Possibility of gas escaping from enclosed pipe work with a risk of explosion and/or toxic hazard. Risk from lack of oxygen leading to suffocation or incomplete burning which would lead to CO poisoning. Risk from oxygen enrichment and fire hazard. Toxicity with risk of poisoning the life support system. Risk of explosion or fire from flammable gases. To certify atmosphere is safe for personnel to work in. 2 GAS TESTING COURSE SAFE ATMOSPHERE . Air = 78% Nitrogen, 21% Oxygen, 1% Argon, etc.. Safe level 19 - 23% Oxygen. Oxygen deficiency: 19% Minimum permissible oxygen level. 15 - 19% Decreases ability to work. 12 - 14% Respiration increased with work, pulse up 10 - 12% Impaired co-ordination and judgment. 8 - 10% Mental failure, nausea and fainting 4 - 8% Respiration ceases and death occurs Oxygen enrichment enhances combustion causing materials that would not normally burn to ignite e.g. steel wool. Incomplete burning caused by oxygen deficiency during welding or cutting operations may produce toxic by-products e.g. Carbon Monoxide Gas monitoring instruments need minimum of 13 % O2. 3 The temperature at which a substance will ignite when an outside ignition source is applied, i.e. methane remains a gas at all temperatures and has no flashpoint temperature.
Propane gases off at 105C and will ignite once an ignition source is applied. GAS TESTING COURSE IGNITION TEMPERATURE .
FLASHPOINT 4 Sometimes known as the spontaneous ignition temperature or just as the ignition temperature. Heating a gas so that it will ignite spontaneously without an outside ignition source being applied. Methane 590C Propane 467C At certain concentrations in air, all petroleum gases will ignite at normal temperatures once an outside ignition source has been applied. Provided no ignition sources are applied it will take extreme heating of the gas for it to spontaneously ignite. GAS TESTING COURSE IGNITION TEMPERATURE .
AUTO IGNITION TEMPERATURE 5
LEL AND UEL Lower Explosive Limit - Given as a percentage mixture by volume compared to that of air the lowest percentage mixture when ignition could take place.
Upper Explosive Limit - The highest percentage mixture by volume in air when ignition could take place. GAS TESTING COURSE RANGE OF FLAMMABILITY .
A gas will only ignite in air if it is in the correct mixture. Too Lean - Insufficient gas vapour in air to ignite Too Rich - Insufficient air for gas mixture to ignite.
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SIMPLE ASPHYIANTS Gases such as Methane, Carbon Dioxide and Nitrogen have no effect on the body in small doses. Large volumes of these gases will reduce the oxygen content in the atmosphere to cause suffocation.
CHEMICAL ASPHYXIANTS Gases such as Carbon Monoxide, Hydrogen Sulphide can poison the life support system. These types of gases can cause sickness, paralysis or death even when in the atmosphere in minute concentrations. GAS TESTING COURSE TOXICITY OF A GAS
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GAS TESTING COURSE TOXICITY OF A GAS
IRRITANTS Substances such as Sulphur Dioxide, Chlorine and Ammonia can irritate the respiratory tract, and lungs.
BLOOD POISONS Substances such as Benzene, Arsine can damage red and white blood cells
8 OCCUPATIONAL EXPOSURE LIMITS (OEL) Limit below which no health damage can occur. i.e. dose at which a person can cope. OEL set by Health and Safety Executive (HSE) published annually in Guidance Note EH/40 Maximum Exposure Limit (MEL). Occupational Exposure Standard (OES) Long term Exposure Limit (LTEL) 8 hour time weighted average. Short Term Exposure Limit (STEL) Single 10 minute exposure threshold limit Value (TLV) GAS TESTING COURSE EXPOSURE LIMITS
9 Gases that are lighter than air have a number less than 1 e.g. Methane 0.55 Gases that are heavier than air have a number greater than 1 e.g. H2S 1.2
GAS CLOUDS Gases move from place to place under two influences: Gravity and natural buoyancy, normal turbulence In event of a leak gases remain mixed until each component is removed by condensation, diffusion or bulk air movement. -Natural and Mechanical ventilation affects the movement of gas/air mixtures. GAS TESTING COURSE DENSITY
10 WARNING DEVICES Both audio and visible alarms are situated on each instrument to alarm at a designated reading. i.e. 19%+23% for oxygen
10% LEL for flammable gases
10 ppm for Hydrogen Sulphide GAS TESTING COURSE GAS METERS