0.008 186.75 0.001896 0.0072 198.33 0.002016 0.006 210.54 0.002214 0.005 221.2 0.00317 0.0032
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Hf KJ/Kg 0 16.8 62.9 188.4 419.1 697.2 852.4 1013.8 1085.8 1345 1671.9 1716.6 1764.2 1818 1890.2 2107.4
Hfg Hg KJ/Kg KJ/Kg 2501.6 2501.6 2492.1 2508.9 2466.1 2529 2394.9 2583.3 2256.9 2676 2064.8 2762 1938.5 2790.9 1788.5 2802.3 1714.6 2800.4 1406 2751 895.8 2567.7 813.8 2530.4 721.2 2485.4 610 2428 452.6 2342.8 0 2107.4
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Steam Generation
Heating Surface Phenomenon Water Surface Phenomenon Due to occurrence of vapour pressure Due to occurrence of low relative humidity
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Wet Steam
- Either saturation temperature or saturation Pressure
- dryness fraction (DF) = Ms/M(s+w)
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Thank you
4th October, 2008